11

th
(P&J) (Date: 10-02-2013) Final Test
PAPER-2
Code-A
ANSWER KEY
MATHS
SECTION-2
PART-A
Q.1 D
Q.2 A
Q.3 C
Q.4 B
Q.5 C
Q.6 A
Q.7 B
Q.8 A
Q.9 D
Q.10 BC
Q.11 BD
Q.12 CD
Q.13 AB
PART-B
Q.1 (A) Q, S;
(B) P, R;
(C) Q, R
PART-D
Q.1 0840
Q.2 0013
Q.3 0003
Q.4 0003
Q.5 0019
PHYSICS
SECTION-3
PART-A
Q.1 C
Q.2 C
Q.3 C
Q.4 D
Q.5 A
Q.6 B
Q.7 A
Q.8 A
Q.9 A
Q.10 AB
Q.11 AC
Q.12 BD
Q.13 BC
PART-B
Q.1 (A) P,Q,R,S
(B) P,Q
(C) Q,S
PART-D
Q.1 0005
Q.2 0003
Q.3 0020
Q.4 0020
Q.5 0029
CHEMISTRY
SECTION-1
PART-A
Q.1 C
Q.2 B
Q.3 D
Q.4 A
Q.5 C
Q.6 D
Q.7 D
Q.8 C
Q.9 C
Q.10 AD
Q.11 AC
Q.12 C
Q.13 AB
PART-B
Q.1 (A) P,S
(B) R,Q
(C) P,Q
PART-D
Q.1 0375
Q.2 0002
Q.3 0005
Q.4 8000
Q.5 0144
CHEMISTRY
Code A Page # 1
PART-A
Q.1
[Sol. ! (Mean free path) l

=
* 2
N 2
1
#$
l

%
*
N
1
%
&
'
(
)
*
+
V
n
1
%
V
n
If V and n are constant, l is constant
! Z
1
=
avg
* 2
U N 2#$
Z
1
% N
*
U
avg
%
V
n
U
avg
%
T .
T
P
%
T
P
! Average relative speed of approach =
2
U
avg
(Assuming avg. angle of approach = 90)
0
M
RT 8
2
#
, -
=
0
M
RT
4
#
-
]
Q.2
[Sol.
O O
(1)
>
O
>
O
>
) 4 (
OEt C CH
| |
O
3
. .

O
OH OH

3 3
CH C CH CH
|
OH
. - .
OEt C CH
|
OH
2
. -
]
Q.3
[Sol. N
2
O
4(g)
2NO
2(g)
Initial moles 1 0
At eq
m
moles 1 % 2%
K
P
=
) 1 (
P ) 2 (
2
2
% .
%
=
) 1 (
P 4
2
2
% .
%
CHEMISTRY
Code A Page # 2
2
2
) 1 . 0 ( 1
3 . 3 ) 1 . 0 ( 4
.
, ,
=
2
2
) 2 . 0 ( 1
P ) 2 . 0 ( 4
.
, ,
96 . 0
P 4
99 . 0
3 . 3
-
! P = 0.8 atm Ans.
Alternate solution
N
2
O
4
! 2NO
2
10% dissociation at 3.3 atm pressure
if P / extent of dissociation 0
1 P should be less than 3.3
hence (D) is the only option. ]
Q.4
[Sol.
F
E
F
Z E

Z
H
E 2 Opp side (higher priority)
Z 2 Same side (higher priority) ]
Q.5
[Sol.
N
H
: show inter molecular H-bonding having highest boiling point among given molecules.]
Paragraph for Question no. 6 & 7
Q.6
[Sol. H
4
P
2
O
7
H
2
S
2
O
7
Pyrophosphoric acid Pyrosulphuric acid
P
O
HO O
OH
P
O
OH
OH
S
O
O
O HO S
O
O
OH
p#d# = 2 p#d# = 4
acidic H = 4 acidic H = 2 ]
CHEMISTRY
Code A Page # 3
Q.7
[Sol. ! For meta acids at least 3 acidic hydrogen must be present in parent acid.
! For pyro acids at least 2 acidic hydrogen must be present in parent acid.
! Chloric acid (+5)
32 3
4O
Perchloric acid (+7) not peroxy chloric acid
Peroxy is used when theositical oxidation state is higher than maximum. ]
Q.8
[Sol. ! Radial part of wave function of 4p
x
and 3p
y
are not same.
! Radial part depends on n and l and angular part depends on l and m]
Q.10
[Sol. C
x
H
2y
O
y
Mol. Mass ! 12x + 18 y = 150
2x + 3y = 25 ......(i)
C
x
H
2y
O
y
+ xO
2
2 xCO
2
+ yH
2
O
taken n moles 4nx mole
(four times of
required quantity)
After reac
n
0 3nx moles nx mole ny mole
Given ny =
18
9 . 0
= 0.05 ......(ii)
3nx + nx =
300 0821 . 0
1 926 . 4
,
,
= 0.2 ....(iii)
dividing (iii) by (ii)
4
y
x 4
-
1 x = y
Substituting in eq. (i) x = y = 5
Hence compound is C
5
H
10
O
5
Mass % of H =
%
15
100
100
150
10
- ,
If 10 ml of organic compound is taken, oxygen taken should be 4 10 5 = 200 ml ]
Q.12
[Sol. (A)
NH
2
CH
3

NH
2
more basic
SIP
(B)
COOH
CH
3
>
COOH
more acidic due to ortho effect
CHEMISTRY
Code A Page # 4
(C)
NMe
2
CH
3
>
NMe
2
more basic due to SIR effect
(D)
NO
2
CH
3
2 There is no resonance between NO
2
group & benzene ring due to SIR effect ]
Q.13
[Sol. (A) IE of Kr < He or EA of He
+
> Kr
+
So He
+
gains electron from Kr and releases energy.
(B) IE of Si < Cl
(C) IE of Cl

> I

or EA of Cl > I
(D) IE of O

< S

or EA of O < S ]
PART-B
Q.1
[Sol. (A) Enol is more stable than Keto form
(B) HCN is more stable than HNC
(C) HPO(OH)
2
is more stable than P(OH)
3
due to resonance. ]
PART-D
Q.1
[Sol. | 5P | =
6
6
d
h
2
5x =
6
6
, #
-
5 #
d
h
4
h
P 4
h
2
=
6 , #
6
d 4
2
=
01 . 0 4
) 150 (
2
# , #
#
=

4
100 150,
=
nm
4
1500
= 375 Ans. ]
Q.2
[Sol.
CH
2
CH
2
GG G

net
= 0.8 D and X
anti
= 0.6
g
= ?
X
anti
+ X
gauche
= 1
X
gauche


=

1 X
anti
= 1 0.6 = 0.4

net


=

gauche
X
gauche
0.8 D =
g
0.4

g
=
4 . 0
8 . 0
= 2D
g
= 2 Debye ]
CHEMISTRY
Code A Page # 5
Q.3
[Sol. IE of Li < Be > B
C < N > O
Si < P > S
Al < Ga > In
Na < Mg > Al ]
Q.4
[Sol. Boyle's Temperature of the gas T
B
=
Rb
a
=
1 . 0 0821 . 0
105 . 4
,
= 500K
At T
B
gas behaves like an ideal gas
(for low pressure)
d =
RT
PM
0
=
500 0821 . 0
2 . 164 2
,
,
g/L
=
5 21 . 8
2 . 164 2
,
,
g/L = 8 g/L = 8000 g/m
3
]
Q.5
[Sol. Na
+
Mg
+2
Z 11 12
config.
6 2 2
p 2 s 2 s 1 1s
2
2s
2
2p
6
3s
1
$ = 2 0.85 + 7 0.35 2 1 + 8 0.85
- 4.15 8.8
Z
eff
6.85 3.2
I.E. = 13.6
2
eff
n
Z
159.5 15.5
Difference = 144 ]
MATHEMATICS
Code A Page # 1
PART-A
Q.1
[Sol.
!
"
#
"
sin
3
sin
x
C sin
h
.....(1)
and
!
"
#
"
2 sin
4
sin
x
B sin
h

