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Comments
• Remember to give answer in 1 dp
Comments:
• Remember to convert to SI units when using the PV=nRT formula.
(d)(i)
F x xx
F
x
Xe
x xx
x
F F
Comments:
• Xe can expand its octet. Hence, there will be a total of 6 electron
pairs around Xe.
• Thus, it is not surprising to see Xe exists in compounds.
Kwok YL 1
N2004 P3
2 (a)
V Temp: 298 K
Pressure: 1 atm
Pt electrode
1 moldm-3 of Fe3+,
1 moldm-3 of H+
1 moldm-3 of Fe2+
3 (a) A weak acid is an acid that does not dissociates completely to give H+
E ions.
Kwok YL 2
N2004 P3
[H+ ]2
1.74 × 10-5 = (assuming 0.100 >> [H+])
0.100
[H+] = 1.319 × 10-3 mol dm-3
pH = -lg (1.319 × 10-3)
= 2.88
(b)(ii)
pH
14
2.88
0
10.0 Volume of NaOH /cm3
Comments:
• When choosing an indicator for titration, always relate to the working
pH of the indicator.
• No need to calculate the specific pH at the equivalence point. You
would need to show the relative pH at the equivalent point.
3 (a) A buffer is a solution containing a weak acid (or base) and its soluble
O salt. It is able to resist change in pH when small amounts of acid or
base is added, resulting in a negligible change in the pH.
Comments:
• Do take note that pH of a buffer change very very very slightly when
small amount of acid or base is added. However, the pH of the
buffer remains relatively the same hence, we claim that buffer
resists pH changes instead of saying no pH change occurs.
Kwok YL 3
N2004 P3
(c) [HCO2 ]
−
pH = pKa + lg
[CO 2 ]
= -lg (7.90 × 10-7) + lg 20
= 7.40
4 (a) Higher density; higher melting point (or boiling point); higher
conductivity; higher tensile strength (stronger); harder; smaller
metallic/atomic radius (any 2)
(b)(ii) 1s22s22p63s23p63d34s2
Comments:
• Because of the electronic configuration of V, hence it results in the
+1 oxidation number of V to be unfavourable, as V would rather lose
a minimum of 2 electrons from the 4s subshell.
(b)(iv) In [V(H2O)6]3+, the 3d subshell of V3+ are split into 2 sets of orbitals with
different energies by the ligands i.e. H2O. The electrons from the lower
energy d-orbitals absorb energy corresponding to orange-red light and
are excited to the higher energy 3d-orbitals. The unabsorbed
wavelengths correspond to the blue-green colour observed.
Comments:
• Mention about what causes the d subshell to split.
• Mention about absorbing of a particular light colour.
• Mention about the reflection of the complementary colour.
Kwok YL 4
N2004 P3
(b)(i) AlCl3 has a low melting point/ reacts with water to form an acidic
solution/ does not conduct electricity/ dissolves well in organic solvents.
(b) NaCl – ionic bonding; MgCl2 – ionic bonding; AlCl3- covalent bonding;
SiCl4 – covalent bonding
Comments:
• Please show the reaction of the chloride when dissolved in water first
before showing any form of partially hydrolysis that is taking place
due to the polarising power of the cation.
Kwok YL 5
N2004 P3
(d)(i) Element S Cl
% mass 31 100 – 31 = 69
31 69
mass ratio
32.1 35.5
mol ratio 1 2
Empirical formula is SCl2.
(d)(ii)
Cl S Cl
x
xx
x
6 (a) H H H
H H H H H H H H H H C C H
H C C C H H C C C H C C H
C C H H C C H H C H
H H H H H H
1 2a 2b
H H H H H H H H H
H C C H C C H H H C C H
C C H H H C C H C C
H C H H C H H C H
H H H H H
3 4 5
Kwok YL 6
N2004 P3
and
(ii)
CH3CH=CHCH2OH CH2 CH OH
Compound A Compound B
CH3 CH O CO CH2 O CO
Compound A Compound B
Heat under reflux with NaOH(aq), cool down, add I2(aq) and NaOH(aq)
and warm.
Compound A would produce a yellow precipitate of CHI3 while
compound B would not.
Comments:
• In trying to distinguish two different esters, hydrolysis should be
carried out first. Occasionally, distillation should also occur after so
as to ensure the desired positive result is obtained.
(c)
Cl CHO COCl
Compound A Compound B
AgNO3(aq), room conditions
Compound B would produce white fumes of HCl and a white precipitate
of AgCl while compound A would not.
OR
AgNO3(aq), excess NH3(aq), warm
Compound A would produce a silver deposit while compound B would
produce a white precipitate.
(d)
CONHCH3 CH3CONH
Compound A Compound B
Heat under reflux with NaOH(aq), cool the mixture and acidify with
followed by with HCl(aq.
A white precipitate (benzoic acid) would be formed with compound A
while mixture from compound B would not.
OR
Kwok YL 7
N2004 P3
Heat under reflux with NaOH(aq), cool the mixture and neutralise the
mixture carefully with HCl(aq), followed by addition of Br2(aq) under
room conditions.
Mixture from compound B would decolourise the reddish-brown Br2
while the mixture from compound A would not.
Comments:
• In trying to distinguish two different amides, hydrolysis should be
carried out first. Occasionally, distillation should also occur after so
as to ensure the desired positive result is obtained.
• The second test which makes use of Br2(aq) has to be done carefully
hence it is not a very suitable test.
8E (a)(i) G is formed from C2H5OH and reacts with alkaline aqueous iodine
⇒ G has the CH3CH(OH)- or CH3CO- group
G reacts with 2,4-dinitrophenylhydrazine and Fehling's reagent
⇒ G is a aliphatic aldehyde
Hence, G is CH3CHO.
H reacts with sodium metal
⇒ H contains -OH group
H is produced from G (CH3CHO) by reaction with HCN and trace of
NaCN
⇒ nucleophilic addition of G has occurred to produce a cyanohydrin
RCH(OH)CN
Hence, H is CH3CH(OH)CN
8O (a)(i) Cl2, UV
Cl + H C C + HCl
H H
The C6H5CH2• radical will then react with a Cl2 molecule to form
C6H5CH2Cl and a Cl• radical.
H H
C + Cl Cl C Cl + Cl
H H
Finally, in the termination stage, 2 radicals will combine e.g.
Kwok YL 8
N2004 P3
H H
C + Cl C Cl
H H
Cl + Cl Cl Cl
(b)(i) C6H5CH2CN
(c)(ii) Reduction
Kwok YL 9