Sample Paper 2008 Class XII Subject - Chemistry Time: Three Hours 1. All questions are compulsory. 2.

2. Question nos. 1 to 8 are very short answer questions and carry 1 mark each. 3. Question nos. 9 to 18 are short answer questions and carry 2 marks each. 4. Question nos. 19 to 27 are also short answer questions and carry 3 marks each . Question nos. 28 to 3! are lon" answer questions and carry marks each #. $se lo" ta%les i& necessary' use o& calculators is not allowed. 1. 2. 3. 4. . (hat type o& dru" pencillin is) *ive one e+ample o& %iode"rada%le polymer) (hat is meant %y anomers) (rite ,witter ion o& amino acetic acid. *ive the -$.A/ name o& the &ollowin" compounds0 Max.Marks: 70

1 1 1 1

#. 7. 8. 9. 1!. 11. 12.

(hy propanol has hi"her %oilin" point than that o& the hydrocar%on' %utane) *ive the chemical &ormula &or the compound potassium he+acyanoco%altate 1---2 3tate 4ardy53chul,e rule. *ive three di&&erences %etween amorphous and crystalline compounds) An element has a %ody centred cu%ic 1%cc2 structure with s cell ed"e o& 288pm. 6he density o& o& the element o& 7.2"7cm3. 4ow many atoms are present in 2!8" o& the element) 3tate 8aoult9slaw &or a solution o& volatile liquids. /alculate the equili%rium constant &or the reaction0 :n1s2 ; /u;21aq2 :n;21aq2 ; /u1s2' *iven0 <o:n;27:n = 5!.7#3> and <o /u;27/u = ;!.34>.

1 1 1 2 2 2

2 2

13.

(hat is lanthanoids contraction) (hat are the consequences o& lanthanoids contraction)

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$sin" valance %ond theory' predict the "eometry and ma"netic %ehaviour o& ?@i/l4A52. (hat are amident nucleophiles) <+plain with suita%le e+ample. <+plain why tert5%utyl chloride reacts with aqueous sodium hydro+ide %y 3@1 mechanism while n5%utyl chloride reacts %y 3@2 mechanism)

2 2 2

Bistin"uish %etween Cchain "rowth polymerisation9 and Cstep "rowth polymerisation9 and "ive one e+ample o& each type. 2 Be&ine the &ollowin" and "ive one e+ample o& each0 i2 Antihistamines ii2 Antacids a2 Be&ine vitamins and state their classi&ication. Dist two vitamins o& each class. %2 (hat are en,ymes) 3tate the activity o& an en,yme. *ive reason0 i2 -t is di&&icult to prepare pure amines %y ammonolysis o& alkyl halide. ii2 Aniline is a weaker %ase than cyclohe+ylamine. iii2 Amines have lower %oilin" points than those o& the correspondin" alcohols. <+plain the &ollowin" with suita%le e+ample0 i2 Eol%e9s reaction ii2 8eimer56iemann reaction iii2 (illiamson ether synthesis. -ndicate the steps in the preparation o& E2/r2F7 &rom chromite ore. /omplete the &ollowin" reactions0 i2 -2 ; @a/lF3 iii2 GeH2 ; 42F ii2 -2; 32F352 3 3 2 2

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22. 23.

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(rite short notes on the &ollowin" "ivin" e+ample0 i2 Ia"netic separationA ii2Aluminothermic process. iii2 Diquation 3tate what is o%served when0 i2 the electrodes connected to a %attery are dipped into a sol. ii2 an electrolyte solution is added to a sol. iii2 an emulsion is su%Jected to hi"h speed centri&u"ation. a2 (hat is corrosion) (hat are the &actors which a&&ect corrosion) /F2 always present in natural water. <+plain its e&&ect 1increases' stops or no e&&ect2 on rustin" o& He. %2 *ive the cell reaction in 425F2 &uel cell. Betermine the amount o& /a/l2 1 i= 2.472 dissolved in 2. litre o& water such that its osmotic pressure is !.7 atm at 27o/.

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2#.

3 3

27.

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a2 6ime required &or 1!K completion o& a &irst order reaction at 298E is equal to that required &or its 2 K completion at 3!8E. -& the value o& A is 4 + 1!1!s51.calculate k at 318E and <a. %2 Account a%out pseudo &irst order reaction with suita%le e+ample. c2 3how that in a &irst order reaction' time required &or completion o& 99.99K is 1! times o& hal&5li&e 1t1722 o& the reaction. i2 Ge has hi"hest polarisin" power. (hy) ii2 4alo"ens are coloured. (hy) iii2 @o%le "ases are mostly chemically inert. (hy) iv2 @itro"en does not &orm pentahalide. (hy) v2 Lismuth is a stron" o+idisin" a"ent in pentavalent state. (hy) a2 An or"anic compound CA9 /84# on treatment with dilute 423F4 containin" mercuric sulphate "ives compound CL9. (hich can also %e o%tained &rom a reaction o& %en,ene with acid chloride in the presence o& Al/l3) CL9 on treatment with -2 in aq.EF4 "ives C/9 and yellow compound CB9. -denti&y A'L'/ and B. *ive the chemical reactions involved. %2 4ow will you convert0 i2 acetophenone to ethyl %en,ene ii2 propanone to 25.ropanopl. 3tate conditions and reactions in each case. -----------------------------all the best-----------------------

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Posted by: Mr.VINTU.P.VARGH ! M!" UG# N T !e$.Gr. %e"turer &e'artme(t o) #hemistry TAN& M *U+AIT