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(A study Report)
Abstract
A reactor is the heart of a chemical process industry. So its design has a vital role. In its design, the reactor geometry is taken as the most important factor. The reactor geometry means to get the minimum reactor size (reactor volume) for the maximum yield; either it is a single reactor or the different reactor combinations of same/different sizes. In the optimization of the reactor design, we establish the rules for good reactor behavior by minimizing the overall cost and maximizing the yield and ultimately the profit by correlating different design parameters with the economic factors. In this report, some of these rules are elaborated.In the last, the major findings of the whole report are briefly discussed
Contents
1. 2. 3. Scope of Optimization in Chemical Reactor Design.............................................................................. 1 Optimum Performance ......................................................................................................................... 2 Different Cases ..................................................................................................................................... 2 a) Optimum operation of reversible reaction in an adiabatic reactor design .......................................... 2 b) Determining the best system for the given conversion ....................................................................... 5 c) Optimum Recycle Ratio ......................................................................................................................... 6 d) Optimum Temperature progression..................................................................................................... 7 e) Maximizing the desired product in series reaction .............................................................................. 8 f) Optimum Cycle period with Downtime ................................................................................................. 9 g) Optimum Reaction Temperature with Downtime .............................................................................. 11 h) Minimum residence time in a PFR ...................................................................................................... 13 i) Optimal Temperature for Staged Packed Bed reactor ........................................................................ 14 j) Autocatalytic reactions with recycle .................................................................................................... 15 k) Optimum operation of Fermenters .................................................................................................... 16 l) Optimization of the Process Conditions to get maximum yield .......................................................... 17 m) Optimization of the reactor volume to get maximum yield .............................................................. 17 Summary ..................................................................................................................................................... 20 4. Optimum Operation of Reactors ............................................................................................................ 22 Findings ....................................................................................................................................................... 24 Appendix ..................................................................................................................................................... 25
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Coulson and Richardsons Chemical Engineering series, R K Sinnott, Volume 6 , Edition 4 , Page # 486.
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2. Optimum Performance2
A few specific conclusions about optimum performance can be stated: The minimum total volume of a CSTR battery for first-order reaction, and near-minimum for second order, is obtained when all vessels are the same size. An economical optimum number of CSTRs and their auxiliaries in series is 4 to 5. In a sequence of PFR and CSTR, better performance is obtained with the PFR last. Performance of reversible reactions is improved with the CSTR at a higher temperature. For the consecutive reactions A B C, a higher yield of intermediate B is obtained in batch reactors or PFRs than in CSTRs. When the desirable product of a complex reaction is favored by a high concentration of some reactant, batch or semi-batch reactors can be made superior to CSTRs. Conversion by a reversible reaction is enhanced by starting out at high temperature and ending at low temperature if equilibrium conversion drops off at high temperature. For a reversible reaction, the minimum size or maximum con-version is obtained when the rate of reaction is kept at a maximum ateach conversion by adjustment of the temperature.
3. Different Cases
a) Optimum operation of reversible reaction in an adiabatic reactor design 3
Consider an adiabatic reactor in which a reversible exothermic reaction is being conducted by the variation in the feed temperature; there are following two cases Using a very high feed temperature the specific reaction will be close to zero, consequently very little product will be produced. Using a very low feed temperature the specific reaction rate will be small that virtually all of the reactant will pass through the reactor without reacting. Between these two extremes, there must be an optimum feed temperature that maximizes conversion. This optimum inlet temperature is shown in the figure 1.1.
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Chemical Engineers Handbook, Perry, Volume 1, Edition 7, Page # 7-25. rd Elements of Chemical Reaction Engineering, H. Scott Fogler, Edition 3 , Page # 486. th Chemical Engineers Handbook, Perry, Edition 7 Page # 7-16,7-17.
Figure 1.1:Finding the optimum feed temperature. For exothermic reactions, while the temperature and conversion increase down the length of reactor, the equilibrium conversion decreases. To determine the maximum conversion that can be achieved in an exothermic reaction carried out adiabatically, we find the intersection of the equilibrium conversion as a function of temperature with temperature-conversion relationships from the energy balance in figure 1.2.
Figure 1.2:Graphical solution of equilibrium and energy balance equations to obtain adiabatic
temperature and equilibrium conversion.
Figure 1.3: Variation of equilibrium conversion with temperature for an exothermic reaction. Take an example of first order reversible chemical process. ( ) ( )
( )
Where, A1 = frequency factor for forward reaction B1 = Activation energy for forward reaction A2 = frequency factor for backward reaction B2 = Activation energy for backward reaction
Figure 1.4: The graphical representation of the variables for two mixed flow reactors in series. This figure 1.5 shows that the total reactor volume is as small as possible (total shaded area is minimized) when the rectangle KLMN is as large as possible which is called the maximization of rectangles.
