SMK LUTONG

CHEMISTRY
Paper 2
<Test Name>

<Date>

Class :

Time :
Marks :

This question paper consists of three sections: Section A, Section B and Section C.
Kertas soalan ini mengandungi tiga bahagian: Bahagian A, Bahagian B dan Bahagian C.
Section A
Bahagian A
[60 marks]
[60 markah]
Answer all questions in this section.
Jawab semua soalan dalam bahagian ini.
1. The diagram below shows the apparatus set up to measure the average rate of reaction between 2 g of
granulated calcium carbonate and 25 cm3 of 1.0 mol dm3 hydrochloric acid.
Rajah di bawah menunjukkan susunan radas untuk menghitung purata kadar tindak balas bagi tindak balas
antara 2 g cebisan kasium karbonat dan 25 cm3 asid hidroklorik 1.0 mol dm3.

DIAGRAM/RAJAH
The gas evolved is measured at 30-second intervals. The results collected are shown in the table below.
Gas yang dibebaskan dihitung pada setiap selang masa 30 saat. Keputusan yang dikumpul ditunjukkan dalam
jadual di bawah.

TABLE/JADUAL
(a)i. Write a chemical equation for this reaction.
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Tulis satu persamaan kimia bagi tindak balas ini.

____________________________________________________________________________________
_
[1 mark/1 markah]
ii. Name the gas evolved in this reaction.
Namakan gas yang dibebaskan dalam tindak balas ini.
____________________________________________________________________________________
_
[1 mark/1 markah]
iii.Give a test to identify the gas collected.
Berikan satu ujian untuk mengesahkan gas yang terkumpul.
____________________________________________________________________________________
_
[1 mark/1 markah]
(b Plot a graph of the volume of gas against time.
) Plot satu graf bagi isi padu gas lawan masa.

[3 marks/3 markah]
(c)Based on the graph in (b), calculate
Berdasarkan graf dalam (b), hitung
i. the average overall rate of reaction.
Purata kadar tindak balas keseluruhan.

ii. the average rate of reaction for the fi rst 90 seconds.

purata kadar tindak balas bagi 90 saat pertama.

iii. the rate of reaction at 90 seconds.

kadar tindak balas pada 90 saat.

[6 marks/6 markah]
(d Compare the rate of reaction at 60 seconds and that at 90 seconds. Give one reason for your answer.
) Bandingkan kadar tindak balas pada 60 saat dan 90 saat. Berikan satu sebab bagi jawapan anda.
_____________________________________________________________________________________
_____________________________________________________________________________________
[2 marks/2 markah]
2.

The diagram below shows two sets of experiments carried out to study a factor aff ecting the rate of reaction
2

between magnesium ribbon, Mg, and sulphuric acid, H2SO4.

Rajah di bawah menunjukkan dua set eksperimen yang dijalankan untuk mengkaji faktor mempengaruhi
kadar tindak balas antara pita magnesium, Mg dan asid sulfurik, H2SO4 .

DIAGRAM/RAJAH
(a) Write a balanced chemical equation for the reaction in these experiments.
Tulis satu persamaan kimia seimbang bagi tindak balas dalam eksperimen tersebut.
_____________________________________________________________________________________
[2 marks/2 markah]
(b) What is the data needed to be taken in both experiments to determine the rate of the reaction in 3 minutes?
Data apakah perlu diambil dalam kedua-dua eksperimen untuk menentukan kadar tindak balas dalam
masa 3 minit?
_____________________________________________________________________________________
[1 mark/1 markah]
(c) Calculate the average rate of the reaction in Experiment I.
Hitung kadar tindak balas purata dalam Eksperimen I.

[1 mark/1 markah]
(d) i. Compare the rate of the reaction in Experiment I with that in Experiment II. Explain your answer based
on the factor aff ecting the rate of reaction.
Bandingkan kadar tindak balas dalam Eksperimen I dan Eksperimen II. Terangkan jawapan anda
berdasarkan faktor yang mempengaruhi kadar tindak balas.
__________________________________________________________________________________
__________________________________________________________________________________
[2 marks/2 markah]
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ii. Explain your answer in (d)(i) with reference to the collision theory.
Terangkan jawapan dalam (d)(i) dengan merujuk kepada teori perlanggaran.
__________________________________________________________________________________
__________________________________________________________________________________
[3 marks/3 markah]
(e) Sketch the graph of volume of hydrogen gas produced against time for the two sets of experiments in the
first 5 minutes.
Lakarkan graf bagi isi padu gas hidrogen yang dihasilkan melawan masa bagi kedua-dua eksperimen
dalam masa 5 minit pertama.

[2 marks/2 markah]
3.

