Structure of Atom

JEE Advanced/ IIT-JEE

The mass of a hydrogen atom is ............. kg.
(1982 - 1 Mark)
Isotopes of an element differ in the number of: ............. in
their nuclei. (1982 - I Mark)
When there are two electrons in the same orbital, they have
............. spms. (1982 - 1 Mark)
Elements of the same mass number but of different atomic
numbers are hown as : ............... (1983 - 1 Mark)
The uncertainty principle and the concept of wave nature
of matter were proposed by ............... and ...............
respectively. (Heisenberg, Schrodiiger, Maxwell, de Broglie)
(1988 - 1 Mark)
The light radiations with discrete quantities of energy are
called ................. (1993 - 1 Mark)
Wave functions of electrons in atoms and molecules are
called ................ (I993 - 1 Mark)
The 2px, 2py and 2p. orbitals of atom have identical
shapes but differ in their ................ (1993 - 1 Mark)
The outermost electronic configuration.of Cr is ................
I
(1994 - 1 Mark)
1. The outer electronic configuration of the ground state
chromium atom is 3d'4s2. (1982 - 1 Mark)
2. Gamma rays are electromagnetic radiations of wavelengths
of 1 0-6 cm to 1 0-5 cm. (1983 - 1 Mark)
3. The energy of the electron in the 3d-orbital is less than that
in the 4s-orbital in the hydrogen atom. (1983 - 1 Mark)
4. The electron density in theXYplane in 3d orbital is
x - Y
zero. (I986 - I Mark)
5. In a given electric field, P-particles are deflected more than
a-particles in spite of a-particles having larger charge.
11993 - 1 Mark)
1. The number of neutrons in dipositive zinc ion with mass
number 70 is (1 9 79)
(a) 34 @) 36
(4 38 (d) 40
Rutherford's experiment on scattering of a-particles showed
for the fust time that the atom has (1981 - 1 Mark)
(a) electrons (h) protons
(c) nucleus (d) neutrons
-Any p-orbital can accommodate upto (1983 - I Mark)
(a) four electrons
@) six electrons
(c) two electrons with parallel spins
(d) two electrons with dpposite spins
The principal quantum number of an atom is related to the
(1983 - 1 Mark)
(a) size of the orbital
@) spin angular momentum
(c) orbital angular momentum
(d) orientation ofthe orbital in space
Rutherford's scattering exljeriment is related to the size of
the (1983 - 1 Mark)
(a) nucleus @) atom
(c) : electron (d) neutron
The increasing order '(lowest first) f o ~ the values of elm
(chargelmass) for electron (e), proton (p), neutron (n) and
alpha particle (a) is :
. . (1984 - 1 Mark)
(a)' e,p, n;a @) n,p, e, a '. ,
(c) n , ~ , a, e (d) n, a,p, e
Correct set of four quantum numbers for the vaience
(outermost) electron ofrubidium (Z=37) is :
(1984 - 1 Mark)
(a) 5,0,0,+% @) 5, 1,0,+%
(c) 5, I , I,+% (d) 6,0,0,+%
Whikh electronic level would allow the hydrogen atom to
absorb a photon but not to emit a photon?
(1984 - I Mark)
(a) 3s @) 2~
( 9 ' 2s (d) 1s
Bohr model can explain : (1985 - 1 Mark)
(a) the spectrum of hydrogen atom only
(b) spectrum of an atom or ion containing one electron
only
(c) the spectrum of hydrogen molecule
(d) the solar spechum , .
The radius of an atomic nucleus is' of the order of:
(I985 - 1 Mark)
(a) 10-lOcm~ @) 10-' ~cm
(c) 10-Is cm (d) 104cm
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Topic-wise Solved Papers - CHEMISTRY
11.
Electromagnetic radiation with maximum wavelength is :
(1 985 - 1 Mark)
(a) ultraviolet . (b) radiowave;
(c) x-ray. (d) infrared
12. Rutlierford's alpha particle scattering experiment eventually
led to the conclusion that : (1986,- 1 Mark)
(a) mass and energy are related
(b) . electrons occupy space around the nucleus
(c) neutrons are buried deep in the nucleus
(d) the point of impact with matter ..can be. precisely
determined.
