Jee Main 2014 Question Paper 06.04.2014E

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RST
: PHYSICS, CHEMISTRY & MATHEMATICS

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PART A PHYSICS
1.
The current voltage relation of diode is

given by
I5(e1000V/T21)
1.
mA, where the
applied voltage V is in volts and the

temperature T is in degree Kelvin. If a
student makes an error measuring
60.01 V while measuring the current of
U U U- U
I5(e1000V/T21) mA , V
U U U T U
l 300 K U 5 mA U
60.01 V U U ,
U mA U ?
5 mA at 300 K, what will be the error in

the value of current in mA ?
2.
(1)
0.2 mA
(1)
0.2 mA
(2)
0.02 mA
(2)
0.02 mA
(3)
0.5 mA
(3)
0.5 mA
(4)
0.05 mA
(4)
0.05 mA
From a tower of height H, a particle is
2.
thrown vertically upwards with a

speed u. The time taken by the particle, to
hit the ground, is n times that taken by it
H U , u
U U U
U
n
to reach the highest point of its path.

The relation between H, u and n is :
H, u n
(1)
2 g H5n2u2
(1)
2 g H5n2u2
(2)
g H5(n22)2u2
(2)
g H5(n22)2u2
(3)
2 g H5nu2(n22)
(3)
2 g H5nu2(n22)
(4)
g H5(n22)u2
(4)
g H5(n22)u2
E/Page 2
SPACE FOR ROUGH WORK /
3.
A mass m is supported by a massless
3.
string wound around a uniform hollow

cylinder of mass m and radius R. If the
string does not slip on the cylinder, with
what acceleration will the mass fall on
R m
U U UU
m UU U
, U U
U U?
release ?
4.
(1)
2g
3
(1)
2g
3
(2)
g
2
(2)
g
2
(3)
5g
6
(3)
5g
6
(4)
(4)
A block of mass m is placed on a surface
4.
with a vertical cross section given by
x3
. If the coefficient of friction is 0.5,
6
the maximum height above the ground at
y5
which the block can be placed without
cU U
(1)
1
m
6
(1)
1
m
6
(2)
2
m
3
(2)
2
m
3
(3)
1
m
3
(3)
1
m
3
(4)
1
m
2
(4)
1
m
2
U
x3
cU U S U y5
6
0.5 , U U
, U U
,
slipping is :
E/Page 3
5.
When a rubber-band is stretched by a
5.
distance x, it exerts a restoring force of

magnitude F5ax1bx2 where a and b are
constants. The work done in stretching
the unstretched rubber-band by L is :
6.
U U x U
; U F5ax1bx2
a b SU
U U L U

(1)
aL21bL3
(1)
aL21bL3
(2)
1
(aL21bL3)
2
(2)
1
(aL21bL3)
2
(3)
aL2
bL3
1
2
3
(3)
aL2
bL3
1
2
3
(4)
1 aL2
bL3
2 2
3
(4)
1 aL2
bL3
2 2
3
A bob of mass m attached to an
6.
inextensible string of length l is suspended

from a vertical support. The bob rotates
in a horizontal circle with an angular
speed v rad/s about the vertical. About
l U m
U U U
U U v rad/s
U
U
the point of suspension :

(1)
angular momentum is conserved.
(1)
U U
(2)
angular momentum changes in
(2)
U U U

(3)
U U
U
(4)

UU
magnitude but not in direction.

(3)
angular momentum changes in

direction but not in magnitude.
(4)
angular momentum changes both in

direction and magnitude.
E/Page 4
7.
Four particles, each of mass M and
7.
equidistant from each other, move along

a circle of radius R under the action of their
mutual gravitational attraction. The speed
M U U
U U , U L
R U

of each particle is :
8.
(1)
GM
R
(1)
GM
R
(2)
2 2
(2)
2 2
(3)
GM
(1 1 2 2 )
R
(3)
GM
(1 1 2 2 )
R
(4)
1 GM
(1 1 2 2 )
2 R
(4)
1 GM
(1 1 2 2 )
2 R
GM
R
The pressure that has to be applied to the
8.
ends of a steel wire of length 10 cm to keep

its length constant when its temperature
GM
R
10 cm
SU U U U
h 1008C
SU U U U
is raised by 1008C is :
(For
steel
Youngs
modulus
is
231011 N m22 and coefficient of thermal

expansion is 1.131025 K21)
(SU S 231011 N m22

U U U 1.131025 K21 )
(1)
2.23108 Pa
(1)
2.23108
(2)
2.23109 Pa
(2)
2.23109
(3)
2.23107 Pa
(3)
2.23107
(4)
2.23106 Pa
(4)
2.23106
E/Page 5
9.
There is a circular tube in a vertical plane.
9.
Two liquids which do not mix and of

densities d1 and d2 are filled in the tube.
Each liquid subtends 908 angle at centre.
Radius joining their interface makes
d1
an angle a with vertical. Ratio d is :
2
U U ,
U d1
d2 , U U
908 U U cU
U a
d1
d2
(1)
1 1 sin a
1 2 sin a
(1)
1 1 sin a
1 2 sin a
(2)
1 1 cosa
1 2 cosa
(2)
1 1 cosa
1 2 cosa
(3)
1 1 tan a
1 2 tan a
(3)
1 1 tan a
1 2 tan a
(4)
1 1 sin a
1 2 cosa
(4)
1 1 sin a
1 2 cosa
E/Page 6
10.
On heating water, bubbles being formed
10.
at the bottom of the vessel detatch and rise.

Take the bubbles to be spheres of radius R
and making a circular contact of radius r
with the bottom of the vessel. If r << R,
and the surface tension of water is T, value
U U,
U U U U U
R U
S r r << R
U cU T ,
U r
of r just before bubbles detatch is :
(density of water is r )
w
(1)
R2
rw g
(2)
R2
rw g
(3)
R2
rw g
(4)
R2
3rw g
E/Page 7
3T
6T
( rw )
(1)
R2
rw g
(2)
R2
rw g
(3)
R2
rw g
(4)
R2
3rw g
3T
6T
11.
Three rods of Copper, Brass and Steel are
11.
welded together to form a Y - shaped

structure. Area of cross - section of each
rod54 cm 2 .
End of copper rod is
maintained at 1008C where as ends of

brass and steel are kept at 08C. Lengths of
the copper, brass and steel rods are 46, 13
and 12 cms respectively. The rods are
thermally insulated from surroundings
except at ends. Thermal conductivities of
copper, brass and steel are 0.92, 0.26 and
, SU U Y - U
U U U
S U 54 cm2 U
U 1008C
SU U 08C U U ,
SU U
46, 13 12 cms U , U
UU, U c U
, SU c
0.92, 0.26 0.12 CGS U
c U
0.12 CGS units respectively. Rate of heat

flow through copper rod is :
12.
(1)
1.2 cal/s
(1)
1.2 cal/s
(2)
2.4 cal/s
(2)
2.4 cal/s
(3)
4.8 cal/s
(3)
4.8 cal/s
(4)
6.0 cal/s
(4)
6.0 cal/s
One mole of diatomic ideal gas undergoes
12.
a cyclic process ABC as shown in figure.

