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DuTemp Corporation provides the owners representative management function normally provided by executives of major oil refining companies. A number of our individuals have prior greenfield refinery project development experience in major refining complexes around the world. DuTemp's Financial Guarantees are Tradable Instrument from "AA" Rated Bank with up to 7.5% interest coupon Equal to Amount of Investment.
DuTemp Corporation provides the owners representative management function normally provided by executives of major oil refining companies. A number of our individuals have prior greenfield refinery project development experience in major refining complexes around the world. DuTemp's Financial Guarantees are Tradable Instrument from "AA" Rated Bank with up to 7.5% interest coupon Equal to Amount of Investment.
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DuTemp Corporation provides the owners representative management function normally provided by executives of major oil refining companies. A number of our individuals have prior greenfield refinery project development experience in major refining complexes around the world. DuTemp's Financial Guarantees are Tradable Instrument from "AA" Rated Bank with up to 7.5% interest coupon Equal to Amount of Investment.
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and Cogeneration 1 Prepared By: Farid Seif / CEO DuTemp Corporation
Table of Contents
2 Introduction Section I Section IV Section II Section III Section V Section VI DuTemp Corporation Plasma Arc Reactors Plasma Arc Process DuTemp Business Model & Costs DuTemp Plasma Arc Flow Charts Introduction to Plasma Arc Technology Current Gasification Technologies Section VI Case Study Illinois Who We Are DuTemp Corporation provides the owners representative management function normally provided by executives of major oil refining companies addressing all of the applicable and typical issues and phases involved in a project of this nature. Our capabilities come from years of working in refining related areas.
These areas include:
refinery project development; greenfield and revamped refinery project startup; crude and product supply and coordination; refinery operations, maintenance, staffing and organizational development.
With this function, significant expertise is provided in areas of refining markets, grass roots refining configuration and project development, efficient manning and operations, and possibly most important, refining engineering problem solutions not addressed by other engineering firms.
This expertise consists of smaller issue-specialized analytical capabilities derived form former oil executives, refinery managers, engineering managers and project construction executives who are willing to contribute to the project's success. A number of our individuals have prior greenfield refinery project development experience in major refining complexes around the world. 3 DuTemps Performance Guarantee DuTemp Corporation will GUARANTEE the Performance of its Plants against the Benchmarks set by FEED Study; In the event of Plant Performances not meeting the Benchmarks set by FEED Study, DUTEMP RETURNS 100% OF INVESTMENT WITHOUT ANY QUESTIONS; DuTemps Financial Guarantees are Tradable Instrument from AA Rated Bank. The said instrument maybe any of following: Bank Guarantee (BG) Bank Promissory Note Medium Term Note (MTN) with up to 7.5% interest coupon Equal to Amount of Investment (DuTemps Choice) DuTemp builds its Plants under Standard Guarantee requirements mandated by the Hosting State/Country; DuTemp Corporation is the ONLY Company in the World that provides Performance Guarantee and Financial Guarantees towards Plasma Arc Reactor. DuTemps Plants design exceeds all emission mandates set by US- EPA, European Union, IMF, World Bank and WTO and will meet all ISO Certifications. 4 PLASMA ARC TECHNOLOGY Section I 5 Plasma Arc Technology WHAT IS PLASMA?
Fourth State of Matter, Ionized Gas Created by Converting Electrical Energy into Thermal Energy, Creates Extremely High Temperature / Energy Levels, Thermal Arc at 30,000 to 33,000 Degrees Fahrenheit, Fourth State of Matter, Ionized Gas at High Temperature Capable of Conducting, Lightening is an Example from Nature. 6 Chemistry Basic Chemistry Matter is made up of molecules
Molecules are two or more atoms held together
Atoms are held together Atomic Bonds
Atomic Bonds have a certain amount of energy the Bond Energy
If the Bond Energy is exceeded, the Bond Breaks Plasma Chemistry With these high temperatures (above 2,250 Degree Fahrenheit), molecules exposed to a plasma are ionized and broken into individual atoms.
These atoms can then be re- combined into simple compounds when temperature is lowered.
It does not matter what molecule is exposed to plasma, all will dissociate. 7 Plasma Arc Technology PYROLYSIS:
Without Oxygen, materials in furnace dont combust,
Pyrolysis Dissociation of Compounds into their elemental atoms and reforming them into a fuel gas-referred as Reversed Nano Gasification.