13. Which one of~t he following sets of quantum numbers
represents an impossible arrangement? (1986 - 1 Mark)
I n
ms
(a) 3 2 -2 . % , , ,
_(b) 4 0 0 %
(c) . 3. 2 -3 % ;
( 4 5 3 0 . -%
14. The ratio of the energy of a photon of 2000.A wavelength.
radiation to that of 4000A radiation is : (1986 - I Mark)
(a) '/. (b) 4
(c) % ; (d): 2
15. The triad of nuclei that is isotonic is (1988 - I Mark)
14 14 17
(c) ,5' , 7 N, gF
14
(d) ,c, ';N, ';F 1
16. The wavelength of a spectral line for an electronic transition
is inversely related to : (1988 - 1 Mark)
(a) the number of electrons undergoing the transition
(b) the nuclear charge ofthe atom
(c) the difference in the energy of the energy levels
involved in the transition
(d) the velocity of the electron undergoing the transition.
17. , The orbital diagram in which the Aufbauprinciple is violated
is :
(1988 - I Mark)
2s ZP
18. The outermost electronic configuration of the most
electtonegative element is (1988 - 1 Mark)
(a) ns2 np3 (b) ns2 np4
(c) ns2 np5 (d) ns2 np6
19. The correct ground state electronic configuration of
chromium atom is : (I989 - 1 Mark)
(a) [Ar] 3dS 4s' (b) [Arl 3&43
(c) [Ar] 3 8 4s0 (d) [Ar] 4dS 4s'
20. The correct set of quantum numbers for the unpaired
electron of chlorine atomis : (1989 - IMark)
n 1 m
(aj ' 2' .I. o
(b) 2 1 1
1
(c) 3 1
(d), 3 - 0 0
21. Which of the following does not chgacterise X-rays?
(1992 -.I Mark)
(a) ' The radiation can ionise gases A . .
(b) It causes ZnS to fluorescence
(c) Deflected by electric and magnetic fields
(d) Have wavelengths shorter than ultraviolet rays
22. Which of the following relates to photons both as wave
motion and as a stream of particles? (1992 -I-Mark)
(a) Inference (b) &=mcZ.
(c) Diffraction (d) E = hv
23. A 3p orbital has : (1 995s)
(a) two non sphkrical nodes
(b) two spherical nodes
(c) one spherical & one non ~~herical' node
(d) one spherical and two non spherical nodes ' .
24. . The orbital angular momentum of an electron in 2s orbital i s
(1996 - 1 Mark)
- .
(b) Zero
25. The first use of quantum theory to explain the structure of
atom was made by (1997C- 1 Mark)
(a) Heisenberg (b) Bohr
(c) Planck (d) Einstein
26. For a d-electron, the orbital angular momentum is
(1997- 1 Mark)
-(c) (h12x) . - (d) 2(h/2n)
27. The electrons, identified by quantum numbers n and I, (i) n
=4,l=l,(ii)n=4,l=0,(iii)n=3,1-2,and(iv)n=3,l=i
' .
can be placed in order of increasing energy, from the lowest
to highest, as (1999 - 2 Marks)
a ( v < (i ) < ( i ) < (i) (b) (ii) < (iv) < (i) C(iii)
(c)' (i) < (iii) < (ii) < (iv) (d) (iii) <(i) < (iv) < (ii)
- 28, The number of nodal planes in ap, orbital is (2OOOS)
(a) one . (b) two
(c) three. , . ' (d) zero
29. The electronic configuration of an element is Is2, 2s2 2p6,
3s2 3p6 3dS, 4s1. This represents its(2000S)
(a) excited state (b) ground state ~ ~
(c) cationic folm . (d) anionic form
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30. The wavelength associated with a golfball weighing200 g
and moving at a speed of 5 m/h is of the order (ZOOIS)
(a) 10-iOm (b) 10-20m
(c) 10-"m (d) 10AOm
31; The quantum numbers +1/2 and -112 for the electron spin
represent (2001s)
(a) rotation ofthe electron in clockwise and anticlockwise
direction respectively
@) rotation ofthe electron in anticlockwise and clockwise
direction respectively
(c) magnetic moment of theelectron pointing up and.down
, . . , respectively , ,
(d) two quantum mechanical spin states which have no
classical analogue
32. Rurtherford's experiment, which established the nuclear
model ofthe atom, used a beam of (2002s)
. .
(a) I3-particles, which impinged on a metal foil and got ,;
absorbed . . ' . ..