The process BC is adiabatic.
The
temperatures at A, B and C are 400 K,

800 K and 600 K respectively. Choose the
mU
ABC U
BC Lhc A, B C
400 K, 800 K 600 K

correct statement :
(1)
The change in internal energy in
(1)
whole cyclic process is 250 R.

(2)
The change in internal energy in the
(2)
process CA is 700 R.
(3)
(3)
process AB is 2350 R.
(4)

process BC is 2500 R.
E/Page 8
(4)
U
U 250 R
CA U U
700 R
AB U U
2350 R
BC U U
2500 R
13.
An open glass tube is immersed in mercury
13.
in such a way that a length of 8 cm extends

above the mercury level. The open end of
the tube is then closed and sealed and the
tube is raised vertically up by additional
46 cm. What will be length of the air
U U U
U SU 8 cm U
U U
U U U U
46 cm U U U U
S ?
column above mercury in the tube now ?
14.
(Atmospheric pressure 576 cm of Hg)
(U 5Hg
(1)
16 cm
(1)
16 cm
(2)
22 cm
(2)
22 cm
(3)
38 cm
(3)
38 cm
(4)
6 cm
(4)
6 cm
A particle moves with simple harmonic
14.
motion in a straight line. In first t s, after

starting from rest it travels a distance a,
and in next t s it travels 2a, in same
76 cm)
U U U
US U U
t U U a U t U U 2a
U
direction, then :
15.
(1)
amplitude of motion is 3a
(1)
3a
(2)
time period of oscillations is 8t
(2)
8t
(3)
amplitude of motion is 4a
(3)
4a
(4)
time period of oscillations is 6t
(4)
6t
velocity of sound in air is 340 m/s.
85 cm U
U S

1250 Hz
340 m/s
(1)
12
(1)
12
(2)
(2)
(3)
(3)
(4)
(4)
A pipe of length 85 cm is closed from one
15.
end. Find the number of possible natural

oscillations of air column in the pipe whose
frequencies lie below 1250 Hz.
E/Page 9
The
16.
Assume that an electric field E 5 30 x 2 i

exists in space. Then the potential
16.
difference V A 2V O , where V O is the

potential at the origin and VA the potential
l E 5 30 x 2 i
U VA2VO, VO U
VA, x52 m U ,
at x52 m is :
17.
(1)
120 J
(1)
120 J
(2)
2120 J
(2)
2120 J
(3)
280 J
(3)
280 J
(4)
80 J
(4)
80 J
A parallel plate capacitor is made of two
17.
circular plates separated by a distance of

5 mm and with a dielectric of dielectric
constant 2.2 between them. When the
electric field in the dielectric is 33104 V/m,
U, U 5 mm ,
U ^ U
Ul SU 2.2 Ul U
Ul l 33104 V/m ,
U
the charge density of the positive plate will

be close to :
18.
(1)
631027 C/m2
(1)
631027 C/m2
(2)
331027 C/m2
(2)
331027 C/m2
(3)
33104 C/m2
(3)
33104 C/m2
(4)
63104 C/m2
(4)
63104 C/m2
In a large building, there are 15 bulbs of
18.
40 W, 5 bulbs of 100 W, 5 fans of 80 W

and 1 heater of 1 kW. The voltage of the
electric mains is 220 V. The minimum
, 40 W 15 , 100 W
5 , 80 W 5 1 kW 1 UU
U 220 V
$
capacity of the main fuse of the building

will be :
(1)
8A
(1)
8A
(2)
10 A
(2)
10 A
(3)
12 A
(3)
12 A
(4)
14 A
(4)
14 A
E/Page 10
19.
A conductor lies along the z-axis
19.
at 21.5 [ z < 1.5 m and carries
U U U
a fixed current of 10.0 A in 2 a z

direction (see figure).
53.0310 24
e 20.2x
10.0 A
For a field
2 az
SU U
U ( )
B 53.0310 24 e 20.2x a y T
a y T, find the
the x-axis.
SU x52.0 m, y50 m
531023 s U
x- U U

(1)
1.57 W
(1)
1.57 W
(2)
2.97 W
(2)
2.97 W
(3)
14.85 W
(3)
14.85 W
(4)
29.7 W
(4)
29.7 W
power required to move the conductor at

constant speed to x52.0 m, y50 m in
531023 s. Assume parallel motion along
20.
z- 21.5 [ z < 1.5 m
The coercivity of a small magnet where the
20.
ferromagnet gets demagnetized is

33103 A m21. The current required to be
passed in a solenoid of length 10 cm and
number of turns 100, so that the magnet
gets demagnetized when inside the
solenoid, is :
UU ,
, 33103 A m21
100 10 cm U
U ,
U U U ,

(1)
30 mA
(1)
30 mA
(2)
60 mA
(2)
60 mA
(3)
3A
(3)
3A
(4)
6A
(4)
6A
E/Page 11
21.
In the circuit shown here, the point C is
21.
kept connected to point A till the current

flowing through the circuit becomes
constant. Afterward, suddenly, point C
is disconnected from point A and
connected to point B at time t50. Ratio
U , C A
U U
U SU , ,
C A UU B t50
U t5L/R U U
U U U U U
of the voltage across resistance and the

inductor at t5L/R will be equal to :
e
12 e
(1)
e
12 e
(2)
(2)
(3)
21
(3)
21
(4)
22.
(1)
12 e
e
(4)
12 e
e
waves in a medium :
l U U
U
(1)
(1)
(2)
(3)
l
UU
(4)
During the propagation of electromagnetic
22.
Electric energy density is double of

the magnetic energy density.
(2)
Electric energy density is half of the

magnetic energy density.
(3)
Electric energy density is equal to the

magnetic energy density.
(4)
Both electric and magnetic energy

densities are zero.
E/Page 12
23.
A thin convex lens made from crown glass
m 5
m 5 3 has focal length f. When it is
measured in two different liquids having
5
3
refractive indices
24.
23.
4
5
and , it has the focal
3
3
4
3
UU ,
f1
lengths f1 and f2 respectively. The correct

relation between the focal lengths is :
(1)
f15f2 < f
(1)
f15f2 < f
(2)
f1 > f and f2 becomes negative
(2)
f1 > f
(3)
f2 > f and f1 becomes negative
(3)
f2 > f U f1
(4)
f1 and f2 both become negative
(4)
f1 f2
f2
U f2

angle(u). Select the correct statement.
U U - UcU
U (u)
(1)
(1)
908 U
SU U
(2)
SU, U
U ,
U
(3)
SU, U
U ,
U
(4)
SU
U U
A green light is incident from the water to
24.
the air - water interface at the critical

The entire spectrum of visible light
will come out of the water at an
angle of 908 to the normal.
(2)
The spectrum of visible light whose

frequency is less than that of green
light will come out to the air
medium.
(3)
The spectrum of visible light whose

frequency is more than that of green
light will come out to the air
medium.
(4)
The entire spectrum of visible light

will come out of the water at various
angles to the normal.
E/Page 13
25.
Two beams, A and B, of plane polarized
25.
light with mutually perpendicular planes

of polarization are seen through a
polaroid. From the position when the
beam A has maximum intensity (and
beam B has zero intensity), a rotation of
polaroid through 308 makes the two beams
appear equally bright.