The diagram below shows the processes by which the monomer of natural rubber, X, is changed to vulcanized
rubber.
Rajah di bawah menunjukkan proses-proses menukarkan monomer getah asli X kepada getah tervulkan.

DIAGRAM/RAJAH
(a) Name monomer X.
Namakan monomer X.
_____________________________________________________________________________________
[1 mark/1 markah]
(b) Monomer X undergoes process I to form natural rubber.
Name process I.
Monomer X melalui proses I untuk menghasilkan getah asli.
Namakan proses I.
_____________________________________________________________________________________
[1 mark/1 markah]
(c) Draw the structure of the polymer formed.
Lukis struktur polimer terbentuk.

[1 mark/1 markah]
(d) Name process II by which natural rubber is changed to vulcanized rubber.
Namakan proses II untuk menukarkan getah asli kepada getah tervulkan.
_____________________________________________________________________________________
[1 mark/1 markah]
(e) Suggest one substance, Y, that can be used to vulcanize natural rubber.
Cadangkan satu bahan Y yang boleh digunakan untuk menvulkan getah asli.
_____________________________________________________________________________________
_____________________________________________________________________________________
[1 mark/1 markah]
(f) Give one example of a chemical that will coagulate latex.
Berikan satu contoh bahan kimia yang boleh menggumpalkan lateks.
_____________________________________________________________________________________
_____________________________________________________________________________________
[1 mark/1 markah]
(g) When latex is exposed to air, coagulation occurs naturally. Give a reason.
Apabila terdedah kepada udara, lateks akan tergumpal secara semula jadi. Beri satu sebab.
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
[3 marks/3 markah]
4.

Diagram below shows the arrangement of the apparatus in an experiment to investigate the effect of another
metal on the rusting of steel. Both test tubes are left for two days. The colour of the jelly in test tube A turns
pink whereas the colour of the jelly in test tube B turns blue.
Rajah di bawah menunjukkan susunan alat radas satu eksperimen untuk mengkaji kesan logam lain ke atas
pengaratan besi. Kedua-dua tabung uji dibiarkan selama dua hari. Didapati warna agar-agar dalam tabung
uji A berubah menjadi merah jambu sementara warna agar-agar dalam tabung uji B berubah menjadi biru.

Diagram /Rajah
(a) (i) Write the formula of potassium hexacyanoferrate(III).
Tulis formula bagi sebatian kalium heksasianoferat(III).
__________________________________________________________________________________
__________________________________________________________________________________
[1 mark/1 markah]
(ii) What is the reason for adding potassium hexacyanoferrate(III) solution into each test tube?
Apakah tujuan mencampurkan larutan kalium heksasianoferat(III) ke dalam setiap tabung uji?
__________________________________________________________________________________
__________________________________________________________________________________
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__________________________________________________________________________________
[2 marks/2 markah]
(b) What particle causes the colour change in...
Apakah zarah yang menyebabkan perubahan warna dalam
(i) test tube A: ________________________________________________________________________
tabung uji A:
(ii) test tube B: ________________________________________________________________________
tabung uji B:
[2 marks/2 markah]
(c) Write a half-equation for each of the following reactions:
Tuliskan setengah persamaan bagi tindak balas:
(i) reduction in test tube A.
penurunan dalam tabung uji A.
__________________________________________________________________________________
__________________________________________________________________________________
[1 mark/1 markah]
(ii) oxidation in test tube B.
pengoksidaan dalam tabung uji B.
__________________________________________________________________________________
__________________________________________________________________________________
[1 mark/1 markah]
(d) Give one suitable metal which can replace metal Y in test tube B to get the same observation as in test tube
B.
Berikan satu contoh logam sesuai untuk menggantikan logam Y di dalam tabung uji B untuk
mendapatkan pemerhatian yang sama seperti di dalam tabung uji B.
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
[1 mark/1 markah]
(e) Arrange the three metals X, Y, and iron according to decreasing electropositivity.
Susunkan ketiga-tiga logam X, Y dan ferum mengikut keelektropositifan menurun.

[1 mark/1 markah]
(f) What is the manipulated variable in this experiment?
Apakah pemboleh ubah dimanipulasikan dalam eksperimen ini?
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
[1 mark/1 markah]
5. The diagram below shows the energy profile diagram for the reaction between hydrogen and chlorine.
Gambar rajah di bawah menunjukkan gambar rajah profil tenaga untuk tindak balas di antara hidrogen dan
klorin.

Diagram/Rajah
(a)Is the reaction exothermic or endothermic?
Explain your answer.
Adakah tindak balas tersebut eksotermik atau endotermik?
Terangkan jawapan anda.
_____________________________________________________________________________________
[2 mark/markah]
(b Heat energy is required for bond breaking. What are the bonds that have been broken?
) Tenaga haba diperlukan untuk pemecahan ikatan. Apakah ikatan-ikatan yang telah dipecahkan?
_____________________________________________________________________________________
[2 mark/markah]
(c)Heat energy is released from bond making. What is the bond that has been formed.
Tenaga haba dibebaskan daripada pembentukan ikatan. Apakah ikatan yang terbentuk?
_____________________________________________________________________________________
[1 mark/markah]
(d 7.1 g of chlorine reacts completely with hydrogen.
) Sebanyak 7.1 g klorin bertindak balas dengan lengkap dengan hidrogen.
Calculate
Hitung
(i) the number of moles of chlorine gas that reacted.
[Relative atomic mass: Cl, 35.5]
bilangan mol gas klorin yang bertindak balas.
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[Jisim atom relatif: Cl, 35.5]

____________________________________________________________________________________
_
[1 mark/markah]
(ii) heat change, in joules, in the experiment.
perubahan haba, dalam joule, di dalam eksperimen.
____________________________________________________________________________________
_
[1 mark/markah]
Given that the heat released from the experiment is used to heat 500 g of water.
Diberi bahawa haba yang dibebaskan daripada eksperimen digunakan untuk memanaskan 500 g air.
[Specific heat capacity of water = 4.2 J g1 C1. Density of water = 1.0 g cm3]
[Muatan haba tentu air = 4.2 J g-1C-1; Ketumpatan air = 1.0 g cm-3]
(iii Predict the expected rise in temperature of the water.
) Ramalkan kenaikan suhu air yang dijangkakan.
____________________________________________________________________________________
_
[2 marks/markah]

6.

Diagram below shows the arrangement of the apparatus used for preparing substance Z. Substance Z is the
potassium salt of a carboxylic acid salt a long chain. In this experiment, 20 cm3 of palm oil are mixed with 50
cm3 of 3 mol dm3 potassium hydroxide solution and the mixture is heated until it has boiled for 10 minutes.
The mixture is constantly stirred with a glass rod throughout the heating. At the end of the heating, substance
Z is formed in the solution.
Rajah di bawah menunjukkan susunan radas yang digunakan untuk menyediakan satu bahan Z. Bahan Z
merupakan suatu garam kalium asid karboksilik berantai panjang. Dalam eksperimen ini, 20 cm3 minyak
kelapa sawit dicampur dengan 50 cm3 larutan kalium hidroksida 3 mol dm3 dan campuran itu dipanaskan
sehingga mendidih selama 10 minit. Campuran itu sentiasa dikacau dengan rod kaca sepanjang proses
pemanasan itu. Pada akhir pemanasan, bahan Z terbentuk di dalam larutan itu.

Diagram /Rajah
8

(a) What is the name of the reaction that takes place in this experiment?
Apakah nama tindak balas yang berlaku dalam eksperimen ini?
__________________________________________________________________________________
__________________________________________________________________________________
[1 mark/1 markah]
(b) What is the function of potassium hydroxide?
Apakah fungsi kalium hidroksida?
__________________________________________________________________________________
__________________________________________________________________________________
[1 mark/1 markah]
(c) (i) What can be observed when sodium chloride salt is added to the product of the reaction in the beaker?
Apakah yang dapat diperhatikan apabila garam natrium klorida ditambah kepada hasil tindak balas
dalam bikar?
__________________________________________________________________________________
__________________________________________________________________________________
[1 mark/1 markah]
(ii) Why is sodium chloride added?
Mengapakah garam natrium klorida ditambahkan?
__________________________________________________________________________________
__________________________________________________________________________________
__________________________________________________________________________________
[1 mark/1 markah]
(d) Suggest one method of obtaining solid substance Z in the solid form from the solution after the mixture of
palm oil and potassium hydroxide solution has been heated for 10 minutes.
Cadangkan satu kaedah untuk memperoleh pepejal bahan Z daripada larutan selepas campuran minyak
kelapa sawit dan larutan kalium hidroksida dipanaskan selama 10 minit.
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
[2 marks/2 markah]
(e) Name one substance that can replace palm oil in the preparation of substance Z.
Namakan satu bahan lain yang boleh menggantikan minyak kelapa sawit di dalam penyediaan bahan Z.
_____________________________________________________________________________________
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_____________________________________________________________________________________
[1 mark/1 markah]
Section B
Bahagian B
[20 marks]
[20 markah]
Answer any one questions from this section.
Jawab mana-mana satu soalan daripada bahagian ini.
7.

(a) Diagram below shows the structural formulae of four organic compounds.
Rajah di bawah menunjukkan formula struktur empat sebatian-sebatian organik.

Diagram/Rajah
Based on the structural formulae shown above, state the homologous series and functional group for each
of the organic compounds.
Berdasarkan formula struktur di atas, nyatakan siri homolog dan kumpulan berfungsi bagi setiap sebatian
organik yang ditunjukkan.
[4 marks/4 markah]
(b) Compound S is found to undergo addition reactions. State three addition reactions of compound S and give
one example of each reaction.
Sebatian S didapati mengalami tindak balas penambahan. Nyatakan tiga tindak balas penambahan bagi
sebatian S dan berikan satu contoh bagi setiap tindak balas.
[9 marks/9 markah]
(c) State two industrial processes that can be used to produce compound R.
Nyatakan dua proses industri yang boleh digunakan untuk menghasilkan sebatian R.
[4 marks/4 markah]
(d) State the materials needed for the preparation of compound Q and write a balanced equation for the
reaction.
Nyatakan bahan yang diperlukan untuk penyediaan sebatian Q and tuliskan persamaan seimbang bagi
tindak balas.
[3 marks/3 markah]

10

8.

(a) A hydrocarbon compound has molecular formula, C5H12. By drawing and naming according to IUPAC
system, show how isomerism occurs in this compound.
Satu sebatian hidrokarbon mempunyai formula molekul, C5H12. Dengan lukisan dan penamaan
berdasarkan system IUPAC, tunjukkan bagaimana isomer wujud di dalam sebatian ini.
[5 marks/5 markah]
(b)

Diagram/Rajah
Based on the flow chart below, explain briefly how ethyl ethanoate can be produced from glucose. Include
the following in your explanation.
Berdasarkan carta alir ditunjukkan di atas, terangkan bagaimana etil etanoat boleh dihasilkan daripada
glukosa. Di dalam penerangan kamu, masukkan perkara berikut:
(i) Chemical equations
Persamaan kimia
(ii) Conditions for the changes
Keadaan bagi perubahan
(iii Observation
) Pemerhatian
(iv)Reactants or reagents that are required
Bahan tindak balas atau reagen yang diperlukan
(v) Name of the process
Namakan proses itu
[15 marks/15 markah]
Section C
Bahagian C
[20 marks]
[20 markah]
Answer any one questions from this section.
Jawab mana-mana satu soalan daripada bahagian ini.
9.

(a) What are isomers?

Apakah isomer?
[ 2 marks/markah]
(b) Give two properties of isomers.
Berikan dua sifat isomer.
[ 2 marks/markah]
(c) Pentene, C5H10, has five isomers. Draw the structural formula for all the isomers and give their IUPAC
name.
Pentena,C5H10, mempunyai lima isomer.Lukiskan formula struktur bgi kesemua isomer dan berikan nama
11

IUPAC.
[ 10 marks/markah]
(d) When steam is mixed with pent-1-ene. A mixture of the products is obtained. Explain why?
Apabila stim dicampurkan dengan pent-1-ena, satu campuran hasil diperoleh. Terangkan kenapa?
[ 6 marks/markah]
10. (a) The flow chart below shows two chemical reactions of propan-1-ol.
Carta alir di bawah menunjukkan dua tindak balas kimia pada propan-1-ol.

DIAGRAM/RAJAH
Based on the flow chart, answers the following questions.
Berdasarkan carta alir di atas, jawab soalan-soalan berikut.
State the observations when propan-1-ol is converted to compound A by reaction I. Your explanation must
have the following:
Nyatakan pemerhatian apabila propan-1-ol diubah kepada sebatian A di dalam proses Proses I.
Penerangan kamu mesti mengandungi perkara-perkara berikut:
i. - Name of compound A
Nama sebatian A
- Observation
Pemerhatian
- Chemical equation
Persamaan kimia
[4 marks/4 markah]
ii. Name reaction II. Draw the apparatus set up to show the reaction.
Name and draw the structural formula of compound B.
Namakan Proses II. Lukis susunan radas bagi proses ini.
Nama dan lukis formula struktur bagi sebatian B.
[5 marks/5 markah]
iii. When propan-1-ol reacts with compound A, another organic compound, C, is formed.
Apabila propan-1-ol bertindakbalas dengan sebatian A, satu bahan organik, C terbentuk.
Describe how this reaction can take place.
Huraikan bagaimana tindak balas ini dapat dijalankan.
State two physical properties of compound C.
Berikan dua sifat fizik bagi organik C.
[5 marks/5 markah]
(b) You are given two bottles containing n-hexane and n-hexene respectively. State two simple chemical tests
which can be carried out to show that these two compounds are from diff erent homologous series.
Kamu diberi dua botol mengandungi n-heksana dan n-heksena masing-masing. Berikan dua ujian kimia
ringkas yang boleh dijalankan untuk menunjukkan bagaimana sebatian ini berasal daripada siri homolog
12

berlainan.
[6 marks/6 markah]

13