ESHch 40

Chapter 40
Hazardous Materials
Chapter Outline
1 Overview 2
1.1 Hazards/Impacts 2
2 Scope 3
2.1 Exemptions 3
2.1.1 Chemical Exemptions 3
3 Implementation 3
4 Requirements 3
4.1 General 3
4.1.1 Chemical Management Services 3
4.1.2 Hazard Communication Program 4
4.1.3 Chemical Hygiene Program 5
4.1.4 Nanomaterial Management 6
4.1.5 Hazardous Materials Management 6
4.1.6 Hazardous Materials Transportation 9
4.1.7 Hazardous Materials Contingency Planning 9
4.1.8 Roles and Responsibilities 10
4.2 Procedures and Specific Requirements 12
4.2.1 Chemical Hygiene Program 12
4.2.2 Hazardous Materials Management 12
4.2.3 Industrial Hygiene 17
4.2.4 Accidental Exposures 17
4.2.5 Fire Prevention 19
4.3 Training 20
4.3.1 Chemical Worker 20
4.3.2 Chemical Hygiene Worker 21
4.3.3 Personal Protective Equipment Training 22
4.3.4 Job- and Chemical-specific Safety Training 22
5 Definitions 22
6 References 24
4 Jan 2007 (updated 21 Sep 2009) SLAC-I-720-0A29Z-001-R023.3 40-1
SLAC Environment, Safety, and Health Manual Chapter 40: Hazardous Materials
6.1 Program Documents 24
6.2 Standards 25
6.3 Related Documents 28
7 Document Information 29
1 Overview
Chemicals and materials for which occupational exposure poses a health or safety risk are considered
hazardous materials at SLAC. Hazardous materials are routinely used and stored at SLAC, and their
acquisition, use, handling, storage, and disposal are strictly controlled to provide a safe work environment
and protect the health of SLAC personnel and guests.
The hazards associated with chemicals and materials are communicated to personnel and mitigated through
the hazard communication (HazCom) program and the chemical hygiene program (CHP). The hazardous
materials inventory at SLAC is managed through the use of a comprehensive chemical management
services (CMS) system, developed for the specific chemical lifecycle at SLAC and based on the existing
supply chain model used to acquire hazardous materials and chemicals. These three components make up
the hazardous materials program.
Operations at SLAC include elements covered by the following Occupational Safety and Health
Administration (OSHA) standards:
1. Title 29, Code of Federal Regulations, Labor, Part 1910, Occupational Safety and Health
Standards, Section 1450, Occupational Exposure to Hazardous Chemicals in Laboratories
(chemical hygiene) (29 CFR 1910.1450)
2. Title 29, Code of Federal Regulations, Labor, Part 1910, Occupational Safety and Health
Standards, Section 1200, Hazard Communication (29 CFR 1910.1200)
Descriptions of the specifics for these standards are included in sections 4.1.1and 4.1.3. This chapter
satisfies the requirements for a written hazard communication program.
This chapter describes the requirements for informing personnel of chemical and material hazards in their
work areas and the controls used to mitigate these hazards. The CMS and associated procedures used for
inventory control and the requirements for the management of hazardous materials are also described in
this chapter. While the role of hazardous materials management in pollution prevention and hazardous
waste reduction is described in this chapter, the management of hazardous waste and pollution prevention
are covered in detail in Chapter 17, Hazardous Waste and Chapter 22, Waste Minimization and
Pollution Prevention.
1.1 Hazards / Impacts
SLAC operations involving the handling, storage, use, or disposal of hazardous materials may pose a risk to
the health and safety of personnel. These hazards must be communicated to all potentially exposed persons.
Operations involving potential chemical exposure to personnel must include appropriate hazard controls to
ensure exposures are kept below occupational exposure limits. Operations involving the use of hazardous
40-2 SLAC-I-720-0A29Z-001-R023.3 4 Jan 2007 (updated 21 Sep 2009)
Chapter 40: Hazardous Materials SLAC Environment, Safety, and Health Manual
materials that may adversely impact the environment or generate hazardous waste must be managed to
mitigate impacts through waste reduction and pollution prevention.
2 Scope
The requirements of this chapter apply to the purchasing, use, handling, storage, transportation and disposal
of all hazardous materials, and apply to all employees, subcontractors, and users.
Radioactive materials are not covered by this chapter. Radioactive material procurement, handling, use, and
storage are covered in Chapter 9, Radiological Safety.
2.1 Exemptions
2.1.1 Chemical Exemptions
Materials containing hazardous chemicals that are inextricably bound in a product and cannot be released,
and consumer products used for the purpose intended by the manufacturer in quantities not greater than
those purchased by the average consumer, are exempt from the requirements of this chapter.
3 Implementation
The requirements of this chapter take effect September 21, 2009.
4 Requirements
4.1 General
4.1.1 Chemical Management Services
SLAC utilizes the chemical management services (CMS) supply chain model for hazardous materials
management. Haas TCM is the SLAC CMS vendor. All chemical purchase must be initiated and fulfilled
using the Haas Total Chemical Management Information System (tcmIS), which greatly enhances the
ability of SLAC to comply accurately with hazard communication, inventory, and chemical usage reporting
obligations.
The industrial hygiene and hazardous materials program managers are notified of all new chemical material
requests that are processed using tcmIS. In the event of special hazards associated with the material (for
example, highly toxic, carcinogenic, highly flammable, reactive, radioactive), the program managers may
contact the requester to require a further review of the material and/or operation associated with the use of
the proposed material. This review will verify the intended use of the material includes the necessary
considerations and controls to ensure it can be stored, used, and disposed of safely and in accordance with
any applicable regulations. If the safety and/or environmental issues cannot be resolved, the program
managers reserve the right to deny the acquisition of this material. (See Hazardous Materials: Purchasing
Procedure and Hazardous Materials: Chemical Screening Criteria.)
No other means of acquiring chemicals for on-site use is permitted without prior management approval and
program review. Possible ramifications for purchases made outside of this policy include the following
sanctions:
Petty cash purchases: no reimbursement will be issued
P-card purchases: first violation, verbal warning and written warning; second violation, p-card revoked
All purchases: note of infraction(s) placed in annual performance review
4.1.2 Hazard Communication Program
With the exception of areas covered under the chemical hygiene program (see Section 4.1.3, Chemical
Hygiene Program), all personnel who may be exposed to hazardous materials in their work area are
subject to the requirements of the HazCom program. This program requires area managers and supervisors
whose personnel may be exposed to hazardous materials to implement the HazCom program in their work
area. Hazard communication will include the following elements:
1. Maintaining a material safety data sheet (MSDS) on each hazardous material used or stored at SLAC
2. Providing accurate and complete hazardous material inventory in each work area where hazardous
materials are store or used. This can be accomplished through local inventories and/or SLAC
inventory.
3. Proper labeling of all hazardous materials
4. Providing appropriate training for all affected personnel
Employees of subcontractors are subject to the HazCom programs of their employers. For hazards located
in SLAC areas where subcontractors will be working, the project manager or university technical
representative (UTR) must provide HazCom information.
4.1.2.1 Material Safety Data Sheet Access
A current MSDS for each hazardous material used or stored will be maintained in the HazCom module of
the tcmIS system, and made available for viewing online through the DOE MSDS viewer. The MSDS
viewer allows personnel to view and copy each MSDS in the system and is available to all SLAC
employees, users, guests, and subcontractors, 24 hours a day. Managers and supervisors will ensure all
personnel working in areas where hazardous materials are used or stored have ready access to the MSDS
viewer or make available a hard copy of the MSDS for each hazardous material in their work area.
4.1.2.2 Container Labeling
Hazardous material containers will be labeled meeting the following requirements:
Every hazardous material container will be clearly labeled with the material name and appropriate
hazard information. Required label elements (per the OSHA hazard communication standard, [29 CFR
1910.1200]) include the following:
Name and address of the chemical manufacturer, importer, or other responsible party
Identity of the hazardous chemical(s) contained therein
Appropriate hazard warnings, or alternatively, words, pictures, symbols (or a combination thereof)
that provides information regarding the hazards of the chemicals, and which presents personnel
with the specific information regarding the physical and health hazards of the hazardous chemical
Manufacturer-affixed labels will not be removed or defaced on the primary chemical container if it still
contains the hazardous material. If a container label is missing or illegible, or if the material is
transferred into a secondary container, a secondary hazardous material label must be affixed. These are
available through the hazardous materials program manager and Haas on-site customer service
representative.
Supervisors and managers will be immediately notified when unlabeled hazardous material containers
are discovered. Unlabeled containers that may contain hazardous materials should be assumed to be
hazardous. An attempt should be made to determine the contents of the container and a correct label
should be affixed to the container. If a determination cannot be made about the contents, the hazardous
materials program manager should be contacted.
All new installations of hazardous material pipes and tubes will be labeled in accordance with ANSI
A13.1 requirements.
Custodians responsible for tanks will ensure the tanks are appropriately labeled with the following
elements:
1. Name and concentration of the materials contained within the tank
2. NFPA 704 hazard diamond indicating the health, flammability, reactivity, and any special hazards of
the material
4.1.2.3 Work Area Hazardous Materials Inventory
A current, accurate, work area hazardous material inventory will be maintained. This can be accomplished
through local inventories and/or SLAC inventory. Chemicals purchased before 2006 may not be captured
on the SLAC inventory and require manual inventory by work area personnel. All chemicals purchased
through Haas can be captured for inventory purposes through the building inventory query tool or
procurement records through Haas tcmIS.
4.1.2.4 Training
See Section 4.3.1, Chemical Worker, for HazCom program training requirements.
4.1.3 Chemical Hygiene Program
Under the SLAC chemical hygiene program, a written chemical hygiene plan (CHP), is required for all
chemical laboratories in which the following conditions are met:
1. Chemical manipulations are carried out on a laboratory scale.
2. Multiple chemical procedures or chemicals are used.
3. Chemical procedures are not part of a production process and do not simulate a production process.
4. Safety equipment and personal protective equipment (PPE) are available and in use.
For a list of affected laboratories, see Hazardous Materials: Chemical Hygiene Program Laboratories List.
Laboratory safe operating procedures will be written and maintained by the laboratory supervisor. All
laboratory personnel will follow these procedures to ensure the safe storage, handling, use, and disposal of
hazardous chemicals. The Chemical Hygiene Plan provides guidelines and specific requirements for the
development of laboratory specific chemical hygiene plans. Recommended chemical handling practices are
provided in Section 4.2.2, Hazardous Materials Management, and in chemical-specific safe handling
guidelines (see Section 6.1, Program Documents).
Prior to working in any laboratory with a CHP, personnel must acknowledge in writing that they have read
and are familiar with the laboratory chemical hygiene plan and will comply with the requirements of the
plan.
4.1.4 Nanomaterial Management
Prior to the purchase, use, synthesis or storage of nanomaterials, the Nanomaterial Safety Plan must be
reviewed and incorporated into work area procedures. The following materials and activities are covered
under this plan:
Engineered nanomaterials, that is, intentionally created in contrast with natural or incidentally
formed engineered nanomaterials with dimensions of less than 100 nanometers. This definition
excludes biomolecules (proteins, nucleic acids, and carbohydrates), and materials for which the
occupational exposure limit (OEL) documentation of national consensus or regulatory standards has
specifically addressed nanoscale particles for that material.
Nanoparticles, that is, dispersible particles having two or three dimensions greater than 0.001
micrometer (1 nanometer) and smaller than about 0.1 micrometer (100 nanometers) and which may or
may not exhibit a size-related intensive property. (See ASTM E2456-2006 for terminology.)

