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RNul,No, F,,,ff=l,N Ei
generally expand when heat is absorbed; and contract
en
Gases
and solids.
Different
or contraction of solids, liquids and gases incrudes the ti n j; y t9",so.i"s ;l;;;. ;;;';,.: ffi L:' :i",.'l'J; H:?_,f Li l: at "h" witt that is heated its merting ..rv "r-,\-,!,fL pornt vyrrr s.r\F,qrrLJ expand orrLr uguomgs a llqul o While this is generally true, there is an important ""u-0""o--lr-Jli""ra. exception for water. Water actually expands when it coors from 4 .c io 0 .c. This'lnrrr"r property of water explains why ice floats on water instead of sinking to the bottom. e effects of thermal, expansion v/\l.',qrrorLrtt qttLr and uullLlatul.lon contraction arg are lls listed sreq petow: below: Railway tracks are bent due to the thermal expansion o of the steel rails on a very hot day
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To
calculations need to be made to determine wr,at tlre maiimum possible that it will not pose a danger. I Land and sea breezes r During the night, the sea is hotter than the land. Hence the air above the sea rises. The cool air from the land comes in and replaces the hot air that rises from the sea. This movement of air is known breeze. o During the day, the land is hotter than ""-lrna the sea. Hence the air above the land rises' The cool air from the sea comes in and replaces the hot air that rises from the tand. This movement of air is known ;;; breeze. ln addition, the effects of thermal expansion ";; and contraction can be used to our advantage in our daily lives.
sag is, such
A hot rivet is inserted through hores in two metar prates. The open end of the rivet is hammered to form a new rivet head. wh"n the hot rivet coors down, it contracts and hords the two metar prates together. 0 Fixing an axle to a wheel o The axle of a wheel is cooled such that it contracts and become smaller. lt is then fitted into the wheel. when it is warmed, it expands and fits tightly with the wheel. t Thermometer o The expansion and contraction of mercury in a mercury-in-glass thermometer is commonly used for measuring temperature. > The thermometer is praced in contact with the object to be measured. The temperature wiil then be indicated on a scare that depends on the length of the mercury, which in turn depends on the expansion or contraction of the mercury.
Riveting
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.
Thermostat
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A thermostat can be made from brass and iron joined together two different pieces of metars, such as lengthwise. This is known strip. ,l , bimetallic
t,
':n?: ks n p p icatio n of th rm t i=t:n ^"_!rj,!yr!,t11 expansion.,, jil;.j ;;;::":,:::' :"' ::f :: *-:;:,":-:1:l':^ {r an application of An appliiatiion of thermal ":o'r': lhe_rm"l.
c
is. a a
t
expansion needs to be
us
sotids and
tiquids
Gases are actuaty poorer conductors_of liquids' The reason *t,v g"r;"-Jr;nd heat as compared to sorids and
li:gT:$"1"r"r^":::_:i:-f,3.;;ve those or sorids riq,iJ". ##;?"":l,l'#:ff:.ntffi:,Tsil:lJ rapidly away from "nothe source Jt-tif i"",, causing it to expand.
il;
-To ttct or
"
open a ilghtty scywed iam jar with a mebr rid, we can either coot the stass jar._ o.in heat the iZti.,js witt be just as easv.,, than coorinb the qtass iar T b e ca u s e m eta s ffii,*r"tl"*r:.::g,ytiiT'.:^"Iv"[" rj;$ "".i", s e n e ra v e' p- ; ;i not to touch the hot metal il:"ff . Jl'i i;"i"'?il.:x'.i f iO *iif, Voui O"r" handsl
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n A: Multiple-choice Ouestions
I question, four suggested answers are given. Choose the most appropriate and write its letter in the brackets prorided.
objects expand, expand,
the same
contract
".rr*
wh":t"Tff::,
D
expand contract, contract
when cooled.
m temperatu re),
A
amount of heat is supplied to the following objects (which are all at which of it will expand the least?
lron
Oxygen
B D
the temperature of an object measured by a mercury thermometer? ABv observing the length of the mercury in the thermometer BBv observing the time the mercury takls to traver in the thermometer cBv observing the colour change in the thermometer DBv observing the pressure exerted by the mercury (
,How is
diagram below shows a liquid at room temperature in a round-bottomed Which of the following actions will result in the water level in the tube falling ?
e
sk.
Tube
Round-bottomed flask
A
B
c
D
Holding the flask in your hands Moving the setup into a refrigerator
of hot water
ErrEcrs
5.
