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FIITJEE

J EE (Advanced), 2013
PART TEST-I
(18 November 2012)

Paper 1

I Code 11302A
Time Allotted: 3 Hours
carefully. the You

Maximum Marks: 210

are Hall allotted before 5 the minutes end of

Please read the instructions specifically for this purpose. You are not allowed to leave th e test.

Examination

INSTRUCTIONS
Check all the header of all SET marked CHANGE the sheets of this question paper. Please ensure the same SET is marked on the sheets inside as indicated on the top left corner of this page. In case is not the same on all pages, immediately inform the Invigilator and Question paper for a correct one.

Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.

A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets. 2. This question paper contains Three Parts. 3. Part-I is Physics, Part-II is Chemistry and Part.1II is Mathematics. 4. Each part is further divided into two sections: Section-A & Section-C 5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be , provided for rough work. . ~ 6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices, in any form, are not allowed.

B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR sheet. 2. On the OMR sheet, darken the appropriate bubble with black pen for each character of your Enrolment No. and write your Name, Test Centre and other details at the designated places. 3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For All Three Parts.

(i) Section-A (01 to 10) contains 10 multiple choice questions which I:lav.e-onlyone correct answer. Each question carries +3 marks for correct answer and - 1 mark for wrong answer. Section-A (11 to 15) contains 5 multiple choice questions which have more than one correct answer. Each question carries +4 marks for correct answer. There is no negative marking. (ii) Section-C (01 to 05) contains 5 Numerical based questions with answers as numerical value and each question carries +4 marks for correct answer. There is no negative marking.

Name of the Candidate

Enrolment

No.

DDDDDDDDDDDDDDD DDDDDDDDDDDDDDD DDDDDDDDDDDDDDD

Vlhar, New Delhi

FIITJEE Ltd., FIITJEEHouse, 29.A, Xalu

Saral,

SaTl1aprlya

.110016, Ph 46106000,26569493,

Fax

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..

Useful Data

PHYSICS
Acceleration due to gravity Planck constant Charge of electron Mass of electron Permittivity of free space Density of water Atmospheric pressure Gas constant R = 8.314 J K-1 morl Pwater = 10 kg/m
3 3

10 m/s2

h = 6.6 x10-34 J-s

me =9.1

10-31kg

CHEMISTRY
Gas Constant
R

Avogadro's Number Na Planck's constant h 1 Faraday 1 calorie 1 amu 1 eV Atomic No:

= = = = = = = = = =

8.314 J K,-l mor1 0.0821 Lit atm K-1 mor1 1.987", 2 Cal K-1 mol-1 6.023 x 1023 6.625 x 10-34 J.s 6.625 x 10-27 erg.s 96500 coulomb 4.2 joule 1.66 x 10-27 kg 1.6 x 10-19 J

H=1, He = 2, Li=3, Be=4, B=5, C=6, N=7, 0=8, N=9, Na=11, Mg=12, 8i=14, AI=13, P=15, 8=16, G1=17, Ar=18, K =19, Ca=20, Cr=24, Mn=25, Fe=26, Co=27, Ni=28, Cu = 29, Zn=30, As=33, Br=35, Ag=47, 8n=50, 1=53, Xe=54, Ba=56, Pb=82, U=92. Atomic masses- H=1 He=4 U=7 Be=9 B=11 C=12 N=14 0=16 - F:!::19,Na=23, Mg=24, = 27, 8i=28, P=31', 8=32', CI=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59, Ni=58.7, Cu=63.5, Zn=65.4, As=75, Br=80, Ag=108, 8n=118.7, 1=127,Xe=131, Ba=137, Pb=207, U=238.

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Physics

PART -I
SECTION -A Straight Objective Type

This section contains 10 multiple choice questions numbered 1 to 10. Each question has 4 choices (A), (B), (C) and (0), out of which ONLY ONE is correct. 1. A toy car is moving on a closed track whose curved portions are semicircles of radius 1m. The adjacent graph describes the variation of speed of the car with distance moved by it (starting from point P). The time t required for the car to complete one lap is equal to 6k second. Find k. (take nln2 "'"2)

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(A) 4 (C) 12 2.

(B) 8

(0) 16 Y

A particle Pisto be projected from a fixed point A on the ground with a fixed speed u. Another particle Q is also to be projected from a point B which is directly above the point A. The trajectory of the particle Q touches all possible trajectories (for different angle of projection) of the particle P in the vertical x-y plane. The equation of trajectory of the particle Q is, (Take the point A as origin, horizontal axis x-axis and vertical axis y-axis. Consider the figure.)

B :::;

u: P
A x

Rough work

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3.

A small coin is placed on a stationary horizontal disc at a distance r from its centre. The disc starts rotating about a fixed vertical axis through its centre with a constant angular acceleration u. Determine the number of revolutions N, accomplished by the disc before the coin starts slipping on the disc. The coefficient of static friction between the coin and the disc is Ils.

vertical

{(~g)' +a,r
(A)

{(";g)'
(8)
(0)

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(C)

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4.

A wedge of mass M resting oil a horizontal frictionless surface is acted upon by a force F in the horizontal direction as shown in figure. The net horizontal force acting on the shaded portion of the wedge is (8) F/3 (A) F (0) zero (C) F/6 A person rolls a small ball with speed u along the floor from point A. If x 3R, determine the required speed u so that the ball returns to A after rolling on the circular surface in the vertical plane from 8 to C and becoming a projectile at C. (Neglect friction and radius of ball)

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(A) (C)

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(8)

~J9R 2 "!.-J9R
2

(0) Rough work

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In the figure shown when the massless spring isin relaxed state its free end is at point B. A very small block 'is pressed against the spring by a distanceS and then released from rest. Except the portion Be where coefficient of kinetic friction is J.1K, track is smooth everywhere. Determine the spring compression S so that the block 'enters a small hole at :E. Consieer aU vall:les shown in the figure.

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rough surface

7.

The wheel of radius R rolls without slipping on horizontal rough surface, and its centre 0 has an horizontal 3cceleration aDin forward direction. A point P on the wheel is a distance r from 0 and angular position 8 from horizontal. For a given values of aD,Rand r, determine the angle 8 for which point P has no acceleration in this position.
(A) cos
-1

r R R

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8.

The two identical rectangular steel frames with the dimensions shown are fabricated from a bar of the same material and are hinged. Rectangular at the midpoints A and 8 of their sides(3m x 1m). If the frame is resting in the position shown on a horizontal surface with negligible friction, determine the velocity v with which each of the upper ends of the frame hits the horizontal surface if the cord 0 is cut. (Take the value of dimensions shown in figure c = 1 m, b = 3/2 m and e = 74

. . e 3 I.e., 510"2=5

an

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10

1 2) ms c

(A) 5 m/s (C) 3 m/s 9.

(8) 8 m/s (D) 4 m/s

A car C of mass m is initially at rest on the boat A of mass M tied to the identical boat 8 of same, mass M through a massless inextensible string as shown in the figure. The car accelerates from rest to velocity Vo with respect to boat A in time to sec. At time t = to the car applies brake and comes to rest relative to boat in negligible time. Neglect friction between boat and water find the velocity of boat A just after applying brake. (A) (C) Mmvo (2M + m)(M + m) 2Mmvo (M+2m)(M+m) (8) Mmvo (M + 2m)(M + m)

(D) zero Rough work

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10.

In the figure shown a river of width 4 km is flowing with the speed of 5 km/h. A swimmer whose swimming speed relative to the water is 4 km/h, starts swimming from a point A on a bank. On the other bank B is a point which is directly opposite to A. What minimum distance (in km) the swimmer will have to walk on the other bank to reach the point B. (A) 2 (C) 4 (B)3 (0) 5 Multiple Correct Choice Type

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This section contains 5 multiple choice questions. Each question has 4 choices (A), (8), (C) and (0) for its answer, out which ONE OR MORE is/are correct. 11. Under the action of force P, the constant acceleration of block 8 is 6 m/sec2 up the incline. For the instant when the velocity of 8 is 3 m/sec up the incline. Choose the correct option(s) (A) Velocity of 8 relative to A is 1m/s (B) Acceleration of 8 relative to A is 2 m/s2 (C) The velocity of point C of thecable(in (0) Velocity of 8 relative to A is 2m/s 12. ground frame) is 4 m/s
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horizontal. (A) The normal reaction acting on cube is zero (B) The value of ao is g-./3. (C) The value of ao is g. (0) Acceleration of the particle in ground frame is g Rough work

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13.

Two identical particles A and B of mass m each are connected together by a light and inextensible string of length e. The particle are held at rest in air in same horizontal level at a separation
Va

e. Both

particles are released simultaneously and one of them (say A) is given speed o
2

vertically upward. Choose the correct options(s). Ignore air resistance.

8g
V

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(B) The kinetic energy of the system of A and B when the centre of mass is at its highest point, is

mv0 __
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4g
V

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__ 2 mv0 4

14.

