SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

Gardobond 24D R
Version: 2 16.06.2008
1 / 7
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
English
Product information
Commercial Product Name Gardobond 24D R
Recommended use:
Phosphating solution for metal surfaces.
Company: Chemetall plc
Denbigh Road
Bletchley Milton Keynes MK1 1PB
Lead Organisation:
Contact person:
Telephone: 01908 649333
Telefax: 01908 373939
Product safety:
Telephone: +44(0)1908 649333
E-mail address: ukinfo@chemetall.com
Emergency telephone: 01908 649333
2. HAZARDS IDENTIFICATION
Risk advice to man and the environment
Classification:
Harmful R22 Harmful if swallowed.
Carcinogenic Category 3 R40 Limited evidence of a carcinogenic effect.
sensitizing R42/43 May cause sensitization by inhalation and skin contact.
Irritant R36/38 Irritating to eyes and skin.
Dangerous for the
environment
R50/53 Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
Zinc bis(dihydrogen phosphate) 10.00 - 25.00 %
CAS-No.: 13598-37-3 EINECS-No. : 237-067-2
Classification: Xn; R22 N; R50/53
SAFETY DATA SHEET
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Orthophosphoric acid 10.00 - 25.00 %
CAS-No.: 7664-38-2 EINECS-No.: 231-633-2
Classification: C; R34
Nickel(II)compound 2.50 - 10.00 %
CAS-No.: 13138-45-9 EINECS-No. : 236-068-5
Classification: O; R 8 Xn; R22 Carc.Cat.3; R40 R42/43 N; R50, R53
Zinc hexafluorosilicate 2.50 - 10.00 %
CAS-No.: 16871-71-9 EINECS-No. : 240-894-1
Classification: Xn; R22 N; R50, R53
WEL substance:
Manganese bis(dihydrogen phosphate) 2.50 - 10.00 %
CAS-No.: 18718-07-5 EINECS-No. : 242-520-2
4. FIRST AID MEASURES
General advice:
Take off contaminated clothing and shoes immediately.
Eye contact:
In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Skin contact:
Wash off immediately with soap and plenty of water.
Inhalation:
Move to fresh air. If symptoms persist, call a physician.
Ingestion:
Clean mouth with water and drink afterwards plenty of water. Call a physician immediately.
5. FIRE-FIGHTING MEASURES
Specific hazards during fire fighting:
Combustion may cause: nitrogen oxides (NOx)
Special protective equipment for fire-fighters:
In the event of fire, wear self-contained breathing apparatus.
Suitable extinguishing media:
Carbon dioxide (CO2), Dry powder, Water spray, Alcohol-resistant foam
Further information:
Collect contaminated fire extinguishing water separately. This must not be discharged into
drains.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions:
Use personal protective equipment.
Environmental precautions:
Do not flush into surface water or sanitary sewer system.
Methods for cleaning up:
Soak up with liquid binder (sand, kieselguhr, acid binder, universal binder). Sweep up or vacuum
SAFETY DATA SHEET
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Gardobond 24D R
Version: 2 16.06.2008
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up spillage and collect in suitable container for disposal. Ensure adequate ventilation.
7. HANDLING AND STORAGE
Handling
Safe handling advice:
Have eye wash bottle or eye rinse ready at the work place. Avoid contact with eyes. Provide
sufficient air exchange and/or exhaust in work rooms.
Advice on protection against fire and explosion:
No special protective measures against fire required.
Storage
Requirements for storage areas and containers:
Keep container tightly closed in a dry and well-ventilated place. Store at room temperature in the
original container.
Further information:
Avoid contact with metals.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Orthophosphoric acid 7664-38-2
Value Update Basis
TWA 1.00 mg/m3 02 2006 EU ELV
STEL 2.00 mg/m3 02 2006 EU ELV
TWA 1.00 mg/m3 2007 EH40 WEL
STEL 2.00 mg/m3 2007 EH40 WEL
Manganese bis(dihydrogen phosphate) 18718-07-5
Value Update Basis
TWA 0.50 mg/m3 as Mn 2007 EH40 WEL
Nickel(II)compound 13138-45-9
Value Update Basis
TWA 0.10 mg/m3 as Ni 2007 EH40 WEL
SKIN_DES as Ni
Can be absorbed through the skin.
2007 EH40 WEL
TWA 0.50 mg/m3 as Ni 2007 EH40 WEL
SKIN_DES as Ni
Can be absorbed through the skin.
2007 EH40 WEL
Personal protective equipment
Respiratory protection:
Not required; except in case of aerosol formation.
Hand protection:
Material: Neoprene
General advice: The selected protective gloves have to satisfy the specifications of EU Directive
89/689/EEC and the standard EN 374 derived from it., The exact break through time can be
obtained from the protective glove producer and this has to be observed.
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Eye protection:
Tightly fitting safety goggles
Skin and body protection:
Protective suit
Hygiene measures:
Avoid contact with the skin and the eyes. Keep away from food, drink and animal feedingstuffs.
Take off contaminated clothing and shoes immediately. Wash hands before breaks and at the
end of workday.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form: liquid
Odour: none
Melting point/range: < -5 C
Boiling point/range: ca. 100 C
Flash point: not applicable
Density: 1.4 g/cm3
Water solubility: completely miscible
pH: ca.2
10. STABILITY AND REACTIVITY
Conditions to avoid:
To avoid thermal decomposition, do not overheat.
Materials to avoid:
Contact with organic substances or other reducing agents can form mixed nitrous gases (toxic).,
Incompatible with bases.
Hazardous decomposition products:
nitrogen oxides (NOx)
Hazardous reactions:
Gives off hydrogen by reaction with metals.
Thermal decomposition:
> 320 C
11. TOXICOLOGICAL INFORMATION
Skin irritation:
Irritating to skin.
Eye irritation:
Irritating to eyes.
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Sensitisation:
May cause sensitization by inhalation and skin contact.
Further toxicological information:
Limited evidence of a carcinogenic effect.
12. ECOLOGICAL INFORMATION
Elimination information (persistence and degradability):
Chemical Oxygen Demand (COD):
0 mg/g
Further information:
Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration. Toxic to
aquatic organisms, may cause long-term adverse effects in the aquatic environment. water
endangering
13. DISPOSAL CONSIDERATIONS
Waste key for the unused product:
110106 acids not otherwise specified
Product:
Dispose of as hazardous waste in compliance with local and national regulations.
Contaminated packaging:
Dispose of as hazardous waste in compliance with local and national regulations.
14. TRANSPORT INFORMATION
Regulation : ADR
UN/ID No.: 1805
Proper shipping name: Phosphoric acid
Packaging group: III
Class: 8
ADR/RID-Labels: 8
Regulation : RID
UN/ID No.: 1805
Proper shipping name: Phosphoric acid
Packaging group: III
Class: 8
ADR/RID-Labels: 8
Regulation : IMDG
UN/ID No.: 1805
Proper shipping name: PHOSPHORIC ACID
Packaging group: III
Class: 8
EmS: F-A S-B
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Regulation : IATA_C
UN/ID No.: 1805
Proper shipping name: PHOSPHORIC ACID
Packaging group: III
Class: 8
Regulation : IATA_P
UN/ID No.: 1805
Proper shipping name: PHOSPHORIC ACID
Packaging group: III
Class: 8
15. REGULATORY INFORMATION
Hazardous components which must be listed on the label:
Nickel(II)compound
Labelling: Harmful
Dangerous for the environment
R-phrase(s): R22 Harmful if swallowed.
R36/38 Irritating to eyes and skin.
R40 Limited evidence of a carcinogenic effect.
R42/43 May cause sensitization by inhalation and skin
contact.
R50/53 Very toxic to aquatic organisms, may cause long-
term adverse effects in the aquatic environment.
S-phrase(s): S23 Do not breathe vapour.
S26 In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice.
S36/37 Wear suitable protective clothing and gloves.
S45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S60 This material and its container must be disposed of
as hazardous waste.
S61 Avoid release to the environment. Refer to special
instructions/ Safety data sheets.
Other regulations:
German regulation: Soluble nickel salts are carcinogenic substances, category 1.
Other regulations:
The product is classified and labelled in accordance with EC directives or respective national
laws.
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Gardobond 24D R
Version: 2 16.06.2008
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16. OTHER INFORMATION
Text of R phrases mentioned in Section 3
R 8 Contact with combustible material may cause fire.
R22 Harmful if swallowed.
R34 Causes burns.
R40 Limited evidence of a carcinogenic effect.
R42/43 May cause sensitization by inhalation and skin contact.
R50 Very toxic to aquatic organisms.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R53 May cause long-term adverse effects in the aquatic environment.
Text of R phrases mentioned in Section 3
The information provided is based on our current knowledge and experience and apply to the
product as delivered. Regarding the product properties, these are not guaranteed. The delivery of
this safety datasheet does not free the recipient of the product from his own responsibility to
follow the relevant rules and regulations concerning this product.