Precursors, intermediates, and wastes used during, or resulting from synthesizing such nanomaterials
Laboratory-scale activities involving chemical containers, reaction vessels, material transfers, and
other handling of substances that are designed to be easily and safely manipulated by one person.
Laboratory-scale excludes those workplaces the function of which is to produce commercial quantities
of materials per 29 CFR 1910.1450(b).
4.1.5 Hazardous Materials Management
4.1.5.1 General Precautions
Prior to the use of any hazardous material or chemical, the MSDS provided by the manufacturer must be
reviewed. Hazardous materials and chemicals will be handled carefully at all times, stored in appropriate
containers, and transported in carrying devices, and all chemical containers will be labeled in accordance
with the requirements of this chapter. Open containers should be closed after use, and unneeded hazardous
materials must be returned to storage.
The ESH Division may issue a safe chemical use and handling guideline for a chemical in use at SLAC
with particularly hazardous properties. (See Section 6.1, Program Documents.)
4.1.5.2 Hazard Controls
To control exposure to material and chemical hazards, personnel who use chemicals and hazardous
materials must first evaluate the hazards associated with these chemicals, then identify and implement
appropriate hazard controls and procedures prior to using these hazardous materials. Personnel selecting
hazardous materials for use at SLAC will consider the following hazard controls, in order of preference:
Material/Process Design Selection
Select the safest chemical for a given job
Use and store the smallest useful quantities to minimize the amount of material on hand
Generate the smallest amount of hazardous waste
Engineering Controls
Provide engineering controls and suitable facilities to minimize hazards
Use the smallest vessels, apparatus, or equipment practical and safe for a given job
Complete design review to identify and qualify hazards, evaluate risks, and design appropriate
control measures prior to installing equipment or using a chemical
Use warning devices (horns and flashing lights)
Comply with manufacturer operating instructions for equipment
Administrative Controls
Chemical acquisition control and inventory
Training
MSDSs
Labels and signs
Medical surveillance and certification
Personal Protective Equipment
Using PPE appropriate for the chemicals involved, such as gloves, coveralls, aprons, indirectly
vented goggles, and respirators
4.1.5.3 Chemical Storage Assets
In any single room or laboratory, the maximum quantity of any one hazardous material or chemical should
be kept at a minimum. Personnel should rely on just-in-time delivery provided by CMS vendors. Any
exceptions to the storage occupancy amounts or permissible exterior storage amounts in the California Fire
Code must be approved in writing by the fire marshal and the relevant manager of the SLAC directorate.
Managers may choose to further limit the amount of hazardous materials and chemicals stored or used at
their building, facility or facility area when required to provide a safe work environment for personnel.
In general, there are eight types of chemical storage assets in use at SLAC for storing chemical containers:
1. Bulk storage tanks
2. Tube trailers
3. Flammable material storage cabinets
4. Corrosive material storage cabinets
5. Chemical refrigerators
6. Laboratory hoods and equipment with built-in hazardous materials storage
7. Other cabinets used to store lesser hazardous materials
8. Gas racks used to store compressed gas cylinders (See Chapter 38, Compressed Gas Cylinders)
For all eight classes, the locations of the assets will be shown on the CMS chemical use maps and area
managers and supervisors will designate a custodian for each chemical storage asset. It is the responsibility
of the chemical asset custodian to ensure the following requirements are met:
1. The local hazardous materials inventory is correct and up-to-date and made available to the hazardous
materials program manager.
2. Chemical assets have been assigned a property control (PC) identification number (other cabinets and
gas racks are exempted from this requirement).
3. Required inspections and testing of the assets are performed.
4. Documentation of inspections and testing is maintained.
5. Contact information for the asset custodian (name and extension) must be posted on the asset.
All chemical storage cabinets must be approved storage cabinets (that is, compliant with the California
Fire Code, see Hazardous Materials: Chemical Storage Asset Requirements.)
All chemical storage assets are required to be inspected monthly. (See Hazardous Materials: Storage
Inspection Procedure and Form pdf or Word.)
4.1.5.4 Chemical and Oil Containing Equipment
Chemical- and oil- containing equipment, though not considered a chemical asset, have requirements
associated with their use. Oil-filled and chemical process equipment must be evaluated for inclusion in the
Hazardous Materials Inventory Statement (HMIS) and appropriate warning labels and signs by the
hazardous materials program manager. Equipment containing oil or chemicals must include spill
prevention measures effective against any release of material that could impact human health or the
environment.
4.1.5.5 Process Safety Analyses
In addition to the safety analysis documentation required by Department of Energy (see Chapter 1,
General Policy and Responsibilities and Chapter 2, Work Planning and Control), SLAC is subject to
two regulatory programs covering chemical process safety:
1. OSHA Process Safety Management (29 CFR 1910.119)
2. Cal EPA, Cal ARP program, administered locally by San Mateo County
These two programs list certain highly hazardous or toxic chemicals and threshold quantities for each. If a
facility uses one of these materials in any single process in an amount above the threshold quantity, the
facility must prepare process safety management and accidental release prevention documentation for that
process, and implement the resulting safety and hazard control recommendations. The industrial hygiene
program manager is responsible for the process safety management (PSM) program, and the air quality
program manager is responsible for the Cal ARP program. Any proposed new process at SLAC involving
the use of chemicals listed on either the PSM or Cal ARP lists, or any modification of an existing process
using these chemicals, must be reviewed by the appropriate program manager who will perform a threshold
determination analysis. The Hazardous and Experimental Energy Committee (HEEC) will also be
consulted. In the event a threshold is exceeded, the line organization must change the process so exposure
remains under threshold quantities, or perform the required safety studies and implement controls to satisfy
the requirements of the PSM and Cal ARP programs.
4.1.6 Hazardous Materials Transportation
4.1.6.1 Hazardous Materials Transportation to/from SLAC
Transport of chemicals from an off-site location to SLAC will be accomplished only through the CMS
acquisition process. Transportation of hazardous materials from SLAC to off-site locations will be
managed and arranged by properly trained shipping and receiving department personnel, using the
appropriate shipping containers, labels, and other necessary equipment.
Transportation of hazardous waste from SLAC to off-site locations will be managed and arranged by
properly trained Waste Management (WM) Group personnel, using the appropriate shipping containers,
labels, and other necessary equipment (see Chapter 17, Hazardous Waste).
4.1.6.2 Hazardous Materials Transportation within SLAC
Specific information regarding hazardous materials packaging, labeling, and security is specified in the US
Department of Transportation Hazardous Materials Transportation specifications (49 CFR 171 and
following). Hazardous Materials: On-site Transportation Requirements describes packaging, labeling, and
securing hazardous materials and waste for on-site transportation from one room to another, from one floor
in a building to another, or from one building to any other location at SLAC.
4.1.7 Hazardous Materials Contingency Planning
4.1.7.1 Consolidated Contingency Plan
SLAC will prepare and maintain a consolidated hazardous materials contingency plan in the format
specified in Section 25503.4 of the California Health and Safety Code (HSC 2550025520) SLAC has
developed a consolidated chemical contingency plan (CCCP) to integrate various regulatory requirements
for hazardous materials (including hazardous wastes) emergency planning into a single functional
