1

2
MATHEMATICS
01. If a line l passes through (k, 2k), (3k, 3k) and (3, 1), k 0 = , then the distance from the
origin to the line l is
1)
3
5
2)
2
5
3)
1
5
4)
4
5

Key: 3
Hint: Collinear
k 1 3k 1
k
2k 3 3k 3

= =

02. If The image of
7 6
,
5 5
| |
|
\ .
in a line is (1,2), then the equation of the line is
1) 4x y 0 = 2) 3x 4y 1 + = 3) 4x 3y 1 + = 4) 3x y 0 =
Key: 2
Hint: Mid point =
1 2
,
5 5
| |
|
\ .

Equation is
2 3 2
y x
5 4 5
| |
= +
|
\ .

03. The equation of a straight line, perpendicular to 3x 4y 6 = and forming a triangle of
area 6 square units with coordinate axes, is
1) 4x 3y 24 0 + + = 2) 3x 4y 24 + = 3) x 2y 6 = 4) 4x 3y 12 + =
Key: 4
Hint: Perpendicular line is 4x 3y k + =
Area =
2
k
6 k 12
24
= =
04. The point P(1, 3) undergoes the following transformations successively:
(i) Reflection with respect to the line y =x
(ii) Translation through 3 units along the positive direction of the X-axis
(iii) Rotation through an angle of
6
t
about the origin in the clockwise direction.
The final position of the point P is
1)
6 3 1 6 3
,
2 2
| |
+
|
|
\ .
2)
6 3 1 6 3
,
2 2
| |
+
|
|
\ .
3)
6 3 1 3 6
,
2 2
| |
+
|
|
\ .
4)
7 5
,
2 2
| |
|
\ .

Key: 2


3

Hint: ( ) I 3,1
( ) II 6,1

6 3 1 3 6
III ,
2 2
| |
+

|
|
\ .

05. The locus of the centroid of the triangle with vertices at ( ) ( ) a cos , asin , bsin , bcos u u u u
and (1, 0) is (Here u is a parameter)
1) ( )
2
2 2 2
3x 1 9y a b + = + 2) ( )
2
2 2 2
3x 1 9y a b + + =
3) ( )
2
2 2 2
3x 1 9y a b + + = + 4) ( )
2
2 2 2
3x 1 9y a b + =
Key: 1
Hint: a cos bsin 3x 1 u+ u =
a sin bcos 3y u u =
( )
2
2 2 2
3x 1 9y a b + = +
06. If the mean and variance of a binomial variate X are 8 and 4 respectively then
( ) P X 3 < =
1)
16
697
2
2)
16
265
2
3)
15
265
2
4)
16
137
2

Key: 4
Hint: n 16, p 1/ 2, q 1/ 2 = = =
( ) ( ) ( ) ( )
16
137
p x 3 p x 0 p x 1 p x 2
2
< = = + = + = =
07. A random variable X has the probability distribution given below. Its variance is
X 1 2 3 4 5
( ) P X x =
k 2k 3k 2k k
1) 5/ 3 2) 10/ 3 3) 16/ 3 4) 4/ 3
Key: 4
Hint: Variance = ( )
2 2
i i
4
x p x x
3
= =

4
08. A candidate takes three tests in succession and the probability of passing the first
test is p. The probability of passing each succeeding test is p or p/ 2 according as he
passes or fails in the preceding one. The candidate is selected if he passes at least
two tests. The probability that the candidate is selected is
1)
2 3
p p p + + 2) ( )
2
p 1 p 3) ( )
2
p 2 p 4) ( ) p 2 p
Key: 3
Hint: = ( ) ( ) ( ) ( )
2
p p
p.p 1 p p 1 p 1 p p p.p.p p 2 p
2 2
+ + + =
09. A six-faced unbiased die is thrown twice and the sum of the numbers appearing on
the upper face is observed to be 7. The probability that the number 3 has appeared
at least once is
1) 1/ 3 2) 1/ 4 3) 1/ 5 4) 1/ 2
Key: 1
Hint: Sum =7 ( )( )( )( )( )( ) { }
1, 6 6,1 2, 5 5, 2 4, 3 3, 4 6 =
( ) ( )
2
n E 2 P E
6
= =
10. If A, B and C are mutually exclusive and exhaustive events of a random experiment
such that ( ) ( )
3
P B P A
2
= and ( ) ( )
1
P C P B
2
= then ( ) P A C =
1) 6/ 13 2) 7/ 13 3) 10/ 13 4) 3/ 13
Key: 2
Hint: ( ) ( ) ( )
4 3 7
p A C p A p C 0
13 13 13
= + = + =
11. If
1 2 n
x , x ,....., x are n observation such that
n
2
i
i 1
x 400
=
=

and
n
i
i 1
x 80
=
=

then the least value

of n is
1) 15 2) 16 3) 18 4) 12
Key: 3
Hint:
( )
2
2
i i
x x
0
n n
| |
>
|
|
\ .

, by verification n 18 =
12. The mean of four observations is 3. If the sum of the squares of these observations is
48 then their standard deviation is
1) 3 2) 5 3) 7 4) 2


5
Key: 1
Hint:
1 2 3 4
x x x x 12 + + + =
( )
2 48
3 3
4
o = =
13. The shortest distance between the skew lines
( ) ( )
r i 2j 3k t i 3j 2k = + + + + + and
( ) ( )
r 4i 5j 6k t 2i 3j k = + + + + + is
1) 2 3 2) 3 3) 6 4) 3
Key: 2
Hint: S.D =
a c b d
b d
(

14. If x,y,z are non-zero real numbers, a xi 2j, b yj 3k = + = + and c xi yj zk = + + are such that
a b zi 3j k = + then a bc
(
=


1) 9 2) 6 3) 3 4) 10
Key: 1
Hint: a b zi 3j k z 6, x 1, y 1 = + = = =
15. If a , b and c are vectors with magnitudes 2,3 and 4 respectively then the best upper
bound of
2 2 2
a b b c c a + + among the given values is
1) 87 2) 90 3) 93 4) 97
Key: 1
Hint:
( ) ( ) ( )
2
2 2 2
2 a b c 2 a.b b.c c.a & a b c 0 + + + + + + >
16. The angle between the lines
( ) ( )
r 2i 3j k i 4j 3k = + + + + and
( ) ( )
r i j 2k i 2j 3k = + + + is
1)
1
7
cos
84

| |
|
\ .
2)
3
t
3)
2
t
4)
1
9
cos
91

| |
|
\ .

