Tugas Dasar-dasar Kimia Analisa Pertemuan 5 Kelompok 7 : Amaliah Agustina Berly Dwikaryani Sri Dwiwati

No. Pertanyaan 1. Tuliskanlah reaksi reaksi kation No 1 sd 6!

Jawaban
1. Perak (Ag+) a. AgNO3(aq) + HCl(aq) AgCl(s) + HNO3(aq) AgCl(s) + NH4OH(aq) Ag(OH)(aq) + NH4Cl(aq) b. AgNO3(aq) + HCOOH(aq) HCOOAg(s) + HNO3(aq) c. AgNO3(aq) + KI(aq) AgI(s) + KNO3(aq) d. 2AgNO3(aq) + K2CrO4(aq) Ag2CrO4(s) + 2KNO3(aq) 2. Raksa I (Hg+) a. Hg(NO3)2(aq) + 2HCl(aq) Hg2Cl2(s) + 2HNO3(aq) b. 2HgNO3(aq) + Cu(s) Cu(NO3)2(aq) + 2Hg(s) 2HgNO3(aq) + Zn(s) Zn(NO3)2(aq) + 2Hg(s) 3. Raksa II (Hg+) a. HgCl2(aq) + Na2S(aq) HgS(s) + 2NaCl(aq) b. HgCl2(aq) + 2NaOH(aq) HgO(s) + H2O(l) + 2NaCl(aq) c. HgCl2(aq) + Zn(s) ZnCl2(aq) + Hg(s) HgCl2(aq) + Cu(s) CuCl2(aq) + Hg(s) 4. Timbal Nitrat (Pb2+) a. Pb(NO3)2(aq) + 2HCl(aq) PbCl2(s) + 2HNO3(aq) b. Pb(NO3)2(aq) + K2CrO4(aq) PbCrO4(s) + 2KNO3(aq) c. Pb(NO3)2(aq) + H2SO4(aq) PbSO4(s) + 2HNO3(aq)

d. Pb(NO3)2(aq) + 2KI(aq) PbI2(s) + 2KNO3(aq) 5. Bismut (Bi3+) a. 2Bi(NO3)3(aq) + 3NaCO3(aq) Bi2(CO3)3(s) + 6NaNO3(aq) b. Bi(NO3)3(aq) + 3NaOH(aq) Bi(OH)3(s) + 3NaNO3(aq) c. 2Bi(NO3)3(aq) + 3Zn(s) 3Zn(NO3)2(s) + 2Bi(s) 2Bi(NO3)3(aq) + 3Cu(aq) 3Cu(NO3)2(aq) + 2Bi(s) d. 2Bi(NO3)3(aq) + 3K2Cr2O7 Bi2(Cr2O7)3(s) + 6KNO3(aq) 6. Tembaga II (Cu2+) a. CuSO4(aq) + 2NaOH(aq) Cu(OH)2(s) + Na2SO4(aq) CuSO4(aq) + H2C4H4O6(aq) 2NaOH(aq) + H2SO4(aq) + 2H2O(aq) + Cu(Na)2 b. CuSO4(aq) + 2NH4(aq) Cu(OH)2(s) + (NH4)2SO4(aq) c. CuSO4(aq) + 2KI(aq) CuI2(s) + K2SO4(aq)

2.

Tuliskanlah reaksi reaksi kation No 7 sd 12!

1. Cadnium nitrat (Cd2+) a. (CH3COO)2 Cd (aq) + 2NaOH (aq) 2CH3COONa (aq) + Cd(OH)2 (s) (bening TB) (bening) (bening) (TB) b. (CH3COO)2 Cd (aq) + 2NH4OH (aq) 2CH3COONH4 (aq) + Cd(OH)2 (s) (bening TB) (putih) c. (CH3COO)2 Cd (aq) + K2CO3 (aq) CdCO3 (s) + 2CH3COOK (aq) (bening TB) (putih) (putih keruh) 8. Arsen III (As3+), Arsen V (As5+) a. As2O5 (aq) + 10HNO3 (aq) 2As(NO3)5 (aq) +3H2O (l) As2O5 (aq) + 10HNO3 (aq) + 5(NH4)2MoO4 (aq) As2(MoO4)5 (aq) + 10NH4(NO +5H2O(l) b. As2O3 (aq) + 3Na2S (aq) As2S3 (s) + 3Na2O (aq) (kuning) c. CHCl3 (aq) + As2O5 (aq) + 10HCl (aq) + 10 KI (aq) 2AsI3 (aq) +10 KCl (aq) +CHCl3(aq) + 2I2 (s) + 5H2O(l)
(kunning)

9.

d. As2O5 (aq) + 6Zn (s) + 6H2SO4 (aq) 2AsH3(g) + ZnSO4 (aq) + 3H2O(l) (bening) (abu-abu) (bening TB) AsH3 (g) + 6AgNO3 (aq) + 3H2O (aq) 6Ag(s) + 6HNO3(aq) + H3AsO3 (aq) (coklat) Antimon (III), Antimon (V) a.2SbCl3 (aq) + 3Na2S (aq) Sb2S3 (s) + 6NaCl (aq) (merah jingga) b. SbCl3 (aq) + 2KI (aq) + HCl (aq) +CHCl3 (aq) SbCl3 (s) + I2 (aq) + 2KCl(aq)+ HCl (aq) +
(aq)

CHCl3

c. 2SbCl5 (aq) + 5Zn (s) 2Sb (s) + 5ZnCl2 (aq) 10. Timah II (Sn2+), Timah IV (Sn4+) a. SnCl2 (aq) + 2NaOH (aq) Sn(OH)2 (s) + 2NaCl (aq) (putih susu) (bening TB) (putih susu) (bening TB) b. SnCl2 (aq) + 2 HgCl2 (aq) SnCl4 (aq) + Hg2CL2 (s) (bening TB) (putih susu) (bening) c. SnCl4 (aq) + 2Zn(OH)2 (aq) Sn(OH)2 (s) + 2ZnCl2 (aq) 11. Aluminium (Al3+) a. AlCl3 (aq) + 3NH4OH (aq) Al(OH)3 (s) + 3NH4Cl (aq) (bening TB) (bening TB) (putih) (bening TB) b. AlCl3 (aq) + 3CH3COONa (aq) Al(CH3COO)3 (s) + 3NaCl (aq) (bening TB) (putih) 12. Krom (Cr3+) a. CrCl3 (aq) + 3NH4OH (aq) Cr(OH)3 (s) + 3NH4Cl (aq) (hijau tua) (bening TB) (hijau) (hijau keruh) b. CrCl3(aq) + 4NaOH ( aq) NaCr(OH)4 (aq) + 3 NaCl (aq) (bening TB) (larutan hijau)

3.

Tuliskanlah reaksi reaksi anion no 1

1. Klorida (Cl-) 2NaCl (aq) +H2SO4(aq) Na2SO4(s) + 2HCl(aq)

2Na+ + 2Cl- + 2H+ + SO42- Na2SO4 + 2H+ + 2Cl2HCl(aq) + H2SO4(aq) Cl2(g) + SO2(g) + 2H2O(I) NaCl(aq) + AgNO3(aq) NaNO3(aq) + AgCl(s) Na+ + Cl- + Ag+ + NO3- Na+ + NO3- + AgCl AgCl(s) + 2NH4OH(aq) [Ag(NH3)2]Cl(aq) + 2H2O(I) 10NaCl(aq) + 8H2SO4(aq) + 2KMnO4(aq) K2SO4(s)+ 2MnSO4(aq)+5NaSO4(aq)+8H2O(I)+5Cl2(g) Bromida (Br-) 2KBr(aq) + H2SO4(aq) K2SO4(aq) + 2HBr(aq) 2HBr(aq) + H2SO4(aq) Br2(g) +SO2(g) + 2H2O(l) 2KBr(aq) + 2H2SO4(aq) K2SO4(aq) + Br2(g) + SO2(g) + 2H2O(l) KBr(aq) + HNO3(aq) HBr(s) + KNO3(aq) K+ + Br- + H+ +NO3 - HBr(s) + K+ + NO3 HBr(s) + 2NH4OH(aq) [H(NH3)2]Br(aq) + 2H2O(l) KBr(aq) + Cl2(aq) 2KCl(aq) + Br2(g) K + + Br- + 2Cl- 2K + + 2Cl- +2Br-

4.

Tuliskanlah reaksi reaksi anion no 2

5.

Tuliskanlah reaksi reaksi anion no 3

Iodida (I-) 2Kl (aq)+ H2SO4(aq) K2SO4(aq) + 2HI (g) 2k+ + 2I- + 2H+ + SO4 2- 2k+ + SO42- +2HI 2HI(g) )+ H2SO4(aq) I2(g) + SO2(g) + 2H2O(l) Kl (aq)+ HNO3(aq) KNO3(aq) + HI(s) HI(s) + 2NH4OH [H(NH3)2 ] (aq) + 2H2O(l)

6.

