EENADU - PRATIBHA

AIEEE MODEL GRAND TEST - 2 2012

KEY-SHEET
PHYSICS
1) 4

2) 3

3) 1

4) 3

5) 1

6) 2

7) 3

8) 4

9) 3

10) 4

11) 1

12) 2

13) 2

14) 3

15) 2

16) 1

17) 2

18) 3

19) 4

20) 2

21) 2

22) 3

23) 4

24) 1

25) 4

26) 2

27) 1

28) 2

29) 1

30) 3

CHEMISTRY
31) 4

32) 4

33) 2

34) 1

35) 3

36) 2

37) 1

38) 3

39) 3

40) 3

41) 3

42) 4

43) 1

44) 3

45) 3

46) 2

47) 3

48) 4

49) 3

50) 3

51) 1

52) 3

53) 4

54) 1

55) 2

56) 1

57) 1

58) 4

59) 3

60) 1

MATHEMATICS
61) 4

62) 1

63) 3

64) 1

65) 2

66) 1

67) 4

68) 3

69) 4

70) 1

71) 1

72) 3

73) 1

74) 2

75) 4

76) 3

77) 2

78) 3

79) 2

80) 1

81) 2

82) 3

83) 3

84) 4

85) 3

86) 3

87) 1

88) 1

89) 3

90) 1

(13)

EENADU - PRATIBHA
AIEEE MODEL GRAND TEST - 2 2012
SOLUTIONS

PHYSICS
01.

E = w0 +

hc
hc

1
mv 2
2

= w0 + E
= w 0 + 2E

02.

N = N 0 e t , t =

t1

N
fraction = N
0

03.

From given circute A.B + A

04.

cos = power factor =

R
2
, Z = R 2 + ( xL xC )
Z

1
w = 100, xL = wL , X C = w .
C

05.

R = 0.01, = 400, r = 1cm = 1 102 m, l = 20cm = 20 102 m

B = 0 ni = 0 n

06.
07.

e
.
R

1 1
w w
1
+ = 2, 1 + 2 = 0,
= 5D .
f1 f 2
f1 f 2
f1

According induction principle, V=

Q 2 - Q3
.
2C

09.

l l
r = R 1 2 .
l2
P = mV apply significant figures concept P = ( 2.01 ) ( 4.126 ).

10

= 1

08.

(273 + 7 ) T = ?
T2
50
T

= 1 2 = 1
1
T1
100
T1
T1

(273 + 7 ) T = ?
70
= 1
1
.
100
T1

(14)

11.

Q
r1r2
This is based on radial heat flow, so t r r .
2
1

12.

K .E =

13.

TE
ground  TE
at certain height

3
3
KT , Vrms =
nRT .
2
2

PE
ground  KE
ground  TE
at h

Gmm 1 9 2
Gmm
 m Ve  
R
Rh
2 4
14.

m1 4 KE1 3 F1 1
= ,
= ,
=
m2 1 KE2 2 F2 2
w=

1 2 1
mv mu 2
2
2

1
w = mas = ma at 2 .
2

15.

1
During non-zero accelaration, retardation area of graph A = base height
2
1
1
But total area = 20 1 + 10 3 10 3 + 20 1 .
2
2

2m1m2
kg .wt .
m1 + m2

16.

T=

17.

m1 d1v1
=
m2 d 2 v2 , but density pressure

4T
3
P0 +
R1
R1
m1
=
m2
4T
3 .
P0 +
R2
R2

18.

It is parallel combination of capillaries. =

r 4 = r1 + r2 r = r1 + r2
4

r4
pr 4
v=
p
8vl
8l

19.

v
m1 = n

v vs

v
m2 = n

v + vs

20.

beats = m1  m2 .
As each bulb has same resistance, Across `C` bulb more potential difference can be observed.
So `C` glows brightly.

21.

EC E A = (EC EB ) + ( EB E A )

E=
(15)

hc

1
1 1
= + .
3 1 2

22.

