(216871532) MSDS

OIL & NATURAL GAS CORPORATION LIMITED HAZIRA PLANT, SURAT
MATERIAL SAFETY DATA SHEET (MSDS)
MATERIAL SAFETY DATA SHEET
SL NOS. AA) 1 2 3 4 5 6 7 BB) 8 9 10 CC) 11 12 13 14 15 16 17 18 19 20 21 DD) 22 23
CONTENTS PRODUCTS AVIATION TURBINE FUEL HIGH SPEED DIESEL KEROSENE LIQUIFIED PETROLEUM GAS NAPHTHA PROPANE SWEET GAS BY PRODUCTS HYDROGEN SULPHIDE SULPHUR SULPHUR DIOXIDE PROCESS CHEMICALS CHLORINE ETHYL MERCATAN HYDRO CHLORIC ACID HYDRAZINE METHANOL METHYL DIETHANOL AMINE POTASSIUM HYDROXIDE SODIUM HYDROXIDE SULPHURIC ACID TRI ETHYELNE GLYCOL UREA FIRE FIGHTING CHEMICALS AQUEOUS FILM FORMING FOAM DRY CHEMICAL POWDER
PAGE NOS.
1-2 3-4 5-6 7-8 9-10 11-12 13-14 15-16 17-18 19-20 21-22 23-24 25-26 27-28 29-30 31-32 33-34 35-36 37-38 39-40 41-42 43-44 45-46
MATERIAL SAFETY DATA SHEET (AQUEOUS FILM FORMING FOAM) 1. CHEMICAL IDENTITY Chemical Name Synonyms Trade Name Chemical Classification Formula Hazardous Ingredients Regulated Identification Shipping name Fire fighting chemicals Codes/Label Hazardous Waste Hazchem Code Hazardousclassification C.A.S. No. U.N. No. Hazardous Ingredients C.A.S.No. Physical state Vapour Pressure @35C Ph Appearance Odour Others(Molecular wt) Flammability TDG Flammability LEL UEL Flash Point C Flash Point C Combustible Liquid Flammable Material Pyrophoric Material Explosive Material N.A. Liquid Not determined -Clear Amber coloured liquid Mild sweet odour
--
N/A, this is a mixture
MIXTURE
N/A C.A.S.No. 112-34-5
2.PHYSICAL/CHEMICAL DATA Boiling Pt/Range 100C Melting/Freezing Pt. Vapour Density (Air =1) Specific Gravity (Water =1) Solubility, In water at 30C
1 1.01 Soluble (100%)
3.FIRE /EXPLOSION HAZARD DATA Auto ignition TemperatureC N.A. Explosion sensitivity to impact Explosion sensitivity to static Electricity Hazardous combustion products Hazardous Polymerization Will not occur Oxidiser Organic Peroxide Corrosive Material Others 4. REACTIVITY DATA
Incompatibility with other material Reactivity Hazardous Reaction Prods.
NO
No
Chemical stability Stable Reactive metals, any material reactive with water & give electrical connection
None
5. HEALTH HAZARD DATA Routes of Entry : Eye contact, Skin contact, Inhalation & Ingestion Inhalation : Inhalation is not anticipated to be a problem. Ingestion : Low oral risk Effects of Exposure/ when used as intended, may cause Nausea, do not induce vomiting when ingested. Symptoms
Skin & Eye contact : May cause mild transient irritation. Emergency treatment : Inhalation : Remove victim to fresh air area, Seek medical attention, if discomfort continues. Ingestion : If Patient is conscious, give large amount of water & do not induce vomiting, seek medical help. Skin : Wash with soap & water if irritation persist. Seek medical attention. Eye contact : Flush with large amount of gentle flowing water, if irritation persists, seek medical attention.
LD50 (oral Rat) Permissible exposure limit TLV (ACGIH) STEL Odour Threshold IDLH
NFPA Hazard Signals Health 0 Flammability 0 Reactivity 0 Special -
MATERIAL SAFETY DATA SHEET (AQUEOUS FILM FORMING FOAM ) 6. PREVENTIVE MEASURES : Use protective rubber hand gloves & chemical goggles for eye protection. Personnel Protective Equipment Handling &Storage Recommended storage environment is within +40 to 0C. Store product in Precautions original shipping container or tank design for product storage.
7. EMERGENCY/ FIRST AID MEASURES :
FIRE Fire Extinguishing Media Special Procedure Unusual Hazards Exposure First Aid measures/ Emergency Treatment
This is an extinguishing agent Rinse floor thoroughly with water as material is slippery. Prevent material from reaching sewers or water ways to avoid nuisance foaming. --None
Inhalation : Remove victim to fresh air area. Seek medical attention if discomfort continues. Ingestion : If Patient is conscious, give large amount of water & do not induce vomiting. Seek medical help. Eyes : Flush with large amount of gentle flowing water, if irritation persist, seek medical attention. Skin : Wash with soap & water. If irritation persists, seek medical attention.
Antidotes/Dosages : SPILLS Steps to be Taken Waste Disposal Method
-Shut off leaks if without risk The product can be successfully treated in biological waste water system with proper dilution. Local legal regulations to be complied to for discharge into common Drainage / Sewage system.
8. ADDITIONAL INFORMATION/REFERENCES
The above information is provided in good faith & is said to be accurate to the best of our knowledge and belief as of the effective data. However, the company is not responsible as it is the responsibility of the buyer to ensure that is complies with the above regulation. Place risk as required by other health & safety legislation.
9. MANUFACTURERS/SUPPLIERS DATA M/s. K.V. FIRE Chemicals (I) Pvt. Ltd., Kamala Nivas, 2nd floor, Plot 32, Lane-D, Sector -8 Vashi, Navi Mumbai 400 703. 022- 27826733 Contact Person in case of Emergency Name of Firm 10. DISCLAIMER
Information contained in this MSDS is believed to be reliable but no representation, guarantee of warranties of any kind are made as to its accuracy, suitability for a particular application of results to be obtained for them. It is up to the user to ensure that the information containing in the material safety data sheet is relevant to the product manufactured/handled or used by him as the case may be. Helps makes no warranties expressed or implied in respect of the adequacy of this document for any particular purpose.
11. Abbrevations
C.A.S. No. U.N. No. LD50 (Oral-Rat) STEL TDG Flammability ACGIH TLV LEL UEL TWA PPM IDLH Mg/m3 Chemical Abstracts Service United Nations Number Identification of Materials during transportation Lethal Dose=50,(LD-50, Specify Laboratory Animal species & Routs for Tests) Short-Term Exposure Limit-Max. Concentration Transport of Dangerous Goods Flammability, Classification by United Nations American Conference of Governmental Industrial Hygienists Threshold Limit value Lower Explosive Limit Lowest Concentration Upper Explosive Limit- Highest Concentration Time Weighted Average Exposure Limit Parts per Million Immediately Dangerous to Life or Health, Indicates Maximum concentration Milligrams(mg) of a material per cubic metre (m3) of air.
1. CHEMICAL IDENTITY Chemical Name Synonyms Trade Name Chemical Classification Formula Hazardous Ingredients
MATERIAL SAFETY DATA SHEET (AVIATION TURBINE FUEL) Regulated Identification Aviation Turbine Fuel Shipping name Jet A-1 Codes/Label Combustible Liquid ATF Hazardous Waste CO, CO2 as combustion product Combustible Hydrocarbon Hazchem Code
Liquid
Hydrocarbon Mixture C.A.S.No.
Hazardousclassification C.A.S. No. 8008-20-6 U.N. No. Hazardous Ingredients C.A.S.No. Physical state Vapour Pressure @35C pH Appearance Odour Others(Molecular wt) Flammability TDG Flammability LEL UEL Flash Point C Flash Point C Combustible Liquid Flammable Material Pyrophoric Material Explosive Material Liquid 1 PSi -Clear & Bright Kerosene Like
--
2.PHYSICAL/CHEMICAL DATA Boiling Pt/Range 150 to 260C Melting/Freezing Pt. Vapour Density (Air =1) Specific Gravity (Water =1) Solubility, In water at 30C -50C 0.7940 Insoluble
3.FIRE /EXPLOSION HAZARD DATA Auto ignition TemperatureC 210C (410F) Explosion sensitivity to impact Explosion sensitivity to static Electricity Hazardous combustion products Hazardous Polymerization Will not occur Oxidiser Organic Peroxide Corrosive Material Others 4. REACTIVITY DATA
YES
0.7% 5% 45C(min)
YES YES YES YES
Chemical stability - Stable under normal conditions of storage & Handling Strong oxidizing Agents Nil Oxides of Carbon (on burning)
5. HEALTH HAZARD DATA 1) Routes of Entry : Combustible liquid & Vapour Harmful or fatal if swallowed. May cause lung damage if swallowed. May cause Effects of Exposure/ respiratory tract. Inhalation : If inhaled, causes Skin irritation. Toxic to aquatic Symptoms
organisums. Eye : Not expected to cause prolonged or significant eye irritation. Skin : Contact with the skin causes irritation. Symptoms may include Pain, itching, discolouration, swelling & blistering, contact with the skin is not expected to cause an allergic Skin response : Not expected to be harmful to internal organs if absorbed through the skin. Ingestion : Because of its low viscosity, this material can directly enter into lungs, if swallowed or if subsequently vomited.
MATERIAL SAFETY DATA SHEET (AVIATION TURBINE FUEL ) 6. PREVENTIVE MEASURES : Liquid vapourises & forms vapor (fumes) which can catch fire & burn with explosive Personnel Protective force. Vapour spreads easily and can be set on fire by source such as pilot light, Equipment
welding equipment & electric motors & switches. Fire hazard is greater as liquid temp rises above 35C
Handling &Storage Precautions
Do not get in eyes or skin or on clothing. Do not breath the vapor or fumes. Do not breadth mist. Do not taste or swallow. Wash thoroughly after handling . Water Do not use as portable heater or appliance fuel. Toxic fumes may accumulate & cause death. Avoid contaminating soil or releasing this material into sewage & drainage systems and bodies of water. Do not use or store near heat, sparks & open flames. Use and store only in well ventilated area. Keep container closed when not in use.
7. EMERGENCY/ FIRST AID MEASURES : Inhalation
FIRE Fire Extinguishing Media Special Procedure Unusual Hazards Exposure First Aid measures/ Emergency Treatment
Use water fog, dry chemical or CO2 to extinguish flames. Fire extinguishing media : Dry chemical, alcohol foam or carbon dioxide, water spray may be used to keep fire exposed materials cool. Water or foam may cause frothing. Special Information : In the event of a fire, wear full protective clothing & self contained breathing apparatus. Eye : ;No specific first aid measures are required. As a precautions, remove contact lenses, if worn, & flush eyes with water, Skin : Wash skin into water immediately & remove contaminated clothing & Shoes Get medical attention if any symptoms develop. To remove the material from Skin , use soap & water. Ingestion : Get immediate medical attention. Do not induce vomiting. Never give anything by mouth to an unconscious person.
Eyes
Antidotes/Dosages : SPILLS Steps to be Taken Waste Disposal Method 8. ADDITIONAL INFORMATION/REFERENCES
--
Precautionary measures : Do not get in eyes, or skin, or an clothing. Do not breathe vapour or fumes. Do not breathe mist. Do not taste or swallow. Wash thoroughly after handling.
9. MANUFACTURERS/SUPPLIERS DATA ONGC, Hazira Plant, Surat, Tel. Nos.(0261-2875500, Fax (091) (0261 2875577) Contact Person in case of Emergency Name of Firm : ONGC, Hazira Plant, Surat, Gujarat-394 518. Contact person : Shri K Raman, GM- Head Operation, ONGC, Surat 10. DISCLAIMER
11. Abbrevations
C.A.S. No. U.N. No. LD50 (Oral-Rat) STEL TDG Flammability ACGIH TLV LEL UEL TWA PPM IDLH Mg/m3 Chemical Abstracts Service United Nations Number Identification of Materials during transportation Lethal Dose=50,(LD-50, Specify Laboratory Animal species & Routs for Tests) Short-Term Exposure Limit-Max. Concentration Transport of Dangerous Goods Flammability, Classification by United Nations American Conference of Governmental Industrial Hygienists Threshold Limit value Lower Explosive Limit Lowest Concentration Upper Explosive Limit- Highest Concentration Time Weighted Average Exposure Limit Parts per Million Immediately Dangerous to Life or Health, Indicates Maximum concentration Milligrams(mg) of a material per cubic metre (m3) of air.
MATERIAL SAFETY DATA SHEET (CHLORINE) Regulated Identification CHLORINE Shipping name CHLORINE None Codes/Label Non Flammable Gas, Poison, Class-2 Hazardous Waste ID. NO 17 Inorganic Gas or Liquid Hazchem Code 2xE Cl2 Hazardous Classification C.A.S.No. C.A.S. No. 7782-50-5 7782-50-5 U.N. No. 1017 Hazardous Ingredients C.A.S.No. 3 4 Physical state Vapour Pressure pH Appearance Odour Others Flammability TDG Flammability LEL UEL Flash Point C LIQUIFIED Compr. Ga 4800 mm Hg at 20C Not Pertinent Greenish Yellow Irriting, Bleach like Choking Odour
Soluble in Alkalies
1. CHEMICAL IDENTITY Chemical Name Synonyms
Chemical Classification Formula Hazardous Ingredients 1. Chorine 2.
2.PHYSICAL/CHEMICAL DATA Boiling Pt/Range -34C Melting/Freezing Pt. -101.0C Vapour Density (Air =1) 2.49 Specific Gravity (Water =1) 1.47 at 0C Solubility, In water at 30C Slighly Soluble
3.FIRE /EXPLOSION HAZARD DATA Auto ignition TemperatureC Not Pertinent Explosion sensitivity to Stable impact Explosion sensitivity to static Stable Electricity Hazardous combustion Toxic products are products generated when combustible burn in Cl Hazardous Polymerization Will not occur Oxidiser Yes Organic Peroxide NO Corrosive Material Yes Others Yes 4. REACTIVITY DATA Incompatibility with other material Reactivity Hazardous Reaction Products
No 2 Not Pertinent % Not Pertinent % Not Pertinent %
Flash Point C Combustible Liquid Flammable Material Pyrophoric Material Explosive Material Chemical stability
Not Pertinent (CC) NO NO NO NO Stable
