Symrise: Uv Protection Systems

Symrise, always inspiring more 1
SYMRISE
UV PROTECTION SYSTEMS
Wavelength (nm).
THE ELECTROMAGNET
SPECTRUM
COSMIC
RAYS
GAMMA
RAYS
X-RAYS
VACUUM
UV
UV
VISIBLE INFRARED
MICRO-
WAVES
RADIO
WAVES
200 290 320 340 400
VACUUM
UV
MIDDLE-WAVE UV
UV-B
LONG-WAVE UV
UV-A
VISIBLE
LIGHT
SHORT-WAVE UV
UV-C
UVA II UVA I
COMPOSITION OF RADIATION
REACHING THE SKIN
> Infra red 56%
> Visible 39%
> UVA 4.9%
> UVB 0.1%
70% of UVB
is absorbed by
Stratum Corneum
UVR
Hair Shaft
Sebaceous
Glands
Arteriole
(blood supply)
Veinlet
(blood supply)
Sweat
Glands
Dermis (1000 to 4000 m)
Subcutaneous
Tissue
UVA penetrates
to the Dermis where it is
absorbed by the structural
proteins (Collagen/Elastin)
promoting wrinkling
Stratum Corneum
(10 to 20 m)
UVA UVB
PENETRATION OF UV RADIATION
THROUGH THE SKIN
PRODUCT
RANGE
> The Neo Heliopan
product range contains a comprehensive

selection of UV absorbers that play an important role world-wide.
This versatility affords the formulator a high degree of flexibility in
developing suncare and cosmetic products for daily use.
PRODUCT RANGE
water-soluble UV-B Phenylbenzimidazole
Sulfonic Acid
Hydro
oil-soluble UV-A Butyl
Methoxydibenzoylmethane
357
oil-soluble UV-B Isoamyl p-Methoxy-
cinnamate
Galanga
natural sunscreen
oil-soluble UV-B Isoamyl p-Methoxy-
cinnamate
E 1000
nature-identical
oil-soluble UV-B Ethylhexyl
Methoxycinnamate
AV
Solubility Type of UV
Absorber
INCI Name Neo Heliopan
Product
PRODUCT RANGE
water-soluble UV-A Disodium Phenyl
Dibenzimidazole
Tetrasulfonate
AP
oil-soluble UV-A Menthyl Anthranilate
MA
oil-soluble UV-B and UV-A Benzophenone-3
BB
oil-soluble UV-B Homosalate
HMS
oil-soluble UV-B 4-Methylbenzylidene
Camphor
MBC
oil-soluble UV-B Ethylhexyl Salicylate
OS
oil-soluble UV-B Octocrylene
303
Solubility Type of UV
Absorber
Product
> The UV absorber range is complemented by Zinc Oxides.
PRODUCT RANGE
oil and water
phase
UV-B and UV-A Zinc Oxide
Zinc Oxide Pi
oil phase UV-B and UV-A Zinc Oxide, Dimethicone
Zinc Oxide NDM
oil and water
phase
UV-B and UV-A Zinc Oxide
Zinc Oxide neutral
Dispersability Type of UV
Absorber
INCI Name Product
+ approved
o not approved
Part 1
PRODUCT RANGE
PRESENT LEGISLATION IN KEY MARKETS
+ + +
+ 303
+ + +
+ 357
+ + +
+ Hydro
+ 0 0
+ E 1000 and Galanga
+ + +
+ AV
AUSTRALIA JAPAN USA EU Neo Heliopan

+ approved
o not approved
Part 2
PRODUCT RANGE
+ 0 0
+ AP
+ 0 + 0
MA
+ + +
+ BB
+ + +
+ HMS
+ 0 0
+ MBC
+ + +
+ OS
AUSTRALIA JAPAN USA EU Neo Heliopan