Oxygen is a by-product and not part of Process versus Incineration /Atmospheric Gasifiers that requires Oxygen (all others).
Oxygen is not part of the process but a by-product.
8 Plasma IS More Efficient
Plasma is more efficient than older methods of gasification.
The Carbon to Carbon Bonds are more difficult to break. This can not be done easily in conventional Atmospheric Gasifiers due to their low temperatures that is why Char is formed. Plasma breaks these bonds so all of the carbon is converted.
The Plasma Reaction is Endothermic. Therefore, all of the Energy required for the process is available for recovery later. 9 Plasma Arc Technology Remediation Experience Heavy Metals
Radioactive Wastes
Industrial Sludges
Municipal Solid Waste
Electric Arc Furnace Dust
Liquid / Solid Organic Wastes
PCBs
Spent Fuel (Rods)
Asbestos
Chemical Wastes
Medical Wastes
Plastics
Used Tires
Coals (Hi Sulphur / Low Grade)
Heavy Crude Oil
Bio Hazardous
Bio-Radioactive
10 Syngas By-Products The following is a short list of products directly derived from Syngas: Middle Distillates: 107 to 125 Octane Near Pure Bio-Gasoline 75 to 77 Cetane Near Pure Bio-Diesel Jet Fuel 1 to 8 Near Pure Form Naphtha, Paraffin, LPG Ammonia Urea Ammonium Sulfate Hydrogen Dimethyl Ether Ethanol Various Ox chemicals Used in Paint Manufacture Butyraldehyde Butanol 2-Ethylhexanol Di-octyl-phthalate Carboxylic Acids Polymers: Ethyl, Ethylene, Polyethylene, Propylene, Polypropylene, Styrene, etc..
11 GASI FI FACTI ON TECHNOLOGI ES Section II 12 How Many Gasification Technologies Are Out There? 1. ATMOSPHERIC GASIFIER OR HYBRID INCINERATION USING FLAME AND STARVED OF OXYGEN.
2. ATMOSPHERIC GASIFIER OR HYBRID INCINERATION USES PLASMA TORCH AND STARVED OF OXYGEN.
3. PLASMA TORCH TECHNOLOGY WITH ENCLOSED REACTORS AND GASIFICATION IN ABSENCE OF OXYGEN
4. DUTEMP/ATONN SYSTEM: PYROLYSIS IN ABSENCE OF OXYGEN WITHIN ENCLUSED REACTOR. 13 Atmospheric Gasifier or Hybrid Incineration using Flame and Starved of Oxygen
Atmospheric Gasifier or Hybrid Incineration using flame and starved of Oxygen manufactured by: GE, Shell, Conoco, Chevron, Texaco, Sasol, Eastman Kodak, Chinese Low Temp, Gasifier, (hereinafter: others) cannot meet EPA mandates and requires CO2 sequestering.
Low rate of conversion up to 32% of Carbon Molecules.
Operating Temperature is less than 1700 degrees Fahrenheit producing Furans, Dioxins, CO and CO2 during gasification process.
System could go in reveres at any time that will cause shut down and re-starting.
Requires land-filling, massive scrubbing and gas cleanup.
Produced Syngas is not clean. Use of Amine unit for CO2 separation considered very challenging/expensive as the impurities in produced Syngas will shut down the Amine Unit. Finished products contain contamination and not very clean.
14 Atmospheric Gasifier or Hybrid Incineration uses Plasma Torch and Starved of Oxygen Atmospheric Gasifier or Hybrid Incineration uses plasma torch and starved of Oxygen manufactured by: Westinghouse currently owned by Plasco Energy Group of Canada and marketed by Green Energy Technologies of Florida, (hereinafter: others) CANNOT meet EPA mandates and requires CO2 sequestering.
Low rate of conversion- up to 32% of Carbon Molecules.
Operating Temperatures is about or less than 1700 degrees Fahrenheit producing Furans, Dioxins CO and CO2 during gasification process.
System could go in reveres at any time that will cause shut down and re-starting.
Requires land-filling, massive scrubbing and gas cleanup. Produced SynGas is not clean.
Use of Amine Unit for CO2 separation considered very challenging/expensive as the impurities in produced SynGas shut down the Amine Unit.
15
Plasma Torch Technology with enclosed Reactors and Gasification in Absence of Oxygen
Plasma Torch Technology with enclosed Reactors and Gasification in absence of Oxygen marketed by others, can meet all EPA mandates and does not require CO2 sequestering.
Excellent systems for small applications when quick On and Off (such as Hazmat) is required
Operating temperatures is over 2650 degrees Fahrenheit thus Furans, Dioxins will not form.
Conversion rate of Carbon Molecules is 88% or better and does not require land-filling.
All by-products are saleable.
Produced Syngas is very clean and near pure form.
Amine unit works properly to its maximum life expectancy.
System could go in reveres seldom that will cause shut down and re-starting.
16
DuTemp/ATONN Systems: Pyrolysis in absence of Oxygen within Enclosed Reactor:
ATONN system: Pyrolysis in absence of Oxygen within enclosed reactor, jointly developed in NASA and U.S Governments labs. Patents were released by year 2000.
Can meet/exceed all current/future air and water permit requirements/mandates.
Excellent system for large operations where the reactor can stay on continuously for a year or more.
Conversion rate of Carbon Molecules is 98% or better and does not require land-filing.
All by-products are saleable. Produced Syngas is very clean and near pure form therefore Amine Unit works properly to its maximum life expectancy.
U.S Government has been the primary user of ATONN Reactors with over 30 years experience.
Massive Data for different applications including Coal processing has been collected by DOE, DOD, EPA, NASA, Los-Alamos Lab. Current use by U.S Government. 17 DuTemp CTL Plants DO NOT Differentiate Between the Quality of the Coal DuTemp CTL plants do not differentiate between the quality of coal. Our concern is the actual chain of Carbon Molecules. Our process is not combustion but Pyrolysis or the dissociation of molecules or breaking apart of Molecular Bonds.
18 PLASMA ARC REACTORS Section III 19 Standard Atmospheric Gasifier by Others, NOT Plasma Arc Enclosed Reactors 20 Some of the Advantages of Plasma Arc Reactor DOES NOT Differentiate between the Quality of Feedstock;
ANY TYPE of Carbon is Considered Feedstock;
Moisture in Coal is a Plus in this Process;
Coals BTUs are NOT Important in this Process since it is NOT Combustion;
In the Absence of Primary Feedstock, Plant can Switch to Other Sources of carbon base materials
Feedstock without Limitation;
Can Produce Electricity, Liquid Fuels or BOTH;
The Plant can be easily Expanded without Major Transformation of Original Installations.
21 Plasma Torch in Enclosed Reactor
Can meet the US-EPA Emission Guidelines, Produces NO Greenhouse Gas, Produces 10% or more Slag (pending % of in-organics) for Every Ton of Feedstock that Converts to Rockwool, Has the Ability to Recover Metals in Slab Form, $42,000 Per Barrel on Gasifier Only, Extremely High Maintenance and Expense Due to Short Life Cycle of Torch, Operating Cost for MSW is $440 per Ton and for Coal is $800 per Ton, Maximum Life Cycles are: 30 Days on Torch to Replace the Copper-Head and Torch Replacement, Every 6 to 12 months the Torch must be Revamped, Every year the Reactor must be Maintained, Reactor Life-cycle is 30 plus years, 30 Months to Implement 22 Plasma Arc Enclosed Reactors (Controlled Process) Exceed All the Current US-EPA Emission Guidelines; Zero Emissions from Reactors, Zero Wastewater Discharges; Produce 10% b to 30% slag (pending % of in-organics) for every Ton of Coal that Convert to Rockwool or Gypsum; Metal Recovery is Viable when its Presence is 2% plus in the feedstock; Every Liquid fuel/Polymer By-Products from Syngas are Near Pure (with Exception of Trace Elements of Catalysts from the Conversion of Syngas to Liquid Forms in PPM/PPB); Construction cost is $33,000 per Barrel on Reactor Facilities Only; Extremely Low Maintenance Cost Due to the Long Life Cycle (50 years); Maintenance Cost Less Than $2.0 Million per Reactor per year (1000 MT/Day); Operating Cost for MSW is between $17 to $22 per MT and Coal is up to $65 per MT but can be reduced significantly in larger operations; Maximum Life-cycle is 50 years before major revamp; Every 12 to 18 months requires Maintenance and Graphite Rods replacement in a 12 day Maintenance Shut Down; Manufacturing and Installation is between 24 to 30 Months. 23 Plasma Arc Technology The End Product from the Reactor are Always the Same. The Ratios may Vary depending on Changes in Chemistry or carbon chains.
WHAT GOES IN MUST COME OUT..
ORGANICS: Turn to Syngas as a Fuel or Chemical Raw Material;
INORGANICS: Turn to Vitreous Slag that is Non-Leaching and exceeds EPA Tests;
METALS: Are Recoverable in Ingots or Billets in Reducing Environment. 24 Plasma Arc Process and Its Finished Products
SYNGAS: Mainly Hydrogen and Carbon Monoxide. Significant Raw Material;
SLAG: Can be Spun into Rockwool for Insulation, Fibers have Multiple Uses (Hydroponics, Tiles, etc), Turn to Frit for Blasting Media, Cast into Tiles or Used as Aggregate;
METALS: Pig Iron, Billets. Very Easy to Analyze and Provide Chemical Certification. 25 Coal the Most Abundant Fossil Fuel in the World.. LOCATION OF THE WORLDS MAIN FOSSIL FUEL RESERVES
26 PLASMA ARC PROCESS Section IV 27 Heat Balance
The Carbon content of average Coal (on net basis) will dissociate or thermally depolymerise into 180,000 to 196,000 cubic feet of synthesis gas per net ton, having an energy value of 300 BTU per standard cubic foot of gas. The heat rate for ATONN combined cycle power generating system is expected to be about 42.277 or lower, generating 8,160 kW per ton of Coal that is processed. The processing of 1000 tons of Net Coal per day or 41 tons per hour will release 8,118,000 cubic feet of synthesis gas per hour with a total BTU value of 2,435,400,000 BTU/HR. At a heat rate of 7,277 the ATONN combined cycle gas turbine system will generate a gross of 334.56 Megawatts of Electricity per hour, twenty-four hours a day. When we deduct 104 Megawatts of this electric current to maintain the plasma arc and for other plant requirements, we are left with available supply to the grid of 230.56 Megawatts per hour (5,533.44 Megawatts per day). Heat Recovery through Freon Driven Turbines are added value and can increase the power production between 5% to 7%.
Disclaimer: All above numbers must be verified through FEED Study and Turbine selection.
28 CO2 Capturing Gas separation occurs 2 times during the Syngas production process: right after gasification itself and during burning the Syngas for power generation purposes. DuTemp Reactors will separate most impurities up front during the gasification itself. Therefore, there are less pollutants in produced Syngas versus the Atmospheric Gasification which cannot scrub out any impurities during first phase of gasification and must goes through expensive clean-up in a later phases through scrubbing techniques that are proven too costly. In the said system (by others), produced Syngas (only up to 32% conversion rate based on the carbon molecules) is highly contaminated with all different components including lots of CO, CO2, Sulphur and Metals due to uncompleted process. The presence of such impurities make it very difficult and expensive to manage the Syngas Clean Up. In order to separate the CO2 from the smoke-stack, the plant must be equipped with: Alkyl base Amine Unit , or Membrane Base Amine Unit Both type of Amine Units will shut down with the presence of impurities, especially metals in the processed gas. The gases produced in our power plants would not effect the performance or efficiency of Amine Units as there are no impurities present in the gas (Impurities are scrubbed out upfront and in the reactor and water filtration). 29 CO2 Capturing (contd)
CO2 separation success rate in in ATONN systems' power generation Smoke-Stack is 98% or better that it is far below US-EPA mandates. All other known systems including Atmospheric Units (such as GE, Duke, Shell, Texaco, Sasol, Conoco, Chinese Gasifies, Eastman Kodak) or those using Atmospheric Units with Plasma Torch (Westinghouse Systems and most others claiming they are selling Plasma Technologies(, cannot use the Amine Units efficiently due to impurities in their produced Syngas (first phase) and in their Smoke Stack (second phase) that will cause Amine shut down quickly. The captured CO2 requires sequestering process due to hi contaminants and difficulties with Amine process. CO2 sequestering is experimental, expensive and not a viable solution for 21 st
century. When the costs of Scrubbing and sequestering are added to a project value (CAPEX), the project financially is bankrupt. It is our opinion that the U.S Government shall not be responsible for CO2 Sequestering or its associated costs as it will permit bad practices. 30 How to Eliminate Nox, reduce CO2 Foot Print and Increase Efficiency in Power Plants? DuTemp will consider using the following blends of gases in its power generation units: 40% Syngas 12% Hydrogen 48% Pure Oxygen No Air is permitted in the Power Plants fire chamber thus no Nox.
With Using this Model, your finished products from the Smoke-Stack are: Near Pure Water that will be recycled back to the Plasma Reactor or Hydrogen Plant for self consumption; Steam through use of Freon Driven Turbines, its heat is extracted to produce electricity and also the steam will be condensed to produce more water. Near pure CO2 will be captured by Amine Unit for sale. If no market for sale, CO2 will be recycled back to Plasma Reactor. This balance is not possible with any other fuel for power generation except near pure Syngas produced in DuTemps Reactors.
31 Leach ability of Vitrified Coal Residue (TCLP) by US-EPA Metal Permissible Concentration (mg/l) Measured Concentration (mg/l) Arsenic 5.0 <0.1 Barium 100.0 <0.5 Cadmium 1.0 <0.02 Chromium 5.0 <0.2 Lead 5.0 <0.2 Mercury 0.2 <0.01 Selenium 1.0 <0.1 Silver 5.0 <0.5 32 Syngas Properties By US-EPA Total Vapor Flow rate Lbmol/hr 3731.9294 3731.9294 Molecular Weight 13.2391 13.2391 Enthalpy Btu/lbmole 473.6162 473.6162 Entropy Btu/lbmo/R 2.4659 2.4659 Cp Btu/lbmol/R 7.0096 Cv Btu/lbmol/R 5.0181 Cp/Cv 1.3969 Density Lb/ft3 0.034993 Z-Factor 1.0005 Flow rate (T-P) Ft3/sec 392.2015 Flow rate (STP) Mmscfd 33.9839 Viscosity cP 0.014973 Thermal Conductivity Btu/ft/hr/F 0.054064 Critical Temperature (Cubic EO) F 705.2 Critical Pressure (Cubic EOS) psia 3198.8 Heating Value (gross) Btu/scf 307.89 Heating Value (net) Btu/scf 277.35 Dew Point Temperature F 100 Bubble Temperature F -379.67 33 Sample Emissions Data From Plasma Treatment Process
DATA OBTAINED FROM PLASMA TREATMENT OF MEDICAL WASTE BY US-EPA
34 TOTAL SUSPENDED PARTICULATE MATTER 0 100 200 300 400 500 600 700 Plasma Terminal Treatment System Typical Incinerators US EPA Regulations SYSTEM C O N C E N T R A T I O N
( m g / d s c m ) BUSI NESS MODELS & COSTS Section V 35 Business Model - I Coal Conversion Plant through Plasma Arc Reactor to convert 2000 to 3000 MT/day of net Coal and produce 530 MWH to 720 MWH Electricity, (all numbers are assumptions and not valid until evaluated through FEED Study);
The Coal Conversion facilities will be designed for 24/7/365 operation by using one spare additional Reactor for maintenance;
Total Reactors are either 5 x 1000 MT/day or 7 x 1000 MT/day (Size of Reactors processing capacities are based on MSW. When consuming Coal, processing will be reduced by 50% of its actual feeding capacity but the SynGas production is 4 to 6 times higher);
One Reactor is on Standby for the maintenance of Other Reactors working on-line;
Power Generation Equipment may vary, but for this assumption, we propose 3 x GE Frame- 7FA or Dual GE Frame-9FA Power Plants;
Secondary Power Generation through Freon/Propane Driven Turbines are viable and increases the yield between 5% to 7% (additional investment required). 36 Business Model - I / Advantages Near Zero Emission from Plasma Reactors;
Very Low Emissions from the Power Plants;
Zero Fly Ash, No Mercury, etc.
Produced CO2 from burning the Syngas in Power Plant are free of any impurities and 98% of CO2 can be captured for sale in pure form or can be recycled back into the Plasma Reactor as feedstock in absence of market demand;
No Land-filling, No Residuals, All By-Products are Marketable;
No need for Cooling Towers and thus, less Water Consumption; Water quality for usage is not important.
50 years Life Expectancy on Plasma Reactors;
Price Tag is about $1.2 Million to $1.4 Million per MW of Power or between $720 Million to $840 Million for Plant with Power Generation capacity of 530 MWH to 720 MWH (must be verified through FEED Study);
The Cost of Implementation is 1/3 less than IGCC configuration with Atmospheric Gasifier by Others such as Sasol, Shell, GE, etc.. 37 Business Model - II Two Step Construction of a 250,000 bbl/day Coal to Liquid (CTL) Facility;
Feedstock: any types of Coal Deposits
First Phase: 8000 MT/day Net Coal to produce 50,000 bbl/day Liquid Fuels and 100 MW/HR Electricity for export to the Grid; Second Phase: Additional 26,000 MT/day Net Coal to produce 200,000 bbl/day of Liquid Fuels and 300 MWH Electricity;
Types of Fuels in First Phase: All Bio Diesel, Gasoline, Jet Fuel
Second Phase Fuel Production: Additional Core Products including C-3 to C-15 for secondary manufacturing.