Combustible substance, finely divided metals Violent reaction with Alcohols, explosive reaction with metals, potentially dangerous reaction with Hydrocarbons, Lewis Acids, Sulfides, Trialkyl Boranes.
Toxic products are generated when combustible burn in Cl
5. HEALTH HAZARD DATA Routes of entry : Inhalation, Ingestion Skin & Eyes Skin & Eyes : Irritation, sneezing, copious salivation, general exsitement, rentlessness. Effects of Inhalation : High concentration causes respiratory distress & violent coughing, often Exposure/Symptoms
with retching. Death may result from suffocation.
LD50 (oral Rat) Permissible exposure limit TLV (ACGIH) STEL Odour Threshold
Not Listed mg/kg 1 ppm 3 mg/m3 1 ppm 3 mg/m3 3 ppm 9 mg/m3 3.5 ppm 10.16 mg/m3
NFPA Hazard Signals Health Flammability Reactivity Special 3 0 0 -
MF=16 HC = -BTU/lbx103 Molecular Weight 70.91 1 ppm = 2.90 mg/m3
MATERIAL SAFETY DATA SHEET IDLH 10 ppm
MATERIAL SAFETY DATA SHEET (CHLORINE) 6. PREVENTIVE MEASURES Personnel Protective Avoid contact with liquid or vapours. Provide PVC gloves, gumboots, rubber overcoat, head mask, self-contained breathing apparatus. Equipment Handling &Storage Store in dry, cool, relatively isolated, well ventilated place. Store in cylinders, pressure vessels or pipeline Precautions 7. EMERGENCY/ FIRST AID MEASURES FIRE Fire Extenguishing Media Not flammable Special Procedure Keep the containers cool spraying water if exposed to heat or flame. Unusual Hazards Poisonous gas may be produced in fire Exposure First Aid Measures/Emergency Treatment
Inhalation : Remove the victim to fresh air area, apply artifical respiration or oxygen if needed Ingestion : Get Medical care urgently Skin : Wash eye or skin with plenty of water under quick opening safety shower and eye wash fountain Eyes : Flush with plenty of water for 15 min.
Antidotes/Dosages SPILLS Steps to be Taken Waste Disposal Method
Not available
Shut off leaks without risk. Contain the leaking liquid on earth/sand. Prevent the liquid from entering the sewer. Vapour create toxic atmosphere. Knock down vapour with water spray Neutralise small liquid spillages with soda ash & drain with abundant water. Cover pool with protein foam, so that the release of vapour to atmosphere is low and undercontol.
In case of large gas escapes, the presence of cloud can be marked with ammonia with which it will turn into a mist. Run away from the gas clouds in a direction perpendicular to the wind direction. Avoid liquid chlorine from leaking and body contact. Persons with pulmonary diseases should avoid the exposure. A concentration of 3.5 ppm produces a detectable odour. 15 ppm causes immediate irritation of the throat conc. Of 50 ppm are dangerous for even short exposures. 1000ppm is fatal. Can react to cause fire/explosion on contact with Turpentine, illuminating gas Polypropylene, Rubber, Sulfamic Acid, Acetaldehyde, Alcohols, Bring the leaking portion of the cylinder to the upper most position so that only the gas escapes and not the liquid.
9. MANUFACTURERS/SUPPLIERS DATA Contact Person in case of Emergency Name of Firm 10. DISCLAIMER
11. Abbrevations
C.A.S. No. U.N. No. LD50 (Oral-Rat) STEL TDG Flammability ACGIH TLV LEL UEL TWA PPM IDLH Chemical Abstracts Service United Nations Number Identification of Materials during transportation Lethal Dose=50,(LD-50, Specify Laboratory Animal species & Routs for Tests) Short-Term Exposure Limit-Max. Concentration Transport of Dangerous Goods Flammability, Classification by United Nations American Conference of Governmental Industrial Hygienists Threshold Limit value Lower Explosive Limit Lowest Concentration Upper Explosive Limit- Highest Concentration Time W eighted Average Exposure Limit Parts per Million Immediately Dangerous to Life or Health, Indicates Maximum concentration. Mg/m3 Milligrams(mg) of a material per cubic metre (m3) of air
MATERIAL SAFETY DATA SHEET (DRY CHEMICAL POWDER) Regulated Identification Mono Ammonium Shipping name Fire fighting Phosphate Chemical Codes/Label DCP (MAP) Hazardous Waste Mixture Hazchem Code N/A Hazardousclassification C.A.S.No. C.A.S. No. 1310-73-2 U.N. No. Hazardous Ingredients C.A.S.No. Physical state Vapour Pressure @35C pH Appearance Odour Others Powder N/A Powder Fine blue Powder Odourless --
1. CHEMICAL IDENTITY Chemical Name Synonyms Trade Name Chemical Classification Formula Hazardous Ingredients 1. Dry Chemical powder
2.PHYSICAL/CHEMICAL DATA Boiling Pt/Range N/A Melting/Freezing Pt. Vapour Density (Air =1) Specific Gravity (Water =1) Solubility, In water at 30C N/A N/A -Soluble
3.FIRE /EXPLOSION HAZARD DATA Auto ignition TemperatureC N/A Explosion sensitivity to impact Explosion sensitivity to static Electricity Hazardous combustion Ammonia, products Phosphorus oxides Hazardous Polymerization May occur Oxidiser Organic Peroxide Corrosive Material Others 4. REACTIVITY DATA Incompatibility with other material Reactivity Hazardous Reaction Prods.
Flammability TDG Flammability LEL UEL Flash Point C Flash Point C Combustible Liquid Flammable Material Pyrophoric Material Explosive Material Chemical stability None
No
NA
NO NO
5. HEALTH HAZARD DATA 2) Routes of Entry :Eye contact, Skin contact, Inhalation Health Hazard (Acute & Chronic) Breathing dust may irritate the nose & Throat & cause Effects of Exposure/ coughing and chest discomfort. Dusts may irritate the eyes. Prolonged contact can Symptoms
produce slight skin irritation. Medical condition generally aggravated by explosure : Respiratory disease including Asthma & Emphysema.
NFPA Hazard Signals Health Flammability Reactivity Special -
MATERIAL SAFETY DATA SHEET (DRY CHEMICAL POWDER) 6. PREVENTIVE MEASURES Personnel Protective Equipment Handling &Storage Precautions 7. EMERGENCY/ FIRST AID MEASURES FIRE Fire Extinguishing Media This is an extinguishing agent Special Procedure Unusual Hazards None Exposure First Aid Measures/Emergency Treatment Eye contact Flush thoroughly with water for atleast 15 mins. Get medical assistance. Inhalation : Remove from further exposure if unconsciousness occurs. Seek immediate medical assistance and call a physician if breathing has stopped. Use mouth to mouth resuscitation. Skin : Wash contact areas with soap & water. Ingestion : Not expected to be a problem, how ever, if more than half litre ingested, immediately give 1 to 2 glasses of water & call a physician. Do not induce vomiting or give anything by mouth to an unconscious person Antidotes/Dosages : -SPILLS Wear protective equipment including rubber boots, rubber gloves, rubber Steps to be Taken
apron and a full face piece or a hand mask air purifying cartridge respirator with particular filters wear chemical goggles if a half mask is worn. For small spills ,sweep up & dispose off in Dot approved waste container. Dispose off contaminated product & materials used in cleaning up spills or leaks in a manner approved for this material. Consult appropriate state and local regulatory agencies to ascertain proper disposal procedures.
Waste Disposal Method
8. ADDITIONAL INFORMATION/REFERENCES 9. MANUFACTURERS/SUPPLIERS DATA Contact Person in case of Emergency Name of Firm 10. DISCLAIMER
11. Abbrevations
C.A.S. No. U.N. No. LD50 (Oral-Rat) STEL TDG Flammability ACGIH TLV LEL UEL TWA PPM IDLH Mg/m3 Chemical Abstracts Service United Nations Number Identification of Materials during transportation Lethal Dose=50,(LD-50, Specify Laboratory Animal species & Routs for Tests) Short-Term Exposure Limit-Max. Concentration Transport of Dangerous Goods Flammability, Classification by United Nations American Conference of Governmental Industrial Hygienists Threshold Limit value Lower Explosive Limit Lowest Concentration Upper Explosive Limit- Highest Concentration Time W eighted Average Exposure Limit Parts per Million Immediately Dangerous to Life or Health, Indicates Maximum concentration Milligrams(mg) of a material per cubic metre (m3) of air.
MATERIAL SAFETY DATA SHEET (EHTYL MERCAPTAN) Regulated Identification EHTYL MERCAPTAN Shipping name EHTYL MERCAPTAN ETHANETHIOL, Codes/Label Flammable liquid, MERCAPTOETHANE Class-3 Thioethy Alcohol Hazardous Waste ID NO. 17 Ethyl Sulphydrate Mercaptan Hazchem Code 2XE C2H6S Hazardousclassification C.A.S.No. C.A.S. No. 75-08-01 75-08-1 U.N. No. 1228 Hazardous Ingredients C.A.S.No. Physical state Vapour Pressure @35C pH Appearance Odour Others Liquid Not Available Not Available Colourless to Yellow Strong Penetrating like Garlic odour
Soluble in Alkalies
1. CHEMICAL IDENTITY Chemical Name Synonyms Trade Name Chemical Classification Formula Hazardous Ingredients Ethyl Mrcaptan
2.PHYSICAL/CHEMICAL DATA Boiling Pt/Range -34.4C Melting/Freezing Pt. Vapour Density (Air =1) Specific Gravity (Water =1) Solubility, In water at 30C -147C 2.49 0.826. e 20C solid Soluble
3.FIRE /EXPLOSION HAZARD DATA Auto ignition TemperatureC 298.9C Explosion sensitivity to Stable impact Explosion sensitivity to static Explodes Electricity Hazardous combustion Emits toxic fumes of products SOX Hazardous Polymerization Will not occur Oxidiser NO Organic Peroxide NO Corrosive Material NO Others --4. REACTIVITY DATA Incompatibility with other material Reactivity Hazardous Reaction Prods.
Flammability TDG Flammability LEL UEL Flash Point C Flash Point C Combustible Liquid Flammable Material Pyrophoric Material Explosive Material Chemical stability
YES 3 2.8% 18.2% < - 17.7 (OC) Not available (CC) YES YES NO NO Stable
Acids, water, steam & oxidizers Voilent reaction with Ca(ocL)2. Reacts vigorously with oxidizers. Contact with Acid fumes emit highly toxic fumes of SOX Not available
5. HEALTH HAZARD DATA Routes of entry : Inhalation, Ingestion, Skin & Eyes Inhalation : Causes muscular weakness convulsions, respiratory paralysis. High Effects of Concentration may cause pulmonary irritation. Ingestion : Causes nausea & irritation Exposure/Symptoms
of mouth and stomach. Eye & Skin : Causes irritation. Emergency Treatment : Inhalation : Remove the victim to Fresh air area, Provide Respiration or oxygen if indicated. Ingestion : Induce vomiting & follow with gastric lavage. Seek medical aid immediately.
NFPA Hazard Signals Health 2 0.5 ppm, 1.0 mg/m3 Flammability 4 Reactivity 0 0.001ppm,0.0026 mg/mg3 Special -
1960 mg/kg
MATERIAL SAFETY DATA SHEET (EHTYL MERCAPTAN) 6. PREVENTIVE MEASURES Protective Equipment Avoid contact with liquid or vapour Provide Rubber hand gloves, Protective over clothing side covered safety goggles/ Face shield. Handling &Storage Keep in dry, cool, well ventilated area away from heat,flame or Precautions oxidizers. Keep the containers tightly closed. 7. EMERGENCY/ FIRST AID MEASURES FIRE Fire Extinguishing Media Dry chemical powder, Foam, CO2 Special Procedure Keep the containers cool by spraying water if exposed to Heat or flame Unusual Hazards Poisonous gases are produced in fire Exposure First Aid Measures/Emergency Treatment
Inhalation : Remove the victim to fresh air area, provide artificial respiration or oxygen if needed. Ingestion : Induce vomiting & follow with gastric lavage. Eyes : Flush with water for 15 mins. Skin : wash the affected area with plenty of water & soap. Seek medical aid immediately.
Not available Shut off leaks if without risks. Contain the spillage on earth or sand. Dissolve in a combustible solvent as Alcohol. Benzene etc. Burns in furnace with an after burner & scrubber to neutralise Sulphur Dioxide.
LC 50 = 4420 ppm/4H (inh-rat). A very dangerous fire hazard when exposed to heat or flame. A moderate explosion hazard, when exposed to spark of flame will reacat with water steam to produce toxic & flammable vapours.
11. Abbrevations
1. CHEMICAL IDENTITY Chemical Name Synonyms Trade Name Chemical Classification Formula Hazardous Ingredients 1. Hydrogen Sulphide
MATERIAL SAFETY DATA SHEET (HYDROGEN SULPHIDE) Regulated Identification HYDROGEN Shipping name Hydrant Sulphide SULPHIDE Liquified SPLUTTERED Codes/Label Flammable gas, HYDROGEN Class-2 -Hazardous Waste ID. NO. 6 Inorganic Gas Hazchem Code 2 WE H2S Hazardousclassification C.A.S.No. C.A.S. No. 7783-06-4 7783-06-4 U.N. No. 1053 Hazardous Ingredients C.A.S.No. Physical state Vapour Pressure @35C 82.8C pH 1.189 Appearance 0.916 at - 60C Liquid Odour Soluble Others -Gas 15200 @ mm Hg at 25.5C Not Pertient Colourless Odour of rotten eggs Soluble in Gyecrol, Crude Oil YES 2 4% 46% --YES YES NO NO
2.PHYSICAL/CHEMICAL DATA Boiling Pt/Range Melting/Freezing Pt. Vapour Density (Air =1) Specific Gravity (Water =1) Solubility, In water at 30C
3.FIRE /EXPLOSION HAZARD DATA Auto ignition TemperatureC 260C Explosion sensitivity to Stable impact Explosion sensitivity to static Not available Electricity Emits toxic fumes of Hazardous combustion SOX products Hazardous Polymerization Does not occur Oxidiser NO Organic Peroxide NO Corrosive Material NO Others -4. REACTIVITY DATA Incompatibility with other material Reactivity Hazardous Reaction Prods.
Flammability TDG Flammability LEL UEL Flash Point C Flash Point C Combustible Liquid Flammable Material Pyrophoric Material Explosive Material
Chemical stability - Stable

