CHEMISTRY

HIGHER LEVEL
PAPER 1
Tuesday 16 May 2000 (afternoon)
1 hour
M00/420/H(1)
INTERNATIONAL BACCALAUREATE
BACCALAURAT INTERNATIONAL
BACHILLERATO INTERNACIONAL
220-203 16 pages
INSTRUCTIONS TO CANDIDATES
! Do not open this examination paper until instructed to do so.
! Answer all the questions.
! For each question, choose the answer you consider to be the best and indicate your choice on the
answer sheet provided.
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2 M00/420/H(1)
220-203
1. According to the equation:
2 2
2 2 3
SO (g) O (g) SO (g) ! "
what volume of air (20 % ) is required to react with 10 of ? O
2
dm
3
SO
2
A. 2 dm
3
B. 5 dm
3
C. 10 dm
3
D. 25 dm
3
2. Which of the following compounds has the greatest empirical formula mass?
A. C H
6 6
B. C H
4 10
C. C H
3 6
D. C H
2 6
3. CaCO (s) CaO(s) CO (g)
3 2
+
When heated, decomposes as shown above. When 20 g of impure is heated, CaCO
3
( ) M
r
# 100 CaCO
3
0.15 moles of are obtained. What is the percentage purity of the ? (Assume that none of the CO
2
CaCO
3
impurities produce upon heating.) CO
2
A. 15
B. 25
C. 55
D. 75
3 M00/420/H(1)
220-203 Turn over
4. v w x y z C H Cl(g) O (g) CO (g) H O(g) HCl(g)
2 3 2 2 2
+ + +
Chloroethene can be burned in oxygen as shown above. What is the value of w when ? v = 2
A. 2
B. 3
C. 4
D. 5
5. Which of the following particles contain more electrons than neutrons?
I.
1
1
H
II.
17
35
Cl
$
III.
19
39
K
!
A. I only
B. II only
C. I and II only
D. II and III only
6. The first four ionisation energies for a particular element are 550, 1064, 4210 and 5500 ( ) kJ mol
$1
respectively. This element should be placed in the same Group as
A. Li
B. Be
C. B
D. C
4 M00/420/H(1)
220-203
7. A certain element with two isotopes of masses M and is introduced into a mass spectrometer, M ! 2
vaporised and ionised. Which of the following paths are most likely for the resulting ions?
+

I
II
III
IV
M M ! 2
A. I IV
B. II I
C. IV III
D. IV II
8. A certain element has the electronic configuration . Which oxidation state(s) 1 2 2 3 3 4 3
2 2 6 2 6 2 3
s s p s p s d
would this element most likely show?
A. +2 only
B. +3 only
C. +2 and +5 only
D. +2, +3, +4, +5
9. Which one of the following increases in value from Li to Cs?
A. Atomic radius
B. Electronegativity
C. Ionisation energy
D. Melting point
5 M00/420/H(1)
220-203 Turn over
10. Which of the following chlorides give neutral solutions when added to water?
I. NaCl
II. Al Cl
2 6
III. PCl
3
A. I only
B. I and II only
C. II and III only
D. I, II and III
11. In which of the following is there at least one double bond?
I. O
2
II. CO
2
III. C H
2 4
A. I only
B. III only
C. II and III only
D. I, II and III
12. According to VSEPR theory, which molecule would be expected to have the smallest bond angle?
A. H O
2
B. H CO
2
C. CH
4
D. NH
3
6 M00/420/H(1)
220-203
13. Which of the following can exist in both polar and non-polar forms?
A. CH Cl
2 2
B. C HCl
2
C. C H Cl
2 2 2
D. C H Cl
2 3
14. What are the states of hybridisation for the carbon atoms in ? NCCH COOH
2
CN COOH CH
2
A. sp sp
3
sp
2
B. sp sp
2
sp
3
C. sp
2
sp
2
sp
3
D. sp
2
sp
3
sp
2
15. Which of the following best accounts for the observation that gases are easily compressed?
A. Gas molecules have negligible attractive forces for one another.
B. The volume occupied by the gas is much greater than that occupied by the molecules.
C. The average energy of the molecules in a gas is proportional to the absolute temperature of the gas.
D. The collisions between gas molecules are elastic.
16. Which expression represents the density of a gas sample of relative molar mass, , at temperature, T, M
r
and pressure, P?
A.
PM
T
r
B.
RT
PM
r
C.
PM
RT
r
D.
RM
PT
r
7 M00/420/H(1)
220-203 Turn over
17.
400 800 1200 1600
10
30
50
Energy added / J
T
e
m
p
e
r
a
t
u
r
e

/

C
The heating curve for 10 g of a substance is given above. How much energy would be required to melt
completely 20 g of the substance that is initially at C? 10
!
A. 2400 J
B. 1200 J
C. 800 J
D. 400 J
18. N (g) O (g) NO(g)
N (g) O (g) NO (g)
2 2
2 2 2
2
2 2
! "
! "

H
H
#
#
180 4
66 4
.
.
kJ
kJ
Use the enthalpy values above to calculate H for the reaction;
NO(g) O (g) NO (g) +
1
2
2 2
A. 57 kJ
B. 114 kJ
C. 57 kJ
D. 114 kJ
8 M00/420/H(1)
220-203
19. In which reaction is the change in entropy (S) closest to zero?
A. SO (g) O (g) SO (g)
2
1
2
2 3
! "
B. Br (l) Br (g)
2 2
"
C. H (g) I (g) HI(g)
2 2
2 ! "
D. 3
2 3 2
Ca(s) N (g) Ca N (s) ! "
20. The BornHaber cycle for the formation of potassium chloride includes the steps below:
I. K(g) K (g) e " !
! $
II.
1
2
2
Cl (g) Cl(g)
III. Cl(g) e Cl g) ! "
$ $
(
IV. K (g) Cl (g) KCl(s)
+
! "
$
Which of these steps are exothermic?
A. I and II only
B. III and IV only
C. I, II and III only
D. I, III and IV only
21. Some collisions between reactant molecules do not form products. This is most likely because
A. the molecules do not collide in the proper ratio.
B. the molecules do not have enough energy.
C. the concentration is too low.
D. the reaction is at equilibrium.
9 M00/420/H(1)
220-203 Turn over
22. Doubling which one of the following will double the rate of a first order reaction?
A. Concentration of the reactant
B. Size of solid particles
C. Volume of solution in which the reaction is carried out
D. Activation energy
23. F (g) ClO (g) FClO (g)
2 2 2
2 2 +
The following data were obtained for the reaction above. Use these data to determine the orders for the
reactants and . F
2
ClO
2
[F (g)] / mol dm
2
3 33 3
[ClO (g)]/ mol dm
2
3 33 3
Rate / mol dm s
3 1
0.1 0.01 12 10
3
.

0.1 0.04 4 8 10
3
.

0.2 0.01 2 4 10
3
.

Order of reaction
F
2
ClO
2
A. 1 1
B. 1 2
C. 2 1
D. 2 4
24. 2 2 197 8
2 2 3
SO (g) O (g) SO (g) kJ ! # $ ! H .
The reaction above is an important step in the production of sulfuric acid. An increase in which of the
following will increase the ratio of at equilibrium?
SO (g)
SO (g)
3
2
A. Pressure only
B. Temperature only
C. Both temperature and pressure
D. Neither pressure nor temperature
10 M00/420/H(1)
220-203
25. 2
2 3
H O(l) H O (aq) OH (aq) !
! $
!
The equilibrium constant for the reaction above is at C and at C. What can 10 10
14
. %
$
25
!
21 10
14
.