Plants required land is between 220 acres to 500 acres with Buffer zone mandated by Local Codes and State Regulations. 38 Plasma CTL Process by DuTemp 39 DATE 11/01/07 BY JH PROJECT P102 DuTemp Coal To Liquids Plant DuTemp Corporation SIMPLIFIED PROCESS FLOW DIAGRAM 210-1556 + Coal Feeder Slurry 210-1403 FV HP Steam 2 1 0 - 1 1 0 7 FV TV F V Quench 210-1511 CW 2 1 0 - 1 2 0 2 210-1536 210-1326 PV P V To Flare PV OFFGAS OFFGAS 210-1537 LV LV % s3015 5,1 82 ID E T a n g e nt 17 , 955 A 1 A 2 D 510 610 610 2420 1525 4550 1525 By B 5 B 2 PSA ADSORBER BEDS PC FC PC PC 623 660 210-1230 2 1 0 - 1 2 3 1 210-1556 2 1 0 - 1 1 1 0 CW 210-1385 LV s1410 210-1555 s 1 4 1 2 210-1335 + s1419 . % LV s 1 4 1 6 s1407 FV s1421 s1420 11-T-101 11-T-101 11-T-101 11-T-101 MCC Fame 7FA Steam Turbine Steam Turbine Fame 7FA Power Plant Plasma Unit Fischer-Tropsch CCR Platformer Amine Unit Compression Unit Diesel Gasoline To Amine Unit FromAmine Unit Recycle from FT Reactors 5,1 82 ID E T a n g e nt 17 , 955 A 1 A 2 D 510 610 610 2420 1525 4550 1525 By B 5 B 2 5,1 82 ID E T a n g e nt 17 , 955 A 1 A 2 D 510 610 610 2420 1525 4550 1525 By B 5 B 2 Preliminary Flow Diagram Size Does Matter No Other Company is proposing gasification plants using plasma over 1500 barrels per day production from processing 300 MT/day Coal due to their reactor size restrictions. Such an operation is not feasible to the market place and does not impact it in any way or shape.
DuTemp proposes to start with a 50,000 barrels per day production unit through processing 8000 MT/day of net Coal that can easily be ramped-up to 250,000 barrels per day plants using 33,000 MT/day net Coal. Such an implementation would gets the markets attention as it is making a statement with its operational size.
The most difficult aspect of fuel production after producing near pure Syngas is the Compression Units prior to FT process (Liquid Phase). This has been solved by DuTemp while still a major obstacle for others;
Bigger Plants are more efficient due to the ability to use larger frame power plants. When comparing the GE LM6000 with Frame-9FA, the Frame-9FA is 300% more efficient with while consuming the same amount of SynGas. 40 Cost of Construction Per Plant
$33,000+ plus per Barrel on Reactors $22,000+ plus per Barrel on GTL Vessels First Phase Investment: $2.45+ Billion Second Phase: $4.8+ plus Billion (can be self-financed against the income of first phase after 6 months in operation) Total Cost for 250,000 bbl/day: $7.25+ plus Billion Storage Facilities: 15 days Storage Target Capacity: 90 Days through additional investment.
41 Conversion on $$ Basis One Ton of average Quality Coal is up to $50 USD delivered to Plant; One Ton of Standard Specs Liquid Fuel being made from Crude Oil is about $700 USD/Ton; One Ton of CTL Fuel with Near Pure Specs is above $1500+ USD/Ton; GTL Products are being made from Natural Gas (NG) only at this time; The Three Major Producers of GTL Products in the world are: Qatar, Iran & Saudi Arabia while U.S. is a net importer of these products at this time, There has been Limited Production of GTL in the World due to the High Price of NG in the past; GTL/CTL Products are Primary Additive Components for Refiners as Octane and Cetane boosting components; Octane and Cetane boosting processes in Refineries are the most costly and dangerous part of refining; Refiners are the Main Importers of GTL Fuels around the World; CTL Plant can complement the Refiners Daily Operations and Reduce their cost of Importation that will be passed to their consumers; Coal to Liquid Plants compete directly with Gas to Liquid Plants (GTL); CTL production costs are 1/3 less than GTL production costs due to lower price of feedstock.
