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Vidyamandir Classes

VMC/Electrochemistry 9 HWT-6/Chemistry
DATE : TIME : 40 Minutes MARKS : [ ___ /15] TEST CODE : ELCM [1]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 15 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. AgNO
3
(aq) was added to an aqueous KCl solution gradually and the conductivity of the solution was measured. The plot of
conductance ( ) A versus the volume of AgNO
3
is :
(A) P (B) Q (C) R (D) S
2. Resistance of 0.2 M solution of an electrolyte is 50O. The specific conductance of the solutions is
1
1.3S m

. If resistance of the
0.4 M solution of the same electrolyte is 260O, its molar conductivity is :
(A)
2 1
6250Sm mol

(B)
4 2 1
6.25 10 Sm mol

(C)
4 2 1
625 10 Sm mol

(D)
2 1
62.5 Sm mol

3. By diluting a weak electrolyte, specific conductivity (K


c
) and equivalent conductivity
c
( ) change as
(A) both increase (B) K
c
increases,
c
decreases
(C) K
c
decreases,
c
increases (D) Both decrease
4. The one which decreases with dilution is :
(A) molar conductance (B) conductance
(C) specific conductance (D) equivalent conductance
5. The value of
eq

A for NH
4
Cl, NaOH and NaCl are respectively, 149.74, 248.1 and
1 2 1
126.4 cm equiv

O .
The value of
eq 4
of NH OH

A is :
(A) 371.44 (B) 271.44 (C) 71.44
(D) Cannot be predicted from given data
6. Which of the following does not conduct electricity?
(A) Fused NaCl (B) Solid NaCl (C) Brine solution (D) Copper
7. Which one of the following solutions will have highest conductivity?
(A) 0.1 M CH
3
COOH (B) 0.1 M NaCl (C) 0.1 M KNO
3
(D) 0.1 M HCl
8. The equivalent conductances of two strong electrolytes at infinite dilution in H
2
O (where ions move freely through a solution) at
25 C

are given below


2
CH COONa
3
91.0 S cm / equiv A =

2
HCl
426.2 S cm / equiv A =

What additional information/quantity one needs to calculate A

of an aqueous solution of acetic acid?


(A) of NaCl A

(B)
3
of CH COOK A

(C) The limiting equivalent conductance of



H
H
+
+

(D) A

of chloroacetic acid (ClCH


2
COOH)
Vidyamandir Classes
VMC/Electrochemistry 10 HWT-6/Chemistry
9. The specific conductivity of 0.1 N KCl solution is
1 1
0.0129 cm

O . The cell constant of the cell will be.
(A) 1.10 (B) 1.29 (C) 0.56 (D) 2.80
10. For strong electrolytes the plot of molar conductance vs C is :
(A) parabolic (B) linear (C) sinusoidal (D) circular
11. The specific conductance ( ) k of an electrolyte of 0.1 N concentration is related to equivalent conductance ( ) A by the following
formula :
(A) A = k (B) 10 A = k (C) 100 A = k (D) 10000 A = k
12. The units of equivalent conductance, are :
(A)
2 1
cm equiv

O (B)
2
cm equiv O (C)
1 2 1
cm equiv

O (D)
2
cm equiv O
13. The molar conductivities
NaOAc HCl
and A A

at infinite dilution in water at 25 C

are 91.0 and 426.2 S cm


2
/mol respectively. To
calculate
HOAC
A

, the additional value required is :


(A)
H O
2
A

(B)
KCl
A

(C)
NaOH
A

(D)
NaCl
A

14. Resistance of a conductivity cell filled with a solution of an electrolyte of concentration 0.1 M is 100O. The conductivity of this
solution is
1
1.29 S m

. Resistance of the same cell when filled with 0.2 M of the same solution is 520O . The molar conductivity
of 0.02 M solution of the electrolyte will be :
(A)
4 2 1
124 10 S m mol

(B)
4 2 1
1240 10 S m mol

(C)
4 2 1
1.24 10 S m mol

(D)
4 2 1
12.4 10 S m mol

15. Which of the following has the highest molar conductivity?


(A) Diaminedichloroplatinum (II) (B) Tetraaminedichlorocobalt (III) chloride
(C) Potassium hexacyanoferrate (II) (D) Hexaaquochromium (III) bromide
(E) Pentacarbonyl iron (0)
Vidyamandir Classes
VMC/Electrochemistry 11 HWT-6/Chemistry
DATE : TIME : 25 Minutes MARKS : [ ___ /15] TEST CODE : ELCM [2]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 15 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. The highest electrical conductivity of the following aqueous solutions is of :
(A) 0.1 M difluoroacetic acid (B) 0.1 M fluoroacetic acid
(C) 0.1 M chloroacetic acid (D) 0.1 M acetic acid
2.
Calculate
HOAc
A

using appropriate molar conductances of the electrolytes listed above at infinite dilution in
2
H O at 25 C

