Name______________ Rate of Reaction & Equilibrium Test

1. How does raising the temperature of a reaction typically change its outcome? A. B. C. D. increases the number of moles of reactants decreases the number of moles of reactants increases the speed of the reaction decreases the speed of the reaction

2. Which statement most accurately describes when dynamic equilibrium is reached? A. B. C. D. When the rate of the forward reaction equals the rate of the reverse reaction When the concentration of the products is equal to the concentration of the reactants When all of the reactants are converted to products When the reverse reaction has completely occurred and only reactants remain

3. Which statement correctly explains how particle size increases reaction rate? A. B. C. D. Smaller particles expose more surface area to react Smaller particles expose less surface area to react Larger particles expose more surface area to react Larger particles are exposed to more catalysts

4. Which of the following statements about collisions and reaction rate is most correct? A. B. C. D. More energy causes fewer collisions and increases the reaction rate More energy causes more collisions and increases the reaction rate Less energy causes particles to collide with more force and decreases reaction rate Neither energy nor collisions affects the reaction rate

5. Which of the following graphs most correctly illustrates the typical relationship between reaction rate and temperature?

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6. What happens when reactants have sufficient energy and proper orientation?

7. Students measured the rate of a reaction and tested three different variables to produce the graphs below.

Rate Rate

Rate

Temperature

Concentration

Surface Area

Which variable increased the reaction rate the most?

8. Why do catalysts not appear as reactants or products in chemical equations?

9. In a chemical reaction, what is the result of increasing the number of collisions of atoms and the amount of energy in each collision? A. B. C. D. an endothermic reaction. an increase in amount of reactant a larger product molecule a higher rate of reaction

10. Explain why refrigerators prevent food from spoiling. hint: food spoiling is a chemical reaction.

11. Why does increasing the concentration of reactants often increase the rate of the reaction? A. B. C. D. the temperature will rise the activation energy is increased the number of collisions increases the products stop reverting back into reactants

12. In the graph below, at what time is equilibrium achieved? 2

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13. 14.

13. Why do carbon and oxygen not react to form carbon dioxide at room temperature?

Use this equation to answer questions 14-15:

2SO2 (g) + O2 (g)

2SO3 (g) + heat

14. How would increasing heat affect the equilibrium? A. B. C. D. It would stay the same It would increase the amount of SO2 and O2 It would decrease the amount of SO2 and O2 It would increase the amount of SO3

15. If the reaction were at equilibrium how would adding more SO3 affect the equilibrium?

16. Which of the following increases reaction rate? Choose all that apply. A. Adding a catalyst B. Decreasing concentration C. Increasing particle size D. Decreasing Temperature E. Increase concentration F. Increase Surface Area 17. Why do catalysts not appear as reactants or products in chemical equations? 18. In a chemical reaction, what is the role of the catalyst? Use this gra ph to ans wer

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A. B. C. D. Increased the activation energy. Increased the amount of time the reaction takes Decreased the activation energy needed. Decrease the rate of reaction

19. In the following recipe, circle all the factors that will increase the rate of reaction. In order to make bread, a student follows the recipe below. 1. The student pre-heats the oven 350 degree Celsius. In a big bowl, the student then mixes flour, sugar, eggs, and water. 2. In a separate small bowl, the student heated up cup of water to 35 degree Celsius and then mixed the yeast and the warm water together for about 30 seconds. 3. The student then poured the yeast water mixture into the big bowl. The student then kneads (mixes) everything for 10 minute. 4. The student then puts the bread in the oven and bakes it for 40 minutes.

20. After the reaction: CO2(g) + H2(g) adding more CO2 affect the equilibrium? A. B. C. D.

CO(g) + H2O(g) has reached equilibrium, how would

It would stay the same It would increase the amount of CO and H2O It would decrease the amount of CO and H2O It would increase the amount of H2

21. After the reaction: N2(g) + 3H2(g) A. B. C. D. E. F. Increasing the amount of N2 Increasing the amount of NH3 Reducing the amount of NH3 Reducing the temperature Increase temperature Decrease the amount of N2

2NH3(g) + heat has reached equilibrium, which of the following would cause the equilibrium to shift to the left? Pick all the answers that apply.

22. NO2 is a brown gas and N2O4 is a colorless gas. The rate of the forward reaction is equal to the rate of the reverse reaction. Imagine both of these gases are in a sealed flask. When you place the flask in ice water the gas clears up. When you place the flask in hot water you see more brown gas. Write the equation for this equilibrium reaction and explain your reaction below.

23. Using Information from graphs to draw warranted conclusions about reaction rates: 4

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An investigation was conducted to study the effect of the concentration of a reactant on the total time needed to complete a chemical reaction. Four trials of the same reaction were performed. In each trial the initial concentration of the reactant was different. The time needed for the chemical reaction to be completed was measured. The data for each of the four trials are shown in the table below.

Describe the trend of the data from the experiment above.

Infer from your graph how long it would take for a solution with a concentration of 0.012M to react.

Identify the independent variable and dependent variable in the experiment above.

24. 24. A student is studying rate of reaction using the reaction Mg + HCl- MgCl2 + H2 5

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She tries the reaction 2 times. For both reactions she controls unwanted variables by making sure that she uses acid that is at the same temperature and making sure that the she adds the same size piece of Magnesium. Reaction number 1 stops bubbling after 5 minutes and Reaction number 2 stops bubbling after 3 minutes.

Sketch concentrations of the acids in the beakers below: Remember to identify each beaker with reaction times.

Identify the independent variable, dependent variable and constants in the experiment above.

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Exceeding standard: Bond Energies (kJ/mol) Consider the following reaction:

Pt

C2H6

C2H4 + H2

C-C 348 C=C 614 C-H 413 H-H 436

a) b) c) d)

Calculate the bond energy of the reaction Determine if it is endothermic or exothermic reaction Draw energy diagram that show the calculated energies Show the Pt in the energy diagram. Pt lowers the activation energy by 1044 KJ/mol