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BiS 271 Spring, 2006

Biomechanics and
Materials
V. Material Properties
V.1 Properties of Materials
Prof. Young-Ho CHO
Department of BioSystems, KAIST
http://biosys.kaist.ac.kr

Phn: +82-42-869-8699 E-mail: mems@kaist.ac.kr http://mems.kaist.ac.kr

BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST

V.1.1 Mechanical Properties [Note] Analysis of mechanical deformation

How strong is it?


(1) Young’s Modulus Under what sort of deformation?

(2) Mechanical Strength (yield, ultimate, fracture)


Tension Compression
(3) Poisson’s Ratio

(4) Residual Stress (thermal, intrinsic)

(5) Hardness Torsion


Shear

BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
[Review] Tensile Test [Review] Stress-Strain Curve

σu
σy

• Specimen is “pulled” in tension at a


constant rate σf
σe
• Load (F) necessary to produce a
given elongation (ΔL) is monitored σ e : Elastic Limit
• Load vs elongation curve σ y : Yield Strength
• Converted to stress-strain curve σ u : Ultimate Strength
σ f : Fracture Toughness

BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST

(1) Young’s modulus [Note] Resonant Test Method for Young’s Modulus

The test structure is driven in the parallel direction to the silicon substrate by the
electrostatic force. From the measured natural frequency of the test structure, Young’s
modulus can be estimated.
σy
beam
Young’s modulus = modulus of elasticity Measure
σe the dimension of the test structure truss
and the natural frequency

Hooke’s Law: 2 π 2 f n2 mL 3
E =
σ ( stress ) = Eε ( strain) tw 3
σ
plate

Young ' s modulus, E = 1


where m = m p + mt +
12
mb
ε 4 35
[KAIST]

BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
[Note] Blister Test for Young’s modulus and residual stress (2) Yield Strength
Pressurizing or blistering a diaphragm with pressure-deflection measurements
Measurement of residual tensile stress and Young’s modulus. Yield Strength: Strength when a definite amount of
TP7658 polymer
plastic strain has occurred (0.2%)
cylinder micrometer [Al Technology Inc.]
Norm alized Displacem ent vs. Pressure
4500000

4000000

specimen 3500000

Normalized Pressure
3000000

tube
2500000
Yield strength
2000000 E = 0.198 GPa
knob 1500000
σ = 1.45 MPa
Dial pressure
gauge 1000000

microscope -0.002 0.000 0.002 0.004 0.006 0.008

Normalized Displacement
0.010 0.012 0.014

[KAIST]
σtd ⎡ E ⎤ td
3
p = C1 2 + C2 ⎢ • Young Modulus : 0.198GPa
⎣1 − ν ⎥⎦ a
4
a • Residual Stress : 1.45MPa
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST

(3) Ultimate and Fracture Strength [Note] Fracture Toughness

*Energy required to fail → area under stress-strain curve.


Ultimate Strength: Maximum stress

Engineering smaller toughness (ceramics)


tensile larg er toughness
Fracture Toughness: Stress at Fracture stress, σ (metals, PMCs)

smaller toughness-
unreinforced
polymers

Engineering tensile strain, ε

BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
[Note] Pull Test for ultimate strength [Note] Blade Test for Fracture Toughness

Inserting Pre-inserted blade


blade
Silicon Pyrex glass
Pyrex #7740 glass h
δb Bonded area
Silicon wafer H
a
Crack propagation length
10mm
3h 2δ 2
G= 4 b 3 [KAIST]
c1a (1 + γη )

[Nagoya Univ.] [UCLA]


BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST

[Note] Ductility (4) Poisson’s Ratio, υ


A Isotropic material
Ductility: degree of plastic εx εy
F υ=− =− • Elastic strain in compression perpendicular
L deformation at fracture εz εz
to extension caused by tensile stress
⎛ A − AF ⎞ • Cannot be directly obtained from stress-
% Reduction in Area = ⎜⎜ 0 ⎟⎟ ×100
⎝ A0 ⎠ strain curve
⎛ L f − L0 ⎞ • υ = 0.26 to 0.35 for common metal alloys
⎛ L f − L0 ⎞ % Elongation = ⎜⎜ ⎟⎟ × 100
% EL = ⎜⎜ ⎟⎟ × 100
⎝ Lo ⎠ ⎝ L0 ⎠ • υ < 0.25 for ceramics
• υ has a maximum value of 0.50 (no volume
Brittle Materials have a
change)
fracture strain of less than
approx. 5%

BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
[Example] A cylindrical rod is made of steel having poisson’s ratio,0.3,
(5) Hardness
is deformed under tensile loading. The initial length of the rod
is 4m, and its original diameter is 1m. When the elongation is 1) Hardness
0.1m, calculate the change in diameter of given rod.
- Material’s resistance to localized plastic deformation
- Test tools: Rockwell, Brinell, Knoop, Vickers
L=4m ε radial = −υε longit
Tensile load
2) Hardness vs. Tensile Strength
ε radial = −0.3 × 0.1 = −0.03
For metals,
d=1m Δd = d × ε radial = 1× (−0.03) = −0.03m su = 3.45 HB [MPa]
or 500 HB [psi]
3) Assumptions for material dimension and loading conditions:
(e.g.) material thickness > 10 X indentation depth

BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST

(6) Residual Stress 1) Thermal residual stress


Origin - thermal expansion coefficient mismatch
• Residual Stress : σ r = σ rt + σ ri αf
ε=0
αf
εrt

Intrinsic
αs αs
Thermal
stress stress T = Td T = Tr

ε rt = (α f − α s )(Td − Tr ) αf > αs → εrt > 0 : tensile


αf < αs → εrt < 0 : compressible

(ex) Poly silicon on (100) Silicon wafer


αf = 2.8x10-6 /K, αs = 3.2x10-6 /K, Td = 625°C & Tr = 25°C
→ εrt = -2.4x10-4
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
2) Intrinsic residual stress 3) Residual Stress Control
Origin – many !!
ƒ Doping (+, -) ~ ionic radius effect in substitutional site ƒ Compensate dopant strain
σri > 0 σri < 0 (ex) Boron doping in Poly-Silicon
Si B Si Si P Si
(tensile) (compressive)
ƒ Material composition
ƒ Atomic peening (-) ƒ Process conditions
densified compressive film in ion bombardment by atoms
(ex) Sputtering ~ gas pressure, substrate bias
ƒ Void (+)
ƒ Gas entrapment (-) PECVD ~ everything affects residual stress
ƒ Shrinkage during cure (+) LPCVD ~ temperature
ƒ Grain boundaries (complex, poorly understood)
ƒ Etc.
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST

[Note] Disk or Curvature Method for residual Stress [Note] Beam Buckling Method for Residual Stress

Disk method is based on a measurement of the deflection in the center of the disk substrate The test structure, composed of a series of clamped-clamped beams, is used to
before and after processing. measure the compressive residual stress. When a clamped-clamped beam is buckled,
the compressive residual stress can be estimated.
Assumption
• Substrates ; thin, transversely isotropic, no bow Euler’s formula for elastic instability
• Film ; thin, uniform, constant stress : no internal moments
• System ; uniform temperature, mechanically from gradients in residual stress
free When the critical load clamped beam
2 for buckling is
1 E T
σ = 4π 2 I
R 6 (1 − ν ) t Pcr = E 2
Lc
Then, the residual stress is
Thin Film -
4π 2 1
substrate σ = E [KAIST]
+ [KAIST]
A L 2c
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
[Note] Gauge Needle Method for Residual Stress [Note] Bent-Beam Strain Gauge Method for Residual Stress

The test structure measures strain by interconnecting two opposed beams The narrow beams amplify and transform deformations
such that third beam to rotate as a gauge needle. caused by residual stress into opposing displacement of
The rotation of a gauge needle quantifies the residual strain. the apices, where vernier scales are positioned to quantify
the deformation.

