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PGE368
Fall 2001 Semester
December 5 and 7
Fundamentals of
Nuclear Magnetic Resonance
Logging
Carlos Torres-Verdn, Ph.D.
Assistant Professor
Bedding scale Well logs
Stratum scale
Core plug scale
Pore scale
SPIN MAGNETIZATION
N
S
Proton
H
Hydrogen
PRECESSION
B
Parallel
Antiparallel
100,006
100,000
o
B
o
Larmor Precession
freq. = 4258
H
Gauss
z
B
o
ELEMENTAL NMR RESPONSE
Nucleus
[most common
applications in log &
core analysis]
2
ss
Natural
abundance
(%)
Relative
sensitivity I
(Hz/Gau )
4257.59
1
H
[core and log]
2
H
[aqueous phase]
13
C
[need high freq.]
19
F
[nonwetting phase]
1/2 99.99 1.000
653.57 1 0.015 0.0097
1070.5 1/2 1.10 0.0159
4005.5 1/2 100.00 0.833
23
Na
[salinity]
11.26 3/2 100.00 0.0925
TRANSVERSAL TIPPING
TRANSVERSAL TIPPING and PROTON PRECESSION
B
0
N
S
A time-constant magnetic
field used to polarize the
spins
A time-varying RF
magnetic field to excite
the spins
A magnetic receptor to
measured the spin
response
COMMERCIAL NMR WIRELINE TOOLS
MRIL CMR
B
0
Magnet
B
1
vs. Homogeneous B
0
Gradient field
LONGITUDINAL AND TRANSVERSE RELAXATION
T
W
T2
T1
T
E
T
w
= wait time
T
E
= inter-echo time
T1= Longitudinal magnetization build up
T2= Transverse magnetization decay
T1 BUILD-UP OF OILS
T1 Buildup
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
0
0
.
5
1
1
.
5
2
2
.
5
3
3
.
5
4
4
.
5
5
5
.
5
6
6
.
5
7
7
.
5
8
8
.
5
9
9
.
5
1
0
1
0
.
5
1
1
1
1
.
5
1
2
1
2
.
5
1
3
1
3
.
5
1
4
1
4
.
5
1
5
Time (sec.)
%
P
o
l
a
r
i
z
a
t
i
o
n
0.2 cP
0.4 cP
0.6 cP
0.8 cP
1 cP
2 cP
4 cP
Water (512 m)
Water (256 ms)
Water (64 ms)
Water (16 ms)
TRANSVERSE RELAXATION
Amplitude Decay Explanation
Gradient Field and Diffusion
Gradient Field and Diffusion
T T
1 1
T T
2 2
B
B
0 0
+
+
B
B
0 0
B
B
0 0
B
B
0 0
B
B
0 0
f
f
+
+
f
f f
f
f
f
-
-
f
f
Diffusion during the pulse sequence causes a reduction Diffusion during the pulse sequence causes a reduction
in signal amplitude with time and decreases T2. in signal amplitude with time and decreases T2.
M
M
Time
Time
Elements of T2 Decay
Elements of T2 Decay
(Wetting Phase Saturation = 100%)
(Wetting Phase Saturation = 100%)
1
2
T
=
+
+
1
T
2D
S
V
1
T
2b
Bulk Fluid Relaxivity
Surface Relaxivity Pore Surface Area to Volume Ratio Pore Surface Area to Volume Ratio
Diffusion Decay Diffusion Decay
Primary Controls on T2 Decay
Primary Controls on T2 Decay
(Wetting Phase Saturation = 100%)
(Wetting Phase Saturation = 100%)
1
1
2
2
T
T
=
=
+
+
+
+
S
S
V
V
1
1
T
T
2b
2b
Pore Fluid Viscosity
Pore Fluid Diffusivity
Magnetic Field Gradient
Inter-Echo Spacing (TE)
1
1
T
T
2D
2D
Pore Size & Geometry
M
a
g
n
e
t
i
c
s
Pore Mineralogy
Wettability
T
T
2
2
Decay and Pore Size
Decay and Pore Size
(Wetting Phase Saturation = 100%)
(Wetting Phase Saturation = 100%)
0
20
40
60
80
100
0 50 100 150 200 250 300 350 400 450 500
Time (ms)
E
c
h
o
A
m
p
l
i
t
u
d
e
(
p
u
)
Small Pore Size = Rapid Decay Rate
Large Pore Size = Slow Decay Rate
Single Exponential Decay
Single Exponential Decay
y
y
=
=
por
por
.
.
e
e
-
-
t / T
t / T
2 2
64ms 64ms
16 ms 16 ms
256 256
ms ms
t
t
A
m
p
l
i
t
u
d
e
(
y
)
A
m
p
l
i
t
u
d
e
(
y
)
y = y = por por
. .
e e
- -t/256 t/256
y = y = por por
. .
e e
- -t/64 t/64
y = y = por por
. .
e e
- -t/16 t/16
I
n
c
r
e
m
e
n
t
a
l
I
n
c
r
e
m
e
n
t
a
l
(
(
p
u
p
u
)
)
T
T
2 2
(ms)
(ms)
16 64 256 16 64 256
Multi
Multi
-
-
exponential Decay
exponential Decay
=
=
por
por
.
.
e
e
-
-
t / T
t / T
2 2
16 64 256 16 64 256
T
T
2 2
(ms)
(ms)
I
n
c
r
e
m
e
n
t
a
l
I
n
c
r
e
m
e
n
t
a
l
(
(
p
u
p
u
)
)
10 10
15 15
64 ms 64 ms
16 ms 16 ms
256 256
ms ms
5 5
= 30p.u.
= 30p.u.
t
t
y = 5 y = 5
. .
e e
- -t/ t/16 16
+ 10 + 10
. .
e e
- -t/ t/64 64
+ 15 + 15
. .
e e
- -t/ t/256 256
T2 RELAXATION AND PORE SIZE
0.5 100 10 1.0 1,000
T
2
ms
Clay Silt Fine
Coarse
Clay Domain
2
= 1 m/s
Sand Domain
2
= 5m/s
Water-Wet Hydrocarbon-Bearing Rock Formation
Clay
Wilcox Sand
Oklahoma City
1 cm
Close-Up
Effect of Pore Size on T2 Spectra
Effect of Pore Size on T2 Spectra
I
n
c
r
e
m
e
n
t
a
l
P
o
r
o
s
i
t
y
[
p
u
]
T
2
[msec]
0.00
0.50
1.00
1.50
2.00
0.1 1. 10. 100. 1000. 10000.
T
2
Spectra @ Sw = 1.0
Formation A
Formation B
T
2
Cut-off
Small Pores Large Pores Micro-Pores
NMR
= 25 pu
Formation B (high-k)
Formation A (Low-k)
BVI = 10 pu
BVM = 15 pu
BVI = 6 pu BVM = 19 pu
(Wetting Phase Saturation = 100%)
(Wetting Phase Saturation = 100%)
Surface
Surface
Relaxivity
Relaxivity
and T
and T
2
2
Decay
Decay
Controls on Surface
Controls on Surface
Relaxivity
Relaxivity
MRIL
= 26.25 pu
BVI = 5.95 pu
Time (ms)
25
20
15
10
5
Limestone Block
core
= 25.5%
E
c
h
o
A
m
p
l
i
t
u
d
e
0 15 150 135 120 105
90
75 60 45 30
MRIL
= 19.82 pu
BVM = 15.61 pu
BVI = 4.21 pu
Echo Spacing of 1.5 ms
Time (ms)
20
15
10
5
Berea Sandstone Block
core
= 20.3%
BVM Fit Results
Echo Amplitude
Complete Echo Fit Results
Mineralogy
Mineralogy
-
-
Independent Porosity
Independent Porosity
Gulf of Mexico Sandstone
Gulf of Mexico Sandstone
Middle East Carbonate
Middle East Carbonate
20
Core Porosity (%)
M
R
I
L
P
o
r
o
s
i
t
y
(
%
)
0
2
4
6
8
10
12
14
16
18
20
0 2 4 6 8 10 12 14 16 18
0
0.05
0.1
0.15
0.2
0.25
0.3
0 0.05 0.1 0.15 0.2 0.25 0.3
Core Porosity (frac.)
M
R
I
L
P
o
r
o
s
i
t
y
(
f
r
a
c
.
)
Porosity Considerations
Porosity Considerations
Although NMR porosity is
Although NMR porosity is
mineralogically
mineralogically
Independent, it is not fluid independent.
