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The term "air pollution" is used to describe substances that are artificially introduced into the air. Air pollution stems from gases and airborne particles which, in excess, are harmful to human health, buildings and ecosystems. Four major impacts determine the classification of pollutants under the traditional policy field Air Pollution :
the acidification of soil and water by pollutants such as sulphur oxides, nitrogen oxides and ammonia; the damage to buildings sensitive to the same acidifying substances; the formation of tropospheric ozone from so-called ozone precursors, e.g. volatile organic compounds, nitrogen oxides and carbon monoxide which indirectly affect human and animal health and vegetation; direct effects on human health and ecosystems e.g. through high atmospheric concentrations of particles, and VOCs.
Excluded from this chapter are emissions of CO 2, N 2O, CH 4 and CFCs, which are covered in the policy fields Climate Change and Ozone Layer Depletion . Emissions of highly toxic substances are given special consideration under the heading Dispersion of Toxic Substances . Although some of these pollutants are also produced by nature, the main environmental problems result from human activities. Air pollutants are often transported over considerable distances, affecting air quality, ecosystems, lakes and other surface water, groundwater, soils and buildings in adjacent and distant countries. The Fifth Environmental Action Programme (5EAP) treats Air Pollution under Section 5.2: "Acidification and air quality." Public concern is focused mainly on damage to forests and smog, though in Nordic countries emphasis is also placed on the acidification of lakes. The main EU air directives cover emissions of SO 2 (AP-3) and NO x (AP-1) from large combustion plants, the sulphur contents of fossil fuels (AP-6), and emission limits for transport vehicles (AP-5 ). Many of these specific measures have been underpinned by the UNECE Convention on LongRange Transboundary Air Pollution, which was adopted in 1979 and signed by 35 countries, including EU Member States. The 5EAP lists the following targets to reduce air pollution:
SO2 emissions : reduction by 35% from 1985 levels by 2000, NOx emissions : reduction by 30% from 1980 levels by 2000, VOC emissions : reduction by 30% from 1990 levels by 1999.
The following list of indicators selected by the Scientific Advisory Group (SAG) "Air Pollution" comprises four indicators of pressure. The two "background" or "driving force" indicators Consumption of petrol & diesel oil by road vehicles and Primary energy consumption represent the major causes of these pressures.
Interconversion of Primary Air Pollutants to Secondary Air Pollutants, Along with Their Removals through Delayed Mechanisms
Manju Agarwal, Abhinav Tandon
Abstract
In this paper, two - dimensional time dependent mathematical models are presented to study the fate of primary and secondary air pollutants in the atmosphere, under the variable wind speed and eddy diffusivity. Primary pollutants are emitted from an elevated line source whereas secondary pollutants are formed by chemical reactions of primary pollutants with other constituents of air. The conversion of primary to secondary pollutants is considered to be the first order instantaneous process. Besides this conversion, their removals through rainout/washout are also taken to be first order process, but, instead of instantaneous, it is taken to be delayed (slow) type. The dry deposition of pollutants at the ground and leakage in the atmosphere at the inversion layer are also considered. The developed models are applied to study the conversion of sulphur dioxide to by the fractional step method in which the advection parts are solved by the Lagrangian approach whereas for the diffusion parts, the Eulerian finite difference scheme is employed. The solutions are analysed by means of concentration profiles in order to determine the behaviour of primary and secondary pollutants with time, wind, transformation and removal processes. It is also revealed that, most of the time, the delay in removal by rainout/washout leads to lesser reduction of primary and secondary pollutants from the atmosphere as compared to no - delay.
Bibliography See B. Commoner, Science and Survival (1966) and The Closing Circle (1971); M. H. Brown, The Toxic Cloud (1987); C. S. Silver, One Earth, One Future (1988); J. Marte et al., Toxics A to Z (1991); M. Feshbach and A. Friendly, Jr., Ecocide in the USSR (1992). Sections in this article: Introduction Public Recognition of Pollution as a Problem Control and Abatement Bibliography
The Columbia Electronic Encyclopedia, 6th ed. Copyright 2012, Columbia University Press. All rights reserved.
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