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JEE(Advanced),2013
PART TEST - II (PAPER - 1 & 2 )

(9th December,
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2012)

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QUESTIONS ANSWERS & SOLUTIONS

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ANSWERS, HINTS & SOLUTIONS PART TEST - II PAPER-1

Physics

PART -I

2. 3. 4. 5. 6. 7. ~ 8. 9.
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Physics

PART -I
SECTION-A
Single Correct Choice Type

This section contains 9 multiple choice questions. out of which ONLY ONE is correct. 1.

Each question has four choices (A), (B), (C) and (0)

In a certain region of space a unifonn and constant electric field and a magnetic field parallel to 4 each other are present. A proton is fired from a point 'A' in the field with speed v = 4 X 10 mls at an angle of a with the field direction. The proton reaches a point B in the field where its velocity makes an angle 13with the field direction. If s~na:=.J3 . Find the electric potential difference
SIO

13

Sol.

between the points A and B. Take mp (mass of proton) 1.6 x 10. kg and e (magnitude of 19 electronic charge) = 1.6 x 10. C. (A) 16 V (B) 16/3 V (C) 90 V (0) 30 V A Work done by magnetic force is zero . . 1 2 1 2 s2 from work energy theorem - mpYB :=- mpVA + q8 V. ;: 2';j: 2,). and simultaneously there is no change of velocity component along the direction of perpendicular . tq,electric and magnetic field. > v~ sina := VB sinl3 After solving !w

27

,;

16 Volt R

2.

A metallic disc of radius r is made .of a material of negligible resistance and can rotate about a conducting horizontal shaft. A smaller non conducting disc of radius a is fixed onto the same shaft and has a massless cord wrapped around it, which is attached to a small object of mass m as shown. Two ends of a resistor of resistance Rare connected to the perimeter of the disc and to the shaft by sliding contacts. The system is then placed into a unifonn horizontal magnetic field B and the mass m is released. Find the tenninal angular velocity with which the disc will rotate finally. 1 (Take r 10cm, a 2cm, R := 100 Q. B 0.2 T, m 50 gm, g

= 10 m/s')

(A) 200 rad/s (C) 100 rad/s

(B) 300 radls (0) .10 radls

Sol.

C
At tenninal stage, torque applied on the smaller disc by the rope
2 .

= mga

current to the disc

Bwr
2R

(where

(D

is terminal angular velocity)

4

torque applied by magnetic field B"(J}r So. -. 4R

ID

B2
4R

_.Wf.

:=mga

==

100 rad/sec

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3. ~:~hti~~~ ~I~~~~al~e~al~~~~:~~~:'i~~dp~a~~r~~i~ ~e~ 51~r: ~ distance from each other and they are connected by a coil of inductance L = 9mH as shown in figure. One of the spheres (say A) is imparted an initial charge and the01her is kept uncharged. The switch S is closed at t = O. After what minimum time t does the charge on the first sphere decrease to half of its initial value? (A) (C)
1t

10-6 sec

(B)

2: x 10--6 sec
4

2: x 10--6 sec
2
(f)

(D) 2n x 10-6 sec

Sol.

B
Angular frequency of the LC oscillation = ~21TORL required time is one fourth of the time period

4.

A non conducting infinite rod is placed along the zcaxis: the upper half of the rod (lying along z 2: 0) is charged positively with a unifonn linear charge density +1. while the lower half (z < 0) is charged negatively with a unifonn linear charge density i.. The origin is located at the junction of the positive and negative halves of the rod. A unifonnlycharged annular disc (surface charge density: aD) ofinner radius R and outer radius 2R is placed in the x-y plane with its centre at the origin. Find the force on the rod due to the disc. (A) 2ao}.R
I I I I

Co

(i";

Sal.
I I
I
I

(C) ao/,R Co C The force on the rod due to the annular disc is equal and opposite to that on the disc due to the rod. We take an annular strip of radius r and width dr and find the force acting on it dF ..

I I

= (ao 21tr d)r

The force F
2R

-- i.

= -

I.GO

2m:or

Co

ao/.
co.

dr

aoi.R .
Co

- R

5.

A insulating cylindrical rod a unifonn surface charge outside the curved surface electlic field. due to charge

of diameter d and length f. ( f. d) has density such that the electric field just of the cylinder at point M is Eo. Find the distribution at point P (r 0. ~El~
0

.(.r;\HO ..

M.(
(

<

: )

WE~
~E~
Sol.

o 2r2 03r'

4rL
r2

~E2ld
0

B
---

2"

-E

21tl'od i.

=
,

m:odEo .
4r

_ todl Sa Ep--- 2

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6.

Electric field given by the vector

=0 ~..Q.(xi
(

+ Yl) N/C is present in the

(o./l~

x-y plane. A small ring of mass M carrying charge +Q, which can slide freely on a smooth non conducting rod, is projected along the rod from the point (0, ) such that it can reach the other end of the rod. Assuming there is no gravity in the region. What minimum velocity
jf (f, 0)

should be given to the ring (in mts)? (A) 2 (C) 2.5 A For the electric field, V=:-

in S.1. unit QEo( =:8

(B) 3 (0) 3.5

Sol.

+K 2 2 QE 2 1 QE from energy conservation - __ 0 - + k + _Mv2 =:- -' _0

_0_ - ~

E x2

f2 . .:- x 2

f.

+K

v = 2 mts
7.
One mole of an ideal monoatomicgas under goes a process V = aT increasesby 100 K. Which of the following is incorrect? (A) the work done by the gas in the process is 200 R Joule (B) the molar heat capacity for the process is 7R
2 .

The temperature

of the gas

.;
2

(C) for the process PT = constant (D) for the process coe'tftcient of volume expansion is Sol. C For the process, P = aT So, work done by the gas = 200 R Joule . 3 RT For the process, molar heat capacity C = -R + -2aT 2 V . ffi . 1 dV Vo Iume expansIon coe rClent ",=' - -. V dT 8. 2 = -T
'j' ;, .... ~

= --

7R 2

A point source of heat of power P is placed at the centre of a spherical shell of mean radius R. the material of the shell has thermal conductivity K. If the temperature difference between the outer.and the inner surface of the shell is not to exceed T, then the thickness of the shell should . not exceed (A) 2nR KT
2

(B) 4nR KT

P
(C) nR KT
2

P
(D)
lIR

P
. Sol.

KT 4P of the

B
At equilibrium energy radiated by point source shell

heat conducted through the thickness

9.

Two infinite sheets carrying charge density +0 and -(J are arranged perpendicularly as shown in the figure. Select the approximate electric field lines for the charge system near the intersection .

+XO

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7
(B)
+0

(A)

x (C)
(D)

Sot

B
Tangent on the electric field lines give the direction of net electric field at that point. Assertion -Reasoning 10 to
..

Type question
,':,'.

This

I'''!':'

$ection

contains

4 questions

n,mnbered
:i}':'.'

13. Each

contains

STATEMENT-1
'

(A~sertiOn)

and STATEMENT-2 iscorrect.:;;:.

(Reason)..

Each question has 4 choices (A), (B), (C) and (D) out of
i'

which QNlYONE 10.

-----t;y

A current of one ampere flows, through a wire made of copper and aluminium as shown in figure. They have the same cross.section A. STATEMENT-1 : Some charge accumulates at the boundary between the metals.

and
STATEMENT.2: According to Gauss's law, ~ E ..

Cu

1A

. (is =

qenclosed

Co

for a closed surface. for for

(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation .Statement-1. (B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation Statement-1. (C) Statement-lis True, Statement -2 is False. (D) Statement-1 is False, Statement-2 is True.

Sol.

A
Electric field inside copper and aluminium are different due to different gauss's law the interface should contain some charge resistivity. So, from

11.

1 mole of an ideal gas is contained in a cubical volume V, ABCDEFG at 300K. One face of the cube EFGH is made up of a material which totally absorbs any gas molecule incident on it. At any given time. STATEMENT-1 : The pressure of EFGH would be half that on ABeD.

and

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STATEMENT-2: Gas molecules colliding with the wall EFGHare loosing ijs kinetic energy. (A) Statement-1 is True. Statement-2 is True; Statement-2 is a correct explanation Statement-1. (B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation Statement-1. (C) Statement-1 is True, Statement -2 is False. (D) Statement-1 is False, Statement-2 is True.

for for

Sol.
12.

8
In the figure shown a charged capacitor is being discharged by an external load resistance Rl. STATEMENT-1: A magnetic field is not present at point P which is situated inside the capacitor as shown in the figure.

and
STATEMENT-2: From ampere's law,

CJ
shape and parallelto the for for spectrum for all

tS.d7 = f.Lo(ienclosed)'

An ampere loop (circularin

plane of the plates) passing through P does not encloses any current. (A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation Statement-1. (8) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation Statement-1. (C) Statement-1 is True, Statement -2 is False. (D) StatEfment-1 is False, Statement-2 is True. Sol. 13. D STATEMENT-1: In a black body radiation, wavelengths.

energy is uniformly

distributed

in the radiation

and
STATEMENT-2: From Stefan - Boltzmann's law radiated energy from a black body is proportional to the fourth power of its surface temperature in Kelvin. (A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1. (B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1. (C) Statement-1 is True, Statement -2 is False. (D) Statement-1 is False, Statement-2 is True. Sol. D

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Type

Comprehension

This section contains 2 groups of questions. Each group has 3 multiple choice question based on a paragraph. Each question has 4 choices (A), (8), (C) and (D) for its answer, out of which ONLY ONE is correct.
!

Paragraphfor An engineer is instructed to design a tank to mJasure the heat capacity of liquids. The tank is designed and it consists 01 insulating walls of negligible heat capacity, with a hole in the bottom, a drain plug fitted with a light rod to co~er the hole, and 10 .eledric immersion hebters each of 5 V0N. The tank has been shown inthe adjacent figure. For testing, water . is lfilled in the tank at 20C and heaters are SW1itchedon. After 15 hour of switching on the heaters water starts boiling at normal at+osPheric 'pressure. The water is then re~laced by an equal volume of oil whose boiling point is 220C at normal atmospheric prbssure and its specific gravity is 0.7. The engineer reported that th~oil took 3.15 hour to raise its temperature from 20 C to 60 C at normal atmospheric pressur.e.
1 '. .

Question

Nos. 14 to 16

Immersion heaters

Drain plug Figure: Synthetic lubricating oil tank

"/',

14.

Sol. I

From the report of the engineer the specific capacity of the oil is approximately found out (A) 60% of specific heat of water (B) 80% of specific heat of water (C) 90% of specific heat of water (D) equal to specific heat of water A The amount of oil in the tank is nearly, equal to (A) 1.2 :x 103 kg (C) 3.6 :x 103 kg8

Sol.
16I
, 1

'1
I

(8) 5.7 (D) 4.8

x x

10~kg 103 kg

Sol. I

1\ is suggested that the air in the tank above the oil can be pressurized at 4 atm above normal air pressure, which of the following is incorrect if pressure is increased to the suggested .value. (A) The time required to heat the oil would be greatly extended. (B) The drain plug would be more difficult to lift. (C) Fluid velocity would be increased when the tank is drained. (D) The tilT)e required to drain the tank would decrease. A In case of water, (5x 10~ x 10 x 15x 3600 V x PIN X S.,y x (100 - 20) In case of oil, (5 x 1o~ x 10 x 3.15 x 3600 V x Po x So x (60 - 20) 3 After solving SrlS.,., 0.6 and V x Po 5.7 x 10 kg

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Paragraph for Question

AITS-PT -II-{Paper -1 }-PCM(S )-JEE(Advanced

w
00CCiYt

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.

Nos. 11 to 19

d A space shuttle is designed in such a way that magnetic force d is used to reduce its acceleration during the landing of the shuttle on a newly discovered planet. For this planet, it was R known that gravitational acceleration above the surface of the . B planet is constant towards perpendicular downward to the planet surface and is equal to g and the magnetic field B produced by the planet is uniformly B and is directed parallel to the planet's surface. There is no atmosphere above the x y planet surface. The space shuttle is given such a shape, such that it can be idealized like conducting disc of mass m. radius R and thickness d (thickness d is much smaller than R) ,as nnnn7ne~aJlyjJY9J9)nnnn shown in the figure. x and yare two flat surfaces of the shuttle. Neglect any type of eddy current appeared during the motion.

~0-1g

17.

The amount of charge induced on' flat surface (say x) of the shuttle during the falls in the gravitational and magnetic field of the planet in terms of the shuttle speed v is (A) conR2Bv (C) f-onRdBv (B) 2coR2Bv (D) conR B v d
3 2

Sol.

A The magnetic force acting (A) conR2Bda' (C) 2conR2B2da

19,~
Sol. 19.

on the shuttle during its fall in termSof

(B) conR2B2d? (D) conR3B2a

the shuttle acceleration a is " ~)_

B
The acceleration of the space shuttle during the fall is

(A)

1+-----

9 BconR2d

(B)

'g B conR2d 1-------2

m
d

(0) B

oTIR

m
Sol.

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SECTION - 8
Matrix. - Match Type !hi1s section contai~s 3 questions. Each question contains ~atements given In two columns, which have to be matched. The statements 10 Column I are lab:elled A, B, C and D, while the statements in Column II are labelled p, q, r, s ~nd t. Any given statement in Column t can have correct matching with ONE OR MORE statement(s) in Column II. The appropriate bubbles co~resPOnding to the answers to these questions have to be darkened as illustrated in the following example: If t~e correct matches are A - p, sand t; B - q and r; C - P and q; and D - s and t; then the corred darkening of bubbles will look like the following:
I .

p
A

c
D

1.

Column-I contains some thermodynamic following columns.

system and column-II contains its properties. Match the.

Column -I
(A) Ametallic cube placed in open atmosphere, and gets heated. from surrounding (p)

Column-II
Work done by the system is positive

_-IT.:
--~

17_-_

--rr.
(8)

r"

---

~ 2 ~-1l

i!~-

(q)

a:i~,'

~ 7.1IL ~:~

:~ :;..::~ <::>-".- '0 - - -""-~6-- -:-{;l:-S?-~

rrrr"FFFF: ~

~~

Work done by the system is negative

.h The conducting

cylinder, coptaining gas and enclosed by a movable piston. The cylinder is submerged in an ice water mixture. The piston is quickly pushed down from position-1 to position-2.

I
I

i---~

(C)

~-~ 2~-d -:l2 .. Y . -~__-_- :LILA. -_

~
-7\

7:

:-iI-~

II

(r)

17v.

-~ -o~ ~ --A-.-- - --_:q.6"::-:-o.:-~-&

Iffffffff/:'

I I

Increament in the internal. energy is equal to the heat transferred to the system

The conducting cylinder, containing gas and enclosed by movable piston. The cylinder is submerged in an ice water mixture. The piston is very slowly pushed down from position-1 to position-2.
p

(D)

p;O'''r
T0I2 To T

(s)

Increament in the internal energy is less than the heat transferred to the system

A monoatomic gas follows the given process. The process 1 to 2 follows the thermodyn~mic relation (I) . T<= Tg P.

I
I

Heat is transferred. system.

into

the

Po

51

(A) -) (P, S, t) (8) ~ (q)

(C) -; (q)

(D) -) (q, t)

12
2. Column-I contains some charged following. Column -I system

AITS-PT -1I-{Paper-1 )-PCM(S )-JEE(Advanced)113

...

and column-II

contains its properties. Column - II

Match the

ChargeSystem
(A) z
y

Properties
(p) Electric filled at the origin is zero

........ + +

A ring placed in x-y plane symmetrically, having equal and opposite uniformly . distributed charge as shown in the figure. y (B) z

(q)

Electric field at z-axis, Ez is along positive z-direction for z>O and Ez is along negative z-direction for z < 0

x ++;+++++

A s4'uare placed in x-y plane symmeW~lIy, ~aving a~ternate positiv.e I and negatIve umformly dlstnbuted charge r on each side of the square as shown in the figure. (C) (r) Electric field at positive x-direction z-axis is along

-+'~
p ';" p p

Four identical dipoles placed symmetrically with respect to origin in x-y plane as I shown in the figure. f (0)
z
XX

(s)

Electric potential at any point on zaxis is zero

Electric potential at any point on zaxis is some nonzero positive value.

Sol.

(A) -~ (r, 5) (B) -)- (p, s)

(C) -)- (p, q, t)

(D) -)- (r, s)

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13
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' HC

n'

y,: 'OYr TN'

OX!

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(X'"

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3.

Column-I contains some circuits and column -II contains some properties. In column-II current signifies instantaneous current and potential difference refers instantaneous potential difference. Column - I Column - " Charge System Properties

(A) x~
E =&osin(rot) A closely sep<;llratedconducting wire is wrapped over an insulating cylinder. Wire is connected to a resistance R and an alternating source via a switch S. which is closed at t = 0

(p)

In branch

x. current

varies

"

(B)

(q)

Between points a and b, potential difference decreases always.

A charged metallic sphere of radius r is earthed with a resi?tance R and a switch S, which is closed at t =0.
l

(C)

R r
t-"NV\(\., -./

I I (r)
~ S b

In branch x, current is constant

I:

An inductor L and resistor R is connected to a cell of emf c and internal resistance r with a switch(s),which is closed at t 0

(D)

r~ ~
I: -~

I
(s) Between points a and b, potential difference is constant.

a b / A circuit (used to measure an unknown resistance) is in balanced conditions (Galvanometer reads zero)

~1Vw..J

I I (t)

Rate of heat generation through the resistor R is constant.

Sol.

(A) ---')(p) (B) --+ (p, q) (C) ---')(P, q)

(D) ---') (r, s, t)

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14
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Chemistry

PART - II
SECTION-A Straight Objective Type

This section contains 9 multiple choice questions numbered 1 to 9. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct. 1. The number of alkenes (open chain as well as cyclic) of six carbon giving same product with HBr in presence of peroxide and absence of peroxide. (A) 8 . (B) 6

~7
Sol. C

~3
Me

o
'..

Et

\
/

c=c

Et / \

Me
\

Me

/ Me

c=c

\ Me Me

Me

o
Me

Et

/ H

c=c

H /
\

Et

0(,
C;., I

.... -. ~1.;

2.

Sol.
3.

Diethyl ether is very less water soluble but Tetrahydrofuran is completely soluble due to (A) Aromatic nature of tetrahydrofuran (B) Due to Sp3 hybridisation of diethylether (C) Flipping of ethyl group prevents H-bond in diethylether (D) Diethylether stability in comparison of five membered ring intetrahydrofuran C Find out the correct match for the following compounds regarding their cis and trans configuration

(B)

Sr CHz

(C)

(D)

.
H

(E)

ir--I~CH3
l~ Sf

(F)

f:):::jC~CH~ I '.

'/

Sol.
'In'H

(A) A - Cis, B -'-trans, F - Cis (C) C - Cis, B - Cis. 0 - Cis B Because

Ltd:.'FirrJEE

(B) A - Cis, B - Trans, E - Cis (0) B - Trans, E - Cis, F - Cis

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15
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nxr

Cr"PDX

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A - Cis, B - Trans, C - Cis D - Trans, E.,.. Cis. F - Trans 4. Two drugs shown below are known as non-steroidal orally by the patient
F
((

anti-inflammatory

drugs (NSAIDS) taken

//

\_---,. \ . ./

\\

CH:;O

',:---CH- C-OH

I!

\~

\
(Ansaid) (I)

I
(Mortein) (II)

Which of the following is true: (A) I is more soluble in H20 than II (C) Both are equally soluble in water

(8) II is more soluble in H20 than 1 (D) Both are insoluble in water

Sol.

A
Because. of presence of F, it develops H-Bonding,

5.

The amino acid produced reagents. (i) PBr3. Br2 (ii). H20 (iii): NH3 , .1 (A) Alutamic acid (C) Valine,,,

when propanoic

acid is subjected

to the following

sequence

of

S I.

(B) Aspartic (D), Alanine

acid

H~.,C-CH2-C-OH -~~)
6,:

o II

PSr,

H . C-CH-C~Sr
-

II

H"C-CH-C-OH

II

Sr

8r

NH;o ,-'

, R
H . C-CH-C-OH

NH2

6.

S ,I.

Find the correct statement: (A) 2, 4-pentanedione exists more as enol content in hexane than inwater (B) 2,4-pentanedione exists more as enol content in water than in hexane (C) 2,4-pentanedione is equally stable in water and hexane in keto form (D) 2,4-pentanediene exists mainly as keto form in water than in hexane A Due to intramolecular H-bonding. Among the compounds:

7.

H,)'CH,
(i)

&
(ii)

Ph-OH (iii)

NO:

The correct order .of pKa values are: (A) IV < III < II < I (e) IV < II < III < I

(B) IV < I < II < III (D) IV < III < I < II

s ,I.

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16 OH

AITS-PT -11-( Paper -1 }-PCM( S)-JEE(Advanced)/13

NrMtN . iXCO"

r6l
Ph-OH

pKa=835 N02
pKa = 9.98

H3C-C-OH

II

pKa=476

8.

In the reaction sequence:

co
CH3

OTs , OH
1. X

2 lsCl,pyri<jne

~ ~_:

.'

'-6uOK/HluOH)

X & Yare:

(A)

(C)

cD 6J
. H
H'

(B)

o
0s0 . ~

(0) m-CPBA.

V
OH CH-.)

Sol.B OH

co
CD
'

0.0, ~fOt-.yo'O"y.at.o~

.Cb
o

OH

lsCtiP) TOS)1ahor: a: I~S- hr.deted OH 0'0 . ;::.

(r'o~t~
0-8u-'
'-BuOH

cL>
H.C==C
L \

9.

The relative reactivities of compounds A, Band C with HBr is ICH.) ICH.) ICH.) H~C==C
L \

H-C==C
'\

OCH3

CH3 (8)

CH2-O-CH:; (C)

(Ai

Sol.

(A) A > C > B (C) B > A > C 0

(B) C > A > B (0) A > B > C H- .

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Type (Assertion)

Reasoning

This section contains 4 questions numbered 10 to 13. Each question contains STATEMENT-l an~ ST ATEMENT-2 O~E is correct.
I

(Reason).

Each question has 4 choices (A), (B), (C) and (D) out of which ONLY

N-2 is better nucleophile than N-1 arx:JN-3

o.

STATEMENT-l:

In the cytosine

and

o
H3C~I.

STATEMENT-2:

In the thymine

lG~!./""
N

(111)~:~
& cytosine, N-2 of cytosine is better
nucleophile than N-2 of thymine. 0

.
for

(A) Statement-l is True, Statement-2 is True; Statement-2 is a correct explanation Statement-l. (B) Statement-l is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-l. (C) Statement-l is True, Statement -2 is False. (D) Statement-l is False, Statement-2 is True,

B
Statement 1, compare basicity of

/ 1"'I

in same molecule while in second statement the basicity

is compared between two different molecules. In cytosine lone pair of N-2 is not in conjugation while lone pair of N-l and N-3 in the same are participating mesomerism. in mesomerism, In thymine lone pair of both N-l and N-2 are taking part in

OH

STATEMENT-1:

and

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(0"

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OH

STATEMENT-2:

OH
-~

etc.'--

STATEMENT -2: (A) Statement-l is True, Statement-2 is True; Statement-2 is a correct explanation Statement-l. (8) Statement-l is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-l. (C) Statement-l is True, Statement -2 is False. (D) SV~tement-l is False. Statement-2 isTrue. Sot. 12. A STATEMENT-l: Cinnamaldehyde cannot go self aldol condensation.

for

and
STATEMENT-2: (A) It does not have a-hydrogen. for Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation Statement-l. (8) Statement-l is True, Statement-2 is True; Statement-2is NOT a correct explanation for Statement" 1. (C) Statement-l is True, Statement -2 is False. (D) Statement-1 is False, Statement-2 is True. C In Cinnamaldehyde e.g. PhCH (PhCH
.

Sol.

= CH -

CHO) there is no acidic a.-hydrogen.

-

= CH -

CHO~PhCH

= C~ CHO

The carbanion is not sufficiently stabilized . . 13. STATEMENT-l: When mixture of 1 mole of benzaldehyde and 1 mole of cyclohexanone is treated with semicarbazide. semicarbazone of cyclohexanone precipitates first and finally precipitate of semicarbazone of benzaldehyde is formed. I and STATEMENT-2: Initial one is kinetically controlled product and the other one is thermodynamically controlled product. (A) Statement-1 is True, Statement-2 is True; Statement-2' is a correct explanation for Statement-l. (8) Statement-l is True, Statement-2 is True; Statemenl-2 is NOT a correct explanation for Statement-l. (C) Statement-l is True, Statement -2 is False. (D) Statement-1 is False. Statement-2 is True.

Sol.

A
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~ITS-PT -110{ Paper -1 }-PCM(S)-JEE(AdvancedV13

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Comprehension

Type

I . Tlhis section contains 2 groups of questions. Each group has 3 multiple choice question based on a P1aragraph. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is cprrect. . Paragraph for Question (yellow precipitate) Nos. 14 to 16

(C,:,03J

"0:,0.

!ekO

I
o,~ C
0, Zn,HzO

)8+0

Jleasant

smell)
1. CH.o,O-Na~

1
.

2. CH3

Br(1eq) G

HO, H;:0
.1

1 OK" (excess),~

-CH~
2 K"
.:',

14.

Compound C is (A)

. (BY

(C)

(D)

srI.
I

B Compound
j

15.

is

o
II
.>

H-C-C-CH -CH-C-O-CH
2

1/

(A)

(B)

CH3

(C)
I SFI. 16.
I
I

CH.O 3 II 1 11 ~C-C~-C-?-C-O-C~
CH3

(D)

D Compound B is (A) It is pleasant smelling, red coloured liquid (B) Sold in paint stores for general clean up work (C) It is less volatile than water (D) All the above B
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20
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AITS-PT -1I-(Paper-1 }-PC M(S)-JEE(Advanced)/13

o
(C)H~C-y=CH-t-eH3.

--

"

o
(D}H,C-C-C-H

CH~

~ ;
CH3

l!