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The area of the rectangle is according to equation 3; the area is maximized when M is at that point where the curve equals the slope of the diagonal NL of the rectangle. The optimum size ratio of the two reactors is achieved where the slope of the rate curve at M equals the diagonal NL. The best value of M is shown in figure 1.5; this determines the intermediate conversion X1 as well as the size of units needed. From this study some special cases arises: For the special case of first-order reactions equal size reactors are the best. For the reaction orders n>1, the small reactor should come first. For n<1, the larger should come first.
rd
[ .
] / (
, -
Figure 1.6:Correct recycle ratio compared with recycle ratios which are too high and too low. In words, the optimum recycle ratio introduces to the reactor a feed whose 1/r A value (KL in figure 1.6) equals the average - 1/rA value in the reactor as a whole (PQ in figure 1.6).
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Initial feed temperature In the adiabatic reactor operation the temperature inside the reactor is controlled by the initial feed temperature. The following heat balance equation (point slope form) over a reactor is used to find the initial feed temperature. ( Where, XA1 and XA2 are the initial and final conversions of a key component A. Cp is the heat capacity of the reactants. Hr is the heat of reaction. T2 is the required temperature inside the reactor. T1 is the initial feed temperature For an exothermic reaction T1 is always lower than T2 while for an endothermic reaction T2 is greater than T1. In the adiabatic reactor in which the heat is exchanged with the surroundings, the equation 5 is modified as follows. ( )( ) ( ) )( ) ( )
Where R is the desired product. The values of k1& k2 give the location and maximum conversion of R. This may be found by differentiating the equation 7,8&9.
Chemical Reaction Engineering, Octave Levenspiel, Edition 3 , Page # 53-56. nd Elements of Chemical Reaction Engineering, H. Scott Fogler, Edition 2 , Page # 461.
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, -
The number of daily batches can be found as, ( The daily yield is found as, . . / Where, k = rate constant Vr = Volume of the reactor Co = Initial molar concentration The ordinate of the plot is which is proportional to the daily yield. The peaks in the /
, -
The downtime is 1 h per batch. Find the temperature at which the daily production is a maximum. The reaction time of one batch is, ( )
as a function of temperature. Equation 13 is integrated with POLYMATH for at 550K, tb=0.6 and =0.3105.
several temperatures and results are plotted. The tabulation gives the integration at 550 K. the
Figure 1.10
[(
Figure 1.11
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Figure 1.12:Optimum two-stage packed bed reactor. Guess Ta. Move along the adiabatic line until the following condition is satisfied: ( ) ( )
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This gives point b in Fig. 1.12, thus the amount of catalyst needed in the first stage as well as the outlet temperature from that stage. Especially in preliminary design it may not be convenient to use the criterion of Eq. 14. A simple alternative is a trial-and-error search. Usually two or three carefully chosen trials keeping away from low rate conditions will yield a good design, close to the optimum. Cool to point c which has the same rate of reaction as point b; thus (-ra)leaving a reactor = (-ra)entering the next reactor Move along the adiabatic from point c until the criterion of Eq. 14 is satisfied, giving point d. If point d is at the desired final conversion then we have guessed T a correctly. If point d is not at the desired final conversion try a different incoming temperature T a. Usually three trials will very closely approach the optimum.
Figure 1.13: Sketch showing how staged packed beds can closely approach the optimal
temperature progression.
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Figure 1.14
shown in Fig. 1.15. With this form of rate-concentration curve we should operate as follows: To reach any point between A and B run part of the feed at A in mixed flow and mix with the rest of the feed. To reach any point between A and 0 go directly to point A in mixed flow, then use plug flow beyond A. These two rules represent the key to optimum reactor behavior.
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By seeing the balanced chemical equation, we can have three ways to maximize the yield of ammonia:By continual withdraw of ammonia after intervals, the equilibrium will shift to forward direction in accordance with Le-Chateliers Principle Increase the pressure to decrease the volume of the reaction vessel. Four moles of the reactants consign to give the two moles of the products. High pressure will shift the equilibrium position to sight to give more and more ammonia Decreasing the temperature will shift it to the forward direction according to LeChateliers . One needs a compromise to optimize the yield and the rate. The temperature is raised to a moderate level and a catalyst is employed to increase the rate. If one wants to achieve the same rate without a catalyst, then it requires much high temperature, which lowers the yield. Hence the optimum conditions are the pressure of 200-300 atm and temperature around 673K (400 oC). The catalyst is the piece of iron catalysts emsedeled in a fused mixture of MgO, Al2O3 and SiO2. The equilibrium mixture has 35 % by volume of ammonia. The mixture is cooled by refrigeration coils until ammonia condenses (B.P = -33.4 C) and is removed. Since B.P`s of N2 and H2 are very low, they remain in the gaseous state and are recycled by pumps back into the reaction chamber.