Independent, it is not fluid independent.
NMR porosity can be too low when
NMR porosity can be too low when
:
:
S
S
V
V
2b
2b
water water
(
(
Sw
Sw
)
)
S
S
V
V
Non-Wetting Phase Relaxivity
1
1
2
2
hc hc
T
T
=
= +
+
1
1
T
T
2D
2D
hc hc
1
1
T
T
2b
2b
hc hc
T2 Spectra for Various Fluid Types
T2 Spectra for Various Fluid Types
Water
Water
Oil
Oil
Gas
Gas
Effect of Pore Size on T2 Spectra
Effect of Pore Size on T2 Spectra
Small Pores Large Pores Micro-Pores
NMR
= 25 pu
Formation B (high-k)
Formation A (Low-k)
BVI = 10 pu BVM = 15 pu
BVI = 6 pu BVM = 19 pu
I
n
c
r
e
m
e
n
t
a
l
P
o
r
o
s
i
t
y
[
p
u
]
T
2
[msec]
0.00
0.50
1.00
1.50
2.00
0.1 1. 10. 100. 1000. 10000.
T
2
Spectra @Sw = Swir
Formation A
Formation B
T
2
Cut-off
(2
(2
-
-
Phases with Wetting Phase Saturation @ Irreducible)
Phases with Wetting Phase Saturation @ Irreducible)
Default T
Default T
2 2
Cut
Cut
-
-
off Values
off Values
T
2
[msec]
Carbonates : 92 msec Sandstones : 33 msec
0.00
1.00
2.00
3.00
4.00
0.1 1 10 100 1000 10000
BVI
BVM
4.00
0.00
1.00
2.00
3.00 T
2
Cut-off
I
n
c
r
e
m
e
n
t
a
l
P
o
r
o
s
i
t
y
(
p
u
)
CBW
Core
Core
-
-
Calibration Process
Calibration Process
Capillary Pressure Data
Core NMR Data
Calibrate BVI Model
Core Perm Data Calibrate Permeability Model
T
T
2
2
Cut
Cut
-
-
off from Core NMR
off from Core NMR
-
-
Obtain two core NMR measurements at:
Obtain two core NMR measurements at:
Sw
Sw
= 1.0
= 1.0
Sw
Sw
=
=
Swir
Swir
(obtained with centrifuging)
(obtained with centrifuging)
-
-
Determine T
Determine T
2 2
cut
cut
-
-
off where the terminal
off where the terminal
cumulative porosity @
cumulative porosity @
Sw
Sw
=
=
Swir
Swir
is equal
is equal
to the cumulative porosity @
to the cumulative porosity @
Sw
Sw
= 1.0.
= 1.0.
T
2
Cut-offs from Core NMR
T
2
(ms)
10 10 10
0 2 4
0
5
10
15
C
u
m
u
l
a
t
i
v
e
(
p
u
)
T
2
cut-off (Sxo = Swi)
S
w
= 1.0
S
w
(air-brine) = S
wir
BVI
T
2
cut-off
(Sxo = 1.0)
S
w
(oil-brine) = S
wir
T
2
Cut-offs from
Core
Core NMR
T2 vs. Cumulative Porosity
0.0
5.0
10.0
15.0
20.0
25.0
0.1 1.0 10.0 100.0 1000.0 10000.0
T2 (ms)
C
u
m
u
l
a
t
i
v
e
P
o
r
o
s
i
t
y
(
p
u
)
100% Water Saturated De-Saturated with Isotek
De-Saturated with Air
T
2
cut-off
(Sxo = 1.0)
T
2
cut-off
(Sxo = Swir)
BVI
C
u
m
u
l
a
t
i
v
e
P
o
r
o
s
i
t
y
(
p
u
)
T2 vs. Incremental Porosity
0.0
0.5
1.0
1.5
2.0
2.5
3.0
0.1 1.0 10.0 100.0 1000.0 10000.0
T2 (ms)
I
n
c
r
e
m
e
n
t
a
l
P
o
r
o
s
i
t
y
(
p
u
)
100% Water Saturated De-Saturated with Isotek
De-Saturated with Air
T
2
cut-off
(Sxo = 1.0)
T
2
cut-off
(Sxo = Swir)
I
n
c
r
e
m
e
n
t
a
l
P
o
r
o
s
i
t
y
(
p
u
)
T
T
2 2
Cut
Cut
-
-
off from Pc & Log NMR Data
off from Pc & Log NMR Data
0
100
Sw (%)
Pc
T
2
cutoff
Capillary Pressure Data
Swir
core
BVI
core
NMR Post-Processing