2H1 He2

23

Energy released = BEproducts - BEreactants

At t = 0 key is inserted , finally inductor becomes good conductor. So, `i` three `10 ` is zero.

24.

2
X L = 15, X C = 11, R = 3 , Z = R + ( X L X C ) ,
2

i=

v
,
z

from that we can find VL VC .

25.

26.

T = 2
k=

R1 = 3R
R2 = R .
3

v2
R

P=

F
e

m
k

y=

FL
e F
=
=k,
Ae
L Ay

e = e1 + e2
=

FL F
+
Ay k

3 D
.
d

27.

3 =

28.

n1 = (n + 1) 2 .

29.

2
k2
1 2 k2
1
mv 1 + 2 = mgh + m (v1 ) 1 + 2
2
2
R
R

30.

KET 
KER 

2
1
m v1 
2

1 2
IX
2

}}m

1
KER m (v )
=
2
KET
v
I
R
2

CHEMISTRY

31.

ZnS + O2
SO2 + ZnO
SO2 is acidic and ZnO is amphotenic

32.

Glucose on oxidation with mild oxidant gives gluconic acid, but with HNO3 gives saccparic acid.

33.

PCl3 is polar, because it has unsymmetrical pyramidal structure.

34.
35.

PCl5 is polar, because it is acquires unsymmetry due to difference in bond angles and starched bonds.
2x
3
Change in P.E. =   2 x
x
4
2

1
1
+E  13.6 Z 2 2  2 eV atom-1
n1 n2
For the ionization of Li2+ (Z=3) from first excited state, n1=2 and n2= d
1
2 1
Hence, IP= +E  13.6 q 3 2  2 = 30.6 eV
2
d
(16)

36.

Work done =  P%V   nRT


37.

2 s 8.314 s 298
1000

 4.955 kJ

The rearrangement is possible with syn-ethyl methyl ketoxime

CH3CH2

k}m

C=NOH

CH3-CH2-NH
C=O
CH3

CH3

38.

Presence of electron with drawing NO2 group on benzene ring decreases reactivity.
Presence of electron donating OR group on benzene ring increases reactivity.

39.

r1  k[ A]2 [ B]; r2  k[2 A]2 [2 B]  8 r1

40.

k

P
2.303
log i ;
t
Pt

CH 3 2

N 2 m C2 H 6  N 2

at t = 0

200

200-x
x
x
as per given data 200+x=350
k

41.

after 40 min
x = 150

200
2.303
4
1
log
200  150  5.77 q10 sec
t

Due to low value of Kb and common ion effect we can neglect x with respect to 0.01 when x  cB
Kb 

x q 0.01
0.02

x  [ NH 4 ]  3.6 q105

42.

NI(CO)4; EAN = 28 + (24) = 36

[NI(CN)4]2 ; EAN = (282) + (2 4) = 34

43.

Adsorption of ore particles into the froth

44.

4LiNO3

45.

One of the lone pairs of oxygen in furan is delocalised along with two pi bonds. 4n + 2 = 6; n = 1. Hence
Huckels rule is obeyed.

46.

Lone pair of N is involed in +M effect in conjugation with 3 pi bonds in the compound

%
}}
m 2Li O + O
2

_ 4NO2

N
H

47.

HCONH2 is methanamide

48.

1, 3, 5-Cyclohextrione has 3 keto groups and can give 3 OH groups on tautomerisation.

49.

Partial hydrogenation with Na in ammonia gives

C=C
H

50.

SO3 as well as CO32  are planar trigonal

51.

Bond order in O2 is 2; in O2 is 2.5 and in O2 is 1.5

52.

Configuration of O+ is l

CH6H5

CH3

l . It is half filled and stable. Removal of electron requires more energy

Among F+ (like O) and N+ (like C); more energy is required to remove electron from F+
(17)

53.

Ni2+ in [Ni(NH3)6]2+ has ln ln ln l l configuration.

It has 2 unpaired electrons and undergoes sp3d2 hybridisation with the use of 4d orbitals (outer)

54.

H2 S U 2H   S2 

Presence of acid (H+), acts as common ion and supresses the dissociation of H2S.
55.

Let volume of fcc unit cell = V

4q M A
8q M B
SA 
and S B 
N A .V
N A .V
SA
MA
30


 0.3
2M B
2 q 50
SB

SB 

SA
 3.33 g / cc
0.3

SA  1.0 g / cc
Total density = S A  S B  4.33 g / cc
56.

Let x milli-moles of KOH is added

s  x s  x
10  x
;
6  5  log
 10 or
 10 x  8.18
a  x a  x
10  x
Mass of KOH = 8.18q 10-3q 56 = 0.458 g

57.

Ozonolysis gives a dial

58.

CO3+ has 24 electrons with 3d6 configuration

59.

0.1
0.05
Equivalent of Zn2+ produced = 0.1 or moles of Zn2+ =
2
Positive charge increases in first compartment so due to interaction and maintain electrical neutrality Zn2+
move toward second compartment and NO3 move towards first compartment. Solution is always
electrically neutral, so charge of 1 Zn2+ is neutralized by 2 NO3

[Zn2+] in first compartment  1 

60.

0.05
 1.025M
2

Concentration of NO3 in second compartment 1 

0.05
 0.95M
1

MATHEMATICS
61.

C2 C2 C1
4sin 2 x

f ( x ) = (1 sin c )

3 + 6sin x

(1 sin x )

(1 + sin x )

1 + 2sin x

sin 2 x

2
2

C3 C3 C1
4sin 2 x
= (1 sin x )

(1 + sin x )

1 4sin 2 x

3 (1 + 2 sin x )

1 + 2 sin x

(1 + 2sin x )

R2 R3 R2
By doing expantion we get k = 4.

(18)

62.

x 2 (k 1) x + k (k + 4 ) = 0

2nd equation is
x2 (k + 2 + 1)x + (k +2)1=0
x  k  2 or 1

f (1) f (k + 2 ) < 0

(1 (k 1) + k (k + 4))((k + 2) (k 1)(k + 2) + k (k + 4)) < 0

(2 k + k + 4k )((k + 2 )(3) + k (k + 4 )) < 0
(k + 3k + 2 )(3k + 6 + k + 4k ) < 0
(k + 1)(k + 2 )(k + 7k + 6 ) < 0
2

(k + 1) (k + 2 )(k + 6 ) < 0
2

6 < k < 2 .

63.

Required area = ( Area of Equilateral triangle ) - ( 3 times of

64.

3
1

(4 ) 3 12
4
3
2

.
2

CB1 : r = (ai ) + t (ai + ak )

AB : r = ai + s (ai aj )
d=
=

65.

[2ai ai + ak ai aj ]
(ai + ak ) (ai aj )
2a
3

x 2 20 x + 64 = 0 ,

4 =4
1

1
1 cos

= 16, = 4
= 900
(19)

1 cos =

16 = 4

1
1 cos

1
2

1
= cos
2

= 600 , 1200
66.

We know that
C1 + C3 + C5 + C7 + ........... = 2n 1

n
4
-------------------------------------------------n

C1 C3 + C5 C7 + ........... = 2 2.sin

n
1 n 1
n
2

2
2
.sin
C3 + C7 + ........... .................. =

2
4

67.

sin 1 (sin 5 ) = 5 2
cos 1 (cos10 ) = 4 10

Tan 1 (Tan (6 )) = 2 6
cot 1 (cot (10 )) = 4 10 .
68.

Number of non-decreasing functions = m + n Cn - 1 = 10 + 20 - 1C20 - 1

total number of functions = n m = 2010.

69.

If 0 < f ( x ) 1 then f ( x ) f ( x )

g (x ) = 0
If 1 f ( x ) < 0 then f ( x ) = f ( x )

g (x ) =
Min. of

e ( ) e ( ) 1 e ( )
=
f x
f x
2 f x
e ( ) + e ( ) 1+ e ( )
f x

f x

g (x ) =

2 f x

1 e 2
1 + e2

1 e 2
Range = 1 + e 2 , 0 ..

