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PART A PHYSICS

1.

In terms of resistance R and time T, the 1.

m
of the permeability
e
m and permittivity e is :

dimensions of ratio

2.

A
U R U T ,
l e

(1)

[RT22]

(1)

[RT22]

(2)

[R2 T21]

(2)

[R2 T21]

(3)

[R2]

(3)

[R2]

(4)

[R2 T2]

(4)

[R2 T2]

The initial speed of a bullet fired from a 2.


rifle is 630 m/s. The rifle is fired at the
centre of a target 700 m away at the same
level as the target. How far above the
centre of the target the rifle must be aimed

m
e

U U U
630 m/s SU U 700 m U
U U
U
U ?

in order to hit the target ?


(1)

1.0 m

(1)

1.0 m

(2)

4.2 m

(2)

4.2 m

(3)

6.1 m

(3)

6.1 m

(4)

9.8 m

(4)

9.8 m

English : 1

Set : 11

Hindi : 1

Set : 11

3.

A body of mass 5 kg under the action of 3.

r
constant force F5Fx i 1 Fy j has velocity
at t50s as

r
v 5 6 i 22 j m/s and at

r
r
t510 s as v516 j m/s. The force F is :

SU

r
F5Fx i 1 Fy j

5 kg

r
v 5 6 i 22 j m/s

r
v516 j m/s

t50s

(1)

(23 i 14 j ) N

(2)

3
4
i1
j N
2
5
5

(2)

(3)

(3 i 2 4 j ) N

3
4
i1
j N
2
5
5

(3)

(3 i 2 4 j ) N

(4)

3
4
i 2 j N
5
5

(4)

3
4
i 2 j N
5
5

English : 2

Set : 11

Hindi : 2

t510 s

(23 i 14 j ) N

(1)

r
F

Set : 11

4.

A small ball of mass m starts at a point A 4.


with speed v o and moves along a

frictionless track AB as shown. The


track BC has coefficient of friction m. The

ball comes to stop at C after travelling a

m UU A vo
U U U AB U
BC
m C U U L
L L :

distance L which is :

(1)

(2)

(3)

(4)

v2
2h
1 o
2m g
m

(1)

v2
2h
1 o
m
2m g

v2
h
1 o
m
2m g

(2)

v2
h
1 o
m
2m g

v2
h
1 o
mg
2m

(3)

v2
h
1 o
2m
mg

v2
h
1 o
2m
2m g

(4)

v2
h
1 o
2m
2m g

English : 3

Set : 11

Hindi : 3

Set : 11

5.

of the surface at a place which receives 100

3.031025 kg
U 9 m/s
S U 100 cm S
UU cU U mU SU

cm of rain in a year.

(1)

3.53105 J

(1)

3.53105 J

(2)

4.053104 J

(2)

4.053104 J

(3)

3.03105 J

(3)

3.03105 J

(4)

9.03104 J

(4)

9.03104 J

The average mass of rain drops is 5.


3.031025 kg and their average terminal
velocity is 9 m/s. Calculate the energy
transferred by rain to each square metre

6.

is M and its mass per unit length at the

L U
l U U U
U M
U U U lo ,
U U

lighter end is lo, then the distance of the


centre of mass from the lighter end is :

(1)

l L2
L
2 o
2
4M

6.

A thin bar of length L has a mass per unit


length l, that increases linearly with
distance from one end. If its total mass

(1)

L
l L2
2 o
2
4M

(2)

l L2
L
1 o
3
8M

(2)

l L2
L
1 o
3
8M

(3)

l L2
L
1 o
3
4M

(3)

l L2
L
1 o
3
4M

(4)

l L2
2L
2 o
3
6M

(4)

l L2
2L
2 o
3
6M

English : 4

Set : 11

Hindi : 4

Set : 11

7.

From a sphere of mass M and radius R, a 7.

smaller sphere of radius R 2 is carved out


such that the cavity made in the original

R 2 UU U

U ( )
U U U
U 3R ,
L

sphere is between its centre and the


periphery. (See figure).

For the

configuration in the figure where the


distance between the centre of the original

sphere and the removed sphere is 3R, the


gravitational force between the two
spheres is :

(1)

(1)

(2)

(3)

(4)

41 GM 2

(2)

3600 R 2

41 GM 2

(3)

450 R 2
59 GM 2
450 R

(4)

41 GM 2
3600 R 2
41 GM 2
450 R 2
59 GM 2
450 R 2

GM 2
225 R 2

GM 2
225 R 2

English : 5

Set : 11

Hindi : 5

Set : 11

8.

The Bulk moduli of Ethanol, Mercury and 8.


water are given as 0.9, 25 and 2.2
respectively in units of 109 Nm22. For a
given value of pressure, the fractional

9
. Which of
compression in volume is
V
the following statements about

9
for
V

, U S
109 Nm22 0.9, 25 2.2
,

9
V

9
V

these three liquids is correct ?

9.

(1)

Ethanol > Water > Mercury

(1)

(2)

Water > Ethanol > Mercury

(2)

(3)

Mercury > Ethanol > Water

(3)

(4)

Ethanol > Mercury > Water

(4)

A tank with a small hole at the bottom has 9.


been filled with water and kerosene
(specific gravity 0.8). The height of water
is 3 m and that of kerosene 2 m. When the
hole is opened the velocity of fluid coming
out from it is nearly : (take g510 ms22
and density of water 5103 kg m23)

> > U
> > U
U > >
> U >

UU U U ^
( 0.8) U
3 m U ^ 2 m U
,
: (g510 ms 22 U
5103 kg m23)

(1)

10.7 ms21

(1)

10.7 ms21

(2)

9.6 ms21

(2)

9.6 ms21

(3)

8.5 ms21

(3)

8.5 ms21

(4)

7.6 ms21

(4)

7.6 ms21

English : 6

Set : 11

Hindi : 6

Set : 11

10.

An air bubble of radius 0.1 cm is in a liquid 10.


having surface tension 0.06 N/m and
density 103 kg/m3. The pressure inside
the bubble is 1100 Nm22 greater than the
atmospheric pressure. At what depth is

cU 0.06 N/m U 103 kg/m3


0.1 cm
U U
1100 Nm22 cU
U U ? (g59.8 ms22)

the bubble below the surface of the


liquid ? (g59.8 ms22)

11.

(1)

0.1 m

(1)

0.1 m

(2)

0.15 m

(2)

0.15 m

(3)

0.20 m

(3)

0.20 m

(4)

0.25 m

(4)

0.25 m

A hot body, obeying Newtons law of 11.


cooling is cooling down from its peak value
808C to an ambient temperature of 308C.
It takes 5 minutes in cooling down from
808C to 408C. How much time will it take
to cool down from 628C to 328C ?
(Given ln 250.693, ln 551.609)
(1)

3.75 minutes

(2)

8.6 minutes

(3)

9.6 minutes

(4)

6.5 minutes

English : 7

Set : 11

U U
S 808C U
308C UU 808C 408C
UU 5 U 628C 328C
U ?
( ln 250.693, ln 551.609)
(1) 3.75 U
(2) 8.6 U
(3) 9.6 U
(4) 6.5 U

Hindi : 7

Set : 11

12.

During an adiabatic compression, 830 J of 12.


work is done on 2 moles of a diatomic ideal
gas to reduce its volume by 50%. The
change in its temperature is nearly :
(R58.3 JK21 mol21)

Lhc U, mU
2 50%
830 J U
U (R58.3 JK21 mol21)

(1)

40 K

(1)

40 K

(2)

33 K

(2)

33 K

(3)

20 K

(3)

20 K

(4)

14 K

(4)

14 K

English : 8

Set : 11

Hindi : 8

Set : 11

13.

An ideal monoatomic gas is confined in a 13.


cylinder by a spring loaded piston of cross
section 8.031023 m2. Initially the gas is at
300K

and

2.4310 23

occupies

m3

volume

of

and the spring is in its

relaxed state as shown in figure. The gas is


heated by a small heater until the piston
moves out slowly by 0.1 m. The force
constant of the spring is 8000 N/m and the
atmospheric pressure is 1.03105 N/m2.
The cylinder and the piston are thermally
insulated. The piston and the spring are
massless and there is no friction between
the piston and the cylinder. The final
temperature of the gas will be :

S U 8.031023 m2
U U SU mU U
U U 300 K U U
2.431023 m3 U U
o S
UU UU mU UU
SU U 0.1 m U
8000 N/m U
U 1.03105 N/m2
SU cU SU
U SU

(UU U U
U UU U cU ) :

(Neglect the heat loss through the lead


wires of the heater. The heat capacity of
the heater coil is also negligible)

(1)

300 K

(2)

800 K

(3)

500 K

(4)

1000 K

English : 9

Set : 11

(1)

300 K

(2)

800 K

(3)

500 K

(4)

1000 K

Hindi : 9

Set : 11

14.

oscillator is given by,

k
r2
v5 2
where k is the spring
4m 2
m

k
r2
v5 2
k
4m 2
m

constant, m is the mass of the oscillator and

m U r SU

r is the damping constant. If the ratio

The angular frequency of the damped 14.

(1)

increases by 1%

(1)

(2)

increases by 8%

(2)

(3)

decreases by 1%

(3)

(4)

decreases by 8%

(4)

Two factories are sounding their sirens 15.


at 800 Hz. A man goes from one factory
to other at a speed of 2 m/s. The velocity
of sound is 320 m/s. The number of beats
heard by the person in one second will

r2
is 8%, the change in time period
mk
compared to the undamped oscillator is
approximately as follows :

15.

r2
5 8%
mk

SU ,

1%

h
8% h
1% U
8% U

UU U 800 Hz U U
2 m/s UU
U
320 m/s U mU
S

be :
(1)

(1)

(2)

(2)

(3)

(3)

(4)

10

(4)

10

English : 10

Set : 11

Hindi : 10

Set : 11

16.

A cone of base radius R and height h is 16.

located in a uniform electric field E

parallel to its base. The electric flux

U R h U

U l E S
U l :

entering the cone is :


(1)

1
EhR
2

(1)

1
EhR
2

(2)

EhR

(2)

EhR

(3)

2EhR

(3)

2EhR

(4)

4EhR

(4)

4EhR

English : 11

Set : 11

Hindi : 11

Set : 11

17.

A parallel plate capacitor is made of two 17.


plates of length l, width w and separated
by distance d. A dielectric slab (dielectric
constant K) that fits exactly between the
plates is held near the edge of the plates.
It is pulled into the capacitor by a force

U
F5 2
where U is the energy of the
x
capacitor when dielectric is inside the
capacitor up to distance x (See figure). If
the charge on the capacitor is Q then the
force on the dielectric when it is near the
edge is :

U U U U
l, U w U U d U U
Ul ^ (Ul K) U
U , U U
U U U U

F5 2

(2)

(3)

(4)

Q2 d
2 wl 2 eo
Q2 w
2 dl 2 eo
Q2 d
2 wl 2 eo
Q2 w
2 dl 2 eo

English : 12

K
(2)

( K21)

(3)

( K21)

mU U U

Ul U U x U
U ( ) U U Q ,
Ul U , U ,

(1)
(1)

U
x

(4)

Q2 d
2 wl 2 eo
Q2 w
2 dl 2 eo
Q2 d
2 wl 2 eo
Q2 w
2 dl 2 eo

( K21)

( K21)

Set : 11

Hindi : 12

Set : 11

18.

In the circuit shown, current (in A) 18.


through the 50 V and 30 V batteries are,

U , 50 V
U (A )

30 V

UU

respectively :

19.

(1)

2.5 and 3

(2)

3.5 and 2

(3)

4.5 and 1

(4)

3 and 2.5

Three straight parallel current carrying 19.


conductors are shown in the figure. The
force experienced by the middle conductor

3
(2) 3.5 2
(3) 4.5 1
(4) 3 2.5
U U
25 cm mU
:
(1)

2.5

U
631024 N U
931024 N U
U

of length 25 cm is :

(1)

331024 N toward right

(1)

(2)

631024 N toward left

(2)

(3)

931024 N toward left

(3)

(4)

Zero

(4)

English : 13

Set : 11

331024 N

Hindi : 13

Set : 11

20.

Three identical bars A, B and C are made 20.


of different magnetic materials. When
kept in a uniform magnetic field, the field
lines around them look as follows :

M U A, B C
Z
U , U U
U

U Z (D),
(F) (P) U U U :

Make the correspondence of these bars


with their material being diamagnetic (D),
ferromagnetic (F) and paramagnetic (P) :

21.

(1)

A D, B P, C F

(1)

A D, B P, C F

(2)

A F, B D, C P

(2)

A F, B D, C P

(3)

A P, B F, C D

(3)

A P, B F, C D

(4)

A F, B P, C D

(4)

A F, B P, C D

0.01 s. The e.m.f. induced in the coil is :

U 4 cm2
S U U
U U
1022 Wb m22 0.01 s U U
U l

(1)

400 mV

(1)

400 mV

(2)

200 mV

(2)

200 mV

(3)

4 mV

(3)

4 mV

(4)

0.4 mV

(4)

0.4 mV

A coil of circular cross-section having 21.


1000 turns and 4 cm2 face area is placed
with its axis parallel to a magnetic field
which decreases by 10 22 Wb m 22 in

English : 14

Set : 11

1000

Hindi : 14

Set : 11

22.

An electromagnetic wave of frequency 22.


131014 hertz is propagating along z - axis.
The amplitude of electric field is 4 V/m. If
e o58.8310 212 C 2/N-m 2, then average

energy density of electric field will


be :

23.

131014 U l U
z - U U U U l
4 V/m
eo58.8310212 C2/N-m2, l
:

(1)

35.2310210 J/m3

(1)

35.2310210 J/m3

(2)

35.2310211 J/m3

(2)

35.2310211 J/m3

(3)

35.2310212 J/m3

(3)

35.2310212 J/m3

(4)

35.2310213 J/m3

(4)

35.2310213 J/m3

An object is located in a fixed position 23.


in front of a screen. Sharp image is
obtained on the screen for two positions
of a thin lens separated by 10 cm. The size
of the images in two situations are in the
ratio 3 : 2. What is the distance between

SU S S S
10 cm U U S
U ScU S
U 3 : 2 S
U ?

the screen and the object ?


(1)

124.5 cm

(1)

124.5 cm

(2)

144.5 cm

(2)

144.5 cm

(3)

65.0 cm

(3)

65.0 cm

(4)

99.0 cm

(4)

99.0 cm

English : 15

Set : 11

Hindi : 15

Set : 11

24.

Two monochromatic light beams of 24.


intensity 16 and 9 units are interfering.
The ratio of intensities of bright and dark
parts of the resultant pattern is :

25.

16 9
U U U
U S

(1)

16
9

(1)

16
9

(2)

4
3

(2)

4
3

(3)

7
1

(3)

7
1

(4)

49
1

(4)

49
1

of the compound microscope should be :


1.2 cm U
3.0 cm S
1.25 cm U U U ,
U

(1)

200

(1)

200

(2)

100

(2)

100

(3)

400

(3)

400

(4)

150

(4)

150

In a compound microscope the focal length 25.


of objective lens is 1.2 cm and focal length
of eye piece is 3.0 cm. When object is kept
at 1.25 cm in front of objective, final image
is formed at infinity. Magnifying power

English : 16

Set : 11

Hindi : 16

Set : 11

26.

A photon of wavelength l is scattered 26.


from an electron, which was at rest. The
wavelength shift Dl is three times of l and
the angle of scattering u is 608. The angle
at which the electron recoiled is f. The
value of tan f is : (electron speed is much

o S U U l
U U SU
Dl U l U
u5608 U f U
tan f (U
)

smaller than the speed of light)

27.

(1)

0.16

(1)

0.16

(2)

0.22

(2)

0.22

(3)

0.25

(3)

0.25

(4)

0.28

(4)

0.28

A radioactive nuclei with decay constant 27.

100 U SU U SU

0.5/s is being produced at a constant rate

0.5/s

of 100 nuclei/s. If at t50 there were no


nuclei, the time when there are 50 nuclei

UU U
t50 U S ,
50

is :
(1)

1s

(1)

1s

(2)

4
2 ln s
3

(2)

4
2 ln s
3

(3)

ln 2 s

(3)

ln 2 s

(4)

4
ln s
3

(4)

4
ln s
3

English : 17

Set : 11

Hindi : 17

Set : 11

28.

The currents I, IZ and IL are respectively

U UU UU U
U U
I, IZ IL

(1)

15 mA, 5 mA, 10 mA

(1)

15 mA, 5 mA, 10 mA

(2)

15 mA, 7.5 mA, 7.5 mA

(2)

15 mA, 7.5 mA, 7.5 mA

(3)

12.5 mA, 5 mA, 7.5 mA

(3)

12.5 mA, 5 mA, 7.5 mA

(4)

12.5 mA, 7.5 mA, 5 mA

(4)

12.5 mA, 7.5 mA, 5 mA

A Zener diode is connected to a battery 28.


and a load as shown below :

English : 18

Set : 11

Hindi : 18

Set : 11

29.

-I (l U h U)
-II (l SU )
U

Match the List - I (Phenomenon associated 29.


with electromagnetic radiation) with
List - II (Part of electromagnetic spectrum)
and select the correct code from the
choices given below the lists :
List - I
I Doublet of sodium

- I

List - II
A

Visible
radiation

Wavelength
corresponding to
II temperature associated
with the isotropic
radiation filling all space

B Microwave

Wavelength emitted by
III atomic hydrogen in
interstellar space

Short
C
radiowave

Wavelength of radiation
IV arising from two close
D X - rays
energy levels in hydrogen

- II

U m

II

cU
U UU h
UU

UU

III

UU U
UU mU
UU

UUU UU

IV

UU SU
U UU

D X - U

(1)

(I)-(A), (II)-(B), (III)-(B), (IV)-(C)

(1)

(I)-(A), (II)-(B), (III)-(B), (IV)-(C)

(2)

(I)-(A), (II)-(B), (III)-(C), (IV)-(C)

(2)

(I)-(A), (II)-(B), (III)-(C), (IV)-(C)

(3)

(I)-(D), (II)-(C), (III)-(A), (IV)-(B)

(3)

(I)-(D), (II)-(C), (III)-(A), (IV)-(B)

(4)

(I)-(B), (II)-(A), (III)-(D), (IV)-(A)

(4)

(I)-(B), (II)-(A), (III)-(D), (IV)-(A)

English : 19

Set : 11

Hindi : 19

Set : 11

30.

In the circuit diagrams (A, B, C and D) 30.


shown below, R is a high resistance and S
is a resistance of the order of galvanometer
resistance G.

The correct circuit,

corresponding to the half deflection

U (A, B, C D) , R
U U S U G
U U U
h-
U

method for finding the resistance and


figure of merit of the galvanometer, is the
circuit labelled as :
(A)

(A)

(B)
(B)

(C)

(C)

English : 20

Set : 11

Hindi : 20

Set : 11

(D)

(D)

(1)

RS
Circuit A with G5 (
R 2 S)

(2)

Circuit B with G5S

(3)

Circuit C with G5S

(4)

RS
Circuit D with G5
R2 S

English : 21

Set : 11

RS
R 2 S)

(1)

G5 (

(2)

G5S

U A

(3)

U B
G5S U C

(4)

G5

Hindi : 21

RS
R2 S

U D

Set : 11

PART B CHEMISTRY
31.

If lo and l be the threshold wavelength 31.


and wavelength of incident light, the
velocity of photoelectron ejected from the

B U
lo U l $ U U
U S
U

metal surface is :

32.

(1)

2h
( lo 2 l )
m

(1)

2h
( lo 2 l )
m

(2)

2hc
( lo 2 l )
m

(2)

2hc
( lo 2 l )
m

(3)

2 h c lo 2 l
m l lo

(3)

2 h c lo 2 l
m l lo

(4)

2h 1
1
2

m lo
l

(4)

2h 1
1
2

m lo
l

The appearance of colour in solid alkali 32.


metal halides is generally due to :
(1)

Schottky defect

(2)

Frenkel defect

(3)

Interstitial position

(4)

F-centres

English : 22

Set : 11

U U U U U

(1) U
(2) $
(3) U S
(4) F-

Hindi : 22

Set : 11

33.

In the reaction of formation of sulphur 33.


trioxide

by

contact

process

mU $U UU
2SO21O2 2SO3
d [O2 ]

2SO21O2 2SO3 the rate of reaction was

measured as

M U [SO2] M

d [O 2 ]
dt

dt

522.531024

L21 s21

L21 s21

522.531024mol L21 s21. The

rate of reaction in terms of [SO2] in mol


L21s21 will be :

34.

(1)

21.25310 24

(1)

21.25310 24

(2)

22.50310 24

(2)

22.50310 24

(3)

23.75310 24

(3)

23.75310 24

(4)

25.00310 24

(4)

25.00310 24

Assuming that the degree of hydrolysis is 34.


small, the pH of 0.1 M solution of sodium
acetate (Ka=1.031025) will be :
(1) 5.0

U (U)
, U U U 0.1M
(Ka=1.031025) pH
(1)

5.0

(2)

6.0

(2)

6.0

(3)

8.0

(3)

8.0

(4)

9.0

(4)

9.0

English : 23

Set : 11

Hindi : 23

Set : 11

35.

For the reaction, 2N2O5 4NO21O2, the 35.


rate equation can be expressed in two
ways 2
1

36.

d[N2O5 ]
dt

5 k [ N 2 O 5 ] and

2N2O5 4NO21O2, U
U U
2

d [ NO 2 ]
5 k9 [ N 2 O 5 ]
dt

d[N2O5 ]
dt

5 k [N2O5 ]

d [ NO 2 ]
5 k9 [ N 2 O 5 ]
dt

U k M ?

k and k are related as :

(1)

k5k

(1)

k5k

(2)

2k5k

(2)

2k5k

(3)

k52k

(3)

k52k

(4)

k54k

(4)

k54k

In some solutions, the concentration of


H3O1 remains constant even when small 36.
amounts of strong acid or strong base are
added to them. These solutions are known
as :

U U U
U H3O1 SU
U

(1)

Ideal solutions

(2)

Colloidal solutions

(1)

(3)

True solutions

(2)

(4)

Buffer solutions

(3)
(4)

English : 24

Set : 11


U
S
U (Buffer)

Hindi : 24

Set : 11

37.

37.

Given
Fe31(aq)1 e2Fe21(aq); E8=10.77 V
A l 3 1 ( a q ) 1 3 e2 A l ( s ) ; E 8 = 2 1 . 6 6 V
Br2(aq)12 e22B r2 ; E8=11.09 V

Considering the electrode potentials,


which of the following represents the
correct order of reducing power ?

38.

(1)

Fe21< Al < B r2

(2)

B r2 < Fe21< Al

(3)

Al < B r2 < Fe21

(4)

Al < Fe21< B r2

38.

The initial volume of a gas cylinder is


750.0 mL. If the pressure of gas inside the

Fe31()1 e2Fe21(); E8 =10.77 V


Al31()13 e2Al(s); E8 = 21.66 V
2
Br2()12 e 2B r2 ; E8 = 11.09 V
UU U U
S U ?
(1)

Fe21< Al < B r2

(2)

B r2 < Fe21< Al

(3)

Al < B r2 < Fe21

(4)

Al < Fe21< B r2

U U U
750.0 mL UU
840.0 mm Hg U 360.0 mm Hg

cylinder changes from 840.0 mm Hg to


360.0 mm Hg, the final volume the gas will

(1)

1.750 L

be :

(2)

3.60 L

(1)

1.750 L

(3)

4.032 L

(2)

3.60 L

(4)

7.50 L

(3)

4.032 L

(4)

7.50 L

English : 25

Set : 11

Hindi : 25

Set : 11

39.

The molar heat capacity (Cp) of CD2O is 39.


10 cals at 1000 K. The change in entropy
associated with cooling of 32 g of CD2O
vapour from 1000 K to 100 K at constant
pressure will be :
(D = deuterium, at. mass = 2 u)

40.

U c U (Cp) 1000 K U
10 cals 32 g CD2O c 1000 K
100 K SU U UU U U h
U U
(D = UUU, U U
= 2 )
CD2O

(1)

23.03 cal deg21

(1)

23.03 cal deg21

(2)

223.03 cal deg21

(2)

223.03 cal deg21

(3)

2.303 cal deg21

(3)

2.303 cal deg21

(4)

22.303 cal deg21

(4)

22.303 cal deg21

Based on the equation :

(523 218 -

40.