In the adjacent figure a uniform rod of length

e and

mass m is kept

l
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at rest in horizontal position on an elevated edge. The value of x (consider the figure) is such that the rod will have maximum angular acceleration ex., as soon as it is set free.

(A) x is equal to

2,,3

er;;

(B) ex. is equal to g13

2e

(C) ex. is equal to --

g,13

(D) x is equal to ~ Rough work

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A Block 'A' is placed on a smooth horizontal surface and a particle C is suspended with the help of light fad ffOm point B of the block as shown. Now both the -block A and the partiole C are given velocity Vo towards left. The block A strikes a fixed wall and suddenly stops. Then, (The rod BCis free to rotate about 8)

Vo +---

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(A) the smallest velocity Vofor which the particle C will swing in a full circle about the point 8 is

J4g.
(8) the smallest velocity Vofor which the particle C will swing in a full circle about the point B is

JQj.
(C) velocity of point C at the highest .point of the circle {for the smallest value of vo)is zero. (0) velocity of point C at the hi@hestpoint of the circle (for the smallest value of vo) is SECTION-C Integer Answer Type
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1. A disc 'A' of mass M is placed at'rest on the smooth incline surface of inclination e. A batl B of mass m is suspended vertically from the centre of the disc A by a light inextensible string of length as shown in the figure. If the acceleration of the 'disc B immediately after the system is
IS '

released from rest

. (M+km)gsin2e
2'

Fmdk.

M+msin

El Rough work

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A uniform rod AB of mass M and length "1/2R is moving in a vertical plane inside a hollow sphere of radius R. The sphere is rolling on a fixed horizontal surface without slipping with velocity of its centre of mass 2v. When the end B is at the lowest position, its speed is found to be v as shown in the figure. If the kinetic energy of the rod at this instant is

Hollow sphere

iMv
K

Find K.
; vertical centre line

3.

A small particle is given an initial velocity va = 1a m/s along the tangent to the brim of a fixed smooth hemisphere bowl of radius ra = 15"1/2 m as shown in the figure. The particle slides on the inner surface and reaches point B, a vertical distance h =15 m below A and a distance r from the vertical centerline, where its velocity v makes an angle e with the horizontal tangent to the bowl through B. If e = 15 KO. Find the value of K. (take g = 1a m/s2) A smooth disc of mass M and radius

4.

is placed at rest horizontally

on a smooth horizontal surface. A massless pin is fixed at point P at a distance U2 from centre 0 of the disc as shown in the figure. Now a thin uniform rod of mass M and length L is placed horizontally on the surface of the disc parallel to the line OP such that its mid point and centre 0 of the disc just coincide as shown in figure. Now rod has given angular velocity (uo = 24 rad/sec in counter clockwise direction as shown. As a result, the end of the rod strikes the pin P and sticks to it rigidly. Calculate the angular velocity of disc just after collision. 5. One end of the pile of chain falls vertically through a hole in its support and pull the remaining links steadily. The links which are at rest acquire the velocity of the hanging position suddenly and without having interaction with the remaining stationary links and with the support. If the acceleration a of the falling chain is g/k. Find k. Ignore any friction.
x

Rough work

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Chemistry

PART - II
SECTION-A Straight Objective Type

This section "Contains 10 mulliplechoice questions numbered 1 to lO. Each question .has 4 choices (A), (B), (C) and (0), out 'of which ONLY ONE is correct. 1. In a small sample of H atoms 'inexcited state n 5, transition to ground state releases aU possible lines except the ones in Paschen series. How many spectral .Iines are released in the emission spectra: (A) 6 (B) 7 (C) 8 (0) 9 The following equilibria is maintained in a closed vessel:

2.

N2 (g) + 3H2 (g)~2NH3{g)

Moles@equilibrium 1 3 2 .Equilibrium is now disturbed by removing x moles of H2 and simultaneously doubling the volume Of vessel. At new equilibrium, 17 gms of NH3 is obtained. Find x. (A) 1 (B) 1.3 (C) 1.9 (0) 2.5 3. Asolid particle having spherical shape is assumed to react only on its surface. However the amount of reactant contained in it is detennined 'by its volume. Consider the following rate ~aw for a solid particle shrinking due to reaction:
--

dV dt

k S(S = surface area) (B) 1 (0) 3/2.

j

The order of the above reaction will be: (A) 0 (C) 2/3 4.

