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SURFACE CHEMISTRY QUESTIONS 1.

A small amount of silica gel and that of anhydrous CaCl2 are placed in two corners of a vessel containing water vapour. What phenomena will occur? 2. What is the difference when a concentrated solution of KCl is shaken with blood charcoal in ine case and a dilute solution of KCl in the second case? . !ow is adsorption of a gas related to its critical temperature? ". !ow can the constants K and n of the #reundlich adsorption e$uation be calculated? %. &n case of chemisorptions first increases and than decreases? '. What type of solution (aCl forms in ben)ene? *. What is te difference in the nature of a dilute soap solution and a concentrated soap solution? +. What is the difference between a colloidal sol, gel and emulsion? -. Why lyiphillic colloidal sols are more stable than lyophobic colloidal sols? 1.. What types of colloidal sols are formed in the following? /i0 1ulphur vapours are passed through cool water /ii0 White of an egg mi2ed with water. /iii0 1oap solution. 11. What happens when a freshly prepared #e/3!0 is shaken with a little amount of dilute solution of #eCl . 12. Why is a colloidal sol stable? 1 . What happens when a colloidal sol of #e/3!0 is mi2ed with that of As23 ? 1". What happens to a gold sol if gelatin is added to it? 1%. 4he conductance of an emulsion increased on adding common salt. What type of emulsion is this? 1'. What happens when persistence dialysis of a colloidal solution is carried out? 1*. What is adsorption? Why adsorption takes place only at the interface? 1+. 52plain adsorption and absorption with an e2ample each. 1-. Compare characteristic of physical adsorption and chemisorption. 2.. 6ive si2 differences between physical adsorption and chemisoption. 21. 7iscuss the effect of pressure, temperature and mechanical rubbing on the adsorption of gases on solids. 22. 7escribe how adsorption of a gas on a solid depends on /i0 6as pressure /ii04emperature. 2 . 52plain the term physiosorption and chemisorption. !ow does adsorption of a gas on a solid surface vary with pressure? 2". Write the mathematical form of #reundlich adsorption isotherm. 52plain the difference symbols used in the e$uation and its limitations. 2%. What are 8adsorption isobar9? &n case of chemical adsorption, e2plain why adsorption first increases and then decreases. 2'. What do you mean by adsorption isotherm? 2*. What are lyophobic and lyophilic sols? 6ive their chief distinguishing characteristics. 2+. Write a note on multimolecular colloids.

2-. Why heat of adsorption is negative? .. What do you mean by :6?

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