1
1
2 2
2
n
n 1
2

U
(523 218 -

the wavelength of the light that must be


absorbed to excite hydrogen electron from
level n=1 to level n=2 will be :
(h = 6.625310234 Js, C= 33108 ms21)

1
1
2 2
2
n
n 1
2

U U U U SU n=1
SU n=2 U ,
, U

(h = 6.625310234 Js, C = 33108 ms21)

(1)

1.325310 27 m

(1)

1.325310 27 m

(2)

1.325310210 m

(2)

1.325310210 m

(3)

2.650310 27 m

(3)

2.650310 27 m

(4)

5.300310210 m

(4)

5.300310210 m

English : 26

Set : 11

Hindi : 26

Set : 11

41.

Which of the following series correctly 41.


represents relations between the elements

U$ X U Y
M U ?

from X to Y ?
X Y
(1)
(2)

3Li
9F

X Y

19K Ionization

(3)

9F 35Br U

6C 32Ge U

(4)

18Ar 54Xe

enthalpy

(1)

35Br Electron gain enthalpy


with negative sign

(2)

increases

increases

42.

(3)

6C

(4)

18Ar 54Xe Noble character increases

32Ge Atomic radii increases

3Li

19K

C S
2

The correct order of bond dissociation 42.

S N2, O2,

is shown in
energy among N2, O2, O2
2
which of the following arrangements ?

(1)

> O2
N2 > O2
2

(1)

N2 > O2
> O2
2

(2)

2
O 2 > O2 > N2

(2)

2
O 2 > O2 > N2

(3)

N2 > O2 > O2
2

(3)

N2 > O2 > O2
2

(4)

O2 > O2
> N2
2

(4)

O2 > O2
> N2
2

English : 27

Set : 11

Hindi : 27

O2

Set : 11

43.

Which of the following statements about 43.


Na2O2 is not correct ?

44.

(1)

It is diamagnetic in nature.

(2)

It is a derivative of H2O2.

(3)

Na2O2 oxidises Cr31 to CrO422 in


acid medium.

(4)

It is the super oxide of sodium.

Which of the following statements about 44.


the depletion of ozone layer is correct ?
(1)

The problem of ozone depletion is less


serious at poles because NO 2
solidifies and is not available for
consuming ClO radicals.

(2)

The problem of ozone depletion is


more serious at poles because ice
crystals in the clouds over poles act
as catalyst for photochemical
reactions

involving

decomposition of ozone by

the
Cl

Na2O2


?
(1)
(2) H2O2
(3) Na 2O 2 Cr 31
CrO422
(4) U U- U
SU U
?
(1) $ U S
U NO2 U U
U ClO U

(2)

$ U S
U U
SU Cl U ClO
UU mU U $
-U

and

ClO radicals.
(3)

Freons, chlorofluorocarbons, are

(3)

inert chemically, they do not react


with ozone in stratosphere.
(4)

Oxides of nitrogen also do not react


with ozone in stratosphere.

English : 28

Set : 11

(4)

(UU ) U M
U U
S $ U
U U $ UU
U U

Hindi : 28

Set : 11

45.

A gaseous compound of nitrogen and 45.


hydrogen contains 12.5%(by mass) of
hydrogen. The density of the compound
relative to hydrogen is 16. The molecular

U U U
12.5% U U U
16

formula of the compound is :

46.

(1)

NH2

(1)

NH2

(2)

N3H

(2)

N3H

(3)

NH3

(3)

NH3

(4)

N2H4

(4)

N2H4

Shapes of certain interhalogen compounds 46.


are stated below. Which one of them is

U U
?

not correctly stated ?

47.

(1)

IF7 : pentagonal bipyramid

(1)

(2)

BrF5 : trigonal bipyramid

(2)

(3)

BrF3 : planar T-shaped

(3)

(4)

ICl3 : planar dimeric

(4)

Consider the following equilibrium


1

47.

mUU
BrF5 : mUU
BrF3 : T-U
ICl3 : UU ( S)
IF7 :

AgCl 12NH3 Ag ( NH 3 )2 1 Cl2

AgCl 12NH3 Ag ( NH 3 )2 1 Cl2

White precipitate of AgCl appears on


adding which of the following ?

U U AgCl
?

(1)

NH3

(1)

(2)

aqueous NaCl

(2)

(3)

aqueous HNO3

(3)

(4)

aqueous NH4Cl

(4)

English : 29

Set : 11

NH3

NaCl
HNO3
NH4Cl

Hindi : 29

Set : 11

48.

Which of the following name formula 48.

- ?

combinations is not correct ?


Formula

49.

Name

(1) K2[Pt(CN)4]

Potassium
tetracyanoplatinate (II)

(1) K2[Pt(CN)4]

U UU UU (II)

(2) [Mn(CN)5]22

Pentacyanomagnate (II) ion

(2) [Mn(CN)5]22

U U(II)

(3) K[Cr(NH3)2Cl4]

Potassium diammine
tetrachlorochromate (III)

(3) K[Cr(NH3)2Cl4]

U
UUUUU(III)

(4) [Co(NH3)4(H2O)I]SO4

Tetraammine aquaiodo
cobalt (III) sulphate

(4) [Co(NH3)4(H2O)I]SO4

UU UU
(III) $$U

Consider the coordination compound, 49.


[Co(NH3)6]Cl3. In the formation of this
complex, the species which acts as the
Lewis acid is :

50.

[Co(NH3)6]Cl3
UU U
(Lewis acid) ,

(1)

[Co(NH3)6]31

(1)

(2)

Cl2

[Co(NH3)6]31

(2)

Cl2

(3)

Co31

(3)

Co31

(4)

NH3

(4)

NH3

Which one of the following does not have 50.


a pyramidal shape ?

M UU ?

(1)

(CH3)3 N

(1)

(2)

(SiH3)3 N

(CH3)3 N

(2)

(3)

P(CH3)3

(SiH3)3 N

(3)

(4)

P(SiH3)3

P(CH3)3

(4)

P(SiH3)3

English : 30

Set : 11

Hindi : 30

Set : 11

51.

51.

The following reaction

?
(1) U
(2) UU - $U
(3)
(4) UU

is known as :

52.

