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CHEM 161 Fall 2013

NAME: ________________________________

PRACTICE EXAM IV
Any incidents of Academic Misconduct will result in automatic failure for the course and further disciplinary action!

Helpful Tidbits: 1000 mL = 1 L PV = nRT 1 m = 1 x109 nm q = mCST T(K) = T(C) + 273 n = g/MM c = 3.0 x 108 m/s 760 torr = 1 atm 1 mole = 6.022 x 1023 h = 6.626 x 10-34 Js [
[] ]0

R = 0.08206 Latmmol-1K-1 1000 J = 1 kJ E=h c=

H=(Hproducts)-(Hreactants)

G=H-TS

NAME: ________________________________

_______ 1)

Determine the molecular geometry

of XeF4.

________ 2) Determine the rate law for the following reaction using the data provided.
NO(g) + O2(g) 2 NO2(g) [NO]i (M) 0.030 0.030 0.060 [O2]i (M) 0.0055 0.0110 0.0055 Initial Rate (M-1s-1) -3 8.55 x 10 -2 1.71 x 10 -2 3.42 x 10

A) octahedral B) square planar C) tetrahedral D) trigonal bipyramidal

A) Rate = k[NO][O2] B) Rate = k[NO][O2]1/2 C) Rate = k[NO]2[O2]2 D) Rate = k[NO]2[O2]

_______ 3) What is the concentration of SO4-2(aq) in a 0.333 M solution of Al2(SO4)3? A) 0.333 M B) 0.666 M C) 0.999 M D) 0.111 M

________ 4) Consider a reaction that has a negative H and a positive S. Which of the following statements is TRUE? A) This reaction will be spontaneous only at high temperatures. B) This reaction will be spontaneous at all temperatures. C) This reaction will be nonspontaneous at all temperatures. D) This reaction will be nonspontaneous only at high temperatures.

_______ 5) Calculate Hrxn for the reaction: CH4(g) + 4 Cl2(g) CCl4(g) + 4HCl(g) Use the following reactions and given Hs.
C(s) + 2 H2 (g) CH4(g) C(s) + 2 Cl2 (g) CCl4(g) H2 (g) + Cl2 (g) 2 HCl(g) H = -74.6 kJ/mol H = -95.7 kJ/mol H = -92.3 kJ/mol

________ 6) Consider the following reaction and its equilibrium constant: 4 CuO(s) + CH4(g) CO2(g) + 4 Cu(s) + 2 H2O(g) Kc = 1.10 A reaction mixture contains 0.22 M CH4, 0.67 M CO2 and 1.3 M H2O. Which of the following statements is TRUE concerning this system? A) The reaction will shift in the direction of products. B) The equilibrium constant will increase. C) The reaction quotient will increase. D) The reaction will shift in the direction of reactants.

A) -206 kJ/mol B) -113 kJ/mol C) -355 kJ/mol D) 113 kJ/mol

_______ 7) Using the VSEPR model, the electrondomain geometry of the central atom in SF2 is ________. A) linear B) trigonal planar C) tetrahedral . Better answer is BENT D) trigonal bipyramidal

______ 8) The Toyota Prius, a hybrid electrical vehicle, has an EPA gas mileage rating of 52 miles per gallon. How many kilometers can a Prius drive on 15 liters of gasoline? 1 Liter = 0.264 gallons 1 mile = 1.61 km a) b) c) d) 1260 km 0.122 km 840 km 330 km

_______ 9) Express the equilibrium constant for

the following reaction.


16 CH3Cl(g) + 8 Cl2(g) 16 CH2Cl2(g) + 8 H2(g)

________ 10) A gas mixture contains 0.60 moles of N2, 0.20 moles H2, and 0.10 mole of CH4. If it was kept at constant temperature and volume, what is the partial pressure of N2 if the total pressure was 887 torr? A) 0.70 atm B) 0.78 atm C) 0.30 atm D) 0.56 atm

A) K =

B) K =

C) K = D) K =

_______ 11) For which

reaction will Kp = Kc?

________ 12) According to MO theory, which species has the most unpaired electrons?

A) C(s) + O2(g) CO2(g) B) 2 HgO(s) Hg(l) + O2(g) C) CaCO3(s) CaO(s) + CO2(g) D) H2CO3(s) H2O(l) + CO2(g)

A) C22B) C2 C) F2 D) N22-

_______ 13)

What are the units of k in the following rate law? Rate = k[X][Y] A) B) Ms C) D)

________ 14) Which atom has the most unpaired electrons? A) O B) B C) C D) N

_______ 15)

Give the hybridization for the C in

HCCH. A) sp3d2 B) sp3d C) sp3 D) sp2 E) sp

________ 16) What is the correct Lewis Dot Structure for N2O?

C is correct

_______ 17)

Given the following balanced equation, determine the rate of reaction with respect to [H2]. N2(g) + 3 H2(g) 2 NH3(g) A) Rate = + B) Rate = C) Rate = + D) Rate = -

________ 18) At

a certain temperature, Kc equals 1.4 102 for the reaction: 2 CO(g) + O2(g) 2 CO2(g).

If a 3.00-L flask contains 0.400 mol of CO2 and 0.100 mol of O2 at equilibrium, how many moles of CO are also present in the flask? A) 0.555 mol B) 0.185 mol C) 0.107 mol D) 0.0114 mol

_______ 19)

For the following example, identify the following. H2O(l) H2O(g) A) a negative H and a negative S B) a positive H and a negative S C) a negative H and a positive S D) a positive H and a positive S

________ 20) What

data should be plotted to show that experimental concentration data fits a first-order reaction? A) 1/[reactant] vs. time B) [reactant] vs. time C) ln[reactant] vs. time D) ln(k) vs. 1/T