.
(A) 217.5 (B) 390.7 (C) 552.7 (D) 517.2
3. Given,
1
/ a 0.5 cm , R 50 ohm, N 1.0 l

= = = . The equivalent conductance of the electrolytic cell is :
(A)
1 2 1
10 cm g equiv

O (B)
1 2 1
20 cm g equiv

O
(C)
1 2 1
300 cm g equiv

O (D)
1 2 1
100 cm g equiv

O
4.
1 2 1
ClCH COONa
2
224 cm g equiv

A = O
1 2 1
NaCl
38.5 cm g equiv

A = O
1 2 1
HCl
230 cm g equiv

A = O
What is the value of
ClCH COOH
2
? =
(A)
1 2 1
288.5 cm g equiv

O (B)
1 2 1
289.5 cm g equiv

O
(C)
1 2 1
388.5 cm g equiv

O (D)
1 2 1
59.5 cm g equiv

O
5. Specific conductivity of a solution :
(A) increases with dilution (B) decreases with dilution
(C) remains unchanged with dilution (D) depends on mass of electrolyte
6. Ionic mobility of Ag
+
is
1 1 2 1
Ag
5 10 cm equiv

+
| |
= O
|
\
(A)
9
5.2 10

(B)
9
2.4 10

(C)
9
1.52 10

(D)
9
8.25 10

7. 9.65 C of electric current is passed through fused anhydrous MgCl


2
. The magnesium metal thus obtained is completely converted
into a Grignard reagent. The number of moles of Grignard reagent obtained is :
(A)
4
5 10

(B)
4
1 10

(C)
5
5 10

(D)
5
1 10

8. What will be pH of aqueous solution of electrolyte in electrolytic cell during electrolysis of CuSO
4
(aq) between graphite
electrodes?
(A) pH = 14.0 (B) pH > 7.0 (C) pH < 7.0 (D) pH = 7.0
Electrolyte KCl KNO
3
HCl NaOAc NaCl
( )

A
2 -1
S cm mol
149.9 145.0 426.2 91.0 126.5
Vidyamandir Classes
VMC/Electrochemistry 12 HWT-6/Chemistry
9. During the electrolysis of molten NaCl solution, 230 g of sodium metal is deposited on the cathode, then how many moles of
chlorine will be obtained at anode?
(A) 10.0 (B) 5.0 (C) 35.5 (D) 17.0
10. Give the products available on the cathode and the anode respectively during the electrolysis of an aqueous solution of MgSO
4
between inert electrodes.
(A) H
2
(g) and O
2
(g) (B) O
2
(g) and H
2
(g) (C) O
2
(g) and Mg (s) (D) O
2
(g) and SO
2
(g)
11. If F is faraday and N is Avogadro number, then charge of electron can be expressed as :
(A) F N (B)
F
N
(C)
N
F
(D) F
2
N
12. By passing 9.25 A current for 16 min 40 s, the volume of O
2
liberated at STP will be :
(A) 280 mL (B) 560 mL (C) 1120 mL (D) 2240 mL
13. In the electrolysis of acidulated wate, it is desired to obtain 1.12 cc of hydrogen per second under STP condition. The current to be
passed is :
(A) 1.93 A (B) 9.65 A (C) 19.3 A (D) 0.965 A
14. Which substance is obtained in the solution on electrolysis of aqueous CusO
4
solution using graphite electrodes?
(A) H
2
O (B) H
2
SO
4
(C) Na
2
SO
4
(D) Cu (OH)
2
15. Use of electrolysis is not done in :
(A) production of Na (B) production of water
(C) purification of metals (D) production of KOH
Vidyamandir Classes
VMC/Electrochemistry 13 HWT-6/Chemistry
DATE : TIME : 25 Minutes MARKS : [ ___ /15] TEST CODE : ELCM [3]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 15 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. Electrolysis of dilute aqueous NaCl solution was carried out by passing 10 mA current. The time required to liberate 0.01 mole of
H
2
gas at the cathode is :

1
1 F 96500C mol

=
(A) 9.65 10
4
s (B) 19.3 10
4
s (C) 28.95 10
4
s (D) 38.6 10
4
s
2. When electric current is passed through acidified water for 1930 s, 1120 mL of H
2
gas is collected (at STP) at the cathode. What is
the current passed in amperes?
(A) 0.05 (B) 0.50 (C) 5.0 (D) 50
3. The amount of substance deposited by the passage of 1 A of current for 1s is equal to :
(A) equivalent mass (B) molecular mass
(C) electrochemical equivalent (D) specific equivalent
4. When a quantity of electricity is speed through CuSO
4
solution, 0.16 g of copper gets deposited. If the same quantity of electricity
is passed through acidulated water, then the volume of H
2
liberated at STP will be : [Given, atomic weight of Cu = 64]
(A) 4.0 cm
3
(B) 56 cm
3
(C) 604 cm
3
(D) 8.0 cm
3
5. A current of 12 A is passed through an electrolytic cell containing aqueous NiSO
4
solution. Both Ni and H
2
gas are formed at the
cathode. The current efficiency is 60%. What is the mass of nickel deposited on the cathode per hour?
(A) 7.883 g (B) 3.941 g (C) 5.91 g (D) 2.645 g
6. The cathodic reaction of a dry cell is represented by
2
2 2 4
2MnO (s) Zn 2e ZnMn O (s)
+
+ +
If, there are 8 g of MnO
2
in the cathodic compartment then the time for which the dry cell will continue to give a current of 2 mA
is :
(A) 25.675 day (B) 51.35 day (C) 12.8 day (D) 6.423 day
7. In acidic medium
4
MnO

