ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI

IIT JEE 2014 TW TEST MARKS: 65

TIME: 1HR TOPICS:CHEMICAL EQUILIBRIUM

SECTION-I
This section contains 10multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D) for its answer, out which ONLY ONE is correct.
(+3, - 1)

1. The graph below shows the variation of concentration with time for the reaction
3A(aq) B(aq) +2C(aq) at 25
o
C.

What is the value of the equilibrium constant?
(a) 1.18 (b) 0.845 (c) 0.567 (d) 0.222

2. Consider the reaction: 2CO(g) +O
2
(g) 2CO
2
(g). If the equilibrium concentrations of CO(g) is 1.6
10
-2
m/L, O
2
is 9.010
-2
m/L and CO
2
is 6.410
-2
m/L, what was the initial O
2
concentration
before the reaction started to form any CO
2
(g)?
(a) 1.2 M (b) 12 M (c) 0.12 M (d) 0.012 M

3. Calculate the equilibrium concentration of H
2
in a 1.0 L container initially containing 0.118 mole of
HBr at 1400 K. K
c
=1.510
-5
at 1400 K for the reaction
2HBr(g) H
2
(g) +Br
2
(g)
(a) 1.810
-6
M (b) 0.118 M (c) 1.510
-5
M (d) 4.510
-4
M

4. X, Y and Z react in the 1:1:1 stoichiometric ratio. The
concentration of X, Y and Z where found to vary with time as
shown in the figure below.
Which of the following equilibrium reacting may represent the
correct variation of concentration with time
(a) X(g) +Y(g) Z(g)
(b) X(g) +Y(s) Z(g)
(c)Z(g) +Y(g) X(g)
(d)Z(g) +X(g) Y(g)


5. The equilibrium constant for a reaction.
A B C D + + is
2
1.0 10

at 298 and is 2.0 at 373 K. The chemical process resulting in the

formation of C and D is
(a) Exothermic (b) Endothermic (c) Unpredictable (d) None

2
X
Time (Minutes)
C
o
n
c
.

(
M
)
4
8
10
6
1 2 3 4 5 6
Y
Z
C
A
B
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6. 1 mol of
2
N is mixed with 3 mol of
2
H in a litre container. If 50% of
2
N is converted into ammonia
by thereaction ( ) ( ) ( )
2 2 3
N g 3H g 2NH g + , then the number of moles of gas at the equilibrium are
(a) 1.5 (b) 4.5 (c) 3.0 (d) 6.0

7. Consider the reaction
( ) ( ) ( ) ( ) A g B g C g D g + +
Which occurs in one step. The specific rate constant are 0.25 and 5000 for the forward and reverse
reaction, respectively. The equilibrium constant is
(a)
4
2.0 10

(b)
2
4.0 10 (c)
5
5.0 10

(d)
6
2.5 10

8. For the equilibrium system
( ) ( ) ( )
2 2
2HX g H g X g +
the equilibrium constant is
5
1.0 10

. What is the concentration of HXif the equilibrium

concentration of
2
H and
2
X are
3
1.2 10

M, and
4
1.2 10

M respectively?
(a)
4
12 10 M

(b)
3
12 10 M

(c)
2
12 10 M

(d)
1
12 10 M

9. 8 mol of gas
3
AB are introduced into a
3
1.0dm vessel. It dissociates as ( ) ( ) ( )
3 2 2
2AB g A g 3B g +
At equilibrium , 2 mol of
2
A is found to be present. The equilibrium constant for the reaction is
(a)
2 2
2mol L

(b)
2 2
3mol L

(c)
2 2
27mol L

(d)
2 2
36mol L

10. What concentration of
2
CO be in equilibrium with 0.025 M CO at
o
120 Creaction
( ) ( ) ( ) ( )
2
FeO s CO g Fe s CO g + +
If the value of
c
K 5.0 = ?
(a) 0.125M (b) 0.0125M (c) 1.25M (d) 12.5M


SECTION-II

This section contains 7 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D) for its answer, out which ONE OR MORE is/are correct.
(+3, 0)

11. Consider the following reversible systems
N
2
+O
2

1
K


2NO;

2 2
1 1
N O
2 2
+
2
K


NO
2NO
3
K


N
2
+O
2
,
NO
4
K


2 2
1 1
N O
2 2
+
Correct relation between K
1
, K
2
, K
3
and K
4
is
(a) K
1
K
3
=1 (b)
1 4
K K 1 = (c)
3 2
K K 1 = (d) none of these

12. The equation
D d
(n 1)d

o =

is correctly matched for : (o is the degree of dissociation, D and d are the

vapour densities before and after dissociation)
(a)
n n
A B C
2 3
| | | |
+
| |
\ . \ .
(b)
n 2n
A B C
3 3
| | | |
+
| |
\ . \ .

(c)
n n
A B C
2 4
| | | |
+
| |
\ . \ .
(d)
n
A B C
2
| |
+
|
\ .


13. Variation of equilibrium constant K for the reaction
2A(s) +B(g) C(g) +2D(g)
is plotted against absolute temperature T in figure as: ln K Vs (1/T)
(a) the forward reaction is exothermic
(b) the forward reaction is endothermic
(c) the slope of line is proportional to H A
(d) adding A favours forward reaction

14. For the reaction ( ) ( ) ( )
2 2
H g I g 2HI g + , the equilibrium can be shifted in favour of product by
(a) Increasing the | |
2
H (b) Increasing the catalyst
(c) Increasing the | |
2
I (d) By using the pressure

15. In a reaction ( ) ( ) ( )
2 2 4
A g 4B g 2AB g + , H 0 A < . The formation of
4
AB is favoured by
(a) Low temperature and high pressure (b) High temperature and low pressure
(c) Low temperature and low pressure (d) High temperature and high pressure

16. For which of the following reactions at equilibrium at constant temperature, doubling the volume
will cause a shift to the right?
(a) ( ) ( )
2 4 2
N O g 2NO g (b) ( ) ( ) ( )
3 2
CaCO s CaO s CO g +
(c) ( ) ( ) ( )
2 2
2CO g O g 2CO g + (d) ( ) ( ) ( )
2 2
N g O g 2NO g +

17. Which of the following statements is/are wrong?
(a) At equilibrium, concentrations of reactants and products become constant because the reaction
stops.
(b) Addition of catalyst speeds up the forward reaction more than the backward reaction.
(c) Equilibrium constant of an exothermic reaction decreases with increase intemperature.
(d)
p
K is always greater than
c
K .

SECTION-III (Paragraph Type)

This section contains 2 groups of questions. Each question has 4 choices (A), (B), (C) and (D)
for its answer, out of which ONLY ONE is correct.
(+3, -1)

( ) ( ) ( )
2 2 3
N g 3H g 2NH g ; H 22.4kJ + A =

The pressure inside the chamber is 100 atm and temperature at 300K.

18. If
p
K for the given reaction is
5
1.44 10

, then the value of

c
K will be:
(a)
( )
5
1
2
1.44 10
mol L
0.082 500

(b)
( )
5
1
2
1.44 10
mol L
8.314 200

(c)
( )
5
1
2
1.44 10
mol L
0.082 700 s

(d) none of these

19. The preparation of ammonia by Habers process is an exothermic reaction. If the preparation follows
the following temperature-pressure relationship for its % yield. Then for temperature
1 2
T,T , and
3
T
the correct option is:








(a)
3 2 1
T T T > > (b)
1 2 3
T T T > > (c)
3 2 1
T T T < < (d)
1 2 3
T T T = =


SECTION-IV (Integer Answer Type)

This section contains 2 questions. The answer to each of the questions is a single digit integer,
ranging from 0 to 9. The correct digit below the question number in the ORS is be bubbled.
(+4, 0)

20. For the reaction A B C + , the rate constants for the forward and the reverse reactions are
2
4 10
and
2
2 10 respectively. The value of equilibrium constant K for the reaction would be


21. One mole of ethanol is treated with one mole of ethanoic acid at
o
25 C. Half of the acid changes into
ester at equilibrium. The equilibrium constant for the reaction will be.




















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ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI
TOPICS:CHEMICAL EQUILIBRIUM(ANSWER KEY)


1. a 2. c 3. d 4. b 5. b

6. c 7. c 8. c 9. c 10. a

11. a, b, c 12. b 13. a, c 14. a, c 15. a

16. a, b 17. a, b, d 18. d 19. c 20. 2.

21. 1

Head Office: Andheri: 26245223 MUMBAI / DELHI/ AKOLA / KOLKATA / LUCKNOW
Chemical Equilibrium Solution

5. (b)
Since K increases on increasing temperature, so the reaction will go forward by increasing
temperature and hence is endothermic.

6. (c)

50
50% 0.5
100
o = = =

2 2 3
N 3H 2NH +
Initial 1 3 0
Final 1 o 3 3 o 2o
Total Moles 1 3 3 2 = o + o + o
4 2 = o
4 2 0.5 3 = =

7. (c)

5 f
b
R 0.25
K 5.0 10
R 5000

= = =

8. (c)
( ) ( )
2 2
2HX H g X g +
At equilibrium?
3
1.2 10 M

4
1.2 10 M

| || |
| |
2 2
2
H X
K
HX
=

| |
3 4
5
2
1.2 10 1.2 10
10
HX

=
| |
7
5
1.2 1.2 10
HX
10

=

1
1.2 10

=

2
12 10 M

=

9. (c)
( ) ( ) ( )
3 2 2
2AB g A g 3B g + +
Initial 8 0 0
At eq.
8 2x
1

x
1

3x
1

Since volume
3
1md 1L = =
At eq.| |
2
A 2mol x = =

| |
3
AB 8 2 2 4M = =
| |
2
A 2M =

| |
2
B 3 2 6M = =
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| | | |
| |
3
2 2 2 2
2
3
B A 6 6 6 2
K 27mol L
4 4
AB


= = =

10. (a)
( ) ( ) ( ) ( )
2
FeO s CO g Fe s CO g + +
At eq. - 0.025 - x
solid solid

( )
( )
2
c
CO g x
K 5.0
CO g 0.025
(
= = =
(
(

(Given)
x 0.125M =
| |
2
CO 0.125M =


14. (a, b)
Increasing the concentration of reactants favours the product formation

18. (d)
( ) ( )
( ) n 2 4
p c c
K K RT K RT
A
= =
( )
( )
2
c
c 2
K
K RT
0.082 300

=
(


19. (b)

1 2 3
T T T > >
The % yield will decreases with rise I temperature since it is exothermic.

20. (2)
We know that
f
b
K
K
K
=

2
2
4 10
K 2
2 10

= =

21. (1)

2 5 3 3 2 5 2
C H OH CH COOH CH COOC H H O + +
Initial 1 1 0 0
At equ.
1
1
2

1
1
2

1
2

1
2


| || |
| | | |
3 2 5 2
2 5 3
1 1
CH COOC H H O
2 2
K 1
1 1
C H OH CH COOH
2 2

= = =
(