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JABATA N PELAJARAN JOHOJ PAPER 1 (KERTAS 1) 'R JABATAN PELAJARAN JOHOR JABATA N
JABA TAN PELAJA RA N JOHOA JnOM m. r "~Jn~" Jvu ciR JABATAN PELAJARAN JOHOR JABATAN
JABATAN PELAJARAN MULTIPLE-CHOICE (ANEKA PILIHAN) . PELAJARAN JOHOR JABATA N
JABATA N PELAJARA N . PELAJA RA N JOHOR JABATA N
JABATAN PF.f.A.JARAN.I()H()R .JARATAN PF.1A.JA RAN .f()H()R.lA RATA N PF.f.A.JARA N JOHOR JABATAN
JABATAA One hour and forty-five minutes (Satu jam empat puluh lima mlnit) IOHOR JABA,TAN
JABATAfI _ __. ________ . __ ___ _• __ ._. __ . __ . __...... __. __ .. _ ___ .. _ .. _.... _ __.....__... JOHORJABATAN
JABATAN PELAJARAN JOHOR JA BA TAN PELAJARAN JOHOR JABATAN PELAJARAN JOHOR JABATA N
Instructions to candidates:
DO NOT OPEN TIllS QUESTION PAPER UNTIL YOU ARE TOLD TO DO SO.
There are rthy questions in this paper. For each question, four suggested answers are given.
Choose Doe correct answer and indicate it on the multiple-choice answer sheet provided.
STPM962/1
*This question paper is CONFIDENTIAL until the examination is over. CONFIDENTIAL"
»
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CONFIDENTIAL" 2
Section A
Four suggested answers labelled A, B, C and 0 are given for each question. Choose one
correct answer. .
1. Which of the following sketches show part of the mass spectrum of the refrigerant,
CF2CI 2? [The isotopes are : 12C , 18F t M et 31CO
11 (, I
A c
mle J'IIlio
120 122 [24 120 122 124
2. The unit cell of a metal M is shown below. Given the volume of the unit cell is V, cm 3 and
the volume of 1 mol of M atoms is V 2 cm 3 • What is the value of the Avogadro constant?
g.
(, 'f
-:i ./' .. • ../
';5 j .
..... .....
,
e n' h. . o t-
(J'~ ..
../ • /'
A. V,/V, 01,/V,)x4
CONFIDENTIAL' 4
3. Antimony Sb, is in Group 15 of the Periodic Table. The ion below has a square-based
I
pyramidal shape.
1-1 ; He F
.-
l\ Be 60 Co N;o.Fl Ne
,~J~F
F~~
Deduce the total number of electrons around the antimony atom and the value of n?
Total number of elec;trons value of "
10 1
10 2
12 1
12 2
)( n(n-t) -\\ 0
. ((I - I) ~').
\/ (\-+ \ 4. Gaseous particle X has a proton number n and a charge of +1 . Gaseous particle Y has a
proton number of (0+1) and is isoelectronic with X. VVhich statement correctly describes X and
Y?
0) X has a larger radius than Y
B X requires more energy than Y when the second electron is removed f
from each particle
c X releases more energy than Y when an electron is added to each particle
6. o H
6,-11 Y '" (J
HLC~LH
I
H
VVhich of the following correctly describes the approximate values of the bond angles in
the molecule above?
6 y (J
CONFIDENTIAL' , 6
6. In which pair of mo~utes is the permanent dipole in molecule I greater than that in
molecule II?
I II
CI CI
"
CH, CI
C=C/' "I C= C'\ /'
/' '\
CH, CH, CI CH,
B CH,CHCI,
H CI
HC. C H
Ii ~I
CI
C ~CI
CI
~
CI
CI
~ CI
CI
CONFIDENTIAL', 8
------ y
/ /' - - - --x
8. In the diagram above, curve X was obtained by observing the decomposition of 100 em3 of
1.0 mol dm" hydrogen peroxide, catalysed by manganese (IV) oxide.
Which alteration to the original experimental condition would produce curve Y?
A Adding water
® Adding some 0.1 mol dm" hydrogen peroxide
C Using less manganese(lV) oxide
D Lowering the temperature
9. The graph below shows the variation of pH value with volume of base added in an acid·
base titration .