Which of the foilowing is not an apprication of the effects of heat? A Riveting B Fixing the axle of a wheel lVleasuring temperature with a thermometer 9 D The bending of 'rails due to thermat expansion Thermostats work by.
6.
I B C D
7.
using a bimetallic strip measuring the temperature breaking the circuit when the temperature is too hot or cold expanding when it is hot and contracting when it is cold
1l
Where are bimetallic strips found? (l) Fire alarms (lt1 Air conditioners (lll) Convectional ovens (lV1 lndicator lights in a car A
B
c
D
I and lV only ll and lll only l,lll and lV only All of the above
8.
The diagram below shows an inverted flask containing air. A tube is placed the flask and,then placed in a beaker of water as shown.
lnverted flask
Tu
be
Beaker
what will be observed if ice is placed in contact with the bottom of the flask? A Nothing wiil be observed. B The water level in the tube will drop. C The water level in the tube will rise. D Bubbles will be formed in the water.
Given
that Metal A expands more than Metal B, which of the following circuit
Metal
Contact
Contact
Contact
A B C D
the contraction of the plastic bottle the expansion of the plastic bottle the contraction of water upon freezing the expansion of water upon freezing
A
B
Volume lncreases
Decreases
c
D
lncreases
Decreases
[,, A l
t
B C D
The axle is first heated and inserted into the hub of the wheel. The axle is first cooled and then inserted into the hub of the wheel. The axle and wheel are heated and then inserted into each other' The axle and wheel are cooled and then inserted into each other'
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13. The following shows the length of four different metals before and after
Metal A Metal
heating,
Original length
H e a te
ffi
tl:l:l:l=-=-:l:r:l:l:l:l=-:--:l:l:j:l:l:li:lJ
Original lensth
Heated length
ffi Metal
D
engt
Metal
ungrnar rengtn
Heated
Original length
Heated length
W
:
A C
Metal A Metal C
B D
Metal Metal
LiquidX LiquidY
LiquadZ
A B C D
LiquidY expanded more than Liquid X but less than Liquid Z. All of the liquids expanded. Liquid Z is actually Liquid X. They all expanded by the same amount.
nF H Eer
during the night because of the air blowing from the sea during the day because of the air blowing irom land because the land is warmer than the sea in the day because the sea is warmer than the land in the night
0bject Z has a melting point
the
rA
B
c
D
of 200 oc and a boiling point of 250 following situations does ObjectZ have the gr"-rt"st density? Object Z at 249 oC Object Z at S0 'C Object Z at 300 "C Object Z at 180 "C
ln which of
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Section B: Short-answer
1.
Ouestions
Metal X
(a)
(bl
(cl
lf the bimetallic strip is cooled, draw in the space below what you will expect to see.
(dl
Errecrs
Explain the
(al
(b)
Telephone lines are installed with some slack instead of being taut.
(cl
A test tube that has just been heated cracks when placed under cold water.
(a) What
(b) A mercury thermometer has its markings worn off after many years of use.
When it is placed in ice, its length is 3 cm long. When it is placed in steam, the length is 15 cm long. lf it is placed in a liquid and the length is 9 cm, what is the temperature of the liquid?
(cl
(d)
Mercury is poisonous and can be lethal if ingested. Given this fact, why solids not used in place of mercu rY?
are
4.
Round-bottomed flask
(al
When the flask is heated directly with a Bunsen burner, the water level the tube drops initially. Why?
in
(bl
(cl
What can be done such that the water level in the tube drops less initial
(d)
The liquid in the round-bottomed flask is replaced with a gas. The liquid the tube remains. What will happen now if the flask is heated with a Bu
burn er? Explain.
t).
rf,F H Eer
t
il
ion G:
la)
Free-response
I Structured
Ouestions
your answers
(b)
Based on your answer in (a), explain why liquids are commonly used in thermometers as opposed to solids.
(cl
2. (al
Ib)
Errecrs EF Hear
3.
Describe an experiment to measure the amount of expansion of a gas when it is heated. Explain how you would use the results and experiment setup to measure temperature. lnclude a diagram of your experiment setup. (Hint:You do not need to measure the volume of the gas directly.)
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KEY
0
LEARNINtri FtrIINTS
form of energy.