A B U mU
S A
(U B ) UU
308 l
U
IA IB ,
If the initial
IA
IB
intensities of the two beams are IA and IB

IA
respectively, then I equals :
B
26.
(1)
(1)
(2)
3
2
(2)
3
2
(3)
(3)
(4)
1
3
(4)
1
3
The radiation corresponding to 32

transition of hydrogen atom falls on a
26.
metal surface to produce photoelectrons.

These electrons are made to enter a
magnetic field of 331024 T. If the radius
of the largest circular path followed by
these electrons is 10.0 mm, the work
U U 32 U
cU U U UU
U U 331024 T
U U mU
10.0 mm ,

function of the metal is close to :

(1)
1.8 eV
(1)
1.8 eV
(2)
1.1 eV
(2)
1.1 eV
(3)
0.8 eV
(3)
0.8 eV
(4)
1.6 eV
(4)
1.6 eV
E/Page 14
27.
Hydrogen (1H1), Deuterium (1H2), singly

ionised Helium ( 2 He 4 ) 1 and doubly
27.
ionised lithium ( 3Li 6 ) 11 all have one

electron around the nucleus. Consider an
electron transition from n52 to n51. If
the wave lengths of emitted radiation are
l 1 , l 2 , l 3 and l 4 respectively then

approximately which one of the following
U (1H1), UUU (1H2),

(2He4)1 U m
(3Li6)11 U U
U n52 n51 U U
U U U
l1, l2, l3 l4 ,
?
is correct ?
28.
(1)
4l152l252l35l4
(1)
4l152l252l35l4
(2)
l152l252l35l4
(2)
l152l252l35l4
(3)
l15l254l359l4
(3)
l15l254l359l4
(4)
l152l253l354l4
(4)
l152l253l354l4
The forward biased diode connection is :
28.
(1)
(1)
(2)
(2)
(3)
(3)
(4)
(4)
E/Page 15
29.
Match List - I (Electromagnetic wave type)
29.
with List - II (Its association/application)

and select the correct option from the
choices given below the lists :
List - I
(a)
Infrared
waves
List - II
(i)
- I
To treat muscular
strain
(b) Radio waves (ii) For broadcasting
30.
- I (l U U )
- II ( h/)
U

(c) X - rays
To detect fracture
(iii)
of bones
Ultraviolet
(d)
rays
Absorbed by the
(iv) ozone layer of the
atmosphere
(a)
(b)
(c)
(d)
(1)
(iv)
(iii)
(ii)
(i)
(2)
(i)
(ii)
(iv)
(3)
(iii)
(ii)
(4)
(i)
(ii)
- II
(a)
U U
(i)
(b)
UU U
(ii)
(c)
-U
(iii)
(d)
U
U
(iv)
a S

U
$
U mU
(a)
(b)
(c)
(d)
(1)
(iv)
(iii)
(ii)
(i)
(iii)
(2)
(i)
(ii)
(iv)
(iii)
(i)
(iv)
(3)
(iii)
(ii)
(i)
(iv)
(iii)
(iv)
(4)
(i)
(ii)
(iii)
(iv)
A student measured the length of a rod
30.
and wrote it as 3.50 cm. Which instrument

did he use to measure it ?
(1)
A meter scale.
(2)
A vernier calliper where the

10 divisions in vernier scale matches
with 9 division in main scale and
l U U
3.50 cm U
?
(1) UU S
(2) U U S
10 S 9
U S 1 cm 10
main scale has 10 divisions in 1 cm.

(3)
A screw gauge having 100 divisions
(3)
S $ U S
100 U 1 mm
(4)
S $ U S 50
U 1 mm
in the circular scale and pitch as

1 mm.
(4)
A screw gauge having 50 divisions

in the circular scale and pitch as
1 mm.
E/Page 16
B U
PART B CHEMISTRY
31.
The correct set of four quantum numbers
31.
for the valence electrons of rubidium atom
MU U (Z537) U
U U U U
(Z537) is :
32.
(1)
5, 0, 0, 1
1
2
(1)
5, 0, 0, 1
1
2
(2)
5, 1, 0, 1
1
2
(2)
5, 1, 0, 1
1
2
(3)
5, 1, 1, 1
1
2
(3)
5, 1, 1, 1
1
2
(4)
5, 0, 1, 1
1
2
(4)
5, 0, 1, 1
1
2
If
is
compressibility
factor,
32.
van der Waals equation at low pressure
Z U U
U
can be written as :
33.
(1)
Z511
RT
Pb
(1)
Z511
RT
Pb
(2)
Z512
a
VRT
(2)
Z512
a
VRT
(3)
Z512
Pb
RT
(3)
Z512
Pb
RT
(4)
Z511
Pb
RT
(4)
Z511
Pb
RT
CsCl crystallises in body centred cubic
33.
lattice. If a is its edge length then which

of the following expressions is correct ?
U SU
U a
- U ?
CsCl
(1)
rCs1 1 rCl25 3a
(1)
rCs1 1 rCl25 3a
(2)
3a
rCs1 1 rCl25
2
(2)
3a
rCs1 1 rCl25
2
(3)
3
rCs1 1 rCl25
a
2
(3)
3
rCs1 1 rCl25
a
2
(4)
rCs1 1 rCl25 3a
(4)
rCs1 1 rCl25 3a
E/Page 17
34.
For the estimation of nitrogen, 1.4 g of an
34.
organic compound was digested by
Kjeldahl method and the evolved ammonia

M
was absorbed in 60 mL of
sulphuric
10
acid. The unreacted acid required 20 mL
M
of
sodium hydroxide for complete
10
neutralization. The percentage of nitrogen
60 10 U

U 20
35.
6%
(2)
10%
(3)
3%
(4)
5%
Resistance of 0.2 M solution of an

electrolyte is 50 V.
The specific
35.
conductance of the solution is 1.4 S m21.