Key: 3
Hint:
1 2 1 2 1 2
a a b b c c 0
2
t
+ + = u =


6
17. If a , b and c are non-coplanar vectors and if d is such that
( )
1
d a b c
x
= + + and
( )
1
a b c d
y
= + + where x and y are non zero real numbers, then
( )
1
a b c d
xy
+ + + =
1) 0 2) 2a 3) 3c 4) a
Key: 1
Hint: a b c xd 0 & ya b c d 0 + + = + + + =
a b c d 0 + + + =
18. Three non-zero non-collinear vectors a, b, c are such that a 3b + is collinear with c ,
while 3b 2c + is collinear with a . Then a 3b 2c + + =
1) 3b 2) 4c 3) 0 4) 2a
Key: 3
Hint: a 3b 2c a + + =
a 3b 2c a 3b c 0 = + =
2 = a 3b 2c 0 + + =
19. If in a triangle ABC,
1 2
r 2, r 3 = = and
3
r 6 = then a =
1) 2 2) 3 3) 4 4) 1
Key: 2
Hint: ( )( )
2
2 3 3 1
a r r r r 9 a 3 = + = =
20. If the angle of a triangle are in the ratio 1: 1: 4 then the ratio of the perimeter of the
triangle to its largest side is
1) 3 2 : 2 + 2) 3 2: 3 + 3) 2 2 : 3 + 4) 3: 2
Key: 2
Hint:
0 0
A: B: C 1:1: 4 A B 30 , C 120 = = = =

1 1 3 3
a b c: c 2R : 2R.
2 2 2 2
| |
+ + = + +
|
|
\ .

21. In any
( )( )( )( )
2 2
a b c b c a c a b a b c
ABC,
4b c
+ + + + +
A =
1)
2
cos B 2)
2
sin A 3)
2
sin B 4)
2
cos A
Key: 2


7
Hint:
2
2
2 2
16
sin A
4b c
A
=
22.
1 1
1 3
sec h cosech
2 4

| | | |
=
| |
\ . \ .

1)
e
2 3
log
3
| |
+
|
|
\ .
2)
e
2 3
log
3
| |

|
|
\ .
3)
( ) ( ) e
log 3 2 3 + 4)
e
1 3
log
3
| |
+
|
|
\ .

Key: 1
Hint: Formulae
23. If x 0, y 0, z 0, xy yz zx 1 > > > + + < and if
1 1 1
tan x tan y tan z

+ + = tthen x y z + + =
1) 3xyz 2) xyz 3) 0 4) xyz
Key: 4
Hint: tanA tan A x y z xyz = t + + =

24. The sum of the solutions in ( ) 0, 2t of the equation
1
cos x cos x cos x
3 3 4
t t | | | |
+ =
| |
\ . \ .
is
1) 2t 2) 3t 3) 4t 4) t
Key: 1
Hint: cos3 1 u = , solutions are
2 4
, , sum 2
3 3
t t
= t
25. If x and y are acute angles such that cos x cos y 2 / 3 + = and sin x sin y 3 / 4 + = then
( ) sin x y + =
1) 3/ 5 2) 4/ 5 3) 2/ 5 4) 3/ 4
Key: 2
Hint: Use transformations and find
x y
tan
2
+ | |
|
\ .

Use the formulae ( )
2
x y x y
sin x y 2tan / 1 tan
2 2
+ + | | | |
+ = +
| |
\ . \ .

26.
0 0 0 0
tan81 tan 63 tan 27 tan 9 + =
1) 2 2) 4 3) 6 4) 0
Key: 2
Hint: Use formulae tan cot 2cosec2 u+ u = u


8
27. If R is the set of all real numbers and if { } f : R 2 R is defined by ( )
2 x
f x
2 x
+
=

for
{ } x R 2 e , then the range of f is
1) { } R 1 2) { } R 1 3) { } R 2 4) R
Key: 2
Hint: Let
( ) 2 y 1 2 x
y x
2 x y 1
+
= =
+
{ } R 1
28. Let Q be the set of all rational numbers in [0, 1] and | | | | f : 0,1 0,1 be defined by
( )
x for x Q
f x
1 x for x Q
e
=

e

Then the set | | ( )( ) { }

S x 0,1 : f 0f x x = e = is equal to
1) | | 0,1 Q 2) ( ) 0,1 3) | | 0,1 4) Q
Key: 3
Hint: ( )
x if xis rational
fof x
x if xis irrational

( ) fof x x = is possible for all values in [0,1]
29. ( )
2n 1
k 1
2
k 1
1 .k
+

=
=

1) ( )( ) n 1 2n 1 + 2) ( )( ) n 1 2n 1 + 3) ( )( ) n 1 2n 1 4) ( )( ) n 1 2n 1 + +
Key: 4
Hint: By verification ( ) n 1 or 3 =
30. If a,b,c and d are real numbers such that
2 2 2 2
a b c d 1 + + + = and if
a ib c id
A
c id a ib
+ + (
=
(
+


then
1
A

=
1)
a ib c id
c id a ib
(
(
+

2)
a ib c id
c id a ib
+ + (
(


3)
a ib c id
c id a ib
+ (
(


4)
a ib c id
c id a ib
+ (
(
+ +


Key: 1
Hint:
1
2 2 2 2
a ib c id
1
A
c id a ib a b c d

(
=
(
+ + + +




9
31. If the matrix
1 2 3 0
2 4 3 2
A
3 2 1 3
6 8 7
(
(
(
=
(
(
o

is of rank 3, then o =
1) 4 2) 1 3) 5 4) 5
Key: 3
Hint: By making det is equal to zero, 5 o =
32. If k 1 > , and the determinant of the matrix
2
A , where
k k
A 0 k
0 0 k
o o (
(
= o o
(
(

, is
2
k then o =
1)
2
k 2)
1
k
3)
2
1
k
4) k
Key: 2
Hint:
( )
2 2 4 2
A k det A k . = o = o

4 2 2
1
k . k
k
o = o =
33. The number of solutions for
3
z z 0 + = is
1) 2 2) 3 3) 5 4) 1
Key: 3
Hint: Put z x iy = +
No. of Solutions =5
34. The least positive integer n for which ( ) ( )
n n
1 i 1 i + = holds is
1) 4 2) 6 3) 8 4) 2
Key: 1
Hint:
n
1 i
1 n 4
1 i
+ | |
= =
|

\ .

