Formulating manual dish wash detergents: an optimum hand dish wash liquid formula can be

developed by using LAS, SLES and cocamidopropyl betaine and perhaps some cocamide DEA. Read
on to learn how to develop a variety dish wash detergents.
FOAM, VISCOSITY AND GREASE cutting power are some of the basic requirements for manual dish
wash detergent. Go a little further than the basic formula and it may require good foam stability
and a certain pH range. Still not satisfied? Try adding performance in hard water and cold
temperatures. Want still more? Throw in quick rinsing and drying. For even more discerning
consumers, add mildness and moisturizing effects. Or, how about adding benefits such as
naturally-derived, DfE-approved and readily biodegradable? Last, but not least, some formulators
add aromatherapy and antibacterial effects.

Let's start with the basics--foam, viscosity and grease cutting--and create a very economical
formula, one with the raw material cost of 5-10 cents per 16oz. So, if you can get a bottle, cap and
label and the labor for about 15-25 cents, the total cost of a 16oz. dish wash detergent in a bottle
ready to be shipped to a customer can be between 20-35 cents. The formula is simple. It has 95%
water, 0.63% sodium hydroxide (50% solution), 2.4% DDBSA (Pilot's Calsoft LAS-99), 1.2%
cocamide DEA (Pilot's Calamidc C), 0.77% sodium chloride and preservatives and dye as required.
The blending procedure is easy. Add the ingredients in the order listed with continuous mixing
until a clear, smooth and homogenous batch is obtained that is free of lumps and particles. Adjust
the pH to 8-9 with DDBSA or sodium hydroxide.
To make an economy formula, start with economy ingredients. DDBSA is one of the lowest cost
anionic surfactants in its class, as is cocamide DEA. Together, these two ingredients bring the
essentials of a manual dishwash performance attributes to the formula. DDBSA is generally sold as
95% plus active material. With today's high shipping costs it is an obvious advantage. Cocamide
DEA is also a high active material with no water or solvent in it. Neutralized DDBSA is an excellent
foamer with good detergency and oily soil removal capabilities. Cocamide DEA adds foam
enhancement and stability, emulsification and viscosity building properties. The formula listed
above has a viscosity of 200 cp. at 70[degrees]F, as measured by Brookfield RV viscometer using
spindle number 3 at 20 RPM. We can develop a wide range of formulas using essentially the
DDBSA, sodium hydroxide and cocamide DEA and perhaps some tetra-sodium EDTA or sodium
citrate as builders for water softening. So, for example, using the two surfactants, caustic soda
neutralized DDBSA (also called sodium alkyl benzene sulfonate) and cocamide DEA and, optionally,
some EDTA and salt, we can build formulas for hand dishwash liquids with increasing active
contents to fit various categories on a retailer's shelf. The categories can include economy,
medium grade and premium. Also, the same formulas with little modifications can be used for
pots and pan cleaners in I&I applications. The formulas are listed in Table 1 on the following page.
All amounts are listed in weight percents.







Table 1. Hand Dishwash Formulas


Economy Medium Premium

Water to 100%

Sodium hydroxide 50% 1.26 2.52 5.04

DDBSA (Pilot's LAS-99) 4.80 9.60 19.20

Cocamide DEA (Pilot's Calamide C) 1.20 1.20 2.40

pH adjustment Adjust pH to 8-9 by DDBSA or sodium hydroxide

Sodium chloride 1.0 1.2

Preservative, perfume, dye Q.S Q.S Q.S

% Solids 7.63 13.26 24.12

Viscosity (Cp.) at 70[degrees] F 300 700 5500

Ross Miles Foam
Height mm 0.1% in D.I water

Initial 100 120 135

After 5 min. 85 105 125

National Brand (37% solids)

Initial 140

After 5 min. 140

The most economical way to add sodium alkyl benzene sulfonate is to neutralize the DDBSA while
making the batch. Make sure your mixing tank and agitator arc constructed of a material that can
take pH extremes. The preferred procedure for neutralization of DDBSA is to add the formula
amount of water into the mixing tank and start mixing. Add the formula amount of sodium
hydroxide 50% solution and then slowly add the DDBSA. Adjust the mixer speed so that it will mix
the contents well but at the same time will not generate excessive foaming. Remember, you are
handling strong alkali and strong acid, so be careful as these are corrosive material, read
MSDS and take appropriate precautions. Also, this neutralization reaction is exothermic. It
generates a considerable amount of heat. So also take precautions to accommodate the heat
generation, particularly if you are manufacturing a large batch with big amounts of DDBSA and
sodium hydroxide. Alternatively, you can buy pre-neutralized material as well. It will probably cost
more but may be worthwhile in some instances. Pre-neutralized materials or the sodium salts of
DDBSA, also called sodium linear alkyl benzene sulfonate or sodium LAS, are available in 30-, 40-,
50-and 60% active varieties. Some of these materials may contain a hydrotrope (sodium
xylene sulfonate) to reduce the viscosity and make the product easier to handle. Others that do
not contain a hydrotrope, may come in a paste or gel form. These high viscosity versions need
special handling and storage.

