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Temperature
The sense of temperature comes primarily from touch. Our common experience tells that
ice is cold and boiling water is hot. Many other objects spread all around, may be neither
hot nor cold.
Temperature is a relative measure which is to express the degree of hotness or coldness
of matter. The temperature is indicated by a number according to some chosen scale.
Definition of Temperature:
The quantity that tells how hot or cold an object is with respect to some standard is
called temperature.
[Note: When we touch something and say that it is either hot or cold with respect to
some ‘standard’, the standard is our own body.]
Our temperature sense is somewhat unreliable and limited due to the following reasons:
• There is a limited range of temperature which can be sensed by us. We can not
touch too hot or too cold a thing.
• We can not have a quantitative idea of temperature. Also the feeling of
temperature may vary from one person to another. (This depends on the
difference of body temperature of the person involved.)
• Two things having same temperature can sometimes be mistaken to be at different
temperatures. As for example, if we remove a metal tray and a packet of
vegetables from the refrigerator, it appears that the metal tray is colder even
though they have the same temperature.
When we touch a hot iron rod, energy enters our hand from the hot rod and we can sense
that to be hot. When we touch a piece of ice, energy passes out of our hand to the colder
ice and we sense that to be cold. Energy is always transferred from a warmer object to a
colder object when in thermal contact*. (This energy transfer is a natural process which
happens in various ways.)
Definition of Heat:
The energy transferred from one object to another because of temperature difference
between the objects is called heat.
[Note: Matter does not contain heat as it is energy in transit from an object of higher
temperature to one of lower temperature. Matter contains internal energy in the form of
atomic and molecular motions and vibrations etc. The analogy can be drawn with work.
Work is done to transfer energy. But a body does not contain work.]
*
Thermal contact: when heat is transferred between two objects, whether or not they are touching, they
are said to be in thermal contact.
Fundamental Physics I by Dr. Abhijit kar Gupta (email: kg.abhi@gmail.com) 2
When our thermal sensation appears to be the same as we touch different things, we can
say that the things are at thermal equilibrium. The household things in a room are usually
found to be in thermal equilibrium. (The precise definition of thermal equilibrium will be
given later.)
A tray of ice when left open in a room for a sufficient time, the ice melts and
subsequently the ice-cold water in the tray does not remain cold. On the other hand a pot
of hot water when left open, it cools down and attains a temperature which is that of other
objects in the room. In both the cases water finally turns to be in thermal equilibrium with
other things in the room.
Thermodynamics:
A system that is described in terms of thermodynamic coordinates is called
thermodynamic system. The subject is called thermodynamics.
Under the purview of thermodynamics we can attach a more precise meaning of the
word, ‘equilibrium’. A state of a system in which the independent thermodynamic
coordinates that remain constant as long as the external conditions are unchanged is
called an equilibrium state.
The concept of temperature can be derived from the zeroth law of thermodynamics. We
may conclude that two systems when in thermal equilibrium may have some common
property. When a system A is in thermal equilibrium with another system C and also
another system B is in thermal equilibrium with C then the systems A and B are in
thermal equilibrium with each other. Therefore, there is some common property between
A and C which is also common between B and C. This property is temperature.
Thus we can define temperature in the following way:
[Note: The concept of temperature can be derived in a more concrete and mathematical way
which is beyond the scope of this syllabus.
There are three more fundamental laws of thermodynamics. The first law and second law of
thermodynamics will be discussed in a subsequent chapter. The zeroth law was postulated
after all other laws were discovered and the name was suggested by R.H. Fowler.]
Thermometer:
We have already discussed that temperature of a substance can only be merely sensed by
touching. But we need to quantitatively measure temperature.
Examples ⇒
• The Clinical thermometer: the mercury thermometer, we use at home. The
column of mercury expands with temperature. The property of thermal expansion
(or contraction) is used here. This is a common thermometer, in general, liquid-in-
glass type. Coloured alcohol is also used for the same purpose. These substances
(mercury or alcohol) are chosen because of their large thermal expansion and also
because they remain liquids over normal temperature ranges.