oxidizers Metals Vigorous reaction with metal powders, incandescent reaction with chromium Tri-oxide. Reacts violently with NI3NF3 P-Bromo-Benzene-Diazonium chloride Acetaldehyde etc. Mixture of Hydrogen Sulphide & Air may explode violently. Reacts with 4-bromobenzene diazonium chloride to form an explosive product.
5. HEALTH HAZARD DATA Routes of Entry :Inhalation, Skin and Eyes Inhalation : if high concentrations are inhaled, hyperpnoea & respiratory symptoms Effects of Exposure/ Paralysis may occur very High concentration may produce pulmonary edema. Skin & Symptoms
Eyes : Causes severe irritation .Emergency Treatment : Inhalation : Remove the victim to fresh air area. Provide respiration or oxygen if needed. Eyes : Irrigate with plenty of water for 15 mins. Skin : Remove the contaminated clothing and wash the affected area with plenty of water & soap. Seek medical aid immediately.
Not available 10ppm Not 14 mg/m3 0.5 ppm 14 mg/m3

2,15 ppm, 21 mg/m3
0.0047 ppm
MATERIAL SAFETY DATA SHEET (HYDROGEN SULPHIDE) 6. PREVENTIVE MEASURES Personnel Protective Equipment Avoid contact with gas. Provide rubber framed side covered, goggles respirator, rubber hand gloves, over-clothing & shoes Handling &Storage Precautions Keep in a cool, dry, well ventilated area. Away from oxidizing Agents
7. EMERGENCY/ FIRST AID MEASURES FIRE Fire Extinguishing Media Alcohol Foam, CO2, DCP Special Procedure Keep the container cool by spraying water if exposed to heat or flame. Unusual Hazards Flash back along vapour trail may occur. Exposure First Aid Measures/Emergency Treatment Inhalation : Remove victim to fresh area, Provide artificial respiration or oxygen, if needed. Eyes : Irrigate with plenty of water for 15 mins. Skin : Remove the contaminated clothing and wash the affected area with plenty of water & Soap. Seek medical aid immediately. Antidotes/Dosages : Not available. SPILLS Steps to be Taken Shut off leaks if without risk Waste Disposal Method If in the liquid form, allow to vapourise. In case of gas leakage, pass through Recl3 solution with a trap in line for prevention of back siphoning,. Place cylinder in or near hood and leave bleed off. 8. ADDITIONAL INFORMATION/REFERENCES
LC50- 444 ppm/4H (inh-rat) Extremely hazardous, poisonous & flammable gas. An asphyxiate. Low concentratory 20-150 ppm causes irritation of eyes. Slightly higher concentration may cause irritation of upper respiratory tract. Exposures of 8001000 ppm may be fatal in 30 mins. Higher concentrations are instantly fatal. H2S poisoning occur even more rapidly than that of HCN. Potentially explosive reaction into copper + Oxygen. Explosive reaction when heated with Perchlory Fluoride (above 100C ). Explodes when in contact oF2, Hcl3, Br2, F5, CLF3, CL2o & silver fulminate.
11. Abbrevations
1. CHEMICAL IDENTITY
Chemical Name Synonyms Trade Name Chemical Classification Formula Hazardous Ingredients 1. Hydrochloric Acid
MATERIAL SAFETY DATA SHEET (HYDROCHLORIC ACID) Regulated Identification

Hydrochloric Acid Muratic Acid Muratic Acid Inorganic Acid HcL C.A.S.No. 764-01-0 Shipping name Codes/Label Hazardous W aste Hazchem Code Hazardousclassification C.A.S. No. U.N. No. Hazardous Ingredients Physical state Vapour Pressure @35C pH Appearance Odour Others
2R 764-01-0 1789 C.A.S.No. Fuming liquid/gas 4 atm at 17.8C Acidic Colourless Strong Pungent --
2.PHYSICAL/CHEMICAL DATA
Boiling Pt/Range Melting/Freezing Pt. Vapour Density (Air =1) Specific Gravity (Water =1) Solubility, In water at 30C -84.8C -114.3C 1.27 -Soluble
3.FIRE /EXPLOSION HAZARD DATA

Auto ignition TemperatureC Explosion sensitivity to impact Explosion sensitivity to static Electricity Hazardous combustion products Hazardous Polymerization Oxidiser Organic Peroxide Corrosive Material Others Not applicable Not applicable Not applicable Not applicable Will not Polymerise NO NO YES --
Flammability
TDG Flammability LEL UEL Flash Point C Flash Point C Combustible Liquid Flammable Material Pyrophoric Material Explosive Material
NO
3 Not applicable 18.2% Not applicable (OC) Not applicable (OC) NO NO NO NO
4. REACTIVITY DATA Incompatibility with other material Reactivity Hazardous Reaction Prods.

Acids, W ater, Steam & oxidizers. Reacts explosively with Potassium permangate, Sodium, Tetraselenium Tetraitride is also explosive Reacts rapidly with bases Nil
5. HEALTH HAZARD DATA 3) Routes of Entry :Inhalation, Skin and Eyes Inhalation : The major effects of actute exposure to HCL are usually to upper Effects of Exposure/ respiratory tract Exposure to the gas causes cough, burning of the throat & laryx. Symptoms
Explosure to higher concentration may cause laryngeal spasm & ocdema of the lungs & vocal cords. Prolonged or repeated exposure may cause dental decolouration & erosion. Gastritis & chronic bronchitis have been also reported in exposed workers. giddiness, mental confusion & nausea. Skin Contact : Causes skin burns & may produce Keloid & rectile Scarring . Facial burns may result in serious & disfiguring scars. Frequent contact with dilute acid may cause dermatitis & photosensitization may result from industrial contyract. Eye Contact : HCL is a strong eye irritant and contact with the acid may cause burns, reduced vision & total blindness. Ingestion :Ingestion of Hcl causes severe burns & corrosion of mouth esophagus & stomach. Symptom include dysphasia, Pain, Nausea, vomiting, Diarrhea & thirst. Emergency Treatment : Eye Wash eye with flowing water for 10 mins. LUNG : Remove casualty from the area of exposure. If unconscious, do not give any thing to drink, give artificial ventilation, chest compression or place in the recovery position if unconscious, give oxygen if available. Mouth : Do not make the casualty vomit. Treat unconscious casualty as for lunges. Skin : Remove contaminated clothing immediately. Drench the affected area with running water for atleast 10 minutes, transfer the patient to hospital as soon as possible.
5 ppm, 7 mg/m3
3 ppm
MATERIAL SAFETY DATA SHEET MATERIAL SAFETY DATA SHEET (HYDROCHLORIC ACID) 6. PREVENTIVE MEASURES Personnel Protective Equipment Approved respirator safety goggles, neoprene, Viton or butyl rubber glove and acid resistant outer clothing, mechanical exhaust. Handling &Storage Precautions It should be handled wearing approved & appropriate personal protective equipment as indicated above. It should be kept in a cool, well ventilated place away from oxidizing materials and protected against physical damage.
7. EMERGENCY/ FIRST AID MEASURES FIRE Fire Extinguishing Media Hydrochloric Acid is not combustible so an extinguisher appropriate to the surrounding fire condition should be used. Special Procedure -Unusual Hazards Exposure First Aid Measures/Emergency Treatment As described in Health Hazard Data Antidotes/Dosages : Not available. SPILLS Cover spill with sodium bicarbonate or a 50-50 mixture of soda Ash-Calcium Hydroxide Steps to be Taken st
& slowly & carefully mix to a slurry. If highly concentrated acid is spilled, the 1 priority is to contain by dyking & dilute with water spray to reduce fuming before neutralization. Waste Disposal Method :Ventilate the area & wear personal protective equipment. Add slowly to a large amount of soda ash & slaked time by stirring. Discharge the solution with large amount of water into a sink lined with protective matting & filled with plenty of running water. Allow 2-3 minutes between each stage as heat is generated by neutralisation.
Waste Disposal Method 8. ADDITIONAL INFORMATION/REFERENCES 9. MANUFACTURERS/SUPPLIERS DATA Contact Person in case of Emergency Name of Firm 10. DISCLAIMER
11. Abbrevations
MATERIAL SAFETY DATA SHEET MATERIAL SAFETY DATA SHEET (HYDROCHLORIC ACID) (HIGH SPEED DIESEL) 1. CHEMICAL IDENTITY Chemical Name Synonyms Regulated Identification Shipping name Diesel Oil Codes/Label Hazardous Waste Hazchem Code Hazardous Classification C.A.S. No. U.N. No. Hazardous Ingredients 3 4 Physical state Vapour Pressure @35C pH Appearance Odour Others Class-B, Flammable Liquid ID NO. 5 3Z
High speed Diesel (HSD) Gas Oil Diesel Fuel A complex mixture of Hydrocarbons C.A.S.No.
Chemical Classification Formula Hazardous Ingredients 1. Methyl Alcohol 2.
1202 C.A.S.No.
2.PHYSICAL/CHEMICAL DATA Boiling Pt/Range 110C to 400C Melting/Freezing Pt. Vapour Density (Air =1) Specific Gravity (Water =1) Solubility, In water at 30C 0.18C 3.0 5.0 0.82 gm/1@!15C Insoluble in water Floats on water.
Liquid @ 15C & 1atm < 0.1 psi @ 38C Not Pertinent Oily Brown to Yellow Charcteristic Odour
Sulphur Content 1% (max)
3.FIRE /EXPLOSION HAZARD DATA Auto ignition TemperatureC 277C Stable Explosion sensitivity to impact Explosion sensitivity to static Stable Electricity Hazardous combustion Acrid products smoke/CO/CO2/NOx Hazardous Polymerization Does not occur Oxidiser NO Organic Peroxide NO Corrosive Material NO Others NO 4. REACTIVITY DATA Incompatibility with other material Reactivity Hazardous Reaction Products
YES 3 1.3% 6% 55C TO 100C NA (OC) YES YES NO YES Stable
Saturated aliphatic hydrocarbons, which are contained in GAS OIL may be incompatible with strong oxidizing agents such as nitric acid. Charring may occur followed by ignition of unreacted hydrocarbon and other nearby combustibles. Mostly unreactive. Not affected by aqueous solutions of acids, alkalis, most oxidizing agents, and most reducing agents. When heated sufficiently or when ignited in the presence of air, oxygen or strong oxidizing agents burns exothermically.
5. HEALTH HAZARD DATA Routes of entry : Inhalation, Ingestion Skin & Eyes Inhalation : Dizziness, headache, Ingestion : Nausea & vomiting. Irritation of mouth & Effects of gastro intestinal tract may follow. Skin & Eye Contact : Irritation will remove natural fat Exposure/Symptoms
from skin. Prolonged contact should be avoided. Otherwise skin chapping, cracking or possible contact dermatitis may result.
LD50 (oral Rat) Permissible exposure limit TLV (ACGIH) STEL
5 to 15 g/kg Not Listed 5 mg/m3 Not Listed
NFPA Hazard Signals Health 1 Flammability 2 Reactivity 0
MF=16 HC = 18.7 BTU/lbx103 Molecular Weight 226.43
Odour Threshold
MATERIAL SAFETY DATA SHEET MATERIAL SAFETY DATA SHEET (HYDROCHLORIC ACID) Not Listed Special -
Conversion
MATERIAL SAFETY DATA SHEET MATERIAL SAFETY DATA SHEET (HIGH SPEED DIESEL) 6. PREVENTIVE MEASURES Personnel Avoid contact with liquid or vapours Protective Equipment Use Gum boot, Hand gloves while handling the product Handling &Storage Store in dry, cool, well ventilated area away from heat and flame. Keep away from oxidizing agents. Precautions 7. EMERGENCY/ FIRST AID MEASURES FIRE Fire Extenguishing Media Dry Chemical Powder, CO2 & Foam Special Procedure Keep the containers cool spraying water if exposed to fire Unusual Hazards Flashback may occur along vapour trail Exposure First Aid Measures/Emergency Treatment
Inhalation : Maintain respiration; administer oxygen if needed Ingestion : Give victim water or milk; do not induce vomiting; guard against aspiration into lungs. Skin : Remove the contaminated clothing and wash the affected area with plenty of water and soap Eyes : Wash with copious quantity of water
Not available Shut off leaks if no risks involved. Cantain/absorb spillage in earth/sand bund. Prevent liquid from entering into sewers. Seal all waste in vapour tight plastic bags for eventual disposal
Emergency treatment : If inhaled, remove the victim to fresh air, if not breathing, give artificial respiration. if unconscious but breathing, place in unconscious (recovery) position. Give external cardiac massage if necessary. If ingested to not induce vomiting. Remove contaiminated clothing, wash all effected skin thoroughly with soap and water irrigate affected eye with copious amount of water. Administration of medical paraffin may reduce absorption through digestive table. Gastrict lavage should be done only after endotracheal Intubation in view of respiration which may cause serious chemical pneumonitis for which antibiotic and corticosteroid therapy may be indicated.
11. Abbrevations
1. CHEMICAL IDENTITY Chemical Name Synonyms Trade Name Chemical Classification Formula Hazardous Ingredients 1. Hydrazine
MATERIAL SAFETY DATA SHEET MATERIAL SAFETY DATA SHEET (HIGH SPEED DIESEL) (HYDRAZINE) Regulated Identification HYDRAZINE Shipping name Hydrazine Anhydrous Hydrazine Anhydrous Codes/Label Flammable, corrosive Diamine liquid, Class-3 -Hazardous Waste Id. No.17 Inorganic compound Hazchem Code 2 PE H4N2 Hazardousclassification C.A.S.No. C.A.S. No. 302-01-2 302-01-2 U.N. No. 2029 Hazardous Ingredients C.A.S.No. Physical state Vapour Pressure @35C pH Appearance Odour Others Liquid N/A. 14.9 mm Hg at 25C Alkaline Colourless, fuming liquid Ammonical odour Miscible with methyl, Ethyl, Propyl & ISObutyl Alcohols YES
3 4.7% 100% 37.7(OC) N.A. (CC) YES YES NO YES
2.PHYSICAL/CHEMICAL DATA Boiling Pt/Range 113.5C Melting/Freezing Pt. Vapour Density (Air =1) Specific Gravity (Water =1) Solubility, In water at 30C 1.4C 1.1 1.008 at 20C Soluble

Auto ignition TemperatureC 270C Explosion sensitivity to impact Explodes Explosion sensitivity to static Explodes Electricity Hazardous combustion products Emits highly toxic fumes of NOX & NH3 Hazardous Polymerization Does not occur Oxidiser NO Organic Peroxide NO Corrosive Material YES Others --
Flammability
4. REACTIVITY DATA Incompatibility with other material Reactivity Hazardous Reaction Prods.
Chemical stability - Stable at room temp. decomposed if heated

Oxidizers, Hydrogen peroxide, Nitric Acid, Metal oxides/Acids & Porous materials Violent reaction with Benzene seleminimc Acid or anhy. CO2 + steel, copper oxide, Lead oxide, potassium Peroxodisulphate, Ruthen (iii) Chloride Forms sensitive explosive mixture with 2 Chloro 5- Methyl Nitrobenzene, Metal Salts (e.g. Cadium perchlorate, copper chlorate, Magnesium Nitrate (Heat sensitive) Hg(I) & (II) chlorites & Nitrates.
5. HEALTH HAZARD DATA 4) Routes of Entry :Inhalation, Ingestion, Skin, and Eyes Vapours may cause itching, swelling & blistering of eyelids, skin, nose & throat. The Effects of Exposure/ symptoms may be delayed for several hours. Temporary blindness may occur. Liquid Symptoms
Causes a caustic like burn, if not washed off at once. Ingestion or absorption through skin caused nausea, dizziness, headache., severe exposure may cause death. Emergency treatment : For any type of exposure, seek medical aid immediately. Inhalation : Remove the victim to fresh air area. Observe for development of delayed symptoms. Keep the victim quiet. Ingestion : Induce vomiting. Give egg white or other emollient. Skin & Eyes : Wash with large amounts of water for atleast 15 mins.
LD50 (oral Rat) Permissible exposure limit TLV (ACGIH) STEL
60 mg/Kg 0.1 ppm (Skin) 0.1 ppm (Skin)

Not listed
NFPA Hazard Signals Health 3 Flammability 3 Reactivity 2
Odour Threshold
MATERIAL SAFETY DATA SHEET MATERIAL SAFETY DATA SHEET (HIGH SPEED DIESEL) 3-4 ppm Special -
MATERIAL SAFETY DATA SHEET (HYDRAZINE) 6. PREVENTIVE MEASURES Personnel Protective Equipment Avoid contact with liquid or vapour. Provide self contained breahing apparatus, Ammonia like gas mask, rubber or plastic hand gloves over clothing. Side covered safety glasses, shoes & safety shower nearby. Handling &Storage Precautions Strict precautions are to be observed for storage. Should be stored in sealed glass containers, in a cool and dark place, away from heat, flame & other materials. 7. EMERGENCY/ FIRST AID MEASURES FIRE
Fire Extinguishing Media Water, Alcohol Resistance foam, CO2, Dry chemical powder. Special Procedure Keep the container cool by spraying water if exposed to heat fire or flame. Unusual Hazards Explodes if confined & flash back may occur. Exposure First Aid Measures/Emergency Treatment For any type of exposure, seek medical aid immediately. Inhalation : Remove the victim to fresh air area. Observe the development of delayed symptoms. Keep the victim quiet. Ingestion : Induce vomiting, give white egg or other emollient.Skin & Eyes : Wash with large amount of water for atleast 15 mins. Antidotes/Dosages : Not available. SPILLS Steps to be Taken Shut off leaks if without risk. Contain the spillage on sand or earth. Waste Disposal Method Dilute with water to produce atleast 40% solution. Neutralise with dilute sulphuric Acid. Drain into sewer with abundant water.
LC 50-570 ppm/4H (Inh-root). The compound is corrosive & suspected from human carcinogen (SHC). Severe explosion hazard when exposed to heat or flame or by chemical reaction. Explodes on contact with Barium / calcium compounds (at 130C). Potentially explosive reaction with alkali metals. Forms explosive mixture with methanol & nitro methane,
air, Lithium, perchlorate sodium perchlore & sodium. Ignites on contact with cotton waste & heavy metals, dinitrogen oxide, Rhenium & Alumins. Nitric Acid, H2O2 Ignites spontaneously in air. Full instructions to be obtained from the manufacturer. It is very sensitive & must not be used without full & complete instructions from the manufacturers for handling, storage and disposal, on contact with metal catalysts, it decomposes to NH3, H2 & N2 which may ignite or explode. violent reaction with i-chloro 2,4 Dinitrobenzene, oxidants & Thiocynate.
11. Abbrevations
1. CHEMICAL IDENTITY Chemical Name Synonyms (common) Trade Name Chemical Classification Formula Hazardous Ingredients
MATERIAL SAFETY DATA SHEET (KEROSENE) Regulated Identification KEROSENE Shipping name Codes/Label Petroleum Solvent, Light Naphtha Hazardous Waste Illuminated oil, Hazchem Code
Miscellaneous Hydrocarbon mixtures
C2H2+2 C.A.S.No.
Hazardousclassification C.A.S. No. 8008-20-8 U.N. No. 3.3/ 1223 Hazardous Ingredients C.A.S.No. Physical state Vapour Pressure @35C pH Appearance Odour Others Liquid
2.PHYSICAL/CHEMICAL DATA Boiling Pt/Range 392-500C F=200260C (at 1 atm) Melting/Freezing Pt. -50F=-45.6C Vapour Density (Air =1) Specific Gravity (Water =1) 0.80 at 15C liquid Solubility, In water at 30C
Characteristic
3.FIRE /EXPLOSION HAZARD DATA Auto ignition TemperatureC 444F Explosion sensitivity to impact Explosion sensitivity to static Electricity Hazardous combustion Not pertinent products Hazardous Polymerization Oxidiser Organic Peroxide Corrosive Material Others 4. REACTIVITY DATA Incompatibility with other material Reactivity Hazardous Reaction Prods. 5. HEALTH HAZARD DATA
Reactivity with water No reaction, Stability during transport Stable Polymerization Not pertinent Reactivity group = 33 Reactivity with common materials No reaction Neutralising agents for Acids & Caustic Not pertinent
5)
Routes of entry : 1)PPE Protective gloves, goggles or face shield, 2) Threshold limit valve 200 ppm, 3)Toxicity by Ingestion grade 1 LD = 5 to 15 g/kg, 4)Short term inhalation limits 2500 mg/m3 for 60 mins., 5)Symptoms following exposure Vapour causes slight irritation of eyes & nose. Liquid irritates stomach. If taken into lungs, causes distress & rapidly developing pulmonary edema.
Effects of Exposure/ Symptoms LD50 (oral Rat) Permissible exposure limit TLV (ACGIH) STEL Odour Threshold IDLH
1 ppm Data not available
MATERIAL SAFETY DATA SHEET (KEROSENE) 6. PREVENTIVE MEASURES Personnel Protective Equipment
Exposure - Call for medical aid, Harmful it swallowed. Liquid Irritating to skin & Eyes. Remove contaminated clothing & shoes. Flush affected areas with plenty of water. If in eyes hold eyelids open & flush with plenty of water. If swallowed & victim is conscious, have victim drunk water or milk. Do not induce vomiting.
Handling &Storage Precautions 7. EMERGENCY/ FIRST AID MEASURES FIRE Fire Extinguishing Media Combustible Extinguish with dry chemicals, Foam or carbon dioxide. Water may be ineffective on fire. Cool exposed containers with water. Special Procedure Unusual Hazards Exposure First Aid Measures/Emergency Treatment Exposure - Call for medical aid, Harmful it swallowed. Liquid Irritating to skin & Eyes. Remove contaminated clothing & shoes. Flush affected areas with plenty of water. If in eyes hold eyelids open & flush with plenty of water. If swallowed & victim is conscious, have victim drunk water or milk. Do not induce vomiting. Antidotes/Dosages SPILLS Steps to be Taken Waste Disposal Method 8. ADDITIONAL INFORMATION/REFERENCES
NFPA Hazard Classification : Category Health & Hazard (Blue) Flammability (Red) Reactivity (Yellow) Classification 0 2 0
11. Abbrevations
MATERIAL SAFETY DATA SHEET (LIQUEFIED PETROLEUM GAS) 1. CHEMICAL IDENTITY Regulated Identification Chemical Name Shipping name LIQUEFIED PETROLEUM GAS Synonyms LPG, Propane, Butane, Codes/Label Bottled gas, Propylene, Purofax Trade Name LPG Hazardous Waste Chemical Classification Hydrocarbon Mixture Hazchem Code Formula C3H8,C4H10(MIXTURE) Hazardous classification Hazardous Ingredients C.A.S.No. C.A.S. No. 1. 68476-85-7 U.N. No. 2. Hazardous Ingredients 1. Hydrogen sulfide 2 Butane 3. Propylene 2.PHYSICAL/CHEMICAL DATA Boiling Pt/Range > - 40C Melting/Freezing Pt. Not pertinent Vapour Density (Air =1) 1.189 Specific Gravity (Water =1) 0.51 0.58 at -50C Solubility, In water at 30C Slight Physical state Vapour Pressure @35C pH Appearance Odour Others
PETROLEUM GAS LIQUEFIED Flammable gas , Class-2 ID NO. 5 2 WE
1075 C.A.S.No. 74-98-6 106-97-8 115-07-1 Gas, 15C & 1atm N/A mm Hg. Not Pertinent Colourless Mercaptan added as an odouriser
Soluble in organic solvent, Alcohol
3.FIRE /EXPLOSION HAZARD DATA Auto ignition TemperatureC 460.1 Propane,405 Butane Explosion sensitivity to Not established impact Explosion sensitivity to static May explode Electricity Hazardous combustion Prod. Emits CO, CO2 Hazardous Polymerization Does not occur Oxidiser NO Organic Peroxide NO Corrosive Material NO Others -4. REACTIVITY DATA Incompatibility with other material Reactivity Hazardous Reaction Products
YES 3 1.9% 9.5% (OC) 104.4(CC) YES YES NO NO Stable
Strong, Oxidisers No reaction with common material but may react with oxidizing material Not available
5. HEALTH HAZARD DATA Routes of entry Inhalation, Skin Conservation in air greater than 10% causes dizziness in few minutes and conc gives Effects of the same symptoms in 10 Mtrs. High concentration causes asphyxiation. Liquid on skin Exposure/Symptoms
causes frostibote. Emergency treatment : If inhalation, remove the victim to fresh air area. Provide artificial resuscitation. Skin : Remove the wetted clothes & wash the affected area with plenty of water. Eyes : Flush with plenty of water for 15 mins. Seek medical aid immediately.
Not Listed Not ppm Not Listed 1000 ppm, 1800mg/m3 Not listed 5000 to 20000ppm mg/m3
MATERIAL SAFETY DATA SHEET (LIQUEFIED PETROLEUM GAS) 6. PREVENTIVE MEASURES Personnel Protective Avoid contact of gas. Provide hand gloves, Equipment Safety goggles, gas mask, protective over clothing & shoes. Handling &Storage Keep in a tightly closed cylinders in a cool well ventilated area, Away from heat, flame & sparks. Precautions 7. EMERGENCY/ FIRST AID MEASURES FIRE Fire Extenguishing Media CO2,Dry Chemical Powder, Water spray Special Procedure Keep the containers cool by spraying water if exposed to fire or heat. Unusual Hazards If not cooled sufficient, containers will explode in fire. Exposure First Aid Measures/Emergency Treatment
If inhaled, remove the victim to fresh air area and artificial respiration may be provided if required. If skin is affected with Liquid, remove the clothing & wash the affected area with plenty of water. Seek medical aid
Not available Shut off leaks if without risk. Warn everybody that air mixture is explosive. Allow gas to burn under control
Avoid contact with oxidizers. Olefinic impurities may lead to narcotic effect or it may act as a simple Asiphyxiant. A very dangerous hazard when exposed to heat or flame. If fire is big, keep surrounding area cool by spraying water.
11. Abbrevations
MATERIAL SAFETY DATA SHEET (METHANOL) Regulated Identification METHYL ALCOHOL Shipping name Methanol Codes/Label Flammable Liquid, Methanol, Wood Class-3 Alcohol Wood spirit, colonial Spirit Hazardous Waste ID NO. 17 Alcohol Hazchem Code 2PE CH3OH Hazardous Classification C.A.S.No. C.A.S. No. 67-56-1 67-56-1 U.N. No. 1230 Hazardous Ingredients C.A.S.No. 3 4 Physical state Vapour Pressure @35C pH Appearance Odour Others Liquid @35CC100mm Hg at 21.2C Neutral Colourless, Watery Alcoholic Odour
Miscible with Ethanol, Ether, Benzene, Ketones & other Organic Solvents
1. CHEMICAL IDENTITY Chemical Name Synonyms
Trade Name Chemical Classification Formula Hazardous Ingredients 1. Methyl Alcohol 2.
2.PHYSICAL/CHEMICAL DATA Chemical Name 64.5C Boiling Pt/Range Melting/Freezing Pt. Vapour Density (Air =1) Specific Gravity (Water =1) Solubility, In water at 30C -97.8C 1.1 0.79 20C(liqu.)
3.FIRE /EXPLOSION HAZARD DATA Auto ignition TemperatureC 463.8 Explosion sensitivity to Stable impact Explosion sensitivity to static Vapours are explosive Electricity Hazardous combustion Emits acrid smoke & products imitating fumes Hazardous Polymerization Will not occur Oxidiser NO Organic Peroxide NO Corrosive Material NO Others 4. REACTIVITY DATA Incompatibility with other material Reactivity Hazardous Reaction Products
YES 3 6.00% 36.5% 16.1 (OC) 12.2 (OC) YES YES NO NO Stable
strong Oxidisers, Berylium Dihydride, Metals (K Mg), Carbon Tetrachloride + Metal (Al. Mg. Zn.), Dichloromethane, Oxidants Violent reaction with Alkyl Aluminium salts, Acetyl Bromide, Chloroform + NaOH, CrO3, Nitric Acid, HCIO4, P2O3
5. HEALTH HAZARD DATA Routes of entry : Inhalation, Ingestion Skin & Eyes Skin & Eyes : Exposure to vapours causes eye irritation, headache, fatigue, Effects of drowsiness, High concentration can produce central nervous sytem depression and Exposure/Symptoms
optic nerve damage. 50000 ppm will probably cause death in 1-2 hrs. Can absorb through skin ingestion : Sweeling may cause death or eye damage.
5628 mg/kg 200 ppm(skin) 200 ppm(skin) 250 ppm(skin) 100 ppm
NFPA Hazard Signals Health 2 Flammability 3 Reactivity 0 Special 0
MF=16 HC = 8.6 BTU/lbx10-3 Molecular Weight 32.1 Conversion
MATERIAL SAFETY DATA SHEET IDLH 6000 ppm 1 ppm = 1.31 mg/m3
MATERIAL SAFETY DATA SHEET (METHANOL) 6. PREVENTIVE MEASURES Personnel Avoid contact with liquid or vapours Protective Equipment Provide air-supplied respirator, (Do not use organic cannister Mask), Wear boots, Safety goggles, protective appron and rubber gloves. Provide eye wash and basin nearby. Handling &Storage Store away from heat, ignition source, sparks, Keep away from heat and flame. Precautions 7. EMERGENCY/ FIRST AID MEASURES FIRE Fire Extenguishing Media CO2 Dry chemicals powder, Alcohol Foam, Water Mist/Fog. Special Procedure Keep the containers cool by spraying water if exposed to heat or flame. Unusual Hazards Containers may explode in fire. Exposure First Aid Measures/Emergency Treatment
Inhalation : Remove the victim to fresh air area. Seek Medical Aid Immediately Skin : Remove the soak clothes and wash the affected area with plenty of water and soap Eyes : Immediately wash with plenty of water for 15 minutes
Baking soda in glass of water Shut off leaks if without risks. Drench with water Seal all waste in vapour tight plastic bags for eventual disposal
A human poison by ingestion. Poison also by skin contact. The main toxic effect is extended to the nervous system, particularly optic nerves and Ratina, which may lead to permanent blindness. Once absorbed, it is slowly eliminated, Coma by severe exposure may lost for 2-4 days. Person with eye, liver, kidney & lung problem should avoid contact. Periodic medical check up is recommended. Dangerous fire hazard when exposed to heat, flame and oxidizers.
11. Abbrevations
MATERIAL SAFETY DATA SHEET (N-METHYL DIETHANOLAMINE (MDEA) Regulated Identification N Methyl Diethanol Shipping name Fire fighting Amine (MDEA) Chemical N-di (2-Hydraxyethyl) Codes/Label N- METHYLAMINE Hazardous Waste Hazchem Code CH3-3(CH2-CH2-OH)2 Hazardousclassification C.A.S.No. C.A.S. No. 105-59-9 105-59-9 U.N. No. Hazardous Ingredients 2.PHYSICAL/CHEMICAL DATA Boiling Pt/Range 247C (477F) Melting/Freezing Pt. Vapour Density (Air =1) Specific Gravity (Water =1) Solubility, In water at 30C -21C (-5.8F) 4.1 1.04189 at 20C Infinitely soluble Physical state Vapour Pressure @35C pH Appearance Odour Others(Molecular wt) Flammability TDG Flammability LEL UEL Flash Point C Flash Point C Combustible Liquid Flammable Material Pyrophoric Material Explosive Material 136C(CC) C.A.S.No.
1. CHEMICAL IDENTITY Chemical Name Synonyms Trade Name Chemical Classification Formula Hazardous Ingredients 1. N Methyl Diethanol Amine
0.001at 20C
Colourless to light yellow

Slight amine like odour 119.16
3.FIRE /EXPLOSION HAZARD DATA Auto ignition TemperatureC N/A Explosion sensitivity to impact Explosion sensitivity to static Electricity Hazardous combustion products Hazardous Polymerization Will not occur Oxidiser Organic Peroxide Corrosive Material Others 4. REACTIVITY DATA
Chemical stability - Stable under ordinary conditions of use and storage. Darkens on exposure to air or light . Burning may produce CO, CO2, nitrogen oxides.
5. HEALTH HAZARD DATA 6) Routes of Entry : Inhalation : No adverse effects expected since MDEA has a low vapor pressure. Effects of Exposure/ Ingestion : May cause burns in the mouth, pharynx & esophagus, abdominal pain, Symptoms
Nausea, vomiting & diarrhea. Skin contact : May cause irritation, redness & pain especially on prolonged or repeated contact. Eye contact : Corrosive, contact causes severe irritation, burns, redness & pain. May cause irritation, redness, Pain & corneal damage.
MATERIAL SAFETY DATA SHEET IDLH
MATERIAL SAFETY DATA SHEET (N-METHYL DIETHANOLAMINE (MDEA ) 6. PREVENTIVE MEASURES Personnel Protective Equipment Handling &Storage Precautions Keep in a tightly closed container, Store in a cool, dry ventilated area. Protect
against physical damage isolate from any source of Heat or ignition. Avoid contact with copper & copper alloys. Material is suitably handled in stainless steel equipment. Do not use aluminum for storage of aqueous solution, outside or detached storage is preferred. Isolate from Acidic materials. Do not store above 43C (110 F)
7. EMERGENCY/ FIRST AID MEASURES : Inhalation : Not expected to require first aid measures. Ingestion : If
swallowed, Do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
FIRE Fire Extinguishing Media
Special Procedure Unusual Hazards Exposure First Aid Measures/Emergency Treatment

Eyes
Fire extinguishing media : Dry chemical, alcohol foam or carbon dioxide, water spray may be used to keep fire exposed materials cool. Water or foam may cause frothing. Special Information : In the event of a fire, wear full protective clothing & self contained breathing apparatus.
: Use chemical safety goggles and / or a full face shield where splashing is possible. Maintain eye wash fountains & quick drench facilities in work area.
Antidotes/Dosages : SPILLS Steps to be Taken Waste Disposal Method
--
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility.
Label Hazard warning : Harmful if swallowed. Causes skin irritation and severe eye irritation. Avoid contact with eyes, skin & clothing. Wash thoroughly after handling. Avoid breathing vapour. Keep container closed. Use with adequate ventilation. Label first aid : If swallowed, do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person. Remove contaminated clothing & shoes. Wash clothing before reuse. If inhaled, remove to fresh air. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 mins. If not breathing, give artificial respiration. In all cases, get medical attention.
9. MANUFACTURERS/SUPPLIERS DATA
Contact Person in case of Emergency Name of Firm : Advance Petrochemicals Ltd, 167, PIRANA ROAD, PIPLAJ, Ahmedabad -382 405 Phone (091)-7925715196, 25711218, Fax 091-79-25710027
10. DISCLAIMER
11. Abbrevations
1. CHEMICAL IDENTITY Chemical Name Synonyms Chemical Classification Trade Name Chemical Classification Formula Hazardous Ingredients 1. Naphtha 2.
MATERIAL SAFETY DATA SHEET (NAPHTHA) Regulated Identification NAPHTHA Shipping name Gasoline Petroleum Naphtha Codes/Label 33/Class 3, Flammable Liquid Coal Tar Solvent Hazardous Waste 5 Hazchem Code 3YE A complex mixture of Hazardous Hydrocarbon Classification C.A.S.No. C.A.S. No. 8030-30-6 8030-30-6 U.N. No. 1255 Hazardous Ingredients C.A.S.No. 3 4 Physical state Vapour Pressure pH Appearance Odour Others Liquid @ 15C & 1atm Not available Neutral Darkstraw coloured to colourless Petrol like Odour
Soluble in Benzene Toluene Xylene
2.PHYSICAL/CHEMICAL DATA Chemical Name Boiling Pt/Range 35C to 205C Melting/Freezing Pt. Not available Vapour Density (Air =1) Specific Gravity (Water =1) Solubility, In water at 30C 2.5 to 4.8 0.69 to 0.78 gm/1 @ 20C Insoluble in water, Floats on water