The resistance of 0.5 M solution of the same
electrolyte is 280 V.
The molar
conductivity of 0.5 M solution of the

electrolyte in S m2 mol21 is :
36.
(1)
5310 24
(2)
5310 23
(3)
5310 3
(4)
5310 2
For complete combustion of ethanol,

C2H5OH(l)13O2(g) 2CO2(g)13H2O(l),
36.
the amount of heat produced as measured

in bomb calorimeter, is 1364.47 kJ
mol21
at 258C. Assuming ideality the Enthalpy

of combustion, DcH, for the reaction will
be :
(R58.314 kJ mol21)
(1)
21366.95 kJ mol21
(2)
21361.95 kJ mol21
(3)
21460.50 kJ
mol21
21350.50 kJ
mol21
(4)
E/Page 18
M
10
UU U

in the compound is :
(1)
U 1.4 .
U U
(1)
6%
(2)
10%
(3)
3%
(4)
5%
l U 0.2 M U
50 V cU
1.4 S m21 l U 0.5 M
U 280 V l U
0.5 M U S m2 21

(1)
5310 24
(2)
5310 23
(3)
5310 3
(4)
5310 2
,
C2H5OH(l)13O2(g) 2CO2(g)13H2O(l),
UUU 258C U
1364.47 kJ mol21
, DcH,
(R58.314 kJ mol21)
(1)
21366.95 kJ mol21
(2)
21361.95 kJ mol21
(3)
21460.50 kJ mol21
(4)
21350.50 kJ mol21
37.
The equivalent conductance of NaCl at
37.
concentration C and at infinite dilution are

l C and l : , respectively. The correct
relationship between lC and l: is given
as :
(B SU )
(where the constant B is positive)

(1)
38.
lC5l:1(B)C
(1)
lC5l:1(B)C
(2)
lC5l:2(B)C
(2)
lC5l:2(B)C
(3)
lC5l:2(B) C
(3)
lC5l:2(B) C
(4)
lC5l:1(B) C
(4)
lC5l:1(B) C
Consider separate solutions of 0.500 M
38.
C 2 H 5 OH(aq), 0.100 M Mg 3 (PO 4 ) 2 (aq),

0.250 M KBr(aq) and 0.125 M Na3PO4(aq)
strong electrolytes ?
They all have the same osmotic
pressure.
(2)
0.100 M Mg 3 (PO 4 ) 2 (aq) has the

highest osmotic pressure.
(3)
0.125 M Na3PO4(aq) has the highest

osmotic pressure.
(4)
0.500 M C 2 H 5 OH(aq) has the

highest osmotic pressure.
1
For the reaction SO2(g)1 O2(g) SO3(g),
2
0.125 M Na3PO4()
258C U
UU
- ?
(1) U

(2) 0.100 M Mg 3 (PO 4 ) 2 ()
U
(3) 0.125 M Na 3 PO 4 ()
U
(4) 0.500 M C 2 H 5 OH ()
U
these solutions, assuming all salts to be

(1)
0.500 M C2H5OH(),
0.100 M Mg 3 (PO 4 ) 2 () , 0.250 M
KBr()
at 258C. Which statement is true about
39.
C U U U NaCl
U lC U l:

39.
if KP5KC(RT)x where the symbols have

usual meaning then the value of x is :
SO2(g)1
1
O
SO3(g)
2 2(g)
KP5KC(RT)x U
(assuming ideality)
U UM x

(1)
21
(1)
21
(2)
(2)
(3)
1
2
(3)
1
2
(4)
(4)
E/Page 19
1
2
1
2
40.
For the non - stoichiometre reaction
U U 2A1B C1D
298 K U

40.
2A1B C1D, the following kinetic data

were
obtained
in
three
separate
experiments, all at 298 K.

Initial
Initial rate of
Initial
Concentration Concentration formation of C
(A)
(B)
(mol L2S2)
0.1 M
0.1 M
1.2 3 10 23
U
(A)
U
(B)
0.1 M
0.1 M
1.2 3 10 23
0.1 M
0.2 M
1.2 3 10 23
0.1 M
0.2 M
0.2 M
0.1 M
2.4 3 10 23
1.2 3 10 23
0.2 M
0.1 M
2.4 3 10 23
C U
The rate law for the formation of C is :
41.
(1)
dc
5k[A] [B]
dt
(1)
dc
5k[A] [B]
dt
(2)
dc
5k[A]2 [B]
dt
(2)
dc
5k[A]2 [B]
dt
(3)
dc
5k[A] [B]2
dt
(3)
dc
5k[A] [B]2
dt
(4)
dc
5k[A]
dt
(4)
dc
5k[A]
dt
decreasing order of acid strength is :
(1)
HOCl > HClO2 > HClO3 > HClO4

HClO4 > HOCl > HClO2 > HClO3
(1)
(2)
HOCl > HClO2 > HClO3 > HClO4

HClO4 > HOCl > HClO2 > HClO3
HClO4 > HClO3 > HClO2 > HOCl

(3)
(4)
Among the following oxoacids, the correct
(2)
(3)
(4)
42.
U
U ( L2S2)
C
41.
salts is :

U (l U)

(1)
Ag
(1)
Ag
(2)
Ca
(2)
Ca
(3)
Cu
(3)
Cu
(4)
Cr
(4)
Cr
The metal that cannot be obtained by
42.
electrolysis of an aqueous solution of its
E/Page 20
43.
The octahedral complex of a metal ion
43.
M31
with four monodentate ligands L1,

L2, L3 and L4 absorb wavelengths in the
region of red, green, yellow and blue,
respectively. The increasing order of ligand
U U,
L1, L2, L3 U L4 cU U
, U, U S UZ
U U U U

M31
strength of the four ligands is :
44.
(1)
L4 < L3 < L2 < L1
(1)
L4 < L 3 < L 2 < L 1
(2)
L1 < L3 < L2 < L4
(2)
L1 < L 3 < L 2 < L 4
(3)
L3 < L2 < L4 < L1
(3)
L3 < L 2 < L 4 < L 1
(4)
L1 < L2< L4 < L3
(4)
L1 < L 2 < L 4 < L 3
Which one of the following properties is
44.
NO -
U ?
not shown by NO ?
(1)
It is diamagnetic in gaseous state
(1)
(2)
It is a neutral oxide
(2)
(3)
It combines with oxygen to form
(3)
U U
UU

(4)
nitrogen dioxide
(4)
45.
Its bond order is 2.5
In which of the following reactions H2O2
45.
acts as a reducing agent ?
2.5