PRODUCT RANGE
Approval
10
*1
6
10 Oil UV-B/UV-
A
Benzophenone 3
BB
10 0
0
10
Water UV-A
Disodium Phenyl Dibenzimidazole
Tetrasulfonate
AP
15
10
15 10 Oil UV-B
Homosalate HMS
4
0 0
4 Oil UV-B
4-Methylbenzylidene Camphor
MBC
5 10 3
5
Oil UV-A
Butyl Methoxydibenzoylmethane
357
10
10 10 10 Oil UV-B Octocrylene 303
4 3 4 8 Water UV-B
Phenylbenzimidazole Sulfonic Acid
HYDRO
5 10 5 5 Oil UV-B
Ethylhexyl Salicylate (Octyl Salicylate)
OS
10
0 0 10 Oil UV-B
Isoamyl p-Methoxycinnamate
GALANGA
5
0 5
0 Oil UV-A
Menthyl Anthranilate MA
10 0 0 10
Oil
UV-B
Isoamyl p-Methoxycinnamate E1000
10 10 7.5 10 Oil UV-B
Ethylhexyl Methoxycinnamate (Octyl
Methoxycinnamate)
AV
AU JP US EC Solubility UV-filter
Typ
Max conc. in "%" ; "0" not approved
*1rinse-off 100%, leave-on 5%, mucous membranes 5%
Neo Heliopan
AV AND E1000
Neo Heliopan
AV AND E1000
EEC: max. 10 %
USA: not approved
Japan: not approved
Canada: not approved
Australia: max. 10 %
South Africa: max. 10 %
Brazil: max. 10 %
EEC: max. 10 %
USA: up to 7.5 %
Japan:
rinse-off: max. 20%
leave-on: max.20%
mucous memb.: max. 8%
Canada: max. 8,5%
Australia: max. 10 %
Brazil: max. 10 %
Approved dosages:
approved in EEC
USA: approval applied for
World-wide approved
Regulations:
Isoamyl p-Methoxycinnamate Ethylhexyl Methoxycinnamate
INCI Name:
E 1000 (656083) AV (660523) Neo Heliopan

Neo Heliopan
AV AND E1000
Neo Heliopan
AV
0,0
0,1
0,2
0,3
0,4
0,5
0,6
0,7
0,8
0,9
1,0
1,1
250 260 270 280 290 300 310 320 330 340 350
1%
E
1cm
UV-C UV-B UV-A
wavelength in nm
Neo Heliopan
E 1000
0,0
0,1
0,2
0,3
0,4
0,5
0,6
0,7
0,8
0,9
1,0
1,1
250 260 270 280 290 300 310 320 330 340 350
1%
E
1cm
UV-C UV-B UV-A
wavelength in mm
Neo Heliopan
AV AND E1000
oil-soluble, not soluble in water;
higher solvent capacity than Neo
Heliopan AV for crystalline and oil-
soluble ingredients
oil-soluble, not soluble in water;
excellent solvent for crystalline and oil-
soluble ingredients
Solubility:
liquid (- 30C) liquid (- 10C)
Condition:
E 1000 (656 083) AV (660 523) Neo Heliopan

> Increase in SPF (sun protection factor) through the use of a
combination of Neo Heliopan
E1000 and AV
Neo Heliopan
AV AND E1000
7.4 (+ 48 %) 3.75 % E 1000 and
3.75 % AV
(Total: 7.5 %)
6.3 (+ 26 %) 2.5 % E 1000 and
2.5 % AV
(Total: 5.0 %)
5.0 7.5 % AV
Sun Protection Factor
Mean SPF (FDA) on 15
Subjects
Quantities used in an O/W
Emulsion
Neo Heliopan
AV AND E1000
IMPORTANT PROPERTIES
> Broadly used as essential UV-B absorbers
> Excellent UV-B absorbers for UV-broadband protection products
> Excellent UV-B absorbers for waterproof products
> Very good compatibility to the skin; comprehensive safety studies
> Moderate photostability
> Easily to incorporate into emulsions; cold processing possible
> Excellent compatibility with cosmetic ingredients
NEO HELIOPAN
AV AND E1000
> Excellent solvent for crystalline and oil-soluble UV absorbers;
E1000 has a higher solvent capacity than AV
> Combinations of AV and E 1000 in sunscreen products can increase
the effectiveness (SPF)
> E 1000 is the only frequently used sunscreen which is found in nature
> Synthetically produced Isoamyl p-Methoxycinnamate is identical to the
p-Methoxycinnamic Acid Isoamyl Ester that is found in the nature; E 1000
is therefore "nature-identical"
Neo Heliopan
GALANGA
> Chemically identical to the synthetic Isoamyl p-Methoxycinnamate
(Neo Heliopan E1000)
> A very safe and effective natural UV-B absorber
> A patent application has been filed for manufacturing process and
employment in cosmetic products
> Registered as a UV filter
> Price indication: /kg 1.000,00
> Marketing strategy:
application to: high class products
niche products
Neo Heliopan
GALANGA
Neo Heliopan
HYDRO
Neo Heliopan
HYDRO
EEC: max. 8 %
USA: up to 4 %
Japan: rinse-off: max. 3%
leave-on: max.3%
mucous memb.: not allowed
Canada: max. 8%
Australia: max. 4%
Brazil: max. 8%
Approved dosages:
World-wide approved
Regulations:
Phenylbenzimidazole Sulfonic Acid
INCI Name:
Hydro (103089) Neo Heliopan

Neo Heliopan
HYDRO
1%
E
1cm
0
0,1
0,2
0,3
0,4
0,5
0,6
0,7
0,8
0,9
1
1,1
250 260 270 280 290 300 310 320 330 340 350 360 370 380 390 400
Wavelenght in nm
UV-C UV-B UV-A
Neo Heliopan
HYDRO
> Condition
fine crystalline powder
> Solubility
The free acid is not water-soluble. With the addition of a base, Hydro forms highly
water-soluble salts.
> Commonly used bases
Triethanolamine
Sodium Hydroxide
Monoethanolamine
Tetrahydroxypropyl Ethylenediamine
> Quantity of base for the neutralization of 100 g Hydro
approx. 54.4 g
approx. 14.6 g
approx. 22.3 g
approx. 110.0 g
Triethanolamine
Sodium Hydroxide
Monoethanolamine
Tetrahydroxypropyl
Ethylenediamine
> Recommended pH value in finished products: 7.0 to 7.5
Neo Heliopan
HYDRO
> Solubility of Hydro (calculated as free acid):
when neutralized with Triethanolamine
when neutralized with Sodium Hydroxide
when neutralized with Potassium Hydroxide
approx. 56 g Hydro in 100 g of water
> Equivalence points of the neutralization curves when neutralized with:
Triethanolamine
Monoethanolamine
Sodium Hydroxide
Tetrahydroxypropyl Ethylenediamine
pH value 6.0
pH value 6.9
pH value 7.9
pH value 6.1
Neo Heliopan
HYDRO
> Neutralization curve of Neo Heliopan
Hydro
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
ml neutralizing agent
p
H

v
a
l
u
e
0.1 mol/l sodium hydoxide
0.1 mol/l triethanolamine
> SPF results of sunscreen formulations with different dosages
Neo Heliopan
HYDRO
4,0 3,0 2,0 1,0 % Dosage Neo
Heliopan
Hydro
10,3 8,0 6,7 4,6 SPF
H 102-11-9 H 102-11-8 H 102-11-7 H 102-11-6 Formulation No.:
4,6
6,7
8
10,3
Sun Protection Factor (FDA Method)
> Increase in sun protection factor through the use of a combination
of Hydro and AV or E 1000
Neo Heliopan
HYDRO
7.4 (DIN) 1.5 % E 1000 and
1.0 % Hydro
4.4 (DIN) 3.5 % E 1000
10.4 (DIN) 3.0 % AV and
1.0 % Hydro
4.1 (DIN) 4.0 % AV
8.7 (DIN) 2.5 % AV and
0.5 % Hydro
3.5 (DIN) 3.0 % AV
Sun Protection Factor
(SPF)
Quantities used in an O/W
Emulsion
> Hydro is one of the most effective UV-B absorbers
> A tremendous SPF increase could be reached by combining Hydro with
AV or E 1000 in sunscreen products. Only a minimum of concentration
of these combinations is necessary to achieve the desired SPF
> Hydro is very suitable for water-based transparent sunscreen products
such as gels or sprays
> It is possible to formulate waterproof sunscreen products with Hydro
> Excellent photostability
Neo Heliopan
HYDRO
Neo Heliopan
303
Neo Heliopan
303
EEC: max. 10 %
USA: max. 10 %
leave-on: max.10%
Canada: max. 12%
Australia: max. 10%
Brazil: max. 10 %
Approved Dosage:
World-wide approved Regulations:
Octocrylene INCI Name:
303 (600154) NEO HELIOPAN

0,0
0,1
0,2
0,3
0,4
0,5
0,6
0,7
0,8
0,9
1,0
1,1
250 260 270 280 290 300 310 320 330 340 350 360 370 380 390
1%
E
1cm
UV-C UV-B UV-A
wavelength in nm
Neo Heliopan
303
Neo Heliopan
303
> Used in combination with other UV-B absorbers to formulate high SPF
sunscreen products.
> Can improve the in-vitro photostability of Butyl Methoxydibenzoylmethane
> Excellent UV-B absorber to formulate waterproof sunscreen products
because of its very high resistance to water wash-off.
> Shows remarkable protection in the shorter UV-A range (320 to 340 nm).
> Is excellent photostable.
> Easily to incorporate into emulsions.
> Cold processing of sunscreen products possible.
> Excellent solvent for crystalline and oil-soluble UV absorbers and
cosmetic ingredients.
Neo Heliopan
MBC
Neo Heliopan
MBC
EEC: max. 4 %
Canada: max. 6%
Australia: max. 4%
Brazil: max. 4 %
Approved dosages:
EEC: approved
USA: approval applied for
Japan: not approved
Regulations:
4-Methylbenzylidene Camphor
INCI Name:
MBC (600266) NEO HELIOPAN

0,0
0,1
0,2
0,3
0,4
0,5
0,6
0,7
0,8
0,9
1,0
1,1
250 260 270 280 290 300 315 320 330 340 350
1%
E
1cm
UV-C UV-B UV-A
wavelength in nm
Neo Heliopan
MBC
Neo Heliopan
MBC
> Highly effective; care must be taken to ensure that MBC is completely
dissolved (excellent solvents are E 1000, AV, 303, OS, HMS and MA)
> MBC is excellent in waterproof sunscreen products as it is not soluble in
water; in combination with AV, E 1000 and 303, high SPF waterproof
sunscreen products can be formulated
> MBC can improve the in-vitro photostability of Butyl
Methoxydibenzoylmethane
Neo Heliopan
357
Neo Heliopan
357
EEC: max. 5%
USA: max. 3% (only with certain UVB Filters)
leave-on: max. 10%
Canada: max. 5%
Australia: max. 5%
Brazil: max. 5 %
Approved dosages:
World-wide approved
Regulations:
Butyl Methoxydibenzoylmethane
INCI Name:
357 (622501) NEO HELIOPAN

Neo Heliopan
357
wavelength in mm
> The most important UV-A filter in world.
> Maximum absorption is at 357nm with a specific extinction of about 1100
and it has additional absorbing properties in the UVA II spectrum
> Highly effective; care must be taken to ensure that 357 is completely
dissolved (excellent solvents are E 1000, AV, 303, OS, HMS and MA)
> Neo Heliopan 357 should be used in association with effective UVB
absorbers to achieve formulations with broad-spectrum protection.
> In combination with the water soluble UVA II absorber Neo Heliopan
AP very broad spectrum UVA protection products can be formulated
Neo Heliopan
357
> When formulating with Neo Heliopan 357 a chelating agent should be
added to the oil phase of the emulsion to avoid the formation of colored
complexes with free metal ions such as iron.
> The use of formaldehyde doning preservative systems, or preservation
systems with reactive methylene groups, should be avoided since these
species react with Neo Heliopan 357 at temperatures above 30C. This
results in loss of preservation in the formulation.
> The combination of Neo Heliopan 357 and Zinc Oxide can interact to
form a complex which may precipitate out
> Neo Heliopan 303 and Corapan TQ (Diethylhexyl 2,6-Naphthalate)
can improve the photostability of Neo Heliopan 357
Neo Heliopan
357
IMPORTANT ADVICES FOR FORMULATIONS
Neo Heliopan
OS & HMS
Neo Heliopan
OS & HMS
EEC: max. 10%
USA: max. 15%
leave-on: max. 10%
Canada: max. 15%
Australia: max. 15%
Brazil: max. 15 %
EEC: max. 5%
USA: max. 5%
leave-on: max. 10%
Canada: max. 6%
Australia: max. 5%
Brazil: max. 5 %
Approved dosages:
worldwide approved worldwide approved
Regulations:
Homosalate Ethylhexyl Salicylate
INCI Name:
HMS (182573) OS (131494) NEO HELIOPAN

Neo Heliopan OS
0,0
0,1
0,2
0,3
0,4
0,5
0,6
0,7
0,8
0,9
1,0
1,1
250 260 270 280 290 300 310 320 330 340 350
1%
E
1cm
UV-C UV-B UV-A
wavelength in nm
Neo Heliopan
OS & HMS
Neo Heliopan HMS
0,0
0,1
0,2
0,3
0,4
0,5
0,6
0,7
0,8
0,9
1,0
1,1
250 260 270 280 290 300 310 320 330 340 350
1%
E
1cm
UV-C UV-B UV-A
wavelength in nm
Neo Heliopan
OS & HMS
> Both are used for products with low and in combination with other UV
filters high sun protection factors.
> They are effective solubilizers for crystalline UV absorbers such as Neo
Heliopan 357, BB, MBC, Ethylhexyl Triazone, Diethylhexyl Butamido
Triazone, Diethylamino Hydroxybenzoyl Hexyl Benzoate and Bis-
Ethylhexyloxyphenol Methoxyphenyl Triazine.
> They are oil soluble and can therefore be used in water-resistant
sunscreens.
Neo Heliopan
BB
Neo Heliopan
BB
EEC: max. 10%
USA: max. 6%
leave-on: max. 5%
Canada: max. 6%
Australia: max. 10%
South Africa: max. 10%
Brazil: max. 10%
Approved dosages:
worldwide approved
EEC: 0.5 % or more is liable to declare
contains Oxybenzone
Regulations:
Benzophenone-3
INCI Name:
BB (116210) NEO HELIOPAN

0,0
0,1
0,2
0,3
0,4
0,5
0,6
0,7
0,8
0,9
1,0
1,1
250 260 270 280 290 300 310 320 330 340 350 360 370 380 390
1%
E
1cm
UV-C UV-B UV-A
wavelength in nm
Neo Heliopan
BB
> Effective broad-spectrum absorber with maximum protection in the
short-wave UVB and UVA spectra (UVB approx. 286 nm, UVA approx.
325 nm)
> Excellent co-absorber in combination with a specific UVB absorber
(Neo Heliopan AV, E1000, OS, HMS or Hydro)
> Suitable to protect products from colour fading
> USA: Combination with Octyl Methoxycinnamate to
achieve higher SPF's
Neo Heliopan
BB
Neo Heliopan
AP
Neo Heliopan
AP
EEC: max. 10%
Australia: max. 10%
South Africa: max. 10%
Brazil: max. 10%
Approved dosages:
EEC: approved
USA: not approved
Japan: not approved
Canada: not approved
Regulations:
Disodium Phenyl Dibenzimidazole Tetrasulfonate
INCI Name:
AP (106796) NEO HELIOPAN

N
N
N
N
H
H
HO
3
S
SO
3
Na
SO
3
H
SO
3
Na
Neo Heliopan
AP
> A yellow, hygroscopic powder with a slight to neutral odour. The fully
neutralized salt is a water soluble UVA filter with a maximum
absorbance at 335 nm in water at a pH of 7.0.
Neo Heliopan
AP
0
0,1
0,2
0,3
0,4
0,5
0,6
0,7
0,8
0,9
1
1,1
250 260 270 280 290 300 310 320 330 340 350 360 370 380 390 400
Wavelenght in nm
UV-C UV-B UV-A
1%
E
1cm
wavelength nm
%

T
r
a
n
s
m
i
s
s
i
o
n
> Transmission Curve of 2.2% Neo Heliopan
AP
in an O/W Emulsion - 8 Cuvette / Challenge Australian UV-A Standard
Neo Heliopan
AP
0
10
20
30
40
50
60
70
80
90
100
290 300 310 320 330 340 350 360 370 380 390
Neo Heliopan
AP
> Neo Heliopan
AP is virtually insoluble in water (0.25%).

> Its salts are water soluble :
Sodium salt
Potassium salt
TEA salt
Ammonium salt
12%
13%
22%
22%
> Neo Heliopan
AP is therefore preferably made into an aqueous

premix of the desired salt and then added to the aqueous phase
of the emulsion.
86.3 parts distilled water
9.00 parts Neo Heliopan
AP
4.70 parts KOH (30% solution in water)
> Mix about 2/3 of the neutralization agent with water and add Neo Heliopan
AP. Add the remaining neutralizing agent with stirring until all of the Neo
Heliopan
AP is dissolved.
10% Solution of Na Salt pH 7.0 - 7.5
AP
10.90 parts NaOH (10% solution in water)
22% Solution of TEA Salt pH 7.0-7.5
AP
21.30 parts triethanolamine
9% Solution of K Salt pH 7.0 - 7.5
Neo Heliopan
AP
PREPARATION OF NEUTRALIZED SOLUTIONS
Neo Heliopan
AP
> Neutralization curve of Neo Heliopan
AP
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
ml neutralizing agent
p
H
v
a
l
u
e
0.1 mol/l sodium
hydroxide
0.1 mol/l
triethanolamine
> Neo Heliopan AP is a highly effective and photostable UVA II absorber which
forms water soluble salts with the addition of a base.
> Neo Heliopan AP is practically odorless, has an excellent stability and is
compatible with other ingredients and packaging
> In sun care formulations it shows synergistic effects with oil-soluble UVB
filters
> In combination with the UVA I absorber Neo Heliopan 357 very broad
spectrum UVA protection products can be formulated
> It has an excellent safety profile including extremely low skin penetration.
> Suitable for water-based transparent sunscreen products such as gels or clear
sprays
> Waterproof sunscreens can be formulated
Neo Heliopan
AP
> Neo Heliopan AP is a fine yellow powder. The free acid is virtually insoluble in
water. By the addition of a base such as sodium hydroxide, potassium hydroxide
or triethanolamine the water soluble salts will be formed.
> Neo Heliopan AP can be added non-neutralized to the aqueous phase of the
formulation, addition of a neutralization base with vigorous stirring will form the
salt which then dissolves into the aqueous phase
> Neo Heliopan AP can be also added as aqueous pre-mix.
> In finished formulations Neo Heliopan AP is stable in a wide pH range (5.0
9.0) without incurring the risk of crystallization.
> Care has to be taken when Neo Heliopan AP is used in the presence of
quaternary ammonium salts since complexes may form.
Neo Heliopan
AP
> To fulfill the requirements of the Australian Standard about 2.2% active Neo
Heliopan AP are necessary. It should be noted that Neo Heliopan AP is not
soluble in the solvents recommended by method 1 of the standard and therefore
to strictly conform with the standard methods 2 or 3 should be used. An
alternative solution method is to use a 50 : 50 mixture of Isopropanol and
Methanol as solvent.
> Tocopherol is known to incur discoloration problems in a number of formulations;
therefore we recommend the usage of tocopheryl acetate when formulating with
Neo Heliopan AP.
> Neo Heliopan AP is an electrolyte and therefore will have an effect upon the
viscosity of carbomer-thickened emulsions or gels. The addition of a non-
carbomer derived thickening agent such as xanthan gum and its derivatives will
increase the viscosity of the formulation
> If Neo Heliopan AP is combined with Zinc Oxide we recommend to disperse
Neo Heliopan AP directly into the aqueous phase and then dissolve it by adding
the neutralizing agent until a pH of about 5 is reached
Neo Heliopan
AP
Neo Heliopan
AP
> No Crystals of Disodium Phenyl
Dibenzimidazole Tetrasulfonate
(pH 5.0)
> Synergistic effects with oil soluble UV-B filters
Neo Heliopan
AP
SPF 3
SPF 7
SPF 14
2.2% AP 5% 303 + 3% MBC 2.2% AP + 5% 303 + 3% MBC
PPD PF 4.7 PPD PF 4.6
1.5% N.H. AP 1.5% N.H. 357
Neo Heliopan
AP
INORGANIC PIGMENTS
ZINC OXIDE
ZINC OXIDE
> Zinc Oxide has a long history of use as a skin protectant and has been used
in a wide range of dermatological and cosmetic preparations. In addition to
its protecting, soothing, healing and antimicrobial properties, zinc oxide
effectively scatters and absorbs UV radiation to provide broad band UV
protection. It is commonly used in combination with organic UV filters to
obtain an optimum level of protection.
> Symrise supply 3 grades of Zinc Oxide, 2 of which are microfine inorganic
pigments and the other is a submicron pigment with a primary particle size
above 200nm. All of these 3 grades can be used in suncare formulations
without incurring an unacceptable whitening effect upon the skin.
ZINC OXIDE
oil and water phase UV-B and UV-A Sub-micron Zinc Oxide USP
Zinc Oxide Pi
oil phase UV-B and UV-A Zinc Oxide neutral coated with
Dimethicone and is USP
Zinc Oxide NDM
oil and water phase UV-B and UV-A Microfine zinc oxide which has a neutral
pH and is USP
Zinc Oxide neutral
Dispersability Type of UV
Absorber
Type Product
> Light transmission curve
Zinc Oxide neutral
Instrument: Perkin Elmer Lambda 2, UV / vis Spectrophotometer.
Concentration: 10% Dispersion in Isopropyl Palmitate.
Cell Thickness: 10 m Quartz cell (calibrated against Isopropyl Palmitate)
Wavelength (nm)
T
r
a
n
s
m
i
t
t
a
n
c
e
(
%
)
6
9
15
0
2
4
6
8
10
12
14
16
5 10 15
% Microfine Zinc Oxide
S
P
F
> Linearity of SPF by dosage of Zinc Oxide neutral.
from W/O exipient formulated with Zinc Oxide neutral V-21872
Zinc Oxide neutral
DISCLAIMER
These suggestions and data are based on information we believe to be reliable. They are offered in
good faith, but without guarantee, as conditions and methods of use of our products are beyond our
control. Symrise makes no warranties, either expressed or implied, as to the accuracy or
appropriateness of this data. Symrise expressly disclaims any implied warranty of fitness for a
particular use.
We recommend that prospective users determine for themselves the suitability of Symrise materials
and suggestions for any use prior to their adoption. We also recommend that prospective users, as
required, obtain approval from appropriate regulatory authorities. Suggestions for uses of our
products or the inclusion of descriptive material from patents and the citation of specific patents in
this publication should not be understood as recommending the use of our products in violation of
any patent or as a permission or license to use any patent of Symrise.

Symrise: Uv Protection Systems

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AP is virtually insoluble in water (0.25%).

AP is therefore preferably made into an aqueous

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