Heat is a
Conduction The transmission of heat through a material from a region of higher temperature to a region of lower temperature without any visible movement of the material. > A material that allows heat to flow through it quickly is known as a good conductor of heat; whereas a material that does not allow heat to flow through it quickly is known as an insulator of heat. e Convection > The transmission of heat through a fluid from a region of higher temperature to a region of lower temperature by the movement of the fluid itself. r Radiation > The transmission of heat through space from a body that emits heat and does not require any medium. lt can be transmitted through a vacuum. > This is done in the form of infra-red radiation (a type of electromagnetic radiation). > Shiny, silvery and smooth surfaces are poor emitters and absorbers'of heat. > Dull, black and rough surfaces are best emitters and absorbers of heat. Conduction, convection and radiation can be used to explain phenomenon and everyday applications such as: I The formation of sea or land breezes. 0 The use of insulators, such as plastics and wood for handles of cooking utensils; while metals are used for the base of them as they are good conductors of heat. 0 Vacuum flasks have a shiny, silvery and smooth surface.
lt moves from a region of higher temperature to a region of lower temperatu re. There are three ways by which heat can be transmitted:
>
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"Conduction only happens in solids.', Conduction occurs in liquids. However, the effects of convection are much ' greater than that of conduction in liquids. ln gases, however, conduction is usually neglected because the partictes of tnJ gases are far aparu hence they collide and transfer their energy less often thai that in solids and liquids.
"
lf
th-ere are
one."
two obiects, onty the hotter one will radiate heat towards the colder
All objects emit radiation except those that are at absolute zero (the lowest temperature possible, whereby the atoms/moiecutes do not move at all)' However, the overall direction of flow of heat is from that of higher temperature to that of the lower temperature.
"
Infra-red radiation is the only form of radiation.,, lnfra-red radiation happens to be the one that causes things to heat up. Besides this, there are other forms of radiation such as ultraviolet radiation and gamma radiation. ln fact, all the different parts of the electro."gn"ii.' spectrum such as radiowaves, visibre right, and microwaves, can be considered radiation as well.
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Section A: Multiple-choice
For each question,
Ouestions
four suggested answers are given. Choose the most appropdate in the brackets provided.
(t)
1.
(uflu
A
B
ref lecto r
a
bso rbe r
c
D
bsorber
bso rbe r
ref lecto r
a
bsorber
2.
A Conduction C Diffusion
13.
I
B D
Convection Radiation
i i
I
Convection occurs more readily in gases as compared to liquids. Which of the following statements best explains this?
i
I I
A B C D
Liquids are denser than gases. Liquids have particles that are more closely packed together compared to particles in gases. Gases expand more than liquids for the same rise in the temperature. Gases expand less than liquids for the same rise in temperature. (
ln
I
The following diagrams show pieces of wax on different positions of a metal rod. The metal rod is heated at one end as shown. ln which setup will the wax
melt first?
A
B
fi :
H-
wax
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5.
A B C D
6.
Air
Vacuum
Aluminium
Cork
The base of an electric iron is made of metal because A it is a good insulator of heat ' B it is a good conductor of heat C it is a good radiator of heat D it is a Poor radiator of heat is on the table. which is the Edward is seated at his desk. A cuP of hot water to him? fastest waY the heat in the cup can be transferred
7.
A B C D
8.
Conduction Convection Radiation amount of time All the methods of heat transfer will take the same
(l) (ll) A B C D
9.
(lll)
Solids Liquids
Gases
Radiationisthetransferofheatfromoneplacetoanotherbymeansof
A
B
c
D
;1
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A beaker of water is heated as shown. Which diagram best illustrates the convection cu rrentS in the beaker of water?
A B
fl$
Which of
the following is not an application of dull, black surfaces? in solar panels in cooling fins of refrigerators in vacuum flasks in radiators in cars
A B C D A B C D
Heat is a
a a a a
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difference in the setuPs 13. The following setups are placed under the sun. The only will the thermometer setup which ln is the surface of the container as indicated. register the highest reading after 30 minutes?
B
White
Shiny
black
Dull black
Silvery
A B G D
c
D
the temPerature of the object the surface area of the obiect the nature of the surface of the object the medium in which the radiation arrives or leaves
same 16. ln which of the substances will heat be transferred through the process(es)?
(l)
A C
(ll)
(lll)
B D
r:F t{ ner
ring the
e
(l)
formation of
(ll)
ruT
La nd
the land is hot and the sea is cold and this results in
breeze.
(Il
A B C D
The
Day Day
Sea
La nd
Night Nisht
Sea
diagram below shows the cross-section of a typical vacuum flask. A vacuum is found between the outer and inner walls of the flask.