Temperature (K) 200 300 400 500 600 700 800 KC 7.17 x 1015 2.69 x 108 3.94 x 101 1.72 x 102 4.53 x 100 2.96 x 10-1 3.96 x 10-2
High pressure, low temperature with the use of catalyst and continual removal of NH 3 will give the maximum yield of ammonia
called the Trambouze reactions are to be run in four equal-size MFR's (mixed flow reactors), connected any way you wish. The feed is CAo = 1, the feed flow rate is = 100 liters/min. The best scheme that the computer could come up with to maximize the fractional yield of S, or (S/A) & optimize the volume of four reactors.
Figure 1.17
First of all, the computer solution looks somewhat complicated from the engineering point of view. But never mind; let us proceed with our calculations. The instantaneous fractional yield, (S/A), is
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Thus the best way of running these four reactors is to keep the conditions at the optimum in all four units.
Figure 1.17
The volume of MFR comes from the performance equation.
Summary15
For the optimum reactor system, the rules for good reactor behavior for both homogenous and heterogeneous systems are summarized as follows: Rule 1. For Single Reactions To minimize the reactor volume, keep the concentration as high as possible for a reactant whose order is n > 0. For components where n < 0, keep the concentration low. Rule 2. For Reactions in Series Consider reactions in series, as shown:
To maximize any intermediate, do not mix fluids that have different concentrations of the active ingredients-reactant or intermediates. See Figure. 1.17. Rule 3. For Parallel Reactions Consider the parallel reactions with reaction orders ni
To get the best product distribution, Low CA, favors the reaction of lowest order. High CA, favors the reaction of highest order. If the desired reaction is of intermediate order then some intermediate C A, will give the best product distribution. For reactions all of the same order the product distribution is not affected by the concentration level.
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Figure 1.17:(a) Plug flow (no intermixing) gives the most of all the intermediates. (b) Intermixing
depresses the formation of all intermediates.
Rule 4. Complex Reactions These networks can be analyzed by breaking them down into their simple series and simple parallel components. For example, for the following elementary reactions, where R is the desired product, the breakdown is as follows:
This breakdown means that A and R should be in plug flow, without any recycle, while B can be introduced as you wish, at any concentration level, since it will not affect the product distribution. Rule 5. Continuous versus Non-continuous Operations Any product distribution that can be obtained in continuous steady-state flow operations can be gotten in a non-flow operation and vice versa. Figure 1.18illustrates this.
Figure 1.18:Correspondence between the residence time distribution of steady flow and either nonflow, batch or semi-batch systems
a high temperature favors the reaction with larger E, while a low temperature favors the reaction with smaller E. Let us now see how these six rules can be used to guide us to the optimum.
Feed a stream containing reactant A to a reactor and let R, S, T,... be formed, with R being the desired product. Then by optimum We could mean maximizing the overall fractional yield of R, or ( ) ( )
We could mean running the reactor system so that the production of R is maximized, or ( ) ( )
For reactions in series we calculate the maximum production rate of R directly. However, for reactions in parallel we find it useful to first evaluate the instantaneous fractional yield of R, or ( ) ( )
and then proceed to find the optimum. If unused reactant can be separated from the exit stream, re-concentrated to feed conditions and then recycled, then ( ) ( )
Findings16
As for the optimal reactor design is concerned, my findings in this report are described as follows: Generally the isothermal tubular reactor (PFR) is better than the CSTR for the same conversion for all types of reactions because of its smaller volume. For Autocatalytic reactions, mixed flow reactor (CSTR) is more efficient at low conversions; (PFR) is more efficient at high conversions. For all types of Auto-thermal (in which heat may be considered to be the product which sustains in the reaction) reactions CSTR will be preferred because with PFR the reaction will die out. For all types of ordinary nth order reactions (n>0), PFR is always more efficient than CSTR but a PFR will not operate at all with feed of pure reactants. So feed must be continually primed with product that PFR with some recycle (recycle reactor) must be used. For final conversion smaller than the point of maximum rate, PFR is better than any recycle reactor. For conversions higher than the point of maximum rate, the recycle reactor with proper recycle ratio is superior to rather the PFR or CSTR.
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Chemical Reaction Engineering by Octave Levenspiel,Edition 3 nd Elements of Chemical Reaction Engineering by H. Scott Fogler.Edition 2 , th th Coulson and Richardsons Chemical Engineering series by R K Sinnott, Volume 6 , Edition 4 . Chemical Engineers Handbook, Perry, & Section 7, Volume 1, Edition 7.
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Appendix
[1]Optimum Recycle Ratio
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Initial Conditions
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