Auto ignition TemperatureC 229- 293C Explosion sensitivity to impact Stable Explosion sensitivity to static May Explode Electricity Hazardous combustion products Acrid smoke & irritating fumes Hazardous Polymerization Will not occur Oxidiser NO Organic Peroxide NO Corrosive Material NO Others NO
Flammability
YES
3 1.10% 5.90% -20 - 50C (OC) NA (OC) YES YES NO NO
4. REACTIVITY DATA Incompatibility with other material Reactivity Hazardous Reaction Products
Chemical stability
Incompatible with strong oxidizers
Stable
Does not react with common materials but may react with oxidizing agents
Data Not available
5. HEALTH HAZARD DATA Routes of entry : Inhalation, Ingestion Skin & Eyes Inhalation : Can causes consciousness which may go to coma, Strentorious breathing Effects of & bluish tint to the skin. ingestion : In mild form, intoxication resembles drunkeness. Exposure/Symptoms
Sometimes headache, lack of appetite, dizziness, sleeplessness, Indigestion & nausea. Chemical pneumonitis results if aspirated during ingestion of while vomiting. Can causesyestemic effects after repeated exposure. Skin : Causes Irritation, Prolonged contact will dry & defat skin with dermatitis. Eye : Imitation
Not listed mg/kg 300 ppm 900 mg/m3 300 ppm 900 mg/m3 500 ppm 1500mg/m3 0.25 ppm 1300 mg/m3
NFPA Hazard Signals MF=16 Health 1 HC =18.0 BTU/lbx103 Flammability 3 Molecular Weight Reactivity 0 Special 0
MATERIAL SAFETY DATA SHEET (NAPHTHA) 6. PREVENTIVE MEASURES Personnel Avoid contact with liquid or vapours Protective Equipment Hand gloves, Gas Mask. PVC Suit Handling &Storage Keep in cool, well ventilated area away from heat flame or Oxidisers. Keep the containers tightly closed as the vapour fumes when exposed Precautions to air. 7. EMERGENCY/ FIRST AID MEASURES FIRE Fire Extenguishing Media Dry Chemical powder, CO2, Foam Special Procedure Keep the containers cool, spraying water if exposed to fire Unusual Hazards Exposure Flashback may occur along vapour trail First Aid Measures/Emergency Treatment
Inhalation : Remove the victim to fresh air area. Apply artificial respiration or Oxygen if needed Ingestion : Seek medical aid immediately, Skin : Remove the contaminated clothing and wash the affected areas with plenty of water & soap Eyes : Flush with plenty of water for 15 mins. Seek medical aid immediately without delay
Antidotes/Dosages SPILLS Steps to be Taken
Baking soda in glass of water Collect leaking product into closed container. Use water spray to dilute the vapours. Prevent run-off from entering into sewer. Shut off leaks if no risk involved . Cantain/absorb spillage in earth/sand. Eliminate all source of ignition. Ventilate the area. Collect all the waste in vapour tight plastic bags for eventual disposal.
Waste Disposal Method
Emergency treatment : Remove victim to fresh air. Give artificial respiration, if required, Remove contaminated clothing quickly. Do not induce vomiting if ingested. Keep patient warm and quit. Olive oil or any other vegetable oil should be given orally to retard absorption of naphtha.
11. Abbrevations
1. CHEMICAL IDENTITY Chemical Name Synonyms Trade Name Chemical Classification Formula Hazardous Ingredients 1. Potassium Hydroxide
MATERIAL SAFETY DATA SHEET (POTASSIUM HYDROXIDE) Regulated Identification Potassium Hydroxide Shipping name Potassium Hydroxide Caustic Pottash Lye Codes/Label Corrosive Class-8 -Hazardous Waste ID No.16 Inorganic Alkali Hazchem Code 2R KoH Hazardousclassification C.A.S.No. C.A.S. No. 1310-58-3 1310-58-3 U.N. No. 1813-1814 Hazardous Ingredients C.A.S.No. Physical state Vapour Pressure @35C pH Appearance Odour Others Solid N.A. 13..5(0.1M Ag. Soln) WHITE Odourless Soluble in Alcohol, Glycerols NO NA Not pertinent Not pertinent
2.PHYSICAL/CHEMICAL DATA Boiling Pt/Range 1320C Melting/Freezing Pt. Vapour Density (Air =1) Specific Gravity (Water =1) Solubility, In water at 30C 360C Not pertinent 2.04 Soluble
3.FIRE /EXPLOSION HAZARD DATA Auto ignition TemperatureC Not pertinent Explosion sensitivity to Stable impact Explosion sensitivity to static Stable Electricity Hazardous combustion Emits toxic fumes of products K2O Hazardous Polymerization Does not occur Oxidiser NO Organic Peroxide NO Corrosive Material YES Others -4. REACTIVITY DATA Incompatibility with other material Reactivity Hazardous Reaction Prods.
NO NO NO NO

When wet, attacks metals such as aluminium, Tin, Lead & Zinc Violent exothermic reaction with water, Potentially explosive reaction with Bromoform crown ethers, chlorine dioxide, nitrobenzene nitro-methane, nitrogen-tri chloride, Per oxidized THF. React with Ammonium hexa-chloro-platinate (2-)+heat, to form a heat sensitive explosive product.
5. HEALTH HAZARD DATA 7) Routes of Entry : Skin, ,Eyes, Ingestion and Inhalation Ingestion : Causes severe pain in the throat and epigastrium, hernatemesesis, Effects of Exposure/ collapse. Eyes & Skin : Causes severe irritation.. Inhalation : Causes severe Symptoms
irritation. Emergency treatment : Ingestion : Do not induce vomiting, give plenty of water & milk to drink. Eyes : Flush with a lot of water for 15 mins. Skin : Remove wetted clothes & flush the affected area with plenty of water & rinse with dilute vinegar solution. Inhalation : Remove the victim to fresh air area, seek medical aid immediately
365 mg/Kg
Not listed
2 (ceiling) mg/m3
Not listed
Not available
MATERIAL SAFETY DATA SHEET (POTASSIUM HYDROXIDE) 6. PREVENTIVE MEASURES Personnel Protective Equipment Avoid contact with liquid, solid, vapours or dust. Provide close fitting safety goggles/face shield respirator for dust, long sleeves cotton jacket, rubber gloves, rubber shoes & rubber apron. Handling &Storage Precautions Keep the containers tightly closed & away from moisture & metals. 7. EMERGENCY/ FIRST AID MEASURES FIRE Fire Extinguishing Media Not flammable Special Procedure Keep the container cool by spraying water if exposed to fire or heat. Unusual Hazards Poisonous gases are produced. Exposure First Aid Measures/Emergency Treatment Skin, Eyes & Ingestion Ingestion : Give water. Do not induce vomiting. Seek medical aid immediately. Eyes : Irrigate with plenty of water for 15 mins. Skin : Remove the wetted clothing & boots & flush the affected area with plenty of water. Antidotes/Dosages : Not available. SPILLS Steps to be Taken Sweep & collect without making dust. Wash the surface with plenty of water & soap. Waste Disposal Method Neutralise with HCl & discharge into sewer with sufficient water. 8. ADDITIONAL INFORMATION/REFERENCES 9. MANUFACTURERS/SUPPLIERS DATA Contact Person in case of Emergency Name of Firm 10. DISCLAIMER
11. Abbrevations
1. CHEMICAL IDENTITY Chemical Name Synonyms Trade Name Chemical Classification Formula Hazardous Ingredients 1. Propane
MATERIAL SAFETY DATA SHEET (PROPANE) Regulated Identification PROPANE Shipping name Liquefied Petroleum gas, Red label Dimethyle Methane, Codes/Label Flammable gas, Propyle hydride Class-2 --Hazardous Waste --Hydrocarbon Hazchem Code 2 WE C3H8 Hazardousclassification C.A.S.No. C.A.S. No. 74-98-6 U.N. No. 1978 Hazardous Ingredients C.A.S.No. Physical state Vapour Pressure @35C pH Appearance Odour Others Compr Liquid Gas 6840 mm Hg at 20C Not Pertinent Colourless Odourless
Soluble in Alcohol. Ether, chlorofarm
2.PHYSICAL/CHEMICAL DATA Boiling Pt/Range -42C Melting/Freezing Pt. Vapour Density (Air =1) Specific Gravity (Water =1) Solubility, In water at 30C -0.186C 1.6 0.5 6.5 @ 18C
3.FIRE /EXPLOSION HAZARD DATA Aut oignition TemperatureC 470C Stable Explosion sensitivity to impact Explosion sensitivity to static May explode Electricity Hazardous combustion None in particular products Hazardous Polymerization Does not occur Oxidiser NO Organic Peroxide NO Corrosive Material NO Others --4. REACTIVITY DATA Incompatibility with other material Reactivity Hazardous Reaction Products
YES -2.10% 9.5% -156C (OC) (CC) YES YES NO YES Stable
Oxidizers Explosive Reaction with clO2, violent exothermic reaction with Barium Peroxide. Not available
5. HEALTH HAZARD DATA Routes of entry Inhalation, Skin contact & Eye contact Inhalation : Simple axphyxiant- shortness of breadth, Headache, drowsiness, Effects of unconsciousness. Skin : Frostibite, Redness, Pain, Blister. Eye : Frostbite, Redness, Exposure/Symptoms
Pain, Impaired vision. Emergency Treatment : Inhalation : Fresh air, rest, artificial Respiration if indicated. Refer to medical attention. Skin On frosibite, rinse with plenty of water, do not remove clothes,. Refer for medical attention. Eye Contact First rinse with plenty of water for several mins. (Remove contact lenes if easily possible), then take to Doctor.
--
MATERIAL SAFETY DATA SHEET (PROPANE) 6. PREVENTIVE MEASURES Personnel Protective Avoid contact with liquid or vapours Equipment Provide self contained breathing apparatus, Safety goggles, hand gloves and shoes Handling &Storage Keep in dry, cool, well ventilated area away from heat,flame or Precautions oxidizers 7. EMERGENCY/ FIRST AID MEASURES FIRE Fire Extinguishing Media Stop flow of gas, foam, CO2, Dry chemical powder. Special Procedure Stop the flow of gas, keep the containers cool by spraying water if exposed to heat or flame. Flashback along vapour trail may occur. Unusual Hazards Exposure First Aid Measures/Emergency Treatment
Inhalation : Guard against self injury if stuporous, confused or anesthetised. Apply artificial respiration if breathing is difficult. Avoid administration of Epinephrine or other sympathomimetric Amines. Prevent aspiration of vomitus by proper positioning of head. Give symptomatic & supportive treatment. Seek medical aid immediately.
Not available Shut off leaks if without risks. Warn verybody that air mixture is explosive. All the gas to burn under control
A simple Asphyxient. Flammable gas may cause flash fire.
11. Abbrevations
1. CHEMICAL IDENTITY Chemical Name
Synonyms Trade Name Chemical Classification Formula Hazardous Ingredients 1. Sodium Hydroxide
MATERIAL SAFETY DATA SHEET (SODIUM HYDROXIDE) Regulated Identification SODIUM HYDROXIDE Shipping name SODIUM HYDROXIDE Solid/ Solution Caustic soda, Soda lye, Codes/Label Corrosive, Class-8 lye, Sodium Hydrate Caustic Soda Hazardous Waste Id. No. 16 Alkaline Inorganic Hazchem Code 2R
Compound
Naoh C.A.S.No. 1310-73-2
Hazardousclassification C.A.S. No. 1310-73-2 U.N. No. 1823/1824 Hazardous Ingredients C.A.S.No. Physical state Vapour Pressure @35C pH Appearance Odour Others Solid 1 mm Hg at 730C 13-14 While flakes/Pellets Odourless Soluble in Alcohol, Methanol & Glycerol, NO NA Not pertinent Not pertinent (OC) (CC) NO NO NO NO
2.PHYSICAL/CHEMICAL DATA Boiling Pt/Range 1390-1557C Melting/Freezing Pt. Vapour Density (Air =1) Specific Gravity (Water =1) Solubility, In water at 30C 318.4-322C Not pertinent 2.12 at 24/4C Soluble
3.FIRE /EXPLOSION HAZARD DATA Auto ignition TemperatureC Not pertinent Explosion sensitivity to Stable impact Explosion sensitivity to static Stable Electricity Emits toxic fumes of Hazardous combustion Na2O products Hazardous Polymerization Will not occur Oxidiser NO Organic Peroxide NO Corrosive Material YES Others -4. REACTIVITY DATA Incompatibility with other material Reactivity Hazardous Reaction Prods.