is converted to Mn
2+
. The quantity of electricity in faraday required to reduce 0.5 mole of
2
4
MnO to Mn
+
would be :
(A) 2.5 (B) 5 (C) 1 (D) 0.5
8. A lamp draws a current of 1.0 A. Find the charge in coulomb used by the lamp in 60 s :
(A) 0.6 C (B) 60 C (C) 600 C (D) 0.06 C
9. When electric current is passed through an ionic hydride in molten state :
(A) hydrogen is liberated at anode (B) hydrogen is liberated at cathode
(C) no change takes place (D) hydride ion migrates towards cathode
10. Which of the following is not correct?
(A) Aqueous solution of NaCl is an electrolyte
(B) The units of electrochemical equivalent are g-coulomb
(C) In the Nernst equation, n represents the number of electrons transferred in the electrode reaction
(D) Standard reduction potential of hydrogen electrode is zero volt
Vidyamandir Classes
VMC/Electrochemistry 14 HWT-6/Chemistry
11. If 3 F of electricity is passed through the solutions of AgNO
3
, CuSO
4
and AuCl
3
, the molar ratio of the cations deposited at the
cathodes will be :
(A) 1 : 1 : 1 (B) 1 : 2 : 3 (C) 3 : 2 : 1 (D) 6 : 3 : 2
12. The product obtained at anode when 50% H
2
SO
4
aqueous solution is electrolysed using platinum electrodes is :
(A) H
2
SO
3
(B) H
2
S
2
O
8
(C) O
2
(D) H
2
13. In electrolytic purification, which of the following is made of impure metal?
(A) Anode (B) Cathode (C) Both (A) and (B) (D) None of these
14. Consider the following cell reaction :
2
2 2
2Fe(s) O (g) 4H (aq) 2Fe (aq) 2H O( ), E 1.67V l
+ +
+ + + =

At
2 3
2
[Fe ] 10 M, P(O ) 0.1 atm
+
= = and pH = 3, the cell potential at 25 C

is :
(A) 1.47 V (B) 1.77 V (C) 1.87 V (D) 1.57 V
15. The reduction potential of hydrogen half-cell will negative if :
(A) p(H
2
) = 1 atm and [H
+
] = 2.0 M (B) p(H
2
) = 1 atm and (H
+
) = 1.0 M
(C) p(H
2
) = 2 atm and [H
+
] = 1.0 M (D) p(H
2
) = 2 atm and [H
+
] = 2.0 M
Vidyamandir Classes
VMC/Electrochemistry 15 HWT-6/Chemistry
DATE : TIME : 40 Minutes MARKS : [ ___ /15] TEST CODE : ELCM [4]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 15 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. The standard redox potentials for the reactions
2 3 2
Mn 2e and Mn e M are 1.18 V and1.51 V
+ + +
+ +
respectively. What is the redox potential for the reaction
3
Mn 3e Mn
+
+ ?
(A) 0.33 V (B) 1.69 V (C) 0.28 V (D) 0.85
2. E
1
, E
2
and E
3
are the emfs of the following three galvanic cells respectively
I. Zn (s) | Zn
2+
(0.1 M) || Cu
2+
(1 M) | Cu (s)
II. Zn (s) | Zn
2+
(1 M) || Cu
2+
(1 M) | Cu (s)
III. Zn (s) | Zn
2+
(1 M) || Cu
2+
(0.1 M) | Cu (s)
Which one of the following is true?
(A) E
2
> E
1
> E
3
(B) E
1
> E
2
> E
3
(C) E
3
> E
1
> E
2
(D) E
3
> E
2
> E
1
3. The standard emf of a galvanic cell involving 2 moles of electrons in its redox reaction is 0.59 V. The equilibrium constant for the
redox reaction of the cell is :
(A) 10
20
(B) 10
5
(C) 10 (D) 10
10
4. Which of the following reactions is correct for a given electrochemical cell at 25 C

?
2 2
Pt | Br (g)| Br (g)||Cl (aq)|Cl (g)| Pt

(A)
2 2
2Br (aq) Cl (g) 2Cl (aq) Br (g)

