UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS General Certificate of Education Ordinary Level

CHEMISTRY Paper 1 Multiple Choice Additional Materials: Multiple Choice Answer Sheet Soft clean eraser Soft pencil (type B or HB recommended)

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May/June 2011 1 hour

*5566194136*

READ THESE INSTRUCTIONS FIRST Write in soft pencil. Do not use staples, paper clips, highlighters, glue or correction fluid. Write your name, Centre number and candidate number on the Answer Sheet in the spaces provided unless this has been done for you. There are forty questions on this paper. Answer all questions. For each question there are four possible answers A, B, C and D. Choose the one you consider correct and record your choice in soft pencil on the separate Answer Sheet. Read the instructions on the Answer Sheet very carefully. Each correct answer will score one mark. A mark will not be deducted for a wrong answer. Any rough working should be done in this booklet. A copy of the Periodic Table is printed on page 16.

This document consists of 13 printed pages and 3 blank pages.

IB 06_5070_12/FP UCLES 2011

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2 1 A drop of liquid bromine is placed in the bottom of a gas jar. Brown fumes of bromine vapour slowly spread through the covered gas jar. Why does this happen? A B C D 2 Bromine vapour is less dense than air. Bromine molecules and the molecules in air are always moving around. Bromine molecules are smaller than the molecules in air. Bromine molecules move faster than the molecules in air.

Copper(II) sulfate crystals are separated from sand using the four processes listed below. In which order are these processes used? 1st A B C D filtering filtering dissolving dissolving 2nd dissolving dissolving evaporating filtering 3rd crystallising evaporating filtering evaporating 4th evaporating crystallising crystallising crystallising

The diagrams show an experiment with aqueous ammonium chloride.

poured in

moist litmus paper

solution X aqueous ammonium chloride mixture

heat
A gas, Y, is produced and the litmus paper changes colour. What are solution X and gas Y? solution X A B C D aqueous sodium hydroxide aqueous sodium hydroxide dilute sulfuric acid dilute sulfuric acid gas Y ammonia chlorine ammonia chlorine

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3 4 A student tested a solution by adding aqueous sodium hydroxide. A precipitate was not seen because the reagent was added too quickly. What could not have been present in the solution? A 5 Al 3+ B Ca2+ C NH4+ D Zn2+

In which of the following is there a lattice of positive ions in a sea of electrons? A B C D liquid potassium chloride sand solid graphite solid magnesium

What is the mass of oxygen contained in 72 g of pure water? [Relative atomic masses: H = 1; O = 16] A 16 g B 32 g C 64 g D 70 g

A covalent bond is formed by A B C D electron sharing between metals and non-metals. electron sharing between non-metals. electron transfer between non-metals. electron transfer from metals to non-metals.

Which molecule has the largest number of electrons involved in covalent bonds? A C2H4 B CO2 C CH3OH D N2

The equation for the reaction between calcium carbonate and hydrochloric acid is shown. CaCO3(s) + 2HCl (aq) CaCl 2(aq) + H2O(l) + CO2(g) How many moles of calcium carbonate will give 24 cm3 of carbon dioxide when reacted with an excess of the acid? (Assume one mole of carbon dioxide occupies 24 dm3.) A 1 mol B 0.1 mol C 0.01 mol D 0.001 mol

10 Element X has the electronic structure 2,8,5. Element Y has the electronic structure 2,8,7. What is the likely formula of a compound containing only X and Y? A XY3 B X2Y3 C X3Y D X3Y2

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4 11 The empirical formula of a liquid compound is C2H4O. To find the empirical formula, it is necessary to know the A B C D density of the compound. percentage composition of the compound. relative molecular mass of the compound. volume occupied by 1 mole of the compound.

12 Which statement about both chlorine atoms and chloride ions is correct? A B C D They are chemically identical. They are isotopes of chlorine. They have the same number of protons. They have the same physical properties.

13 The diagram shows the electrolysis of molten lead(II) bromide using inert electrodes.

brown gas silvery metal molten lead(II) bromide

heat
What happens during this electrolysis? A B C D Atoms change to ions. Covalent bonds are broken. Ions change to atoms. New compounds are formed.

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5 14 The energy profile diagram for the reaction between hydrogen and chlorine is shown.