"

o
o
H

II

II 0

(ElHoC-C--CH-C-O-CH , _!

o
CH3

II I
CH3

(F)H~C-C-CH2

(G) HO-C-CHo

o
(H)

o
I
2

II
CH3

II
(J)

o
II
3 2 I

0
II

CI-C-CH

(I)H,C-O-C-CH3

H C-CH -C-O-CH-C-O-CH

H,C Paragraph for Question Nos. 17 to 19

CH3CO H+ E (KM~O.

a.dation

A[C H ]
9

j.
II

12

H,!3eq)
Pd-C)

B C9H~6

aq, H2S04

HgS04

C+D (isomeric ketohes) .

o
O 'If E __ II T-CH2OH

H2C-C-OHO

II CH C CO' 2- H2- 7- H

and compoundC gives positive iodoform test

Compound B is (A) CH3

(8)

O-CH2CH2CH' (D)

Sol. 18.

C Compound C is

(8)
(A) Q-CH'CH2CH2CH,

o
(C) (D)

Sol.

D
Hou~.,

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y
'OT'

)-JEE(Advanced)/13
'itp(<<
't<MWtidttSlXtro>X
W OJ

21

'0

yy n . Y

Y -C"fPtSfU'

"5st"'Ptt'tttt:CWetSXt"

'ON

'W

rt(ii'(C''',wti

rtxAX#U((t<M

'0 y,o,."X"to"o

. x,

19. (B)

(0)

Sol.

Solution for the Q, No. 17 to 19.

o-CH2-CH2-CH2-CH3

(B)

I 0(C)

CH2CH2C-CH3

11

\ i~

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AITS-PT -"-(Paper~ 1)-PCM(S)-JEE(Advanced)/13

'cxmttt'PttYd'tt'H

SECTION-B (Matrix Type) This section contains 3 questions. Each question contains statements given in two columns, which have to be matched. The statements in Column I are labelled A, B, C and D, while the statements in Column II are labelled p, q, r, sand t. Any given statement in Column I can have correct matching with ONE .OR MORE statement(s) in Column II. The appropriate bubbles corresponding to the answers to these questions have to be darkened as illustrated in the following example: If the correct matches are A - p, sand t; B - q and r; C:.- p and q; andD - s and t; then the correct darkening of bubbles will look like the following: 1. For each of the statements in Column I, choose a substituent
p q

A@)00@Et9 B0~@00) c@@(00)

D

(~)0)0@@
II that fits the

from Column

description, for the compound.~z

Column..J Z-donates electrons. inductively, but does not donate or withdraw electrons by resonance Z-withdraws electrons inductively and withdraws electrons by resonance Z-deactivates the ring towards electi'ophile and directs ortho, para positions Z-withdraws electrons inductively but donates electrons by resonance and activates the ring. Column-II (p) (q) (r) (s) (t)

(A) (B) (C) (D)

-OH
-Br -O-R -Et -N02

I
i

I
I
!

Column-II (p)

!~~!X rOT n ~
.i.
.

CD3

(q)

(r)

I I (s)

~CH' .d-iH
~o N(CH3h(OD) ....
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i,

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I

A\TS-PT -1I-Waper-1t-PCM(S)..JEE(Advanced)113

23
mnxT'X'$'Q) ,

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A ~ s; B ~ r, t; C ~ q; 0 ~ p, t
Cope elimination (a typical syn-:elimination) General mechanism:

R1 04.1+

$~~'
3. Match the following: (A) (B) (C) (D) Sol. CgHg' C9H~ C4H~' C 4H~'

"
/

C/

II

"
Column-ll (Properties)
(p) (q) (r) (s) (t) Contains 2, n-electrons Contains 6, n-electrons Contains 8.n-electrons Aromatic in nature

Column-I (Monocyclic species where I all carbon atoms are part of cycle)

Contains 10,n-electrons

A ~ s, t; B ~ r; (A)

C ~ p, t; D ~ q, t
(B)

'.,

(C)

W
.

8
(D)

.~

[]0

[]V

r>.

I
'. '. :... -.1., I' ',"Ju'
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24
p' '(

AITS-PT -f1-(Paper-1 }-PCM(S)-JEE(Advanced)/13

-'O?T'"rtrtOXxit ""oxt"
'ttf)Y-O

Y'=,(Y"cneooz

"y;"."tC" t1)YOT'-CiNfd't<t'tt'Xit

.,...,.-Y'r:XtYXf'i

"

Mathematics

PART - III
SECTION -A

Straight Objective Type

This section contains 9 multiple choice questions numbered 1 to 9. Each question has 4 choices (A), (B), (C) and (0), out of which ONLY ONE is correct. 1. px + qy 40 is a chord of minimuml.~n~th of the circle (x - 10)2 + (y - 20i passes through (5, 15). Then (p2013 + q'o,) is equal to (A) 0 (B) 2 2014 (C) 22013 (0)2

729. If the chord

Sol.

o
-=-1:::>p=q

Now, 5p + 15q = 40 :::>p + 3q

= 8 :::>p = q = 2

2.

-=-=-----

mt2 -1

503t 503t

2:.:2013m
4026

=>

m=--- m=--

e'

:::>

t =

/4026 ')1/3 -1-\ 503

:. Only one common tangent 3. The number of ordered pairs (x, y) satisfying Ixl+ IYI

= 3 and

sin( 2x

\3

!
j

= 1 is/are

(A) 7 (C) 9

(B) 8 (0) 10
'\

Sol.

B
i

sinl2x2

,3

=> x2 = 2(4n+1)

/ 3

1=1
for n

= 0, 1 only
=8
I'll

=> x = :t~2 ' :t~-2- and for each x, there are two values of y .

f3

'15

:. The number of ordered pairs

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-1I-{Paper-1 )-PCM(S)-JEE(AdvancedV13

25
.r'
nXS?Xii '

nxsn

?Z>'tf . , ..

)>>

4.

If the asymptotes of the hyperbola (x + y + 1/ - (x-y - 3)2 = 5 intersect at A and the coordinate axis at Band C, then the equation of the circle passing through A, Band C is (A) 4(x2 +y2)~4x+6y+3 == 0 (6) 4(x2 +y2)-4X+y ",0 (C)

x2 + l

-x + 2y == 0

(D) none of these

Sol.

C
Centre of rectangular hyperbola is (1. -2) :. Equation of Asymptotes are x = 1, Y =-2 Radius of circle =

J5 .
2

5.

>

Sol.

Let PQRS be a square with length of the side 10. The points A and 6 are taken on the side PQ and C is taKen on the side RS. Then the circumradius of the triangle ABC can be (A) 3.1 (6) 4.2 (C) 5.5 (D) 8 C Let M be the circumcentre Now MA + MC ~ AC ~ SP = 10 :. The minimumvalue of circumradius = 5 Now a circle through PQRS has the radius :. 5:0:: radius s

5.J2

and the points P,- Q, R lie on or inside the-square

s.J2
If

6.

In triangle ABC with A as obtuse angl,~_,AD and AE are median and,.\,,~ltitude respectively. ~AD == IDAE == IEAC , then sin3 A cos A equals ," 3 3(.
3

(A) 3a

64b2c
3

3a3 (6) 128b2c (D) _ 3a _ 512b"c

3

(C)3a 256b2c

Sol.

6
Clearly triangle ADC is isosceles. =:. AD = AC = b =:> DE = CE ~ ~
4

Now sin3 A cos ~ == sin2 A 2sin A cos A 3 3 2 3 3 3 1 . = -Sin

2

A . 2A -sln-

1 (EC')2
= "2

b;

(BE}
I,AB

a2

== "2'16b2

'4'c == 128b2c'
+ sec"(x

3a 1

3a3

7.

If sin" (x2 + y2) + tan" (A) (-1,1) (C) R C x2 + y2 ::; 1,

Jy2 - 2

- 2)= K has no solution. then exhaustive range of K is ( 1 (6) 1--'==,

--/2

1' -1 .J2)

(D) none of these

Sol.

lYI:?.J2

and

Ix -

21 ~ 1

No such (x, y) exists :. K E R

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'O"LSlf ' "q .. Y" "r - - -0- X'X

AITS-PT -II-(Paper-1 }-PCM(S)-JE

ea:c

E(Advanced)113

"""""'J)YW'O

8.

P is a point '{' on the parabola y2 4ax and PO is a focal chord. PT is a tangent at P and ON is a normal at O. The minimum distance between PT and ON is equal to '1\ (A) 0 (B) ,j1+e + ~1+e

al

(C) a Sol. C P(at2,

t +1

)3/2

j--z

(D) a-v1+ t

t2

2at) ,

o( t~, _ t ,
a
2

2a1

Equation of tangent PT is ty = x + at" 2 Equation of normal at is xt - yt3 - a - 2ae

=0

:. PT II aN
d = l-at
4 -

a - 2ae 1= ah

+ 1)3/2

,)t4
9. WS
Sol.

+ t6

t2

The area enclosed by the curve max (C) 10 A Area enclosed by the region ABCD 2k' 2k => 4k~ 100 k=S

{Ix - 11,WI} = kis

~8

100, then I<. is equal to

(D) none of these

= =

Y =k
x

"

BY
x=k+1

=-1<.

x=1-k
Reasoning Type

This section contains 4 questions numbered 10 to 13. Each question contains STATEMENT-1 (Assertion) and ST ATEMENT-2 (Reason). Each question has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct. . ab - rr . STATEMENT 1: In tnangle ABC, 12 == R .

10.

r3

STATEMENT 2: In any triangle ABC. _a_ = _b_ =._c_ = 2R . sinA sinB sinC (A) Both the statements are true and Statement 2 is correct explanation of Statement 1. (B) Both the Statements are true and Statement 2 is not the correct explanation of Statement 1. (C) Statement 1 is true and Statement 2 is false. (D) Statement 1 is false and Statement 2 is true, Sol.

o
ab = 4R2 sin A sin B rh = 4R2 sinAsinBcos2
~

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27

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I

ST~TEMEN~1: If xox:::l are the 1::9th of the segments of the focar":~:':~"~:IiPse whose latus rectum is given by 2(x). Then major axis of the ellipse cannot exceed 2. STATEMENT 2: Semi latus-rectum is the HM between the segments of the focal chord. (A) Both the statements are true and Statement 2 is correct explanation of Statement 1. (B) Both the Statements are true and Statement 2is not the correct explanation of Statement 1. (C) Statement 1 is true and Statement 2 is false. (D) Statement 1 is false and Statement 2 is true.

Ix)

= --

2x{x}

x+ {x}

=> [xl

b2 => -=1

=> a(1 - e

= 1 => 2a > 2

STATEMENT 1: The normals at the ends A and Bof a focal chord of the parabola y2 = 4ax meet the parabola again at C and D respectively then AB = 3CD because. STATEMENT 2: The normal at 't,' (A) (B) (C) (D) A meets the parabola again at 't2' then 12

= -t, -

3...
t,

Both the statements are true and Statement 2 is correct explanation of Statement 1, Both the Statements are true and Statement 2 is not the correct explanation of Statement 1. Statement 1 is true and Statement 2 is false. . Statement 1 is false and Statement 2 is true.
. 2

Let A = (at , 2at),

B=

(a12' - 2a'

-t )

Also normal at A meets the parabola at C

, (2' . ... c=lai-t--) ... 2

/ 2' ' '(1 ,2a(-t--lJand.D=la!-+2tl.2al-+2tl . \ L \ ~t

"2

'1 t

") /.

Sol.

STATEMENT 1: In any triangle ABC. the minimum value of cot2 A + cae B + cotL C is .J3 . STATEMENT 2: y = cot x is a concave downward curve in 10, n). (A) Both the statements are true and Statement 2 is correct explanation of Statement 1. (B) Both the Statements are true and Statement 2 is not the correct explanation of Statement 1. (C) Statement 1 is true and Statement 2 is false. (D) Statement 1 is false and Statement 2 is true. C Comprehension Type

I'

This section contains 2 groups of questions. Each group has 3 multiple choice question based on a p~ragraph. Each question has 4 choices (A), (B), (C) and (D) for its answer. out of which ONLY ONE is I . ct;>rrect. Paragraph for Question Nos. 14 to 16

R:ead the following write up carefully and answer the following questions: Bly taking B(-3, 0) and C(3, O),triangles PBC of perimeter 16 are constructed. If S is the locus of incentre of triangle ABC, then 11
1 ,

I SOl.

Equal.ion o! S is (A) x< + 4yl = 4 2 {C)x +4l=12 B As ID -.LBC

FIlTJ" Ltd., Tlrr.fE
HOUH,

(B) Xi + 4/ 9 (D) none of these

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Now x = BD - BO = 5 - b ~ b = 5- x ".C=10-b=5+x Now /j (8y)2

2

~8(8 - 6)(8 - 5 + x)(8 - 5 - x) - x)

----------

= 16(3 + x)(3

~ x +

4l = 9

. 15.

A ray emanating from (- 3;3 . equation of the reflected ray is (A) 4x + 313y = 12 (C) 8x + 313y = 1213

0)

is incident on the curve S at P whose ordinate is

%.