,.
13
12
11
10
•
8
pH 7
,
6
•
J
2
1
.L-_ _-----~---
Volume of base addcdIcm 3
Which of the following statements is not true about the mration above?
'" A The acid and base used in the titration may probably be ethanoic acid
and sodium hydroxide respectively.
v B The pK. of the acid used is equal to 4.7.
C The sa~ formed in the titration undergoes hydrolysis to produce OH'
ions.
® A suitable indicator for the above titration is methyl orange',
, - - - - - - - -- -
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CONFIDENTIAL' 10
10. The pH of a 1.0 mol dm-3 solution of a weak monobasic acid is 5. What is the
dissociation constant of the weak acid?
A 1.0 x llr mol dm"
B 1.0 x 10-' mol dm"
@ 1.0 x 10. , 0 mol dm,3
o 1.0 x 10". mol dm-3
Which of the following aqueous solutions when added would cause the system at
equilibrium to shift to the left?
< •
A Ammonium chloride
B Sodium carbo~ate
C Sodium ethanoate .
-'-
'·:T ...
@ Ammonia ~
..". :
12. When the system CI,(g) + PCI,(g) ........ PCI,(g) is in equilibrium at 600'C, at 1
atm pressure, the value of the equilibrium constant , Kp is 30.
VVhat is the valUe of ~ at a pressure of 2 atm at the same temperature?
.S:.
\
A 20 ® 30 C. 60 D 100
13. A solute, S exists in the same molecular state when dissolved in ether and water.
When the two solutions are in equilibrium, the concentration of solute S in ether solution is 6
times higher than that of the aqueous solution. A solution containing 14.0 9 of 5 in 240 em' of
water is extracted with 40 cm 3 of ether. Calculate the total mass of S extracted from water.
A 2.0g
'J 8,.6 c '
B 6.0g ,
'(
© 7.0g
'+O ~
D ,
8.0 9
2'10 I~. 'I( " {
b
fif?'
I;!
>I = \3 >(
,~ " lL
Ilx - 14 - l(
·3>" it
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a mixture of
Under standard conditions, the cell a.m.t would be 3.61 V , but in the body a potential of 3.25 V
is more usual. What is the best explanation of this lower a.m.f?
17. The enthalpy change for two reactions are given by the following equations.
18. Which value would be required to estimate the lattice energy for the hypothetical ionic
compound. MgH?
® The electron affinity of hydrogen
B The first ionisation energy of hydrogen
C The magnesium-hydrogen bond energy
o The standard enthalpy change of formation of MgH z
x+ \
2
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,
!
,
c., 1-\ I .. I 0,- _~) ~CO"L ... ~ H.O
CONFIDENTIAL' .;;. 16
19. 4.0 9 of a hydrocarbon required 16.0 9 of oxygen for complete combustion and 9.0 9 of
water was produced in the reaction. What was the mass of carbon dioxide produced?
[Relative atomic mass of 0=16, C=12, H=lJ
A Ug B Mg
@ 11 .0 9 0 22.0 9
Substance pI<"
NH, 4.75
CH,NH, 3.36
CH 3CH2 NH2 3.27
CeHsNH2 9.38
22. The process of chemical etching consists of partially dissolving a metal in a suita~e
solvent. By careful masking of the metal, it is possible to produce a pattern in or on the metal.
Which of the following aqueous solutions could be used to etch a pattern in aluminium?
A Ethanoic acid
B Dilute nitric acid Ht NO,-
@) Sodium hydroxide No' OH-
0 Concentrated nitric acid
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CONFIDENTIAL' 18
23. Which of the following statements regarding lead(lV) oxide is not true?
- A It is amphoteric
.., 8 It easily decomposes when heated
C It has ionic bonding with covalent characteristics.
@ It is formed by heating strongly lead(lI) oxide in oxygen
24. Which reaction of ammonia does not involve the non·bonding pair of electrons on the
nitrogen atom?
A NH,(g) + CH,I(g) _ CH,NH; r (s)
B NH,(g) + HCI(g) _ NH,CI(s)
C 2NH,(I) + 2Na(s) _ 2NaNH,(s) + H,(g)
® 2NH,(aq) + Ag'(aq) _ [Ag(NH,)'J'(aq)
25. p. Q, and R are three elements in Group 17. a is a solid at room temperature. P- ion is
the weakest reducing agent among P-, a- and R- .