The foam height data listed in Table 1 shows that the national brand commercial product has
better foam stability than the premium formula made with LAS and alkanolamide. So, the obvious
question is how to increase the foam stability? We tried adding lauramine oxide and cocamido-
propyl betaine to the medium formula. First we added 3% active lauramine oxide to the "medium"
formula. The initial foam height increased to 130mm but it dropped 120mm after five minutes.
When 3% active cocami-dopropyl betaine was added to the "medium formula" the initial foam
height increased to 135mm and after five minutes it dropped to 130mm. This shows that in LAS-
based formulas, the cocamidopropyl betaine may be a better choice as a secondary
surfactant than lauramine oxide. Polymers like cellulose ethers (hydroxypropyl methykellulose, for
example) can also be used as foam stabilizers although they may not be as economical as amine
oxides and betaines, will take longer to process and will not add to the foam volume in any
considerable quantity.

We then tried using sodium lauryl sulfate and sodium laureth-2 sulfate as primary surfactants in
dishwash formulas. We chose the medium formula and replaced the LAS with equal amount of
active SLS. The initial foam height, as well as the height after five minutes, was the same as those
listed for the LAS based formula (initial, 120mm and after 5 min., 105mm).

Next we made a modification to the medium formula by replacing LAS with an equal active
amount of SLES (2 mole EO). This formula showed a slight reduction in initial foam height
compared to the LAS formula but an improvement in the foam stability (foam height after five
minutes). The initial foam height was 115mm and after five minutes it dropped to 110mm.

In light of these experiments and their results, an optimum hand dishwash liquid formula can be
developed by using LAS, SLES, and cocamidopropyl betaine and perhaps some cocamide DEA. Let
us develop a 15% active formula using these surfactants. A starting formula can be made using 6%
active LAS, 4% active SLES, 3% active cocamidopropyl betaine and 2% cocamide DEA. This formula,
when diluted 0.1% with deionized water, gave an initial foam height of 135mm and five minutes
later the foam went down to 133mm (Ross Miles foam test). In contrast, when lauramine oxide
was substituted for cocamidopropyl betaine in the above-mentioned formula, the initial foam
height was 120mm and after five minutes it went down to 115mm. That means cocamidopropyl
betaine is a better secondary surfactant in an LAS/SLES formula than lauramine oxide.

One or two percent of tetrasodium EDTA or sodium citrate can be added to this formula as a
builder; viscosity can be reduced by adding SXS, propylene glycol or denatured ethyl alcohol. A
naturally-derived product can be formulated using SLES, cocamide DEA and cocamidopropyl
betaine. SLES will give better foam stability than LAS, particularly in hard water. A DEA-free
formula can be developed by using LAS, SLES and cocamidopropyl betaine. A sulfate-free and DEA-
free formula can be developed using LAS and cocamidopropyl betaine. Both surfactants are listed
on the Cleangredients' database used by EPA's Design for Environment.

Alkyl diphenyloxide disulsonates (AD-PODS), such as Calfax DB-45 from Pilot Chemical Co., is an
excellent additive to improve cold water efficacy and low streaking and spotting properties in
hand dishwashing formulas. These powerful anionic surfactants have excellent
hydrophilic properties and act as hydrotropes as well as surfactants. AD PODS can also help create
ultra concentrated detergents. They reduce the viscosity of high active surfactant solutions and,
unlike sodium xylene sulfonate, also add to percent active surfactant in the formula.

To create mild and skin friendly dishwashing liquids, use SLES with three moles of EO like Pilot's
Calfoam ES-303. Cocamidopropyl betaine can be added for improved mildness. Other amphoterics
like sodium lauroamphoacetate can also be used for mildness. Aloe vera, vitamin E, panthenol,
glycerin and other herbal extracts can be added to the formula for skin care benefits in premium
products. Essential oils, such as lavender and rosemary, can be used for aromatherapy benefits.
Triclosan is commonly used as an antibacterial agent. To claim antibacterial/antimicrobial efficacy,
the product must be registered with appropriate regulatory agencies such as FDA and EPA.