70.

9 ways 8ways 8ways 8 ways = 32 x 29

71.

72.

The image of (2, 1) w.r.t. x + 3y 5 = 0

(10)
(10)
 (4,7)
,1  6
10
10
P lies on y = 7 and x + 3y 5 = 0
x = 16
P = (16, 7)

is 2  2

(20)

73.

A, X and B, X are disjoint pairs. A X  B X holds only if A = B.

74.

Applying componend and dividerdo.

75.

R is an equivalence relation

76.

b = cos 4 x +
2 x R
cos 4 x

= b (d, 2]

77.

f(n) = 2 cos n x
f(1). f(n+1) = 2cosx. cos(n+1)x
= cos(n+2)x + cos n x
f(1) f(n+1) - f(n) = f(n+2)

78.

Req. vector is component of b to a

1
a 1

79.

f a
 0
a

1
0

a
1

f (a)  1  a 3  a
f 1 (a)  3a 2  1  0
1
1
a
;a  
3
3
11
f ( a )  6a  0
1
minimum at a 
3
80.

Let us take point m y-axis is (0, k)

4(0)  3(k )  12
16  9

3

3k 12
 o 3q5

k  4
 o 5

S .B. S
k = 1, -9
= (0,1), (0, -9)
81.

In statement 1 we have to take x = 0 to get sum of the coefficients.

82.
number of critical points : 3
83.

T2n to T2n11

term 2n
T210  T2011  T2111
= T2011  210

(21)

84.

12x+4y+3z-328=0; x2+y2+z2+4x-2y-6z-185=0
d=

c = (2, 1, 3)

12 (2 ) + 4 (1) + 3 (3) 327

144 + 16 + 9

r = 4 + 1 + 9 + 155 = 13

13381
= 26
13
Req. distance = 26-13 = 13 .
d=

85.

If a > 0, b > 0 and a + b = 1

1

f ( ) = sin 2 + 2
sin

1

2
+ cos +

cos 2

= sin 4 + cos ec 4 + 2 + cos 4 + sec 4 + 2

= 4 + 1 2sin 2 cos 2 + (1 + cot 2 ) + (1 + tan 2 )

2

= 5 2 sin 2 cos 2 + 1 + cot 4 + 2 cot 2 + 1 + tan 4 + 2 tan 2

= 7 + 2 (2 ) 2sin 2 cos 2 + 2
1
= 13 sin 2 2
2
=

86.

= 13

( cot

1
2

+ tan 4 2 )

25
.
2

r 1

cot 1 2r 2 

 Lt

nmd

tan
n

r 1

1

Tan 1

r 1

d
1
2

tan 1 2
2
2r
4r
r 1

(2r  1)  (2r  1)
1  (2r  1)(2r  1)

 Lt Tan 1 (2r  1)  Tan 1 (2r  1)

n md
r 1

Q Q Q
 Lt Tan 1 (2n  1)  Tan 11   
nmd
2 4 4
7

87.

Tan ( x

Tan ( x

88.

x+9 = t

6 ) dx + Tan (t 2 6 ) dt

t = k

Tan (x

6 ) dx + Tan ( x + 9 ) 6 dx

6 ) dx + Tan (k 2 6 )( dk ) = 0
3

sin < < Tan

2011sin
2011sin
< 2011
= 2010

2010Tan
2010Tan
> 2010
= 2010 = 4020.

(22)

89.

t1 + t2 = , t1t2 1
chord : y (t1 + t2 ) = 2 x + 2at1t2

2 (x + a ) + y = 0

passes through (a, 0 ).

90.

Mean = 8

2 + 4 + 10 + 12 + 14 + x + y
= 8 x + y = 14
7

Varience = 6

1 2
2
2 + 42 + 102 + 122 + 14 2 + x 2 + y 2 ) (mean ) = 16
(
7

x 2 + y 2 = 100

(2 )

Solve ( 1 ) and ( 2 ) x = 6, y = 8.
H H H

(23)

(1)