Chemistry Test Teacher August 18, 2011 Student name ________________ Total points: 35

Solubility , types of mixtures, effect of temperature and pressure on the solubility, enthalpy of solution. Answer the following problems.

1. What visual test can be used to distinguish colloids from solutions? show your answer.
8 pts

Use a diagram to

On the first column, examples of solutions are given. Complete the table.
Mixture Rubbing alcohol air 70 mL water + 30 mL alcohol Oil + water solute Solvent

2.

Which of the following in each pair is soluble in water or in oil Soluble in water

4 pts Soluble in oil

_______________________

(a) b)

CH3CH2OH sugar

and and

C6H6 gasoline

___________________

_____________

________________

3. Predict whether each of the following substances is more likely to dissolve in carbon tetrachloride, CCl4, Mark an X below the soluble column if it is soluble and an X if it is insoluble. 3 pts
Substance C7H16 Water NaCl Soluble in CCl Insoluble in CCl

4. By referring to the solubility graph attached, determine whether the addition of 40.0 g of each of the following ionic solids in 100 g water at 40 C will lead to a saturated solution, unsatureated solution or super saturated solution.
Write your answer on the space provided. 2 pts

(a) NaNO3

_____________________________________

(b) KClO3

_________________________________________

5. When 30 grams of potassium chlorate at 65 C are cooled down to 50 C what type of solution will be produced. After it is cooled down the flask is colorless and without any solute. 2 pts 6. A solution of sodium nitrate which is saturated at 25 C , 3 more grams of the solute is added 0 and heated to 35 C. The flask shows no precipitate at the bottom of the flask. Can you say this solution is supersaturated? 2 pts
0

7. Given the following information , when you measure the temperature of the dissolution process with a thermometer, tell if the temperature increase or decrease for the following. 4 pts

The heat of solution of Sodium chloride is The heat of solution of sodium hydroxide is

+ 4,27 kj/mole - 41, 6 kj/ mole

Temperature will ___________ Temperature will ____________

8. From the following example ( Coca Cola) mention one solute in the gas state, one solute in the solid state . 6pts Solute ______________ in coca cola in the gas state. Solute _____________ in cocal cola in the solid state. Write yes or No Can more gas solute be dissolved when the temperature is increased ? _______________

Can more solid solute be dissolved when the temperature is increased ? _______________ Can more gas solute be dissolved when the pressure is increased? Can more solid solute be dissolved when the pressure is increased? _______________ _________________

9. You have 3 mixtures in 3 separate flaks: a suspension,a colloid and a solution. Use a diagram or explain explicitly how can you distinguish the three mixtures . Please do not define the types of mixtures, explain how to distinguish. 3 pts

10. An example of colloid is ___________________. 1 pt

Molarity and molality Solve the following problems. 1. The molality of sodium chloride at 20 o C is 6,143 m. Will 40,00 g of sodium chloride dissolved in 100, g of water be saturated? 2 pts 2. Calculate the number of grams of calcium nitrate dissolved in 500, mL of water with a 0,100 m of solution.

2 pts 3. Metallic zinc reacts with hydrochloric acid to produce zinc chloride and hydrogen gas. If 2,00 mole of zinc react with 1,00 L of 2,00 M of hydrochloric acid, how many grams of hydrogen gas are produced ? ( Remember limiting reactant ? )

4 pts

4.

If the mass of the solution is 40,0 g and the solution contains 35 g of water, and the solute is HCl , calculate the molality and molarity of the solution. The density of the solution is 1,060 g/ mL.

Solute solvent solution Mass ___________________________________________________40,0 g Volume

6 pts

Evaporamos hasta sequedad 300 mL de una disolucin de la sal NaClO 3 ( aq ) . Si se contina calentando, la sal seca se descompone qumicamente en NaCl ( s ) y O 2 ( g ) , obtenindose 2,24 litros de oxgeno medidos a 27,0C y 1,00 Atm. Calcular cul era la concentracin ( M ) de la disolucin de clorato de sodio?

5.

4pts

6.

If 100, mL of 1,00 M sodium chloride are added to 0,900 L of water. What is the final concentration of the solution? 2pts

If 5,844 g of sodium chloride are present in the 100, mL and 1,00 M of solution. How Many grams of sodium chloride are present at the end of the concentration? 1 pts
3

7.

Una disolucin de cido sulfrico de densidad 1,14 g/cm y del 32% de riqueza en peso, cual es su Molaridad? Molar mass of sulfuric acid is 98,08 g/mole 4 pts