Compound Name Callislignan A (1) It was isolated as a yellowish gum.

Its molecular Formula of C19H2O4

Structure

At 3392 cm_1 . Inspection of 1H NMR spectroscopic data in Combination with COSY correlations indicated that 1 contained resonances assigned to two meta coupled aromatic protons (H 6.67, H-4; H 6.65, H-6), methine (H3.29, H-3) and oxy-methine protons (H 4.97, d, H-2) that were trans coupled (9.6 Hz) (Li et al.,H1997), an aliphatic methyl doublet (H 1.26, d, J = 6.6 Hz) that was vicinal to H-3, a (E)-propenyl group (H 6.23, dq, H-1' ; H 5.94, dq, H-2'; H1.72, dd, H-3'), a 1,2,4-trisubstituted phenyl group (H 6.76 d, J = 8.4, H-5''; H 6.84, dd, J = 8.4, 1.8, H-6''and H 7.03, d, J = 1.8, H-2''),an aromatic methoxyl group (H 3.77, 3'' OCH3) and two phenolic Protons (H 7.85, 7-OH; H 7.63, 4'' -OH).
Callislignan B

The H NMR spectrum (Table 2) contained resonances that were assigned to two 1,2,4-trisubstituted phenyl groups (ring A: H 6.81 (d, H-5), H 6.86 (dd,H-6) H 6.93(d,H-2'), and ring B: H 6.90(d,H-5') H 6.74 (dd,H-6'), H 6.96 (d,H-2). A doublet at H 4.65, a quartet of doublets at H 4.05 and a doublet at H 1.09 were assigned to a benzylic oxymethine proton (H-7),an oxymethine proton (H-8) and a methyl proton (8-

CH3),respectively.Analysis of COSY correlations and coupling constants indicated that H-7 was vicinal to H-8 and their mutual coupling constant of 8.4 Hz suggested that these two protons possessed a threo-relative configuration (lit. J=8.0 Hz,threo;J=3.0,erythro)(Conserva et al., 1990). The presence of a (E)-propenyl group was assigned from signals at H 6.30(dq,H-7'), H 6.86 (dq, H-8') and H 1.85 (dd,H-9'). Two 3JCH correlations from both H-2' and H-6' to C-4' (c 144.4) and C-7'(C 130.4) revealed that the propenyl side chain was attracted to ring B and was para to C-4'.An HMBC correlation between H-8 and C-4' (C 144.4) and C-7 (C 78.3) and between H-7 and C-2 (c 113.2) and C-6 (c 118.9) suggested that An ether bond between C-8 and C-4' linked the two benzylpropanoid groups.A methoxyl group which resonated at H 3.88 was attached at C-3 of ring A since HMBC correlations were observed between 3-OCH3,H-2 and H-5 and C3(c146.8).Accordingly the structure was identified as threo-1-(4hoydroxy-3-methoxyphenyl)-2-(2-hydrox y-4-(E)propenylphenoxy-1propanol.

Betulinic Acid

Betulinic acid: colourless solid; melting point, 295-298 C. The H1 NMR [H: 0.652,0.749,0.900,0.966,0.977 and 1.649],vinyl methyl [H: 1.671 9br d, J= 0.5 Hz)],a secondary carbinol [H: 3.158 (dd, J=9.5,6.0 Hz)] and [H: 2.947 ( ddd,J=9.5, 6.0 Hz,0.5 Hz)], an exomethylene group [H :4.557( H1, d, H : J=0.4 Hz)] and [H :4 .659(1h,d,j=0.4 Hz)].This H1 NMR data (CDCL3) and TLC analysis were in agreement with the data obtained for betulinic acid.(C30H48 O3 ). Another data:

Another compound: Betulin

Another Compound: Betulonic acid

2.)another compound

Lup 20(29)-en-3-ol

Another data: Lup 20(29)-en-3-ol

3-Lup-20(29)-en-3-yl acetate (2):

1,2,3,4,5,6-hexa-O-acetyldulcitol (3).

Alphitolic acid

Oleanic Acid

Another compound:

Ursolic Acid

Another data of Ursolic Acid

Another compound:

Morolic acid 3-O-caffeate

signal overlapping]

Next 3 compound solvent system is pyridine:

30-hydroxyalphitolic acid

Morolic acid 3-O-caffeate

Number 8 compound

Urosilic acid 3-O-caffeate

Compound no 9

Next 4 compounds solvent system is Methanol 1.Pyracrenic acid:

Pyracrenic acid (2) 1H-NMR (400 MHz, CD3OD) :7.52 (1H, d, J= 15.8 Hz, H-7'), 7.03 (1H, d, J = 2.0Hz, H-1'), 6.94 (1H, dd, J =

2.Arjunolic acid:

3.Catechin:

5.Piceatannol