42 Strategic Storage Facilities
If and When the Investor can build and maintain 90 days fuel storage base on 5.0 Million bbls/day usage, it will become a strategic reserve in and around the world; 50 million barrels storage facility would control the prices in the market place,
Governments and Refiners may consider a monthly rental agreement for such reserves in excess of $10.0 Million plus per month;
Storage Shelf Life: Diesel Gasoline Jet-Fuel From Refineries: 6 Months 6 Months 6 Months From CTL Plants: 8 Years 8 Years 8 Years
Biodegradable from Standard Refineries: NO Biodegradable from CTL Plant: YES 43 Other Components From Syngas Downstream Productions The ox synthesis process is also known as hydroformylation. It involves the reaction of CO and H2 with olefinic hydrocarbons to form an isomeric mixture of normal and isoaldehydes.
It is an industrial synthetic route for the conversion of olefins (in the C3- C15 range) to produce solvents, synthetic detergents, flavorings, perfumes and other healthcare products, and other high value commodity chemicals.
Over 2000 components can be made from these chains;
Toys made from Syngas components are free of all hazardous materials. This is a $33.0 Billion USD per year industry. 44 Production Costs Comparison
Ratio of Products from CTL Plants. Diesel: 60% Gasoline: 35% Jet Fuel: 15%
There are up to 15% other components from FT process such as NAPHTHA and Paraffin that is being recycled back to the Plasma Reactor in the first phase plant.
Part of the process to remove Sulphur from Coal is through adding Oxidants/Fluxes such as Lime or Limestone, etc. However, one of the best components for this portion of the process is the use of sludge from waste water that we hope to be used in our plant. 46 DUTEMPS FLOW CHARTS Section VI 47 Table of Contents Bio-Radioactive Waste to Electricity Coal to Electricity General Feed Stocks to Liquid Fuels MSW Tires Oils to Electricity Coal to Ethanol Coal to Liquid Fuels Hudson River Sludge / PCB Mercury Treatment Plant Municipal Solid Waste of Coal to Diesel via Cobalt Catalyst Turning Municipal Solid Waste / Tires to Liquid Fuels Pet Coke Liquid Fuels 48 49 50 51 52 53 54 55 56 57 58 CASE STUDY: I LLI NOI S Section VI 59 Comparative Diesel Qualities & Standards Production Ratio from Illinois Plant 60 Item Commercial California CTL Diesel US-EPA 2006 Cetane Index >32 >48 >70 >46 Aromatics (vol%) <35 <100 0 <3 Sulphur (wt%) <0.30 <0.050 0 <0.0015 Ratio of Products from Illinois Diesel: 60% Gasoline: 35% Jet Fuel: 15%
There are up to 15% other components from FT process such as NAPHTHA and Paraffin that is being recycled back to the Plasma Reactor in the first phase plant.
Part of process to remove Sulphur from coal is through adding Oxidants/fluxes such as Lime or limestone, etc. However, one of the best components for this portion of process is the use of sludge from wastewater plants that we hope to be used in our plant.
61 Summary
DuTemp proposes to conduct a Front End Engineering and Design (FEED) study for Illinois Coal, Part of FEED study would be to gasify 1 Metric Ton of Coal in a Plasma Reactor and log all data, Produce computer modeling for plants operation to verify the viability of processes and set all the performance benchmarks, Cost to produce the FEED study is equal to 1.5% of projects value + $2.5 M USD, To produce the FEED study for Illinois CTL plants first phase, a funding requirement of $27.0 M is needed from the Government or others or; To produce the FEED study for Illinois power plants first phase, a funding requirement of $12.0 M is needed from the Government or others , Duration for this study is 6 to 8 months, This study will be conducted by DuTemp and will be re-stamped by Jacob, Fluor or Stone & Webster, DuTemp will reimburse this cost upon conclusion of financing. However, through support of Coal Bond or Industrial Revenue Bonds, this fee is paid by bonds in advance or; DuTemp is willing to assume 50% of its cost if the structure is base on JV Partnership with the Government, DuTemp is open to dialogue. This is just a scenario and it is not final position of DuTemp. We request a check to DuTemp.
62 During the FEED, The Following is Completed: Process Major Equipment Definition Process Simulation and Modeling Process Flow Diagram Development Mechanical Equipment Data Sheet Development Process Written Description Preliminary Process Data Preliminary Line List Develop P & IDs
Piping Preliminary Estimate of Large Bore Pipe Participate in P & ID Development Valve Drag for Estimate Get Quotes on Pipe and Valves
Mechanical Prepare RFQ and Issue for Major Equipment Get Quotes from Vendors on All Major Equipment
Civil Preliminary Pile Counts Preliminary Drawings for All Major Structures Grey Steel Estimate Cement Estimate Control Systems Quotes for DCS and SIS Systems Quotes on All Inline Instruments 10% Estimate on All Instruments
Electrical MCC Preliminary Design Quote from Powel or GE on the Building with All Equipment Inside Rough Count of All Motors, Cables, and Cable Trays 10% Estimate
Computer Modeling Computer Modeling will Verify the Performance of All Equipments and Validate the Process in Real Time Operation. This Report, will establish All Performance Benchmarks, Processing Data, Air Emission, and Water Quality Benchmarks for Permitting to be submitted to EPA. All Guarantees are Issued based on Results from this Report.
Estimating Adds Construction Costs, including Labor, Transportation, and All Field Expense Rolls, All Disciplines Estimates to One Total Installed Cost Estimate Including: Engineering, Material Costs and Construction.
63 World Energy Facts There is only one empire in Worlds Energy Markets Middle East CTL Plants can offset this balance when it reaches the processing capacity of 150,000 plus Metric Ton Coal per day; Eventually the current price of Crude will tumble with these new alternative plants; To permanently defuse OPEC influence in world energy, Investors must investor in one million barrels per day production of CTL components; Total fuel consumption will be over 40% Bio-Fuels by year 2020; Upon the first implementation, the stock market will shift its financial resources toward Coal Gasification; We forecast the implementation of over 1.0 Million bbl/day CTL plants by the year 2015 with proper funding that can consume 150,000 MT/day low quality Coal; DuTemp has manufacturing capacity to reach this goal by year 2018; Secondary manufacturing will obsolete China as a major exporter to the U.S; Investors can offer high paying jobs and still compete with China and S. Korea manufacturers; Investors will be able to reach the entire North America through its Hub Networks; Investors combined in CTL projects will create up to 2.0 Million high scale manufacturing jobs by 2018 in other manufacturing sectors when it is planned correctly; Same combined projects will create additional 6,000,000 jobs in service industry by 2018; Regions main income will be based on export and the health of the economy will be guaranteed until year 2050; CTL combined projects when all completed, will increase the Export on manufactured products by 30%. 64 Power Generation by Others MORE PROOF THAT COAL AINT CHEAP Duke wins approval for a $3100 / kW Plant Posted by Sean Casten at 1:54 PM on 27 Nov 2007 From E & E News ($ub reqd): Indiana has approved a $2 Billion, 630 MW integrated gasification / combined cycle coal plant. Two Billion divided by 630 MW = $3,174 / kW If we assume that Coal Equity Investors expect to recover their investment over 20 years with an eleven percent return, that works out to 5.7 cents / kWh just to pay off the capital for the power plant. Add in another 3 cents or so for transmission and distribution, and a couple cents for fuel and operating costs, and this plant will work out to be over 10 cents in retail prices. This in a state where the current average retail electric rate is 6.79 cents / kWh. So why was it approved? Simple: In the Midwest, Coal is plentiful and low-cost, and finding ways to burn it cleanly is fundamental to meeting our customers demand for power, Duke Energy Indiana President Jim Stanley said in a statement. The head spins. Excerpts of the story below the fold. Indiana utility regulators approved Duke Energys proposed $2 billion coal-fired power plant equipped with advanced pollution controls about 100 miles southwest of Indianapolis. The Indiana Utility Regulatory Commission decision followed more than two years of planning by Dukes Indiana subsidiary and its predecessor, Cinergy/PSI Indiana, which was acquired by duke in May 2006. The 630-megawatt, integrated gasification combined cycle (IGCC) plant, which still must obtain permits from the Indiana Department of Environmental Management, could begin construction in Knox County early next year with an expected startup in early 2012, Duke Officials said.
Note: Please se financial figures of $3.1 Million USD per MW power plants cost but recently was increased again.