The

(B) 4x - 3.)3y = 12.)3 (D) none of these

Sol.

C Equation of s is x2 + 4y2 = 9 p;:

(0. ~I 2/

313 \ Foci are ( :1:-. -.0

Equation of the reflected ray is 8x + 3.J3y = 1213 16. Twoc:perpendicular tangents to S inter-sect at O. then 1001 is equaf to (@ being origin) ~ (A) }..;~ (B) . ?}2

J5

";'.~

(C)~-j3 2

(0) none of these

Sol.

Paragraph for Question Nos. 17to 19 Read the following write up carefully and answer the following questions: let 0(0, t) is a variable point andR = (3, 0). PO is drawn perpendicular to RO to meet the variable line y = 2t in P. let S represent the locus of P. 17. The equation of S is (A) xy

=4

(B)

r\ x-~Y 2)
3 6

+(y-3i

= 19

(C) y2 = 12x

x2 y2 . (0) -+-- = 1

Sol.

C
Equation of PO is Y - t = ~(x - 0)
t

.'. Coordinates of P

= (.~.

2t]

/'

18.

.... locus of P is y2 = 12x The chord x + y = 1 cuts the curve S in points A and B. The normals at A and B intersect at C. A third line from C cuts the curve S normally at O. Then the coordinates of Dare (A) (3, ~) (B) (0, 0) (C) (6. -3) (D) (12, 12)
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29
taN

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tT'l'C"..-' '(

D Let A : (3m~, - 6~), B': (3m~, - 6m2), -6m2 =1

0: (3m~, - 6111:3)

A and B lies on x + y = 1 ... 3m~ -6m1 =0 and 3~

:. m; - m~ - 2( Ill, - m2) = 0 Ill, + m2 = 2 ~ --m3 = 2

:. Coordinates of 0 are (12; 12) How many nonnals can be drawn from the point (A) 1 (C) 3 C As h > 2a :. 3 nonnals can be drawntos SECTION-B (Matrix Type) Ttlis section contains 3 questions. Each question contains statements given in Itwo columns, Which have to bematched. The statements in Column I are la!,)elled A, 8, C and 0, while the statements in Column II are labelled p, q, r, s ~nd 1. Any given statgmentin Column I can. have cOJrect matching with ONE OR MORE statement(s) in Column II. The appropriate bubbles coirresPOnding to th~ aQ~wers to these questions have 19 be darkened as illustrated in the foHowing example: I . If the correct matches are A - p, sandt; B - q and r; C - P andq; and 0 - s ~jd t:then the correct darkening of bubbles will look like the following: 1.
p q r s

(.J37,

-10)

to s

(8) 2 (0) infinite

Sol.

ACB900@E!9
B

0 ~"'EfD.0c)
Ci)~{~) 0 C0

D~00CDCD

(A) ~ The 4 Which (A) A

(r). (Bl-~ (r) (C) ~ (p) (D)~ (q) 2 points of intersection lie on 2x + 12x - By + 26 = 0 (by adding) is a parabola with vertex = (-3, 1), S = (-3, 2) and directrix y = 0 = 0, 8 = 0; g = 3, f = -2, c = 13 ~ g + f + c = 14 a2+132+1=14

(B) a=-3,p=2:.

(C) Required sum = sum of these points from y = 0 = sum of the ordinates of these points These points of intersection also lie on 20y + 59 0 :. Sum of ordinates = 20 (By subtracting) Since these points lie on a circle and hyperbola so we get a pair of points with same ordinates. Hence sum = 40 .(0) As SG SP 5

l-

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2.

Match the following Column-I

with Column-II (p)

(A)

(8)

(C)

Let P be any point on the parabola = 8x between its vertex and positive end of latus rectum. If 5 be the focus and Nbe the foot of perpendicular from 5 to tangent at P. then possible integral values of area of triangle PN5 is A chord is drawn from a point A(1, a) to the parabola = 4x which cuts the parabola at P and Q such that AP'AQ = 31al. then 'ex' can take the values A trapezium is inscribed in the parabola = 4x such that its

(q)

(r)

diagonals pass through the point (1, 0) and each has length the area of trapezium is A then 16 A is equal to

25 . If 4

25

(D)

Normal to the parabola yl. = 4x at points P and Q of the parabola meet at R(3, 0) and tangents at P and Q meet at T (a., 0), then area of the quadrilateral PTQR is equal to (B) ~ (p. q) (e) ~(s) (D)~ (r)

(s)

12

Sol.

(A) ~ (p)

(B) Equation of the line thro (1, a.) is x -1 cosO ~ (rsinO + o} ~ Ap

2

Y.- a
SIOO

= r . It meets

the parabola at P and Q

-

= 4r(.rcos6
2 -2

+ 1) ~ r2 sin2 H + 2r(tsinO ""t2cose) + (a2

4)

=0

x AQ == 1a.
--

sin
2

e'-

41,~3lal
lal ~ 4
R

la31al41 -

sin e:s; 1 ~ (Ial + 1)(10.1- 4) ~ 0 ~.

(C) The diag0!lals arc the focal cords of the parabola PF 1 + t< a (say) 1 1 5 :. -+-----=1 = a=-. 5

Fora For ex 50 P

25/4-ex 5 2 = -. 1 + ex 442

=-

1 = I = :i~

= 5. t = :i2
= l' ~,
4

11. R = (4, 4), 5 = (4, -4), )

= -75
4 ~ a -2at)

== (~,

.4

11 i

.', Area of Irep (D) If P(a1

2 ,

2at) then

Q = (af,

-at2 x (a,O)

For R, t :t1 ATt=1,a=-1 :, PM = 2at ~ RT= 4

=2 =

Area of quadrilateral

i (i;.-.
x

4 x 2)

= 8 sq. units

'JrfJff

Ltd., FIlTJEE"Hou5',

79.A.

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YU?XXUC"!'WQ

3.

Match the following Column-I (A)

2

with Column-II

If the cirde x +

y2 -

4 X - 6y + k

=0

does not touch or

(p)

(-1,3) -3)v(
4, x,)

intersect the axes and the point (2, 2) lies inside the cirde, then k can lie in the intervallintervals (B) If the line 3x + ay - 20

=0

cuts the circle x2 + y2

= 25

(q) (r)

(-:Y:,

(C)

at real, distinct or coincident points, then a belongs to. If the point (2, k) lies outside the circles x2 +
y2

+ X - 2y - 14

=0

and x2 + y2

= 13,

then k (s)

(~J:.,-,j7Jv[ -fi,oo)
(9, 12)

belongs to the interval (D) If the point (k + 1,k) lies inside the region bounded by the curve x = ~25 - y2 ,thenk (A) ~(q. r, s) (B) ~ (r) belongs tothe interval (D)~ (p)

(e) ~ (q)

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FIITJEE

.JEE[AdvancedJ.20 13
ANSWERS, HINTS & SDLUTIONS PART TEST . II PAPER.2

a.

o NN
a. <r-

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Physics
1 2. 0 0 C C

PART -I

.- W ~W
-I

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0.-

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3.
~ 5. 6. 7.

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0-

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ABC
A A A B A ADD A A 0 A C

A
0

E e
ns
L. .-

0 0).. o 0
L.

Q)

0.-

E Q) o (/)

C C B

:n

0_

(1) .

ns

8. 9. 10.
11

C
C

ns 0 u ...

0;1; .s:;M
Cl>06

1::N

A B A

o o o
A
B A A C

.. A A
B

A A

o
A B A
C

::J e .- ns

E~

~o::
~o

12. 13. 14. 15. 16. 17. 18. 19. 1

o
A A B

1
!

o
A
B

u~

e a.. C'O
(/)..-

o
A
C

o
A B

o
A
C

o
A B

i
i
~ ~ ~ ~ (5) (r) (q) (p) (r) (p) (5) (q)

E C'O
1...

1...0)

.-

g>t.D
EO
L.

..

0..0 ON 00.

o
(A) (B) (C) (0) (~) (B) (C) (0) ~ ~ ~ ~ ~ ~ ~ ~ (r) (p) (5) (q) (5) (p) (q) (r)

o
(A) (B) (C) (0) (A) (B) (C) (0) ~ ~ ~ ~ ~ ~ ~ ~ (5) (r) (q) (p) (5) (p) (q) (r)

o
(A) ~ (B)~ (C) ~ (0) -4 (A) (B) (C) (0) (A) (B) (C) (0) ~ ~ ~ ~ ~ ~ ~ ~ (5) (p) (q) (r) (5) (r) (q) (p) (r) (p) (5) (q)

o
(A) (B) (C) (0)

.... !!! .S
~
UlO

Er--.
I... 2.
e
0)

~
.J

(A) ~ (B) ~ (C) ~ (0) ~

o E o I...
3.

I j
I

(A) ~ (5) (B) ~ (r)

(C) ~ (q)

LL

~_-lJ0)

~ (p)

(A) ~ (r) (B) ~ (p) (C) ~ (5) (0) ~ (q)

(A) ~ (5) (B) ~ (p)

I

(C) ~ (q) (0) ~ (r)

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Ohemistry
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1.
2.
3. 4.

PART - II

:><::>:')--i~it.wll.)-;
B
C
0 D.A B C B

o
o
C B A

B
B

5. 6. 7. 8. 9.
10. 11.
I 12.
I

B B C B A
B
I;A

o
DC
B

BC

o
A B

o
A

113.

t 14.
t . I 15.
~

o
17.
B A B A
1

-1:
I A B

]A

I 18.

A
A (A) --) (r, 5) (B) --) (p, r, s) (C) --) (5, t) (D) --) (q, 5) (A) --) (q, 5) (B) --) (r) (C) --) (p, 5) (D) --) (q, 5)
5, t)

-,
I
I

19
1

A
(A) --) (p, r, s, t) (B) --) (q) . (C) --) (p, q) (D) --) (q) (A) --) (r, s) (B) --) (p, r, s) (C) -~ (s, t) (D) --) (q, s) (A) --) (q,r, t) (B) ~ (r)
I

0
(A) --) (q,f, t) (B) --) (r)

o
(A) --) (q, r, t) (B) --) (r) (C) --) (p, s) (D) --) (q, s) (A) --) (p, (B) --) (q) (C) --) (p, q) (D) --) (q) (A) --) (r,s) (B) --) (p, r,s) (C) --) (5, t) (D) --) (q, s)

1.

(C) --) (p, s) (D) --) (q, s)

(A) --) (r, s) (B) --) (p-,
f,

I I 2.
i

r, t)

r, s, t)

(C) --) (5, t) (D) --) (q, 5) (A) --) (p, "(B) --) (q)

I
I

rI I I 3.
I

r,

(A) --) (p, (B) --) (q)

r, s, t)

(C) --) (p, s) s)

I (D) --~ (q,

I (D) --) (q)

Vlhar,

, (C) --) (p, q)

(C) --) (p, q) (D) -~ (q)

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Mathematics
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PART - III

QillN~'::".:;: :;.':m9V>."
8 8 8 8 8
A

8 8 8 8
C

8
A

o
8 C 8 B 8 8
A

4. 5.
6.

8 8 8 8 8 8
~!~":.~

7. 8.
9. 10. 11. 12. 13. 14. : 15. 16. 17.
1

0 8
C D A

o
A 8

o
8

o
8
'0

A
-;'.\';

0
----1_ 1

o
A

0 0

iA
;
I

o
fA
8
A

A
B A B

iB

IA -----i 8
o

10
I

10
I

18. 19.

IA
IB (A) -" (q) (8) -" (p) (C) -" (r) (D) -" (s) I (A) -" (p, r)

I~
A

I J
!

0
(A) -" (s)

o
(A) -" (p, r) (8) -" (p, q) (C) -" (q, r, s) (D) -" (p, q, s) (A) -" (q) (8) -" (p) (e) -" (r) (D) -" (s) (A) -" (s) (8) -" (q) (C) -"(r)
I

8
(A) -" (q) (8) -" (p) (C)-" (r) (D) -" (5) (A) -" (s) (8) -" (q) (C) -" (r) (D) -" (q)

1.
'"

(B) ----)(q) (C) -"(r) (D) -" (q) (A) -" (p, r)

'.
II

2.

(8) ~ (p, q) (C) ~ (q, r, s) (D) -" (p, q, s) (A) -" (q) (8) -" (p) (C) -" (r) (D) -" (s) _~)

I (8) -" (p, q) I (C) -" (q, r, s)

(D) -" (p, q, s) (A) -" (s)

rl
I
i

(A) -" (p, r) (8) -" (p, q) I (C) -" (q, r, s)

f 3.

I (8) -" (q)

I
i
~.

I (C) -"

(r)

-~ (q)

(D) -" (q)

I (D) -" (p, q. s) I

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-PART -. SECTION-A
. Single Correct Choice Type

Th1issection contains 9 multiple choice questions. oul of which ONLY ONE is correct.

Each question has four choices (A), (B), (C) and (D)

2.

In the figure Box-1 contains one capacitor and one resistor Box-2 contains 1 inductor and one resistor R, resistance in Box 1 R2 resistance in Box 2

= =

Power factor of Box 1 Power factor of Box 2

-r

1
Vosin(rot)

--/5
'0/5

1 = - r=

.
Power factor of Box 1 + Power factor of Box 2 Power factor of Box 3 1 = -----,=

1
----,=
'

--/2

Resistance of Box 3 R, + R2 Current I = sin(wt + ~) On the basis of above mentioned information pick the incorrect option from below:

'a

.J2

(A) ~

Rz

=3
Vo sin(Cilt)

(B)

Z3 =

4.i2R2 (Impedance of box 3) n may be some integer.

(C) 1=

4Rz

(D) (j!

= (2n + 1)n, where

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.,- '-XC",,"Q)xo'o" . mau' 'ECN xno trC'O'scxtcO?'Q$dutttt<:SOXK#t
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Sol.

0
2 1

1 Box 1: 1 -ffiC1 -=2

'

1/roC,

R,

"

"

4>,

Box 2:

wL1 = 2

R, R2
"

Rz
rol,

'.

" "

4>

,sOx 1 + Box 2

1 "-- rol,
ffiC1 =1

R1 +Rz =:> 2R, ~ 2R2 = R, + R2 =:> R, = 3R2

For Box 3:

Impedance of Box 1 + Box 2 = Impedance of Box 3

.'4,~,
~\~

(R, + Rz)12

= 4--J2 R2, phase angle is

1t/4

4--J2 R2, phase angle is -n/4

Current in Box 1 + Bo~ 2 Current In Box 3 = 12 = , = I, +

= I, = ':J.

4",2Rz

sin(wt ~ ~) 4

Vo . ( 1t \1 r;:; SIAl wt - 4",2R2 \ 4;

'2 = 4R Vo
2

sin( t)
(J)

' 3 Vosinffit Impe d anceo f B ox 1 +, B ox 2 +. B ox = ---= Phase angle is zero,

4R'

an

d'

IS

..' t resistive In na ure

'

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AITS-PT-U~Pape~-2)-PCM(S)-JEE(Advanced)/13
it O'

3.

In the figure, OA and OB are two uniformly charged wires, placed along x and y axis respectively. The unit vector in the direction of field at point (0, 0, -Y3L) is

(A)
(B)

-11 + 4} - 313k

144
-11 -

-40 A x L

41 + 313k
144

(C)-1i+4
(D)

ffi
-11 :=1~
.J2
Sot
A

E=

- -- E.i +--k E13. - 2Ey3k ~. + 2Ej "

2 2
y
4E

.
:. E
=

-11+41-3J3i<

.J44
E

x
"r" .

4.

In the figure, A, B, C and D are four concentric spheres of radius a, 2a, 3a and 4a and contain. charges +3q, +6q. -9q and +12q respectively. In the beginning switches 81 and 82 are open. After earthing the sphere C, Ilq1 amount of charge flows from the sphere C to the earth. If the sphere B is also earthed, then Ilq2 amount of charge flows from the sphere B to the earth, the value of IIlq1 (A) (B) (C) (D) 1 3/5 2/3 1/2

I is equal I tiq2 I

to

,!!!!,!!!!!!,!!!!!!!!!!!!!!!!!!,!!!!!!!!,!!!!!!!!,!!!!!!!!!!!!!!!!!!!!!!!!!!!!,!!!!!!!!,!!!!!!!!!!!!!!!!!!,!!!!!!!!,!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!,!!!!!!!!!!!!!!!!,!!!!!!!!!!!!!!!!!!!!!,,,,,_'!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!~!!!!!!!!!:l!!:!!!!:!!!=!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!

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'XStTf D'1

7
00?tt2N

xt ..

":00

Sol.

_1_ [3q
4m::o 3a

-+

6q -+ ~
3a 3a

12q -I =
4a

12q

q, = -18q ~~q11 = 9q

1
41tco

_1_

4m,o 2a Solving

[3 [3

q q2

q3

12q 1 0

12q

3a + 3a + 3a + 4a

J=

q + q2 + ~ + 12q]
2a 3a 4a

q2

= -3q l~q21= 9q I ~q2 I = 1

I L\q, I

5.

A charged particle having charge q and mass m is projected into a region of uniform electric field of strength

Eo,

force particle

with velocityVo perpendicular to Eo' Throughout the motion apart from electric also experiences a dissipative force of constant magnitude q Eo and directed

opposite to its velocity. If

I Va 1= 6 mis, then

its speed when it has turned through an angle of 90, (8) 5 m/s (D) 2 m/s

is equal to
(A) 3 m/s (C) 4 m/s

Sol.

A
Consider the situation when particle turned through an angle of <jJ dv dt dvx ---dt ~
.~

has

= _ qEo [1- sin$]

_qEo[1

m dv = _ dvx
dt

. ",] -Sin,;,

dt v sin
:=

v = -vx + C
v

qEo

= vo -- Vx = vo 1+sin~,

q,

v = --~

=~

1+1

3 m/s

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A uniformly conducting wire is bent to form a ring of mass 'm' and radius 'r', and the ring is placed on .a rough horizontal surface with its plane horizontal. There exists a uniform and constant horizontal magnetic field of induction B. Now a charge q is passed through the ring in a very small time interval Llt. As a result the ring ultimately just becomes vertical. Calculate the value of g (acceleration due to gravity) in terms of other given quantities. Assume that friction is sufficient to prevent slipping and ignore any loss in energy. (A) ~
2

(:r
2 2 --

(B) ~-q6 m2r

2B2

(C)

(q B r)
2m

1t

Sol.

A
Angular momentum, (~mr2)(!)= \2 For the ring to become vertical, .

ldt =

f .dq nr Bdt dt
2

== q1tr2B

2 2

1(3

-mr

2\1
j

2 ill

= mgr

I.e. g=-

1t

2( --I
q B,2
m/

A nQn-conducting wire is bent into a semi-circle of radius R and a chafg'e + Q is uniformly distributed o:~er it as shown in the figure. Find ithe ratio (~:

J of the potential

+0 B+
+

(VA) to the magnitude

of the.

. -------,--------e
:

:0

',A .

electric field (E~, both evaluated at the other end A of diameter AB that bisects the wire (as shown in the figure) (A) R (B) 2R (C) R In (1+12) (D) 2R In (1+

:EA, VA

12 )

Sol.

B E
=
o

. 1 dq I---coso. 4ns r2 o

,.

v=

r_1~dq;

. 4m:o r

where r = 2R cos

4>

+,

, ,
, I

8.

In the figure ABCDEFA

is a closed conducting
2

wire loop. = 1and

The part AFE is a portion of an ellipse, BCD is a portion of the ellipse -+-=1 9a2 4a2 A uniform magnetic field

X2 + 4a a

y;

x2

y2

B ==

Bok. exists in this region. If the frame is rotated about velocity

'r.:)".

the y-axis with a constant angular maximum emf induced in the loop is,
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YN

9
"#(" 'zrtP>tr" 'itttM

",,:,,:,:,w

ttaNtriX

"1YN

' .Nf(

trcox'

(A) (C) Sol. C

1UJ.)

Boa2 _

2
21tCl)Boa 2

(B) 1tlJ)Boa2 (D) 1.S1troBoa2

a, = 2a
a? 3a Area of wire frame n(a2b - alb,) -----=21ta 2 <\l 21tBoa2 cos(lJ)t}
2

= - dljl = 2ll:(J)Boa2sin (rot) dt

peak emf = 211lJ)80a2

9.

In the figure 8" B2 and 83 represent uniform time vaJ)'ing magnetic fields in three different infinitely long cylindrical regions with axis passing through P, Q and Rand perpendicular to the plane of the paper. PQR is an equilateral triangle of side 4"';3 r, where r is the radius of each cylindrical region (r = 1m). The magnetic inductions vaJ)' with time t as B, A+ at, 82 = A - bt and B3 = A + ct. Here a = 2 Testa/s, b = 2 Teslals and c 1 Tesla/s and A is a constant with dimensions of magnetic field and 't' is time. The induced electric field strength at the centroid of the triangle PQR is,

(A) --VIm 8 1 ' (B) - V 1m 8 (C) .. ./13 VIm 8 (D) zero Sol. C The contribution cylinder

,,'S

due

to

anyone .

the

4J3r - - - - - - -3> 0... --------------------__ .j.?9 Q

':- __ EZ~OO E, _'-:' , 4 ' "4 , r, . . " - r ,,
"

<- - - ~~.
, ", , , \

IE 1=~ldBI

= CldBI = !ldBI 2x dt 8r dt 8 dt

'....,'

IE,I =!V 1m 4 IEzl = 1/4 VIm IE 1 = 1/8 VIm

3

O.

E'
3,

,.

-,

(directions as shown in the figure)

,
'",

...

, ,, , ,

:4r / ,,

.
'

IE, + E2 + E31

1-

-.

,,'13
VIm

R
San:apriyu. V,iebs,t~: Fifwr,
UlH"1,{:

E3
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AITS-PT -11-( Paper -2)-PC M(S ).JEE(Advanced)/13

nrx

Assertion This
I

- Reasoning

Type contains STATEMENT-1

section

contains

4 questions

numbered

10 to 13. Each question

(A~sertiOn)

and STATEMENT-2

(Reason).

Each question has 4 choices (A), (B), (C) and (0) out of

whlich ONLY ONE is correct.

101
I

STATEMENT-1: A constant potential difference is maintained between the inner and outer surfaces of an annular homogenous and isotropic conducting sphere of inner radius 'a' and outer radius'b'. The drift speed of charge carriers (Le. , electrons) decreases, with increase in distance from the centre.

and
STATEMENT-2: As we move away from the centre, the electric field decreases in magnitude. . (A) Statement-1 is True, Statement-2is True; Statement-2 is a correct explanation Statement-1. (B)Statement-1 is True, Statement-2 is True; Statement-2is NOT a correct explanation Statement-1. (C) Statement-1 is True, Statement -2 is False. (0) Statement-1 is False, Statement-2is True.

for for

50[1.
11

A
STATEMENT-1: . In the circuit shoWh in the figure initially S~ is closed and S? isopen. After some time, S2 is closed and S1 is opened simultaneously. The ammeter reading shows a sudden change.

and
STATEMENT-2: By Faraday's Law,
em = - d<p, A-.

l,

dt

't'

= magnetic flux,
is True.

!:".,

= Induced emf
is True: Statement-2 is a correct explanation for for

5011.
12

(A) Statement-1 Statement-1. (B) Statement-1 Statement-1. (C) Statement-1 (0) Statement-1 B

Statement-2

is True, Statement-2

is True; Statement-2

is NOT a correct explanation

is True, Statement -2 is False. is False, Statement-2 is True.

STATEMENT-1: The adjacent figures shows two thermally insulated vessels having equal volumes and containing monoatomic and diatomic ideal gaSs separated by a stopper, which prevents the gases from mixing with each other. If the stopper is removed and the gases are allowed to mix, the final equilibrium temperature is 525 K .

mCompressed
monoatomic

ideal gas 5 mole 400 K ~

and
STATEMENT-2: Total energy of the system is conserved.
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11
NXitirUR"'#wtrrstn' rtti,u"'ttXtl"i sur'

(A) Statement-' is True, Statement-2 is True; Statement-2 is a correct explanation Statement-1. (B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation Statement-'. (C) Statement-' is True, Statement -2 is False. (D) Statement-1 is False, Statement~2 is True.

for for

Sol.
13.

A
STATEMENT-1: A metallic sphere 'A' has radius R and a concentric hollow metallic sphere B has radius 3R. The space between them is filled by an annular dielectric of dielectric constant 2K and radius R (inner) and 2R (outer) and another dielectric of . dielectric constant K and radius 2R (inner) and 3R (outer). No charge is deposited at the common interface of the dielectrics .. and STATEMENT-2: Asper Gauss's law ~E.dS = ~E,(Symbols have their usual meanings} (A) Statement-' is True, Statement-2 Statement-1. (B) St'!t~ment-1 is True, Statement-2is.

is True;

Statement-2

is a correct

explanation

for for

Stafem.ent-1.

True; Statement-2
'r:

is NOT a Gorrect explanation

','i.~

Sol.

(C) Stat.ement-1 is True, Statement -2 is False. (D) Statement-1 is False, Statement-2 is::1"rue. D Comprehension Type

This section contains 2 groups of questions. Each group has 3 multiple choice question based on a paragraph. Each question has 4 choices (A), (B), (C) and. (D) for its answer. out of which ONLY ONE is correct. Paragraph for Question Nos. 14to 16 I K,

Four large metallic plates of area A each are kept parallel to each other with a small separation between them, as shown in the figure. A cell of emf V is connected across the two outermost plates through a switch K1. The two inner plates are similarly connected with a cell of emf 2V through a switch K2 Initially, both switches ar.e open and the plates, starting from left to right (i.e., number 1 to 4) are given charges Q, 2Q, -2Q, -Q . respectively. Now answer the following questions. 1 2

14.

Sol.

The charge appearing on the outer surface of plate -1, when switches K1, K2 are open (A) zero (B) Q (C)-Q (D) -3Q A When both switches are open, Charge on outermost surface (net charge on system)!2

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12
I 15.
AITS-PT -IIi Paper -2)-PCM(S)-JEE (Advanced)/13

If K1 is closed and K2 is open, the charge appe~ring on the right surface of plate-2 is

.
2

(A) 0+(EoA1V 2 \d;4 (C)

, \ (COA)V_S

. (B).(EoAI~+30 d)42 (D) 30

,d

2
V

Sol.

B
When K1 is closed and K2 is open

..9!.. + ~
Co Co

+~

=V

, where Co

= eoA
d

Co12

For plate 2,q - q1 = 20 Solving the above equations, we get q-

_ (coA)V 30 -+-

-q

16.

If both switches are closed, the charge appearing on the plate 4 is (A) (C~A ) V (C) 0 (B) 0 + C~A (~)
2t7.

COA"( V'l
d 2.)

(D)

(EoA

Sol.

V'j d )" 3 j V

D When both switches are closed. -~+2V--q-=v

Co

Co/2

._

~,q---l-)'3,d/\3

_ CoV _

(eoA

l(V\)
..

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13
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xt"oxrmx

Paragraph

for Question

Nos. 17 to 19

A calorimeter of water equivalent 250g contains a block of ice at -1 Dec in which there is a solid conducting ball whose water equivalent is 50g: The mass of ice is 800 g. 150g of steam at 1000 is added to the calorimeter and the system is isolated from surroundings.

steam

calorimeter

Given Specific heat of water = 1 cal/g/oC Specific heat of ice = 0.5 cal/g/OC Latent heat of fusion of ice = 80 callg Latent heat of vaporization 540 cal/g . Answer the following questions based on the infonnation above.

17.

Amount of water in the container, when equilibrium has been established, is

(A) 950g (Bl800 9 (C) 150 9

SoJ; 18. (0) cannot be calculated from the information given A Equilibrium temperature of the system is (A) Dec (C) 20CC C

(B) 10QoC (0) 30i'it

Sol.
19.

The density of the material of the ball at O"C is Ip6(OC)}is varies with temperature as PB (Gec)
=

equal to density of \'fater. Also PB

PB (OC) x 1-~)

r\

200/

Ignore the expansion of water and any

pressure changes with temperature. After thermal equilibrium has been reached, the fraction of volume of the ball in air in the calorimeter equals. 1 3 (A) 20 (8) "2 (C) ~ Sol. D (0) ~.

10

10

;\~

. i'lnJEE 1"d" /lTT JF.E Hall,se,

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14

AITS-PT -t1-{Paper-2)-PCM(S

)-JEEl~dvanced)/13y.

SECTION ~ B
p q
r

I Matrix - Match Type T~is section contains 3 questions. Each question contains statements gi~en in two columns which have to be matched. Statements (A, B, C, D) in column I have to b~. matched with statements (p, q, r, s) in column II. The answers to these questions have to be appropriately btbbled as illustrated in the following example. . If ~he com~ct match are A-p, A-s, B-q, B-r, Cop, C-q and O-s, then the correctly bubbled 4 x 4 matrix should be as follows:
....l..... . .

..........................

A@D~Q)@D B0@)@~ c@D~Q)0 00@C0CJ

1.

Column-I contains some thermodynamic system andj:X)lumn-1I contains its properties. Match the following columns. Column - I Column - II (A) A steel rod is clamped at its two ends and rests (p) 400 on a fixed horizontal base. The longitudinal strain developed in the rod when temperature rises to 50C is - 3.6 x 10'4, and the temperature coefficient of linear expansion of steel is 1.2 x 10,5 fc. Find the temperature at which rod is in relaxed state (B) Six hundred mole of a gas undergoes,a process P = 7 x 10 N / 01 iii 2
5 2 "

(q)

27

4m where V is volume in 013 When volume of the gas is 20 01\ its temperature in Kelvin is approximately equal to (C) A block of mass 100 gm slides on a rough horizontal surface of zero heat capacity, When the speed of the block decreases from 10 m/s to o 5 mIs, its temperature rises by O.2S C. The heat capacity of the block in joule/c,C is P(N/m
1 )

+Y..._ 3

(r)

20

(0)

(s) C
isoczj0riC proc.ess isothermal process

15

3 x10

5 ..

10:J

A
-:; t isobaric 'B process

T 600 T (Kelvin) If two moles of a gas consisting of 1 mole of He and 1 mole of H2 undergo a cyclic process A ~ B~ C ~ A as shown in the,figure the total work done in the cycle is -600Rln[9/e] The temperature T in DC is (A) ~ (r) (B) ~ (p) (C) -) (s) (D) ~ (q)

AITS-PT -"-(Paper -2)-PCM(S )-JE E(Advanced)/13

r-m>"''i''''X'CfO't O'tSXtUQ'ffi)'Z
WiN

15
OD'Xsturp

un

(0"("((

XI

.fPCt?SZ

yuxtrn

2.

Match the following columns.

- Column-I

Column-II
(Temperature state) T in steady

(A)
~ __

A
2_K_O

B 3_Ko __ ~ __

C
6_K_o __

(p)

sooe

I
10.C

100.C Three homogenous each of length

I..

T thermal

resistors A, Band

e,

cross-sectional

area A and thennal

conductivity 2Ko. 3Ko and 6Ko respectively are joined in series such thatthere is one dimensional heat flow from left end(temperature 100C) to the right end (temperature 1Q0C). T is the temperature of the interface between resistor Band in the steady state.

(B)

A spherical annular thennal resistor of thennal conductivity K and inner and outer radii 2R and SR respectively, is in steady state with its inner surface. maintained at 100C and its outer surface maintained at 10C (heat flow is radially outwards). The temperature of the concentric spherical interface of radius 3R in steady state is T. . (C)
,

(r) Issoe
_-.
I

'<!SH."?:--/
.100.C
. 2R : ~ . T .

A cylindrical and thennal resistor of inner radius R and outer radius 8R is in steady state with its inner surface maintained at 100C and its outer surface maintained at 10C(heat flow is radially outwards). The temperature of the co-axial cylindrical interface of radius 2R in steady state is T.

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16
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~1I-{Paper-2}-PCM(S)-JEE(Advanced)113
COMC
N

ttt"""n?i

(D)

A
6R b

2l

100C

10C

Sol.

A homogeneous thermal resistor whose outer surface is the frustom of a solid cone, has the two base radii as 6R and 3R respectively and the perpendicular distance between its, two bases is 3L. The two bases are maintained at 100cC and 10C. In the steady state(heat flows from left end to the right . end) the temperature of the interface at a distance of 2L from the left end is T. Assume that L is very large in comparison to Rand the lateral surface of the cylinder is thermally insulated from the surroundings. FindT. (A) ~ (s) (B) ~ (p) (e) ~ (q) (0) ~ (r) Column-I contains some physical systems and column-II contains its properties. following columns. Column - I Column - II (A) A metallic solid sphere of mass 5 kg and radius 2 (p) 60 m is freely rotating about its diameter with angular velocity 00 2 rad/s. The coefficient of 4 thermal expansion of the sphere isa 10. fc. If temperature increases by 20C. the % change in angular velocity of the sphere is (B) A metallic sphere of emissivity 0.8, radius 4 m (q) I' Zero and at a surface temperature of 600 kelvin is emitting radiation. If half of the metallic sphere is covered by some opaque material and the surface temperature increases to [600 (5/2) 1!4} kelvin, the % change in power emitted is Match the ~."

II

J.
ci:: I
I

;: I

(C)

A metallic hollow spherical shell is placed concentrically with a spherical shell of double the radius. The inner sphere is given a charge q while the outer sphere is given a charge 4 q. Now the two sphere are connected together by a metallic wire. The % change in charge on the outer surface of the outer sphere is . Dielectricof
' q~. ~2
~'

(r)

25

(D)

(s)

0.4

~t~c=c~n$tant

C ~
~
V

. ~~
q2
V

Situation -1

Situation-.2

Two identical air capacitors 1 and 2 of capacitance C each are connected in series and a potential difference V is applied across the
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17.

combination as shown in the figure. q1 is the charge of capacitor-1 in situation-1. When a dielectric of dielectric constant 4 is inserted into capacitor-2, a charge q2 flows through the battery in the circuit as shown in the figure in situation-2. Find q2 x 100. Sol.

q1 (A) -t (5) (8) -t (r)

(A) ~MR200

(e) -t(q)

(D) -t (p)

())=
(r)'[

= ~MR2(1+ae)2oo

())o

(1 - 2aO)
x 100

000]

= (2aO)IOO=

0.4 %

())o

(B) P,
P2

= aA!,:600

4 A

= (crN2)f:600 (5/2) = 5/4P,

= 25%

P2 - P1 x 100 P1

(C) % change is zero .

.~

4CV 7CV 3CV (D) q2 = -5- - "2 = 10

&
eV/2

q2

x 100 = 60% .

q,

~:J.~:J Yv Yv
eV/2 4CVl5 4CV/5

qz

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,
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18

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qneml8try

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AITS-PT-IHPaper-2)-PCM(S)-JEE(Advanced)/13
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xi

rrt

'tiC"'

PART 5ECTION-A

n
Type

Straight Objective
I

T~iS section contains 9 multiple choice questions numbered 1 to 9. Each question has 4 choices (A), (8), I (q and (D), out of which ONLY ONE is correct. . . _ 1. How many total stereoisomers do the following compounds have?

.,

,H
(C)

0,0 CO 0/
(~)
I

(:

(B)

(0)

(E)

W
(B)

4
3

3
4

2
2

o
4

o
2 2

2 2

~
Sol.

3
4

4
3

(D) B (A)
-. c' ,

o
OH

(8)

,.--V"
(C) (D)

0.,0./ 0 .'0 , l, c , ,
1 ... OH

r
.~

,
(~
!

4
0

2
2

o o

il

11

t
'.

"

oo
1 t
None Enantiomeric pair
TIITJEE
HOlUB,

(J

(E) (F)

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2.

How many products will formed by reaction:

(,)04 ii)p..;iHSO~

Sol.

(A) 4 (8) 3 (C) 2 (D) 1 C Two -OH groups, above and two below the plane. Which of the following will not exhibit geometrical isomerism: (A)

3.

(8)

(C)

CO
I) <

(D)

Sol.

o
(A)

In A and 8 there is hindered rotation about central. bond between two rings.
CI

I L >-<J
'M

(6)

,00

. Cb'OOCb
H
H

In (C) compound exist in two form cis and (C) H . H .

r'

<>=<1
Cl

trans.

In case of (D) on rotation conformer will develop instead of geometrical isomer. 4. In the reaction:
~CI-~P, N H

Product P, should be: (A) (8)

~CI

(C)

(D)

CI

(J
Sol.

C/1S
~\-..~
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5]
In the followin X F

20

AITS-PT -1I-(Paper-2)-PC M(S )-JE E(Advanced)/13

"urn
l""'f'rTM""")

table the value of di ole moments (in Deb e are as follows CH;,X CH2X2 CHX3 __ a, a2 a3

i
I

CI Br

_b,___ __ c_,_

~
C2

C3 C3

--------j

I d" The correct relation among a" a2. a3, b" ~.~. (A) a3> a2 > a,. b, > ~ > be. (C) C, > C2> C3.d2> d, > d3 S I.

d2 d3 Ch C2.C3 and d" d2 d3 are (B) a2> a,> a3, b, > ~ > b3. (D) C, > C2> C3,b2 > ~ > b, CH2X2 1.97 1:60 1.45 1.1 CHX3 1.65 . 1.03 1.02 1.00

B
X

F
I ! I

CI Br I

CH;,X 1.82 1.94 1.79 1.64

l
C~W"M

N........... \-_ ....... -------N ~N~

rti
Sr /OH ~

consists of three fused chair conformations. If 11.67gms of the above compound undergoes acid catalysedhydrolysis it requires how many grams of water for complete hydrolysis: (At. Masses: C - 12. N -14. H - 1) (B){9 (D) 10

Sol.

(A) 5 '.' (C) 15 B> It is urotropin and its reaction with water is (CH2)EN. +6H20~4NH:o + 6HCHO

7.

In the cyclization reaction given below, the most probable product of the reaction

HO"

.A. ~

... Product is

(A)HO~ (C) HO~

(B)

o ---/
0,>--- OH

(D)

<)--J0H

c
Br

~
.

HO~'.../~)

Na-H: O-H -----

/\8

I.. OH

group nearer to Br is more acidic}

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UC"tUr'tDON'U"''' 'XP"t

21
("tlXtW,.ur'w .. x "wm)'

8_

In the reaction
,. &',(2 &q)
h,. 2. hydrolysIs

,. Br,!2&q)
hv

2 hydrolysis

and

yOEt
~"OEt (2 mole)

1. EtONalEIOH

l (Compound

Q
with six momb&'&O nng)

;: ~so. (dOl)

Then final product is:

(A)

-*
" then

P+Q

00-(0'0005)

lFinalproduct

-'!.

(8)

(C)

o o

o (D)

Sol.

*
o rA-(CHO

ever)
N l\..-!J..
/-----..:, I i'
,CliO ~"""'CH--Br

i(')!
~

CH3

Br

.I

(X::-:
(P)

EtO

Et

:l
.

o~

o
:

H)l r
+ ~OEI H~ 'V

8
OEt EtOH

Et~: Na-

II0

o
EtO-C

)7 q 'Q
COO:O
diI H.SO~

"

d /
EtO EtC

o~:

C-OEI It

eOOH

(t3-ketoacidj

(O!

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.c>:
o
o

:OW

(excess\ , J

o
This compqpnd may further )' ( \ undergo tautomerism to give

~ ~

OH

9.

[HydJOcarbon

Na) liquid. NH3

B ~HO.03)
..

2C~.

2CH3COOH.;. 2C02 (B) less volatile than water (D) non-aromatic compound

Then compound A, is (A) colourless liquid (C) orange red gas

g
(A)

Na/NH",

(8irc"

,.duct""') .)

o
(6)

COOH
1.0:.

2.H,O

I ) H~C " \
COOH

CHJCOOH + CO,

Compound A is benzene which is colourless liquid .

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Reasoning

Type

This section contains 4 questions numbered 10 to 13. Each question contains STATEMENT-1 (Assertion) and STATEMENT-2 (Reason). Each question has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct. 10. ST ATEMENT -1: Acetaldehyde colouration. reacts with alkaline solution of sodium nitroprusside to give red

and
STATEMENT-2: (A) Statement-1 Statement-1. Acetaldehyde is good reducing agent. is Tru~, Statement-2 is True; Statement-2 is a correct explanation for

(B) Slatement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1. (C) Statement-1 is True, Statement -2 is False. (D} Statement-1 is False, Statement-2 is True.

Sol.
11.

B
STATEMENT -1: Ortho iodobenzoic acid is strongest acid among ali ortho halobenzoic acid.

and
STATEMENT-2: Iodine exerts maximum ortho effect so the acidic strength increases. (A) Statement-1 is true, Statement-2 is True; Stafement-2 is a correct explanation Statement-1. (B) Statement-1 is True'>Statement-2 is True; Statement-2is Statement-1. (C) Statement-1 is True, Statement -2 is False. (D) Statement-1 is False, Statement-2 is True. A NOT a correct explanation fof;;" for

Sol. 12.

"

Sol.

Ph-S

/'"

CH-i
CH2

OH S is a better nucleophile than 0 atom and act as neighbouring group participant.

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13.

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AllS-PT -II-(Paper -2)-PC M(S )-JE E (Advanced)/13

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STATEMENT -1: Generally esterification reaction of carboxylic acid and alcohol is carried out in acidic medium while esterifIcation reaction of acid chloride and ~Icohol is carried out in basicmedium.

and
STATEMENT-2: by base. (A) Statement-1 In acid chlorides and alcohols reaction, HC! is released which can be neutralized is True, Statement-2 is True; Statement-2 is a correct explanation for

Statement-1. (B) Statement-1 is True, Statement-2is True; Statement-2is Statement-1. (C) Statement-1 is True, Statement -2 is False. (D) Statem-ent-1 is False, Statement-2 is True.

NOT a correct explanation for

Sol.

A Comprehension Type

This section contains 2 groups of questions. Each group has 3 multiple choice question based on a p1ragraph. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is . c~rrect. . Paragraph for Question Nos. 14 to 16 present to .

\lli'hen wate~ is added&)to an alkene no re.~ction takes place, because there is no electr~phile s~art a reactton by addmg to the nuCleophilic alkene. The O-H bond of water are too strong. CH;, - CH
=

C~h + ~O----4 X the acid

If however, an acid (H:eS040r HCI) is added to the solution, a reaction will occur because provides an electrophile.

T le second order rale conslanl (M-Sec -') lor acid calalysed hydration at 25.C is give n lor each 01 Ihe
fdllOwing a!kenes:
I I

H3C
\

C=CHz / H Compound P Compound Q K2 Compound R K3 Compound S K. CompoundT

FRateconstant:

K,

k.

Sol.

Which is more reactive between (Z)-2 butene and (E)-2 butene towards hydration (A) (E)-2-butene (B) (Z)-2-butene (C) Both are equally reactive (D) Both are inert towards hydration B (E) isomer is more stable hence more free energy of hydration required. Correct relation between rate constants: (A) K3 < K1 < K:e< ~ < Ks (C) K3 < K1 < K2 < Ks < ~

15.

(B) K2 < K1 < K3 < ~ < Ks (D) K3 < K1 < K2 < ~ < Ks

Sol.

A
(A) due to relative stability of carbcation formed.

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xa,m-

25
"wA!tX

Utt

16.

Amongthe (A) Q ~S

given compounds Q, R. Sand T which has maximum number of planes of symmehy (B) R ~T

Sol.

0
There are three planes of symmetry for compound T
H,C \
Xl

i
:

plane

_ ..... H,C

/YC\
l

CH, .,
.... CH3 xy plane

yz plane

Paragraph for Question Nos. 17 to 19 Compound (A), which can be distilled in high vacuum, gives positive test with Br2/H20, but does not react with Na metal in ethereal solution, but compound (B) and(C) gives H2(g) with sodium metal. Compound (A) undergoes following sequence of reactions -

I ":,"

.C

[AJ

LOA/H,

)B

I ,
~~2eq)
:;_ ve "-:''''''k .":
i : '{Y.

B;HsITHF H;0210H'

Products

,
C ~ ~OH

1two
- ve iodoform

structural

iSQrnersl

r /fr,.

test

17.

Compound 'A' should be: (A)

(8)
~

Y
(C)

V
A
~
::::::....
OH

/-'-',,-,/OH

H,C--O/~

n
OH' \

(D)

y::=
i

CHO

Sol.

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'~~"_QY Compound '8'
I

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"'toon) .
07"

(A)

r 11
~OH /A.."

OH

(C)

A Compound 'C' is: (A) OH

(8)
OH

(C)

(D)
~.
..

,~)
~/O" /I

:',-.

HO -

Sol.

Siolution for the Q. No. 17 to 19. C1oH1602(A} 10 + 1- 16 = 3 2 Compound does not react with Na metal, so it does not contain acidic groups like - C- OH , - OH Degree of unsaturalion

o "

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>tOO'dOZY'

27
dXX r' if

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$Mte::e<i

SECTION-B (Matrix Type) This section contains 3 questions. Each question contains statements given in two columns, which have to be matched, The statements in Column I are labelled A. B. C and D, while the statements in Column II are labelled p, q, r, sand t. Any given statement in Column I can have correct matching with ONE OR MORE statement(s) in Column II. The appropriate bubbles corresponding to the answers to these questions have to be darkened as . illustrated in the following example: If the correct matches are A - P. sand t; B - q and r; C - P and qi and Dand t; then the correct darkening of bubbles will look like the following: s
p q
r

A(fj0C0@@ B0@~0Q) c@~00Q) D~00@9QL)

1.

Match the following: Column-I (A) (B) (C) .HCOOH CH3COOH (p) (q) (r) Column-ll Decarboxylates on heating Reacts with Br2/P With Tollen's reagent gives silver mirror

~o
"----',

( r-g~OH
c',

o
~.,

(D)

~CHj-'

-C-OH

"

(s) . (t)

Decarbonylates (removal heating with H2S04 Reduces HgCI2

of

CO)

on

Sol.

A ~ p, r, s, t; B -~ q; C ~P. q; 0 ~ q

2.

Match the following: Column-I (A) CH;; - CH2 - CH2 - NH2 (B) (C) (D)
H3C-N-CH3 CH3

(p) (q)

(r) (s) (t)

Column-II Treatment of NaN02, HCI gives N-nitroso yellow liquid Treatment of NaN02, HCI gives diazonium chloride Treatment of CH3 - I (excess) followed by AgOH; heat gives alkene Treatment of HCI, heat gives non-volatile salt Cannot form H-bond with each other

Ph - NH2

Sol.

A~

r. s; B ~ P. r. s; C ~

S.

t; 0 ~ q,

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28
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. AtTS-PT-IHPaper-2)-PCM(S)-JEE(Advanced)/13
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>tt>" . yX

'tXt.,. X.

c-mx-xnn

)P' Xd"YO

'X xa

rom'ox

iX'

?ttCX&y-"

3.

Match the following: -Column-l (A) (B) (C) (D) PMMA Orion Bakelite Dacron

I
I
I

(p) (q) (r) (s) (t)

Column-ll Thermosetting polymer Thermoplastic polymer Addition polymer Condensation polymer Brittle

-'.

Sol.

A --) q, r, t; B --) r; C --) p, s; 0 --)q, S

PMMA

Polymethylmethacrylate

i -r:]
CH2 \

....

coacH:;

".

CHj/ n CN

Orion

Polyacrylonitnle

CH2

-{j
CH3/

Bakelite

Phenol formaldehyde

OH CH2

OH CHz

Dacron

Polyethylene tetraphthalale

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Mathematics

PART -III
SECTION-A Straight Objective Type

This section contains 9 muhiple choice questions numbered 1 to 9. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct .. 1. Normals PO, PB and PC are drawn to the parabola y2 triangle aBC is equilateral, then possible value of 'a' is (A) 150 (B) 250 (C) 350 (D) 450
C

100x from the point p

(a, 0). If the

Sol.

IPBC = ~

::::> t1

= 2-!3

Equation of nonnal at B is y = -t1x + 2at1.+ at~ y =2.J3x+4-!3a+24.J3a It passes through (a, 0) :. 0 =

" 0

-2../3a + 4'-'2 (25)+

(24../3)25. (24..)3)503 C drawn from origin to any normal of the ellipse -

P{CJ.,O)

= -V3CJ.+ (4-!3)(503)+

=a
2.

= 350

If 'd' be the length of perpendicular then 'd' cannot exceed 1 (A) "2 (C) 2

x2

25

+-

y2

16

=1

(B) 1 (D) none of these

Sol.

B
Equation of nonnal is 5x sec 8 ~ 4y cosec 8 d= ,/25sec2 Now. 25tan
2

=9

9 .J25tan
2

e + 16cosec2e
2

8 + 16cot2 0 + 41

e + 16cOt2 e ~ .J25 x 16
::::>

::::> ::::>

25tan2 d~1

e + 16cot2 (1 ~ 40

25tan2 (1 + 16coe (1 + 41 ~ 81

3.

The maximum value

od.Jx

3x2 - 6x + 13 -

.Jx

+ 5x2 +41 is

W2
~4
Sol. D
1

~3 ~5
+ (x ~ 3)

/(2)2 V x -2

-2

12221 - '.j{x + 2) + X

Le.,

IJ(y - 2)2 + (x -.:3)2 - ~(y

+ 2)2 + x2

i
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Here y = x". If P(x, y) be any point on the parabola, then IPA - PBI ::;AB Where A(3, 2), B{O, -2)::::> AB = ,/9 + 16 = 5
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.AllS-PT .. U-{Paper.. 2)-PCM(S)-JEE(Advanced)/13

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XI?

If tan-1A=tan-1(A2

+n)+~
4
0.

is satisfied by atleast one integral value of A in [0, is/are (B) 1 (D) 2

2J.

Then the

~~S.ot

possible integral values of (A) -1 (C) 0 A

0.

= 1- ~ - A 2 which gives A+1

0.

= -1

only

.22
~;-.

.. 5'..
'

. ,If from a point (1, 0.) two tangents are drawn on exactly one branch of the hyperbola . . then '0.' belongs to
."

~ ~~

= 1,

(A)
(C)

(-1, -~)
(!, 11 ,2
>

(D) none of these

~:Sol.

B Two tangents can be drawn asymptotes OAand OB x The asymptotes are y = :t-

if

the. point

lies

between

the

= ( 1;
.
(

-I 2/
1\

=:;..

(;.'. 1 \ , 1, ..- J

2>

=:;,o.E

\ 2 2;

--,-l

1 1\

6.

In acute angle triangle ABC. r = r..,+ r-. - rl and B > -. Then -. " ~ 3 b (A)

1!

a-c

completely lies in

f!. ~')
!\34)

(B) (~. ~)\ 32

(C)r~.~\) \2 2
Sol.

(D>f~,~'l \2 3;,
rl

B
r

= r2 + r3s s-b

/1 /1./1 ~ -=--+-----

n
s-a

s-c

..

a-cEl/~
b

3')

1'1
y2
at a

7.

If the curve + = 1 and (x - 20)2 + (y - 20)2 = ~ intersect each other orthogonally 400 100 point (20 cos e, 10 sin G), then . G 1 o 1 (B) cot- =(A) cot "2 =

x2

J2

2
l)

(C) cot~ = 100 2

(D) cot2

20

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31

Sol.

B
(20 20) lies on x(20cos8) , 400 => cos

+ y(10sinO)
100

=1

. "1 e + 2 Sin b =

=> Sin

e = --1- case
2

=> cot- = -

0 2
-

1 2 1 2
2

8.

An ellipse 2 + -2 = 1 and the hyperbola

x2
a

y2

XL -

yL ::

intersect orthogonally.

It is given that-the

eccentricity of the ellipse is reciprocal of that of hyperbola, then a 2 is equal to b (A) ~ (B) 2 (0) 4

. 2
4

(C) ~

Sol.