:",

Pure S03(g) is heated in a solid vessel to create the following equilibrium: ~

2S03 (g)~2S02

(g)+02(g)

The vapour density of the equilibrium mixture is: (A) 16 (B) 26

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The self ionization constant for purefonnic

6

acid K

= [HCOOH;][

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1.0- at room temperature. The .density of fonnic acid is 1.15 g/cm3. What percentage of fonnic acid molecules convert to formate anion:
(A) .0..0.01% (C).o ..o.o3% (S) .0..0.02%

(0) .0.'.0.04%

6.

Reactions at the very first instant of their life, Le. shortly after start, follow: (A) Pseudo zero order kinetics (S) Pseudo first order kinetics (C) Pseudo second order kinetics (0) Pseudo third order kinetics If Aufbau rule is not obeyed and instead electronic filling occurs orbit by orbit till saturation is reached, calculate the percentage change in total of (n + ) values for unpaired electrons in an atom of manganese.
(A) 2.0 (S) 4.0

7.

(C) 6.0 8.
3

(0) 8.0

The pH eltwhich a .0..01 M AI+ solution is 99.99% precipitated is : (Ksp AI(OHh (A) 6.67 (S) 7.67 (C) 8.67 (0) 1.0 The styx number for S2H6 is:
(A) 2.012 (C) 2.0.02

=1x

10-18 at 25C)

9.

(S) 2222 (0) 21.02 F 82~C=O . CI 83 ~C=O

10.

.H 8]~'c=o

H F CI Decreasing order of shown angles will be: (A) 81 > 82 > 83

..............................................................

(S) 81 > 83 > 82

................

(C) 83 > 82 > 81

.....................................................

(0) 81 = 82 .................

= 83 ............
.

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Rough Work

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.;

11.

Identify the correct statements w.r.t. the titration curves shown below:

14

Strong Base

pH
Weak Base

'.";

o
(A) (B) (C) phenolphthalein (8 - 9.8) can be used as indicator in both titrations (D) chlorophenol red (4.8 - 6.4) can be used as indicator in both titrations. 12. For solution of alkali metal (M) in liquid NH3 identify which of the following equilibria would simultaneously exist: (A) M+(x+y)NH3~M(NH3): - ~e2(am) ~ -2 (C) 2 eam +e-(NH3)y (B) 2M(am)+2e-~M2(am) (D) M(+am) +e-22~M(-am) ,
Rough Work

Volume of strong acid added ~ equivalence point with strong base is at pH = 7 equivalence point with weak base is at pH = 7

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Which of the following would be observed in the Lewis dot structure of N40: (A) positive charge on N (8) negative charge on N (C) oxygen atom at1he tenninus (0) electronic delocalization

14.

Which of these statements correctly compare between SF4 and SF6: (A) both molecules have same hybridization for Satom (8) both molecules have at (east one linear F - S - Flink (C) SF6 has higher boiling point lhan SF 4 (0) SF4 reacts vigorously with water whereas SF6 is inert towards water

15.

Inorganic benzene surpasses organic benzene in which property: (A) melting point (8) edge length of its hexagon

nx> .m

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-(0) total number of electrons in the molecule >:')"H ;_

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1. Ammonium carbamate is heated at 227C in a closed vessel of volume 8210 ml containing 0.2 mole of Argon gas. The manometer attached to the vessel shows a pressure of 1 atm. Find Kp for the decomposition of ammonium carbamate. NH2COONH4 (s)~2NH3 2. Silver (I) ferrocyanide (g)+C02 (g)

and Bismuth(III) sulphide are sparingly soluble salts with identical water

solubility. The ratio of their Ksp is 3. 4. 5.

(~J .

Find (a + b).

On the Moh's hardness scale, what value is assigned to Gypsum mineral (CaS04.2H20) How many gases/va pours are involved either as reactants or products in Serpeck's process used for concentration of bauxite. The magnitude of potential energy of electron in nth excited of He + ion is ~ times the kinetic

81

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Mathematics

PART - III
SECTION -A Straight Objective Type

This section contains 10 multiple choice questions numbered 1 to 10. Each question has 4 choices (A), (8), (C) and (D), out of which ONLY ONE is correct. 1. Let f(x) {(0.1)3!X1}. (where 1.] denotes greatest integer function and {.} denotes fractional part) If f(x + T) f(x) V x ~ 0, where T is a fixed positive number then the least value of T, is

W2
(C) 6(D) 2.

~4
none of these

The minimum value of the function f(x) = _1_ - {x} occurs at x equals to . 2{-x} (where {.} represents fractional part function) 1 1 (A) n + J2' n EI (8) n - J2' n E I (C) n+ 1

2",2

~' n E I

1 (D) n +-, n E I

3.