35. If
2
x p q, y pw qw = + = + and
2
z pw qw = + where w is a complex cube root of unity then
xyz =
1)
3 3
1 p q + + 2)
3 3
p q 3)
3 3
p q + 4)
2 2
p pq q +
Key: 3


10
Hint: ( )( )( )
2 2 3 3
xyz p q pw qw pw pw p q = + + + = +
36. If
r r r
Z cos i sin
2 2
t t | | | |
= +
| |
\ . \ .
for r 1, 2, 3,..... = then
1 2 3
Z Z Z ...... =
1) 2 2) 1 3) 2 4) 1
Key: 2
Hint:
2
i
i 2 2
1 2 3
Z Z Z ...... e e 1
t t | |
+ +
|
t
\ .
= = =
37. If
1
x and
2
x are the real roots of the equation
2
x kx c 0 + = then the distance between
the points ( )
1
A x , 0 and ( )
2
B x , 0 is
1)
2
c k 2)
2
k 4c 3)
2
k 4c + 4)
2
k c
Key: 2
Hint:
2
1 2
AB x x k 4c = =
38. If x is real, then the minimum value of
2
2
x x 1
y
x x 1
+
=
+ +
is
1) 1/ 2 2) 2 3) 3 4) 1/ 3
Key: 4
Hint: Put x 1 = , minimum value =1/ 3
39. If p and q are distinct prime numbers and if the equation
2
x px q 0 + = has positive
integers as its roots then the roots of the equation are
1) 1, 2 2) 3, 1 3) 1, 1 4) 2, 3
Key: 1
Hint: If 1, 2 o = | = Then equation is
2
x 3x 2 0 + =
Where p 3, q 2 = = are district primes
40. The cubic equation whose roots are the squares of the roots of
3 2
x 2x 10x 8 0 + = is
1)
3 2
x 16x 68x 64 0 + = 2)
3 2
x 16x 68x 64 0 + =
3)
3 2
x 16x 68x 64 0 + + = 4)
3 2
x 8x 68x 64 0 + + =
Key: 3
Hint:
( )
f x 0 =



11

41. Out of thirty points in a plane, eight of them are collinear. The number of straight
lines that can be formed by joining these points is
1) 408 2) 348 3) 296 4) 540
Key: 1
Hint :
30 8
2 2
1 C C +
42. If n is an integer with 0 11 n s s then the minimum value of ( ) ! 11 ! n n is attained when
a value of n =
1) 7 2) 9 3) 11 4) 5
Key : 4
Hint : 5 n =
43. If ( )
3 1 1
....
27 3
a bx x

+ = + + then the ordered pair ( ) , a b =

1) ( ) 3, 9 2) ( ) 3, 9 3) ( ) 3, 27 4)
1
1,
3
| |
|
\ .

Key: 2
Hint:
( )
3
3
3
1
bx
a bx a
a

+ = +
`
)


( )( )
2
3
3 4 3
1 ....
2!
bx bx
a
a a

| |
= + +
` |
\ .

)

44. The term independent of x in the expansion of
18
2
x
x
| |

|
\ .
is
1)
6
18
2
6
| |
|
\ .
2)
8
18
2
6
| |
|
\ .
3)
9
18
2
9
| |

|
\ .
4)
12
18
2
9
| |
|
\ .

Key : 3
Hint :
( )
18
18
1
2
r
r
r r
T C x
x

+
| |
=
|
\ .


18 2
0 9
2
r
r

= =
45. ( )
3 2
4 2 2
2 5 1
, ,
25 5 5
x x Ax B Cx
A B C
x x x
+ + +
= + =
+

1) ( ) 1, 0,1 2) ( ) 1, 2,1 3) ( ) 1,1,1 4) ( ) 1,1, 0

Key : 1
Hint :
0
2
1
A B
A B
A B
=
+ =
= =
1 1 B + = 0 B =




12

46. If cos tan , cot tan x y y z = = and cot tan z x = ; then sin x =
1)
5 1
2
+
2)
5 1
2

3)
5 1
4
+
4)
5 1
4

Key : 2
Hint :
Cosx Tanx =

sin
cos
cos
x
x
x
=
5 1
sin
2
x

=

2
cos sin 0 x x =

2
1 sin sin 0 x x =
47. The solution of ( ) cos sin 1 0
dy
y x y
dx
+ = is
1) tan sec y y cx + = 2) sec tan x y y c + =
3) sec tan x y y c = + 4) tan sec y y cx =

Key : 3
Hint:
cos sin 1
sin 1 cos
dy y dx x y
dx x y dy y

= =


tan sec x y y = +
Use linear differential equation
48. The solution of
/ y x
dy
x y xe
dx
= + with ( ) 1 0 y = is
1)
/
2log 1
y x
e x

+ = 2)
/
log 1
y x
e x

+ =
3)
/
log 1
y x
e x + = 4)
/
log
y x
e x

=

Key : 2
Hint:
y
V
x
=
49. The differential equation of the family of parabolas with vertex at ( ) 0, 1 and having
axis along the y-axis is
1) ' 2 2 0 xy y = 2) ' 1 0 xy y = 3) ' 2 1 0 yy xy + + = 4) ' 1 0 xy y + + =

Key : 1
Hint:
( )
2
4 1 x a y = + eliminate a, by taking one time differentiation
50. The area (in square units) of the region bounded by
2
1, 2, 1 x x y x = = = + and 2 2 y x =
is
1) 8 2) 9 3) 10 4) 7
Key: 2
Hint: ( ) ( )
2
2
1
2 2 1 A x x dx

= +
}
=9



13
51.
/6
4 2
0
cos 3 .sin 6 d
t
u u u =
}

1)
5
256
t
2)
5
192
t
3)
96
t
4)
5
192

Key : 2
Hint:
/ 6
4 2 2
0
cos 3 4sin 3 cos 3
t
u u u
}
let 3 t u =

/ 2
2 6
0
5
4 sin cos
192
t t dt
t
t
=
}

52. By the definition of the definite integral, the value of
4 4 4 4
5 5 5 5 5 5 5 5
1 2 3
lim ....
1 2 3
n
n
n n n n n

| |
+ + + +
|
+ + + +
\ .
is
1)
1
log 2
4

1
log 2
3
3) log 2 4)
1
log 2
5

Key : 4
Hint:
4
5 5
1
n
n
r
r
Lt
r n

=
+

1 n =
r x =

1 4
5
0
1
log 2
1 5
x dx
x
=
+
}

53. If
( )
( ) ( )
2
2
1
2
2
1
1
tan
1 1
x
x x
dx A c
x
x x x x

| |
+ +
= + |
|
+ + +
\ .
}
, in which c is a constant then A =
1) 2 2) 1 3)
1
2
4) 3
Key : 1
Hint: Let
2
1
1 x t
x
+ + =
( )
1
2
2 2tan
1
dt
t c
t

= +
+
}

54. For any integer 2 n > , let tan
n
n
I x dx =
}
. If
1
2
1
tan
n
n n
I x bI
a

= for 2 n > , then the ordered

pair ( ) , a b =
1) ( ) ,1 n 2) ( ) 1,1 n 3)
1
1,
2
n
n
n
| |

\ .
4)
2
1,
1
n
n
n
| |

\ .

Key : 2


14
Hint.
1
2
1
n
n n
Tan x
I I
n

+ =

55. If
( )
2
1 1
1
dx A x B
C
x x
x x x
= + +

+
}
, where C is a real constant then A B + =
1) 1 2) 2 3) 3 4) 0
Key : 4
Hint. Let
2
x t =

( ) ( )
2 4 2
2 2
1 1 1
tdt dt
t t t t t
=
+ +
} }


1
1
4
t + =
56. ( ) ( )
3
sin cos
dx
g x c g x
x x
= + =
}

1)
2
cot x
2)
2
tan x
3)
2
cot x

4)
2
tan x

Key : 4
Hint.
2
2
cos
cot
cot
ec x dx
x t
x
=
}

57. The value of c in the Lagranges mean-value theorem for ( ) 2 f x x = in the interval
| | 2, 6 is
1) 3 2) 4 3)
9
2
4)
5
2

Key : 1
Hint.
( )
( ) ( )
'
f b f a
f c
b a

3 c =
58. If there is an error of 0.04 cm in the measurement of the diameter of a sphere then
the approximate percentage error in its volume, when the radius is 10 cm, is
1) 0.006 2) 0.6 3) 1.2 4) 0.06

Key : 2
Hint.
3
4
3
V r t =

2
4 V r r o t o =

4
100 100
V r
V r
o o
=
r=0.02
r=10



15
59. The condition that ( )
3 2
f x ax bx cx d = + + + has no extreme value is
1)
2
3 b ac = 2)
2
3 b ac < 3)
2
3 b ac > 4)
2
4 b ac =

Key : 2
Hint.
( ) ' 0 f x =
0 A <
60. If the curves
2 2
2 2
1
x y
a b
+ = and
2 2
1
25 16
x y
+ = cut each other orthogonally, then
2 2
a b =
1) 75 2) 41 3) 9 4) 400
Key : 3
Hint.
2 2
25 16 9 a b = =
61. If ( )
1
x
f x
x
=
+
and ( ) ( ) ( )
g x f f x = then ( ) ' g x =
1)
2
1
x
2)
( )
2
1
2 1 x +
3)
( )
2
1
2 3 x +
4)
( )
2
1
1 x +

Key : 2
Hint.
( ) ( ) ( )
g x f f x =

2 1
x
x
=
+

62.
( )
2 2
1 2 2 2
1 1
tan 1 '' 2 '
a x
y a x y a xy
ax

| |
+
= + + = |
|
\ .

1)
2
2a 2) 0 3)
2
2a 4)
2
a

Key : 2
Hint.
ax Tanu =
63. If ( )
1
tan f x x x

= then
( ) ( )
1
1
lim
1
x
f x f
x

1)
1
4
t +
2)
2
4
t +
3)
3
4
t +
4)
4
t

Key : 2
Hint.
1
1
tan
0
4
1 0
x
x x
Lt
x
t

| |
|

\ .

L.H. rule


16
64. If | | : 2, 2 f R is defined by
( )
1 1
2 0
3
0 2
1
cx cx
for x
x
f x
x
for x
x

+
s <

s s

+
is continuous on
| | 2, 2 , then c =
1)
3
2
2)
3
2
3)
2
3
4) 3
Key : 4
Hint. ( ) ( )
0 0 x x
Lt f x Lt f x
+

=
3 c =
65.
2 2
0
1 1
lim
3 1
x
x
x x x

+ +
=

1)
1
log9
2) log3 3)
1
log3
4) log9

Key : 1
Hint. Rationalize and use L.H rule.

66. If ( ) ( ) ( ) ( ) 3, 4, 5 , 4, 6, 3 , 1, 2, 4 & 1, 0, 5 A B C D are such that the angle between the lines
& DC AB is u then cosu =
1)
4
9
2)
5
9
3)
7
9
4)
2
9

Key : 1
Hint.
( ) 2, 2, 1 DC =
( ) 1, 2, 2 AB =

1 2 1 2 1 2
2 2 2 2 2 2
1 1 1 2 2 2
cos
a a bb c c
a b c a b c
u
+ +
=
+ + + +

67. If the direction cosines of two lines are given by 0 l m n + + = and
2 2 2
5 0 l m n + = then
the angle between them is
1)
4
t
2)
3
t
3)
2
t
4)
6
t

Key : 2
Hint.
( ) 1 l m n =
( )
2 2 2
5 0 2 l m n + =
Solve
1
cos
2
u =

3
t
u =


17
68. If the line joining ( ) 1, 3, 4 A and B is divided by the point ( ) 2, 3,5 in the ratio 1: 3 , then
B is
1) ( ) 8,12, 20 2) ( ) 13, 6, 13 3) ( ) 11, 3,8 4) ( ) 11, 3, 8

Key : 3
Hint. Let P divides A,B in 1 : 3

4 3 0 P B A =
4 3 B P A = +
69. A hyperbola passes through a focus of the ellipse
2 2
1
169 25
x y
+ = . Its transverse and
conjugate axes coincide respectively with the major and minor axes of the ellipse.
The product of eccentricities is 1. Then the equation of the hyperbola is
1)
2 2
1
144 25
x y
= 2)
2 2
1
25 9
x y
= 3)
2 2
1
144 9
x y
= 4)
2 2
1
169 25
x y
=

Key : 1
Hint.
1
169 25 12
169 13
e

= =

2
144 25 13
144 12
e
+
= =

1 2
1 e e =
70. An ellipse passing through
( )
4 2, 2 6 has foci at ( ) ( ) 4, 0 & 4, 0 . Its eccentricity is
1)
1
2
2)
1
3
3) 2 4)
1
2

Key : 4
Hint.
' 2 SS ae =
2 8 ae =
4 ae =

( )
2 2
2 2 2
1
1
x y
a a e
+ =

( )
( )
, 4 2, 2 6 x y =
8 a =
1
2
e =




18
71. If tangents are drawn from any point on the circle
2 2
25 x y + = to the ellipse
2 2
1
16 9
x y
+ =
then the angle between the tangents is
1)
3
t
2)
2
t
3) 2
3
t
4)
4
t

Key : 2
Hint. Circle is director circle

72. The slopes of the focal chords of the parabola
2
32 y x = which are tangents to the
circle
2 2
4 x y + = are
1)
1 1
,
15 15

2)
2 2
,
5 5

3)
1 1
,
2 2

4)
1 1
,
3 3

Key : 1
Hint.
2
2 1 y mx m = + +
( )
2
8, 0 15 1 m =

1
15
m =
73. If a normal chord at a point t on the parabola
2
4 y ax = subtends a right angle at the
vertex, then t=
1) 2 2) 3 3) 1 4) 2
Key : 4
Hint.
2
2 2 t t = =
74. The locus of the centre of the circle which cuts the circle
2 2
20 4 0 x y x + + =
orthogonally and touches the line 2 x = is
1)
2
16 y x = 2)
2
4 x y = 3)
2
16 x y = 4)
2
4 y x =
Key : 1
Hint. Let
1
2 ' ' gg ff c c ( + = +


Let r =d
75. The length of the common chord of the two circles
2 2
4 0 x y y + = and
2 2
8 4 11 0 x y x y + + = is
1) 135 2)
135
4
3)
145
4
4)
11
2

Key : 2
Hint. Chord is 8 4 0 x =
Length
2 2
2 r d =


19
76. The condition for the lines 0 lx my n + + = and
1 1 1
0 l x m y n + + = to be conjugate with
respect to the circle
2 2 2
x y r + = is
1) ( )
2
1 1 1
0 r ll mm nn + + = 2) ( )
2
1 1 1
r lm l m nn + =
3) ( )
2
1 1 1
r ll mm nn + = 4) ( )
2
1 1 1
r ll mm nn =
Key : 3
Hint. ( )
2
1 1 1
r ll mm nn + =
77. The point at which the circles
2 2
4 4 7 0 x y x y + + = and
2 2
12 10 45 0 x y x y + + = touch
each other is
1)
14 13
,
5 5
| |
|
\ .
2)
12 21
, 2
5 5
| |
+
|
|
\ .
3)
13 14
,
5 5
| |
|
\ .
4)
2 5
,
5 6
| |
|
\ .

Key : 1
Hint. Common tangent 4 3 19 0 x y + =
By verification
14 13
,
5 5
| |
|
\ .

78. A circle with centre at ( ) 2, 4 is such that the line 2 0 x y + + = cuts a chord of length 6.
The radius of the circle is
1) 21 2) 31 3) 41 4) 11
Key : 3
Hint. 4 2 d =

2 2
2 6 r d =
41 r =
79. If
2 2 2
2 x y y a o | + + = represents a pair of perpendicular lines, then | =
1) 2a 2) 3a 3) 4a 4) a
Key : 4
Hint. 1 o =
0 | o A = =
80. The area (in square units) of the triangle formed by the lines
2 2
3 0 x xy y + = and
1 0 x y + + =
1) 5 2 2)
1
2 5
3)
2
3
4)
3
2

Key : 2
Hint.
2 2
2 2
2
n h ab
am hlm bl

A =
+



20

PHYSICS
81. A wheel which is initially at rest is subjected to a constant angular acceleration about its axis.
It rotates through an angle of
0
15 in time t secs. The increase in angle through which it rotates
in the next 2t secs is
1)
0
30 2)
0
45 3)
0
90 4)
0
120

KEY:- 4
HINT:-
Conceptual

82. A thin wire of length l having linear density is bent into a circular loop with C as its centre,
as shown in figure. The moment of inertia of the loop about the line AB is


1)
3
2
8
l
t
2)
3
2
3
8
l
t
3)
3
2
5
16
l
t
4)
3
2
16
l
t

KEY:- 2
HINT:-
| |
2 2 3
2
2
3 3
2 ,
2 2 8
mr mr l
I mr l r m l

t
t
= + = = = =


83. The ratio between kinetic and potential energies of a body executing simple harmonic motion,
when it is at a distance of
1
N
of its amplitude from the mean position is
1)
2
N 2)
2
1 N 3)
2
1 N + 4)
2
1
N

KEY: 2
HINT:
( )
2
2 2 2 2
2
2
2
2 2
2
1
2
, 1
1
2
A
A m A y
A KE
N
y N
A N PE
m y
N
e
e

= = = =


84. A satellite is revolving very close to a planet of density . The period of revolution of satellite
is
1)
3
G
t

2)
3 G t

3)
3
G
t
4)
3
2 G
t

KEY: 1
HINT:
( )
3
2
2 3
2 3
; 2 ;
GMm GM R
mR T M V
R R GM G
t t
e e t
e
= = = = = =




21
85. Two wires of the same material and length but diameters in the ratio 1: 2 are stretched by the
same force. The elastic potential energy per unit volume for the two wires when stretched by
the same force will be in the ratio
1) 2:1 2) 4:1 3) 16:1 4) 1:1

KEY: 3
HINT:

4
1 2
4
2 1
1
16:1
U r
U
r U r
| |
= =
|
\ .


86. When a big drop of water is formed from n small drops of water, the energy loss is 3E, where E
is the energy of the bigger drop. If R is the radius of the bigger drop and r is the radius of the
smaller drop, then number of smaller drops (n) is
1)
2
2R
r
2)
2
2
4R
r
3)
2
4R
r
4)
4R
r

KEY: 2

HINT:
2 2
4 , 4
b s
E T R E n T r t t = =


2
2
4
3
b s b
R
E E E n
r
= =
87. A steam at
0
100 C is passed into 1kg of water contained in a calorimeter of water equivalent
0.2kg at 9
O
C , till the temperature of the calorimeter and water in it is increased to 90
O
C . The
mass of steam condensed in kg is nearly (sp. heat of water =1cal/ g-
o
C, Latent heat of
vaporization =540 cal/ g)
1) 0.27 2) 0.54 3) 0.81 4) 0.18

KEY: 4

HINT: Heat lost by steam =Heat gained by calorimeter and water

( ) ( ) ( )
| |
st
c w
m L m s t ms t ms t + A = A + A
88. A very small hole in an electric furnace is used for heating metals. The hole nearly acts as a
black body. The area of the hole is 200mm
2
. To keep a metal at 727
o
C, heat energy flowing
through this hole per sec, in joules is
( )
8 2 4
5.67 10 Wm k o

=
1) 1.134 2) 11.34 3) 22.68 4) 2.268


KEY: 2

HINT: ( )
4
4 8 6 7
5.67 10 200 10 1000 11.34 10 E AT t o

= = =



22
89. Five moles of Hydrogen initially at STP is compressed adiabatically so that its temperature
becomes 673K. The increase in internal energy of the gas, in Kilo J oules is
( ) 8.3 / ; 1.4for diatomicgas R J mole K = =
1) 41.50 2) 65.55 3) 80.5 4) 21.55


KEY: 1

HINT: | |
1 2
1
nR
W T T

90. The volume of one mole of the gas is changed from V to 2V at constant pressure P. if is the
ratio of specific heats of the gas, change in internal energy of the gas is
1) PV 2)
1
PV

3)
.
1
r PV

4)
1
R



KEY: 2

HINT:

1
V
PV
dU nC dT

= =

91. A closed pipe is suddenly opened and changed to an open pipe of same length. The
fundamental frequency of the resulting open pipe is less than that of 3
rd
harmonic of the
earlier closed pipe by 55Hz. Then, the value of fundamental frequency of the closed pipe is
1) 55Hz 2) 220Hz 3) 165Hz 4) 110Hz


KEY: 1

HINT:
0
5
55
2 4
c
V V
l l
= and
4
V
n
l
=

92. A convex lens has its radii of curvature equal. The focal length of the lens is f. If it is divided
vertically into two identical plano-convex lenses by cutting it, then the focal length of the
plano-convex lens is
( =the refractive index of the material of the lens)
1) 2f 2) ( ) 1 f 3) f 4)
2
f


KEY: 1

HINT: Conceptual

93. A thin converging lens of focal length f=25cm forms the image of an object on a screen placed
at a distance of 75cm from the lens. The screen is moved closer to the lens by a distance of
25cm. The distance through which the object has to be shifted so that its image on the screen
is sharp again is
1) 12.5cm 2) 13.5cm 3) 37.5cm 4) 16.25cm