Outer wall
lnner wall
Vacuum
(il)
(il t)
B D
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(a)
(b)
(c)
2.(a)Classifythefollowinglistofitemsas'Goodconductorofheat'or'Good
insulator of heat''
copper gold, water, air, silver, Styrofoam, wood, vacuum,
ciF H Esr
The
following diagram shows the flow of air into and out of a box.
(bl
What can you do to make this flow of air visible to the naked eye? lllustrate your answer in the diagram above if required.
(c)
Draw in the diagram below the convection currents formed in the solution when it is heated as shown.
.:
Bea
ker
Bunsen burner
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4.
The diagram below shows two similar containers, A and B filled with water. of them has a dull black surfac, while the other one has a silvery surface.
E
(al
bases? Why?
E!::i:ii:iii!l
AB
lF!i!i:+i:!i:il
(b)
Assuming the bases of A and B are made of the same material and the setup is placed in the Sun for 30 minutes, which thermometer will regi higher reading? Why?
(cl
Assume that both of the surfaces of A and B are dull black, but the base of A is made of styrofoam, while the base of B is made of aluminium. lf they are placed in the sun on a hot tarmac road for 30 minutes, which thermometer will register a higher reading? Why?
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.l
(b)
ThefigurebelowshowsaVacuumflaskfilledwithwater'Thesurfacesofthe
outer
energy lost? Explain your answer' Through which Process is most of the heat
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2.
(a)
to shown in the diagram below help How does a window like the one inside and outside of the house? reduce heat tra n sfe r between the
Window Panes
Layer of air
(b)
between the house and the roof How does the presence of the fibre the inside and outside of the hou help to reduce heat transfer between
'l
F
F
I r i I
and placed in a test tube.The test ice is seen to melt very slowly as shown.The the spot is heated at tube Explain. heated. is being tube the test although
h i
(al Explain how the sea and land breezes are formed.
expla natioh, a diagram showing the
(b)
(i)
lf an air conditioner is installed in the house, where should it be installed? Draw the location in the cross section of the house below.
TnaruEiMlsstctN
(ii)
lf a heater is installed in a hous, where should it be installed? the location in the cross section of the house belo\M.
Air conditioner
Heater
(iii)
^4.A
?
Bu
nsen bu rner
(a)
Explain how heat energy is transferred through the bottom of the the water.
beaker
(b)
(cl
{
Peter places his hand 20 cm away from the Bunsen burner. What is the process by which the heat energy is transferred to his hand?
I o
o
.i::'::,
be balanced, which means that the number of atoms for each erement present on the left hand side should be the same as that on the right hand side of the reaction. 0 Afew examples of chemical reactions are: oBy heating: Combination: By heating different substances together can cause these substances to together to form a new compound. For exampte: when h"ai i" lron + sulphur --> iron sulphide Combustion (burning): The process invorvei the combination of the substance with oxygen. Light and heat is given off during the proces". iti"r.rnpl", r Carbon + oxygen ____> carbon OioxiOe > Oxidation: oxidation is when a substance combines with oxygen to form a new substance' combustion is an example of oxidation]orioution can occur without light and heat given off. For r lron + oxygen _____> being "r"rnpf",. iron ox-ide ln this process, iron is oxidised to give iron oxide (rust). > Thermal decomposition: This occurs when a substance breaks down into simprer substances upon heating. For exampre, most carbon"t", r Calcium carbonate __+ carbon dioxide o"ao"r'po"" on heating: + calcium oxide ln this reaction, carcium carbonate decomposes'to carcium oxide with the release of carbon dioxide. By mixing: > when different substances are mixed together, they can react to give new substances. For example: r Acid + metal --> hydrogen + metal salt r Acid + carbonate _____> dioxide + water + salt r Acid + alkali _____+ salt +"rrbon water r Reactive metal + water _> alkali + hydrogen
>
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ffi *-*,ql*,i{sns
By passing an electric current: > When an electric current is passed through substances, a new su can be formed through combination of these substances. > At the same time, an electric current can also cause the substances decompose into simpler substances. This is known as electrolysis. By exposure to light: > Light is a form of energy. When it is absorbed, it can cause a chemi change. > ln photosynthesis, light energy is used to convert water and carbon dioxide to glucose and oxygen. > Light energy is also used to convert silver bromide into silver in photographic films and these will display as dark areas on the film. is the principle behind photography.
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" When
wax melts, there is a chemical change." The melting of wax itself is a physical change - a change from its so Iid to its liquid state. However, when wax burns, there is combustion and he there is a chemical change.