3 4
C B
A
x
! $!
x
h
# %&#
D
'
!
"
! 2 sin
4
sin
3
3
4
cos 2 " !
3
2
cos " !
. Ans.]
Q.2
[Sol. y = x
2
2 ; x
2
+ y
2
= 8
x
2
= y + 2 ; y
2
+ y + 2 = 8
y
2
+ y 6 = 0 ( y
2
+ 3y 2y 6 = 0
( (y + 3) (y 2) = 0 ( y = 2 or y = 3 (rejected)
If y = 2; x = 2 or 2
' B (2, 2) ; C = (2, 2) and A (0, 2)
( Area of *ABC =
2
4 4+
= 8. Ans.]
Q.3
[Sol. S = 1 C
0
+ 2 C
1
+ 3 C
2
+ ........ + 15 C
14
Re-writing the sum as reverse order
S = 15 C
0
+ 14 C
1
+ 13 C
2
+ ....... + C
14
.

2S = 16 [C
0
+ C
1
+ C
2
+ ...... + C
14
] = 16 2
14
S = 2
3
2
14
= 2
17
( (B)
Aliternatively:
Consider expansion of (1 + x)
14
. Multiply both sides by x. Differentiate w.r.t. x and put x = 1 to get the
answer.]
Q.4
[Sol. Total 3
4
Not onto = 3
4
number of onto functions
Onto function =
! 2 ! 2 ! 1 ! 1
! 3 ! 4
= 36
1
3
2 4
a
c
b
A B
f
' Not onto = 81 36 = 45. Ans.]
MATHEMATICS
Code A Page # 2
Q.5
[Sol. Circle x
2
+ y
2
4x 8y 5 = 0. Centre , (2, 4), radius =
5 16 4 - -
= 5
If circle is intersecting line 3x 4y = m, at two distinct points,
( length of perpendicular from centre < radius of circle.
(
5
m 16 6 & &
< 5 ( | 10 + m| < 25 ( 25 < 10 + m < 25 ( 35 < m < 15
( Number of integral values = 49 Ans.]
Paragraph for Question nos. 6 & 7
[Sol. Area of triangle ABC =
2
9 12 12 5 -
= 30 + 54 = 84
' R =
* 4
abc
=
84 4
15 14 13
13
12
D
15
A(5, 12)
3
4
m
&
"
C (14,0)
x
y
B
5 9
14
H
N
P (c, c)
R =
6 4
15 13
=
8
65
( (B)
Equation of BH is, y = x
4
3
Equation of AD is, x = 5
' H ,
.
/
0
1
2
3
4
15
, 5
H G P (c, c)
.
/
0
1
2
3
4 ,
3
19
.
/
0
1
2
3
4
15
, 5
Also, G ,
.
/
0
1
2
3
4 ,
3
19
(Centroid of the triangle)
' PH =
2
3
GH ........(1)
Now, GH =
2 2
4
15
4 5
3
19
.
/
0
1
2
3
& -
.
/
0
1
2
3
& =
16
1
9
16
-
=
12
9 256-
=
12
265
' PH = .
/
0
1
2
3
2
3
12
265
=
8
265
,
n
m
' (m + n) = 273. Ans.]
Q.8
[Sol. 4 5 4 5 4 5 4 5 1 ) 2 ( f ) 3 ( g f ) 3 ( g f ) 1 ( h g f " & " & & " "
4 5 4 5 4 5 4 5 1 ) 1 ( g ) 1 ( g ) 5 ( h g ) 5 ( h g ) 3 ( f h g & " & " & " & " & "
4 5 4 5 4 5 4 5 4 5 4 5 ) 0 ( h ) 1 ( f h ) 1 ( f h ) 1 ( g f h ) 1 ( g f h " " & " & " &
as h is odd ( h (x) + h (x) = 0
h (0) + h (0) = 0 ( h (0) = 0 ( sum of composite functions is zero.]
MATHEMATICS
Code A Page # 3
Q.9
[Sol. y = {e
x
}=
6
7
6
8
9
: ; &
: ; &
: : < &
3 n x 2 n ; 2 e
2 n x 0 ; 1 e
0 x ; e
x
x
x
l l
l
x= n1 l