@) 't -rays, which impinged on a metal foil and ejected
electrons
(c) helium atoms, which impinged on a metal foil and got
scattered
(d) heliumnuelei, which impinged on a metal foil and got
, .
. .
scattered
33. -1fthenitrogen atom has electronic configuration Is7, $ would
have energy lower than that,of the normal ground state
configuration 1s ~2 s ~2 ~' , ' because the electrons would be
closer to the nucleus. Yet Is7 is not observed because i i
violates. . . , (2002s)
(a)- Heisenberg uncertainty principle
. (b) Hund's rule
(c) Pauli exclusion principle
(d) Bohr postulate of stationary orbits
34. The radius of which ofthe following orbit is same as that of
the first BOhr's orbit of hydrogen atom? (200.Is)
(a) Het (n=2) (b) ' ~ i ~ + (n = 2)
. (c) Li2+ (n= 3) (d) Be3+ (n = 2)
35. . Thenumber of radial nodes of 3s and 2p orbitals are
respectively (2005s)
(a) 2,O (b) 0,2
( 4 1,2 (d) 2, 1
36. Given that the abundances of isotopes 54Fe, 5 6 ~ e and 57 Fe
are 5%, 90% and S%, respectively, the atomic mass of Fe is
(a) 55.8s @) 55.95 (2009s)
(c) 55.75 (d) 56.05
37; The kinetic energy of an electron in the second ~ b h r orbit of
'
a hydrogen atom is [ao is Bohr radius] : (2012)
1. An isqtone of z ; ~ e is : (1984 - 1 Mark)
2. Many elements have non-integral atomic masses because :
(1984 - 1 Mark)
(a) they have isotopes
(b) their isotopes have non-integral masses
(c) their isotopes have different masses
(d) the.constitutents, neutrons, protons and klectrons,
combine to give fractional masses
2.-
When alpha particles are sent through a thin metal foil, most
of them go straight through the foil because : .
'
11984 - 1 Mark)
(a) alpha particles are much heavier than electrons
.,
(b) alpha particles are positively chirged
(c) most part of the atom is emptyspace
(d) alpha particle move with high velocity .. ,
4. The sum ofthe numbe;ofneutrons and proton in the isotope
of hydrogen is : .
,
(1986 - 1 Mark) '
(a) 6 . @) 2
, . (c) 4 (dl. 3
5. The energy of an electron in the first Bohr orbit ofH atomis
-13.6 eV. The possible energy value(s) ofthe excited state(s)
for electrons in BO& orbits of hydrogen is (are)
(1998 - 2 Marks)
(a) -3.4eV (b) -4.2 eV
(c) -6,SeV (d) -1.5eV
6. Which of the following satement(s) iS (arejcoriect?
(1998 - 2 Marks)
(a) The electrbnic configuration of ~r is [Ar] 384s' .
(Atomic Number ofCr = 24)
(b) The magnetic quantum number may have a negative
, .
value.
(c) In silver atom, 23 electrons havea spin of one type and
24 ofthe opposite type. (Atomic Number ofAg = 47)
.
(d) The oxidation state of nitrogen in HN3 is -3.
7. Decrease in atomic number is observed during
. .
(1998 - 2 Marks)
(a) alpha emission (b) beta emission
(c) : positron emission (d) electron capture. . .
8. Ground state electronic configuration of nitrogen atom can
be represented by (1999 - 3 Marks)
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I
C-30 Topic-wise Solved Papers - CHEMISTRY
I 1
11. Find out the number of waves made by a Bohr electron in
one complete revolution in its 3rd orbit. (1994 - 3 Marks)
Naturally occurring boron co~. ~i st s of two isotopes whose
atomic weights are 10.01 and 11.01. The atomic weight of
natural boron is 10.81. Calculate the percentage of each
isotope in natural boron. (1978)
Account for the foliowing. Limit your answer to two
sentences: (1979)
Atomic weights of most of the elements are fractional.