'Digital cameras nowadays do not work on the same principle as film cam o Photography is based on one principle: The capturing of light. ln film cam light is captured by a film that converts silver bromide to silver, which s up as dark areas on the film. ln digital cameras, the light is captured by a sensor which converts the energy into an electrical voltage and is interp as a pixel on the image.
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most aPProPriate question, four suggested answers are given. choose the wer and write its letter in the brackets provided. the formed in a solution for various reasons. ln which of reaction? sign of a chemical following situations is the formation of bubbles a A A beaker of water is heated to 100 'C B A can of carbonated drink is opened
Bubbles can be
cAbeakerofhvdrogenperoxidedecomposingintooxygenandhydrogen
A swimmer exhaling
underwater
light. Magnesium burns in air with a brilliant white formed after burning?
A B C D A B C D
+ hYdrogen + oxygen + oxygen carbon dioxide + wate r + carbon dioxide + water Carbon + oxygen + carbon dioxide potassium chloride + water Potassium hydroxide + hydrochloric acid -+
(
Which of the
A B c D A B C D
ElectrolYsis PhotosYnthesis
in air?
C xEt*tc,A,L E
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6.
Methane + oxygen
->
A
B
c
D
7.
Which of the following is not an example of thermat decomposition? A Cooking of food B Heating of wax C Heating of sugar D Heating of carbon carbonate
8.
A C 9'
B D
which of the following processes involve chemical reactions? (f) Baking of a cake (ll1 Distillation of seawater (lll) Electroplating of jewellery (lv1 Filtration of a mixture of sand and water
A C
10.
B D
I
t
B C D
11.
oxidation occurs in ail of the foilowing situations except during A electrolysis of water
respiratio n
Chemical changes
A I c D
GprEutsl\L ffunruGHs
which of the foilowing is not an exampre of a physical change? A An ice-cream melting B A matchstick being f i"t C Dissolving salt in water D A piece oi metar expanoing when heated
copper chtoride
chrorine + copper
of
following shows a list of raw materials and products. is not an example which of the fotowing of a physical change from the raw materiar to product?
The
A B C D A B C D
Four
Raw Materials
Petrol
which of the
fotowing is not produced during the burning of fossir fuers? Carbon dioxide
Sulphur dioxide
Carbon monoxide
Sulphur
carbonate
(
different pairs of substances are risted berow. ln which a chemicar change of the following will occur when the two of them are mixed togeth er? A Salt and sugar B lron filings anO sulphur C Sodium and water D Water and alcohol
(
Which
by an
iJ.Tl':'"x;::5 gi1;iy i D
of the foilowir is an example of a chemical reaction that electri" can be caused "urr"natn Sulphuric acid + sodium hydroxide _> sodium sulphate water T"", u m i n i u m ch ro ri de + + hyd ros en lron + sulphur __> iron "ulpf.,it"
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Section B: Short-answer
1.
Ouestions
(a)
(b)
(cl
(d)
when copper carbonate is heated, copper oxide is observed and dioxide gas is given off.
carbon
(e)
Hydrochloric acid and potassium hydroxide will neutralise to form potassium chloride and water.
E xEMItr.A,L E rr*NGEs
Explain with the aid of a labelled diagram how an iron rod can be plated with copper by electrolysis.
(a) Hydrogen peroxide solution is often kept in dark bottles and not exposed to
light. Give a reason and write a word equation to support your answer.
(bl
EnevrtrAL
"#'.
Structured Ouestions
(bl
Heating of water is a physical change while electrolysis of water is chemical change. Explain why it is so.
{c)
Define the following terms and give an example of a chemical reaction is due to it.
(i)
that
Oxidation:
E uEMtnAL
l-tn ruffiHs
for the survival of living state two reasons why photosynthesis is essential things.
come from? where and in what form does the energy for photosynthesis
uses the same form of Give another example of a chemical reaction that energy.
harmful products. Nitric acid is ,rChemical reactions can Produce both useful and causes acid rain' needed to make fertilisers while sulphur dioxide
(bl
needed to form nitric Besides nitrogen, what are the other raw materials
acid?
ExeuttrAl EneNseE
(c)
sulphur dioxide?
(e)
Besides causing acid rain, state another harmul effect of sulphur dioxide.
(f)
4.
(a)
One common substance found in the food we eat is glucose. The energy glucose is released for use in our bodies in a process known as respirati Write down the word equation for respiration.
(b)
Given that the chemical formula for glucose is cuH,rou, write down balanced chemical equation for respiration.
(cl
Food is often mixed before consumption. Give an example of a chemical and physical change as a result of this.
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