Consider the function f defined by o , when x ='0 or x is irrational f(x) = 1 . m m . . { - , when x .IS non-zero rational number -, n > 0 and - IS In lowest term n n n which of the following statement(s) is(are) true? (A) x 0 is a point of discontinuity of f (8) any non-zero rational number is a point of continuity of f (C) any irrational number is a point of continuity of f . (D) any irrational number is a point of discontinuity of f

4.

If co-domain is R, then which of the following functions is not a surjective (onto) function? (A) f(x) = Inlln(x-[x))1. (where [.] denotes the G.I.F) (8) f(x) x + cos (n[x)), (where [.] denotes the G.I.F)

(C) f(x) (D) f(x)

= tan-1 x = -2x x -1

,,1 + x

......................

;.

...............

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The value of J((~-X+XlnX)SinX)dX,iS

1

(A) sin e - cos 1 (C) sin e + cos 1 6.

(B) cos e - sin 1 (D) cos e + sin 1

The differential equation of a family of cUlves whose angle of intersection with the family of parabolas (A) dy dx (C) dy dx

= kx, (k = parameter), is ~, is

= =

x+2y x - 2y Y- 2x y +2x

(B)dy= dx

2y-x 2y + x

(D) none of these

7.

The value of x for which the function f(x) (A) x sin x < 0 (C) x cos x < 0

= sin-

sin Ixl is increasing can be given by (B) x sin x > 0 (D) x cos x > 0
4 3 C

8.

If Ibl > la + cl then atleast one root of the equation ax + bx + (A)(-2, 0) (B)(-1, 1) (C) (0, 2). (D) (1, 3)

= 0 lies in the interval

9.

Let f(x) (A) 0 (C) 2

:=

J
1

IOQ1I2(1-

T')dt

then the value of f(2) + f(2 -log23), is (B) 1 (D) 3 - 210g23

10. +x (B) -In --3 5 1+x

1 (1

5 )

+c

1 (1+X (D) -In -- ) 5 1+x

...................... ;;;.; ...... ...................... ........

+c
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Multiple Correct Choice Type This section contains 5 multiple choice questions. Each question has 4 choices (A), (8), (C) and (D) for its answer, out which ONE OR MOREis/are 'correct. 11. Let f : R -7 R,f{x) = x + In(1 + x2)then (A) l is injective (8) lim f(x) = too
X---..-co

(C) there is a point on the graph of y (D) f is bijective ' 12. If .Iim (log3 (ax2 + 3x + 1)Y09(X-')3
X-42

= f(x) where tangent

e

is not parallel to any of the chords

= e , where

is a finite real number then (8) 'a' can have more than one values (D) e = e-1I3

(A) 'a' must be (-1) (C) I!. = e-2/3 13. Let a function f(x), x ~ 0 be such thatf(x) + f(!

x)

1= f(x). f(!)', x
(8) (D)

then f(x) can be

(A) 1(C)

2013

+1

, n 1 2tan- !xl

2 1+klnlxl

14.

Let 9 be the inverse of the continuous function f. Let there be a point (a, /3), where a ~ /3, is such that it satisfies each of y f(x) and y g(x) then (A) the equation f(x) g{x) has infinitely many solutions (B) the equation f(x) g{x) has atleast 3 solutions (C) f must be a decreasing Junction of x (D) 9 can be an increasing function of x

= =

15.

ax: + bx +c . If f(x) is not a constant function and both minimum and maximum values dx + ex +f of f(x) exist then (A) f(x) must be a continuous function (8) 4ac must be more then b2 2 (C) 4fd must be more then e (0) ae must not be equal to bd
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x
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1.

The number of integers belonging to the interval [-3, 30] but not belonging to the range of the function f(x) x{x} - x [-x], X E R, is (where [.] and {.} denote the greatest integer function and fractional part respectively)

2.

Find the maximum possible integral value of

1~ - a 1 ,where 0 < a < ~ < tan- ~ - tan- a

13 , is

3.

Let

I(e) =

cos' x cos~c x sin (e') dx. If the value 01 2~

f -(

~lr( ~l

is 'k' then the value of

64 k2, is 4. Consider a rectangle with vertices A '" (0, 0), B", (4, 0), C '" (4, 6), D", (0, 6). Let S be the region consisting of all points Pinside the rectangle such that d(P, DC) < d(P, AB) < max.{d(P, BC); d(P, AD)}, where d(P, MN) denotes distance of the point P from the line joining points M and N. The area of the region S in square units, is If Rolle's theorem is applicable to the function, f(x) then the value of a + b, is
. .. -~,; ..
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5.

Inx over the interval [a, b], where a, b

X

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