U ?
H2O2
(a)
H2O21 2H112e2 2H2O
(a)
H2O21 2H112e2 2H2O
(b)
H2O222e2 O21 2H1
(b)
H2O222e2 O21 2H1
(c)
H2O212e2 2OH2
(c)
H2O212e2 2OH2
(d)
H2O21 2OH222e2 O212H2O
(d)
H2O21 2OH222e2 O212H2O
(1)
(a), (b)
(1)
(a), (b)
(2)
(c), (d)
(2)
(c), (d)
(3)
(a), (c)
(3)
(a), (c)
(4)
(b), (d)
(4)
(b), (d)
E/Page 21
46.
The correct statement for the molecule,
46.
CsI3 , is :
47.
(1)
it is a covalent molecule.
(1)
(2)
it contains Cs1 and I2

3 ions.
(2)
Cs1 U
(3)
it contains Cs31 and I2 ions.
(3)
Cs31 U I2
(4)
it contains Cs 1 , I 2 and lattice I 2

molecule.
(4)
Cs1, I2 U I2
I3
ratio of number of their molecule is :
U U
1 : 4

(1)
1:4
(1)
1:4
(2)
7 : 32
(2)
7 : 32
(3)
1:8
(3)
1:8
(4)
3 : 16
(4)
3 : 16
The ratio of masses of oxygen and nitrogen
47.
in a particular gaseous mixture is 1 : 4. The
48.
CsI3
Given below are the half - cell reactions :
48.
U h
Mn2112e2 Mn ; Eo521.18 V
Mn2112e2 Mn ; Eo521.18 V
2(Mn311e2 Mn21) ; Eo511.51 V
2(Mn311e2 Mn21) ; Eo511.51 V
The Eo for 3Mn21 Mn12Mn31 will be :
3Mn21 Mn12Mn31
(1)
22.69 V ; the reaction will not occur
(1)
22.69 V ;
(2)
22.69 V ; the reaction will occur
(2)
22.69 V ;
(3)
20.33 V ; the reaction will not occur
(3)
20.33 V ;
(4)
20.33 V ; the reaction will occur
(4)
20.33 V ;
E/Page 22
Eo
49.
Which series of reactions correctly
49.
represents chemical relations related to

iron and its compound ?
(1)
dil H SO
H SO , O
- M
U U
M U ?
(1)
2
4
2
4
2
Fe
FeSO 4
Fe 2 (SO 4 )3
Fe
heat
Fe 2 (SO 4 )3
Fe
(2)
O , heat
dil H SO
(2)
2
2
4
Fe
FeO
Cl , heat
heat, air
(3)
2
Fe
FeCl 3
Zn
O , heat
FeCl 2 Fe
CO, 6008 C
(4)
2
Fe
Fe 3O 4
CO, 700 8 C
The equation which is balanced and
O 2 ,
CO, 6008 C
Fe
Fe 3O 4
CO, 700 8 C
FeO
Fe
50.
Cl 2 ,
,
Fe
FeCl 3
Zn
FeCl 2 Fe
(4)
O 2 ,
H2 SO 4
Fe
FeO
FeSO 4
Fe
heat
FeSO 4
Fe
(3)
H2 SO 4
H2 SO 4 , O 2
Fe
FeSO 4
FeO
Fe
50.
represents the correct product(s) is :
U U
,
(1)
Li2O12KCl 2LiCl1K2O
(1)
Li2O12KCl 2LiCl1K2O
(2)
[CoCl(NH3)5]115H1Co21
(2)
[CoCl(NH 3)5]115 H1 Co 21
15 NH4 1Cl2
(3)
[Mg(H2O)6]211 (EDTA) 42
15 NH4 1Cl2
[Mg(EDTA)]21
[Mg(H2O)6]211(EDTA)42
NaOH
[Mg(EDTA) ] 21
1 6H2O
1 6H2O
(3)
excess NaOH
(4)
CuSO 414 K C N K 2[Cu(CN) 4]
1K2SO 4
E/Page 23
(4)
CuSO 41 4 K C N K 2[Cu(CN) 4]
1K2SO 4
51.
In S N 2 reactions, the correct order of

reactivity for the following compounds :
51.
CH 3 Cl, CH 3 CH 2 Cl, (CH 3 ) 2 CHCl and

(CH3)3CCl is :
CH3Cl, CH3CH2Cl, (CH3)2CHCl U

(CH3)3CCl SN2 U
SU
(1)
CH3Cl > (CH3)2CHCl > CH3CH2Cl

> (CH3)3CCl
(1)
CH3Cl > (CH3)2CHCl > CH3CH2Cl

> (CH3)3CCl
(2)
CH3Cl > CH3CH2Cl > (CH3)2CHCl

> (CH3)3CCl
(2)
CH3Cl > CH3CH2Cl > (CH3)2CHCl

> (CH3)3CCl
(3)
CH3CH2Cl > CH3Cl > (CH3)2CHCl
(3)
CH3CH2Cl > CH3Cl > (CH3)2CHCl
(CH3)2CHCl > CH3CH2Cl > CH3Cl

> (CH3)3CCl
(4)
> (CH3)3CCl
(4)
52.
On heating an aliphatic primary amine
> (CH3)3CCl
52.
with chloroform and ethanolic potassium

hydroxide, the organic compound formed
(CH3)2CHCl > CH3CH2Cl > CH3Cl

> (CH3)3CCl
U U U U
U UU U U
U U
is :
53.
(1)
an alkanol
(1)
(2)
an alkanediol
(2)
(3)
an alkyl cyanide
(3)
(4)
an alkyl isocyanide
(4)
The most suitable reagent for the
53.
R2CH22OH R2CHO
conversion of R2CH22OH R2CHO

is :
(1)
KMnO4
(1)
KMnO 4
(2)
K2Cr2O7
(2)
K2Cr2O7
(3)
CrO 3
(3)
CrO 3
(4)
PCC (Pyridinium Chlorochromate)
(4)
PCC
E/Page 24
(UU U)U
54.
with silver powder is :
U UU
U U U

(1)
Acetylene
(1)
(2)
Ethene
(2)
(3)
2 - Butyne
(3)
2-
(4)
2 - Butene
(4)
2-
The major organic compound formed by
54.
the reaction of 1, 1, 12 trichloroethane
55.
1, 1, 12 UU
which on acetylation produces C.
U $U U 1258C U
CO2 U U
U U C
The major product C would be :
(1)
(1)
(2)
(2)
(3)
(3)
(4)
(4)
Sodium phenoxide when heated with CO2
55.
under pressure at 1258C yields a product
E/Page 25
56.
smallest pKb value ?
U U
pKb
?
(1)
(CH3)2NH
(1)
(CH3)2NH
(2)
CH3NH2
(2)
CH3NH2
(3)
(CH3)3N
(3)
(CH3)3N
(4)
C6H5NH2
(4)
C6H5NH2
Considering the basic strength of amines
56.
in aqueous solution, which one has the
57.
For which of the following molecule
57.
significant m0 ?
(b)
(a)
(c)
(d)
m0
?
(a)
(b)
(c)
(d)
(1)
Only (a)
(1)
(2)
(a) and (b)
(2)
(a) U (b)
(3)
Only (c)
(3)
(4)
(c) and (d)
(4)
(c) U (d)
E/Page 26
(a)
(c)
58.
Which one is classified as a condensation
58.
U ?
polymer ?
59.
(1)
Dacron
(1)
UU
(2)
Neoprene
(2)
(3)
Teflon
(3)
U$
(4)
Acrylonitrile
(4)
Which one of the following bases is not
59.
U DNA ?
present in DNA ?
60.
(1)
Quinoline
(1)
(2)
Adenine
(2)
(3)
Cytosine
(3)
(4)
Thymine
(4)
In the reaction,
60.
LiAlH
PCl
Alc. KOH
,
LiAlH
PCl
Alc. KOH
4
5
CH3COOH
A
B
C ,
4
5
CH3COOH
A
B
C
the product C is :
(1)
Acetaldehyde
(1)
UUU
(2)
Acetylene
(2)
(3)
Ethylene
(3)
(4)
Acetyl chloride
(4)
U UU
E/Page 27
PART C MATHEMATICS
61.
X5{4 n 23n21 : n e N}
natural numbers, then XY is equal to :
Y5{9(n21) : n e N} , N,
, XY UU
(1)
(1)
(2)
(2)
(3)
(3)
(4)
Y2X
(4)
Y2X
If
X5{4 n 23n21
N}
and
61.
Y5{9(n21) : n e N}, where N is the set of
62.
If z is a complex number such that ?z?/2,

then the minimum value of z 1
63.
1
:
2
is strictly greater than
(2)
is strictly greater than
z ?z?/2 ,
z1
5
2
(1)
than
62.
3
but less
2
1
2
(1)
5
2
UU
(2)
3
2
UU U
UU
5
2
5
2
(3)
is equal to
5
2
(3)
5
2
(4)
lies in the interval (1, 2)
(4)
If a e R and the equation
63.
aeR
(1, 2)
23(x2[x])212 (x2[x])1a250
23(x2[x])212 (x2[x])1a250
(where [x] denotes the greatest integer

possible values of a lie in the interval :
( [x] Z
[ x ) Z , a
U S ,
(1)
(22, 21)
(1)
(22, 21)
(2)
(2:, 22) (2, :)
(2)
(2:, 22) (2, :)
(3)
(21, 0) (0, 1)
(3)
(21, 0) (0, 1)
(4)
(1, 2)
(4)
(1, 2)
[ x) has no integral solution, then all
E/Page 28
64.
Let a and b be the roots of equation
64.
px21qx1r50, p0. If p, q, r are in A.P.

and
1
1
1 5 4 , then the value of ?a2b?
a
b
a b U px21qx1r50, p0
p, q, r U
1
1
1 54
a
b
, ?a2b?
is :
65.
(1)
34
9
(1)
34
9
(2)
2 13
9
(2)
2 13
9
(3)
61
9
(3)
61
9
(4)
2 17
9
(4)
2 17
9
If a, b0, and f (n)5an1bn and

3
65.
1 1 f (1) 1 1 f (2)
1 1 f (1) 1 1 f (2) 1 1 f (3)

1 1 f (2) 1 1 f (3) 1 1 f (4)
5K(12a)2 (12b)2 (a2b)2
equal to :
(1)
(1)
(2)
21
(2)
21
(3)
ab
(3)
ab
(4)
1
ab
(4)
1
ab
If A is an 333 non - singular matrix such

that AA95A9A and
B5A21
66.
A9, then BB9
equals :
B21
(1)
B21
(2)
(B21)9
(2)
(B21)9
(3)
I1B
(3)
I1B
(4)
(4)
UU
333
AA95A9A B5A21 A9 , BB9 UU

A
(1)
E/Page 29
1 1 f (1) 1 1 f (2)
1 1 f (1) 1 1 f (2) 1 1 f (3)

1 1 f (2) 1 1 f (3) 1 1 f (4)
5K(12a) 2 (12b) 2 (a2b) 2 , then K is
66.
a, b0, f (n)5an1bn
67.
If the coefficients of x 3 and x 4 in the
67.
expansion of (11ax1bx 2 ) (122x) 18 in

powers of x are both zero, then (a, b) is
(11ax1bx2) (122x)18 x
U x3 x4, , (a, b)
UU
equal to :
68.
69.
(1)
14 , 272
(1)
14 , 272
(2)
16 , 272
(2)
16 , 272
(3)
16 , 251
(3)
16 , 251
(4)
14 , 251
(4)
14 , 251
If (10) 9 12(11) 1 (10) 8 13(11) 2 (10) 7 1...
68.
(10)912(11) 1 (10)813(11)2 (10)71...
110 (11)95k (10)9, then k is equal to :
110 (11)95k (10)9 ,
(1)
100
(1)
100
(2)
110
(2)
110
(3)
121
10
(3)
121
10
(4)
441
100
(4)
441
100
k UU
Then the common ratio of the G.P. is :
U
U U
, U
U
(1)
22 3
(1)
22 3
(2)
21 3
(2)
21 3
Three positive numbers form an increasing
69.
G.P. If the middle term in this G.P. is

doubled, the new numbers are in A.P.
(3)
(4)
E/Page 30
(3)
21 3
31
(4)
21 3
31
70.
71.
72.
lim
sin ( p cos 2 x )
x2
x 0
is equal to :
70.
lim
sin ( p cos 2 x )
x2
x 0
(1)
2p
(1)
2p
(2)
(2)
(3)
p
2
(3)
p
2
(4)
(4)
If g is the inverse of a function f and

1
, then g9 (x) is equal to :
f 9 (x)5
1 1 x5
71.
g f f 9 (x)5 1 1 x 5
, g9 (x) UU
(1)
1 1 { g ( x )}
(1)
1 1 { g ( x )}
(2)
11{g(x)}5
(2)
11{g(x)} 5
(3)
11x 5
(3)
11x 5
(4)
5x 4
(4)
5x 4
f (1)56, then for some ce]0, 1[ :
f g, [0, 1]
f (0)525g(1), g(0)50 U f (1)56 cU
U , ce]0, 1[
(1)
f 9(c)5g9(c)
(1)
f 9(c)5g9(c)
(2)
f 9(c)52g9(c)
(2)
f 9(c)52g9(c)
(3)
2f 9(c)5g9(c)
(3)
2f 9(c)5g9(c)
(4)
2f 9(c)53g9(c)
(4)
2f 9(c)53g9(c)
If f and g are differentiable functions in
72.
[0, 1] satisfying f (0)525g(1), g(0)50 and
E/Page 31
73.
If x521 and x52 are extreme points of