What is the arrangement of the elements in increasing intensity of colour?
® P. R.Q
B R. Q, P
C P,Q, R
,''..
D Q,R, P
A i:
""
Which of the following complexes does not exhibit optical isomerism?
26.
A [Cr(C,O,),(H,O),f ,\
)
B [Cr(C,O,J,]>- -... ' /
C [Co(en),CI~
( /Y~
®
II
[Co(NH,J,(NO,),]
,
27. The intermediate species formed in the mechanism of the reaction between methane
and chlorine in the presence of light is
ACH; Bcr C CHCI,
..
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C C3He ® C4 H10
Ole - c.oo "
NH.
29. Which type of isomerism is shown by each of the following organic compounds?
\..I p.
,c. .,; C.
A @-NH, B @ -CH2NH,
C CH,-N-CH, ® O'N-@-NH,
I
CH,
31 . Lactic acid can be formed from ethanol as shown in the reaction scheme below.
OH
OI,CH,OH -
*pI *'PO
OI,CHO --;;0;- Q
step m
01, - f" - I
C=0
OH
,
Name the types of reaction that occur in step
, I and step III.
B Reduction Esterification
C Condensation Oxidation
0 Dehydration Condensation
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CONFIDENTIAL· 22
32. Which of the following compound is formed when ethanoy1 chloride is reacted with
,?
O-I{_ -q
H,N --<Q(-CH,OH
OH
- A H'N ~CH'OCOCH'
OH
34. Natural rubber is a polymer made up of isoprene units with the structural formula
CH, = C(CH,)CH = CH, . Which of the following is not true about this statement?
A The IUPAC name for isoprene is 2-methylbuta-1 ,3-diene
B Natural rubber is made from unsaturated molecules
C Natural rubber becomes hard when vulcanized
@ Natural rubber is a mixture of cis polymers and trans polymers
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...,
CONFIDENTIAL" 24
c ,
35. X, Y and Z.are three different compounds. X reacts with sodium to give off hydrogen
gas. X and Y react to form an ester. X and Z also react to fonn the same ester but at a much
slower rate. Compound Y is probably X co, b 'Ej I""> rorc(l'1(j~ I
A propan-1-01 y ol:. ol·ci
B propana l ~ i'f0p"no: L
© propanoic acid
D propanoyl chloride
37, When X (a gas) reacts with Y, a mixture of CH,BrCH,Br and CH,BrCH,OH are
produced. X and Yare probably
X Y
D Br2vapour Ethene
38. A compound Q has the following composition by mass. Carbon, 64.3%; hydrogen,
7.1%; oxygen, 28.6%. Q reduces Fehling's solution to copper(l) oxide. 0.1 mol Q reacts with
4480 em' hydrogen gas at s.t.p. with nickel as catalyst. Q is
[Relative atomic mass: H, 1; C, 12; 0 , 16. 1 mol gas occupies 22.4 dm' at s.t.p.]
@ CH, = CHCHO C CH,CH = CHCH = CHCHO
B CH" CCH,OH D CH,COCH = CHCH = CHOH
0
0 /1
C H (-H
5.~58 I .I ITiS8 C3 H. O
\ H. ~ c, H, 0
'+ ". J c,I-I.O *v·2
C, H%O,
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./
CONFIDENTIAL' 26
39. An organic compound, W, is boiled with aqueous sodium hydroxide and the reaction
mixture is allowed to cool. Upon cooling , compound X and compound Y (an alcohol) are
produced. On acidification, compound X is converted to compound Z (C 3Hs0 2) . Compound Y
gives a positive triiodomethane (iodofonn) test. Compound W is likely to have the structural
formula
A CH,CH,COOCH,
B CH,COOCH,
® CH,CH,COOCH,CH,
D CH,CH(OH)CH,COCI
40. Which of the following pairs of reactants will not produce the compound with the
structural fonnula shown below.
