Sri Chaitanya IIT- JEE Academy

RAMAN BHAVAN - VIJAYAWADA

CHEMISTRY IIT TEST

S1 to SI3 ACIDS & BASES Date : 24-07-07 *************************************************************************************** Instr !t"#n : Ans$er a%% t&e ' est"#ns( )#r e*er+ !#rre!t ans$er , -ar.s are a$ar/e/ an/ )#r e*er+ $r#n0 ans$er 1 -ar. $"%% 2e /e/ !t3 1. pKa value of C 3C!! i" #.$%. &hich of the follo'in( "tatement i" correct 1) p of *.1 + C 3C!! i" #.$% ,) p - #.$% then de(ree of di""ociation of C 3C!! i" ma.imum 3) p - #.$% then de(ree of di""ociation of C 3C!! i" minimum #) p - #.$% then /*0 C 3C!! i" di""ociation !ne litre of 1uffer "olution of p - 2.$ can 1e prepared 1y *.**/ mole 3a ,4!# and 5 mole of 3a, 4!#. K, for 34!# - 21*-%. The value of 657 i" 1) *.1 ,) *.*1 3) *.**1 #) *.***1 -2 The "olu1ility of the compound T8,S in pure 'ater i" 31* mol9lit. A""ume that the di""olved S-, ion hydroly"i" almo"t completely into S- and that the further hydroly"i" to ,S can 1e ne(lected. K,: ,S) - 1*-1#. The "olu1ility product of the compound i" 1) ; 1*-1, ,) %.1 1*-,, 3) %.1 1*-1, #) 3.,# 1*-,, Appro.imate p of *.1* + a<ueou" ,S "olution havin( K1 and K, for ,S at ,/*C 1*-$ and 1*-13 re"pectively i" 1) # ,) / 3) ; #) % + The "elf ioni=ation con"tant for pure formic acid> K = HCOOH , HCOO ha" 1een e"timated a" -2 3 1* at room temperature. The den"ity of formic acid i" 1.,, (9cm . The percenta(e of formic acid molecule" in pure formic acid converted to formate ion i" 1) *.**,0 ,) *.**#0 3) *.**20 #) *.**%0 3** ml of "aturated clear "olution of CaC,!#:a<) re<uire" 2 ml of *.**1 + K+n!#:a<) in acid medium for complete o.idation of C,!#-, ion". The K"p of CaC,!# i" 1) / 1*-; ,) / 1*-1* 3) ,./ 1*-; #) ,./ 1*-1* o' many num1er" of mole of A(I 'hich may 1e di""olved in 1 lit. of 1+ C3 - "olution K"p for A(I - 1 1*-1$ m,. A(? ? , C3- A( :C3),- Kc - ; 1*1; +-, 1) *.,#/ ,) *.32$/ 3) *.#;1 #) *.$3/ @oth A( C3S and A( @r i" di""olved in a 'ater. K "p of A(@r - / 1*-13 and K"p of A( C3S - 1 1*-1,. The "olu1ility of A( @r in "olution i" 1) # 1*-$ + ,) , 1*-$ + 3) %.12 1*-$ #) 2., 1*-$ + It i" found that *.1 + "olution of four "odium "alt" 3aA> 3a@> 3aC and 3aA have the follo'in( p value". &hich one of the corre"pondin( acid" i" "tron(e"tB 1) 3aA 11.* ,) 3aC 1*.* 3) 3a@ ;.* #) 3aA $.* An acid C 1a"e indicator ha" Ka - 3.* 1*-/. The acid form of the indicator i" red and the 1a"ic form i" 1lue. The chan(e in D ?E re<uired to chan(e to indicator form $/0 red to $/0 1lue i" 1) % 1*-/ + ,) ; 1*-/ + 3) 1 1*-/ + #) 3 1*-# + The acid ioni"ation con"tant for Fn?, ? ,! Fn:! )? ? ? i" 1.* 1*-; The 1a"ic di""ociation con"tant of Fn:! )? i" 1) 1*-# ,) 1*-/ 3) 1*-2 #) 1*-$ The p of *.**1 + "olution of FnCl, in a1ove pro1lem i" 1) # ,) / 3) 2 #) $ A one litre 1uffer "olution containin( *./ + C 3C!! and *.,/ + C 3C!!3a. The pKa value of acetic acid i" #.$#. The "olu1ility product of Ca:! ), Al:! )3> Cr:! )3 are /./ 1*-2> 1.3 1*-33> 2.3 1*-31 in pure 'ater re"pectively. 4 of the 1uffer "olution i" 1) /.*# ,) #.$# 3) #.*# #) #.## If *.,/ mole of Cl i" added to the 1uffer "olution then the p i"

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1) 3.%2 ,) #.$# 3) #.%2 #) ,.#3 If *.,/ mole 3a! i" added to the 1uffer "olution than the p i" 1) #.*# ,) #.$# 3) #.## #) /.*# 12. AlCl3 i" added to the a 1uffer "olution then the concentration of Al?3 pre"ent in the "olution i" 1) 1.%, 1*-/ + ,) 2.$/ 1*-/ + 3) 2.$/ 1*-# + #) 1.%, 1*-# + ?, ?3 ?3 1$. !ne lit "olution containin( Ca > Al > Cr in *.1 + concentration each. The "olution i" mi.ed 'ith one lit. 1uffer "olution. &hich ion remain" un precipitated 1) Ca?, ,) Al?3 3) Cr?3 #) All Assert"#n 4A5( Reas#n 4R5 t+6e ' est"#ns : 1%. A""ertion :A) G &ater act" a" levellin( "olvent for variou" acid" Hea"on :H) G 8evellin( effect of 'ater i" due to it" hi(h dielectric con"tant and "tron( proton acceptin( tendency 1) A I H are true and H i" correct e.planation of A ,) A I H are true and H i" not correct e.planation of A 3) A i" true 1ut H i" fal"e #) A i" fal"e 1ut H i" true 1;. A""ertion :A) G A 1uffer "olution ha" a capacity to re"i"t the chan(e in p value on addition of "mall amount of "tron( acid or 1a"e to it Hea"on :H) G p value of 1uffer "olution doe" not chan(e on dilution or on Jeepin( for lon( 1) A I H are true and H i" correct e.planation of A ,) A I H are true and H i" not correct e.planation of A 3) A i" true 1ut H i" fal"e #) A i" fal"e 1ut H i" true ,*. A""ertion :A) G 3a,C!3 doe" not affect the p of pure 'ater on di""ociation Hea"on :H) G Salt of "tron( acid and "tron( 1a"e do not under(o hydroly"i" 1) A I H are true and H i" correct e.planation of A ,) A I H are true and H i" not correct e.planation of A 3) A i" true 1ut H i" fal"e #) A i" fal"e 1ut H i" true M#re t&an #ne !#rre!t #6t"#ns : ,1. &hich i"9are 'ron( "tatement" 1) All anheniu" acid" are @ron"ted acid" 1ut all arrheniu" 1a"e" are not @ron"ted 1a"e" ,) All @ron"ted 1a"e" are 8e'in 1a"e" 3) All @ron"ted acid" are 8e'in acid" #) ConKu(ate acid" of "tron( 1a"e i" a "tron( acid ,,. In the follo'in( reaction 1/.
+ Al ( H ,O ) 2 + H ,O H 3O + Al ( H ,O ) / OH A @ C A 1) A i" an acid @ i" a 1a"e ,) A i" a 1a"e @ i" an acid 3) C i" conKucate acid of @ and A i" conKucate 1a"e of A #) C i" conKucate 1a"e of @ and A i" conKucate acid of A &hich a1out "olu1ility product i" correct 1) If ionic product L "olu1ility product> "olution i" un"aturated ,) Mor AlCl3 K"p - ,$S#> en 6S7 "olu1ility in ,! 3) If ionic product N "olu1ility product> precipitate occur" #) Solu1ility AlCl3 in *.1 + KCl i" S.Then K"p - *.**1S &hich of the follo'in( "tatement" are correctB 1) 3 #! i" a 'eaJ 1a"e ,) 3 #Cl form" an acidic "olution in ,! 3) 3@!3 tripotic acid #) C 3C!!3a form" a 1a"ic "olution in 'ater In mi.in( e<ual volume" of the follo'in( "olution"> precipitation of A(Cl 'ill occur :K"p of A(Cl - 1.% 1*-1*) 1) 1*-/ + A(? and 1*-/ +Cl,) 1*-1* + A(? and 1*-1* +Cl-3 ? -2 3) 1* + A( and 1* +Cl #) 1*-# + A(? and 1*-# +Cl+3 +,

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CHEMISTRY 7EE SHEET Date : 24-07-07 1. # 11. , ,1. 3># ,. 3 1,. 3 ,,. 1>3 3. # 13. # ,3. all #. 1 /. , 1#. # 1/. # ,#. 1>,># ,/.3># 2. 3 12. , $. 3 1$. 1 %. 1 1%. 1 Se! : S1 t# SI, ;. # 1;. , 1*. 1 ,*. #