f(x)5a log
?x?1bx21x
73.
then :
1
2
(1)
a52, b52
(2)
a52, b5
(3)
a526, b5
(4)
a526, b52
1
2
1
2
1
2
74.
1 x1
The integral 1 1 x 2 e x d x is
x521
x52,
f(x)5a log ?x?1bx21x
U ,
1
2
(1)
a52, b52
(2)
a52, b5
(3)
a526, b5
(4)
a526, b52
1
2
1
2
1
2
74.
1 x1
1 1 x 2 e x d x
x
UU
equal to :
(1)
(x11)
(2)
2x
(3)
75.
1
x1
x
e
(x21)
(4)
1
x1
x
e
1
x1
x
e
(2)
1c
1
x1
x
e
(3)
1c
1c
(4)
The integral
p
(1)
1c
75.
x
x
1 1 4 sin
2 4 sin d x equals :
2
2
2
2x
1
x1
x
e
(x21)
x
1
x1
x
e
1c
1c
1
x1
x
e
1c
1c
1 1 4 sin 2
x
x
2 4 sin d x
2
2
(1)
4 324
(2)
4 3 2 42
p24
(3)
p24
2p
2 42 4 3
3
(4)
2p
2 42 4 3
3
(1)
4 324
(2)
4 3 2 42
(3)
(4)
E/Page 32
(x11)
1
x1
x
e
p
3
p
3
UU
76.
The area of the region described by

A5{(x, y) :
77.
78.
x21y2
[ 1 and
y2
76.
[ 12x} is :
mU
A5{(x, y) : x21y2 [ 1
(1)
p
2
2
2
3
(1)
p
2
2
2
3
(2)
p
2
1
2
3
(2)
p
2
1
2
3
(3)
p
4
1
2
3
(3)
p
4
1
2
3
(4)
p
4
2
2
3
(4)
p
4
2
2
3
Let the population of rabbits surviving at
77.
y2 [ 12x}
t U U
U
a time t be governed by the differential

dp(t)
1
5 p(t) 2200.
equation
dt
2
If p(0)5100, then p(t) equals :
p(0)5100 ,
dp(t)
1
5 p(t) 2200
dt
2
mU
p(t) UU
(1)
6002500 et/2
(1)
6002500 et/2
(2)
4002300 e2t/2
(2)
4002300 e2t/2
(3)
4002300 et/2
(3)
4002300 et/2
(4)
3002200 e2t/2
(4)
3002200 e2t/2
(1, 21) and parallel to PS is :
PS
P(2, 2), Q(6,21) R(7, 3) (1, 21)
U U, PS U ,
U
(1)
4x17y1350
(1)
4x17y1350
(2)
2x29y21150
(2)
2x29y21150
(3)
4x27y21150
(3)
4x27y21150
(4)
2x19y1750
(4)
2x19y1750
Let PS be the median of the triangle with
78.
vertices P(2, 2), Q(6,21) and R(7, 3). The

equation of the line passing through
E/Page 33
79.
Let a, b, c and d be non-zero numbers. If
79.
the point of intersection of the lines

4ax12ay1c50 and 5bx12by1d50 lies
in the fourth quadrant and is equidistant
a, b, c d U U
4ax12ay1c50 5bx12by1d50
U Z
US ,
from the two axes then :
80.
(1)
3bc22ad50
(1)
3bc22ad50
(2)
3bc12ad50
(2)
3bc12ad50
(3)
2bc23ad50
(3)
2bc23ad50
(4)
2bc13ad50
(4)
2bc13ad50
The locus of the foot of perpendicular
80.
drawn from the centre of the ellipse

x213y256 on any tangent to it is :
81.
x213y256 S
U U
(1)
(x21y 2)256x 212y 2
(1)
(x21y 2)256x 212y 2
(2)
(x21y 2)256x 222y 2
(2)
(x21y 2)256x 222y 2
(3)
(x22y 2)256x 212y 2
(3)
(x22y 2)256x 212y 2
(4)
(x22y 2)256x 222y 2
(4)
(x22y 2)256x 222y 2
Let C be the circle with centre at (1, 1) and
81.
radius51. If T is the circle centred at

(0, y), passing through origin and touching
the circle C externally, then the radius of
C (1, 1) U
51 T (0, y)
U C s M
S U , T UU
T is equal to :
(1)
1
2
(1)
1
2
(2)
1
4
(2)
1
4
(3)
3
2
(3)
3
2
(4)
3
2
(4)
3
2
E/Page 34
82.
The slope of the line touching both the
82.
parabolas y254x and x25232y is :
83.
U y254x x25232y S
U U
(1)
1
8
(1)
1
8
(2)
2
3
(2)
2
3
(3)
1
2
(3)
1
2
(4)
3
2
(4)
3
2
2x2y1z1350
The image of the line
83.
y 23
x 21
z 24
5
5
in the plane
3
1
25
2x2y1z1350 is the line :
y 23
x 21
z 24
5
5
3
1
25
(1)
y 15
x 23
z 22
5
5
25
3
1
(1)
y 15
x 23
z 22
5
5
3
1
25
(2)
y 15
x 23
z 22
5
5
23
21
5
(2)
y 15
x 23
z 22
5
5
23
21
5
(3)
y 25
x 13
z 22
5
5
25
3
1
(3)
y 25
x 13
z 22
5
5
3
1
25
(4)
y 25
x 13
z 12
5
5
23
21
5
(4)
y 25
x 13
z 12
5
5
23
21
5
E/Page 35
84.
The angle between the lines whose
84.
direction cosines satisfy the equations

l1m1n50 and l25m21n2 is :
85.
86.
U , - , U
l1m1n50 l25m21n2 cU U ,

(1)
p
6
(1)
p
6
(2)
p
2
(2)
p
2
(3)
p
3
(3)
p
3
(4)
p
4
(4)
p
4

2
If a3b b3c c3a 5l a b c then l is
equal to :
85.

2
a3b b3c c3a 5l a b c
UU
(1)
(1)
(2)
(2)
(3)
(3)
(4)
(4)
Let A and B be two events such that

P (A B) 5
P (A ) 5
1
,
6
P (A B) 5
1
4
86.
and
1
, where A stands for the
4
complement of the event A. Then the
P (A B) 5
P (A ) 5
1
4
1
,
6
P (A B) 5
A U
1
4
U A B
(1)
independent but not equally likely.
(1)
S U
(2)
independent and equally likely.
(2)
(3)
mutually exclusive and independent.
(3)
USU S
(4)
equally likely but not independent.
(4)
U S
events A and B are :
E/Page 36
, l
87.
The variance of first 50 even natural
87.
50 U
numbers is :
88.
(1)
437
(1)
437
(2)
437
4
(2)
437
4
(3)
833
4
(3)
833
4
(4)
833
(4)
833
1
(sin k x 1 cosk x ) where
k
x e R and k/1. Then f4(x)2f6(x) equals :
Let f k ( x ) 5
88.
1
(sin k x 1 cosk x ) ,
k
x e R k/1 , f4(x)2f6(x) UU
fk ( x ) 5
(1)
1
4
(1)
1
4
(2)
1
12
(2)
1
12
(3)
1
6
(3)
1
6
(4)
1
3
(4)
1
3
E/Page 37
89.
A bird is sitting on the top of a vertical
89.
pole 20 m high and its elevation from a

point O on the ground is 458. It flies off
horizontally straight away from the
point O. After one second, the elevation
of the bird from O is reduced to 308. Then
20 . U U
U U O
458 O U
U , O
U U 308 U (. . )

the speed (in m/s) of the bird is :
90.
(1)
20 2
(1)
20 2
(2)
20 ( 3 2 1)
(2)
20 ( 3 2 1)
(3)
40 ( 2 2 1)
(3)
40 ( 2 2 1)
(4)
40 ( 3 2
(4)
40 ( 3 2
2)
The statement ~(p ~q) is :

(1)
a tautology
(2)
a fallacy
(3)
equivalent to p q
(4)
equivalent to ~p q
90.
-o0oSPACE FOR ROUGH WORK /
E/Page 38
2)
~(p ~q)
(1) L (tautology)
(2) (fallacy)
(3) p q
(4) ~p q
-o0o-
E/Page 39
Read the following instructions carefully :

U U S U U (D -1) U U
U / U U
U D-2 U U / U
/ U U
3. U S/U U U S U
R
4. U

5. U U
- () U
U U ,
U
6. U S U U
US ( U S U
S UU), U U S
U
7. U U U U
, U S
U U mU
, U D U U U
S D U (D 39)
8. U, U / U U
U U
U S
9. U U U U
10. U U
S U
11. U U U S
U U SU U U U
U U U S U SU
U U
U
U S S U

12. U/S U , U
U U
13. U U U .../U
U mU
.../U
U
14. S U S U

15. U mU U / U
U U , S,
, U, U
U U U
U
1. The candidates should fill in the required particulars 1.

on the Test Booklet and Answer Sheet (Side1) with
Blue/Black Ball Point Pen.
2. For writing/marking particulars on Side2 of the 2.
Answer Sheet, use Blue/Black Ball Point Pen only.
3. The candidates should not write their Roll Numbers

anywhere else (except in the specified space) on the
Test Booklet/Answer Sheet.
4. Out of the four options given for each question, only
one option is the correct answer.
5. For each incorrect response, onefourth () of the total
marks allotted to the question would be deducted from
the total score. No deduction from the total score,
however, will be made if no response is indicated for
an item in the Answer Sheet.
6. Handle the Test Booklet and Answer Sheet with care,
as under no circumstances (except for discrepancy in

Test Booklet Code and Answer Sheet Code), another set
will be provided.
7. The candidates are not allowed to do any rough work

or writing work on the Answer Sheet. All calculations/
writing work are to be done in the space provided for
this purpose in the Test Booklet itself, marked Space
for Rough Work. This space is given at the bottom of
each page and in one page (Page 39) at the end of the
booklet.
8. On completion of the test, the candidates must hand
over the Answer Sheet to the Invigilator on duty in the
Room/Hall. However, the candidates are allowed to
take away this Test Booklet with them.
9. Each candidate must show on demand his/her Admit
Card to the Invigilator.
10. No candidate, without special permission of the
Superintendent or Invigilator, should leave his/her
seat.
11. The candidates should not leave the Examination Hall
without handing over their Answer Sheet to the
Invigilator on duty and sign the Attendance Sheet
again. Cases where a candidate has not signed the
Attendance Sheet a second time will be deemed not to
have handed over the Answer Sheet and dealt with as
an unfair means case. The candidates are also required
to put their left hand THUMB impression in the space
provided in the Attendance Sheet.
12. Use of Electronic/Manual Calculator and any
Electronic Item like mobile phone, pager etc. is
prohibited.
13. The candidates are governed by all Rules and
Regulations of the JAB/Board with regard to their
conduct in the Examination Hall. All cases of unfair
means will be dealt with as per Rules and Regulations
of the JAB/Board.
14. No part of the Test Booklet and Answer Sheet shall be
detached under any circumstances.
15. Candidates are not allowed to carry any textual
material, printed or written, bits of papers, pager,
mobile phone, electronic device or any other material
except the Admit Card inside the examination
hall/room.
E/Page 40

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This booklet contains 40 printed pages.

: PHYSICS, CHEMISTRY & MATHEMATICS

1. Immediately fill in the particulars on this page of the Test

Examination Centre Number :

Name of Examination Centre (in Capital letters) :

Name of the Candidate (in Capital letters ) :

Test Booklet Code

The current voltage relation of diode is

mA, where the

applied voltage V is in volts and the

5 mA at 300 K, what will be the error in

From a tower of height H, a particle is

thrown vertically upwards with a

to reach the highest point of its path.

SPACE FOR ROUGH WORK /

A mass m is supported by a massless

string wound around a uniform hollow

A block of mass m is placed on a surface

with a vertical cross section given by

which the block can be placed without

SPACE FOR ROUGH WORK /

When a rubber-band is stretched by a

distance x, it exerts a restoring force of

A bob of mass m attached to an

inextensible string of length l is suspended

the point of suspension :

angular momentum is conserved.

angular momentum changes in

magnitude but not in direction.

angular momentum changes in

angular momentum changes both in

SPACE FOR ROUGH WORK /

Four particles, each of mass M and

equidistant from each other, move along

The pressure that has to be applied to the

ends of a steel wire of length 10 cm to keep

231011 N m22 and coefficient of thermal

(SU S 231011 N m22

SPACE FOR ROUGH WORK /

There is a circular tube in a vertical plane.

Two liquids which do not mix and of

SPACE FOR ROUGH WORK /

On heating water, bubbles being formed

at the bottom of the vessel detatch and rise.

of r just before bubbles detatch is :

SPACE FOR ROUGH WORK /

Three rods of Copper, Brass and Steel are

welded together to form a Y - shaped

End of copper rod is

maintained at 1008C where as ends of

0.12 CGS units respectively. Rate of heat

One mole of diatomic ideal gas undergoes

a cyclic process ABC as shown in figure.

temperatures at A, B and C are 400 K,

The change in internal energy in

whole cyclic process is 250 R.

The change in internal energy in the

The change in internal energy in the

The change in internal energy in the

SPACE FOR ROUGH WORK /

An open glass tube is immersed in mercury

in such a way that a length of 8 cm extends

column above mercury in the tube now ?

(Atmospheric pressure 576 cm of Hg)