KEY: 1

HINT:
1 1 1
f u v
= +



23
94. In a double slit interference experiment, the fringe width obtained with a light of wavelength
0
5900A was 1.2mm for parallel narrow slits placed 2mm apart. In this arrangement, if the slit
separation is increased by one-half times the previous value, then the fringe width is
1) 1.8mm 2) 1.6mm 3) 0.9mm 4) 0.8mm


KEY: 4

HINT:
|
|
| |
1 1
, ;
d
d d d
|
| |
|
=

95. A charge Q is divided into two charges q and Q q . The value of q such that the force between
them is maximum, is
1)
2
Q
2)
3
Q
3) Q 4)
3
4
Q



KEY: 1


HINT:
1 2
, ; 0
2
dF Q
q q q Q q q
dq
= = = =

96. Two concentric hallow spherical shells have radii r and R (R>>r). A charge Q is distributed on
them such that the surface charge densities are equal. The electric potential at the centre is
1)
Q
R r +
2) 0 3)
( )
( )
2 2
0
4
Q R r
R r tc
+
+
4)
( )
( )
2 2
0
4
Q R r
R r tc
+
+

KEY: 3
HINT: conceputal

97. Wires A and B have resistivities
A
and
B
, ( ) 2
B A
= and have lengths
A B
l and l . If the
diameter of the wire B is twice that of A and the two wires have same resistances, then
B
A
l
l
is
1)
1
2
2)
1
4
3) 2 4) 1

KEY: 3

HINT:
l
R
A

= ;
2
1 1 1 2
2
2 2 2 1
R l r
R l r

=
98. In the circuit shown, the heat produced in 5 ohms resistance due to current through it is
50J / s. Then the heat generated / second in 2 ohms resistance is

1) 9 J / s 2) 10 J / s 3) 5 J / s 4) 4 J / s


24
KEY: 3
HINT:
2
2
Q i Rt = ;
2
V i R = ;
1 2
: 2 : 8 1: 4 V V = =

99. A steady current flows in a long wire. It is bent into a circular loop of one turn and the
magnetic field at the centre of the coil is B. If the same wire is bent into a circular loop of n
turns, the magnetic field at the centre of the coil is
1)
2
nB 2)
2
n B 3)
B
n
4) Nb
KEY: 2
HINT:
| 2
B n B


100. An electrically charged particle enters into a uniform magnetic induction field in a direction
perpendicular to the field with a velocity V. Then, it travels
1) in a circular path with a radius directly proportional to V
2

2) in a circular path with a radius directly proportional to its velocity
3) in a straight line without acceleration
4) with force in the direction of the field
KEY: 2
HINT: r v
101. At a certain place, the angle of dip is 60
o
and horizontal component of earths magnetic field
(BH) is
4
0.8 10 T

. The earths overall magnetic field is

1)
3
1.5 10 T

2)
4
1.6 10 T

3)
4
1.5 10 T

4)
3
1.6 10 T

KEY: 2

HINT:
cos
H
B B u =


102. Match the following (Take the relative strength of the strongest fundamental forces in nature
as one)
A B
Fundamental forces in nature Relative strength
(a) Strong nuclear force (e)
2
10

(b) Weak nuclear force (f) 1
(c ) Electromagnetic force (g) 10
10

(d) Gravitational force (h)
13
10

(i)
39
10

The correct match is :
1) (a) (f), (b)-(h), (c)-(e), (d)-(i) 2) (a)-(f), (b)-(e), (c)-(h), (d)-(i)
3) (a)-(f), (b)-(i), (c)-(e), (d)-(h) 4) (a)-(f), (b)-(h), (c)-(e), (d)-(h)
KEY: 2
HINT: conceptual
103. If C the velocity of light, h Plancks constant and G gravitational constant are taken as
fundamental quantities, then the dimensional formula of mass is
1)
1/ 2 1/ 2 1/ 2
h C G

2)
1/ 2 1/ 2 1/ 2
h C G

3)
1/ 2 1/ 2 0
h G C

4)
1/ 2 1/ 2 1/ 2
h C G

KEY: 4

HINT:
a b c
m C h G ;
( ) ( ) ( )
1 2 1 1 3 2
; ; C LT h ML T G M LT




25
104. A person walks along a straight road from his house to a market 2.5kms away with a speed of
5km/ hr and instantly turns back and reaches his house with a speed of 7.5km/ hr. The
average speed of the person during the time interval 0 to 50 minutes is (in m/ sec)
1)
5
6
2)
1
3
3)
2
4
3
4)
5
3


KEY: 4

HINT:
Total distance
Total time
avg
V =

105. Velocity(v) versus displacement(x) plot of a body moving along a straight line is as shown in
the graph. The corresponding plot of acceleration (a) as a function of displacement (x) is

1) 2)



3) 4)


KEY: 1
HINT: conceptual


106. The path of a projectile is given by the equation
2
y ax bx = , where a and b are constants and
x and y are respectively horizontal and vertical distances of projectile from the point of
projection. The maximum height attained by the projectile and the angle of projection are
respectively.
1) ( )
2
1
, tan 2
a
b
b

2) ( )
2
1
, tan
4
a
a
b

3) ( )
2
1
2
, tan
a
a
b

4) ( )
2
1
, tan
2
b
b
a

KEY: 2



26
HINT:
tan a u =
107. A body is projected at an angle u so that its range is maximum. If T is the time of flight then
the value of maximum range is (acceleration due to gravity =g)
1)
2
2
gT
2)
2 2
2
g T
3)
2
2
g T
4)
2
gT


KEY: 1

HINT:
0
45 u = ,
2 sin U
T
g
u
= ,
2
U
R
g
=

108. A mass M kg is suspended by a weightless string. The horizontal force required to hold the
mass at 60
o
with the vertical is
1)
( )
3 1 Mg + 2)
3
Mg
3) Mg 4) 3 Mg


KEY: 4

HINT:
tan F mg u =

109. The force required to move a body up a rough inclined plane is double the force required to
prevent the body from sliding down the plane. The coefficient of friction when the angle of
inclination of the plane is 60
o
is
1)
1
3
2)
1
2
3)
1
3
4)
1
2


KEY: 1

HINT:
( ) ( ) sin cos 2 sin cos mg mg u u u u + =
110. A cannon shell fired breaks into two equal parts at its highest point. One part retraces the
path to the cannon with kinetic energy
1
E and kinetic energy of the second part is
2
E .
Relation between
1 2
E and E is
1)
2 1
4 E E = 2)
2 1
9 E E = 3)
2 1
15 E E = 4)
2 1
E E =


KEY: 2

HINT: conceptual
111. A bus moving on a level road with a velocity V can be stopped at a distance of x, by the
application of a retarding force F. The load on the bus is increased by 25% by boarding the
passengers. Now, if the bus is moving with the same speed and if the same retarding force is
applied, the distance travelled by the bus before it stops is,
1) 5x 2) 2.5x 3) 1.25x 4) x
KEY: 3
HINT: conceptual