The energy ofthe electron in the second and the third Bohr's
orbits of the hydrogen atom is -5.42 x erg and
-2.41 x 10-l2 erg re'spectively. Calculate the wavelength of
the emitted radiation when the electron drops from the third
to the second orbit. (I981 - 3 Marks)
Calculate the wavelength in Angstrom ofthe photon that is
emitted when an electron in the Bohr orbit, n = 2 retuins to
the orbit, n = 1 in the hydrogen atom. The ionization potential
of the ground state hydrogen atom is 2.17 x lo-" erg per
atom. (1982 - 4 Marks)
The electron energy in hydrogen atom is given by
E=(-21.7 x 10-12)ln2 ergs. Calculatethe energy required to
remove an electron completely from then =2 orbit. What is
the longest wavelength (in cm) of light that can be used to
cause this transition? (1984 - 3 Marks)
Give reasons why the ground state outermost electronic
configuration of silicon is : (1985 - 2 Marks)
.IfltlI and not (t.11
7. What is the maximum number of electrons that may be
present in all the atomic orbitals with principal quantum
number 3 and azimuthal quantum number 2?
(1985 - 2 Marks)
8.
According to Bohr's theory, the electronic energy of
hydrogen atom in the nth Bohr's orbit is given by
- 21. 76~10- ' ~ '
E" =
2
J. Calculate the longest wavelength
n
of light that will be needed to remove an electron from the
third Bohr orbit of the Hef ion. (1990 - 3 Marks)
9.
Estimate the difference in energy between 1st and 2nd Bohr
orbit for a hydrogen atom. At what minimum atomic number,
a transition from n = 2 to n = 1 energy level would result in
the emission of X-rays with h=3,0x10-*m? Which
hydrogen atom-like species does this atomic number
correspond to ? (I993 - 5 Marks)
10. What transition in the hydrogen spectrum would have the
same wavelength as the Balmer transition n = 4 to n = 2 of
He+ spectrum? (1993 - 3 Marks)
12. Iodine molecule dissociates into atoms after absorbing light
of 4500 A . If one quantum of radiation is absorbed by each
molecule, calculate the kinetic energy of iodine atoms.
(Bond energy of I, = 240 kJ mol-') (1995 - 2 Marks)
13. Calculate the wave number for the shortest wavelength
transition in the Balmer series of atomic hydrogen.
(1996 - 1 Mark)
Consider the hydrogen atom to be a proton embedded in a
cavity ofradiu. a,, (Bohr radius) whose charge is neutralised
by the addition of an electron to the cavity in vacuum,
infinitely slowly. Estimate the average total energy of an
electron in its ground state in a hydrogen atom as the woik
done in the above neutralisation process. Also, if the
magnitude of the average kinetic energy is half the
magnitude of the average potential energy, find the average
potential energy.
(1996 - 2 Marks)
15. With what velocity should an a-particle travel towards the
nucleus of a copper atom so as to arrive at a distance lo-"
metre from the nucleus of the copper atom?
(1997C- 3 Marks)
16. An electron beam can undergo diffraction by crystals.
Through what potential should a beam of electrons be
accel e~a~ed so that its wavelength becomes equal to 1.54 A.
(1997C - 2 Marks)
17. Calculate the energy required to excite one litre ofhydrogen,
gas at 1 atm and 298 K to the fust excited state of aiomic
hydrogen. The energy for the dissociation of H-H bond is
436kJmoI-'. (2000 - 4 Marks)
18. Wavelength ofhigh energy transition ofH-atoms is 9 1.2nm.
Calculate the corresponding wavelength of He atoms.
(2003 - 2 Marks)
19. The Schrodinger wave equation for hydrogen atom is
(2004 - 2 Marks)
Where a. is-Bohr's radius. If the radial node in 2s be at ro,
then find ro in terms of a,.
A ball of mass 100 g is moving with 100 ms-I. Find its
wavelength. (2004 - 1 Mark)
Find out atomic number and mass number of the element X.
Also identify the element.
Find the velocity (ms-') of electron in first Bohr's orbit of
radius a,. Also find the de Broglie's wavelength (in m). Find
the orbital angular momentum of 2p orbital of hydrogen
atom in units of h I2n. (2005 - 2 Marks)
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STRUCUTRE OPATOM
, c.31
am
Each question contains statements given in two columns, which have to be matched The statements in Column-I are labelled A,
B. C and D, while the statements in Column-11 are labelledp, q, ,: s and t. Any given statement in Column-1 can have correct
matching with ONE OR MORE s{atement(s) in Column-11. The appropriate bubbles corresponding to the answers to these
questions have to be darkened as illustrated in the following example :
Ifthe correct matches are A-p, s and t; B-q andr; C-p andq; andD-s then the correct darkening ofbubbles will look like the given.
~ q . i s t , '
B G90000
c 00000 , .
