1.

Reactor (R-102)

Figure 1: Reactor (R-102)

At T = 246.8 C, P = 3 bar,
Reactions:
1.
2.
3.
4.
5.
6.
7.

4CO + 9H2 C4H10 + 4H2O

3CO + 7H2 C3H8 + 3H2O
8CO + 17H2 C8H18 + 8H2O
16CO + 33H2 C16H34 + 16H2O
20CO + 41H2 C20H42 + 20H2O
21CO + 43H2 C21H44 + 21H2O
9CO + 19H2 C9H20 + 9H2O

Inlet properties:

Components

(Stream S108)

Outlet properties:

CO
H2
CH4
H2 O

352246.176
73852.102
5995.947
6659.948

-3713.238
3210.960
-4074.67
-13005.06

-1.31 x 109
0.24 x 109
-0.02 x 109
-0.08 x 109

CO2

78719.985

-8732.054
Total

-0.69 x 109
-1.86 x 109

Components

(stream S109)
CO

17612.3088

-3713.238

-6.54 x 107

H2

23639.362

3210.96

7.59 x 107

H2 O

221884.394

-13005.06

-288.56 x 107

CO2

78719.9849

-8732.054

-68.74 x 107

CH4

5995.94659

-4074.67

-2.44 x 107

C4H10

7309.33702

-1897.555

-1.39 x 107

C3H8

1848.45992

-2183.289

-0.40 x 107

C8H18

26934.6863

-1569.383

-4.23 x 107

C16H34

115687.098

-1432.463

-16.57 x 107

C20H42

5329.89797

-1394.364

-0.74 x 107

C21H44

3552.05813

-1389.91

-0.49 x 107

C9H20

8960.62406

-1540.12

-1.38 x 107

Total

-383.90 x 107

Deviation
Hand calculation

Aspen software

Error(%)

2.06

Reactor 2 (R-202)

S120-1

S121

B37

S122

Figure 3: Split fraction (B37)

-

bar,

Inlet properties:
Component Name
(Stream 120-1)

Outlet properties:

CO
H2

17416.85
23639.31

-4235.68
-34084.40

-7.38 x 107
-80.57 x 107

H2O

129.60

-16056.30

-0.21 x 107

CO2

70661.51

-9304.24

-65.75 x 107

CH4

5605.18

-5100.29

-2.86 x 107

C4H10

2932.07

-2660.44

-0.78 x 107

C3 H 8

1083.30

-2874.43

-0.31 x 107

C8H18

8560.41

-2297.83

-1.97 x 107

C16H34

0.68

-2104.76

C20H42

-2062.89

C21H44

-2058.74

C9H20

1547.01

-2248.25

-0.35 x 107

Total

-160.18 x 107

Component Name

CO
H2

S121
17406.4343
23639.305

S122
10.4185444
0

-4235.683
-34084.4

-7.38 x 107
-80.57 x 107

H2 O

1.07117449

128.527142

-16056.3

-0.21 x 107

CO2

69790.4626

871.043145

-9304.243

-65.75 x 107

CH4

5597.93899

7.24297221

-5100.289

-2.86 x 107

C4H10

2475.70047

456.365202

-2660.439

-0.78 x 107

C3H8

1048.55559

34.7437472

-2874.434

-0.31 x 107

C8H18

78.6633941

8481.74381

-2297.833

-1.97 x 107

C16H34

0.68218743

-2104.762

C20H42

-2062.887

C21H44

-2058.742

C9H20

78.6633941

1543.96765

-2248.248

-0.36 x 107

Total

-161.69 x 107

Deviation:
Hand calculation
Aspen software
Error (%)

2.58

Compressor C101

S101

S101-1

Figure 4: Compressor (C101)

At T = 550 C, P = 15 bar,
Inlet properties:
Components

(Stream 304)
CH4

240000

-3007.715

-7.2185 x 108

Total

-7.2185 x 108

Outlet properties:
T= 577.1 C, P = 18 bar
Components

(Stream 305)
CH4

240000

-2897.366
Total

-6.9537 x 108
-6.9537 x 108

-6.9537 x 108 ( -7.2185 x 108)

Deviation
Hand calculation
Aspen software
Error (%)

0.0023 0