y=1
Y

x= n2 l x= n3 l
X
Graph of y = {e }
x
and so on
Clearly f(x) is aperiodic on R. ]
Q.10
[Sol. The chords are of equal length, then the distances of the centre from the lines are equal.
Let L
1
be y mx = 0. Centre is
.
/
0
1
2
3 &
2
3
,
2
1
1 m
2
m
2
3
2
-
&
&
=
2
1
2
3
2
1
& &
( 7m
2
6m 1 = 0
( m = 1,
7
1 &
. ]
Q.11
[Hint: Let r be the radius of required circle.
Now, if two circles touches each other then
distance between their centres = 2 r = = 5 (given)
' r = 3, 7
Note: Equation of circles are x
2
+ y
2
= 9 or x
2
+ y
2
= 49]
Q.12
[Sol. 3x 4y + 2 = 0
4x 3y + 5 = 0
Bisectors are 3x 4y + 2 = (4x 3y + 5)
Positive sign 3x 4y + 2 = 4x 3y + 5
x + y + 3 = 0 (containing origin)
Negative sign 3x 4y + 2 = 4x + 3y 5
7x 7y + 7 = 0
x y + 1 = 0 (not containing origin)
Acute/Obtuse
a
1
a
2
+ b
1
b
2
= 0
3 (4) + ( 4) ( 3) = 0
(12) + (12) = 24 > 0
Positive Sign obtuse angle bisector
Negative Signacute angle bisector
x + y + 3 = 0 bisects the obtuse angle containing the origin and
x y + 1 = 0 bisects the acute angle containing the origin. ]
MATHEMATICS
Code A Page # 4
Q.13
[Sol. (A) f (x) =
>
?
@
0 x if x
0 x if 0
0 x if x
:
"
A
( f (x) (bijective
(B) g (x) = x
3/5
obvious bijective
(C) h (x) = x
4
+ 3x
2
+ 1
A polynomial of degree 4 defined from R to R is always into ( not bijective
(D) k (x) =
2 x x
6 x 7 x 3
2
2
& &
- &
N
r
> 0 and D
r
< 0 ( k (x) < 0, B x C R ( into
also k ' (x) = 0 ( x =
2
hence not bijective ]
PART-B
Q.1
[Sol.
(A) f
1
(x) =
4
3
x
4
1
2
1
x
- &
-
( 1
(B) f (g(x)) =
x ) 1 r ( 1
rx
& -
, g( f(x) ) = r x. If f (g(x)) = g( f(x) )
(
x ) 1 r ( 1
rx
& -
= r x ( rx D
E
F
>
?
@
& -
&
x ) 1 r ( 1
1
1
= 0
If this is to be true for infinitely many (all) x, then r = 0 or r 1 = 0 ( 2
(C) Given f (x) = 2x + 1
4 5 ) x ( f f = 2(2x + 1) + 1 = 4x + 3, 4 5 4 5 ) x ( f f f = 8x + 7 ; 4 5 4 5 4 5 ) x ( f f f f = 16x + 15
Now L.H.S = 30x + 26
So 30x + 26 = 116 ( 30x = 90
Hence x = 3. Ans.]
MATHEMATICS
Code A Page # 5
PART-D
Q.1
[Sol. Select 3 places for A, B, C in
7
C
3
way
and arrange them only in 1 way.
Remaining 4 places can be arranged in 4! ways
' Total ways =
7
C
3
4! = 35 24 = 840. Ans.]
Q.2
[Sol. Let a
1
= a d; a
2
= a ; a
3
= a + d
Hence, a d + a + a + d = 18
' a = 6 ( a
1
= 6 d ; a
2
= 6; a
3
= 6 + d
Given that
a
1
+ 1, a
2
, a
3
+ 2 in G.P.
7 d, 6, 8 + d in G.P.
' 36 = (7 d) (8 + d) ( 36 = 56 d d
2
( d
2
+ d 20 = 0
( (d + 5) (d 4) = 0 ( d = 4 or 5
a
1
= 2 or a
1
= 6 + 5 = 11
Sum of all possible values of a
1
= 13. Ans.]
Q.3
[Sol. a (x
2
x + 1) (x
2
+ x + 1) G 0
a G
1 x x
1 x x
2
2
- &
- -
; a G
1 x x
x 2 ) 1 x x (
2
2
- &
- - &
a G 1 +
1 x x
x 2
2
- &
; a G 1 +
1
x
1
x
2
&
.
/
0
1
2
3
-
; a G
max
1
x
1
x
2
1
D
D
D
D
E
F
&
.
/
0
1
2
3
-
-
Now for x G 2
min
x
1
x
D
E
F
-
=
2
5
a G 1 +
3
2 2
; a G 1 +
3
4
or a G
3
7
Smallest integral value = 3. Ans.]
Q.4
[Sol. | 9a 72 | + | 8b + 96 | + | 23 c 69 | = 0
This is possible if each term is zero.
Hence, a = 8; b = 12 and c = 3.
' Circle is x
2
+ y
2
+ 8x 12y + 3 = 0 .......(1)
r = 3 36 16 & - = 49 = 7
Now, given that circle (1) is orthogonal
with the circle x
2
+ y
2
+12 x + 2ky + 9 = 0 .......(2)
Hence, 2 (4) (6) + 2 ( 6) (k) = 12 ( 48 12 = 12k ( k = 3. Ans.]
MATHEMATICS
Code A Page # 6
Q.5
[Sol. Let
15
%
= ! ( 15! = % and ! = 12
(sin 2! + sin 4!) + (sin 7! sin !) ( 2 sin 3! cos ! + 2 cos 4! sin 3!
2 sin 3! [cos 4! + cos ! ] ( 2 sin 36 [cos 48 + cos 12]
2 sin 36 [2 cos 30 cos 18] ( 3 2 sin 36 cos 18
3 [sin 54 + sin 18] (
D
E
F
>
?
@
&
-
-
4
1 5
4
1 5
3
D
E
F
>
?
@
2
5
3 (
4
15
,
b
a
( (a + b) = 19. Ans.]
PHYSICS
CodeA Page # 1
PART-A
Q.1
[Sol. Initial separation=0
v
rel
= const.
dt
ds
= const.
when, it ball collides, 2nd ball moves with increasingspeed. So
dt
ds
| ]
Q.2
[Sol. mg cos u =
R
mv
2
u
u
mg
mg (R Rcos u) =
2
1
mv
2
cos u =
3
2
a
t
= g sin u = g
3
5
]
Q.3
[Sol. Dopler effect
f =
v c
c

f
0
=
30 300
300

20 =
27
30
20 =
9
200
= 22.22 ]
Q.4
[Sol. 1000 =
3
10 2
RT 3

=
3
10 2
T
3
25
3

T =
25
10 2 10
3 6

= 80 ]
Q.5
[Sol. AV = V
0
(r
L
r
u
)AT
= 5 (130 80) 10
6
20 10
3
cc = 5 cc ]
Q.6
[Sol. p
1
= 1 sin
|
.
|

\
|
t
t
t 600
4
2
p
2
=
3
sin (t 600 tt)
p
1
+ p
2
= p = cos 600 tt +
3
sin 600 tt
p
max
=
2 2
) 3 ( 1 +
= 2 Pa ]
PHYSICS
CodeA Page # 2
Q.7
[Sol. p = 2 sin
|
.
|

\
| t
+ t
6
t 600
30
2
3
1
600 t +
6
t
= nt
t =
t
t
600 6
5
=
720
1
sec. ]
Q.8
[Sol.
m
T = '
m
T' ]
Q.9
[Sol.
e
v
0
e
v
0
Fr
]
Q.10
[Sol.
L 2
2
340 = f
1
25 . 0 4
1

340 = f
2
f
2
= 340 Hz f
1
= 345 Hz or 335 Hz
335
330
= 4L or
69
68
= L ]
Q.11
[Sol. A=
2
2
a
a 2 |
.
|

\
|
+
45
2 / a
2 / a
a
45
a
=
2
a + a =
( ) 1 2 +
a
E =
2
1
kA
2
=
2
1
k
( )
2
1 2 +
a
2
= E
0
(2 + 1 +
2 2
) ]
Q.12
[Sol. (A)
V
P
W = +ve
(B)
V
P
W = ve
(C)
V
P
W = +ve
(D)
V
P
W = ve
]
PHYSICS
CodeA Page # 3
Q.13
[Sol. At maximumdescent v =0
mg y
2
1
ky
2
= 0
y
max
=
k
mg 2
=
100
80
= 80 cm
at mean y =
2
80
= 40 cm
mg = ky
mg y
2
1
ky
2
=
2
1
mv
2
40 0.4
2
1
100 (0.4)
2
=
2
1
4v
2
16 8 = 2v
2
v =2m/s
T
max
at y
max
= k
xy
= 100 0.8 = 80 N ]
PART-B
Q.1
[Sol. (A) a =
2
ml
I
1
sin g
+
u
=
5
2
1
R
gx
+

=
) R (
g
7
5

x
x
u
R
u
T
2t
= e=
) R ( 7
g 5

T = 2t
g 5
) R ( 7
E = mgh = mg (R ) (1 cos u) = mg
2
2
u
(R )
(B) T =
t 2
g
u
E = mg (1 cos u
0
) = mg
2
2
u
]
(C)
T
1
= f =
L 2
1

mg
T = 2L
mg

PHYSICS
CodeA Page # 4
E =
8

A
2
e
2
2
2
t
vA
2
f =
2
2
t

mg
AA
2

L 2
1

mg
=
2
2
t
A
2

L 2
mg
]
PART-D
Q.1
[Sol. mg
2
L
=
2
1
Ie
2
=
2
1

3
mL
2
e
2
e =
L
g 3
K =
2
1
I
C
e
2
=
2
1

12
mL
2

L
g 3
=
8
mgL
=
8
1 10 4
= 5 J ]
Q.2
[Sol. 4 10 = 4v
4
+ v
1
1 =
10
v v
4 1

(v
1
v
4
= 10)
v
1
+ 4v
4
= 40
5v
4
= 30
v
4
= 6 m/s
v
1
= 16 m/s
4 1
6 16
4 6 16 1 = 4v
4
+ 1v
1
e = 1 =
22
v v
4 1

8 = 4v
4
+ v
1
4 22 = v
1
v
4
v
1
= 19.2 v
4
= 2.8
4 1
2.8 19.2
e =
4 . 16
v v
1 4

= 1
4 2.8 + 1 19.2 = 4v
4
+ 1v
1
30.4 = 4v
4
+ v
1
16.4 = v
4
v
1
46.8 = 5v
4
v
4
= 9.36 m/s
v
1
= 7.04 m/s
9.36 7.04
No more collision
Total 3collisions.
PHYSICS
CodeA Page # 5
Q.3
[Sol.
B
A
10
f
f = 10
A
10 + 8 = 30
f = 20 N
]
Q.4
[Sol.
dt
dQ
= ms
dt
dT
=
t
kA 2
(69.5 27)
2400 7 10
4
1 2100
t
1
A
=
3
4
10 1
10 7 3 2

(42.5)
At =
5 . 42
10 700 1200
3

=
5 . 42
7 120
~ 20 sec. ]
Q.5
[Sol. v
1
=
m
rRT
=
10 10 28
294
3
25
4 . 1
3

= 350 m/s
v
2
=
P
B
=
3
9
10
10 1025 . 2
= 1450 m/s
A
t
=
2 1
2
v v
v 2
+
A
i
=
350 1450
1450 2
+

18
=
1800
2900
18 = 29 Pa ]