D G9@080
1. According to Bohr's theoly, ' (2406- 6M)
E,, = Total energy, K,8 = Kinetic energy, V,, = Potential energy, r,) = Radius of nth orbit
Match the following :
Column I Column I1
(A) V, / %=? ,@) 0
) If radius of nth orbit E,X, x = ? (4) -1
(C) Angular momentum in lowest orbital (r) -2
2.
Match the entries in Column I withthe correctly related quantum number@) in Column 11. Indicate your answer by darkening the
appropriate bubbles oft he4 x 4 matrix given in the ORS
(2008 - 6M)
Column I Columnll
(A) Orbital angular momentum of the electron in a (p) Principal quantum number
hydrogen-like atomic orbital
@) A hydrogen-like one-electron wave function ((1) Azi,muthal quantum number
obeying Pauli principle
(C) Shape, size and orientation of hydrogen- like (r) Magnetic quantum number
. ~
atomic orbitals
@) Probability density of electron at the iudleus (s) Electron spin quantum number
in hydrogen-like atom
The hydrogen-like species Liz+ is in a spherically symmetric state
S, with one radial node. Upon absorbing light the ion undergoes
transition to a state S2. The state S, has one radial node and its
energy is equal to the ground state energy ofthe hydrogen atom.
(2010)
1 . The state S, is :
(a) 1 s @) 2s
( ~ 1 2 ~ .. ( 4 3s
2.
Energy ofthe state S, in units of the hydrogenatom gro'und
state energy is :
(a) 0.75. . @) 1.50
(c) 225 (d) 4.50
3. The orbital angul&momentum quantum number ofthe state
S, is : . .
(a) 0 @) 1
(c) 2 (4 3
1. ASSERTION : Nuclide :?-A1 is less stable than 4; Ca
(1998 - 2 Marks)
REASON : Nuclides having odd number of protons and
neutrons are generally'unstable.
(a) If both assertion and reason are correct, and reason is
the correct explanation of the assertion.
'@) If both assertion and reason are correct, but reason is
not the correct explanation of the assertion..
(c) If assertion is correct but reason is incorrect.
(d) If assertion is incorrect but reason is correct.
2. This question contains STATEMENT-1 (Assertion):and
. . STATEMENT-2 (Reason) and has 4 choices (a), (b); (c) and
(d) out ofwhich ONLY ONE is correct.
STATEMENT-1 : Band gap in germanium is small.
because
STATEMENT-2 : The energy gap ofeach germanium atomic
energy level is infinitesimallysmall. (2007)
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I C-32 Topic-wise Solved Papers - CHEMISTRY
I
(a) Statement-1 is True, Statement-2 is True; Statement-:!
is a correct explanation for statement-I I @ - I B
(b) Statement-l is True, Statenrent-2 is True; Statement-2
The work function (+) of some metals is listed belo,w, The
is not a correct explanation for Statement-l
number ofmetals which will show photoelectric effect when
(c) Statement-1 is True, Statement-2 is False
(d) Statement-1 is False. Statement-2 is True. .
light of 300 nm wavelength falls on the metal-is (2011)
3. STATEMENT-1 : he plot of atomic number (y-axis) versus
number of neutrons (x-axis) for stable nuclei shows a
curvature towardsx-axis from the line of 45" slope as the
atomic number is increased.
STATEMENT-2 : Proton-proton e!ectrostatic repulsions
begin to overcome attractive forces involving protons and
neutrons in heavier nuclides. .. (2008)
(a) Statement-1 is True,.Statement-2 is True; Statement-:!
is a correct explanation for Statement-1 .' - ~
(b) Statement-l is ~ i e , statement-2 is True; statem'enG2
is NOT a co=ect explanation for Statement-1
(c) Statement-l is True, Statement-2 is False
(d) Statement-l is ~a l s e , Statement-2 is True
Metal I Li I Na I K I Mg ] Cu 1 Ag 1 Fe 1 Pt 1 W
$(eV) 1 2.4 1 2.3 1 2.2 1 3.7 1 4.8 1 4.3 1 4.7 1 6.3 14.75
2. The maximum number of electrons that can have principal
1 .
quantum numbe:; n = 3, and spin quantum m, = --, 1s
2
(2011)
3. The atomic masses of 'He' and 'Ne' are 4 and 20 a.m.u.,
respectively. The value ofthe de Broglie wavelengthof 'He'
gas at-73C is"M" times that ofthe de Broglie wavelength
of 'Ne' at 727C 'M' is (JEEAdv. 2013)
I $ JEE Main/ AlEEE
. 1. In a hydrogen atom, if energy of an electron in ground state 6.
is 13.6. ev, then that in the 2"* excited state is [ZOO21
(a) 1.51 eV (b) 3.4eV
(c) 6.04eV (d) 13.6eV.
2. Uncertainty in position of a minute particle of mass 25 g in
space is 10"~m. What is the uncertainty in its velocity
(in ms-I) ? (h = 6.6 x 1 0-34 JS)
7.
I
. ' [2002]
(a) 2.1 ~ ~ 1 0 " ~ ' '
(b) 0.5 x
(c) 2.1 x (d) 0.5 x
3. The number of d-electrons retained in Fez+ (20031
(At. no.of Fe = 26) ion is
(a) 4 (b) 5. 8.
(cl 6 (d) 3.
4. The orbital angular momentum for anslectron revolving in
In Bohr series of lines dfhydrogen spectrum, the third line
from thered end corresponds to d i c h one ofthe following
inter-orbit jumps of the eleckon 'for Bohr orbits in an atom'
of hydrogen . , [ZOO31
(a) 5 -+ 2 . . ( b) 4 + l
(c) 2 + 5 (d) 3 + 2
The de Broglie wavelength of a tennis ball of mass
60 g
moving with a velocity o f 10 metres per second is
, >
approjtimately . .
. .
(20031
(a) 10~"met r es (b) 10-16metres ' ,
(c) 10-25.metres , (d) 10-33metres
~lanck' s constant, h=.6.63 x .IS
-
Which of the following sets of quantum numbers is correct
for an electron in 4f orbital ? [2OO4l
(a) n=4, ! =3, m=+l , s=+%
I
h (b) n=4,!=4,m=-4, s=-%
an orbit is given by m.%. This momentum for an
(c) 0=4, t =3, m=+4, s =+! h
s-electron will be given by [ZOO31
(a) zero
1 h
(d) +-.-
2 2n
\
5. Which one of the following groupings represents a
collection of isoelectronic species ?(At. nos. : Cs : 55,
Br: 35) 120031
(a) N3-, F, Na+ (b) ~ e , AP+, Cl-
(c) Caz", Cs', Br (d) Na+, Ca2+, MgZ+
(d) n=3, 1=2, m=- Z, s=+%
9. Consider the ground state of Cr atom (X = 24). The number
of electrons with the azimuthal quantum numbers, e = 1 and
2 are, respectively [2004]
(a)- 16and4 @) 12and5
(c) 12&d4 ' ' (d) 16and5
10. The wavelength oftheradiation emitted, when in a hydrogen
atom electron falls from infinity to stationary state 1, would
be (Rydberg constant = 1. 097~ 107m-I) I20041
(a) 406nm (b) 192nm , '
(c) 91nm (d) 9.1x104nm
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Tel:0120-4616500 Ext - 204
11.
Which one of the following sets of ions represents the
collection of isoelectronic species? [2004]
(a) K+, CI; MgZ+, Sc3+ (b) NaC, CaZf, Sc3+, F-
(c) KC, Ca2+, Sc3+, Cl- (d) ~ a + ; Mg2+, APf, CI- . .
, ( ~t omi c nos. : F = 9, CI =,I?, Na= 11, Mg = 12,A1= 13,
K=19,Ca=20,Sc=21)
12.
In a multi-electron atom, whicli of the .foliowing oibitals
described by the three quantum members will have the sanie
energy in the absence i f magnetic and electric fields?
, ~
120051
(A) n=l , / =O, m=@ (B) n=2, 1=0, m=O
(C) n=2, l =l , m=l @) n=3, / =2, m=l
(E) n=3,1=2,m=O
(a) ( D) and( ~) , - (b) (C)and(D)
( 4 (B) and (C) (d) (A) and (B) ,
13. Of the following sets which onedoes,NOT contain
isoelectronic species? , [2005]'
(c) CN-, N2, c:- (d) PO:-, SO:-, C104
14. According to Bohr's theory, the angular momentum of an
electron in 5Ih orbit is
120061
(a) I Ohl n , .(b) 2. 5hl n
(c) 25 h/ n (d) 1.0 h l n
15.- uncertainty in the position of an electron (mass = 9.1 x
lo5' kg) moving with a velocity 300 ms-I, accurate upto
O.OOl%will be 120061
(a) 1.92~10-Zm (b) 3.84 x 10-2m~
(c) 19.2x10-Zm " (d) 5.76 x 10-Zm
(h=6.63 x 10-34Js)
16. Which one of the following sets of ions represents a
collection of isoelectronic species? [2006] . ,
(a) N3-, 02-, F, Sz-
(b) LiC, Na+, Mg2+, Ca2+ _
(c) K+, CI-, Caz+, Sc3+ (d) Baz+, S$+, Kc, Ca2+
17. Which ofthe following sets of quantum numbers represents
the highest energy of an atom? 120071
(a) n=3, 1=0, m=O, s ~+I / 2
(b) n=3, l = I,m=.l,s=+1/2
(c) n=3, 1=2, m=l , s=+1/ 2
(d) n=4,l=O,m=O,s=+li2.
18. Which one of the following constitutes a group of the
isoelectronic species? [2008]
(c) CN;,N~,O?,C:- ( 4 N 2 , 0 ~ , N O f , ~ 0
19. The ionization enthalpy of hydrogen atom is 1.312 x lo6 J
mol-I. The energy required to excite the electron in the atom
f r omn=l t on=2i s [2008]
. ..
(a) ' 8.51 x 10SJmol-l (b) 6.56 x 1OSJmol-'
(c) 7.56 x 10SJmol-' (d) 9.84 x 1OSJmoI-'
20. Calculate the wavelength (in nanometer) associated,with a
proton moving at 1.0 x lo3 ms-I.
(Mass of proton = 1.67 x kg and h = 6.63 x
Js)
(a)' OAOnm (b) 2.5 nm [2009]
(c) 14.0im (d) 0.32nm . . . .
21. 1nan atom, an electron is moving with a speed of 600 mls
with an accuracy of 0.005%. Certainity with which the' ',
- . position ofthe electron can belocated is ( h = 6.6 x loJ4 kg
m2s:', mass ofelectron, em =9.1 x loJ1 kg) : 120091 .
(a) 5.'10;10-~m (b) 1 . 9 2 ~ 10- ~m
(c) 3 . 8 4 ~ 10"m (d) 1.52 x 104m
22. The energy required to break one mole bf C1 - CI bonds in
C12 is 242 kJ mol-I. The longest wavelength of light capable
- .
of breaking a'single CI- CI bond is
(c= 3 x 1 Ox ms-I and NA = 6.02 x 1.OZ3 mol-I). [2010j . .
(a) 594nm (b) .640nm
(c) 700nm (d) 494nm
23. Ionisation energy of Hei is 19.6 x 10- l ~ J atom!'. The energy
-
of the first stationary state (h = 1)of Liz+ is [ t ol o]
(a) 4.41 x 10-l6 Jatom-I (b) 4 . 4 1 x 10-l7 Jatom:'
(c) -2.2 x 10-Is J atom-' (d) 8.82 x 10-l7 Jatom-'
24. A gas absorbs a photon of 355 nm and emits at two
wavelengths. If one of the ~. emissions . is at 680 nm, the other
is at: [2011]
(a) l035nm (b) 325nm
(c) * 743 nm (d) 518nm .-
. .
25. The frequency of light emitted forthe transition n =4 to n =
2 ofthe He' is eqtial.to the transition in H atom corresponding
to which ofthe following'? [2OllRSJ , .
(a) n =2 t o n L1 (b) n = 3 t o n = 2
(c) n =4 t o n ? (d) n = 3 t o n = l
26. The electrons identified by quantum numbers n and e :
.
. .
(A) n=4;!=1 (B) n=4, e =0
(C) n=3,!=2 (D) n=3, e =1
can be placed in order of increasing energy as : [2012]
( ~) . ' ( c) <( D) <( B) <( A) . @) (D)<(B)<(c)<(A)
(4 (B) < (D) <(A) < ( C) (4 (2) < (C) < (B) <(Dl
Wavelength of light required to excite an electron in an
' .
hydrogen atom from leveln = 1 t on= 2 will be.:
( h ~ 6 . 6 2 ~ JS andc=3, 0x 108ms-I) lJEEM2013j
(a) 1. 214~10- ~r n (b) 2.816 10.-~m - '
(c) 6. 56 x m (d) 8.500 x 10- ~m
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