35
!
be concluded from this information?
A. decreases as the temperature is raised. [ ] H O
3
+
B. is greater than at C. [ ] H O
3
+
[ ] OH
$
35
!
C. Water is a stronger electrolyte at C. 25
!
D. The ionisation of water is endothermic.
26. N (g) H (g) NH (g)
2 2 3
3 2 ! !
What is the equilibrium expression for the reaction above?
A. K
c
NH
N H
#
[ ]
[ ][ ]
3
2 2
B. K
c
NH
N H
#
2
3
2 2
[ ]
[ ][ ]
C. K
c
NH
N H
#
2
3
3
2 2
[ ]
[ ][ ]
D. K
c
NH
N H
#
[ ]
[ ][ ]
3
2
2 2
3
27. 10 of an HCl solution with a pH value of 2 was mixed with 90 of water. What will be the pH cm
3
cm
3
of the resulting solution?
A. 1
B. 3
C. 5
D. 7
11 M00/420/H(1)
220-203 Turn over
28. CH COOH(aq) H O(l) H O (aq) CH COO (aq)
3 2 3 3
! !
! $
!
In the equilibrium above, what are the two conjugate bases?
A. and CH COOH
3
H O
2
B. and CH COO
3
$
H O
3
!
C. and CH COOH
3
H O
3
!
D. and CH COO
3
$
H O
2
29. Which of the following is the weakest acid in aqueous solution?
A. C H OH
6 5
K
a
# %
$
13 10
10
.
B. HCN K
a
# %
$
4 9 10
10
.
C. H Se
2
K
a
# %
$
15 10
4
.
D. HF K
a
# %
$
6 9 10
4
.
30. Which salt will produce the most alkaline solution when dissolved in water?
A. KNO
3
B. MgCl
2
C. CH CO Na
3 2
D. NH SO
4
2
4
b g
31. In the electrolysis of molten sodium chloride, the sodium ion goes to the
A. positive electrode where it undergoes oxidation.
B. negative electrode where it undergoes oxidation.
C. positive electrode where it undergoes reduction.
D. negative electrode where it undergoes reduction.
12 M00/420/H(1)
220-203
32. Which one of the following could reduce to ? Cr O aq
2 7
2
( ) Cr aq
3+
( )
A. Ca aq
2+
( )
B. Cu aq
2+
( )
C. Fe aq
2+
( )
D. Zn aq
2+
( )
33. Tl (aq) e Tl(s) V
Cu (aq) e Cu(s) V
+
+
+ =
+ =
E
E

0 336
2 0 339
2
.
.
The standard electrode potentials for two metals are given above. What are the equation and cell potential
for the spontaneous reaction that occurs?
A. Tl (aq) Cu (aq) Tl(s) Cu(s) V
+ +
+ + =
2
0 003 E

.
B. 2Tl(s) Cu (aq) Tl (aq) Cu(s) V + + =
+ + 2
2 0 675 E

.
C. 2Tl(s) Cu (aq) Tl (aq) Cu(s) V + + =
+ + 2
2 1011 E

.
D. 2Tl (aq) Cu(s) Tl(s) Cu (aq) V
+ +
+ + = 2 0 333
2
E

.
34. When molten magnesium chloride is electrolysed, how many moles of gaseous chlorine will be produced
for every mole of magnesium?
A.
1
2
B. 1
C. 2
D. 4
13 M00/420/H(1)
220-203 Turn over
35. Which names are correct for the following isomers of ? C H
6 14
I. 2-methylpentane CH CH
3
CH
3
CH
2
CH
2
CH
3
II. 2-ethyl-2-methylpropane C CH
3
CH
2
CH
3
CH
3
CH
3
III. 2,3-dimethylbutane CH CH
3
CH
3
CH CH
3
CH
3
A. I only
B. I and II only
C. I and III only
D. I, II and III
14 M00/420/H(1)
220-203
36. Which of the compounds below will show a single peak in its spectrum?
1
H-NMR
I. C CH
3
CH
3
CH
3
CH
3
II. C CH
3
O
O CH
3
III. CH
3
CH
2
OH
A. I only
B. III only
C. I and II only
D. I, II and III
37. What is the correct order of reaction types in the following sequence?
C H Cl
I
C H OH
II
CH COOH
III
CH COOCH
2 5 2 5 3 3 3
" " "
I II III
A. substitution oxidation esterification
B. addition substitution substitution
C. oxidation substitution addition
D. substitution oxidation substitution
38. Which carbon-containing product is most likely from the reaction of and ? C H
2 4
Br
2
A. C H Br
2 5
B. C H Br
2 4 2
C. C H Br
2 3
D. C H Br
2 2 2
15 M00/420/H(1)
220-203 Turn over
39. Which of the following is expected to be a gas at C? 25
!
A. C CH
3
CH
3
O
B. CH
2
CH
3
C H
O
C. O CH
3
CH
2
CH
3
D. C CH
3
OH
O
40. Which of the compounds below is/are more likely to undergo substitution, rather than addition, reactions?
I. CH CHCH
3 2
II. CH CCl
3
3
b g
III. C H
6 6
A. I only
B. II only
C. I and III only
D. II and III only
16 M00/420/H(1)
220-203