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(10-10)
( ) ( )
2 1 2 1
1
o
rev o H
H
T
W T S S U U Q
T
| |
= +
|
\ .
( )
12 12 2 1
H
rev o o net o gen
H
Q
I W W T S S T S T S
T
(
= = = A =
(
Reversible Process with
Multiple Thermal
Reservoirs
W
rev
(U
2
U
1
)
(S
2
S
1
)
Q
k
T
k
T
o
Q
ok
W
HPk
Q
1
T
1
T
o
Q
o1
W
HE1
UPME ME 63 ENQ 1/06 106
10.1.2 OPEN SYSTEM REVERSIBLE WORK AND IRREVERSIBILITY
Consider the control volume undergoing an ACTUAL process during the time interval
t
1
to t
2
described by the following:
1. Heat transfer Q
1
, , Q
k
from or to thermal reservoirs at T
1
, , T
k
respectively ; each Q
k
is transferred across a portion of control mass
boundary at local temperature T
j
not necessarily equal to T
k
.
2. Change of state from 1 to 2 experiences (U
2
U
1
)
cv
, (S
2
S
1
)
cv
, etc.
3. With inlet mass flow streams m
i1
,, m
ix
at inlet states 1, ,x respectively
4. With exit mass flow streams m
e1
,, m
ey
at exit states 1, ,y respectively
5. No change in KE and PE of the control volume
6. Does a total amount of actual work W
CV
1
st
Law:
( )
2 2
2 2 1 1
1 1
1 1
2 2
y x
k i i i i e e e e cv
Q m h V gz m h V gz m u mu W
| | | |
+ + + = + + + +
| |
\ . \ .
Solving for the actual work gives
( )
2 2
2 2 1 1
1 1
1 1
2 2
y x
cv k i i i i e e e e
W Q m h V gz m h V gz m u mu
| | | |
= + + + + +
| |
\ . \ .
(10-11)
2
nd
Law:
2 2 1 1
1 1
y x
k
i i e e gen
k
Q
m s m s ms m s S
T
| |
= + +
|
\ .
(10-12)
Actual Process
m
i1
m
ix
m
e1
m
ey
Q
1
T
1
Q
k
T
k
W
cv
(U
2
U
1
)
(S
2
S
1
)
T
j1
T
jk
cv
UPME ME 63 ENQ 1/06 107
Consider now the control volume undergoing a REVERSIBLE process during the time
interval t
1
to t
2
described by the following:
1. Same heat transfer Q
1
, ,Q
k
from or to thermal reservoirs at T
1
, ,T
k
respectively ; each Q
k
is transferred across a portion of control mass
boundary at local temperature T
j
not necessarily equal to T
k
.
For Q
1
,,Q
k
to be transferred reversibly, reversible heat engines and heat
pumps are used. These heat engines and heat pumps will be inside the
control mass boundary and reject/absorb heat Q
o1
,,Q
ok
respectively
to/from the surrounding thermal reservoir at temperature T
o
. The heat
engines reversible work output W
HE1
and heat pumps reversible work input
W
HPk
are part of the control volume total reversible work W
rev
.
For W
rev
to be maximum,
W
HE1
should be maximum IQ
o1
I should be minimum for a given Q
1
T
o1
should be minimum.
Although T
o1
is arbitrary, T
o1
is usually chosen to be the lowest
naturally occurring reservoir temperature.
W
HPk
should be minimum IQ
ok
I should be maximum for a given Q
k
, (Q
k
= Q
ok
+W
HPk
) T
ok
should be maximum.
Although T
ok
is arbitrary, T
ok
is usually chosen to be the
highest naturally occurring reservoir temperature.