112. A T.V. transmitting antenna is 128m tall. If the receiving antenna is at the ground level, the
maximum distance between them for satisfactory communication in L.O.S. mode is, (Radius of
the earth
6
6.4 10 m = )
1) 128 10 km 2)
64
10
km 3) 64 10 km 4)
128
10
km



27

KEY: 4

HINT:
2
T
d Rh =
113. The output characteristics of an n-p-n transistor represent, [IC=collector current, VCE =
potential difference between collector and emitter, IB=Base current, VBB=voltage given to base;
VBE=the potential difference between base and emitter]
1) changes in IB with changes in VCE
2) change in IC as VBE is changed
3) change in IC as IB and VBB are changed
4) changes in IC with changes in VCE (IB=constant)
KEY: 4
HINT: conceptual
114. A crystal of intrinsic silicon at room temperature has a carrier concentration of
16 3
1.6 10 / m .
If the donor concentration level is
20 3
4.8 10 / m , then the concentration of holes in the
semiconductor is
1)
12 3
4 10 / m 2)
11 3
5.3 10 / m 3)
12 3
53 10 / m 4)
11 3
4 10 / m



KEY: 2

HINT: E h e
o o o =
115. If the radius of a nucleus with mass number 125 is 1.5 Fermi, then radius of a nucleus with
mass number 64 is
1) 1.92Fermi 2) 1.2 Fermi 3) 0.48 Fermi 4) 0.96 Fermi
KEY: 2
HINT:
1
3
r A
116. The radius of the first orbit of hydrogen is
H
r , and the energy in the ground state is 13.6eV .
Considering a

particle with a mass 207 me revolving round a proton as in Hydrogen

atom, the energy and radius of proton and

combination respectively in the first orbit are

(assume nucleus to be stationary)
1)
13.6
,
207 207
H
r
eV

2)
13.6
, 207
207
H
eV r

3) 13.6 207 ,
207
H
r
eV 4) 207 13.6 , 207
H
eV r


KEY: 3

HINT:
conceptual
117. The energy of a photon is equal to the kinetic energy of a proton. If
1
is the de Broglie
wavelength of a proton,
2
the wavelength associated with the photon, and if the energy of the
photon is E, then ( )
1 2
/ is proportional to
1)
2
E 2) E 3)
4
E 4)
1/ 2
E


KEY: 4

HINT: 1 2
;
2
h hc
E ME
= =


28
118. The electric field for an electromagnetic wave in free space is
( )
8
30cos 5 10 E i kz t =

where
magnitude of E is in V/ m. The magnitude of wave vector, k is (velocity of em wave in free
space
8
3 10 / m s = )
1)
1
1.66 rad m

2)
1
0.83 rad m

3)
1
0.46 rad m

4)
1
3 rad m

KEY: 1

HINT:
v
k
e
=
119. A capacitor 50 F is connected to a power source V=220sin50t (V in volt, t in second). The
value of rms current (in Amperes)
1) 2 2)
( ) 0.55
2
A 3)
2
0.55
A 4) 0.55A
KEY: 2
HINT:
0
2
rms
i
i =
120. A coil of wire of radius r has 600 turns and a self inductance of 108mH. The self inductance of
a coil with same radius and 500 turns is
1) 108mH 2) 90mH 3) 80mH 4) 75mH
KEY: 4
HINT: L N

CHEMISTRY
121. In are reaction , A B C D + +

40% of B has reacted at equilibrium, when 1 mol of A was

heated with 1 mol of B in a 10 litre closed vessel. The value of
C
K is
1.0.22 2.0.36 3.0.44 4.0.18
Key:- 3
Hints:- 121.
( )( )
( )( )
( )( )
( )( )
0.4 0.4
0.6 0.6
c
C D
K
A B
= = =
122. If the ionic product of ( )
2
Ni OH is
15
1.9 10

, the molar solubility of ( )

2
Ni OH in 1.0 M NaOH is
1.
15
1.9 10 M

2.
14
1.9 10 M

3.
18
1.9 10 M

4.
13
1.9 10 M

Key:- 1
Hints :-
( )( ) ( )
2
2
2
1
SP
K Ni OH S
+
= =
123. Temporary hardness of water is removed in Clarks process by adding
1.Borax 2.Lime 3.Caustic Soda 4.Calgon
Key:- 2
Hints:- Conceptual


29
124.
2
KO exhibits paramagnetic behavior. This is due to the paramagnetic nature of
1.
2
O 2.
2
O

3. KO

4. K
+

Key:- 2
Hints:- Conceptual
125. Which one of the following correctly represents the variation of electro negativity (EN) with
atomic number (Z) of group 13 elements?
1. 2.
3. 4.
Key:- 2
Hints:- Conceptual
126. Which one of the following elements reacts with steam?
1.Si 2.Sn 3.C 4.Ge
Key :- 2
Hints:- Conceptual
127. What are X and Y in the following reaction?

2 2
uv
CF Cl X Y +
1.
2
, CFCl F 2.
2 2
: , CCl F 3.
2
, CF Cl Cl
- -
4.
2 4 2
, C F Cl
Key:- 3
Hints:- Conceptual
128. What are the shapes of ethyne and methane?
1.linear and tetrahedral 2.trigonal planar and linear
3.square planar and linear 4. tetrahedral and trigonal planar
Key:- 1
Hints:- Conceptual


30
129. What is Z in the following reaction?

/
3 2 2
NaOH CaO
CH CH CO Na Z
O
A

1.ethane 2.ethyne 3.propane 3.n-butane
Key :- 1
Hints :- Conceptual
130. Which of the following gives sooty flame on combustion?
1.
2 6
C H 2.
6 6
C H 3.
2 4
C H 4.
4
CH
Key :- 2
Hints:- Conceptual
131. Which of the following elements on doping with germanium, takes it a p-type semiconductor?
1.As 2.Ga 3.Bi 4.Sb
Key :- 2
Hints:- Conceptual
132. The molar mass of a solute X in g
1
mol

, if its 1% solution is isotonic with a 5% solution of

cane sugar ( molar mass = 342g
1
mol

), is
1.136.2 2.171.2 3.68.4 4.34.2
Key :- 3
Hints:-
1 2
C C =
133. Vapour pressure in mm Hg of 0.1 mole of urea in 180g of water at
0
25 C is ( The vapour
pressure of water at
0
25 C is 24 mm Hg)
1.23.76 2.24.76 3.2.376 4.20.76
Key:- 1
Hints:-
0
0
S s
P P n
P n

=
134. At 298K the molar conductivities at infinite dilution
( )
0
m
. of
4
, NH Cl KOH and KCl are
152.8,272.6 and
2 1
149.8 S cm mol

respectively. The
0
m
. of
4
NH OH in
2 1
S cm mol

and %
dissociation of 0.01 M
4
NH OH with
2 1
25.1
m
S cm mol

. = at the same temperature are

1. 269.6 , 9.6 2. 30 , 84 3. 275.6 , 0.91 4. 275.6 , 9.1
Key:- 4
Hints:- Kohlroush law