Tuliskanlah reaksi reaksi anion no 4

Timbal Nitrat (Pb 2+) Pb(NO3)2(aq)+ 2HCl(aq)

PbCl2(s) + 2HNO3(aq)

Pb2+ + 2NO3- + 2H+ + 2ClPb(NO3)2(aq) + K2CrO4(aq) 2PbCrO4(s) + 2HNO3(aq)

Pb2+ +2Cl- + 2H+ + 2HNO3PbCrO4(aq) + 2KNO3(aq) Pb(NO3)2(aq) + K2CrO7(aq) + H2O(aq)

Pb(NO3)2(aq) + 2H2SO4(aq) Pb2+ + 2NO3- + 2H+ + SO42Pb(NO3)2(aq) + 2KI(aq) Pb2+ + 2NO3- + 2K+ + 2I-

PbSO4(s) + 2HNO3(aq) Pb2++ SO42-+ 2H+ + 2NO3PbI2(s) + 2KNO3(aq) Pb2++ 2I- + 2K+ + 2NO3-

7.

Tuliskanlah reaksi reaksi anion no 5

Bismut (BI3+) 2Bi(NO3)3(aq)+ 3Na2CO3(aq)

Bi(CO3)3(s) + 6 NaNO3(aq)

2 Bi3+ + 6 NO3- + 6 Na+ + 3 CO32-2 Bi3+ + 3 CO32 + 6 Na+ + 6 NO3Bi(NO3)3(aq) + 3 NaOH(aq) Bi(OH)3(s) + 3 NaNO3(aq)

Bi3+ + 3 NO3- + 3 Na+ + 3 OH- Bi3+ + 3 OH- + 3 Na+ + 3 NO32 Bi(NO3)3(aq) + 3 K2CrO7(aq) Bi2(Cr2O7)3(s) + 6 KNO3(aq)

Bi(NO3)3(aq) + 3 Cu(s) 2 Bi(NO3)3(aq)+ 3 K2CrO7(aq)

2 Bi(s) + 3 Cu(NO3)2(aq) Bi2(Cr2O7)3(s)+ 6 KNO3(aq)

8.

Tuliskanlah reaksi reaksi anion no 6

Tembaga II (Cu 2+) CuSO4(aq) + 2 NaOH(aq) Cu(OH)2(s) + Na2SO4

CuSO4 (aq) + H2C4H6 (aq) H2SO4 (aq)+ 2H2O (aq) + Cu(Na2(COOCHO)2) (aq)

CuSO 4(aq) + 3NH4OH(aq) (Cu(NH3)4SO 4 (aq) + 4 H2O (aq)

2 CuSO4(aq) + 5 KI(aq) 2 CuI (s) + 2K2SO4(aq) + KI 3(aq) KI 3(aq) + 2Na2S2O3(aq) 2NaI (s) + KI(aq) + Na2S4O6(aq)

9.

Tuliskanlah reaksi reaksi anion no 7

Nitrat (NO3) 2NaNO3 (aq) + 8FeSO (aq) + (4H2SO4 (aq)

Na2SO4 (aq) + 4H2 (aq)

3Fe2(SO4)3 (aq) + 2Fe(NO)SO4 (aq) 2NaNO3 (aq) + H2SO4 (aq) 2HNO3 (aq) + Na2SO4 (aq) 2HNO3 (aq) + H2O (aq) + 2NO (g) + 3On 2NaNO3 (aq) + H2SO4 (aq) 2HNO3 (aq) + Na2SO4 (aq)

2HNO3 (aq)

H2O (aq) + 2NO (g) + 3On Na2SO4 (aq) + H2S (aq) PbS (aq) + 2CH3COOH (aq)

10.

Tuliskanlah reaksi reaksi anion no 8

Sulfida (S2-) Na2S (aq) + H2SO4 (aq) H2S (aq) + Pb(CH3COO)2

11.

Tuliskanlah reaksi reaksi anion no 9

Sulfit

(SO32-) Na2S2O3 (aq)

Na2SO3 (aq) + S(s)

Na2SO3 (aq) + I2 (aq) + H2O (aq)

Na2SO4

(aq)

+ 2HI

12.

Tuliskanlah reaksi reaksi anion no 10.

Sulfat (SO4 ) Ba(NO3)2 (aq) + Na2SO4 (aq) BaSO4 (s) 2NaNO3 (aq) BaSO4 (s) + 2HCl (aq) BaCl2 (aq) + H2SO4 (aq) Ba2+ + SO2- + 2H+ + Cl- Ba2+ + Cl2- + 2H+ + SO42-

2-

13.

Tuliskanlah reaksi reaksi anion no 11.

Thiosulfat (S2O32-) Na2S2O3 (aq) + H2SO4 (aq) H2S2O3

(aq) +

Na2SO4 (aq)

Na2S2O3 (aq) + H2SO4 (aq) SO2 + S+ H2O + Na2SO4 (aq) 2Na+ + S2O32- + 2H+ + SO42- SO2 + S + H2O + 2Na+ + SO42Na2S2O3 (aq) + I2 (aq) Na2S4O6 (aq) + 2NaI (aq) 4Na+ + 2S2O32- + I2- 2Na+ + 2I- + 2Na+ + S4O62-

14.

Tuliskanlah reaksi reaksi anion no 12.

Karbonat (CO32-) Na2CO3(aq) + H2SO4(aq) CO2(g) + H2O(l) + Na2SO4(aq)

2Na+ + CO32- + 2H+ + SO42- CO2 + H2O(l) + 2Na+ + SO42-

15.

Tuliskanlah reaksi reaksi anion no 13.

Arsenit (AsO33-) Na3AsO3(aq) + I2(aq) + H2O(l) Na3AsO4(aq) + 2HI(aq)

3 Na+ + AsO33- + I2(aq) + H2O(l) 3 Na+ + AsO43- + 2 H+ + 2 IAsO33- + I2(aq) + H2O(l) AsO43- + 2 H+ + 2 I-

16.

Tuliskanlah reaksi reaksi anion no 14.

Arsenat (AsO43-) Na3AsO4(aq) + 3 HCl(aq) NaCl(aq) + H3AsO4(aq)

H3AsO4(aq) + 2 KI(aq) + 5 HCl(aq) AsCl3(aq) + KCl(aq) + 4 H2O(l) + I2(aq) Na3AsO4(aq) + 8 HCl(aq) + 2 KI(aq) 3 NaCl(aq) + AsCl3(aq) + 2 KCl(aq) + 4 H2O(l) + I2(aq) 3 Na+ + AsO43- + 8 H+ + 8Cl- + 2K+ + 2I- 3Na+ + 3 Cl- + As3+ + 3 Cl- + 2K+ + 2 Cl- + 4H2O + I2(aq)

17.

Tuliskanlah reaksi reaksi anion no 15.

Kromat (CrO42-) 2 K2CrO4(aq) + H2SO4(aq) K2Cr2O7(aq) + K2SO4(aq) + H2O(l) 4K+ + 2CrO42- + 2H+ + SO42- 2K+ + Cr2O72- + 2K+ + SO42- + H2O(l) 2CrO42- + 2H+ + SO42- Cr2O72- + H2O(l) + SO42

18.

Tuliskanlah reaksi reaksi anion no 16.

Dikromat (Cr2O72-) K2CrO7(aq) + 2NaOH(aq) Na2CrO4(aq) + K2CrO4(aq) + H2O(l) 2K+ + Cr2O72- + 2Na+ + 2OH- 2Na+ + CrO42- + 2K+ + CrO4 2- + H2O(l) 2OH- + Cr2O72- H2O(l) + 2CrO42K2Cr2O7(aq) + H2SO4(aq) K2SO4(aq) + 2 CrO3(aq) + H2O(l)

2 CrO3(aq) + 6 KI(aq) + 6 H2SO4(aq) Cr2(SO4)(aq) + 6 H2O(l) + 3 I2(aq) + 3 K2SO4(aq) K2Cr2O7(aq) + 7 H2SO4(aq) + KI(aq) 4 K2SO4(aq) + Cr2(SO4)3(aq) + H2O(l) 2 K+ + CrO72- + 14 H+ + 7 SO42- + 6 K+ + 6 I- 8 K+ + 4 SO42- + 3 I2(aq) + Cr2(SO4)3(s) + 7 H2O(l) Cr2O72- + 14 H+ + 3 SO42- + 6 I- 3 I2(aq) + Cr2(SO4)3(s) + 7 H2O

19.

Tuliskanlah reaksi reaksi anion no 17.

Permanganat (MnO4) 2KMn4 (aq) + 10KI (aq) + 8H2SO4 (aq) 5I2 (aq) + 8H2O (l) + 2MnSO4 (aq) 2K+ + 2MnO4- + 10K+ + 10I- + 16H+ + 8SO4210I- + 16H+ + 8O2- + 2MnSO4 + 12K+ + SO422MnO4 (aq) + H2SO4
(aq)

+ Na2SO4 (aq)

K2SO4 (aq) + MnO7 (aq) + H2O(aq) Na2SO4 (aq)

2KMnO4 (aq) + 2H+ + SO42+ SO42- + H2O (l)

MnO4 + 2K+

2KMnO4 (aq) + 8H2SO4 (aq) + 5Na2(COO)2 (aq) K2SO4 (aq) + 2MnSO4 (aq) + 8H2O (l) + 10CO2 (g) + 5MnSO4 (aq)