+ + (B)
2 2
Br (g) 2Cl (aq) 2Br (aq) Cl (g)

+ +
(C)
2 2
Br (g) Cl (aq) Br (aq) 2Cl (g)

+ + (D)
2 2
2Br (aq) 2Cl (aq) Br (g) Cl (g)

+ +
5. E

values of Mg
2+
/Mg is
2 2
2.37V, of Zn / Zn is 0.76V and Fe / Fe is 0.44V
+ +
.
Which of the statements is correct?
(A) Zn will reduce Fe
2+
(B) Zn will reduce Mg
2+
(C) Mg oxidises Fe (D) Zn oxidises Fe
6. What will be the electrode potential of that hydrogen electrode is filled with HCl solution pH value 1.0?
(A) 59.15V (B) 59.15 + (C) 59.15 mV + (D) 59.15mV
7. (i)
2 2
Cu 2HCl CuCl H (g) + +
2
Zn / Zn
[E 0.76V]
+

=
(ii)
2 2
Zn 2HCl ZnCl H (g) + +
2
Zn / Zn
[E 0.80V]
+

= +
(iii)
2
1
Ag 2HCl AgCl H (g)
2
+ +
Ag / Ag
[E 0.80V]
+

= +
Which of the following reaction is feasible?
(A) (ii) (B) (i) (C) (iii) (D) All of these
Vidyamandir Classes
VMC/Electrochemistry 16 HWT-6/Chemistry
8. At 25 C temperature the cell potential of a given electrochemical cell is 1.92 V. Find the value of x.
2 2
Mg(s) | Mg (aq)x M|| Fe (aq) 0.01 M| Fe(s)
+ +
2 2
E Mg/ Mg (aq) 2.37V E Fe/ Fe (aq) 0.45V
+ +
= =
(A) x = 0.01 M (B) 0 < 0.01 M (C) x > 0.01 M (D) x cannot be predicted
9.
3
Fe / Fe
E 0.036V
+

= ,
2
Fe / Fe
E 0.439V
+

= .
The value of standard electrode potential for the charge,
3 2
Fe (aq) e Fe aq
+ +
+ will be :
(A) 0.072V (B) 0.385V (C) 0.770 V (D) 0.270V
10. In which of the following pairs, the constants/ quantities are not mathematically related to each other?
(A) Gibbs free energy and standard cell potential (B) Equilibrium constant and standard cell potential
(C) Rate constant and activation energy (D) Rate constant and standard cell potential
12. Small quantities of solutions of compounds TX, TY and TZ are put into separate test tube contain X, Y and Z solutions. TX does
not react with any of these. TY reacts with both X and Z. TZ reacts with X. The decreasing order of ease of oxidation of the anion
X , Y , Z

is:
(A) Y , Z , X

(B) Z X , Y

, (C) Y , X , Z

(D) X Z , Y

,
13. The potential of the cell for the reaction,
2
2
M(s) 2H (1M) H (g) (1atm) M (0.1 M)
+ +
' + + is 1.500 V. The standard reduction potential for M / M(s)
+
couple is:
(A) 0.170V (B) 1.470 V (C) 14.70 V (D) None of these
14. Given
3 2
Cr / Cr Fe / Fe
E 0.72V, E 0.42V
+ +

= = . The potential for the cell
3 2
Cr / Cr (0.1 M) || Fe (0.01M) |
+ +
F is :
(A) 0.26 V (B) 0.399V (C) 0.330V (D) 0.26 V
14. Hydrogen gas is not liberated when the following metal is added to dil. HCl :
(A) Ag (B) Zn (C) Mg (D) Sn
15. Dipping iron article into a strongly alkaline solution of sodium phosphate:
(A) Does not affect the article (B) From
2 3 2
Fe O xH O on the surface
(C) Form iron phosphate film (D) Forms ferric hydroxide
Vidyamandir Classes
VMC/Electrochemistry 17 HWT-6/Chemistry
DATE : TIME : 40 Minutes MARKS : [ ___ /15] TEST CODE : ELCM [5]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 15 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. Which one of the following condition will increase the voltage of the cell represented by the equation?
2
Cu(s) 2Ag (aq) Cu (aq) 2Ag(s)
+ +
+ +

(A) Increase in the dimension of Cu electrode (B) Increase in the dimension of Ag electrode
(C) Increase in the concentration of
2
Cu
+
ions (D) Increase in the concentration of Ag
+
ions
2. Cu (aq)
+
is unstable in solution and undergoes simultaneous oxidation and reduction, according to the reaction
2
2Cu (aq) Cu (aq) Cu(s)
+ +
+

choose correct E for the above reaction if


2 2
Cu / Cu Cu / Cu
E 0.34 V and E 0.15V
+ + +

= =
(A) 0.38 V (B) 0.49 + (C) 0.38V + (D) 0.19V
3. The standard reduction potentials at 298 K for the following half - cell reactions are given:
2
Zn (aq) 2e Zn(s)
+
+

; 762V
3
Cr (aq) 3e Cr(s)
+
+

; 0.74V
2
2H (aq) 2e H (g)
+
+

; 0.00V +
3 2
Fe (aq) e Fe (aq)
+ +
+

; 0.77V +
Which one of the following is the strongest reducing agent?
(A) Zn(s) (B) Cr(s) (C) H
2
(s) (D)
2
Fe (aq)
+
4. The cell
2 2
Zn| Zn (1M)||Cu (1M) | Cu
+ +
(
cell
E 1.10V

= ), was allowed to be completely discharged at 298 K. The relative concentration of


2
2 2
2
[Zn ]
Zn to Cu
[Cu ]
+
+ +
+
| |
|
|
\
is:
(A) antilog (24,08) (B) antilog(37.3) (C) 10
37.3
(D)
4
9.65 10
5. Given standard electrode potentials
2
Fe 2e Fe
+
+ E 0.440 V = ;
3
Fe 3e Fe
+
+ E 0.036 V =
The standard electrode potential ( E ) for
3 2
Fe e Fe
+ +
+ is :
(A) 0.772V + (B) 0.772V (C) 0.417 V + (D) 0.414V
6. An alloy of Pb-Ag weighing 1.08 g was dissolved in dilute HNO
3
and the volume made to 100 mL. A silver electrode was dipped
in the solution and the emf of the cell set up.
2
Pt(s), H (g) | H (1M) || Ag (aq)| Ag(s)
+ +
was 0.62 V. If
cell
E 0.80V

= , what is the percentage of Ag in the alloy ?


[At 25 C, RT/ F 0.06] =
(A) 25 (B) 2.50 (C) 10 (D) 50
7. The standard oxidation potentials of Zn, Cu, Ag and Ni electrodes are 0.76, 0.34, 0.80 + and +0.25 V respectively. Which of
the following reaction will provide maximum voltage ?
(A)
2
Cu 2Ag (aq) Cu (aq) 2Ag
+ +
+ + (B)
2
Zn 2Ag (aq) Zn (aq) 2Ag
+ +
+ +
(C)
2
2
H Ni (aq) 2H (aq) Ni
+ +
+ + (D)
2 2
Zn Cu (aq) Zn (aq) Cu
+ +
+ +
Vidyamandir Classes
VMC/Electrochemistry 18 HWT-6/Chemistry
8. In the electrochemical reaction,
3 2 2
2Fe Zn Zn 2Fe
+ + +
+ + increasing the concentration
2
Fe
+
(A) Increases cell emf (B) increases the current flow
(C) decreases the cell emf (D) alter the pH of the solution
9. The standard reduction potentials at 298 K for the following half reactions are given against each
2
Zn (aq) 2e Zn(s)
+
+ ; E 0762V =
3
Cr (aq) 3e Cr(s)
+
+ ; E 0.740V =
2
2H (aq) 2e H (g)
+
+ ; E 0.00V =
3 2
Fe (aq) e Fe (aq)
+ +
+ ; E 0.762 V =+
The strongest reducing agent is:
(A) Zn(s) (B) Cr(s) (C) H
2
(g) (D) Fe
2+
(aq)
10. EMF of hydrogen electrode in terms of pH is : (at 1 atm pressure)
(A)
2
H
RT
E pH
F
= (B)
2
H
RT 1
E .
F pH
= (C)
2
H
2.303 RT
E .pH
F
= (D)
2
H
E 0.0591 pH =
11. The standard
red
E

values of A, B and C are + 0.68 V, 0.50 V respectively. The order of their reducing power is:
(A) A > B > C (B) A > C > B (C) C > B > A (D) B > C > A
12. Which one of the following nitrates will leave behind a metal on strong heating ?
(A) Ferric nitrate (B) Copper nitrate (C) Magnanese nitrate (D) Silver nitrate
13. Given the data 25 C ,
Ag I AgI e

+ + ; E 0.152V =
Ag Ag e
+
+ ; E 0.800 V =
What is the value of log
sp
K for AgI?
(A) 8.12 (B) 8.612 + (C) 37.83 (D) 0.38V
14. If the H
+
concentration is decreased from 1 M to
4
10 M

at 25 C for the couple


2
4
MnO / Mn
+
, then the oxidising power of the
2
4
MnO / Mn
+
couple decreases by :
(A) 0.18 V (B) 0.18 V (C) 0.38 V (D) 0.38 V
15. Which of the following statements are correct concerning reducx properties:
I. A metal M for which E for the half reaction
n
M ne M
+
+ = , is very negative will be a good reducing agent.
II. The oxidizing powder of the halogens decreases from chlorine to iodine.
III. The reducing powder of hydrogen halides increase from hydrogen chloride to hydrogen iodide.
The correct choice is :
(A) I, II and III (B) I and II (C) I only (D) II and III only
Vidyamandir Classes
VMC/Electrochemistry 19 HWT-6/Chemistry
DATE : TIME : 40 Minutes MARKS : [ ___ /15] TEST CODE : ELCM [6]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 15 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. Given the standard reduction potentials
2
Zn / Zn 0.74V
+
= ;
2
Cl / Cl 1.36 V

=
2
1
H / H 0V
2
+
= and
2 3
Fe / Fe 0.77V
+ +
=
The order of increasing strength as reducing agent is :
(A)
2
2
Cl , Zn, H , Fe
+
(B)
2
2
H , Zn, Fe , Cl
+
(C)
2
2
Cl , Fe , Zn, H
+
(D)
2
2
Cl , Fe , H , Zn
+
2. The standard reduction potentials of
2 2
Zn | Zn, Cu |Cu
+ +
and Ag | Ag
+
are respectively 0.76, 0.34 and 0.9 V. The following
cells were constructed
I. Zn | Zn
2+
|| Cu
2+
| Cu II. Zn | Zn
2+
|| Ag
+
| AgIII. Cu | Cu
2+
|| Ag
+
| Ag
(A) II > III > I (B) II > I > III (C) I > II > III (D) III > I > II
3. The metal used to recover copper from a solution of CuSO
4
is:
(A) Fe (B) He (C) Na (D) Ag
4. When Cu reacts with AgNO
3
solution, the reaction takes place is :
(A) Oxidation of Cu (B) reduction of Cu (C) oxidation of Ag (D) reduction of
3
NO

5. Which will reduce zinc oxide to zinc?


(A) Mg (B) Pb (C) Cu (D) Fe
6. The metal that does not displace hydrogen from an acid is:
(A) Ca (B) Al (C) Zn (D) Hg
7. Which of the following ions can be replaced by H
+
ions when H
2
gas is bubbled through the solutions containing these ions ?
(A) Li
+
(B)
2
Ba
+
(C)
2
Cu
+
(D)
2
Be
+
8. H
2
cannot be displaced by :
(A) Li
+
(B)
2
Sr
+
(C)
3
Al
+
(D) Ag
+
9. Reduction potentials of A, B, C and D are 0.8 V, 0.79 V, 0.34 V and 2.37V respectively. Which element displaces all the other
three elements?
(A) B (B) A (C) D (D) C
10. The rusting of iron takes place as follows
2 2
1
2H 2e O H O( )
2
+
+ + ; E 1.23 V

= +
2
Fe 2e Fe(s)
+
+ ; E 0.44 V

=
Calculate G A for the net process.
(A)
1
322kJ mol

(B)
1
161 kJ mol

(C)
1
152kJ mol

(D)
1
76kJ mol

Vidyamandir Classes
VMC/Electrochemistry 20 HWT-6/Chemistry
11. A standard hydrogen electrode has zero electrode potential because :
(A) hydrogen is easier to oxide (B) this electrode potential is assumed to be zero
(C) hydrogen atom has only one electron (D) hydrogen is the lightest element
12. The standard reduction potential of the reaction,
2 2
1
H O e H OH at 298 K is
2

+ + :
(A)
w
RT
E ln k
F
= (B)
2
1
2
H
RT
E ln [p ] [OH ]
F

=
(C)
2
1
2
H
[p ]
RT
E ln
F
[H ]
+
= (D)
w
RT
E ln k
F
=
13. The hydrogen electrode is dipped in a solution of pH3at 25 C . The potential would be : (the value of 2.303 RT/F is 0.059V)
(A) 0.177 V (B) 0.087 (C) 0.059 V (D) -0.177 V
14. The standard electrode potentials of Ag / Ag
+
is 0.80 V + and Cu / Cu
+
is + 0.034 V. These electrodes are connected through a
salt bridge and if
(A) Copper electrode acts as a cathode then
cell
E

is 0.34V
(B) Silver electrode acts as anode then
cell
E

is +0.46 V
(C) Copper electrode acts as anode then
cell
E

is 0.34V
(D) Silver electrode acts as a cathode then
cell
E

is 0.34V
15. Four the following cell with hydrogen electrodes at two different pressure p1 and p2
2 2
1 2
Pt(H ) | H (aq) | Pt(H )
p 1M p
+
emf is given by :
(A)
1
e
2
RT p
log
F p
(B)
1
e
2
RT p
log
2F p
(C)
2
e
1
RT p
log
F p
(D)
2
e
1
RT p
log
2F p
Vidyamandir Classes
VMC/Electrochemistry 21 HWT-6/Chemistry
DATE : TIME : 40 Minutes MARKS : [ ___ /15] TEST CODE : ELCM [7]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 15 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. The oxidation potential values of A, B, C and D are 0.03 0.108V, 0.07V and 0.1V + + respectively. The non-spontaneous cell
reaction takes place between :
(A) A and B (B) B and D (C) D and A (D) B and C
2. The standard reduction potential of Zn and Ag is water 298 K are,
2
Zn 2e Zn
+
+

; E 0.76V = and
Ag e Ag
+
+

; E 0.80 V = + . Which of the following reactions take place ?


(A)
2
Zn (aq) 2Ag(s) 2Ag (aq) Zn(s)
+ +
+ + (B)
2
Zn(s) 2Ag (aq) Zn (aq) 2Ag(s)
+ +
+ +
(C)
2
Zn (aq) Ag (aq) Zn(s) Ag(s)
+ +
+ + (D)
2
Zn(s) Ag(s) Zn (aq) Ag (aq)
+ +
+ +
3.
2 2
Zn | Zn (a 0.1M) || Fe (a 0.01 M) | Fe
+ +
= = . The emf of the above cell is 0.2905 V. Equilibrium constant for the cell reaction
is :
(A) 10
0.32/0.0591
(B) 10
0.32/0.0295
(C) 10
0.26/0.0295
(D) e
0.32/0.295
4. In a cell that utilises the reaction,
2
2
Zn(s) 2H (aq) Zn (aq) H (g)
+ +
+ + addition of H
2
SO
4
to cathode compartment, will
(A) lower the E and shift the equilibrium to the left
(B) lower the E and shift the equilibrium to the right
(C) increase the E and shift the equilibrium to the right
(D) increase the E and shift the equilibrium to the left
5. The
3 2
M / M
E
+ +

values for Cr, Mn, Fe and Co are 0.41V, 1.57 V, 0.77V + + and 1.97V + reszpectivtly. For which one of these
metals the change in oxidation state from +2 to +3 is easiest?
(A) Cr (B) Mn (C) Fe (D) Co
6. Copper sulphate solution does not react with
(A) zinc (B) iron (C) silver (D) All of these
7. For the electrochemical cell, M| M || X | X
+
, E (M | M) 0.44V,
+
= E (X | X ) 0.33V

= . From this data, one can deduce that


(A)
cell
E 0.77V

= (B) M X M X
+
+ + is the spontaneous
(C) M X M X
+
+ + is the spontaneous reaction (D)
cell
E 0.77V

=
8. For a cell reaction involving a two - electron change, the standard emf of the cell is found to be 0.295V at 25 C . The equilibrium
constant of the reaction at 25 C will be :
(A)
10
1 10

(B) 29.5 10 (C) 10 (D)


10
1 10
9. Which of the following metal can replace zinc from ZnSO
4
solution ?
(A) Cu (B) Hg (C) Fe (D) Al
Vidyamandir Classes
VMC/Electrochemistry 22 HWT-6/Chemistry
10. The standard emf of the cell,
2
Cd(s) | CdCl (aq) (0.1M) || AgCl(s) | Ag(s) in which the cell reaction is
2
Cd(s) 2AgCl(s) 2Ag(s) Cd (aq) 2Cl (aq)
+
+ + +
is 0.6915 V at 0 C and 0.6753 V at 25 C .
The enthalpy change of the reaction at 25 C is :
(A) 176kJ (B) 234.7kJ (C) 123.5kJ + (D) 167.26kJ
11. Out of Cu, Al, Fe and Zn, metal which can displace all others from their salt solution is :
(A) Al (B) Cu (C) Zn (D) Fe
12. For the cell, T1 | T1
+
(0.001 M) | | Cu
2+
(0.1) M | Cu
cell
E at 25 C is 0.83V.
cell
E can be increased :
(A) by decreasing [Cu
2+
] (B) by increasing [Cu
2+
]
(C) by increasing [T1
+
] (D) None of these
13. Which of the following reactions cannot be a base for electrochemical cell?
(A)
2 2 2
H O H O +
(B)
3 3 2
AgNO Zn Zn(NO ) Ag + +
(C)
3 2
AgNO NaCl AgCl NaNO + ! +
(D)
4 4 2 4 2 4 2 4 3 4 2
KMnO FeSO H SO K SO Fe (SO ) MnSO H O + + + + + +
14. In a hydrogen-oxygen fuel cell, combustion of hydrogen occurs to :
(A) generate heat (B) create potential difference between the two electrodes
(C) produce high purity water (D) remove adsorbed oxygen from electrode surface
15. In galvanic cell, the electrons flow from :
(A) anode to cathode through the solution (B) cathode to anode through the solution
(C) anode to cathode through the external circuit (D) cathode to anode through the external circuit
Vidyamandir Classes
VMC/Electrochemistry 23 HWT-6/Chemistry
DATE : TIME : 40 Minutes MARKS : [ ___ /15] TEST CODE : ELCM [8]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 15 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. Which of the following statements (or equation) is correct ?
(A) The units of cell, emf V
1
cm