A convenient choice of the reservoir temperatures T
o1,
,
T
ok
is the
ambient or atmospheric temperature T
o
. T
o1
,,T
ok
=T
o
2. Same change of state from 1 to 2 experiences same (U
2
U
1
), (S
2
S
1
)
3. With same inlet mass flow streams m
i1
,, m
ix
at inlet states 1,,x
respectively ; with same exit mass flow streams m
e1
,, m
ey
at exit states
1,,y respectively
Reversible Process
m
i1
m
ix
m
e1
m
ey
W
rev
(U
2
U
1
)
(S
2
S
1
)
cv
T
1
T
o1
Q
o1
W
HE1
Q
1
T
k
T
ok
Q
ok
W
HPk
Q
k
UPME ME 63 ENQ 1/06 108
4. No change in KE and PE of the control volume
5. Does a total amount of reversible work W
rev
1
st
Law:
( )
2 2
2 2 1 1
1 1
1 1
2 2
y x
k ok i i i i e e e e rev
Q Q m h V gz m h V gz m u mu W
| | | |
+ + + + = + + + +
| |
\ . \ .
Solving for the reversible work gives
( )
2 2
2 2 1 1
1 1
1 1
2 2
y x
rev k ok i i i i e e e e
W Q Q m h V gz m h V gz m u mu
| | | |
= + + + + + +
| |
\ . \ .
(10-13)
2
nd
Law:
2 2 1 1
1 1
y x
k ok
i i e e
k ok
Q Q
m s m s ms m s
T T
| | | |
= + +
| |
\ . \ .
(10-14)
Since T
o1
,,T
ok
= T
o
, Eq.(10-14) is multiplied by T
o
and solved for Q
ok
giving
( )
2 2 1 1
1 1
y x
o
ok o o i i e e k
k
T
Q T m s m s T ms m s Q
T
| | | |
=
| |
\ . \ .
(10-15)
Substituting Eq. (10-15) into Eq. (10-13) yields
(10-16)
The reversible work can also be grouped and written as
(10-17)
The irreversibility is then
(F)
(10-18)
( ) ( ) ( )
2 2 1 1 2 2 1 1 rev o o e e i i
W T m s ms m u mu T m s ms = +
2 2
1 1
1 1
1
2 2
y x
o
e e e e i i i i k
k
T
m h V gz m h V gz Q
T
| | (
| | | |
+ + + + +
| | | (
\ . \ .
\ .
2 2
1 1
1 1
2 2
y x
rev i i i i o i e e e e o e
W m h V gz T s m h V gz T s
| | | |
= + + + +
| |
\ . \ .
( ) ( )
1 1 1 2 2 2
1
o
o o k
k
T
m u T s m u T s Q
T
| |
+ +
|
\ .
( ) ( )
( )
12 2 2 1 1
k
rev cv o o e e i i o
k
o cv surr o net o gen
Q
I W W T m s m s T m s ms T
T
T S S T S T S
| |
= = +
|
\ .
= A + A = A =
UPME ME 63 ENQ 1/06 109
10.1.3 USEFUL WORK
In many instances, part of the total actual work done by (or on) the control
volume W
cv
, which includes boundary expansion (or contraction) is work done on
(or by) the surroundings W
surr
. The surroundings is assumed to be at constant
pressure P
o
. The rest of the actual total work done by (or on) the control volume
can be regarded as its useful work, W
u
.
Useful Work W
u
, is defined as the difference between the total work actually
done by (or on) the control volume W
cv
and the work done on (or
by) the surroundings at pressure P
o
as the control volume
boundary expands (or contracts).
(10-19)
Since
surr cv
V V A = A , then
(10-20)
- Recognizing useful work W
u
is part of developing the concept of and
determining expressions for availability or exergy.
u cv surr cv o cv
W W W W P V = A
u cv o surr
W W P V + A
UPME ME 63 ENQ 1/06 1010
A rate expression for the useful work for a general control volume undergoing an
actual process is now developed. Consider the control volume below:
1
st
Law:
2 2
1 1
2 2
cv
cv cv i i i i e e e e
dE
Q W m h V gz m h V gz
dt
| | | |
= + + + + +
| |
\ . \ .