Water, acids, flammable Liquids, organic Halides, metals, Al. Sn, Zn, Nitromethane & Nitro compounds Vigorous reaction with organic Halides, Metals, Nitro compounds Not available
5. HEALTH HAZARD DATA 8) Routes of Entry :Inhalation, Skin, Ingestion and Eyes Inhalation : Causes small burns to upper respiratory tract & lungs, mild nose irritation. Effects of Exposure/ Ingestion : Causes severe damage to mucous membrane, severe scaring or Symptoms
perforation may occur. Eyes : Severe damage, Skin : Causes severe burns. Emergency treatment : Inhalation : Remove the victim from exposure support respiration, give oxygen if necessary. Ingestion : Give water or milk followed by dilute vinegar or fruit Juice. Do not induce vomiting. Skin : Wash the affected area with plenty of water & soap. Eyes : Wash with plenty of water for 15 mins. Seek medical aid immediately.
Not listed 2 (ceiling) mg/m3 2 (ceiling) mg/m3

Not listed ppm,mg/m3
Odourless
MATERIAL SAFETY DATA SHEET (SODIUM HYDROXIDE) 6. PREVENTIVE MEASURES Personnel Protective Equipment Avoid contact with solid or liquid. Provide side covered safety goggles, face shield, filter or dust type respirator, Rubber shoes & rubber hand gloves. Handling &Storage Precautions Keep in a cool, dry and well ventilated place. 7. EMERGENCY/ FIRST AID MEASURES FIRE Fire Extinguishing Media Not flammable Special Procedure Keep the container cool by spraying water if exposed to heat or flame. Unusual Hazards Toxic gases are produced. Exposure First Aid Measures/Emergency Treatment If eyes are affected, flush with plenty of water for 15 mins. Skin : Remove contaminated clothes and shoes. Wash the affected area with plenty of water. If inhaled, remove the victim to fresh air area . Support respiration. Seek medical aid immediately for all types of exposures. Inhalation : Eyes : Skin : Antidotes/Dosages : Not available. SPILLS Steps to be Taken Sweeps & collect without making dust. Wash the surface with plenty of water & soap. Waste Disposal Method Put in a large vessel, neutralize with Hcl & drain into sewer with abundant water. 8. ADDITIONAL INFORMATION/REFERENCES
A strong base. Vigorous reaction with 1,2,4,5 Tetrachloro benzene has caused many industrial explosions and burns extremely toxic 2,3,7,8 Tetra chlorodiben zodioxin. Under proper conditions of temp, pressure & state of dilution, it can react or ignite violently with Acetic Acid, Acetaldehyde, Acetic Anhydride, Acrolein, Acrylonitrile, Allyl Alcohol, Allyl chloride.
11. Abbrevations
1. CHEMICAL IDENTITY Chemical Name Synonyms Trade Name Chemical Classification Formula Hazardous Ingredients 1. Sulphuric Acid
MATERIAL SAFETY DATA SHEET (SULPHURIC ACID) Regulated Identification SULPHURIC ACID Shipping name SULPHURIC ACID Oil of vitrol Codes/Label Sulphuric Acid Hazardous Waste corrosive Class-8 ID. NO.16 Toxic/Corrosive Hazchem Code 2P H2SO 4 Hazardousclassification C.A.S.No. C.A.S. No. 7664-93-9 7664-93-9 U.N. No. 1830 Hazardous Ingredients C.A.S.No. Physical state Vapour Pressure @35C pH Appearance Odour Others Liquid 1.00 mg/Hg Highly acidic Colourl;ess/Oily Odourless Soluble in ethyl Alcohol NO Not Pertinent Not Pertinent Not Pertinent Not Pertinent (OC) Not Pertinent (CC) NO NO NO NO Moderate
2.PHYSICAL/CHEMICAL DATA Boiling Pt/Range 330C Melting/Freezing Pt. Vapour Density (Air =1) Specific Gravity (Water =1) Solubility, In water at 30C 10.49C Not applicable 1.84 100%
3.FIRE /EXPLOSION HAZARD DATA Auto ignition TemperatureC Not Pertinent Explosion sensitivity to NIL impact Explosion sensitivity to static NIL Electricity Hazardous combustion NIL products Hazardous Polymerization -Oxidiser YES Organic Peroxide NO Corrosive Material YES Others -4. REACTIVITY DATA Incompatibility with other material Reactivity Hazardous Reaction Prods.
Carbides, Water, Chlorates, Fluminates & Powdered Metals Reacts with water & organic materials with evoluation of heat Reacts with water to produce heat toxic & corrosive fumes. Reacts with matels to form flammable Hydrogen gas.
5. HEALTH HAZARD DATA Routes of Entry : Inhalation, Contact, Ingestion Irritates eyes, nose, throat, dental erosion, Skin & eyes burn. Causes deep burn to Effects of Exposure/ tissue, very dilute solution causes dermatitis. Explosure cause bronchitis. Symptoms
Emergency Treatment : Respiratory support & medial attention
2140 mg/kg N.A. ppm N.A. ppm, 1mg/m3 3 mg/m3

N.A. ppm
MATERIAL SAFETY DATA SHEET (SULPHURIC ACID) 6. PREVENTIVE MEASURES Personnel Protective Equipment Handling &Storage Precautions
Rubber gloves, Safety goggles, Acid Proof overalls. Provide Safety shower, Eye wash fountain, Self contained breathing apparatus. To be stored in non-corrosive, non metallic container. Add acid to water gradually for dilution. Store away from incompatible material.
7. EMERGENCY/ FIRST AID MEASURES FIRE Fire Extinguishing Media Dry chemical powder, Carbon Dioxide Special Procedure N.A. Unusual Hazards Water applied directly results in evolution of heat causes splattering Exposure First Aid Measures/Emergency Treatment Wash eyes & affected area of body with plenty of water immediately. Antidotes/Dosages : Give milk of magnesia water & soda water or cold milk to drink if ingested. SPILLS Steps to be Taken Wash with running water. Neutralise with lime in case of large spills. Waste Disposal Method Add slowly into a large amount of soda Ash & slaked time by stirring. Discharge the solution with large amount of water into a sinked lined with protective matting and filled with chipped marble. 8. ADDITIONAL INFORMATION/REFERENCES
11. Abbrevations
MATERIAL SAFETY DATA SHEET (SULPHUR) 1. CHEMICAL IDENTITY Chemical Name Synonyms Trade Name Chemical Classification Formula Hazardous Ingredients 1. 2. Regulated Identification Shipping name SULPHUR Codes/Label Flammable Solid Class-4.1 Hazardous Waste ID NO. 17 Hazchem Code 2Z Hazardous Classification C.A.S. No. 7704-34-9 U.N. No. 1350 Hazardous Ingredients C.A.S.No. Sulphur 7704-34-9
SULPHUR Brimostone, Bensulfoid colsul -Non Metallic element S C.A.S.No.
2.PHYSICAL/CHEMICAL DATA Boiling Pt/Range 444.6C Melting/Freezing Pt. Vapour Density (Air =1) Specific Gravity (Water =1) Solubility, In water at 30C 106.8C Not permitted 2.07 Insoluble
Physical state Vapour Pressure @35C pH Appearance Odour Others
Liquid Molten solid 1mm Hg at 183.8C Not Pertinent Yellow Faint Rotten Egg odour
Slightly soluble in Benzene,carbon diosulphide
3.FIRE /EXPLOSION HAZARD DATA Auto ignition TemperatureC 230C Explosion sensitivity to Stable impact Explosion sensitivity to static Data not available Electricity Hazardous combustion Emit toxic fumes of products SOX Hazardous Polymerization Will not occur Oxidiser NO Organic Peroxide NO Corrosive Material NO (Yes in presence of moisture) Others -4. REACTIVITY DATA Incompatibility with other material Reactivity Hazardous Reaction Products 5. HEALTH HAZARD DATA Effects of Exposure/Symptoms LD50 (oral Rat) Permissible exposure limit TLV (ACGIH) STEL Odour Threshold IDLH
No NA Not Pertinent Not Pertinent 207C (CC) NA (OC) NO YES NO NO
Chemical stability Stable Oxidisers, Halogens, Carbides, Active Metals Can react violently with Halogens, carbides, Halogenites Not available
Routes of entry Inhalation, Eyes & Skin

Can cause eye irritation, may irritate skin
Not Listed Not ppm Listed Not ppm Listed Not Listed Not ppm available
(SULPHUR) 6. PREVENTIVE MEASURES Personnel Protective Avoid contact with solid or liquid. Provide safety Goggles or face shield, Equipment Rubber hand gloves, Rubber boots & mask for the dust. Handling &Storage Store in dry, cool, well ventilated area away from heat and flame. Keep away from oxidizing materials. Precautions 7. EMERGENCY/ FIRST AID MEASURES FIRE Fire Extenguishing Media Water Special Procedure Keep the containers cool spraying water if exposed to heat or flame Unusual Hazards Burns with blue flame difficult to see in day light Exposure First Aid Measures/Emergency Treatment :Skin Treat molten Sulphur burns with petroleum jelly or mineral
oil Eyes : W ash with plenty of water for 15 mins. Skin : Wash the affected area with plenty of water. Do not seek medical aid immediately.
Not available Sweep and collect without making dust. Wash the surface with plenty of water. Dump into a land fill site.
11. Abbrevations
MATERIAL SAFETY DATA SHEET (SULPHUR DIOXIDE) Regulated Identification SULPHUR DIOXIDE Shipping name Codes/Label Hazardous Waste Hazchem Code SO2 Hazardousclassification C.A.S.No. C.A.S. No. U.N. No. Hazardous Ingredients C.A.S.No. Physical state Vapour Pressure @35C pH Appearance Odour Others
1. CHEMICAL IDENTITY Chemical Name Synonyms Trade Name Chemical Classification Formula Hazardous Ingredients 1. Dry Chemical powder
2.PHYSICAL/CHEMICAL DATA Boiling Pt/Range -10C Melting/Freezing Pt. Vapour Density (Air =1) Specific Gravity (Water =1) Solubility, In water at 30C -75.5C 2.3 HYDROLYSES
3.3 Bar at 20C
Colourless gas PUNGENT Gas vapour heavier than air, may accumulate in confined spaces particularly at or below ground level Product is non flammable
3.FIRE /EXPLOSION HAZARD DATA Auto ignition TemperatureC Explosion sensitivity to impact Explosion sensitivity to static Electricity Hazardous combustion products Hazardous Polymerization Oxidiser Organic Peroxide Corrosive Material Others 4. REACTIVITY DATA
Flammability TDG Flammability LEL UEL None Flash Point C Flash Point C Combustible Liquid Flammable Material Pyrophoric Material Explosive Material
Chemical stability - Reacts with water to form corrosive acids. May react violently with Alkalies. Reacts with most metals in the pressure of moisture liberating hydrogen. An extremely flammable gas with water causes rapid corrosion of some metals.
Incompatibility with other material Reactivity Hazardous Reaction Prods. 5. HEALTH HAZARD DATA 9) Routes of Entry : Effects of Exposure/ Symptoms LD50 (oral Rat) NFPA Hazard Signals Permissible exposure limit Health 2 TLV (ACGIH) 2 ppm Flammability 2 STEL Reactivity 1 Odour Threshold Special IDLH
(SULPHUR DIOXIDE) 6. PREVENTIVE MEASURES Personnel Protective Equipment Keep Suitable chemically resistant protective clothing readily available for Handling &Storage Precautions
emergencies use. Do not smoke while handling product. Ensure adequate ventilation, Protect eyes, face & skin from liquid splashes. Keep the container below 50C in a well ventilated place. Use only properly specified equipment which is suitable for this product. Do not allow back feed into the container.
7. EMERGENCY/ FIRST AID MEASURES FIRE All known extinguishers can be used. If possible stop flow of product. Fire Extinguishing Media Use self contained breathing apparatus & chemically protective clothing. Special Procedure Unusual Hazards Exposure
First Aid Measures/Emergency Treatment Inhalation Toxic by inhalation. Remove victim to uncontaminated area wearing self contained breathing apparatus. Keep victim warm & rested. Call a doctor. Apply artificial respiration if breathing stopped. Inhalation : Ingestion is not considered a potential route of exposure. Skin/Eye Contact : May cause chemical burns to skin & cornea. Immediately flush eyes thoroughly with water for at least 15 min. obtain medical assistance. Ingestion :
Antidotes/Dosages : SPILLS Steps to be Taken Waste Disposal Method 8. ADDITIONAL INFORMATION/REFERENCES
--
Avoid discharge to atmosphere. Do not discharge into any place where accumulation could be dangerous, Do not discharge into areas where there is a risk of forming an explosive mixture with air. Waste gas should be flared through a suitable burner with flash back arrester. Gas may be scrubbed in alkaline solution under controlled conditions to avoid violent reaction. Toxic & corrosive gases formed during combustion should be scrubbed before discharge to atmosphere. Contact supplier if guidance is required.
11. Abbrevations
MATERIAL SAFETY DATA SHEET (TRI ETHYLENE GLYCOL) Regulated Identification TRI ETHYLENE Shipping name GLYCOL Codes/Label TRI ETHYLENE Hazardous Waste ID. NO.17 GLYCOL Hydrocarbon Hazchem Code (CH2OCH2 CH 2 OH)2 Hazardousclassification C.A.S.No. C.A.S. No. U.N. No. Hazardous Ingredients Physical state Vapour Pressure @35C pH Appearance Odour Others Liquid
2.PHYSICAL/CHEMICAL DATA Boiling Pt/Range 291.2C Melting/Freezing Pt. Vapour Density (Air =1) Specific Gravity (Water =1) Solubility, In water at 30C -5C 5.17 1.122 Soluble
Colourless
3.FIRE /EXPLOSION HAZARD DATA Auto ignition TemperatureC 371C Explosion sensitivity to -impact Explosion sensitivity to static -Electricity -Hazardous combustion products Hazardous Polymerization -Oxidiser NO Organic Peroxide NO Corrosive Material NO Others -4. REACTIVITY DATA Incompatibility with other material Reactivity Hazardous Reaction Prods.
0.9% 9.2% 176.6C(OC) (CC) YES YES NO NO Stable
Oxidizing materials
5. HEALTH HAZARD DATA Routes of Entry : Skin, Inhalation, Ingestion Emergency Treatment : Inhalation :Remove victim to fresh Air, Give Artificial Effects of Exposure/ respiration if breathing has stopped. oxygen if breathing is laboured. Ingestion : Give Symptoms
conscious victim water to drink and induce vomiting. Skin : Remove contaminated clothings & flush the affected area with plenty of water. Eyes : Irrigate with plenty of water. Seek medical aid immediately.
(TRI ETHYLENE GLYCOL) 6. PREVENTIVE MEASURES Personnel Protective Equipment Use protective outer clothing as required. Handling &Storage Precautions Should be stored in a cool, well ventilated place away from source of ignition & heat.
7. EMERGENCY/ FIRST AID MEASURES FIRE Fire Extinguishing Media Water spray, CO2 & DCP Special Procedure Water or Foam may cause breathing. Keep the containers cool by spraying water if exposed to heat or flame. Keep away from oxidizing materials. Unusual Hazards Exposure First Aid Measures/Emergency Treatment Inhalation : Remove the victim to fresh air. Give artificial respiration, if breathing has stopped & oxygen if breathing is laboured. Ingestion : Give conscious victim water to drink & induce vomiting. Skin : Remove contaminated clothing & flush the affected area with plenty of water. Eyes : Irrigate with plenty of water. Seek medical aid immediately. Antidotes/Dosages NA SPILLS Steps to be Taken Absorb the slippage in sand or earth. Flush the area with flooding water and then with caustic acid. Waste Disposal Method Spray in to a furnace. Incineration will become easier by mixing with more flammable solvent. 8. ADDITIONAL INFORMATION/REFERENCES
11. Abbrevations
MATERIAL SAFETY DATA SHEET (UREA) Regulated Identification Urea Fertilizer 46-0-0 Shipping name Not regulated by DOT Inorganic Chemical Codes/Label Fertilizer Urea Fertilizer 46-0-0 Hazardous Waste Hazchem Code Co(NH2)2 Hazardousclassification C.A.S.No. C.A.S. No. 57-13-6 U.N. No. Hazardous Ingredients Physical state Vapour Pressure @35C pH Appearance 1.335 Odour 67 gm/100 gm H20 @ Others 32F Flammability TDG Flammability LEL UEL Flash Point C Flash Point C Combustible Liquid Flammable Material Pyrophoric Material Explosive Material Chemical stability
2.PHYSICAL/CHEMICAL DATA Boiling Pt/Range Not applicable Melting/Freezing Pt. Vapour Density (Air =1) Specific Gravity (Water =1) Solubility, In water at 30C
Not Applicable Not listed While prills or granules
3.FIRE /EXPLOSION HAZARD DATA Auto ignition TemperatureC Not Applicable Explosion sensitivity to impact Explosion sensitivity to static Electricity Hazardous combustion products Hazardous Polymerization Will not occur Oxidiser Organic Peroxide Corrosive Material Others 4. REACTIVITY DATA Incompatibility with other material Reactivity Hazardous Reaction Prods.
Non flammable N/A N/A Non flammable
Stable
Conditions to avoid extremely high temps. Strong oxidizing agents. Prolonged contact may cause oxidation of unprotected metals.
Ingestion Minimal hazard under normal conditions and use. Ingestion of large quantities may cause gastrointestinal discomfort, vomiting weakness or other medically related problems. Inhalation Dusty conditions may cause mechanical aggravation to respiratory mucous membranes. Eye-contact Dust from this product may cause particulate discomfort to eyes. Skin Absorption Not normally absorbed through the Skin. Skin Contact Slight dermal abrasion is possible with prolonged contact, especially around cuffs and collars. Effects of Overdose Ingestion of large doses may cause diarrhea, nausea, abdominal cramps or formation of methemoglobinemia. Seek medical attention.
5. HEALTH HAZARD DATA Effects of Exposure/ Symptoms LD50 (oral Rat) Permissible exposure limit TLV (ACGIH) STEL Odour Threshold IDLH
Routes of Entry :
NE
MATERIAL SAFETY DATA SHEET (UREA) 6. PREVENTIVE MEASURES Personnel Protective Equipment Ventilation Protection Adequate ventilation. Eye protection In dusty
conditions, safety glasses with side shields or goggles may be necessary. Respiratory protection Approved dust respirator when necessary. Protective clothing Normal clean work clothing. State in a cool, dry area. Prevent spillage & separate from strong oxidizers. Use normal safety procedure & good personal hygiene. Keep out of reach of children.
Handling &Storage Precautions
7. EMERGENCY/ FIRST AID MEASURES FIRE Use media suitable to extinguish source of fire Fire Extinguishing Media Product is not combustible Special Procedure During extremely high temp fire conditions, the product may reach melting first and Unusual Hazards
decompose to release NH3, SOX, POX OR CN
Exposure First Aid Measures/Emergency Treatment

Ingestion: If large amount is ingested give 2-3 glasses of water and induce vomiting. Seek medical attention. Inhalation: Remove to fresh air. Seek medical attention if condition persists. Eyes : Flush eyes with running water for at least 15 mins. Seek medical attention if condition persists. Skin : Wash with soap and water. Seek medical attention if condition persists. Notes to Physician Consult standard literature. Treatment based on the sound judgement of the physician and the individual reactions.
Pick up with a shovel & broom & use as a fertilizer by applying to soil using good agricultural & soil management.
Environmental Precautions Keep out of water supplies, lakes, ponds, streams and rivers. This product is a fertilizer and may promote algae growth. Steps to be taken in case material is release or spilled - Keep from entering waterways. Sweep up material and place in suitable container for use as a fertilizer or for disposal.
9. MANUFACTURERS/SUPPLIERS DATA J.R. Simplot Company, Po. Box 912, Pocatello, ID -83204 Contact Person in case of Emergency Name of Firm 10. DISCLAIMER
This information relates to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is to the best of our knowledge & belief, accurate & reliable as of the date complied. However, no representation, warranty or guarantee is made as to its accuracy reliability or completeness. It is the users responsibility to satisfy themselves as to the suitability & completeness of such information for their own particular use. We do not accept liability for any loss or damage that may occur from the use of this information nor do we offer warranty against patent infringement.
11. Abbrevations

(216871532) MSDS

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OIL & NATURAL GAS CORPORATION LIMITED HAZIRA PLANT, SURAT

MATERIAL SAFETY DATA SHEET (MSDS)

MATERIAL SAFETY DATA SHEET

SL NOS. AA) 1 2 3 4 5 6 7 BB) 8 9 10 CC) 11 12 13 14 15 16 17 18 19 20 21 DD) 22 23

N/A, this is a mixture

N/A C.A.S.No. 112-34-5

1 1.01 Soluble (100%)

NFPA Hazard Signals Health 0 Flammability 0 Reactivity 0 Special -

Antidotes/Dosages : SPILLS Steps to be Taken Waste Disposal Method

Hydrocarbon Mixture C.A.S.No.

YES YES YES YES

NFPA Hazard Signals Health 0 Flammability 2 Reactivity 0 Special -

Handling &Storage Precautions

7. EMERGENCY/ FIRST AID MEASURES : Inhalation

Antidotes/Dosages : SPILLS Steps to be Taken Waste Disposal Method 8. ADDITIONAL INFORMATION/REFERENCES

1. CHEMICAL IDENTITY Chemical Name Synonyms

Chemical Classification Formula Hazardous Ingredients 1. Chorine 2.

No 2 Not Pertinent % Not Pertinent % Not Pertinent %

Not Pertinent (CC) NO NO NO NO Stable

Toxic products are generated when combustible burn in Cl

NFPA Hazard Signals Health Flammability Reactivity Special 3 0 0 -

MF=16 HC = -BTU/lbx103 Molecular Weight 70.91 1 ppm = 2.90 mg/m3

MATERIAL SAFETY DATA SHEET IDLH 10 ppm

Antidotes/Dosages SPILLS Steps to be Taken Waste Disposal Method

NFPA Hazard Signals Health Flammability Reactivity Special -

Waste Disposal Method

Antidotes/Dosages SPILLS Steps to be Taken Waste Disposal Method

Chemical stability - Stable

Not available 10ppm Not 14 mg/m3 0.5 ppm 14 mg/m3

NFPA Hazard Signals Health 3 Flammability 4 Reactivity 0 Special -

MATERIAL SAFETY DATA SHEET (HYDROCHLORIC ACID) Regulated Identification

3.FIRE /EXPLOSION HAZARD DATA

Chemical stability - Stable

NFPA Hazard Signals Health Flammability Reactivity Special -

Chemical Classification Formula Hazardous Ingredients 1. Methyl Alcohol 2.

YES 3 1.3% 6% 55C TO 100C NA (OC) YES YES NO YES Stable

LD50 (oral Rat) Permissible exposure limit TLV (ACGIH) STEL

5 to 15 g/kg Not Listed 5 mg/m3 Not Listed

NFPA Hazard Signals Health 1 Flammability 2 Reactivity 0

MF=16 HC = 18.7 BTU/lbx103 Molecular Weight 226.43

Antidotes/Dosages SPILLS Steps to be Taken Waste Disposal Method

3.FIRE /EXPLOSION HAZARD DATA

Chemical stability - Stable at room temp. decomposed if heated

LD50 (oral Rat) Permissible exposure limit TLV (ACGIH) STEL

60 mg/Kg 0.1 ppm (Skin) 0.1 ppm (Skin)

NFPA Hazard Signals Health 3 Flammability 3 Reactivity 2

1 ppm Data not available

NFPA Hazard Signals Health 0 Flammability 2 Reactivity 0 Special -

PETROLEUM GAS LIQUEFIED Flammable gas , Class-2 ID NO. 5 2 WE

YES 3 1.9% 9.5% (OC) 104.4(CC) YES YES NO NO Stable

NFPA Hazard Signals Health 1 Flammability 4 Reactivity 0 Special -

Antidotes/Dosages SPILLS Steps to be Taken Waste Disposal Method

1. CHEMICAL IDENTITY Chemical Name Synonyms

Trade Name Chemical Classification Formula Hazardous Ingredients 1. Methyl Alcohol 2.

NFPA Hazard Signals Health 2 Flammability 3 Reactivity 0 Special 0

MF=16 HC = 8.6 BTU/lbx10-3 Molecular Weight 32.1 Conversion

Antidotes/Dosages SPILLS Steps to be Taken Waste Disposal Method

Colourless to light yellow

NFPA Hazard Signals Health 2 Flammability 1 Reactivity 1 Special -

MATERIAL SAFETY DATA SHEET IDLH

FIRE Fire Extinguishing Media

Special Procedure Unusual Hazards Exposure First Aid Measures/Emergency Treatment

Antidotes/Dosages : SPILLS Steps to be Taken Waste Disposal Method

3.FIRE /EXPLOSION HAZARD DATA