• The platinum resistance thermometer: this is used at laboratories. The property
of the change of electrical resistance of platinum wire with temperature is used
here. This is usually used for measuring a wider range of temperature and also for
more accurate measurements.
• The property of a thermo-couple is also used as a thermometer.
Temperature Scale:
Fundamental Physics I by Dr. Abhijit kar Gupta (email: kg.abhi@gmail.com) 4
o In America, the number 32 is assigned to the ice point and the number 212
to the steam point. The space between two fixed points is now 180 and
this is divided into 180 equal intervals or degrees.
o A thermometer with such a scale is called Fahrenheit thermometer. This is
named after its originator, the German Physicist Gabriel Daniel Fahrenheit
(1686-1736).
o The temperature readings are written as 0 F and the temperature
differences are usually written as F 0 .
9
F = C + 32 . (1)
5
Alternatively,
C F − 32
= . (2)’
5 9
From equation (1) or equation (2) it can be easily verified that when C = 0 (which
corresponds to ice point), we have F = 32 . When C = 100 (which corresponds to
steam point), we have F = 212 .
Gas thermometers are difficult to use as they require several corrections. Thus in
laboratories, they are replaced by secondary standard thermometers. Any thermometer
standardized with the help of primary thermometer is called secondary thermometer.
Except ideal gas thermometer, all other thermometers e.g., the resistance thermometer,
the thermo-couple etc., are secondary thermometers.
Fundamental Physics I by Dr. Abhijit kar Gupta (email: kg.abhi@gmail.com) 7
Triple point of water is the standard fixed point used in primary thermometer.
Discussions
Q.1 The temperature of a room is 25 0 C . What can you say about thermal equilibrium
when someone enters in that room?
Ans. Our normal body temperature is 37 0 C (98.6 0 F ). Biologically, through
metabolism, our body tries to maintain this temperature. If we enter into a room of
25 0 C , we will feel cold as the room temperature is below our body temperature. Energy
will flow out of our body to the air of the room to establish equilibrium. But our body
will resist and the equilibrium will not be reached.
[Note: However, if we keep an object of temperature 37 0 C in that room, it will eventually
reach in equilibrium state after exchanging energy with the air of the room.]
Q.2 When in winter, we cover our body with a blanket or a quilt, initially we feel cold
but after a while we get warm. What is the reason?
Ans. Our normal body temperature is 37 0 C . The blanket or the quilt assumes the
temperature of the room which is usually below our body temperature. So they appear
cold at the beginning. After a while the inner side of the cover and the trapped air
surrounding our body reach equilibrium with our body. Thus we feel comfort.
Q.3 Do you have same temperature sense when you touch a steel chair and a wooden
chair?
Ans. If the two chairs are kept in a same room, they will have same temperature due to
thermal equilibrium of them with the room. However, when we touch them, the steel
chair appears colder than the wooden chair (in winter). This is because the steel being a
metal, removes energy more quickly from our hands. But after some time, when the
thermal equilibrium is established, we feel no difference.
Q.4 Can you have an idea of atmospheric pressure with the help of a thermometer?
Ans. Boiling point of water is 100 0 C at standard (normal) atmospheric pressure. When
the pressure above water surface increases the boiling point also increases and the
boiling point decreases as the pressure decreases. Therefore, if the boiling point of water
is found to be more than 100 0 C , this gives an indication that the atmospheric pressure is
* 3
Pa = Pascal (unit of pressure); 101.3 kPa = 1 atm (1 kPa = 10 Pa); 1 atm = standard atmospheric
pressure = the pressure corresponding to 760 mm of Hg column.
Fundamental Physics I by Dr. Abhijit kar Gupta (email: kg.abhi@gmail.com) 8
more than the normal. Likewise, when the boiling point is found to be less than 100 0 C ,
the atmospheric pressure can be assumed to be less than the normal.
Questionnaire
Descriptive type: