Mesure de la conductance dune solution aqueuse

#$ "
' &

I
' & .

1 ,

: . /01


R
! * + )( ' & ! " #$%

67 1 2'.34
01 & /
2 3
3 !1
5

U = RI :

!" )" 6 ) 9 ) : ( Na + + C

C = 102 mol /
6 & 3 ! 16

< "

&=

% )(GBF

. 2V
: :
5 : /1 U = 3 & +# 3 ! 16

" F #
) & H=G
0
3 I 3 /1 <K U

=
:
M"N 6!% <L

80

65

50

40

25

15

)I(mA

2,5

1,98

1, 66

1,34

0,82

0,50

)U(V

5: <O

Q<& I

U3& * /I
849
* M%!% ! I = f ( U ) S "N 6

. U :&

. :

X % $ *

=U

: /1 6!% . U

)( ' =#$% & +#

I = G .U U = R.I

M"N M%!%

. T"/ <O
" !

1
R

WG % I

=G

WG % " N !" ! 6 & 3 . 3 ! 16

/ G P :YH
" <H 0% $ 9 ). (S
[% /
<H "

$
2 . @A1?>= ;9"7
67 3 2'.34
! _ 01 M"N ) W # L . +& $

Page 1

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Allal mahdade

= 9L ! 6 & 3 a b 3
3 & " 1 a b & ` 3 5 S H $
* ! _ M"N $

)
3 !" L$
!" &"* 2#!$
3 !" . ' &d U 3 ! 16)P
*UTI
4
545

5
690

3
415

* ! _ #` M"N S H $ 5
UT* H.I
4
5
34
26

2
70

3
44

61:

)S(cm2
)G(S
)G/S(SI

1
137

& 3 3 ! 16

2
270

L$ 3 :

1
137

)L(cm
)G(S
)G.L(SI

849 .
9L !" a " "
5: = " S H $ G
1 ) 5 : o " G
_H % WG %: & 3 " G . S H $
&`L
) "! " C 9 ` & q $
& #$%
L 3 & " 1 a b 3
5: $
2 ) 5 : o " G
L
_H % 3 & $aN WG %: " G $
) "! " C 9 ` & q & ` S H $
& #$%
3 & " 1 a b . 3
D /.1 .
3 . @A1 = 2
67 4 2'.34
": 1
"a 6 :) 9
! ` ` [!:
01 </ # L & $
/$
2
"! : S1 "a 6 C1 = 10 mol /
"a 6 C 2 = 5.10 3 mol /

"! : S2

"a 6 9 ) : . C 3 = 10 mol /

"! : S3

!" <) < $ 6 !" )" G : # 01 2 ) C = 102 mol / 9

&`L 5
q#P % M #: M H 3 ! 16 $
" " `&
* ! _ M"N & / G<%2
!" M #: M H . & ` ' () H $
)"
"a 6 ) C1 9 C2 . C3 L$ T 2 "N 6!%
& !
*
:
<L
102
5.10 3
2.10 3
( mol / ) C
2

1,3.103
*

&

2
3

3, 2.10

" 1 :) 9

)U(V
)I(A

6, 4.10
< . X % !6

)G(S
2 "N

Na + + OH

H + + C

Na + + C

!"

)U(V
)I(A

12, 4.103

21, 6.10

6, 4.10

<L

)G(S
"

1 U 3 <L 9 ) : `u o ) 1 !" M"N

.
9 : < " !" & 9 < 9 ) :

X <L P
2 3 v" $:
. S / #=& +"/ :
_H " !"
9: < H x !" .
"! 9: : " G
4 G 7 "4'G = f ( C ) F

4 1 67 5 2'.34
" .
! _ 01 M"N ) W # L +& $ / $
"a 6 :) 9
* u) $ U (UF %!: ) "! M"N 2% <H
<L S"1G & " & / G ) W K S N .
:
L$ X % ! M"N "6 <L

Page 2

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"1

Allal mahdade

25

20

15

10

) V ( m

) C ( mmol /

1,75

1,40

1,05

0,70

0,35

)G ( mS

U & G = f ( C ) M%!% . WG % T"G

1 P

& #$%

}1 /

:) 9

" 9L G
WG % : C < 10 mol /
) (2 C 9 !"
"! 3
G = a.C :
+"/ : /&F& a & P * "U "
) ( L,S&= / # ( &< x ! .
2 < "! % )" 6 9 ) :
2L & / G 01 ) W # L
0 +& $ " . G=0,8mS <L% S
9 ) : C !" .
* <x
G7 7 "4'. F
4 2
a
M%!% < G = f ( C ) X
3 a:

9 ) : < <!: !" )" 6 = O ! 1 M"N

2 #P: T:` % U . M%!%

`u
` # /
4 "J 3 =49 G7 7 "4'. F
" 3 3a / G M%!% < "! 9 ) : < <! G = f ( C ) X
a !" a
! [ #` M"N )

( T$x 3 <H a &S

`u U .
/

& ) 3a

" 9L 3 !" M"N aK

3 <H

. C = 102 mol / 3
< G*
a: :) 9 !
.
:) 9) 3 #(
!
& #$%
' &

II
"

S

S
=S/

!"
3
9L
G
L
!"
x
&= / #
3 (
9 )" ) 9
9 )" q/1: x !
WG % = "! " S
$aN WG % = L

: WL

3 <H : a

a M%!% < X

Y !& = .C

"

=U

: +"/

S
3N #/ Y !& G = . = k. : S / m
L

& 2a
" !" <* 0a/ !" : M"N
< & M $
" !" &< x !
x & ) 9
" !" &= / #
+"/ :
C
" !" ) 9
} o / ) WG % : 9

!"
& #$%

3 ( :

" ( 2%N #/ S.m 2 .mol1 C mol / m3

?' &

III
1 : K'.=1
S"/L 9
( .(

!" & < ) (la taille S %!O! " #$% & ) S2 : H

)9
.
& 2a
!" <* Y H 3 : M"N S:
U x
" * & 3N o
2 9 2%N #/

"
:M $
T 3N #/( < & < 9
& <H . S.m2 .mol1
>N
2 =O
!"

"

xb

?' &

Xi H
! n M"N 3

" !" &

$ %!K) T

< U & S W a: q H i = i [ X i ] :
n

i =1

i =1

"

!" )

] = i = i [ X i

Page 3

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Allal mahdade

(S.m )
1

2%N #/ " !"

mol / S%N #/ X i

S.m2 .mol1 2%N #/ X i

"7P K Q$4

Ag +aq
6,2.10-3

CH3COOaq

4,1.10-3

Allal mahdade

74 R
+
Liaq

3,9.10-3

NO3( aq )
7,1.10-3

+
K aq

7,3.10-3

Iaq

7,7.10-3

a %"

a %"

S 7 6 ' J? ?' & T=2

xb

& '?

H +aq

5,0.10-3

34,9.10-3

7,6.10-3

www.chimiephysique.ma

9)

[ Xi ]

"

3
25C .J V

Na +aq

Caq

"

OHaq

19,8.10-3

:a

( S.m / mol )

( S.m / mol )

Page 4