Cumulative Log
NMR Porosity
10
0
10
3
T
2
(ms)
4 8 16 32 64 128 256 512
T
2
(ms)
BVI BVM
Integrated Petrophysical Analysis Results
Integrated Petrophysical Analysis Results
Resistivity &
Permeability
Rock
Volume
Fluid
Saturation
Pore
Volume
T
2
Spectra
NMR Permeability Models
NMR Permeability Models
Where assumed default parameters are: C =10, a = 4 & b = 2
Coates
Coates
-
-
Timur
Timur
Model :
Model :
Kenyon Model:
Kenyon Model:
C
C
k
k
T
T
2
2
Geo. Mean
Geo. Mean
=
=
NMR NMR
b
b
a
a
NMR NMR
BVI
BVI
BVM
BVM
C
C
k
k
b
=
=
a
=
=
a
a
NMR
NMR
NMR
= 25 pu
Formation B (high-k)
Formation A (Low-k)
BVI = 10 pu BVM = 15 pu
BVI = 6 pu BVM = 19 pu
(Wetting Phase Saturation = 100%)
(Wetting Phase Saturation = 100%)
Permeability from NMR
Permeability from NMR
k
k
a
a
S
S
wir
wir
1
1
-
-
S
S
wir
wir
C
C
b
b
=
=
Generalized Coates
Generalized Coates
-
-
Timur
Timur
Model:
Model:
This model is designed to compute the effective (non
This model is designed to compute the effective (non
-
-
wetting
wetting
phase) permeability model based on the lower permeability
phase) permeability model based on the lower permeability
boundary condition which is controlled by the ratio of non
boundary condition which is controlled by the ratio of non
-
-
wetting phase (1
wetting phase (1
-
-
Swir
Swir
) to wetting phase (
) to wetting phase (
Swir
Swir
) saturation .
) saturation .
Permeability from NMR
Permeability from NMR
Coates-Timur Model (NMR version):
NMR
NMR
BVI
BVI
BVM
BVM
C
C
k
k
b
b
=
=
a
a
NMR
= 20 pu
2
k
=
BVI
BVI
NMR
4
10
NMR
P
c
(
p
s
i
)
1 10 100 1000 0 20 40 60 80 100
Sw (%)
0
250
100
150
200
50
T
2
(ms)
T
2
Cut-off @ Reference Pc
Capillary Pressure
T2 Spectra
BVI = 4 pu
BVI = 4.3 pu
BVI = 6 pu
BVI = 5 pu
k = (20/10)
4
(16/4)
2
= 256 md
k = (20/10)
4
(15/5)
2
= 144 md
k = (20/10)
4
(14/6)
2
= 87 md
k
absolute
= 256 md
Limitations of Coates
Limitations of Coates
-
-
Timur
Timur
Permeability Model
Permeability Model
Waxman
Waxman
-
-
Smits
Smits
Model:
Model:
Where, F* is the Total Formation Resistivity
Factor, and Q
v
= Total Q
v
Patchett
Patchett
-
-
Herrick Water Saturation Model
Herrick Water Saturation Model
Patchett
Patchett
-
-
Herrick Model:
Herrick Model:
C
t
=
(1 - V
sh
)
C
w
F*
S
w
n*
F*
S
w
+
B Q
v
(V
sh
C
sh
)
+
Where, V
sh
= Laminar Shale Volume, F* is the
Formation Resistivity Factor of the Sand layers,
and Q
v
= Q
v
of Dispersed Shale in Sand Layers
Core
Core
-
-
Calibrated Analyses Results
Calibrated Analyses Results
Permeability &
Resistivity
T
2
Spectra
Rock
Volumetrics
Fluid
Saturations
Porosity
Volumetrics
Highly Laminated Example
Resistivity &
Permeability
Rock
Volume
Fluid
Saturation
Pore
Volume
T
2
Spectra
Original
Perfs
800
BOPD
Added
Perfs
733
BOPD
Acknowledgements:
Baker Atlas
Schlumberger