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Faridahhamat/chapter 9/saser

CHAPTER 9 : MANUFACTURED SUBSTANCES IN INDUSTRY

Industrial products are very important nowadays. There are manufactured purposely for our comfort.

These products are :

1. Sulphuric acid

2. ammonia

3. alloys

4. synthetic polymers

5. glass

6. ceramics

7. composite materials

SULPHURIC ACID

Uses:

1. Manufacture of : Detergents, artificial fabres and paint.

2. As electrolyte in car batteries

3. production of fertilizer

Manufacture:

The process called Contact Process

The raw materials used are sulphur, air and water.

The stages of process:

STAGE 1:Formation Of Sulphur Dioxide

Molten sulphur is burnt in dry air to produce sulphur dioxde

S

+

O 2

SO 2

Sulphur dioxide alsa can be produced by roasting sulphide ores

( lead )II sulphide) in air.

STAGE 2: Formation Of Sulphur Trioxide

Sulphur dioxide and access oxygen gas pass over vanadium (V) oxide catalyst at 450 C to produce sulphur trioxide , SO 3 .

2 SO 2

+

O 2

2SO 3

Optimum condition used are:

Temperature: 450 C

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Pressure: 1 atm Catalyst : Vanadium(V) oxide

About 97 % conversion occurs under this condition.

STAGE 3 : Formation Of Sulphuric Acid

Consists of 2 steps:

Step 1 : SO 3 is dissolved with concentrated sulphuric acid to form oleum.

SO 3

+

H 2 SO 4

H 2 S 2 O 7

Step 2 :

Oleum is then diluted with water to produce

concentrated sulphuric acid.

H 2 S 2 O 7

+

H 2 O

2 H 2 SO 4

H 2 SO 4 can be formed if react SO 3 directly to water:

SO 3

+

H 2 O

H 2 SO 4

But it is not done in industry because SO3 reacts too violently.

A lot of heat and large cloud of sulphuric acid mist are

produced which are corrosive and can pollute the environment.

It is difficult to condense.

SO 2 And Environment Pollution

SO 2 is released into atmosphere from:

1. burning of fossil fuels containing sulphur

2. The burning of sulphur (Contact process)

3. The extraction of certain metals from their sulphide ores

Will cause:

1. acid rain

2. coughing

3. chest pain

4. shortness of breath

5. bronchitis and lung disease

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AMMONIA ANND ITS SALTS

Uses Of Ammonia

To make fertilizers which is important to provide nitrogen for the healthy growth of plants.

Can be converted to nitric acid which used to synthetic fibres, explosives, wood pulp, paints, varnishes, lacquers rocket propellants.

The Properties of Ammonia

Alkaline

Colourless gas

Pungent smell

Less dense than water

Burns in oxygen gas but not in air

Is very soluble in water

Gives a white fume when a reacted with hydrogen chloride gas, HCl.

Manufacture of Ammonia

Through Haber Process

This process combines nitrogen gas from the air with hydrogen gas derived mainly from natural gas to form Ammonia, NH 3 .

Nitrogen gas is obtained from the fractional distillation of liquid air.

Hydrogen gas obtained from natural gas.

Step :

1. The ratio of one volume of nitrogen gas to three volumes of hydrogen is passed through the reactor.

2. The mixture is compressed to high temperature ( 200 atm) at 450 C.

3. Iron is used as catalyst in this process.

N 2

+

3H 2

2 NH 3

Preparation Of Ammonium Fetilisers :

Ammonium fertilizers contain ammonium ions. In the soil, the ammonium ions are oxidised to nitrate ions.

Example of ammonium fertilisers:

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1. Ammonium sulphate ( (NH 4 ) 2 SO 4 )

2. Ammonium nitrate ( NH 4 NO 3 )

3. Ammonium phosphate ( (NH 4 ) 3 PO 4 )

Example : What is the percentage by mass of nitrogen in ammonium sulphate, (NH 4 ) 2 SO 4

ALLOY

Is mixture of two or more elements with a certain fixed composition in which the major component is metal.

Pure metals are make up of the same type and same size of atoms.

The orderly arrangement of atoms make the metal ductile and malleable.

Orderly arrangement of atoms in metal enables the layer of atoms to slide on one another when force is applied.

of atoms to slide on one another when force is applied. Arrangement of atom in pure

Arrangement of atom in pure Metal: Closely packed & In an orderly manner

Force  Most pure metals are weak and soft.
Force
 Most pure metals are weak and soft.

Layers of atoms slide over each other.

The properties of pure metal can be improved by making them into alloys.

Alloys are stronger, harder, and resistant to corrosion, have a better furnish and luster.

The example of alloy. ( refer text book page 160 )

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Why make alloys ?

1. To improve the appearance of the pure metal

2. to increase the strength and hardness of the pure metal

3. to increase the resistance to corrosion of the pure metal.

The Arrangement Of Atom In Alloys

The presence of atoms of other metals that are of different size

disturb the orderly arrangement of atoms in the metal. This decrease

the layer of atoms from

sliding.

Thus alloy is stronger and harder than its pure metal.

SYNTHETIC POLYMERS

Polymer : Large molecules make up of many identical repeating sub-units called monomers which are joined together by covalent bonds.

Polymerization : a process to join the monomer into chains by repeated linking.

2 types of polymer :

1. naturally occurring polymers

2. Synthetic polymers : man-made polymer. Ex : Polythene, polyvinyl chloride, polypropene, Perspex, nylon and terylena.

GLASS AND CERAMICS

Glass : made from sand

The major component: silica, SiO 2 .

There are so many types of glass; fused glass is the simplest one which is mainly silica, SiO 2 .

Fused glass : Highly resistant glass. It can be heated to an extremely high temperature and then can be plunged into icy, cold water without cracking. It’s expensive but still widely used because of its ;

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1. Great purity

2. optical transparency

3. high temperature

4. chemical durability

5. Resistance to thermal shock.

It is used as :

1. Laboratory glassware

2. lenses

3. Telescope mirrors

4. optical fibres.

Ex : Starch, cellulose, wool, protein, silk and natural rubber.

The most common glass : Soda lime glass

Made by heating sand with limestone/ sodium carbonate.

Can be melted at a relatively low temperature

Easy to be shaped and has a good chemical durability.

High thermal expansion coefficient.

Expands a lot when it is heated and contracts a lot too when it is cooled.

Do not withstand heat.

Used to make : flat glass, electrical bulbs, mirrors and glass containers.

Soda lime glass + Boron oxide, B 2 O 3 Borosilicate glass

Has a lower thermal expansion coefficient

3 times as heat resistant as soda-lime glass

More resistant to chemical attacks because it contains less alkali.

Good to use in cookware, laboratory glassware and automobile headlight.

Used in glass pipelines and applications which require superior resistance to thermal shock and greater chemical durability.

Ceramic

Made from clay. Ex : Kaolin ( Aluminiumsilicate, Al 2 O 3 .2SiO 2 .2H 2 O )

When the clay is heated to a very high temperature, they undergo a series of chemical reactions and are hardened permanently to form ceramic.

Ex : clay pots, bricks, tiles and mugs.

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Ceramics are very hard, brittle, chemically inert, do not corrode, high melting point and are good insulators of electricity and heat.

Suitable for making abrasive, construction material, tableware, insulators in electrical equipments and refractories.

Comparing properties of glass and ceramics

How are they alike:

1. Hard

2. brittle

3. strong under compression

4. do not corrode

5. good electrical insulator

6. good heat insulator

7. resistant to chemical attacks

How are they different:

Glass

 

Ceramics

Highly transparent

Optical transparency

Opaque

Can be melted and remoulded

Moulding

Cannot be melted and remoulded

Lower melting point

Melting point

Very high melting point

COMPOSITE MATERIALS

Structural material that is formed by combining two or more different substances such as metal, alloys, glass, ceramic and polymers. These materials are created for specific application. The material formed has properties that are better than the original components.

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Types of Composite Material

Reinforced Concrete

Concrete: Consists a mixture of stones, chips and sand bound together by cement. It is strong but brittle and weak in tension.

Steel : Strong in tension.

Concrete reinforced with steel wires, steel bars or any polymers fibres, the resulting combination is a very tough material with more tensile strength.

The composites are good for the construction of large structures like high-rise building, bridges and oil platforms.

It is also cheap and can be moulded into any shape.

Superconductors

Capable of conducting electricity without any electrical resistance when they are cooled to extremely low temperature.

They are used in the bullet trains in Japan, magnetic energy-storage systems, generators, transformers and computer parts.

Fibre optic

Fibre optic cable consists of a bundle of glass or plastic threads that are surrounded by a glass cladding.

They are used to replace copper wire in long distance telephone lines, in mobile phone, video camera and to link computer within local area network.

Fibre optic is good to use because they have law material costs, high transmission capacity, chemical stability and less susceptible to interference.

Fibre Glass

Formed when glass fibres are used to reinforce plastic.

Properties : High tensile strength, can be easily coloured, low in density easily moulded and shaped and can be made into thin layers.

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Used to make household products like water storage tanks, badminton rackets, small boats, skis and helmets.

Photochromic Glass

Produced by embedding photochromic substances like silver chloride, AgCl crystals in glass or transparent polymers.

Used for making optical lenses, car windshields, smart energy efficient windows in buildings, information display panels, lense in cameras, optical switches and light intensity meters.