(B)
cell
nF
G
E
A =
(C) In galvanic cell, chemical energy is transformed into electrical energy
(D) Oxidation state of Mn in potassium permanganate is +6
2. When a lead storage battery is discharged :
(A) lead sulphate is consumed (B) SO
2
is evolved
(C) lead is formed (D) sulphuric acid is consumed
3. In the electrolytic cell, flow of electrons is form :
(A) cathode to anode in solution (B) cathode to anode through external supply
(C) cathode to anode through internal supply (D) anode to cathode through internal supply
4. Which colourless gas evolves when NH
4
Cl reacts with zinc in a dry cell battery?
(A) NH
3
(B) N
2
(C) H
2
(D) Cl
2
5. The acid used in lead storage battery is :
(A) H
2
SO
4
(B) H
3
PO
4
(C) HCl (D) HNO
3
6. The best way prevent rusting of iron is :
(A) Making it cathode (B) Putting in saline water
(C) Both (a) and (b) (D) None of these
7. Several blocks of magnesium are fixed to the bottom of a ship to :
(A) keep away the sharks (B) make the ship lighter
(C) prevent action of water and salt (D) prevent puncturing by under - sea-rocks
8. Stainless steel does not rust because :
(A) chromium and nickel combine with iron
(B) chrominum forms an oxide layer and protects iron from rusting
(C) nickel present in it, does not rust
(D) chromium present in it
9. Corrosion of iron is essentially an electrochemical phenomenon where the cell reactions are :
(A) Fe is oxidised to
2
Fe
+
and dissolved oxygen in water is reduced to OH

(B) Fe is oxidised to
3
Fe
+
and H
2
O is reduced to
2
2
O

(C) Fe is oxidised to
2
Fe
+
and H
2
O is reduced to
2
O

(D) Fe is oxidised to
2
Fe
+
and H
2
O is reduced to O
2
Vidyamandir Classes
VMC/Electrochemistry 24 HWT-6/Chemistry
Paragraph for Question 10 - 12
Consider addition of the following half-reactions :
1.
3 0
1
Fe (aq) 3e Fe(s) E 0.45V
+
+ =
2.
2 0
2
Fe(aq) Fe (aq) 2e 2e E 0.04V
+
+ + =
3.
3 2 0
3
Fe (aq) e Fe (s) E ?
+ +
+ =
Because half-reaction (1) and (ii) contain a different number of electrons, the net reaction (3) is another half-reaction, and
0
3
E cant be
obtained simply by adding
0
1
E and
0
2
E . The free energy change, however, are additive because G is a state function :
0 0 0
3 1 2
G G G A = A + A
10. If number of electrons in the reaction are n
1
, n
2
and n
3
respectively, then standard electrode potential of reaction (3) is :
(A)
0 0
0 1 1 2 2
3
3
n E n E
E
n
+
= (B)
0 0
0 1 1 2 2
3
3
n E n E
E
n

= (C)
0
3 1 2
E E E = (D)
0
3 1 2
E E E = +
11. Standard electrode potential for the half-cell
3 2
Fe Fe
+ +
/ of the reaction (3) is :
(A) 0.41 V (B) 1.27 V (C) 0.49 V (D) 1.27V
12. For the reactions :
I.
2
4 2
MnO 8H 5e Mn 4H O
+ +
+ + +
0
E 1.51V =
II.
2
2 2
MnO 4H 2e Mn 2H O
+ +
+ + +
0
E 1.23V =
Then for the reaction :
III.
4 2 2
MnO 4H 3e MnO 2H O
+
+ + +
0
E is :
(A) 1.70 V (B) 5.09 V (C) 0.28 V (D) 0.84 V
Paragraph for Question 13 - 15
Kohlrausch law states that limiting molar conductivity of an electrode can be represented as the sum of the individual contributions of the
anions and cation of the electrolyte.
If an electrolyte on dissociation gives a
+
cations and b

anions then its limiting molar conductivity is given by


m
a b
+ +
A = +
Where, a b
+ + +
= +
13. The conductivcity of 0.001028 M acetic acid is
5 1
4.95 10 S-cm

. The degree of dissociation will be, if
m
A for acetic acid is
390.5
2
Scm / mole .
(A) 1.23 (B) 0.0123 (C) 0.123 (D) None of these
14. The molar ionic conductances of Ca
2+
ion and
4
SO

ion at infinite dilution are 119 and 160
2
Scm / mole respectively.
Calculate the molar conductance of 0.1 M CaSO
4
solution of its degree of dissociation is 10%.
(A) 279 S cm
2
/mole (B) 2.79 S cm
2
/mole (C) 27.9 S cm
2
/mole (D) 30.6 S cm
2
/mole
15. Calculate the value of specific conductance for the above question :
(A)
3
2.79 10 S/ cm

(B)
4
2.79 10 S/ cm

(C)
4
30.6 10 S/ cm

(D)
4
3.06 10 S/ cm