, CH,
@-f-cH,CH,
c
OH
CH,
B I and @-MgBr
CH,CH,-G=O
CONFIDENTIAL' 28
Section B
For each question in this section, one or more of the three numbered statements 1 to 3 may be
COI1>lCf. The responses A to 0 should be selected as follows:
A B C 0
41 The energy-level diagram for a hydrogen atom shows several electronic transitions with
frequencies '1. '2. ().
f. and 's.
n=_
n~4
,,=3
n=2
j. f,
. n= 1
f, f,
CONFIDENTIAL" 30
A B C 0
1 only 1 and 2 only 2 and 3 only 1, 2 and 3
is correct are correct are correct are correct
45. The element X has a proton number of 25. Which of the following statements islare
true of X?
[) The metal X has a high density
D ® X forms coloured complex ions
® The highest oxidation number of X in its ion is "7
46. Which of the following element(s) haslhave the above arrangement of atoms in its
Gl diamond
~ silicon
3. boron
47. Which of tile following reagents react(s) with both benzene and methylbenzene?
(1J Chlorine gas in the presence of anhydrous aluminium chloride
(\ 2 Concentrated sulphuric acid on reflux
3 Acidified potassium manganate(VlI) on reflux
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CONFIDENTIAL" 32
A B C D
48.
CH2=CH-@- CH, Br
49. A compound P decolourise bromine water and does not form a white precipitate with
ethanolic silver nitrate solution. Compound P is
,
(jJ
<2<-CH=CH,
CI
" 2. @-CH,CH,CI
3, CH, =CHCH,CI
CHPH
HO--@-+-CO:;H
OH
50. Which of the following statements is/are true regarding the compound above?
3
Answer any four questions from section B. For this section, write
your answers on the answer sheets. Begin each answer on a fresh sheet 4
ofpaper and arrange your answers in numerical order. Tie your answer
5
sheets to this booklet.
6
Answers may be written in either English or Malay.
7
10
Total
(Jumlah)
STPM96212
*TIris question paper is CONFIDENTIAL until the examination is over. CONFIDENTIAL·
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CONFIDENTIAL· 2
Section A [ 40 marl<s)
(ii) Calculate the number of iodine atoms in one unit cell. [1 mark]
(b) The triple point of carbon dioxide is at -57°C and 5 kPa, while its critical paint
is at 31°C and 73 kPa.
(i) Define triple point. [1 mark]
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CONFIDENTIAL* 4
(ii) Sketch the phase diagram of carbon dioxide based on the information
above. [3 marks]
(iii) Based on your diagram in b(ii) , explain why solid carbon dioxide sublimes at
room temperature. [1 mark]
(iv) A piece of solid carbon dioxide with a mass of 5.50 g is placed in a 10.0 dm3
vessel that already contains air at 93.7 kPa and 24.0oC . After the carbon dioxide
has totally vaporized, calculate the total pressure in the container at 24.0oC.
[3 marks]
- - - - - -- - -- - - - - -
- - -- - - - - -- - -
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CONFIDENTIAL* 6
2. Consider the incomplete Born-Haber cycle and the table of data below.
......................................................
. ....................................................
(a) Complete the Born-Haber cycle above by writing the appropriate chemical
formulae, with state symbols, on the dotted lines. [3 mar1<s]
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CONFIDENTIAL* 8
(b) Use the cycle and the values given in the table to calculate the standard
enthalpy of formation of calcium chloride . [2 marks]
(c) The standard enthalpies of hydration of the Ca 2+ and the cr ions are -1650 kJ
mol-1 and -364 kJ mor1 respectively. Use this information and data from the table in
part (a) to calculate the enthalpy of solution of calcium chloride. [2 marks]
CONFIDENTIAL* 10
CONFIDENTIAL* 12
(i) Write an equation for the reaction between aluminium chloride and
chloromethane to form an electrophile . [1 mark]
(ii) Use your understanding of acids and bases to explain the role of
aluminium chloride in the reaction above . [2 marks]
......................................................................................................................................
(e) State one property which enables aluminium to be used in overhead electric
cables. [1 mark]
......................................................................................................................................
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CONFIDENTIAL* 14
4. (a) The diagram shows how to distinguish between propanal and propanone.
Tollen's reagent
+ propanal or
propanone --If---,
water
t
heat
(ii) State the functional group present in both propanal and propanone .
... .......................................... .. ... ... .. ....... ... .......... ....................... ...................... [1 mark]
.. ..... ...................................... .... ..... .... ... ... ......... ......... ......... .. .. ..... .... ... .. ... .... .... [1 mark]
Propanal .........................................................................................................
............................................. ......... .. .. .... ....... ....... ....... .. .......... ....... ... .. .... . [1 mark)
Propanone .... ...... .......... .. ..... .. ... ...... ........ ..... ......... .... .. .... .. ..... .......... .... ... .. ......
............................................................................. ... ... ............ ..... .... ..... . [1 mark)
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CONFIDENTIAL· 16
(b) Adrenaline is a hormone that acts as a stimulant. It has the structural formula
shown below.
H I
H~~f-,-,-H
HO HO H CH 3
(i) State the type of isomerism that can exist in the adrenaline molecule.
[1 mark]
(ii) Draw the structural formula of the product formed when adrenaline reacts
with
[2 marks]
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CONFIDENTIAL* 18
HCN LiAI~
H~HO p adrenaline
----~
--+~
HO Q
step 1 step 2
(X)
CONFIDENTIAL* 20
5. (a) The equation below shows the reaction between ammonia and a hydrogen
ion.
In tenns of the electrons involved, explain how the bond between the NH3
molecule and the H+ ions is fonned.
Name the type of bond fonned in this reaction. [3 mari<s]
(b) Boiling point data for three hydrides are given in the table below.
Methane 16 -182
Ammonia 17 - 33
Water 18 100
Explain why these three hydrides have very different boiling points.
[4 marks]
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CONFIDENTIAL* 22
CONFIDENTIAL* 24
6. (a) (i) Using a solution of ammonium chloride and ammonia as example, explain
what is meant by a buffer solution. [5 marks]
(ii) Calculate the mass of ammonium chloride that needs to be added to 450
cm 3 of 0.10 mol dm·3 ammonia to produce a solution with pH = 9.0
[1<1) of NH3 = 1.7 X 10-5 mol dm-3 ] [4 marks]
(b) The pK. values of four carboxylic acids are listed in the table below.
1 CH 3 CH 2COOH 4.9
2. CH 3CHCIC02H 2.8
3 CH3CCI2COOH 1.4
(i) Describe and explain the trend in acidic strength shown by acids 1, 2 and
3.
(ii) Give an explanation for the difference in the pKa values for acids 2 and 4.
(iii) Calculate the pH of a 0.010 mol dm-3 solution of propanoic acid (acid 1).
[6 marks]
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CONFIDENTIAL* 26
7. (a) (i) State the trend in the reducing ability of the halide ions from fluoride to
iodide.
[1 mark)
(ii) State what you would observe when chlorine water reacts with a
solution of potassium iodide. Write an equation for the reaction.
State the role of chlorine in the reaction.
[3 marks)
Identify a reagent which could be added to the mixtures from the first test
to confirm the identity of the halide ions. State what would be observed in
each case.
[6 marks]
(b) Carbon tetrachloride and silicon tetrachloride behave in different ways when
added to water. State how each chloride behaves and explain the difference.
[5 marks]
•
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CONFIDENTIAL* 28
(b) Compare and explain the solubility in water, for the solid sulphates formed in
8(a). [7 marks]
(c) The solubility product, Ksp, of magnesium hydroxide has a numerical value of
2.0)( 10-11 •
(i) Write an expression for the Ksp of magnesium hydroxide, stating its units.
(ii) Use the value of Ksp given to calculate the concentration of Mg(OH)2 in a
saturated solution .
CONFIDENTIAL· 30
9. (a) (i) Write the mechanism of the reaction when 1-chloropropane is refluxed with
aqueous sodium hydroxide. Name of the type of reaction involved [3 marks]
(ii) State and explain how the rate of this reaction changes when
1-chloropropane is replaced by 1-bromopropane. [3 marks]
(b) The amino acids alanine and serine are shown below.
H H
I I
H 2N-C--cOOH H 2N-C--cOOH
I I
CH3 CH20H
alanine senne
(i) Draw the structures of the two dipeptides formed by the reaction of
alanIne with serine.
(iii) Draw the structure of the organic compound formed when one molecule
of serine reacts with two molecules of ethanoyl chloride. [4 marks]
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CONFIDENTIAL* 32
Question 1
(a) (i)
00
(1 )
(b) (i) A set of temperature and pressure values where solid, liquid and gas exist in
equilibrium. (1 )
(ii)
liquid
.cUd
5 _ ,.. _ ~ ______ __ _______ L - - -
, 0"
!
r
,
_ ._.. _- ---.---- :r,'......_- --," .._...._-_.....- 31 "" --
The labellings. (1 )
(iii) because its triple pOint occurs at a pressure above the normal atmospheric
pressure. (1 )
p
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= 30.9 kPa (1 )
PI = 30.9 + 93 .7 = 124.6 kPa (1 )
Total: 10 marks
Question 2
(a) Ca 2+(g) + 2e- + 2CI(g) (This is the only answer for the top line) (1)
Ca2+(g) + 2e- + CI2(g) (1)
Ca+ (g) + e- + CI2 (g) (1)
Ca(g) + CI 2 (g) (state symbols and electrons essential) (1)
Note: CI2to 2CI can be in any order but Ca must be in sequence)
Max. 3 marks
(b) Enthalpy of formation = 178 + 590 + 1145 + (2 x 121) - (2 x 364) - 2237 (1)
= - 810 kJ mor1 (1)
Q=mcflT
flT= Qlmc =(0.561x1000)/(50 x4.2) =2.6 (0C) (1)
(allow 2.5 to 2.7; can use 52; ignore units, answer must be at least 2 sig figs)
Final temperature = 20 - 2.6 = 17.4 °c (1)
(Answer is for 20 - previous ans; must be < 20)
Total = 10 marks
Question 4
(a) (i) Ag+/silver (1 )
(ii)(a)
H r
Na(}-~~ -I-I~
Na~ Hb H cH,
(1 )
(13)
(1 )
Total = 10 marks
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Question 5
(a) Lone pair donated / both electrons supplied by one atom (1 )
(b) Van der Waals ( or VrNV) forces between methane molecules (1)
Hydrogen bonds in water more extensive than ammonia because 0 has two lone
pairs (N one) (1 )
Note: If candidates graph does not level off then second mark can be scored for a
CUNe with a continuously decreasing gradient.
(1 )
NO is a catalyst (1)
Question 6
(a) (i) A buffer solution has the ability to resist changes in pH when a little acid or base is
added . (1 )
When a little acid is added, it reacts with NH3. The acid is used up, pH remains
unchanged (1 )
NH3 + H+ NH/ (1 )
When a little base is added, it reacts with OW The base is used up, pH remains
unchanged (1)
NH/ + OH- (1)
p QL1
IU .v
=Pftb + Iog [NH;1
[ NH,J (1 )
(ii) chlorine atom is further away (from O-H) in no. 4, so has less influence (1)
Question 7
(lone) pair of electrons (from the oxygen atom) in a water molecule (1)
cannot form a bond with/be donated to the C atom
Or cannot be accepted by C atom (1)
Question 8
(a) white precipitate formed for barium nitrate (1)
Total = 15 marks
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Question 9
(a) (i)
CH 3CH 2
CH3CH 2 ";:H 2CH 3
1
He- + H-) - :-
H
CI - HO - / ,,- CI
_ HO-C - H +C~
H H
""H
(1) (1 )
bimolecular nucleophilic substitution (1 )
------
---.... CH 3CHCIC H3
(1 )
(b)
(i)
(1 )
H2N-C
f C-N-C-COOH
Y (1)
I· II I 1
CH20H 0 H CH3 penalise polymer both times
(iii)
H
I
H C-C-o-CH - C-COOH
3 II - 1
o 1'H 0 0
(1 )
I
CH3
Total = 15 marks
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Question 10
They don't react with Fehling's solution - they are ketones (1)
o and E gives a positive test with Fehling's solution - they are aldehydes (1)
(2)
Reduction of E gives a long chain compound, F
E is CH 3CH 2CH 2CH 2CHO (1 )
F is CH3CH2CH2CH2CH20H (1 )
«H3 ~
CH 3CH2CH 2C=O + H2NNH--\Q,>-- N02 -- _
Total = 15 marks
12-