FEM Analysis Type B ; uniform response


determines correction factor C f over the widest range of stress

yY tan θ A kL
σ = EC f y L / 2 = 2( )(tan ) where k = F / EI
( LA + LB )( LC + 0.5Y ) k 4

E⎛ FL ⎞ 1 L / 2 ∂y 2
σ= ⎜ ΔL′ + ⎟ where L′ = −
2 ∫0 ∂x
( ) dx
L⎝ 2 Ewt ⎠

BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST

V.1.2 Electrical Properties (0) Electrical Quantities

1) Charge(q) : Coulomb[C] ≡ 1A⋅s


- 1C = charge of 6.24×1018 electrons
(0) Electrical Quantities = charge transfer of 1 A⋅sec
- Charge of single electron = 1.602 × 10-19 C
(1) Resistance
2) Current(i) : Ampere[A] ≡ 1C/s
(2) Capacitance
3) Voltage(v) : volt[V] ≡ 1W/A
(3) Inductance - energy/charge or power/current

4) Electric field strength(E) : [V/m] ≡ N/C

BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
[Note] Electrical Elements and Properties (1) Resistance
Resistance Inductance Capacitance
ρL π d2
I I I Resistance R= 1 For a wire of diameter, d : A =
A 4
V R V L V C ΔA Δd ΔL
=2 = −2ν 3
ρ (resistivity) A d L
L [Henry] F [Farad] ⎛ Δd ΔL ⎞
R [Ohm] ⎜Q = −ν ⎟
dI ⎝ d L ⎠
V =L dV
V = RI I =C L
dt dt A 3 → 2
V
I= 1
I = ∫ Vdt 1 ΔR ΔL Δρ
C∫
R V= Idt = (1 + 2ν ) +
L ΔR ΔL ΔA Δρ
= − + 2
R L ρ 4
ER = ∫0 VIdt
T
ER = ∫0 VIdt
T
R L A ρ
ER = ∫0 VIdt
T

1 1 Dimensional Piezoresistive
= RI 2T = LI 2 = CV 2 Effect Effect
2 2 (Strain gauge) (Semiconductor
Dissipation Storage (K.E.) Storage (P.E.) gauge)
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST

(2) Capacitance
• Piezoresistive effect comes from the effect of strain
on the energy surface
d
• Gauge factor (strain sensitivity)
Area : A
G≡
(ΔR R ) = (1 + 2ν ) + (Δρ ρ ) where ν : Poisson's ratio
(ΔL L ) (ΔL L ) A A
C =ε = ε 0ε r
d d
[Note]
ε = ε0 εr : permittivity [ F/m]
• metal :G=2~5
ε0 = 8.85 pF/m
• p-Si : G = 100 ~ 170
εr = relative permittivity (dielectric constant)
• n-Si : G = -100 ~ -140

BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
(3) Inductance V.1.3. Thermal Properties
Inductors store energy in a
magnetic field
(1) Heat Capacity & Specific Heat

(2) Thermal Conductivity

(3) Thermal Expansion

(4) Temperature Coefficient of Resistance

L = Inductance [V-s/A] (5) Thermoelectric Effects

BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST

(1) Heat Capacity and Specific Heat [Note] Heat Capacity: Comparison

• As the material absorbs heat, its temperature rises material c p (J/kg-K)


• Quantitative: The energy required to increase the ? Polymers at room T
Polypropylene 1925 c p : (J/kg-K)
temperature of the material (J/mol·K) Polyethylene 1850 C p : (J/mol-K)
Polystyrene 1170
Teflon 1050
energy input (J/mol)
heat capacity dQ ? Ceramics
(J/mol-K) C= Magnesia (MgO)

p
940
dT temperature change (K) Alumina (Al 2 O 3 ) 775

increasing c
Glass 840
• Specific Heat, c: Heat capacity per unit mass (J/kg·K) ? Metals
Aluminum 900
Heat Capacity (J/mol-K) Steel 486
Specific Heat C Tungsten 128
(J/Kg-K) c= Gold 138
m Mass (kg)

BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
(2) Thermal Conductivity (2) Thermal Conductivity

• General: The ability of a material to transfer heat. • Proportionality constant (k) that relates heat flow
• Quantitative: temperature rate (dQ/dt) and temperature gradient (dT/dx)
dT gradient
q = −k 1 dQ dx
heat flux dx k=−
(J/m2-s) thermal conductivity (J/m-K-s) A dt dT
• Fourier’s Law is analogous to Fick’s Law
T1 T2 > T 1
x1 x2 dT 1 dQ
heat flux q = −k q=
dx A dt
• Atomic view: Atomic vibrations in hotter region carry
energy (vibrations) to cooler regions. • k in J/(s·m·K)

BiS271: Biomechanics & Materials Prof. Young-Ho Cho 7 KAIST


Spring 2006, BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST

1) Mechanism of Heat Transfer in Solids 2) Heat Transfer in Metals


• Heat transport by atomic vibrations as they move from
high T to low T regions • Free electrons are the main
contributor to heat transport
in high purity metals due to
• Heat transport by free electrons as they gain kinetic high velocities and lack of
energy and migrate to low T areas (in Metals) scattering

• k = k a + ke • Alloying metals (solid


T1 T2 > T 1
solution) introduces
x1 x2
heat flux scattering centers and the
heat transfer reduces
A
e

BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
3) Heat Transfer in Ceramics 4) Thermal Conductivity: Comparison

Material k (W/m-K) Energy Transfer


? Metals
Aluminum 247 By vibration of
• They lack the free electrons of Steel 52 atoms and
metals Tungsten 178 motion of
Gold 315 electrons
? Ceramics
• Phonon transport dominates

increasing k
Magnesia (MgO) 38
and drops with rising Alumina (Al 2 O 3 ) 39 By vibration of
temperature Soda-lime glass 1.7 atoms
Silica (cryst. SiO 2 ) 1.4
? Polymers
Polypropylene 0.12 By vibration/
Polyethylene 0.46-0.50 rotation of chain
Polystyrene 0.13 molecules
Teflon 0.25
Selected values from Table 19.1, Callister 6e.
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho 8 KAIST
Spring 2006,

(3) Thermal Expansion 1) Atomic analysis


• Materials change size when heating. 1 ΔL
α=
L final − L initial L ΔT
= α( Tfinal − Tinitial ) T init
L initial Linit
T final • Bond strength determines α…the greater the bond energy, the
linear coefficient of smaller α
thermal expansion (1/K) Lfinal
• Generally
• Atomic view: Mean bond length increases with T. αceramics < αmetals < αpolymers
Bond energy
r(T 1 )
r(T 5 )

Bond length (r)


increasing T

T5
bond energy vs bond length
curve is 밶symmetric
T1

BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
2) Thermal expansion coefficient properties 3) Comparison

Material α (10 -6 /K)


? Polymers at room T
Polypropylene 145-180
• In general, thermal 106-198
Polyethylene
expansion coefficient Polystyrene 90-150
increases with temperature Teflon 126-216
? Metals
• Q: Why does α

α
• Can have negative α Aluminum 23.6
Steel 12 generally decrease

increasing
• Can have α near zero Tungsten 4.5 with increasing
Gold 14.2 bond energy?
? Ceramics
Magnesia (MgO) 13.5
Alumina (Al 2 O 3 ) 7.6
Soda-lime glass 9
Silica (cryst. SiO 2 ) 0.4

BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST

V.1.4. Optical Properties (2) Optical Energy


(1) Light and its spectrum - Photon has no mass but energy
where h : plank constant
• Radiation (Thermal, Optical) v = 6.63x10-34 J·s = 4.135x10-5 eV·s
E = hf = h [eV] f : wave frequency
• Radiation : Energy transfer by electromagnetic wave phenomena λ
v : wave velocity
λ : wave length
• Spectrum Thermal
radiation • Energy band diagram • Ep = eΦ (work
function)
e
Elevel
10-12 10-10 10-8 10-6 10-4 10-2 101 102 104 λ[m] Evacuum
eΦ Χ
Econduction
• E = Χ (electron affinity)
Cosmic Egap
X-ray UV Infrared(IR) Micro wave Radio (RF) Ef
ray (forbidden band)
Visible
ray
Evalance e
(0.39 μm ~ 0.78 μm)
e
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho v=0 Spring 2006, KAIST
(3) Refraction V.1.5. Bio-chemical Properties
- index of refraction, n (1) Surface Energy
c where c : light velocity
n= v : wave velocity
Quantifies the disruption of chemical bonds when a
v surface is created
(4) Reflection
- reflectivity, R
Surface area
Ir where Ir : intensity of reflected ∝ Surface Energy
R= light Volume
Ii Ii : intensity of incident light
- Normal incident light

⎛ n2 − n1 ⎞
2

R=⎜ ⎟ where n1, n2 : indices of refraction


⎝ n2 + n1 ⎠

BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST

V.1.5. Bio-chemical Properties V.1.6. Material property interactions


(2) Contact Angle
(1) Electro-mechanical
ƒ Young’s Equation (2) Thermo-mechanical
Hydrophilic (3) Opto-mechanical
Mechanical

γ LG θ < 90o (4) Chemo-electrical


Liquid Gas
θ
(5) Opto-electrical Electrical Thermal
γ SL γ SG
(6) Thermo-electrical
Solid
Hydrophobic (7) Thermo-chemical
γ SL = γ SG − γ LG cos θ
θ > 90 o
(8) Chemo-mechanical Optical Chemical
γ SL : Solid - Liquid Surface Tension
γ SG : Solid - Gas Surface Tension (9) Opto-chemical
γ LG : Liquid - Gas Surface Tension (10) Thermo-optical
θ : Contact Angle
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
(1) Electro-mechanical: Piezo-electric ƒ Electrical Charge induced by the external force F
ƒ Asymmetric charge distribution in the material structure
Q = dF = dσA = dεEA
• Voltage potential → Polarization of internal charge → Relative
displacement of internal charges → Deformation (strain)
where, d is charge sensitivity coefficient (matrix) and E is
ƒ Piezoelectric material : Quartz, PZT (Lead Zirconate Young’s Modulus of the material.
Titanate), Zinc Oxide, ZnO, Lithium Niobate
ƒ Change in length per unit applied voltage
Δl C εε A 1 εε εε
= ⋅ Δl = o r ⋅ ⋅ Δl = o r ⋅ Δl = o r
ΔV ΔQ l dF ldσ dE

Δl ε oε r
= ≈ 1.23nm / V
ΔV dE

ƒ Δl is independent of l, only depends on the voltage ΔV and


material properties -> Stack for large Δl

BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST

(2) Thermo-mechanical (3) Opto-mechanical: Optical tweezer

Thermal Stress ƒ A strongly focused laser beam


has the ability to catch and
hold particles (of dielectric
material) in a size range from
• Occurs due to: T room nm to µm.
- uneven heating/cooling L room ΔL d=10um
- mismatch in thermal expansion. ƒ The basic principle behind
T optical tweezers is the
momentum transfer associated
with bending light

•For a constrained solid compressive σ keeps ΔL = 0 ƒ The forces are in the order of
0.01 to 300pN.
σ(ΔT) = Eα(T0 – Tf)
ƒ Possible to manipulate
- Upon heating (Tf>T0), Compressive Stress (σ<0) particles like atoms, molecules
- Upon heating (Tf<T0), Tensile Stress (σ>0) (even large) and small V. Emiliani et.al., Optics Express, Vol.12(2004)
dielectric spheres

BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
(4) Chemo-electrical: Electro-wetting
ƒ In the Rayleigh Regime (diameter of
particle is very small compared to the ƒ ElectroWetting
wavelength, D « λ)

ƒ Scattering force due to the radiation


pressure on the particle
2
I o 128π 5r 6 ⎛⎜ n p − 1 ⎞⎟
2

Fscat = nm
c 3λ ⎜⎝ n p + 2 ⎟⎠
4 2

I o : Intensity
r : Radius of spherical particle ƒ Gradient force due to the Lorenz force
λ : Wave lenght of light acting on the dipole, induced by the No external voltage applied. External voltage applied.
n p : Refractive index of the particle electromagnetic field Charges are distributed at the Charge density at EDL changes
2
nb r 3 ⎛⎜ np −1 ⎞⎟
2
electrode-electrolyte interface, so that γSL and the contact
3
nm : Refractive index of the medium nb
Fgrad = − α∇E = −
2
∇E2
α : Polarizability of particle 2 2 ⎜⎝ np 2 + 2 ⎟⎠ building an EDL. angle decrease or increase.

BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST

Droplet Manipulation using


ƒ Young’s Equation
Electro-Wetting (UCLA)
γ SL = γ SG − γ LG cos θ
γ LG
γ SL : Solid - Liquid Surface Tension
Liquid Gas
γ SG : Solid - Gas Surface Tension
θ
γ SL γ SG
γ LG : Liquid - Gas Surface Tension
Solid θ : Contact Angle

ƒ Lippmann-Young Equation
1 1
cos θ = cos θ 0 + cV 2
γ LG 2
θ : Contact angle
c : Capacitance per unit area
V : Applied voltage

BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
(5) Opto-electrical Effects (6) Thermo-electrical: TCR
1) Photoelectric (PE) 2) Photoconductive (PC) 3) Photovoltaic (PV) 1) Temperature Coefficient of Resistance (TCR)
Ep(λ) → I(V) Ep(λ) → R(I,V) Ep(λ) → V
Ep > eΦ Ep Ep > Eg Ep > Eg R(T ) = Ro(1 + αT + βT 2 + γT 3 +)
Ep

anode semiconductor n I Thermistor


Ep p or metal R Eo
I Ic
Eb
R Eo
e
k [W/cm-K] cp[J/g-K]
Ep e p Ep n Si 1.48 0.7
cathode Ec -
Al 2.37 0.9
Eb Ec
Eg
Ev
Ef Cu 4.01 0.39
+
Ev SiO2 0.014 1.0
• nowadays, seldom used • recombination nose • no recombination nose
• need bias (external source) • no external source required
→ Exposure meter → Solar cell
BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST

2) Seebeck effect 3) Peltier effect 4) Thomson effect [Note]


• Joule heating : Thermal heat conduction (one way)
• Generation of a •Electrical E → Thermal E
thermoelectric voltage due • Absorption or emission of • Seebeck effect, Peltier effect (two way)
to a temperature difference • Heat transfer due to heat due to carrier movement
between the junction of electrical current heat up or down a temperature [Note]
two dissimilar conducting generation/absorption rate gradient • Seebeck effect = Peltier effect + Thomson effect
materials • Reverse of Seebeck effect
A QTA VAB
A T1 I A T2 T1 I T2
VAB Qp
Qp1
T1 > T2 , V1 > V2
T1 Qp2
T1 B B [Note] T ↑ → carrier density ↑ B T2
T2
Heat Heat → carrier diffusion ↑
absorption generation QTB
[Applications]
ΔVAB = S AB ΔT
T2
qT = ∫ φ A IdT
*
Q p = Π AB I = ( S1* − S 2* ) IT T1
1) Voltage, current, power temperature measurement
S*AB : Seebeck coeff. in a wide frequency range (Hz ~ GHz)
qT : heat/sec/voltage
ΠAB : Peltier coeff. 2) Fluid flow, pressure, thermoconductivity measurement
(0.2~80 µV/°C) φA : Thomson coeff.
Q p : Amount of Heat 3) Power generation (~mW)

BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST
(7) Thermo-chemical (8) Chemo-mechanical
Surface tension driven fluid motion under Polymer actuator
Voltage-displacement
temperature gradient
Working principle

Temperature gradient

Surface energy gradient Polymer actuator shifting a coin

BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST

(9) Others References


Opto-chemical interactions
Thermo-optical interactions
[1] J.J. Wortman and R.A. Evans, “Young’s modulus, Shear modulus, and Poisson’s Ratio in
Silicon and Germanium”, J. of Applied Phys., Vol.36, No.1, Jan. 1965, pp.153-156
[2] H. Guckel et al., “Mechanical Properties of Fine Grained Polysilicon : The Repeatability
issue”.
[3] M. Madou, Fundamentals of Microfabrication, CRC Press, 1997, pp.223-224.
[4] Y. B. Gianchandani, “Bent-Beam Strain Sensors,” J. of MEMS, Vol. 5, No. 1(1996), pp.52-58.
[5] K. Najafi, K. Suzuki, “A Novel Technique and Structure for the Measurement of Intrinsic
Stress and Young’s Modulus of Thin Films,” Proc. IEEE MEMS Workshop, Salt Lake City,
1989, pp.96-97.

BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST BiS271: Biomechanics & Materials Prof. Young-Ho Cho Spring 2006, KAIST

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