(10-21)
where
cv k
Q Q total control volume heat transfer = =
(10-22)
. .
cv boundary mechanical electrical
W W W W actual total work of c v = + + =
(10-23)
The control volume work in terms of the useful work from Eq. (10-19) is
cv
cv u o
dV
W W P
dt
= +
(10-24)
Substituting (10-22) and (10-24) into (10-21) gives,
2 2
1 1
2 2
cv cv
k u o i i i i e e e e
dE dV
Q W P m h V gz m h V gz
dt dt
| | | |
= + + + + +
| |
\ . \ .
(10-25)
2
nd
Law:
cv k
i i e e goen
k
dS Q
ms m s S
dt T
= + +
(10-26)
Multiplying (10-26) by the surrounding temperature T
o
results into
cv k
o o i i o e e o o goen
k
dS Q
T T ms T m s T T S
dt T
= + +
(10-27)
Subtracting (10-27) from (10-25) and re-grouping give the expression for:
General control volume
undergoing an actual process
m
i
m
e
W
cv
= W
boundary
+ W
mechanical
+ W
electrical
W
boundary
W
mechanical
W
electrical
dE
cv
/ dt
cv
dS
cv
/ dt
Q
k
T
k
T
k
Q
1
T
1
T
1
UPME ME 63 ENQ 1/06 1011
Control Volume (Open System) USEFUL WORK for an ACTUAL Process
(10-28)
The useful work for an internally reversible process is now obtained by noting that
the entropy generation S
gen
= 0 for such a process. Thus
Control Volume (Open System) USEFUL WORK for a REVERSIBLE Process
(10-29)
The actual useful work and reversible useful work are thus related as follows
, u rev u
W W s
(10-30)
The irreversibility can be expressed in terms of either total work
12 rev cv
I W W =
(10-31)
or in terms of useful work
12 , rev u u
I W W =
( )
2 2
1 1
2 2
1
u i i i i o i e e e e o e
o o
o cv
k o gen
k
W m h V gz T s m h V gz T s
d E PV T S
T
Q T S
T dt
| | | |
= + + + +
| |
\ . \ .
+
| |
+
|
\ .
( )
2 2
,
1 1
2 2
1
rev u i i i i o i e e e e o e
o o
o cv
k
k
W m h V gz T s m h V gz T s
d E PV T S
T
Q
T dt
| | | |
= + + + +
| |
\ . \ .
+
| |
+
|
\ .
UPME ME 63 ENQ 1/06 1012
10.2 AVAILABILITY
Availability is the maximum work potential of a system at a given state determined
by letting the system undergo a reversible process towards a state of equilibrium with
the surroundings (called the dead state) while any heat transfer is solely with the
surroundings.
- Availability of the system in the dead state is zero.
- The availability of a system depends on both the state of the system and
conditions of the surroundings. It is a property of the system-surroundings
combination.
- The availabilities of both non-flowing mass (i.e., inside the control volume)
and flowing mass (i.e, mass streams entering or leaving the control volume)
are identified and corresponding expressions developed.
- Availability can be transferred. In general, availability transfers associated
with mass flow, heat transfer, and work interaction occur during a process.
10.2.1 THE DEAD STATE
The dead state refers to the state of a system when it is in thermal, mechanical, and
chemical equilibrium with the surroundings.
At the dead state,
- no further change of state of the system can occur spontaneously no
further work can possibly be done
- the velocity of a closed system or a fluid stream is zero, potential energy is
also zero
- properties of the system are given the subscript o and are evaluated at the
surrounding pressure P
o
and temperature T
o
so that
P = P
o
u = u
o
= u)
To,Po
V = V
o
= 0
T = T
o
h = h
o
= h)
To,Po
z = z
o
= 0
v = v
o
= v)
To,Po
s = s
o
= s)
To,Po
- availability of the system is zero
UPME ME 63 ENQ 1/06 1013
10.2.2 AVAILABILITY OF NON-FLOWING MASS
The availability (or exergy) of NON-FLOWING mass, such as in a closed system or
that inside the control volume, at a given state is the maximum useful work W
MAX,u
that may be obtained from a system-surroundings combination as the system
proceeds from the given equilibrium state to the dead state by a process where any
heat transfer occurs only with the surroundings.
Consider the closed system at a given state (P, T, V) undergoing a process towards
the dead state while interacting only with the surroundings:
The useful work for a control volume is
( )
2 2
1 1
2 2
1
u i i i i o i e e e e o e
o o
o cv
k o gen
k
W m h V gz T s m h V gz T s
d E PV T S
T
Q T S
T dt
| | | |
= + + + +
| |
\ . \ .
+ | |
+
|
\ .
- m
e
and m
i
are zero for a closed system
- The system does maximum useful work if it goes to the dead state through a
reversible process S
gen
= 0
- Heat exchange only with the surroundings T
k
= T
o
so that third term on
RHS is zero
Evaluating the above equation over t from the given state to the dead state gives the
maximum useful work
( ) ( )
, , MAX u rev u o o o o o
W W E U P V V T S S = = +
This maximum useful work is therefore the availability of the closed system and is
denoted by u at any given state (P, T, V).
W
u
= W
cv
- PoV
Closed System
at T, P, V
Q
Closed system at a given state
and exchanging heat only with
the surroundings
Surroundings
at T
o
, P
o
UPME ME 63 ENQ 1/06 1014
Thus,
Closed System, Control Mass, or Non-Flow Availability
On a per unit mass basis,
The change in availability of a closed system as it undergoes a process from state 1
to state 2 is then
The reversible work in terms of availability is
The irreversibility in terms of availability is
( ) ( ) ( ) ( )
o o o o o o o o o o o o
E U P V V T S S E PV T S U PV T S u + = + +
( ) ( ) ( ) ( )
o o o o o o o o o o o o
e u P v v T s s e Pv T s u Pv T s | + = + +
( ) ( ) ( )
( ) ( )
2 1
2 1 2 1 2 1
2 2 2 1 1 1
o o
o o o o
E E P V V T S S
E PV T S E PV T S
Au = u u
= +
= + +
( ) ( )
1 2 2 1
1
o
rev o k
k
T
W P V V Q
T
(
| |
= u u + +
( |
\ .
( ) ( )
12 1 2 2 1 12
1
o
o k
k
T
I P V V Q W
T
(
| |
= u u + +
( |
\ .
UPME ME 63 ENQ 1/06 1015
10.2.3 AVAILABILITY OF FLOWING MASS
The availability (or exergy) of fluid in steady flow, (i.e., mass stream entering or
leaving the control volume), also known as stream availability, is the maximum
useful work W
MAX,u
that may be obtained as the flowing fluid proceeds from a given
equilibrium state to the dead state by a process where any heat transfer occurs only
with the surroundings.
An expression for the stream availability can be developed by considering a control
volume undergoing a steady-state steady flow process.
The useful work for a control volume is
( )
2 2
1 1
2 2
1
u e e e e o e i i i i o i
o o
o cv
k o gen
k
W m h V gz T s m h V gz T s
d E PV T S
T
Q T S
T dt
| | | |
= + + + +
| |
\ . \ .
+ | |
+ +
|
\ .
- For the SSSF process,
( )
0
o o
cv
d E PV T S
dt
+
=
- The maximum useful work is obtained if the
a) process is reversible T
o
S
gen
=0
b) exit stream is at the dead state h
e
=h
o
, V
e
=0, z
e
=0, s
e
=s
o
The maximum useful work is then
( )
2
,
1
0 0 1
2
o
MAX u e o o o i i i i o i k
k
T
W m h T s m h V gz T s Q
T
| |
| |
= + + + +
| |
\ .
\ .
- Note that only the first two terms on the RHS are associated with the mass
streams while the last term is associated with the control volume.
- Dropping the subscripts for the inlet streams to denote any inlet state, the
stream availability per unit mass is then defined as
Flow or Stream Availability
The control volume reversible work for a given process can be expressed in terms of
availability as follows
( ) ( ) ( )
2 2
1 1
2 2
o o o o o o o o
h V gz T s h T s gz h h T s s V gz
| |
+ + + = + +
|
\ .
( ) ( )
1 1 2 2 1 1 2 2
1
o
rev i i e e o k
k
T
W m m m m P m m Q
T
| | v v
| |
= + +
|
\ .
UPME ME 63 ENQ 1/06 1016
10.2.4 FLOW OF AVAILABILITY OR EXERGY
Availability or exergy transfer is associated with mass, heat, and work interactions
during a process. The availability may be thought of as flowing during these
interactions.
Availability Flow with Heat Transfer
For heat transfer Q
R
from a constant temperature source at T
R
, maximum work is
obtained by transferring Q
R
using a reversible heat engine rejecting heat to the
surroundings at T
o
.
The availability transfer is equal to the work output of the reversible heat engine.
For heat transfer Q
12
that takes place over varying temperature, e.g., in a constant-
pressure process shown below,
the availability transfer is
,
1
o
Q R R Carnot R
R
T
Q Q
T
q
| |
u = =
|
\ .
2
0
,12 12
1
1
Q o
T
Q Q T S
T
o
| |
u = = A
|
\ .
}
UPME ME 63 ENQ 1/06 1017
Availability Flow with Work Interaction
Work interactions by concept are reversible at the point where they occur at the
system boundary.
The availability transfer associated with work transfer equals the value of the useful
work itself.
Availability Flow with Mass Flow
The availability flow associated with mass flow is equal to the stream availability .
10.3 EXERGY BALANCE
The concepts of reversible work, availability, and irreversibility can be expressed in
a unified concept through the formulation of an exergy balance for a control volume
undergoing a process.
For the mass inside the control volume, its exergy at a given state is
( ) ( ) ( )
o o o o o
m m e e Pm v v T m s s | u = = +
The rate of change of exergy becomes
( ) ( ) ( )
o o o o o o o
d me d mv d ms
d dm dm dm
e P Pv T T s
dt dt dt dt dt dt dt
u
= + + (A)
Since
( ) ( ) ( )
, ,
cv cv cv
o o o o
d me d mv d ms
dE dV dS
and h e Pv
dt dt dt dt dt dt
= = = = + ,
Eq. (A) can be written as
( )
cv cv cv
o o o o o
dE dV dS d dm
P T h T s
dt dt dt dt dt
u
= + (B)
The continuity equation for the control volume is
i e
dm
m m
dt
=
(C)
1
st
Law for the control volume:
2 2
1 1
2 2
cv
k cv i i i i e e e e
dE
Q W m h V gz m h V gz
dt
| | | |
= + + + + +
| |
\ . \ .
(D)
UPME ME 63 ENQ 1/06 1018
2
nd
Law for the control volume:
cv k
i i e e cv gen
k
dS Q
ms m s W S
dt T
= + +
(E)
Substituting (C), (D), (E) into (B) yields
( )
2 2
1 1
2 2
1
cv
i i i i o i e e e e o e o o o i e
o cv
k cv o o gen
k
d
m h V gz T s m h V gz T s h T s m m
dt
T dV
Q W P T S
T dt
u
| | | |
( = + + + +
| |
\ . \ .
| |
| |
+
| |
\ .
\ .
(F)
Or
(G)
The above exergy balance equation indicates that for a control volume undergoing a
process, the net change in exergy of the control volume
cv
d
dt
u
= net exergy change in the control volume
is equal to the sum of the following
i i e e
m m
net exergy flow due to mass flow
1
o
cov
T
Q
T
| |
|
\ .
net exergy flow due to heat transfer
cv
cv o
dV
W P
dt
| |
|
\ .
Compressor or Pump
, /
i e
II comp pump
actual
w
q
=
Heat Exchanger
( )
( )
1 2 1
,
3 3 4
II HX
m
m
q