Determination of Total Phosphorus Content Ammonium Molybdate Spectrophotometry GB 5750 !

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This method is used for testing phosphorus content of industrial circulation cooling water containing PO 43- of 0.02-50mg/l. "# Principle In acidic solution use potassium persulphate as decomposer transfer pol!phosphates and organic phosphorus into orthophosphate orthophosphate reacts with ammonium mol!"date to produce !ellow phosphorus mol!"date heteropol! acid and then use ascor"ic acid to reduce it into phosphorus mol!"denum "lue test it with spectrophotometr! at ma#imum a"sor"enc! wa$e length of %&0nm. 'eaction e(uation is the same as clause & of )determination of orthophosphate content*. $# %ea&ent +ame as the determination of orthophosphate and total inorganic content and include the following reagent, 2.&. 40g/l potassium persulphate solution -or 34g/l ammonium persulphate .. /eigh potassium persulphate of 20g with the accurac! of 0.5g dissol$e it into the water of 500ml sha0e to uniform state and then store it into a "rown "ottle -one month for $alidit! period.. '# (nstruments +ame as clause 3.& of orthophosphate determination. )# Analysis steps 4.&. 1apping of wor0ing cur$e +ame as clause 4.& of orthophosphate determination. 4.2. 2etermination of total phosphorous content Ta0e 5.00ml of test solution from the test sample for orthophosphate determination into a conical flas0 of &00ml add sulfuric acid solution of &.0ml - see clause 2.3 of total inorganic phosphorus determination. potassium persulphate solution -clause 2.&. of 5.0ml add water into the conical flas0 to graduation of 25ml set it on ad3usta"le electric sto$e for &5 minutes of "oiling till the solution almost dries off. Ta0e it out and cool with flowing water to am"ient temperature transfer (uantiti$el! it into a 50ml $olumetric flas0. 4dd ammonium mol!"date solution of 2.0ml -see clause 2.4 of orthophosphate determination. ascor"ic acid solution of 3.0ml -see clause 2.3 of orthophosphate determination. dilute with water to the graduation sha0e to uniformit! deposit at am"ient temperature for &0 minutes use a"sorption cell with thic0ness of &cm at %&0nm of spectrophotometer test a"sor"enc! using "lan0 reagent without test solution for 5ero set. 5# Calculation of analysis result The total phosphorous content 6 5 -in PO43-. of the sample in mg/l is calculated as per the following formula -&.,

m3 -&. v3 Of which 138the (uantit! of PO43- chec0ed from wor0 cur$e in ug. 93---the $olume of transferred test solution in ml.
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5.&. -:;2P. content -#<. in mg/l is calculated as per the following formula -2.,

m3 m 2 . -2. v3 v2 Of which &.0=5--- con$ersion coefficient of PO43- into :;2P . 5.2. -:;2P+. content #% in mg/l is calculated in the following formula -3., m3 m 2 . #%7&.54=>-3. v3 v2 Of which &.54=----con$ersion coefficient PO43- into :;2P+. 5.3. -4T1P. content -#=. in mg/l is calculated in the following formula -4., m3 m 2 . #=7&.050>-4. v3 v2 Of which &.050--- con$ersion coefficient of PO43- into 4T1P. 5.4. -;2T1P. content #? in mg/l is calculated in the formula -5., m3 m 2 . #? 7&.&4=>-5. v3 v2 Of which &.&4=--- con$ersion coefficient of PO43- into ;2T1P. 5.5. -;2T1P+. content #&0 in mg/l is calculated in formula -<., m3 m 2 . #&0 7&.<&&>-<. v3 v2 Of which &.<&&---con$ersion coefficient of PO43- into ;2T1P+. The calculated result should ta0e two decimal place.
#< 7&.0=5>*# Allo+able error The result difference of 2 parallel tests should conform to the re(uirement of ta"le 2. Ta"le 2 Total phosphorus content -mg/l. @&0.00 A&0.00 Ta0e arithmetic mean as test result. Attachment A The stipulation of test sample (uantit! range -for supplement. The (uantit! of transferred test solution for the determination of orthophosphate total inorganic phosphate and total phosphorous content in the a"o$e te#t is "ased on normal sample (uantit! when phosphorous chemicals are dosing into circulation water s!stem for normal running. The sample (uantities with different phosphorous contents for circulation water s!stem are listed in ta"le 4&. Ta"le 4& Phosphorous content of sample -in PO43- mg/l. 0-5.0 5.0-&0.0 &0.0-20.0 20.0-30.0 9olume of transferred test solution &2-40 <-&2 3-< 2-3 4"sorption cell thic0ness in cm & & & & 4llowa"le error -mg/l. @0.50 @&.00

If PO43- content of test solution is more than 30mg/l dilution of the solution should "e made "efore test.