Surname (Last name): __________________________________________________ Given name (First name): _______________________________________________ Student Number: _______________________________________________________ Lab Day (circle

one): MON TUE WED THU FRI

Lab TA: ______________________________________________________________

CHM 1311 A Test #1 A Fall 2010

Please keep your work covered at all times and keep your eyes on your own paper! Cheating or any appearance of cheating will result in an F in the course and possible expulsion from the university. There are 10 pages in this test. A periodic table and formula sheet are provided at the end. You may rip these pages off of the exam and use them to cover your work during the test. Any scratch work should be done on the back of the test pages. Please show all work to receive partial credit. You have 80 minutes to complete the test.

Question 1 2 3 4 5 TOTAL

Points Possible Points Earned 10 10 10 10 10 50

TA Initial

#1. (10 points) Short Answer Questions a) Adding a catalyst will shift an equilibrium towards products. TRUE FALSE

b) A brand of toothpaste contains 0.24% m/v sodium fluoride. This concentration expressed in mol/L is: ____________________________________________. c) When the power was turned off to a 125 L water heater, the temperature of the water dropped from 75.0C to 22.5C. The amount of heat, in kJ, transferred to the surroundings was: ______________________________________________. d) Provide the name or chemical formula for the following compounds: MgSO45H2O copper (I) sulfide ________________________________________ ________________________________________

e) You take a 4.0 L volume of gas at 300 K. You compress the gas to a 2.0 L volume and simultaneously heat the vessel to 600 K. The pressure of the gas: DOUBLES HALVES QUADRUPLES STAYS CONSTANT

f) Give the precise chemical symbol for the following:

Number of protons Number of neutrons Number of electrons Chemical Symbol

10

10

g) The standard heat of formation of solid Na2CO3 is -1131 kJ/mol. Write the chemical equation for the reaction to which this value applies.

h) Exactly 2.00 moles of each gas below are placed in a sealed 1.0L flask at 600 K. 2A(g) + B(g) ! C(g) The reaction will proceed towards (circle one) KC = 2.5 at 600 K REACTANTS PRODUCTS

because ________________________________________________________________. i) Four balloons are filled to the same volume with the following gases. If a small hole is made in each balloon, which will deflate the fastest? Ne Ar N2 H2S

#2. (10 points) Alka-Seltzer tablets contain aspirin, sodium bicarbonate, and citric acid. When the tablet is dropped into a glass of water, the sodium bicarbonate and citric acid react to form carbon dioxide gas (causing the trademark fizzing), following the (unbalanced) reaction below. NaHCO3 (aq) 84.01 g/mol + H3C6H5O7(aq) " CO2(g) + H2O(l) + 192.12 g/mol 44.01 g/mol 18.02 g/mol Na3C6H5O7(aq) 258.07g/mol

a) An Alka-Seltzer tablet contains 1.700 g of sodium bicarbonate and 1.000 g of citric acid. What would be the mass of carbon dioxide evolved from one tablet dissolved in water?

Answer: _____________________ b) What is the volume (in L) of carbon dioxide gas produced at 1.000 atm and 25.0C if the above reaction has a percent yield of 88.5%?

Answer: ______________________

#3. (10 points). With the data measured at 298 K provided below, 2A(g) ! 2X(g) 2C(g) ! X(g) + B(g) KP = 35.5 KP = 7.2

a) What is the value of the equilibrium constant at 298 K for the following reaction? A(g) + B(g) ! 2C(g)

Answer: _______________________ b) For the reaction in part (a), 0.500 mol each of gases A and B are added to a 2.00 L flask at 298 K. What will be the partial pressure of gas C at equilibrium?

Answer:_________________________

#4. (10 points) Carbon monoxide can be further oxidized to carbon dioxide according to the reaction: CO(g) + ! O2(g) ! CO2(g) "H = -283.0 kJ/mol a) How much heat, in kJ, is associated with the oxidation of 10.0 grams of CO?

Answer: _____________________ b) What is the change in internal energy for the oxidation of one mole of CO at 298 K under constant pressure conditions?

Answer: ____________________ c) What is the change in internal energy for the oxidation of one mole of CO at 298 K under constant volume conditions?

Answer: ____________________

#5. (10 points) The haemoglobin content of blood is about 15.5g/100mL. The molar mass of haemoglobin is about 64 500 g/mol, and there are four iron atoms in each haemoglobin molecule. a) Approximately how many iron atoms are present in the 6 L of blood in a typical adult?

Answer: _________________________ b) One isotope of iron, iron-57, has a relative abundance of 2.20% and an exact mass of 56.935 g/mol. Approximately how many litres of human blood would contain 1.00 g of iron-57?

Answer: ___________________________

Gas Laws
PV = nRT P T = P1 + P2 + P3 + d = m/V = P(MM) / RT KE = (1/2)mvav2

Thermodynamics
!U = Q + W Wsystem = -P!V = - !nRT !H = !U + P!V QP = !U + P!V CP = CV + R Q = mc!T !Hrxn = "n!Hf(pdts) - "n!Hf(rxts) qrev = -wmax = nRT ln(V2/V1) !S = qrev/T !S (T1-T2) = nCP ln(T2/T1)

RateA = RateB

Mb Ma

Equilibrium
KP = KC(RT)!n

!S (T1-T2) = nCV ln(T2/T1)

Acid/Base
pOH = -log[OH-] pH = -log[H+] pH + pOH = 14 Ka x Kb = KW pH = pKa + log [A-]/[HA]

!G = !H - T!S !G = !G + RT ln(Q) !G = - RT ln(K) ln(K2/K1) = (-!H/R)(1/T2 - 1/T1)

The atom
E = h" c = "# E = -B/n2

pH =

pK a1 + pK a 2 2

Kinetics
[A]t = [A]o kt ln[A]t = ln[A]o kt 1/[A]t = 1/[A]o + kt k = Ae(-Ea/RT) ln(k2/k1) = (-Ea/R)(1/T2 - 1/T1)

Data For Water

Density $ = 1.00 g/mL (25C) C = 2.13 J g-1 K-1 (solid) C = 4.18 J g-1 K-1 (liquid) Cp = 2.01 J g-1 K-1 (gas)

%Hfus = 6.02 kJ mol-1 %Hvap = 40.7 kJ mol-1

Constants and Conversion Factors

1mm Hg = 1 torr 760mm Hg = 1 atm Avogadros Number Boltzmanns constant Faradays constant Gas constant N k F R R R R h c 1 atm = 101.325 kPa 1 atm = 1.01325 bar 6.022x1023 mol-1 1.30866x10-23 JK-1 96 485 Cmol-1 8.31451 JK-1mol-1 0.08206 atmLK-1mol-1 0.08314 barLK-1mol-1 8.31451 m3 PaK-1mol-1 6.62608x10-34 Js 2.99792458x108 ms-1

Plancks constant Speed of light