H2 + Cl 2

reactants energy

2HCl products reaction pathway

What information about this reaction does the diagram show? type of reaction A B C D endothermic endothermic exothermic exothermic sign of enthalpy change, H negative positive negative positive

15 Which pair of metals X and Y will produce the highest voltage when used as electrodes in a simple cell?
V metal X in a solution of a salt of X metal Y in a solution of a salt of Y

porous membrane

metal X A B C D copper magnesium magnesium zinc

metal Y silver silver zinc copper

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6 16 The equation shows what happens in a redox reaction between iron(II) chloride and chlorine gas. 2FeCl 2 + Cl 2 2FeCl 3 Which equation describes the reduction process in this reaction? A B C D 2Cl Cl 2 + 2e Cl 2 + 2e 2Cl Fe2+ Fe3+ + e Fe3+ + e Fe2+

17 Which acid and base react together to produce an insoluble salt? A B C D hydrochloric acid and sodium hydroxide nitric acid and calcium oxide sulfuric acid and barium hydroxide sulfuric acid and zinc oxide

18 Carbon and silicon are both in Group IV of the Periodic Table. Which statement is correct for both carbon dioxide and silicon dioxide? A B C D They are acidic oxides. They are readily soluble in water. They contain ionic bonds. They have giant molecular structures.

19 The following changes could be made to the conditions in the reaction between zinc and hydrochloric acid. 1 2 3 4 increase in concentration of the acid increase in particle size of the zinc increase in pressure on the system increase in temperature of the system

Which pair of changes will increase the rate of reaction? A 1 and 2 B 1 and 4 C 2 and 3 D 3 and 4

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7 20 Which calcium compound does not increase the pH of acidic soils? A B C D calcium carbonate calcium hydroxide calcium oxide calcium sulfate

21 A solution of fertiliser was tested as shown.

add excess aqueous sodium hydroxide solution moist red litmus paper turns blue

fertiliser solution

green precipitate forms

warm the mixture

Which ions must be present in the fertiliser? A B C D Fe2+ and SO42 Fe3+ and NO3 NH4+ and Fe2+ NH4+ and NO3

22 Which pair of properties are both correct for a typical transition element? property 1 A B C D forms coloured compounds high density low density low melting point property 2 soluble in water has variable oxidation states high melting point can act as a catalyst

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8 23 What happens when zinc foil is placed in an aqueous solution of copper(II) sulfate? A B C D Copper(II) ions are oxidised. There is no reaction. Zinc atoms are oxidised. Zinc sulfate is precipitated.

24 Which deduction about the element astatine, At, can be made from its position in Group VII? A B C D It forms covalent compounds with sodium. It is a gas. It is displaced from aqueous potassium astatide, KAt, by chlorine. It is more reactive than iodine.

25 In the apparatus shown, gas P is passed over solid Q.

Q P

heat

No reaction occurs if P and Q are P A B C D hydrogen hydrogen oxygen oxygen Q lead(II) oxide magnesium oxide carbon sulfur

26 The diagram represents the manufacture of sulfuric acid by the Contact process.
sulfur dioxide sulfur trioxide R sulfuric acid

sulfur

What is used in step R? A B C D concentrated sulfuric acid followed by water vanadium(V) oxide water followed by concentrated sulfuric acid water only
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9 27 Aluminium is higher than copper in the reactivity series so the following displacement reaction should be feasible. 2Al (s) + 3CuSO4(aq) Al 2(SO4)3(aq) + 3Cu(s) The reaction does not take place at room temperature. What is the reason for this? A B C D Aluminium has an inert coating all over it. The compound aluminium sulfate does not exist. The reaction is exothermic. The reaction needs to be warmed to take place.

28 Scrap iron is often recycled. Which reason for recycling is not correct? A B C D It reduces the amount of pollution at the site of the ore extraction. It reduces the amount of waste taken to landfill sites. It reduces the need to collect the scrap iron. It saves natural resources.

29 The gases coming from a cars exhaust contain oxides of nitrogen. How are these oxides formed? A B C D Nitrogen reacts with carbon dioxide. Nitrogen reacts with carbon monoxide. Nitrogen reacts with oxygen. Nitrogen reacts with petrol.

30 Which element can only be extracted from its ore using electrolysis? A B C D calcium copper lead silver

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10 31 Which diagram represents the structure of an alloy?

A B C D

32 When a volcano erupts, which gas is produced in significant amounts? A B C D carbon monoxide chlorofluorocarbons methane sulfur dioxide

33 Useful fractions are obtained by the fractional distillation of petroleum. Which fraction is matched by its use? fraction A B C D bitumen lubricating oils paraffin (kerosene) petrol (gasolene) use fuel in cars for making waxes and polishes for making roads aircraft fuel

34 Compounds X and Y are both alkanes. Compound X has a higher boiling point than compound Y. What could be the formulae of compounds X and Y? compound X A B C D C8H16 C8H18 C9H18 C9H20 compound Y C9H18 C9H20 C8H16 C8H18

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11 35 Compound X is a hydrocarbon. It reacts with steam to form an alcohol. Which type of compound is X and what would be its effect on bromine water? type of compound A B C D alkane alkane alkene alkene effect on bromine water turns from brown to colourless turns from colourless to brown turns from brown to colourless turns from colourless to brown

36 Which bond is present in both nylon and Terylene? A CO B C=O C NC D NH

37 With which substance will ethene react to form more than one product? A B C D bromine hydrogen oxygen steam

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12 38 Four hydrocarbon structures are shown.

H H H H H C C H 1 C C H H H H H H C H H C H 2 H C H C H H H

H H H C C H 3

H C C H H H H

H C H H

H C

H C H H

H C H H

C H 4

Which hydrocarbons are isomers of each other? A 1, 2 and 3 B 1, 2 and 4 C 1 and 2 only D 3 and 4

39 When a compound X is reacted with sodium carbonate, carbon dioxide gas is evolved. What could be the formula of compound X? A C2H5CO2CH3 B C3H7CO2H C CH3CO2C2H5 D C4H9OH

40 Which statement about ethanoic acid is correct? A B C D It contains three carbon atoms per molecule. It contains five hydrogen atoms per molecule. It is insoluble in water. It reacts with ethanol to form a sweet-smelling compound.

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DATA SHEET The Periodic Table of the Elements

Group III
1

I H
Hydrogen

II

IV

VI

VII

0
4

He
Helium

1 11 12 14 16 19

2 20

Li
Boron Carbon

Be
5 27 28 6 7

N
Nitrogen

O
Oxygen

F
Fluorine

Ne
Neon

Lithium

Beryllium

8 31 32

9 35.5

10 40

23

24

Na
Aluminium

Mg
13 51 52 55 56 59 59 64 65 70

Al
14

Si
Silicon

P
Phosphorus

S
Sulfur

Cl
Chlorine

Ar
Argon

Sodium

Magnesium

11

12

15 73 75

16 79

17 80

18 84

39

40

45

48

K
Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc

Ca
23 93 96 101 103 106 108 112 24 25 26 27 28 29 30

Sc

Ti

Cr

Mn

Fe

Co

Ni

Cu

Zn
31

Ga
Gallium

Ge
Germanium

As
Arsenic

Se
Selenium

Br
Bromine

Kr
Krypton

Potassium

Calcium

Scandium

Titanium

19

20

21

22

32 115 119

33 122

34 128

35 127

36 131

16

85

88

89

91

Rb
Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver

Sr
41 181 195 184 186 190 192 197 42 43 44 45 46 47

Zr

Nb

Mo

Tc

Ru

Rh

Pd

Ag
48

Cd
Cadmium

In
Indium

Sn
Tin

Sb
Antimony

Te
Tellurium

I
Iodine

Xe
Xenon

Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the publisher will be pleased to make amends at the earliest possible opportunity.

University of Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.
49 201 204 50 207 51 209 52 53 54

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Rubidium

Strontium

Yttrium

Zirconium

37

38

39

40

133

137

139

178

Cs
Tantalum Iridium Tungsten Rhenium Osmium Platinum

Ba
73 77 74 75 76 78

La Ta W Re Os Pt

Hf

Ir
79

Au
Gold

Hg
Mercury

Tl
Thallium

Pb
Lead

Bi
Bismuth

Po
Polonium

At
Astatine

Rn
Radon

Caesium

Barium

Lanthanum

Hafnium

55

56

57

72

80

81

82

83

84

85

86

226

227

Fr
140 141 144 150

Ra

Ac
152 157 159 162 165 167 169 173 175

Francium

Radium

Actinium

87

88

89

*58-71 Lanthanoid series 90-103 Actinoid series Ce

Cerium Praseodymium Neodymium Promethium

Pr
59 60 238 61

Nd

Pm
62

Sm
Samarium

Eu
Europium

Gd
Gadolinium

Tb
Terbium

Dy
Dysprosium

Ho
Holmium

Er
Erbium

Tm
Thulium

Yb
Ytterbium

Lu
Lutetium

58 232

63

64

65

66

67

68

69

70

71

a = relative atomic mass

Key Th
Thorium Protactinium Uranium

X Pa
91 92

X = atomic symbol
90

U
93

Np
Neptunium

Pu
Plutonium

Am
Americium

Cm
Curium

Bk
Berkelium

Cf
Californium

Es
Einsteinium

Fm
Fermium

Md
Mendelevium

No
Nobelium

Lr
Lawrencium

b = proton (atomic) number

94

95

96

97

98

99

100

101

102

103

The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).