B
Ellipse and hyperbola are confocal :. (:t ae, 0) (:t 1, 0)

=> a

= ../2

and e = .~
,.,12
2 . 2

:. equaticmof the ellipse is ~ +

'L = 1
1
_ :'5~:,
,~"

9.

-Sol.

A tangent 'at the point P(20, 25) to a parabola intersects its directrix at (-10, 9)". If the focus of the parabola lies on x-axis, the numbers of such parabolas are (8) 2 (A) 1 (0) none of these (C) infinite B P(20, 25) Let S= (a, 0)

/it:."

As PS.l
::~;> 20 - a

as
9 =-1 -(10+ a)

=>a=5 Let the slope of the "directrix be m Equation of directrix is y - 9 = m(x + 10) Now 120m- 25 + 9 + 10ml = ,.'225 + 625

Jm +1
2

=> 25m - 480 m - 297 0 It gives two distinct values of m. Hence two parabolas

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11h.
STATEMENT STATEMENT of roots = (A) (B) (C) (D)

'W)Y).'i'Q"'ttO"O"XOO

:fzro/,.... oo.w.,.ve."'tiX'l"t'

32
'"XXf')"yart=

AITS-PT -1I-{Paper-2)-PCM{S)-JEE{Advanced)/13 XY ..(O'''O y' -#0"10".,.......,.....-.

Reasoning

Type

This section contains 4 questions numbered 10 to 13. Each question contains STATEMENT-1 (Assertion) ahd STATEMENT-2 (Reason). Each question has 4 choices (A), (B), (C) and (D) out of which ONLY qNE is correct. 1: If
C.I.

with least absolute value is a root of the quadratic equation a:x2 + bx - a == 0, =-1

where a > Oand b < Othen sec{coc1(tanex}-tan.1(cota)}

b 2: For the quadratic equation ax" + bx + c = 0, sum of the roots = -- and product

Sol.

Both the statements are true and Statement 2 is correct explanation of Statement 1. Both the Statements are true and Statement 2is not the correct explanation of Statement 1. Statement 1 is true and Statement 2 is false. Statement 1 is false and Statement 2 is true.

The roots ofax :. aE (-1,0) Now tan(eos.'a)

1

+ bx - a = 0 are negative reciprocals of each other.

= -TI + coC1(tan
tan. (cota)]
1

a) ""secTl=-1

.~,;.sec[ cot- (tancx)11.

Sol.

STATEMENT 1: The area of a triangle whose vertices are the incentr~, eireumcentre and centroid oithe triangle whose sides are 18 em, 24 em and 30 em is equal to 3 em2 because. STATEMENT 2: Centroid divides each of the medians in the ratio 2: 1. (A) Both the statements are true and statement 2 is correct explanation of Statement 1. (B) Both the Statements are true and Statement 2 is nol the correct explanation of Statement 1. (C) Statement 1 is true and Statement 2 is false. . (D) Statement 1 is false and Statement 2 is true. D The triangle given is right angled Take a triangle with vertices (0, 0), (18. D), (0,24). Centroid (6, 8) Circumeentre (9, 12) 6 rs::::> r 6 So ineentre (6, 6)

SO area of the required triangle

= ~ x 2 x 3 = 2 em'.
2(J

12.

STATEMENT

1: If 0 < 0 < - , then ecosec

1t

sin 8 + esec

2 -

t' . cos

e > e2

;
because.

STATEMENT 2: AM of positive numbers is always greater than or equal to their GM. (A) Both the statements are true and Statement 2 is correct explanation of Statement 1. (B) Both the Statements are true and Statement 2 is not the correct explanation of Statement 1. (C) Statement 1 is true and Statement 2 is false. (D) Statement 1 is false and Statement 2 is true.

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caxu"mWUscet (cmxtC~xt'1
yt

33

Sol.

A AM~GM =:> ecosecle sin2

e + esec'e . cos2 e ~ 2~eoosec2e"sec2 6. (cOS2

esin2

e)

= =

2~ellSin'ecos'e . (cOS2 esin2e) e2/sin226.sin28

x2

Now consider f(x) == xe2/ :. f(x) > e2 13.

which c1ear1yis decreasing in (0, 1)

STATEMENT 1: There exists atleast one solution of the equation 20[x 2 - x ~ 5} + 10[ x - ~] == 1+ SO(cosx) (where [.J denote greatest integer function).

Sol.

STATEMENT 2: If x E R. then x = [xJ + {x} where {x} denotes the fractional part of x. (A) Both the statements are true and Statement 2 is correct explanation of Statement 1. (B) aoth the Statements are true and Statement 2 is not the correct explanation of Statement 1. (C) Statement 1 is true and Statement 2 is false. (0) Statement 1 is false and Statement 2 is true. D RHS is always an odd number. So no solution. Comprehension
.

Type
.~
.~

'i~This section contains 2 groups":ibfquestions. Each group has :fmultiple choice question based~';on a paragraph. Each question has 4 choices (A), (B), (C) and (0) for its answer, out of which ONLY ONE is torrect. l: t ;' Paragraph for Question Nos~ 14 to 16

Read the following write up carefully and answer the following questions: A normal to the parabola at a point A on the parabola whose equation is yL 2013x cuts the axis of x at

N. AN is produced to the point B such that NB

= !AN.

14.

If two more normals to the parabola yL (A) coincident (C) indined at ~ 6

Now answer the following questions. 2 2013x pass through B, then they are (B) inclined at ~

4
(D) inclined at ~

Sol.

2
A(am~, --2am)

Equation of normal through A is y == mlx-2aml-a~ :. N(2(2013) + 2013m~, 0) If B

= (h, k), then k = 2013

But mlm~m~ ~ ~

= :.---

ml K =:> m~m2013 < ~

= -1
B

:. Normals are inclined at right angles

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i
I

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. .

M(S)-JEE(Advanced)/13
. >:Cb,.. ')').'>X'O.Sr.T

15.
I :

If C is a point on the parabola CN on x-axis is equal to (A) 2013

= 2013x such ,that 10CN

=:= ~

(0 being origin), then projedion

of

(B) 2013

2
Sol. (C) 4026 A If C == (at2, 2at), equation of CN is y-2at= -~(x-at2) (D) none of these

::::::>N==(at2+4a,0) :. Projedion 16. of CN on x-axis = ON - OL = 4a = 2013.

If the nonnals through" any point of the parabola y2 = 2013x, cutthe line 2x - 2013 = 0, in poi!1ts whose ordinates are in AP, then the slopes of these normals are in (A) AP (B) GP (C) HP (D) none of these

Sol.

B
. 'S 0 Ivmg
::::::>

th e equation .
3

0fl'nonna

2013 th'e or d'mates are --4-' 2013 m 3 With ,x = -2-' 1

---m2 4
2013

2013

::::::>

---m3. 4
==

As the ordinates are in AP

. 3 3 .. m1 +1Tl3

2m3
2

But ml + m3

=-

m2

Solving we get m~ == m1m3 Paragraph for Question Nos. 17 to 19

Riead the following write up carefully and answer the following questions: 2 The ellipse whose equation is given by x + 4/ = 4 is rotated about origin through a right angle in its own I plane. The tangents at any point A on the ellipse before and after rotation intersect at P(o., B) Nbw answer the following questions.
I

1if .

The locus of P is symmetric about (A) origin (C) the line y = 2x

(B) the line y = x (D) the point (1, 1)

A
If (0. + f3f = 3, then (0. - (3)2 equals (A) 2.J5 -1 . (C)

(B) 2M-1 (D) none of these

J1O-1

Sol.
1!:}.

B
Which of the following pairs of points lie on the locus of P (A)

(0, '/'3)

and

(0, - -J3)

(B)

(0, ,/5), (0, -13)

5'01.

(C) (0, 0

.J5)

and (1, 1)

(D) none of these

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35
"N

iYtlF1W XYtC'"it

iXO""t'Yi"'XS

0-

'0)'="""'"00'(

17.-19. Equation of any tangent before rotation is XCOSa+ ysina. = ~4cos2a

J '"

+ sin2 a.
'"

..... (1)

Equation of the tangent after rotation is -xsina (x2 +y2 + ycosa == ,14cos~ a. + sin~ u. ..... (2)

Solving (1) and (2) we get

=4(y+a)2

+(y-xi ~16(Y+X)2 +4(Y-X)2 SECTION-8 (Matrix Type)

or (y+x)2+(y-xf

This section contains 3 questions. Each question contains statements given. in two columns, which have to be matched. The statements in Column I are labelled A. B, C and D, while the statements in Column II are labelled p, q, r, sand t. Any given statement in Column I can have correct matching with ONE OR MORE statement(s) in Column II. The appropriate bubbles corresponding to the answers to these questions have to be darkened as illustrated in the following example: If the correct matches are A - p, sand t; B - q and r; C - P and q; and D - s and t; then the correct darkening of bubbles will look like the following: 1. Match the following:

A~00@@ B0(V@00 c ~.<W>000 D~00(@)@

....

........:.~9Jt.t~...;;U{
(A) (B) Locus of centre of circles touching circle + - 4x - 4y (p) 2 = 0 internally and x + y2 - 6x - 6y + 17 0 externally is The locus of the point (3h - 2, 3k) where (h, k) lies on the (q) 2 circle x + y<- 2x - 4y - 4 0 : . Locus ~f ce~tre of circle touching two circle XL + / + 2x (r) o and Xi + 6x + 5 0 externally is I The extremities of a diagonal for a rectangle are (0, 0) and (s) (4,4) .. The locus of the extremities of the other diagonal is

Straight line Circle Hyperbola Ellipse

(C)
(D)

t-

I I

Sol.

(A) ~ (5)

(8) ~ (q)

(C) ~ (r)

(D)~ (q)

2.

Match the following: (p)

(A) _

2n 4n If cos--cos--cos-1999 1999 divisible by If (1+tan10)(1+tan20)

6n 1998n -k ...... cos-= 2 ,then 1999 1999 .... (1+lan450) = 2Jl then (n+1)

()

k+1

IS

(B)

is divisible of

(q)

(C)
(D)

by The points (0, 0), (a, 11) and (b, 37) are the vertices equilateral triangle then 'ab' is divisible by

an

(r) (s)

5 7

Sol.

tancos-' sintan.-'I-( 1 is divisible by .. ,,42, (A) ~ (p, r) (8) ~ (p, q) (C) ~ (q, r, s)

(D)~ (p, q, s)

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36
(A) Let a = ~ and P denote the desired product 1999 Let Q = sinasin2a .... sin999a then 2999pQ:= (2sinacos = sin2asin4a = (sin2asin4a :=sin2asin4a a)(2sin2acos2a)

AilS-PI

-'.-(Paper -2}-PCM(S}-JE

E(Advanced

)/13

.... (2sin999acos999a)

sin1998a sin998a)[ -sin(2n -1000a)][ -'-sin(27t -1002a)

999

J....[~

sin(21t -1998a)]

sin998asin999asin997a

.... sina = Q k + 1':=1000

It is easy to se that Q :;:.0 hence the desired product is P := T Hence P, Rand T are correct options

(B) '(1 + tankO)(1 + tan( 45 - k)O):= 1+[tankO + tan(45 - k)OJ + tanka tan(45 - k)o :=1tan45 [1-tankO tan( 45 -kt]+ tanko tan(45 - kt = 1+tan45 =2

Hence (1 + tan10)( 1+ tan 44 ) ...(1 +tan22 )(1+ tan 23 )(1 + tan 45 )

~223

~ n+1:= 24 Hence P, Q and T are correct options (C) Let 0 :;;(0,0), A :=(a, 11) and B:= (b, 37) and M be the mid point of segment AS (a+b ~M=1-,241 \,

\ 2

)
and IOMl =

Now OM l-

MA

J3IMAI
if follow that OM=13"'3i+~(a-b)j

..Because AM=--i-13j

.-,-.

a - b ....
2

----.)3

..

. a+b. Hence ~-'+24j=13"'3i+-(a-b)j

J3 .
2
; = 8,/3 315

..

a+b.
.~

. 2

--:=

~. a-b 13./3 and --

= a = 21.)3

and b =

5-8 ~. ab:=

Hence Q, Rand S are correct options. (D) Because cos. t ancos

1.

SlOB

71 . =- 0 and tan -: 2 \2

(n

e = -- 1
'J'

tanO

for 0 < 0 < -, we have for any x> 0 , 2 .

3..

x = t an - - t an x. = -1 2 / X ( 1 .. 1 ~ tancos-1 sintan) = 42 42 Hence P, Q and S are correct options. Match the following: smtan

-1'

-1

l')1

'.1)

+ cos"y

Calufiiri~J:
,; (). .....

.<i

...... .cO:)9.tfi.n~n'.' :.... "

(p) (q) (r) . (s) a square a circular arc part of a rectangular hyperbola a pair of lines

sin"x + cos" y + cos'\ (xy) sec"x + tan"y = 0 (D) Sol. tan"x2 + cor' y" =: .::'.

=~

(A) --'t (q) (8) .~ (p) (C) ~ (r) (D)-~ (s) Use formula for at:jdition of inverse trigonometric functions.