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Biomechanics and
Materials
V. Material Properties
V.1 Properties of Materials
Prof. Young-Ho CHO
Department of BioSystems, KAIST
http://biosys.kaist.ac.kr
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
[Review] Tensile Test [Review] Stress-Strain Curve
σu
σy
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
(1) Young’s modulus [Note] Resonant Test Method for Young’s Modulus
The test structure is driven in the parallel direction to the silicon substrate by the
electrostatic force. From the measured natural frequency of the test structure, Young’s
modulus can be estimated.
σy
beam
Young’s modulus = modulus of elasticity Measure
σe the dimension of the test structure truss
and the natural frequency
Hooke’s Law: 2 π 2 f n2 mL 3
E =
σ ( stress ) = Eε ( strain) tw 3
σ
plate
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
[Note] Blister Test for Young’s modulus and residual stress (2) Yield Strength
Pressurizing or blistering a diaphragm with pressure-deflection measurements
Measurement of residual tensile stress and Young’s modulus. Yield Strength: Strength when a definite amount of
TP7658 polymer
plastic strain has occurred (0.2%)
cylinder micrometer [Al Technology Inc.]
Norm alized Displacem ent vs. Pressure
4500000
4000000
specimen 3500000
Normalized Pressure
3000000
tube
2500000
Yield strength
2000000 E = 0.198 GPa
knob 1500000
σ = 1.45 MPa
Dial pressure
gauge 1000000
Normalized Displacement
0.010 0.012 0.014
[KAIST]
σtd ⎡ E ⎤ td
3
p = C1 2 + C2 ⎢ • Young Modulus : 0.198GPa
⎣1 − ν ⎥⎦ a
4
a • Residual Stress : 1.45MPa
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
smaller toughness-
unreinforced
polymers
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
[Note] Pull Test for ultimate strength [Note] Blade Test for Fracture Toughness
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
[Example] A cylindrical rod is made of steel having poisson’s ratio,0.3,
(5) Hardness
is deformed under tensile loading. The initial length of the rod
is 4m, and its original diameter is 1m. When the elongation is 1) Hardness
0.1m, calculate the change in diameter of given rod.
- Material’s resistance to localized plastic deformation
- Test tools: Rockwell, Brinell, Knoop, Vickers
L=4m ε radial = −υε longit
Tensile load
2) Hardness vs. Tensile Strength
ε radial = −0.3 × 0.1 = −0.03
For metals,
d=1m Δd = d × ε radial = 1× (−0.03) = −0.03m su = 3.45 HB [MPa]
or 500 HB [psi]
3) Assumptions for material dimension and loading conditions:
(e.g.) material thickness > 10 X indentation depth
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
Intrinsic
αs αs
Thermal
stress stress T = Td T = Tr
[Note] Disk or Curvature Method for residual Stress [Note] Beam Buckling Method for Residual Stress
Disk method is based on a measurement of the deflection in the center of the disk substrate The test structure, composed of a series of clamped-clamped beams, is used to
before and after processing. measure the compressive residual stress. When a clamped-clamped beam is buckled,
the compressive residual stress can be estimated.
Assumption
• Substrates ; thin, transversely isotropic, no bow Euler’s formula for elastic instability
• Film ; thin, uniform, constant stress : no internal moments
• System ; uniform temperature, mechanically from gradients in residual stress
free When the critical load clamped beam
2 for buckling is
1 E T
σ = 4π 2 I
R 6 (1 − ν ) t Pcr = E 2
Lc
Then, the residual stress is
Thin Film -
4π 2 1
substrate σ = E [KAIST]
+ [KAIST]
A L 2c
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
[Note] Gauge Needle Method for Residual Stress [Note] Bent-Beam Strain Gauge Method for Residual Stress
The test structure measures strain by interconnecting two opposed beams The narrow beams amplify and transform deformations
such that third beam to rotate as a gauge needle. caused by residual stress into opposing displacement of
The rotation of a gauge needle quantifies the residual strain. the apices, where vernier scales are positioned to quantify
the deformation.
yY tan θ A kL
σ = EC f y L / 2 = 2( )(tan ) where k = F / EI
( LA + LB )( LC + 0.5Y ) k 4
E⎛ FL ⎞ 1 L / 2 ∂y 2
σ= ⎜ ΔL′ + ⎟ where L′ = −
2 ∫0 ∂x
( ) dx
L⎝ 2 Ewt ⎠
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
[Note] Electrical Elements and Properties (1) Resistance
Resistance Inductance Capacitance
ρL π d2
I I I Resistance R= 1 For a wire of diameter, d : A =
A 4
V R V L V C ΔA Δd ΔL
=2 = −2ν 3
ρ (resistivity) A d L
L [Henry] F [Farad] ⎛ Δd ΔL ⎞
R [Ohm] ⎜Q = −ν ⎟
dI ⎝ d L ⎠
V =L dV
V = RI I =C L
dt dt A 3 → 2
V
I= 1
I = ∫ Vdt 1 ΔR ΔL Δρ
C∫
R V= Idt = (1 + 2ν ) +
L ΔR ΔL ΔA Δρ
= − + 2
R L ρ 4
ER = ∫0 VIdt
T
ER = ∫0 VIdt
T
R L A ρ
ER = ∫0 VIdt
T
1 1 Dimensional Piezoresistive
= RI 2T = LI 2 = CV 2 Effect Effect
2 2 (Strain gauge) (Semiconductor
Dissipation Storage (K.E.) Storage (P.E.) gauge)
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
(2) Capacitance
• Piezoresistive effect comes from the effect of strain
on the energy surface
d
• Gauge factor (strain sensitivity)
Area : A
G≡
(ΔR R ) = (1 + 2ν ) + (Δρ ρ ) where ν : Poisson's ratio
(ΔL L ) (ΔL L ) A A
C =ε = ε 0ε r
d d
[Note]
ε = ε0 εr : permittivity [ F/m]
• metal :G=2~5
ε0 = 8.85 pF/m
• p-Si : G = 100 ~ 170
εr = relative permittivity (dielectric constant)
• n-Si : G = -100 ~ -140
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
(3) Inductance V.1.3. Thermal Properties
Inductors store energy in a
magnetic field
(1) Heat Capacity & Specific Heat
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
(1) Heat Capacity and Specific Heat [Note] Heat Capacity: Comparison
p
940
dT temperature change (K) Alumina (Al 2 O 3 ) 775
increasing c
Glass 840
• Specific Heat, c: Heat capacity per unit mass (J/kg·K) ? Metals
Aluminum 900
Heat Capacity (J/mol-K) Steel 486
Specific Heat C Tungsten 128
(J/Kg-K) c= Gold 138
m Mass (kg)
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
(2) Thermal Conductivity (2) Thermal Conductivity
• General: The ability of a material to transfer heat. • Proportionality constant (k) that relates heat flow
• Quantitative: temperature rate (dQ/dt) and temperature gradient (dT/dx)
dT gradient
q = −k 1 dQ dx
heat flux dx k=−
(J/m2-s) thermal conductivity (J/m-K-s) A dt dT
• Fourier’s Law is analogous to Fick’s Law
T1 T2 > T 1
x1 x2 dT 1 dQ
heat flux q = −k q=
dx A dt
• Atomic view: Atomic vibrations in hotter region carry
energy (vibrations) to cooler regions. • k in J/(s·m·K)
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
3) Heat Transfer in Ceramics 4) Thermal Conductivity: Comparison
increasing k
Magnesia (MgO) 38
and drops with rising Alumina (Al 2 O 3 ) 39 By vibration of
temperature Soda-lime glass 1.7 atoms
Silica (cryst. SiO 2 ) 1.4
? Polymers
Polypropylene 0.12 By vibration/
Polyethylene 0.46-0.50 rotation of chain
Polystyrene 0.13 molecules
Teflon 0.25
Selected values from Table 19.1, Callister 6e.
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho 8 KAIST
Spring 2006,
T5
bond energy vs bond length
curve is 밶symmetric
T1
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
2) Thermal expansion coefficient properties 3) Comparison
α
• Can have negative α Aluminum 23.6
Steel 12 generally decrease
increasing
• Can have α near zero Tungsten 4.5 with increasing
Gold 14.2 bond energy?
? Ceramics
Magnesia (MgO) 13.5
Alumina (Al 2 O 3 ) 7.6
Soda-lime glass 9
Silica (cryst. SiO 2 ) 0.4
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
⎛ n2 − n1 ⎞
2
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
Δl ε oε r
= ≈ 1.23nm / V
ΔV dE
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
•For a constrained solid compressive σ keeps ΔL = 0 The forces are in the order of
0.01 to 300pN.
σ(ΔT) = Eα(T0 – Tf)
Possible to manipulate
- Upon heating (Tf>T0), Compressive Stress (σ<0) particles like atoms, molecules
- Upon heating (Tf<T0), Tensile Stress (σ>0) (even large) and small V. Emiliani et.al., Optics Express, Vol.12(2004)
dielectric spheres
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
(4) Chemo-electrical: Electro-wetting
In the Rayleigh Regime (diameter of
particle is very small compared to the ElectroWetting
wavelength, D « λ)
Fscat = nm
c 3λ ⎜⎝ n p + 2 ⎟⎠
4 2
I o : Intensity
r : Radius of spherical particle Gradient force due to the Lorenz force
λ : Wave lenght of light acting on the dipole, induced by the No external voltage applied. External voltage applied.
n p : Refractive index of the particle electromagnetic field Charges are distributed at the Charge density at EDL changes
2
nb r 3 ⎛⎜ np −1 ⎞⎟
2
electrode-electrolyte interface, so that γSL and the contact
3
nm : Refractive index of the medium nb
Fgrad = − α∇E = −
2
∇E2
α : Polarizability of particle 2 2 ⎜⎝ np 2 + 2 ⎟⎠ building an EDL. angle decrease or increase.
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
Lippmann-Young Equation
1 1
cos θ = cos θ 0 + cV 2
γ LG 2
θ : Contact angle
c : Capacitance per unit area
V : Applied voltage
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
(5) Opto-electrical Effects (6) Thermo-electrical: TCR
1) Photoelectric (PE) 2) Photoconductive (PC) 3) Photovoltaic (PV) 1) Temperature Coefficient of Resistance (TCR)
Ep(λ) → I(V) Ep(λ) → R(I,V) Ep(λ) → V
Ep > eΦ Ep Ep > Eg Ep > Eg R(T ) = Ro(1 + αT + βT 2 + γT 3 +)
Ep
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
(7) Thermo-chemical (8) Chemo-mechanical
Surface tension driven fluid motion under Polymer actuator
Voltage-displacement
temperature gradient
Working principle
Temperature gradient
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST