Redox potential CV

Acetonitrile
Adjusted sensitivity
Each ;line represents diff scan rates all been overlayed on one digarm
Scan rates ranged from 0 .1 s-1 to 1
Peak due to iodide oxidation is read from +peak to peak bottom line. Iodide to triiodide
Glycol
Didnt work
Using equation i
p
= 2.69 10
5
n
3/2
A D
1/2
C
1/2 compare to linear equation y = mx+c
y = peak current
x = V1/2
c = zero
Therefore m is = everything else
C = concentration 0.05 M ethylene glycol (acetonitrile ?)
two e- transfer
A = area of platinium elecrtrode given
work out D (diffusion coefficient) of iodide
Prelim

have to wrk out open circuit potential diff between no light and light on. Increase in potential due to light being
absorbed + find open circuit potential then add 0.5V to ocp that gives boundarys high end pottetnial is 0.5 added to
OCP. Low end potential should be zero but taken further to allow easier read off. This is used as values on cyclic
voltammetry.
One light and one dark on all graphs.

Short circuit value is where cv potential is zero
Short circuit current is where cv potential is Zero.


Redox potential CV
Acetonitrile
Adjusted sensitivity
Each ;line represents diff scan rates all been overlayed on one digarm
Scan rates ranged from 0 .1 s-1 to 1
Peak due to iodide oxidation is read from +peak to peak bottom line. Iodide to triiodide
Glycol
Didnt work
Using equation i
p
= 2.69 10
5
n
3/2
A D
1/2
C
1/2 compare to linear equation y = mx+c
y = peak current
x = V1/2
c = zero
Therefore m is = everything else
C = concentration 0.05 M ethylene glycol (acetonitrile ?)
two e- transfer
A = area of platinium elecrtrode given
work out D (diffusion coefficient) of iodide
Prelim

have to wrk out open circuit potential diff between no light and light on. Increase in potential due to light being
absorbed + find open circuit potential then add 0.5V to ocp that gives boundarys high end pottetnial is 0.5 added to
OCP. Low end potential should be zero but taken further to allow easier read off. This is used as values on cyclic
voltammetry.
One light and one dark on all graphs.

Short circuit value is where cv potential is zero
Short circuit current is where cv potential is Zero.


Redox potential CV
Acetonitrile
Adjusted sensitivity
Each ;line represents diff scan rates all been overlayed on one digarm
Scan rates ranged from 0 .1 s-1 to 1
Peak due to iodide oxidation is read from +peak to peak bottom line. Iodide to triiodide
Glycol
Didnt work
Using equation i
p
= 2.69 10
5
n
3/2
A D
1/2
C
1/2 compare to linear equation y = mx+c
y = peak current
x = V1/2
c = zero
Therefore m is = everything else
C = concentration 0.05 M ethylene glycol (acetonitrile ?)
two e- transfer
A = area of platinium elecrtrode given
work out D (diffusion coefficient) of iodide
Prelim

have to wrk out open circuit potential diff between no light and light on. Increase in potential due to light being
absorbed + find open circuit potential then add 0.5V to ocp that gives boundarys high end pottetnial is 0.5 added to
OCP. Low end potential should be zero but taken further to allow easier read off. This is used as values on cyclic
voltammetry.
One light and one dark on all graphs.

Short circuit value is where cv potential is zero
Short circuit current is where cv potential is Zero.


Redox potential CV
Acetonitrile
Adjusted sensitivity
Each ;line represents diff scan rates all been overlayed on one digarm
Scan rates ranged from 0 .1 s-1 to 1
Peak due to iodide oxidation is read from +peak to peak bottom line. Iodide to triiodide
Glycol
Didnt work
Using equation i
p
= 2.69 10
5
n
3/2
A D
1/2
C
1/2 compare to linear equation y = mx+c
y = peak current
x = V1/2
c = zero
Therefore m is = everything else
C = concentration 0.05 M ethylene glycol (acetonitrile ?)
two e- transfer
A = area of platinium elecrtrode given
work out D (diffusion coefficient) of iodide
Prelim

have to wrk out open circuit potential diff between no light and light on. Increase in potential due to light being
absorbed + find open circuit potential then add 0.5V to ocp that gives boundarys high end pottetnial is 0.5 added to
OCP. Low end potential should be zero but taken further to allow easier read off. This is used as values on cyclic
voltammetry.
One light and one dark on all graphs.

Short circuit value is where cv potential is zero
Short circuit current is where cv potential is Zero.


Redox potential CV
Acetonitrile
Adjusted sensitivity
Each ;line represents diff scan rates all been overlayed on one digarm
Scan rates ranged from 0 .1 s-1 to 1
Peak due to iodide oxidation is read from +peak to peak bottom line. Iodide to triiodide
Glycol
Didnt work
Using equation i
p
= 2.69 10
5
n
3/2
A D
1/2
C
1/2 compare to linear equation y = mx+c
y = peak current
x = V1/2
c = zero
Therefore m is = everything else
C = concentration 0.05 M ethylene glycol (acetonitrile ?)
two e- transfer
A = area of platinium elecrtrode given
work out D (diffusion coefficient) of iodide
Prelim

have to wrk out open circuit potential diff between no light and light on. Increase in potential due to light being
absorbed + find open circuit potential then add 0.5V to ocp that gives boundarys high end pottetnial is 0.5 added to
OCP. Low end potential should be zero but taken further to allow easier read off. This is used as values on cyclic
voltammetry.
One light and one dark on all graphs.

Short circuit value is where cv potential is zero
Short circuit current is where cv potential is Zero.


Redox potential CV
Acetonitrile
Adjusted sensitivity
Each ;line represents diff scan rates all been overlayed on one digarm
Scan rates ranged from 0 .1 s-1 to 1
Peak due to iodide oxidation is read from +peak to peak bottom line. Iodide to triiodide
Glycol
Didnt work
Using equation i
p
= 2.69 10
5
n
3/2
A D
1/2
C
1/2 compare to linear equation y = mx+c
y = peak current
x = V1/2
c = zero
Therefore m is = everything else
C = concentration 0.05 M ethylene glycol (acetonitrile ?)
two e- transfer
A = area of platinium elecrtrode given
work out D (diffusion coefficient) of iodide
Prelim

have to wrk out open circuit potential diff between no light and light on. Increase in potential due to light being
absorbed + find open circuit potential then add 0.5V to ocp that gives boundarys high end pottetnial is 0.5 added to
OCP. Low end potential should be zero but taken further to allow easier read off. This is used as values on cyclic
voltammetry.
One light and one dark on all graphs.

Short circuit value is where cv potential is zero
Short circuit current is where cv potential is Zero.