53.

(1)

Perkin reaction

(2)

Gattermann-Koch Formylation

(3)

Kolbes reaction

(4)

Gattermann reaction

The reagent needed for converting 52.

is :

U
(1) U. U
(2) H2/UU U.

(1)

Cat. Hydrogenation

(2)

H2/Lindlar Cat.

(3)

Li/NH3

(4)

LiAlH4

Complete reduction of benzene-diazonium 53.


chloride with Zn/HCl gives :
(1)

Aniline

(2)

Phenylhydrazine

(3)

Azobenzene

(4)

Hydrazobenzene

English : 31

Set : 11

(3)

Li/NH3

(4)

LiAlH4

mU $ U$ UU
U
(1)
(2) $U$
(3) $$
(4) U$$
Zn/HCl

Hindi : 31

Set : 11

54.

55.

described below :

U A, C5H8O; U
H2O, NH3 U CH3COOH U

A is :

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

An organic compound A, C5H8O; reacts 54.


with H 2 O, NH 3 and CH 3 COOH as

In

allene

(C 3 H 4 ),

the

type(s)

of 55.

hybridization of the carbon atoms is (are):


(1)

sp and sp3

(2)

sp2 and sp

(3)

only sp2

(4)

sp2 and sp3

English : 32

Set : 11

() U (U)
U
(1) sp U sp3
(2) sp2 U sp
(3) sp2
(4) sp2 U sp3
C3H4

Hindi : 32

Set : 11

56.

57.

acetaldehyde in the presence of H2SO4

S U $
UUU UU

The major product formed is :

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

Chlorobenzne reacts with trichloro 56.

Tischenko reaction is a modification of :


(1)

Aldol condensation

(2)

Claisen condensation

(3)

Cannizzaro reaction

(4)

Pinacol-pinacolon reaction

English : 33

Set : 11

57.

H 2 SO 4

U M
(1) U
(2) $
(3) $U
(4) -

Hindi : 33

Set : 11

58.

Which one of the following is used as 58.


Antihistamine ?

59.

(1)

Omeprazole

(2)

Chloranphenicol

(3)

Diphenhydramine

(4)

Norethindrone

Which one of the following statements is 59.

U SU M
U ?
(1) $
(2) U $
(3) UU
(4) UU
?

not correct ?
(1)

(1)

(2)

in the following order

U
-

RCH2OH > R2CHOH > R3COH


Carbon-oxygen bond length in

RCH2OH > R2CHOH > R3COH


, CH3OH -

Alcohols are weaker acids than


water

(2)

(3)

Acid strength of alcohols decreases

(3)

methanol, CH3OH is shorter than


that of C2O bond length in phenol.
(4)

The bond angle

in methanol

(4)

The gas liberated by the electrolysis of 60.


Dipotassium succinate solution is :
(1)

Ethane

(2)

Ethyne

(3)

Ethene

(4)

Propene

English : 34

108.98

is 108.98
60.

$ C2O
UU

Set : 11

UU U l

(1)
(2)
(3)
(4)

Hindi : 34

Set : 11

PART C MATHEMATICS
61.

Let f be an odd function defined on the set 61.


of real numbers such that for x/0,
f(x)53 sin x14 cos x.
Then f(x) at x 5 2

62.

(1)

3
12 3
2

(2)

(3)

3
22 3
2

(4)

11p
is equal to :
6

f(x) UU

3
12 3
2

3
22 3
2

If z1, z2 and z3, z4 are 2 pairs of complex


62.
conjugate numbers, then

z
z
arg 1 1 arg 2 equals :
z4
z3
(1)

(2)

p
2

(3)

3p
2

(4)

English : 35

C
f S
U f(x)53 sin x14 cos x mU
x/0

x5 2

(1)

3
12 3
2

(2)

(3)

3
22 3
2

(4)

11p
6

3
12 3
2

3
22 3
2

z1, z2 z3, z4 o
, z
z
arg 1 1 arg 2
z4
z3

Set : 11

(1)

(2)

p
2

(3)

3p
2

(4)

Hindi : 35

UU

Set : 11

63.

64.

x 2 2 4 2 kx 1 2e 4 ln k2 1 5 0 for some k,
and a21b2 5 66, then a31b3 is equal to :

, U
x 2 4 2 kx 1 2e
2 1 5 0
2
2
3
a 1b 5 66, , a 1b3 UU

(1)

248 2

(1)

248 2

(2)

280 2

(2)

280 2

(3)

232 2

(3)

232 2

(4)

2280 2

(4)

2280 2

If a and b are roots of the equation, 63.

64.

Let A be a 333 matrix such that

1 2 3
A 0 2 3 5
0 1 1

(2)

3 2 1
3 2 0

1 1 0

(3)

0 1 3
0 2 3

1 1 1

(4)

1 2 3
0 1 1

0 2 3

English : 36

Set : 11

4 ln k

A 333

A21

Then A21 is :
(1)

1 2 3
A 0 2 3 5
0 1 1

0 0 1
1 0 0

0 1 0

3 1 2
3 0 2

1 0 1

0 0 1
1 0 0

,
0 1 0

(1)

3 1 2
3 0 2

1 0 1

(2)

3 2 1
3 2 0

1 1 0

(3)

0 1 3
0 2 3

1 1 1

(4)

1 2 3
0 1 1

0 2 3

Hindi : 36

Set : 11

65.

Let for i51, 2, 3, pi(x) be a polynomial of 65.


degree 2 in x, pi(x) and pi(x) be the first
and second order derivatives of p i (x)
respectively. Let,

i51, 2, 3, pi(x), x 2
, pi(x) pi(x) U
m U

p1 ( x ) p19 ( x ) p10 ( x )
A( x ) 5 p2 ( x ) p29 ( x ) p20 ( x )
p3 ( x ) p39 ( x ) p30 ( x )

p1 ( x ) p19 ( x ) p10 ( x )
A( x ) 5 p2 ( x ) p29 ( x ) p20 ( x )
p3 ( x ) p39 ( x ) p30 ( x )

and B(x) = [A(x)]T A(x). Then determinant

B(x) = [A(x)] T A(x) , B(x)


U
(1) x 6
(2) x 3
(3) x 2
(4) x U U U
0 9 , U
, 9 , U
U ,

of B(x) :

66.

(1)

is a polynomial of degree 6 in x.

(2)

is a polynomial of degree 3 in x.

(3)

is a polynomial of degree 2 in x.

(4)

does not depend on x.

An eight digit number divisible by 9 is to 66.


be formed using digits from 0 to 9 without
repeating the digits. The number of ways
in which this can be done is :
(1)

72 (7!)

(1)

72 (7!)

(2)

18 (7!)

(2)

18 (7!)

(3)

40 (7!)

(3)

40 (7!)

(4)

36 (7!)

(4)

36 (7!)

English : 37

Set : 11

Hindi : 37

Set : 11

67.

The coefficient of x 50 in the binomial 67.

(11x) 1000 1 x(11x) 999 1x 2 (11x) 998 1

expansion of

......1x1000

(11x) 1000 1 x(11x) 999 1x 2 (11x) 998 1

m U x50

......1x1000 is :

68.

(1)

(1000) !
(50) ! (950) !

(1)

(1000) !
(50) ! (950) !

(2)

(1000) !
(49) ! (951) !

(2)

(1000) !
(49) ! (951) !

(3)

(1001) !
(51) ! (950) !

(3)

(1001) !
(51) ! (950) !

(4)

(1001) !
(50) ! (951) !

(4)

(1001) !
(50) ! (951) !

In a geometric progression, if the ratio of 68.


the sum of first 5 terms to the sum of their
reciprocals is 49, and the sum of the first
and the third term is 35. Then the first term

U o 5
49
U U 35 , U
o

of this geometric progression is :


(1)

(1)

(2)

21

(2)

21

(3)

28

(3)

28

(4)

42

(4)

42

English : 38

Set : 11

Hindi : 38

Set : 11

69.

70.

The sum of the first 20 terms common 69.

oU

between the series 3171111151..... and

1161111161..... ,

1161111161..... , is :

20

(1)

4000

(1)

4000

(2)

4020

(2)

4020

(3)

4200

(3)

4200

(4)

4220

(4)

4220

If
lim

70.
tan ( x 2 2 ){x 2 1 (k22)x 2 2k}
x 2 2 4x 1 4

x 2

71.

55 ,

lim

tan ( x 2 2 ){x 2 1 (k22)x 2 2k}


x 2 2 4x 1 4

x 2

then k is equal to :

k UU

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

Let f(x)5x?x?, g(x) = sin x and

71.

f(x)5x?x?,

h(x) 5(gof ) (x) ,

(1)

h(x) is not differentiable at x50.

(1)

(2)

h(x) is differentiable at x50, but

(2)

(3)

is not continuous at x50.

h(x) is continuous at x50 but it is

(3)

not differentiable at x50.


(4)

h(x) is differentiable at x50.

English : 39

Set : 11

(4)

55

h(x) 5(gof )(x). Then

h(x)

U
cU

3171111151.....

g(x)

sin

h(x), x50 U
h(x), x50 U U h(x),
x50 U
h(x), x50 U , U x50 U

h(x), x50 U

Hindi : 39

Set : 11

72.

For the curve y = 3 sin u cos u, x5eu sin u, 72.


0 [ u [ p, the tangent is parallel to x-axis
when u is :

73.

(1)

3p

(2)

(3)

(4)

y = 3 sin u cos u, x5e u sin u,

0 [ u [ p,

SU x- U ,
u UU
(1)

3p

(2)

(3)

(4)

Two ships A and B are sailing straight 73.


away from a fixed point O along routes
such that AOB is always 1208. At a
certain instance, OA = 8 km, OB = 6 km
and the ship A is sailing at the rate of
20 km/hr while the ship B sailing at the
rate of 30 km/hr. Then the distance

4
6

$ A B, O U
Z U U U AOB 1208
U , OA = 8
OB = 6 $ A, 20 /U
U $ B, 30 /U
U , A B U
U (/U ) U ,

between A and B is changing at the rate


(in km/hr) :
(1)

260

(2)

260 37

(3)

80

(4)

80 37

English : 40

37

37

Set : 11

(1)

260

(2)

260 37

(3)

80

(4)

80 37

Hindi : 40

37

37

Set : 11

74.

The volume of the largest possible right 74.


circular cylinder that can be inscribed in a

3 ,

sphere of radius5 3 is :

75.

(1)

4
3 p
3

(1)

4
3 p
3

(2)

8
3 p
3

(2)

8
3 p
3

(3)

4p

(3)

4p

(4)

2p

(4)

2p

The integral

2
21 1 2 x
x
cos

dx (x > 0) 75.

1 1 x2

dx , (x > 0) UU

is equal to :
(1)

2 x1(11x2) tan21 x1c

(1)

2 x1(11x2) tan21 x1c

(2)

x2 (11x2) cot21 x1c

(2)

x2 (11x2) cot21 x1c

(3)

2 x1(11x2) cot21 x1c

(3)

2 x1(11x2) cot21 x1c

(4)

x2 (11x2) tan21 x1c

(4)

x2 (11x2) tan21 x1c

76.

x cos21 1 2 x 2
11x

n
If for n/1, Pn 5 (log x ) d x , then 76.

P10290P8 is equal to :

P10290P8 UU

(1)

29

(1)

29

(2)

10e

(2)

10e

(3)

29e

(3)

29e

(4)

10

(4)

10

n/1

English : 41

Set : 11

Pn 5 (log x )n d x

Hindi : 41

Set : 11

77.

If the general solution of the differential 77.


equation

y9 5

function

F,

x
y
1 F ,
x
y
is

for

some

given

by


y9 5

x
y
1 F ,
x
y

y ln ?cx?5x,

mU , c SU U ,
UU

y ln ?cx?5x, where c is an arbitrary

F(2)

constant, then F (2) is equal to :

78.

(1)

(1)

(2)

1
4

(2)

1
4

(3)

24

(3)

24

(4)

(4)

1
4

A stair-case of length l rests against a 78.


vertical wall and a floor of a room,. Let P
be a point on the stair-case, nearer to its
end on the wall, that divides its length in
the ratio 1 : 2. If the stair-case begins to
slide on the floor, then the locus of P is :
(1)

an ellipse of eccentricity

(2)

an ellipse of eccentricity

(3)

a circle of radius

(4)

a circle of radius

English : 42

1
2
3
2

l
2

3
l
2

Set : 11

1
4

l U U U
U
P, U U
U , U
1 : 2 U U
U , P
1

(1)

(2)

(3)

(4)

3
l
2

Hindi : 42

Set : 11

79.

The base of an equilateral triangle is along 79.


the line given by 3x14y = 9. If a vertex of
the triangle is (1, 2), then the length of a

U U 3x14y = 9
(1, 2)

side of the triangle is :

80.

(1)

2 3
15

(1)

2 3
15

(2)

4 3
15

(2)

4 3
15

(3)

4 3
5

(3)

4 3
5

(4)

2 3
5

(4)

2 3
5

The set of all real values of l for which 80.


exactly two common tangents can be
drawn to the circles
x21y224x24y1650 and
x21y2210x210y1l50 is the interval :
(1)

(12, 32)

(2)

(18, 42)

(3)

(12, 24)

(4)

(18, 48)

English : 43

Set : 11

S ,
x21y224x24y1650
x 2 1y 2 210x210y1l50 U U
cU SU ,
U ,
(1)

(12, 32)

(2)

(18, 42)

(3)

(12, 24)

(4)

(18, 48)

Hindi : 43

Set : 11

81.

Let L1 be the length of the common chord 81.

of the curves x21y259 and y258x, and

L2 be the length of the latus rectum of


y258x, then :

82.

L1, x21y259 y258x,


cU , L2, y258x
,

(1)

L1 > L 2

(1)

L1 > L2

(2)

L15L2

(2)

L15L2

(3)

L1 < L 2

(3)

L1 < L2

(4)

L1
5 2
L2

(4)

L1
5 2
L2

Let P (3 sec u, 2 tan u) and


p
, be
2
two distinct points on the hyperbola

Q (3 sec f, 2 tan f) where u 1 f 5

y
x
2
5 1 . Then the ordinate of the
9
4
point of intersection of the normals at P

82.

y2
x2
2
5 1 U
9
4

P (3 sec u, 2 tan u) Q (3 sec f, 2 tan f)

u1f 5

p
2

, P Q U

U U

(ordinate)

and Q is :
(1)

11
3

(2)

(3)

13
2

(4)

English : 44

11
3

13
2

Set : 11

(1)

11
3

(2)

(3)

13
2

(4)

Hindi : 44

11
3

13
2

Set : 11

83.

A (2, 3, 5), B (21, 3, 2)

the coordinate axes, then :

C (l, 5, m) ABC A
U , U
,

(1)

5l28m50

(1)

5l28m50

(2)

8l25m50

(2)

8l25m50

(3)

10l27m50

(3)

10l27m50

(4)

7l210m50

(4)

7l210m50

y 22
x 21
z 23
5
5
1
2
3

Let A (2, 3, 5), B (21, 3, 2) and 83.


C (l, 5, m) be the vertices of a DABC. If the
median through A is equally inclined to

84.

The

plane

containing

the

line

y 22
x 21
z 23
and parallel to
5
5
1
2
3

85.

84.

U U

y
x
z
5 5
1
1
4

U ,

y
x
z
5 5 passes through the
the line
1
1
4
point :

U ,

(1)

(1,22, 5)

(1)

(1,22, 5)

(2)

(1, 0, 5)

(2)

(1, 0, 5)

(3)

(0, 3,25)

(3)

(0, 3,25)

(4)

(21,23, 0)

(4)

(21,23, 0)

2
If ? c ? 5 60 and

c 3( i12 j15 k )50

, 85.

? c ?2 5 60

then a value of c . (2 7 i 1 2 j 1 3 k ) is :

(1)

4 2

(1)

4 2

(2)

12

(2)

12

(3)

24

(3)

24

(4)

12 2

(4)

12 2

English : 45

Set : 11

c 3( i12 j15 k )50 ,

c . (2 7 i 1 2 j 1 3 k )

Hindi : 45

c U

Set : 11

86.

A set S contains 7 elements. A non-empty 86.


subset A of S and an element x of S are
chosen at random. Then the probability

S 7 S U
A S x , U
, xA

that xA is :

87.

(1)

1
2

(1)

1
2

(2)

64
127

(2)

64
127

(3)

63
128

(3)

63
128

(4)

31
128

(4)

31
128

If X has a binomial distribution, B(n, p) 87.


with parameters n and p such that
P(X52)5P(X53), then E(X), the mean of

X m U, B(n, p) ,
n, p , U P(X52)5P(X53)
, U X E(X)

variable X, is :
(1)

22p

(1)

22p

(2)

32p

(2)

32p

(3)
(4)

p
p

(3)

(4)

English : 46

Set : 11

p
p

Hindi : 46

2
3

Set : 11

88.

If 2 cos u1sin u51 u 2 ,

88.

(1)

1
2

(1)

1
2

(2)

(2)

(3)

11
2

(3)

11
2

(4)

46
5

(4)

46
5

The angle of elevation of the top of a 89.


vertical tower from a point P on the
horizontal ground was observed to be a.
After moving a distance 2 metres from P

2 cos u1sin u51 u 2

7 cos u16 sin u UU

then 7 cos u16 sin u is equal to :

89.

U P U U
U a P U
U 2 . U,
U b , (.) U

towards the foot of the tower, the angle of


elevation changes to b. Then the height (in
metres) of the tower is :
(1)

2 sin a sin b
sin (b2a )

(1)

2 sin a sin b
sin (b2a )

(2)

sin a sin b
cos (b2a )

(2)

sin a sin b
cos (b2a )

(3)

2 sin (b2a )
sin a sin b

(3)

2 sin (b2a )
sin a sin b

(4)

cos (b2a )
sin a sin b

(4)

cos (b2a )
sin a sin b

English : 47

Set : 11

Hindi : 47

Set : 11

90.

is logically equivalent to :

~(p~q)~(pq) M
,

(1)

(1)

(2)

(2)

(3)

~p
~q

(3)

~p
~q

The

(4)

proposition

~ (p ~ q) ~ (pq)

90.

(4)
-o0o-

English : 48

-o0o-

Set : 11

Hindi : 48

Set : 11

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