31
135. In a first order reaction the concentration of the reactant decreases from 0.6M to 0.3M in 15
minutes. The time taken of the concentration to change from 0.1M to 0.025M in minutes is
1. 30 2.3 3.1.2 4.12
Key:- 1
Hints:-
2.303
log
a
K
t a x
=

136. Assertion (A): van der Waals force are responsible for chemisorption
Reason (R) : High temperature is favorable for chemisorption
The correct answer is
1.A and R are correct but R is not the correct explanation of A
2. A is correct but R is not correct 3.A is not correct but R is correct
4. A and R are correct and R is the correct explanation of A
Key :- 3
Hints :- Conceptual
137. What is the role of limestone during the extraction of iron from haematite ore?
1.reducing agent 2.flux 3.leaching agent 4.oxidizing agent
Key:- 2
Hints :- Conceptual
138. The charring of sugar takes place when treated with concentrated
2 4
H SO . What is the type of
reaction involved in it?
1.Addition reaction 2. Disproportionation reaction
3.Dehydration reaction 4. Hydrolysis reaction
Key :- 3
Hints :- Conceptual
139. The structure of
4
XeOF is
1.Square pyramidal 2.Pyramidal
3.Trigonal bipyramidal 4.Square planar
Key :- 1
Hints :- Conceptual


32
140. Which one of the following ions has same number of unpaired electrons as those present in
3
V
+
ion?
1.
2
Mn
+
2.
3
Cr
+
3.
3
Fe
+
4.
2
Ni
+

Key :- 4
Hints :- Conceptual
141. Match the following
List I List II
a.
3
sp I.
( )
3
3
6
Co NH
+
(


b.
2
dsp II. ( )
4
Ni Co (


c.
3 2
sp d III. ( )
3 2
2
Pt NH Cl (


4.
2 3
d sp IV. | |
3
6
CoF


V. ( )
5
Fe Co (


A B C D
1. II III IV I
2. II III I V
3. III II IV I
4. V II IV III
Key :- 1
Hints :- Conceptual
142. Identify the copolymer from the following
1. 2.
3. 4.
Key :- 3
Hints :- Conceptual


33
143. Lactose is a disaccharide of ..
1. D o Glucose and D | -Ribose 2. D o Glucose and D | -Galactose
3. D o Glucose and D o Fructose 4. D | Glucose and D | Galactose
Key :- 4
Hints :- Conceptual
144. What are the substance with mimic the natural chemical messangers?
1.Agonists 2.Receptors 3.Antibiotics 4.Antagonists
Key :- 1
Hints :- Conceptual
145. Which of the following is more readily hydrolysed by
1
N
S mechanism?
1. ( )
6 5 3
C H CH CH Br 2. ( )
6 5
2
C H CHBr 3. ( ) ( )
6 5 3
2
C H C CH Br 4.
6 5 2
C H CH Br
Key:- 3
Hints :- Conceptual
146.
6 5 2 3
HI
C H O CH CH Y Z
A
+
Identify Y and Z in the above reaction
Y Z
1.
6 5
C H I
3 2
H CCH OH
2.
6 5
C H OH
3 2
H CCH I
3.
6 5
C H OH
3 3
H CCH
4.
2 5
C H I
6 5
C H CHO
Key :- 2
Hints:- Conceptual
147.
Y
X Benzoquinone
Identify X and Y in the above reaction
X Y
1. 2. Zn
3. Zn 4.
2 2 7 2 4
/ Na Cr O H SO
Key :- 4
Hints:- Conceptual


34
148.
3
3 2
H O Dry ether
H CMgBr CO Y Z

+
Identify Z from the following
1.Propanoic acid 2.Methyl acetate 3.Ethyl acetate 4.Acetic acid
Key :- 4
Hints :- Conceptual

149. What is Z in the following reaction sequence?

1.
6 5
C H CHO 2.
6 6
C H 3.
6 5 2
C H CO H 4.
6 5
C H OH
Key:- 1
Hints :- Conceptual
150. In an atom the order of increasing energy of electrons with quantum numbers (i) n=4. 1 l = ,(ii)
n=4, 0 l = ,(iii) 3, 2 n l = = and (iv) 3, 1 n l = = is
1. ( ) ( ) ( ) ( ) i iii ii iv < < < 2. ( ) ( ) ( ) ( ) iv ii iii i < < <
3. ( ) ( ) ( ) ( ) iii i iv ii < < < 4. ( ) ( ) ( ) ( ) ii iv i iii < < <
Key :- 2
Hints:- ( ) n l + values
151. The number of angular and radial nodes of 4d orbital respectively are
1. 3,0 2. 2,1 3. 3,1 4. 1,2
Key :- 2
Hints:- Conceptual
152. The oxidation state and covalency of Al in ( )
2
2
5
AlCl H O
+
(

are respectively
1. 2, 6 + 2. 3, 3 + 3. 6, 6 + 4. 3, 6 +
Key :- 4
Hints:- Conceptual
153. The increasing order of the atomic radius of Si,S,Na,Mg,Al is
1. Na Mg Si Al S < < < < 2. Na Mg Al Si S < < < <
3. S Si Al Mg Na < < < < 4. Na Al Mg S Si < < < <
Key :- 3
Hints :- Conceptual

154. The number of electrons in the valence shell of the central atom of a molecule is 8. The
molecule is
1.
2
SCl 2.
6
SF 3.
3
BCl 4.
2
BeH
Key :- 1
Hints :- Conceptual


35
155. Which one of the following has longest covalent bond distance?
1. C N 2. C O 3. C C 4. C H
Key :- 3
Hints :- Conceptual


156. The ratio of mass of diffusion of gases X and Y is 1:5 and that of Y and Z is 1:6. The ratio of
rates of diffusion of Z and X is
1.30:1 2.6:1 3.1:30 4.1:6
Key :- 1
Hints :-
1
30
y
x
y z
r
r
r r
=
157. The molecular interactions responsible for hydrogen bonding in HF
1.dipole-induced dipole 2.ion-dipole
3.ion-induced dipole 4.dipole-dipole
Key :- 4
Hints :- Conceptual
158.
4
KMnO reacts with KI in basic medium to form
2
I and
2
MnO . When 250mL of 0.1M KI
solution is mixed with 250mL of 0.02M
4
KMnO in basic medium, what is the number of
moles of
2
I formed?
1.0.005 2.0.01 3.0.015 4.0.0075
Key :- 4
Hints :-
( ) ( )
4 2
eq eq
KmnO I
n n =
159. The oxide of a metal contains 40% of oxygen. The valency of metal is 2. What is the atomic
weight of the metal?
1.40 2.36 3.24 4.12
Key :- 3
Hints :-
60 40
? 16

160. The temperature in K at which 0 G A = , for a given reaction with 20.5 H A = kJ
1
mol

and
1 1
50.0 S JK mol

A = is
1.2.44 2.-2.44 3.-410 4.410
Key :- 3
Hints :- G H T S A = A A