document. This single plan approach helps to reduce duplication of effort and needless program
development, implementation, and maintenance burdens. This CCCP helps to ensure adequate
preparedness with rapid and appropriate response to emergency situations involving hazardous materials.
The purpose of this plan is to protect public health; employees, contractors and visitors; and the
environment.
4.1.7.2 Spills and Releases
A chemical spill is the release of any hazardous chemical from its primary container that results in an
increased risk or potential risk to human health, the environment, and property. Refer to Chapter 16,
Spills, for detailed information about spills and releases.
Note Preparation is essential to minimizing the hazards caused by a chemical spill. Assemble a
chemical spill kit, and understand the hazards associated with the chemicals used and stored in
the work area. Consult the MSDS or chemical inventory for more information. Post an emergency
telephone call list near the entrance to each work area as appropriate.
4.1.8 Roles and Responsibilities
4.1.8.1 Hazardous Materials Program Manager
The hazardous materials program manager will
Administer the CMS used for acquisition, distribution, and inventory control of hazardous materials
Maintain the tcmIS and associated MSDS files
Develop general hazard communication and chemical hygiene plan training
Implement and monitor the chemical screening process for new chemicals (see Hazardous Materials:
Chemical Screening Criteria)
4.1.8.2 Industrial Hygiene Program Manager
The industrial hygiene program manager will perform routine inspections to
Identify which laboratories will be covered by the CHP
Ensure hazard control equipment is functioning properly
Perform exposure monitoring to determine exposure levels
Assess the risk of exposures
Recommend controls to minimize such exposure
4.1.8.3 Medical Department
The Medical Department will provide medical consultations and examinations for personnel when the
following conditions are met:
1. Baseline medical surveillance is required based on personnel potential or actual exposure to certain
chemicals.
2. Personnel exposure levels to hazardous materials are found to be in excess of legal or action limits.
3. Personnel show symptoms of overexposure.
4. A spill or other event is likely to result in the overexposure of personnel to hazardous materials.
4.1.8.4 Group Leaders and Department Heads
Group leaders and department heads will ensure managers and supervisors comply with the requirements of
this chapter applicable to their groups and departments, such as CMS procedures for the acquisition of
hazardous materials. Additionally, they will ensure that managers and supervisors provide any necessary
input to the hazardous materials program manager required to maintain regulatory compliance.
4.1.8.5 Chemical Laboratory Supervisors
Chemical laboratory supervisors, supervisory personnel responsible for the operations in laboratories
designated under the CHP, will
Develop laboratory-specific chemical hygiene plans for their laboratories
Sponsor safety meetings, including review of training as well as provide training to lab workers on
non-routine tasks involving chemicals
Monitor work practices on a daily basis
Answer questions regarding safety procedures
4.1.8.6 Managers, Supervisors, and ESH Coordinators
Managers, supervisors, and ESH coordinators will
Select, implement, and maintain appropriate measures for controlling work area hazards associated
with hazardous materials
Provide applicable PPE at no cost to employees
Ensure hazardous materials are properly labeled
Designate chemical asset custodians for their area of responsibility
Provide any necessary inventory information to the hazardous materials program manager to support
maintaining an accurate hazardous materials inventory for regulatory and compliance purposes
Providing accurate and complete hazardous material inventory in each work area where hazardous
materials are store or used. This can be accomplished through local inventories and/or SLAC
inventory.
Ensure personnel complete both ESH training and site-specific on-the-job training (OJT), including
providing training to lab workers on non-routine tasks involving chemicals
Ensure personnel comply with all safety controls
Ensure that all personnel on all shifts have access to relevant MSDSs (either online or a hard copy)
If required, ensure that appropriate emergency eyewash and shower equipment is available in the work
area and that local exhaust ventilation is properly operating
Know the location of hazard control and emergency equipment, inspect the equipment, provide for
equipment maintenance, and notify appropriate personnel to repair or replace the equipment if it is
missing, defective, or inoperative
4.1.8.7 Project Managers and University Technical Representatives
Project managers and UTRs will inform subcontractors in their charge of the following requirements and
information:
Hazardous materials used or stored in SLAC work areas
Measures required to control these hazards
Process by which subcontractors can access MSDS (either electronically or hard copy)
SLAC HazCom requirements
4.1.8.8 Chemical Asset Custodians
Chemical asset custodians will
Ensure compliance with the chemical storage requirements of this chapter
Maintain documentation about the location, inspection, and testing of chemical assets under their
control
4.1.8.9 Personnel
All personnel will
Comply with the requirements of this chapter
Comply with all hazard controls
Properly use PPE
Complete general and site-specific training
4.1.8.10 Subcontractors
Subcontractors will
Comply with the provisions of this chapter
Ensure their employees have received training to comply with the OSHA hazard communication
standard (29 CFR 1910.1200)
Maintain MSDS files for hazardous materials brought to SLAC and make these files available to
supervisors of SLAC personnel who may be exposed to those hazardous materials
Provide PPE for their personnel
4.2 Procedures and Specific Requirements
4.2.1 Chemical Hygiene Program
4.2.1.1 Written Chemical Hygiene Plan
The Chemical Hygiene Plan provides guidelines and specific requirements for the development of
laboratory-specific chemical hygiene plans. Prior to working in any laboratory with a CHP, personnel must
acknowledge in writing that they have read and are familiar with the laboratory chemical hygiene plan and
will comply with the requirements of the plan.
4.2.1.2 Determination of Facilities Covered by the CHP
Determination of facilities covered by the CHP is the responsibility of the industrial hygiene program
manager.
4.2.2 Hazardous Materials Management
4.2.2.1 Chemical Use Planning
Prior to acquiring and using a new chemical, personnel and supervisors will plan for that use. (See
Hazardous Materials: Chemical Use Planning Guidelines.)
4.2.2.2 Chemical Acquisition
All chemical purchases at SLAC are processed through a centralized chemical management and
information system called Haas tcmIS. Only employees authorized by their supervisors may place orders
for chemicals through tcmIS. Access to the system for ordering privileges must be coordinated through the
hazardous materials program manager. SLAC personnel with current ordering privileges are listed on the
CMS web site. It should be noted that approval of an order through the approval hierarchy is
acknowledgement of financial responsibility and is in effect an approval of the invoice. In addition, contact
information for ESH and Haas tcmIS on-site representatives who can assist with this procedure are also
included at this web site. Once access is granted and an approval hierarchy is set up for that user, he/she
will be trained by the hazardous materials program manager and/or Haas tcmIS on-site customer service
representative on how to order and track chemical purchases.
The process description and flow diagram for chemical purchasing Hazardous Materials: Purchasing Flow
Chart.
No other means of acquiring chemicals for on-site use is permitted without prior management approval and
program review. Possible ramifications for purchases made outside of this policy include the following
sanctions:
Petty cash purchases: no reimbursement will be issued
P-card purchases: first violation, verbal warning and written warning; second violation, p-card revoked
All purchases: note of infraction(s) placed in annual performance review
4.2.2.3 Lead Acquisition
Raw metals are not covered by the current implementation of the CMS system. The specific requirements
on elemental lead and lead shielding are covered in detail in Chapter 20, Lead Safety, and any subsequent
clarifications issued by either the hazardous materials or the industrial hygiene program manager.
1

4.2.2.4 Ethanol Acquisition
The purchase and use of ethanol is regulated by the United States Department of the Treasury, Bureau of
Alcohol, Tobacco, and Firearms. There is a federal excise tax on the use of ethanol; however, tax-free
alcohol may be used for scientific, medicinal, and mechanical purposes. SLAC receives its research-use
ethanol through an agreement with Stanford University as the university has a permit under the tax-free
exemption. Users of ethanol can initiate purchase through Haas tcmIS but will be invoiced directly. (See
Hazardous Materials: Ethanol Purchasing Procedure.)
4.2.2.5 Hazardous Waste Minimization and Pollution Prevention
Waste minimization is defined as measures that reduce the volume and toxicity of hazardous waste disposed
in landfills. Pollution prevention is a broader term that includes waste minimization. Pollution prevention is
defined as measures that reduce the generation of non-hazardous and hazardous waste, and prevents
deterioration of the earths atmosphere, water, land, and biota caused by pollution. Pollution prevention
includes resource conservation and spill prevention. Waste minimization and pollution prevention program
requirements are provided in Chapter 22, Waste Minimization and Pollution Prevention. The waste

1 Chemical Management Services (CMS): Frequently Asked Questions, http://www-
group.slac.stanford.edu/esh/groups/cgs/hmaq/cms/cmsfaq.htm
minimization and pollution prevention program is inextricably bound to the hazardous materials program,
as the objectives are the same: to reduce waste and toxicity whenever possible.
4.2.2.6 Inspection and Delivery
All chemicals are required to be transported to SLAC by one of two means: by Haas CMS vendor
subcontractors or by ethanol delivery personnel.. No exceptions are allowed without prior management
approval and program review.
Chemical containers shipped to SLAC through the Haas hub will be inspected and bar-coded at the hub
prior to their arrival on site. Chemicals directly shipped to SLAC from the manufacturing location and
ethanol deliveries will be inspected upon delivery.
Chemical receivers are responsible for inspecting the delivery for accuracy and container integrity before
signing the shipping manifest. Shipments containing the wrong material or quantities need to be flagged for
return or refund. Damaged containers should not be accepted
4.2.2.7 Chemical Storage
The amount of chemicals stored on site should be kept to a minimum. When storage is necessary the
following requirements apply.
Storage Assets
As described in Section 4.1.5.3, Chemical Storage Assets, there are eight classes of storage assets in use
at SLAC, subject to the stated requirements. Requirements for using storage assets safely are in Hazardous
Materials: Chemical Storage Asset Requirements.
Incompatibility
Many chemicals are incompatible with one another and must be kept separate. This can be accomplished by
distance or by secondary containment, depending on the type of incompatibility, the severity of any
possible reactions, and the quantities of the respective chemicals.
Incompatible materials must be separated when the stored materials are in containers having a capacity of
more than five pounds (2.3 kg) or 0.5 gallon (1.9 L). Separation can be accomplished by one of the
following techniques:
Segregating incompatible materials storage by a distance of not less than 20 feet (6.1 m)
Isolating incompatible materials storage by a noncombustible partition extending not less than
18 inches (0.46 M) above and to the sides of the stored material
Storing liquid and solid materials in hazardous materials storage cabinets
Storing compressed gases in approved gas cabinets or exhausted enclosures
Materials that are incompatible may not be stored within the same cabinet or exhausted enclosure.
Do not store chemicals alphabetically as a general group. Chemicals may be separated into compatible
groups and stored alphabetically within those compatible groups. Observe all precautions regarding the
storage of incompatible chemicals and refer to the MSDS and any applicable SLAC chemical handling and
safe use guidelines. (See Section 6.1, Program Documents.) A wall chart listing common chemical
incompatibilities is available through SLAC Stores.
The National Oceanic and Atmospheric Administration (NOAA) has made available a reference tool that
allows one to identify the reactivity of substances or mixtures of substances. The chemical reactivity
worksheet (CRW) is a database of reactivity information for more than 6,000 common hazardous chemicals
where one can determine what dangers could arise from accidentally mixing incompatible chemicals.
2

Spill Prevention
Spill prevention methods are used because equipment or containers could break, leak, or spill their
contents. The type of spill prevention used can vary depending on the material, process and/or quantity. It
can include engineered and administrative controls.
Spill containment is one method that can be used to prevent spills and release to the environment. Spill
containment can include drip pans, gas cabinets, storm drain mats, absorbent material and double walled
piping and tanks, as well as response plans and equipment. Spill containment must be chemically
compatible with the hazardous material being stored. It is required if the following conditions are met:
1. Hazardous material could come in contact with an incompatible material (i.e. it could produce an
incompatible chemical reaction, for example, emitting toxic gas, igniting, or exploding).
2. If it escapes from its primary container it may threaten personnel or the environment (for example,
contaminates soil or water, or can enter a floor drain or sink).
Secondary containment is sized spill containment and is required when any hazardous material is stored in
single containers in excess of 55 gallons of liquid, 550 lbs for solids, or when the aggregate capacity of
multiple vessels exceeds 1,000 gallons (10,000 lbs for solids).
Secondary containment must be designed so that it contains 110 percent of the volume of the primary
container. If any storage or use area will hold multiple containers, the secondary containment must hold
either 10 percent of the aggregate volume or 150 percent of the largest container, whichever is greater. If
the hazardous material is stored in an interior hazardous materials storage room, the secondary containment
must also be able to contain 20 minutes of sprinkler flow, at the design flow rate for that area, plus the
volume of the chemical container. If the hazardous material is stored in an exterior storage area and open to
rainfall, it must be designed to contain the volume of the chemical container plus the volume of a 24-hour
rainfall as determined by a 25-year storm and provisions shall be made to drain accumulations of the
rainwater.
Incompatible materials will not be stored within the same spill containment. See Hazardous Materials:
Secondary Containment Requirements and Chapter 16, Spills, for more information.
Time- or Shock-sensitive Chemicals
Because many chemicals cannot be stored indefinitely, the user should establish shelf-life guidelines.
Materials whose hazardous properties may change upon storage should be dated when first opened.
Chemicals that form peroxides or shock-sensitive characteristics should be marked in accordance with the
criteria set forth for unstable, time-sensitive, and pyrophoric materials.

2 Enter CRW into the Search feature or navigate: Home>Software & Data Sets>Planning for
Environmental Emergencies>The Chemical Reactivity Worksheet
Other Chemical Storage Considerations
Best management practices for the storage of chemicals include the following:
Provide a designated storage place for each chemical and return the chemical to that location after each
use.
Store chemicals at or below eye level; keep lids and caps on securely when returning to storage.
Avoid storing chemicals on bench tops, except for chemicals currently being used.
Do not store chemicals in laboratory hoods except for those currently in use.
Do not expose stored chemicals to direct heat or sunlight unless in approved cabinets.
Chemical Storage Inspections
Each chemical storage asset and area will be assigned a custodian, and each custodian is responsible for
ensuring that periodic inspections of the asset and area are performed. Informal inspections are expected to
occur daily. This simply involves observation of the asset and the chemicals contained therein to ensure
that there are no leaks or spills.
A formal documented inspection of hazardous materials storage assets and areas will occur monthly. (See
Hazardous Materials: Storage Inspection Procedure and Form pdf or Word) The custodian is responsible
for maintaining these inspection reports for at least one year.
Refer to Chapter 17, Hazardous Waste, for information about hazardous waste inspections and the
hazardous waste inspection checklist.
In the event there is mixed storage (that is, hazardous materials and waste) in the same storage asset, use
the most restrictive checklist and documentation requirements.
4.2.2.8 Labeling and Signs
Labels are used to provide critical health and safety information to personnel handling and using hazardous
chemicals and products containing hazardous chemicals. Labels or other forms of warning such as signs
must be legible, in English, and prominently displayed on the container. Other languages may be added to
convey information as long as the information is presented in English as well. When the marking or
labeling is impractical due to the size of the container, other solutions, such as a tray in which the container
is located, or a tag attached by a wire loop, may be used. Refer to Chapter 17, Hazardous Waste, for an
example of approved hazardous materials labels.
4.2.2.9 Hazardous Materials Inventory
The Haas tcmIS is used to track chemicals on site and to maintain inventories. Individuals can request
information from the hazardous materials program manager on how to access the system. This inventory
will be reconciled annually by ESH staff, with assistance as necessary from the chemical asset custodians,
and will be submitted by the hazardous materials program manager to the SLAC CUPA (San Mateo
County) to satisfy hazardous material business plan reporting obligations.
4.2.2.10 Chemical Use Reporting
SLAC has reporting requirements for numerous external environment, safety, and health (ESH) programs
associated with chemical use, as well as internal reporting programs required by the DOE. Some of the
more important programs that require such information include the SLAC annual emissions report under
Title V of the Clean Air Act, its hazardous materials business plan, and its toxic release inventory (TRI)
submittals. The hazardous materials program manager has the responsibility to establish the necessary Haas
tcmIS reporting templates in support of ESH program managers who prepare and submit chemical usage
reports using Haas tcmIS reporting capabilities. (Further information is provided in Hazardous Materials:
Purchasing Flow Chart.)
4.2.2.11 Sharps Disposal
Sharp objects such as needles, syringes, and razors require storage and handling to prevent accidents to
workers. For proper disposal of sharp objects, please see Chapter 46, Blood-borne Pathogens. Sharp
items that are not contaminated with bodily fluids, but may have been contaminated by a hazardous
substance should be treated as hazardous waste, and special consideration should be given to minimize the
risk of cuts. Some sharp objects may need additional labeling and handling based on their hazardous and
radioactive constituents. Consult the Waste Management Group or the Radiation Protection Department for
further guidance and requirements (Chapter 17, Hazardous Waste, and Chapter 9, Radiological Safety).
4.2.3 Industrial Hygiene
Industrial hygiene (IH) monitoring is the measurement of chemical, physical, and biological hazards in the
workplace. Chemical hazards exist when there is a risk of direct skin contact, inhalation, ingestion, or
absorption of hazardous chemicals in the form of liquids, solids, vapors, gases, dusts, fumes, or mists. The
degree of risk associated with handling a specific chemical depends on the toxicity of the chemical and the
magnitude and duration of exposure. Chapter 5, Industrial Hygiene, provides all of the applicable
information regarding this program and its implementation at SLAC.
4.2.4 Accidental Exposures
4.2.4.1 Inhalation Exposures
Many chemicals can become airborne as gases, mists, vapors, or dusts. Exposure through the respiratory
system can be very dangerous because absorption into the blood stream through the lungs occurs quickly.
In addition, many materials can damage the nose, throat, and lungs directly. Persons over-exposed to
chemicals should immediately be relocated to fresh air and be provided with medical attention. This may
include the administration of oxygen as well as other medical treatment. Emergency response should be
notified as soon as possible by dialing 911.
4.2.4.2 Eye Contact
Many chemicals will damage the eyes if contact occurs. If a chemical contacts the eyes, immediately flush
the eyes with copious amounts of water, preferably at the nearest eyewash station. A minimum of
15 minutes rinse time is required. Emergency response should be notified as soon as possible by dialing
911. Do not stop flushing the eyes until emergency personnel arrive on the scene and inform you to stop
flushing.
4.2.4.3 Skin Contact
If a chemical comes into contact with the skin, immediately rinse the affected area with large amounts of
running water. This may be done in a sink if the hands are the only portion of the body contacted or under a
safety shower if the exposure area is more extensive. Emergency response should be notified as soon as
possible by dialing 911 if the chemical is a corrosive or could have been absorbed through the skin.
Remove contaminated clothing while under the shower. Remain under the shower until emergency
personnel inform you to stop, or for a minimum of 15 minutes.
4.2.4.4 Eyewash and Safety Showers
Eyewash stations and safety showers help protect SLAC personnel after an accidental eye or skin exposure
to corrosive or flammable materials. Eyewash stations are required in areas where personnel can come into
contact with corrosive liquids or gases. SLAC relies on the departments responsible for areas with eye or
skin hazards to inspect and ensure the reliability of eyewash stations and safety showers.
Installation, removal, or change of location for any chemical emergency equipment (such as eye washes
and safety showers) must have prior approval by the directorate ESH coordinator or hazardous materials or
industrial hygiene program manager.
Where there is a potential for personnel to be exposed to injurious corrosive materials, the line manager
will ensure appropriate eyewash and shower equipment is available within the work area. Emergency
eyewashes, showers, and drench hoses, however, are not substitutes for proper primary eye and face
protection such as safety glasses, chemical splash goggles, face shields, and protective clothing.
Supervisors (or designees) that are responsible for areas where eyewash stations or safety showers exist
must know the equipment location, inspect the equipment, provide for equipment maintenance, and notify
appropriate personnel to repair or replace the equipment if it is missing, defective, or inoperative.
Below are some of the recommendations and requirements from the ANSI standard (ANSI Z358.1-2004)
for eyewash station and safety shower equipment. For more details about inspections and maintenance that
are not covered in this summary, please refer to the ANSI standards directly (a copy is available in ESH).
The standards summary is provided here as basic reference for supervisors or their designees responsible
for equipment maintenance.
Plumbed eyewashes will be flushed weekly to minimize the accumulation of sediment and other
obstructions. Safety showers will be flushed monthly. Flush until the fluid runs clear.
Each eyewash station and safety shower will be inspected weekly. Log inspections by marking the
inspectors name and inspection date on a tag attached to the equipment. Inspection tags are available
from SLAC Stores. (See Hazardous Materials: Eyewash/Shower Inspection Form pdf or Word.)
The eyewash station or safety shower must comply with the following requirements:
1. Located as close as possible to the chemical use location, preferably within a travel time of ten seconds
from areas where eye or skin hazards are present (consult the ESH Hazardous Materials Group if there
are questions about locations and hazards)
2. Clearly marked
3. Protected from freezing conditions
4. Provided with a path of travel free of obstructions, including closed doors
5. Installed and maintained with no sharp projections in the operating area
6. On the same floor or level as the hazard
7. Equipped with a valve that can be activated in one second or less, (equipped with a crash bar, lever, or
pedal, as opposed to a screw-type valve)
8. Equipped with a hands-free feature that allows for water flow while ones hands are opening eyelids or
removing clothing
9. Capable of flushing both eyes simultaneously (eyewashes only)
10. Protected with nozzle caps or bowl covers (eyewashes only)
11. Capable of delivering no less than 0.4 gallons (1.5 liters) of water per minute for fifteen minutes for
eyewashes 20 gallons (75.7 liters) of water per minute for 15 minutes for safety showers
Note Hand-held drench hoses may be installed to supplement an eyewashes or showers, but may not
replace them.
Self-contained eyewash units may be used in areas where it is not feasible to install plumbed units. Where
the possibility of freezing conditions exists, units will be protected from freezing, or freeze-protected
equipment will be installed.
Tepid water will be provided at all newly installed eyewashes and safety showers, and should be provided
at existing installations whenever possible. The term tepid is defined by ANSI as moderately warm or
lukewarm, but ANSI does not specifically define a temperature range for tepid water. The SLAC ESH
Division agrees with the general industry consensus that tepid water should range from 60 to 92F (15 to
33C). (See Hazardous Materials: Eyewash/Shower Inspection Procedure and Hazardous Materials:
Eyewash/Shower Inspection Form pdf or Word.)
4.2.4.5 Personal Protective Equipment
The use of personal protective equipment (PPE) is required in some areas at SLAC for protection of
workers from various chemical hazards. PPE is not a substitute for adequate engineering or administrative
controls and should be used only if no other measures are adequate or feasible. A description of PPE for
chemical hazards is provided in Hazardous Materials: Personal Protective Equipment Requirements. Refer
to Chapter 19, Personal Protective Equipment, for complete requirements related to PPE, including
PPE: Prescription Safety Glasses Purchase and Reimbursement Procedure
PPE: Prescription Safety Glasses Approval Form pdf or Word
4.2.5 Fire Prevention
The following requirements are specific to fire hazards of hazardous materials. See Chapter 12, Fire and
Life Safety, for complete information about fire prevention, protection, and suppression.
Take measures to prevent ignition of flammables. Smoking, welding, cutting, grinding, and using open
flames or ordinary electric equipment in the vicinity of flammable materials is prohibited. Consult the
fire marshal for specific distance requirements. NO SMOKING signs must be posted on or near
storage cabinets for flammables and in areas where flammables are stored, handled, or used. NO
SMOKING signs and FLAMMABLE signs and labels are available from SLAC Stores.
Anticipate the type of fire extinguisher required should an experiment or other use of chemicals result
in a fire. The fire marshal may be contacted for information regarding type, spacing, and location of
fire extinguishers.
Equipment and containers dispensing flammable or combustible liquids must be properly bonded and
grounded to prevent the accumulation of static and a potential ignition source.
Electrical wiring and equipment in close proximity to flammable and combustible liquids, flammable
gases, and flammable solids, must be installed and maintained in accordance with the NFPA National
Electrical Code and the California Fire Code. Such operations must be classified appropriately and the
appropriate class of electrical equipment must be used (the fire marshal should be consulted to assist in
this classification).
An open flame should only be used when necessary and extinguished when it is no longer needed. For
additional information see Fire and Life Safety: Fire Prevention Hot Work Procedures.
Personnel working in a chemical area should become familiar with the following information:
Location and use of the nearest fire extinguishers
Location and use of the nearest eyewash station and safety shower
Location and use of any chemical-specific antidotes
Location and route to the nearest emergency exit
Location and use of the nearest fire pull box and telephone for emergency notification
Location and proper method for de-energizing and/or isolation of hazardous equipment or
processes
Refer to Fire and Life Safety: Limiting Fire Hazards Guidelines for further information.
4.3 Training
Specific training is required for everyone at SLAC who works with hazardous materials. The training of
chemical workers (see Section 5, Definitions) is described in this section. The overall training curriculum
for hazardous materials is presented in Hazardous Materials: Training Flow Chart.
4.3.1 Chemical Worker
All SLAC employees receive their initial orientation through the following course:
ESH Course 219, Employee Orientation to Environment, Safety and Health (ESH Course 219)
If the worker is a chemical worker or supervises chemical workers, he or she is required to take the
following course:
ESH Course 105, Hazardous Materials Management (ESH Course 105)
This course is taken when an employee is first assigned to a chemical worker job.
Non-chemical workers can take the following resource course if they are interested or if they are required
to do so by their supervisor.

ESH Course 103, Hazard Communication Awareness (ESH Course 103)
In addition to ESH Course 105, chemical workers must receive on-the-job training, provided by their
supervisor. This training is to familiarize chemical workers with the hazards, controls, and procedures
specific to their work area. Personnel will complete both types of training prior to working in areas
containing hazardous chemicals. Supervisors are responsible for performing on-the-job training when either
the hazards change (for example, new chemicals are introduced), the persons job tasks change, or if the
supervisor becomes aware of new hazards (for example, new information about the chemicals, results of an
accident investigation).
Supervisors must ensure that the OJT includes, at a minimum, the following topics:
1. How to access the MSDS for materials in that particular work area
2. Physical and health hazards of the specific chemicals in the work area
3. Measures staff can take to protect themselves from relevant chemical hazards, including the use and
limitations of PPE
4. Methods used to detect the presence or release of hazardous chemicals in the work area
User and subcontractor personnel covered under the hazard communication standard are expected to
receive hazard communication training provided by their employer prior to starting work at SLAC.
4.3.2 Chemical Hygiene Worker
All personnel who work in laboratories covered by the chemical hygiene program (CHP) must receive
specific training in accordance with the CHP. In addition to material covered under ESH Course 105, this
includes
Methods and observations used to determine the presence or release of a hazardous chemical, such as
monitoring conducted by the ESH Department, continuous monitoring devices, and the visual
appearance or odor of hazardous chemicals being used
Measures that lab workers can take to protect themselves from hazards, including appropriate
engineering and administrative controls and PPE
Physical and health hazards and environmental aspects in the work area, including flammable and
reactive materials, irritants and corrosives, acute poisons, chronic organic toxins, allergens, and genetic
toxins
Applicable details of the CHP (that is, the individual elements and its availability), including
laboratory-specific operating procedures and protocols
The course will be available as a template and should be modified by the lab manager to make it specific to
the applicable lab. The lab worker and lab manager should sign the course certification that documents that
lab-specific topics were covered. The frequency for refresher training is not stipulated in OSHA
regulations; therefore, departments and divisions are encouraged to evaluate the need for such training on a
case-by-case basis and in accordance with other ESH training in the individuals training plan. User and
subcontractor personnel who work in the laboratories covered under the CHP must review and sign those
laboratories specific procedures.
If working in a CHP laboratory, he or she is required to take the following course:
ESH Course 199, Laboratory User CHP Training (ESH Course 199)
4.3.3 Personal Protective Equipment Training
Following completion of ESH Course 105 and the chemical hygiene program training, all chemical workers
are required to take the PPE course:
ESH Course 255, Personal Protective Equipment (ESH Course 255)
No retraining is required, unless there is a new job assignment involving new exposure situations, if the
hazards change, or if the supervisor becomes aware of new hazards.
4.3.4 Job- and Chemical-specific Safety Training
Depending upon the results of the SLAC Training Assessment (STA), workers may be required to
complete other chemical-related training programs. Refer to Hazardous Materials: Training Flow Chart for
when these courses are required and the applicable chapter of this manual for further details.
5 Definitions
Chemical. Any element, chemical compound, or mixture of elements and/or compounds
Chemical asset custodian. The individual designated by an area manager as the responsible party for
chemical storage assets (see chemical storage asset)
Chemical laboratory supervisor. Supervisory personnel responsible for the operations in a laboratory
designated under the chemical hygiene program (see Section 4.1.3, Chemical Hygiene Program)
Chemical management services (CMS). A software and material inventory management system through
which chemicals are ordered, inspected, delivered, inventoried, paid for and reported (see Total Chemical
Management Information System, tcmIS)
Chemical storage asset. Items used to either directly store hazardous materials or store containers of
hazardous materials. These include bulk storage tanks, tube trailers, flammable container storage cabinets,
corrosive material storage cabinets, chemical refrigerators, laboratory hoods with built-in storage cabinets,
other cabinets used to store lesser hazardous materials, and gas racks used to store compressed gas
cylinders.
Chemical worker. Persons whose job responsibilities or tasks include the transportation, dispensing,
disposal, or other handling of hazardous materials, or whose work environment provides for a reasonable
probability of exposure to a hazardous material, other than those materials that meet the definition of a
consumer product (see Section 2.1.1, Chemical Exemptions).
Container. Any bag, barrel, bottle, box, can, cylinder, drum, reaction vessel, storage tank, or the like that
contains a hazardous chemical
Control area. A building or portion of a building within which hazardous materials are allowed to be
stored, dispensed, used or handled. This area is partitioned from other areas of the building through the use
of a minimum of one-hour fire rated separations. A maximum of four control areas in a building is allowed.
Hazardous material. Any chemical or material that, due to its physical or chemical properties, poses a risk
to the health or safety of humans, environment, or the physical plant
Hazardous waste. Any hazardous material not appropriate for further use which meets the legal definition
of a hazardous waste
Industrial hygiene (IH). The science devoted to the anticipation, recognition, evaluation, prevention, and
control of those occupational factors or stresses arising in or from the workplace which may cause sickness,
impaired health and well being, or significant discomfort among workers or citizens of the community.
Label. Any written, printed, or graphic material displayed on or affixed to containers of hazardous material
Laboratory scale. Work with substances in which the containers used for reactions, transfers, and other
handling of substances is designed to be easily and safety manipulated by one person
Material safety data sheet (MSDS). A document produced by chemical manufacturers and importers to
relay chemical, physical and hazard information about specific substances
Occupancy classification. The purpose for which a building or part thereof is used or intended to be used.
There are seven main occupancy classifications that may be present at SLAC: Group A (assembly),
Group B (office, professional or service-type occupancies which are not classified as Group H
occupancies), Group F (factory and/or industrial occupancies that are not classified as Group H
occupancies), Group H (hazardous operations occupancies with high fire, explosion or health hazard),
Group R (residential and hotel occupancies), Group S (storage and warehousing occupancies that are not
classified as Group H occupancies), and Group U (includes garages, carports, sheds and agricultural
buildings).
Nanomaterial. Material with at least one dimension between one and 100 nanometers (for more detail, see
Section 1.2, Scope and Applicability, of the Nanomaterial Safety Plan.)
Permissible exposure limit (PEL). The maximum amount or concentration of a chemical that a worker may
be exposed to under OSHA regulations
Tank. Container larger than 60 gallons (227 liters)
Total Chemical Management Information System (tcmIS). The trademarked name of the chemical
information system provided by the SLAC CMS vendor, Haas TCM (see chemical management services)
Threshold limit value (TLV). The American Conference of Governmental Industrial Hygienist (ACGIH)
level of exposure that a typical worker can experience without an unreasonable risk of disease or injury
Threshold quantity (TQ). Term used with regards to the OSHA Process Safety Management (PSM)
Standard and the California Accidental Release Program (CalARP). OSHA PSM TQs are listed in 29 CFR
1910.119, Appendix A; CalARP TQs in 19 CCR 2770.5.
6 References
6.1 Program Documents
Chemical Management Services
Chemical Management Services (CMS)
Chemical Use Maps
DOE MSDS Viewer
Hazard Communication and MSDS References
General
Consolidated Chemical Contingency Plan (SLAC-I-730-3A86H-008)
Chemical Hygiene
Chemical Hygiene Plan (SLAC-I-730-0A09M-002)
Hazardous Materials: Chemical Hygiene Program Laboratories List (SLAC-I-730-0A09V-001)
Nanomaterial
Nanomaterial Safety Plan (SLAC-I-730-0A09M-008)
Purchasing
Hazardous Materials: Purchasing Flow Chart (SLAC-I-730-0A09S-014)
Hazardous Materials: Purchasing Procedure (SLAC-I-730-0A09C-001)
Hazardous Materials: Chemical Screening Criteria (SLAC-I-730-0A09S-033)
Hazardous Materials: Toxic and Hazardous Chemical Justification Form (SLAC-I-730-0A09J-006)
pdf or Word
Hazardous Materials: Ethanol Purchasing Procedure (SLAC-I-730-0A09C-002)
Storage
Hazardous Materials: Chemical Storage Asset Requirements (SLAC-I-730-0A09S-018)
Hazardous Materials: Storage Inspection Procedure and Form (SLAC-I-730-0A09J-001) pdf or Word
Hazardous Materials: Secondary Containment Decision Flow Chart (SLAC-I-730-0A09S-015)
Hazardous Materials: Secondary Containment Requirements (SLAC-I-730-0A09S-020)
Transportation
Hazardous Materials: On-site Transportation Requirements (SLAC-I-730-0A09S-019)
Use
Hazardous Materials: Chemical Use Planning Guidelines (SLAC-I-730-0A09T-018)
Hazardous Materials: Training Flow Chart (SLAC-I-730-0A09S-013)
Hazardous Materials: Personal Protective Equipment Requirements (SLAC-I-730-0A09S-017)
Hazardous Materials: Eyewash/Shower Inspection Procedure (SLAC-I-730-0A09C-003)
Hazardous Materials: Eyewash/Shower Inspection Form (SLAC-I-730-0A09J-003) pdf or Word
Hazardous Materials: Fume Hood Velocity Survey Form (SLAC-I-730-0A09J-002) pdf or Word
Hazardous Materials: Fume Hood Survey Sticker (SLAC-I-730-0A09S-016) pdf or Word
Safe Use Guidelines
Hazardous Materials: Cryogenic Gas Safe Handling Guideline (SLAC-I-730-0A09T-002)
Hazardous Materials: Crystalline Silica Safe Handling Guideline (SLAC-I-730-0A09T-014)
Hazardous Materials: Ethane Safe Handling Guideline (SLAC-I-730-0A09T-003)
Hazardous Materials: Flammable and Combustible Liquids Safe Handling Guideline (SLAC-I-730-
0A09T-004)
Hazardous Materials: Flammable Solids Safe Handling Guideline (SLAC-I-730-0A09T-005)
Hazardous Materials: Hydrochloric Acid Safe Handling Guideline (SLAC-I-730-0A09T-006)
Hazardous Materials: Hydrofluoric Acid Safe Handling Guideline (SLAC-I-730-0A09T-001)
Hazardous Materials: Mercury and Mercury Compounds Safe Handling Guideline (SLAC-I-730-
0A09T-009)
Hazardous Materials: Nitric Acid Safe Handling Guideline (SLAC-I-730-0A09T-010)
Hazardous Materials: Organic Peroxides Safe Handling Guideline (SLAC-I-730-0A09T-012)
Hazardous Materials: Oxygen Safe Handling Guideline (SLAC-I-730-0A09T-011)
Hazardous Materials: Potassium Cyanide Safe Handling Guideline (SLAC-I-730-0A09T-013)
Hazardous Materials: Sodium Hydroxide Safe Handling Guideline (SLAC-I-730-0A09T-015)
Hazardous Materials: Sodium Hypochlorite Safe Handling Guideline (SLAC-I-730-0A09T-016)
Hazardous Materials: Sulfuric Acid Safe Handling Guideline (SLAC-I-730-0A09T-017)
6.2 Standards
The following standards have been adopted by SLAC:
Title 29, Code of Federal Regulations, Labor, Part 1910, Occupational Safety and Health
Standards
Section 94, Ventilation (29 CFR 1910.94)
Section 101, Compressed Gases (29 CFR 1910.101)
Section 102, Acetylene (29 CFR 1910.102)
Section 103, Hydrogen (29 CFR 1910.103)
Section 104, Oxygen (29 CFR 1910.104)
Section 105, Nitrous Oxide (29 CFR 1910.105)
Section 106, Flammable and Combustible Liquids (29 CFR 1910.106)
Section 108, Dip Tanks Containing Flammable of Combustible Liquid (29 CFR 1910.108)
Section 110, Storage and Handling of Liquefied Petroleum Gases (29 CFR 1910.110)
Section 119, Process Safety Management of Highly Hazardous Chemicals (29 CFR 1910.119)
Section 120, Hazardous Waste Operation and Emergency Response (29 CFR 1910.120)
Sections 123126, Dipping and Coating Operations (29 CFR 1910.123126)
Section 132, General Requirements (29 CFR 1910.132)
Section 133, Eye and Face Protection (29 CFR 1910.133)
Section 134, Respiratory Protection (29 CFR 1910.134)
Section 135, Head Protection (29 CFR 1910.135)
Section 136, Occupational Foot Protection (29 CFR 1910.136)
Section 138, Hand Protection (29 CFR 1910.138)
Sections 10001052, Subpart Z, Toxic and Hazardous Substances (29 CFR 1910.10001052)
Section 1025, Lead (29 CFR 1910.1025)
Section 1200, Hazard Communication (29 CFR 1910.1200)
Section 1450, Occupational Exposure to Hazardous Chemicals in Laboratories (29 CFR
1910.1450)
Title 40, Code of Federal Regulations, Protection of the Environment, Chapter I, Environmental
Protection Agency

Part 68, Chemical Accident Prevention (40 CFR 68)

Part 355, Emergency Planning and Notification (40 CFR 355)
Part 372, Toxic Chemical Release Reporting (40 CFR 372)
Title 49, Code of Federal Regulations, Transportation, Chapter I, Pipeline and Hazardous Materials
Safety Administration, Department of Transportation

Part 171, General Information, Regulations, and Definitions(49 CFR 171)
Part 172, Hazardous Materials Table, Special Provisions, Hazardous Materials Communications,
Emergency Response Information , and Training Requirements (49 CFR 172)
Part 173, Shippers: General Requirements for Shipments and Packaging (49 CFR 173)
Part 175, Carriage by Aircraft (49 CFR 175)
Part 177, Carriage by Public Highway (49 CFR 177)
Part 178, Specifications for Packaging (49 CFR 178)
Part 180, Continuing Qualification and Maintenance of Packaging (49 CFR 180)
Department of Energy Handbook 1139/3-2008, Chemical Management, Volume 3, Consolidated
Chemical User Safety and Health Requirements (DOE HDBK-1139/3-2008)
California Health and Safety Code, Division 20, Miscellaneous Health and Safety Provisions
Chapter 6.5, Hazardous Waste Control (HSC 2510025250.28)
Chapter 6.67, Aboveground Storage of Petroleum (HSC 2527025270.13)
Chapter 6.7, Underground Storage of Hazardous Substances (HSC 2528025299.206)
Chapter 6.95, Hazardous Materials Release Response Plans and Inventory (HSC 2550025545)
Title 8, California Code of Regulations, Department of Industrial Relations, Division 1, Department
of Industrial Relations, Chapter 4, Division of Industrial Safety, Subchapter 7, General Industry
Safety Orders
Group 16, Control of Hazardous Substances

(8 CCR 51395155, 51605199, 52005220, 5225
5230)
Group 20, Flammable Liquids, Gases and Vapors (8 CCR 54155612)
Title 19, California Code of Regulations, Public Safety, Division 2, Office of Emergency Services
Chapter 4.5, California Accidental Release Prevention Program (19 CCR 27352785)
Title 22, California Code of Regulations, Social Security, Division 2, Department of Social
Services Department of Health Services, Subdivision 1, Health and Welfare Agency

Chapter 3, Safe Drinking Water and Toxic Enforcement Act of 1986 (22 CCR 12000-14000)
Title 22, California Code of Regulations, Social Security, Division 4.5, Environmental Health
Standards for the Management of Hazardous Waste

Sections 6600168100, various sections (22 CCR 66000168100)
Title 24, California Code of Regulations, Part 9, California Fire Code
Chapters 27 through 41 (24 CCR 27014101)
San Mateo County Environmental Health Division, Certified Unified Program Agency (CUPA); all
requirements covered under Unidocs
3

Department of Energy Policy 456.1, Secretarial Policy Statement on Nanoscale Safety (DOE P
456.1)
ASTM International (ASTM) E2535-2007, Guide for Handling Unbound Engineered Nanoscale
Particles in Occupational Settings (ASTM E2535-2007)
The following additional standards are referred to in other regulatory requirements (for example, OSHA
and the fire code) and must also be followed by SLAC:
American National Standards Institute (ANSI)
ANSI A13.1-2007, Scheme for Identification of Pipelines (ANSI A13.1-2007)
ANSI Z87.1-2003, Occupational and Educational Personal Eye and Face Protection Devices
(ANSI Z87.1-2003)

3 Note: Santa Clara County Fire Chiefs Hazardous Materials Subcommittee and Santa Clara County
Department of Environmental Health (DEH) established a process to standardize many of the forms,
guidelines, and procedures related to the management of hazardous materials and hazardous wastes. To
further assist regulated operations the Unidocs web site was created in 1998. This web site provides
access to the most current versions of hazardous materials regulatory documents and provides links to
the local hazardous materials and hazardous waste regulatory agencies as well as other related sites.
ANSI Z358.1-2004, Emergency Eyewashes and Safety Equipment (ANSI Z358.1-2004)
National Fire Protection Association (NFPA)
NFPA 704, Standard System for the Identification of the Hazards of Materials for Emergency
Response (NFPA 704)
6.3 Related Documents
SLAC Environment, Safety, and Health Manual (SLAC-I-720-0A29Z-001)
Chapter 1, General Policy and Responsibilities
Chapter 2, Work Planning and Control
Chapter 3, Medical
Chapter 5, Industrial Hygiene
Chapter 9, Radiological Safety
Chapter 12, Fire and Life Safety
Chapter 16, Spills
Chapter 17, Hazardous Waste
Chapter 19, Personal Protective Equipment
Chapter 20, Lead Safety
Chapter 22, Waste Minimization and Pollution Prevention
Chapter 27, Asbestos
Chapter 29, Respiratory Protection
Chapter 36, Cryogenic and Oxygen Deficiency Hazard Safety
Chapter 38, Compressed Gas Cylinders
Chapter 42, Subcontractor Construction Safety
Chapter 46, Blood-borne Pathogens
Other SLAC Documents
Building Manager Program Manual (SLAC-I-720-0A03Z-001)
On-site Hazardous Materials Transportation Safety Document (SLAC-I-720-0A86Z-002)
SLAC Chronic Beryllium Disease Prevention Program (SLAC-I-730-0A09M-001)
Other
The Chemical Reactivity Worksheet
4

Proposition 65

4 Enter CRW into the Search feature or navigate: Home>Software & Data Sets>Planning for
Environmental Emergencies>The Chemical Reactivity Worksheet)
California Accidental Release Prevention Program (CalARP)
San Mateo County Health Department The California Accidental Release Program (CalARP)
ASTM International (ASTM) E2456-2006, Terminology Relating to Nanotechnology (ASTM
E2456-2006)
National Fire Protection Association (NFPA) National Electrical Code (NFPA 70-2005)
7 Document Information
Title: Hazardous Materials
URL: http://www-group.slac.stanford.edu/esh/eshmanual/pdfs/ESHch40.pdf
Revision Record: https://www-
internal.slac.stanford.edu/esh/docreview/reports/revisions.asp?ProductID=23
Department: Industrial Hygiene and Information Management
Program: Hazardous Materials
Date Effective: 21 September 2009

Hazardous Materials: Chemical Hygiene Program
Laboratories List
Owner: Program Manager
Authority: ES&H Manual, Chapter 40, Hazardous Materials
1

The following laboratories are required to develop and implement a written chemical
hygiene plan:

Bldg Room Lab Name
120 257 SMB User Sample Preparation Lab
120 258 / 259 SMB Staff Sample Preparation Lab
120 260 SMB User Sample Preparation Lab (Glove Box Room)
131 113 MEIS User Sample Preparation
131 209 SMB User Sample Preparation Lab
130 102 PX Staff Sample Preparation Lab
139 201 SIMES Lab (Electrochemistry Lab)
40 TBD PULSE Lab

1 SLAC Environment, Safety, and Health Manual (SLAC-I-720-0A29Z-001), Chapter 40, Hazardous
Materials, http://www-group.slac.stanford.edu/esh/hazardous_substances/haz_materials/policies.htm
24 Nov 2008 (updated 30 Dec 2008) SLAC-I-730-0A09V-001-R001 1 of 1

Hazardous Materials: Purchasing Flow Chart
1

The CMS data management platform facilitates compliance with environment, safety,
and health reporting and provides a tool for maintaining safe working environments. The
following flow chart details the specific steps in the process.

Requester IDs
desired material
Material in tcmIS
?
Add to Haas
TCM Catalog
Requester
Submits MSDS
Special
hazards?
ESH Notification
no
Review issues
with requester
(e.g., material, use,
quantity, etc.)
ESH issues
resolved?
ESH denies request
and documents
n
o
ESH review
yes
yes
no
Inputs order
Order
approved
1
?
Bulk or direct
2
ship material
?
yes
yes
Min/Max
or
OOR?
no
M/M
4
Order processed by
Haas Gilroy Hub;
Pick & Ship
Order processed by
Haas Purchasing;
Order placed w/supplier;
OOR
4
Received @ Haas Gilroy
Hub; QA/QC; Labeled
Ship to SLAC
Requester drop location
Order closed
Bulk
3
or direct ship
item delivered
directly to SLAC
yes
Notes:
1. Approval by second party and/or order limitation
business rules set up in tcmIS.
2. Bulk gases and compressed gas cylinders.
3. LN2 to be on telemetry, so orders to be placed
automatically.
4. M/M =Min/Max Inventory;
OOR =Order on Request
N
e
x
t

b
u
s
.

d
a
y

w
h
e
n
o
r
d
e
r
e
d

b
y

1
P
M
Ship to Gilroy Hub
Requester
submits New
Chemical Request
Requester given
delivery date
Notified order
denied
3
1 =environmental reporting
SLAC Users HaasTCM SLAC ESH
Responsible Party:
tcmIS
1 2
2 =financial reporting
3 =chemical storage, use & disposal
Refer to Chapter 17 & 22 for Hazardous
Waste and Waste Minimization
Requester IDs
desired material
Material in tcmIS
?
Add to Haas
TCM Catalog
Requester
Submits MSDS
Special
hazards?
ESH Notification
no
Review issues
with requester
(e.g., material, use,
quantity, etc.)
ESH issues
resolved?
ESH denies request
and documents
n
o
ESH review
yes
yes
no
Inputs order
Order
approved
1
?
Bulk or direct
2
ship material
?
yes
yes
Min/Max
or
OOR?
no
M/M
4
Order processed by
Haas Gilroy Hub;
Pick & Ship
Order processed by
Haas Purchasing;
Order placed w/supplier;
OOR
4
Received @ Haas Gilroy
Hub; QA/QC; Labeled
Ship to SLAC
Requester drop location
Order closed
Bulk
3
or direct ship
item delivered
directly to SLAC
yes
Notes:
1. Approval by second party and/or order limitation
business rules set up in tcmIS.
2. Bulk gases and compressed gas cylinders.
3. LN2 to be on telemetry, so orders to be placed
automatically.
4. M/M =Min/Max Inventory;
OOR =Order on Request
N
e
x
t

b
u
s
.

d
a
y

w
h
e
n
o
r
d
e
r
e
d

b
y

1
P
M
Ship to Gilroy Hub
Requester
submits New
Chemical Request
Requester given
delivery date
Notified order
denied
3
1 =environmental reporting
SLAC Users HaasTCM SLAC ESH
Responsible Party:
tcmIS
1 2
2 =financial reporting
3 =chemical storage, use & disposal
Refer to Chapter 17 & 22 for Hazardous
Waste and Waste Minimization

4 J an 2007 (updated 30 Dec 2008) SLAC-I-730-0A09S-014-R001 1 of 1

Hazardous Materials: Purchasing Procedure
URL: http://www-group.slac.stanford.edu/esh/eshmanual/references/hazmatProcedPurchase.pdf
Authority: ESH Manual, Chapter 40, "Hazardous Material"
Date Effective: 19 August 2009
1 Purpose
The purpose of this procedure is to ensure that 1) all chemical purchases are placed and tracked centrally,
using the chemical management services (CMS) and Haas tcmIS and 2) new chemicals are screened against
an established criteria to support their safe management and use. (See Hazardous Materials: Chemical
Screening Criteria.)
2 Scope
This procedure covers adding chemicals to the Haas tcmIS catalog and the associated ESH screening
process, as well as ordering chemicals. In the event there are disagreements in the characterization of
hazards or appropriate controls as the result of the screening process, it also includes appeal and
justification processes.
3 Applicability
This procedure applies to any one who purchases chemicals or needs to add new products to the Haas
catalog.
4 Prerequisites
To access the Haas tcmIS system, employees or approved users must be registered with Haas. To initiate
registration, contact the hazardous materials program manager.
Ordering is accomplished by a process that involves two levels of system registrants for most purchases:
1. Requester: places orders
2. Financial approver: authorizes purchases
A material safety data sheet (MSDS) must be submitted with all requests to add a new item to the catalog.
Additional requirements may be triggered by ESH screening as listed in Section 5.2, Adding Chemicals to
the Catalog.
4 J an 2007 (updated 19 Aug 2009) SLAC-I-730-0A09C-001-R002 1 of 5
5 Procedures
5.1 Ordering from the Catalog
Step Person Action
1. Chemical user Identifies the responsible requester by doing one of the following
Checks the list of authorized CMS requesters
Contacts the on-site Haas representative
Contacts the hazardous materials program manager to place the order if there isnt
a requester assigned to the workgroup.
2. Chemical user /
Authorized CMS
Requester
Checks catalog listing for chemical
If the chemical is not listed, submits a catalog add request as described in Section
5.2, Adding Chemicals to the Catalog
3. Authorized CMS
Requester
Places chemical order through Haas tcmIS
The requesting process results in an e-mail notification to the financial approver
4. Financial approver Approves the order if it is reasonable, within the approved financial limits, and is
using the correct account number. Shipment does not occur until the order is
approved. Financial approval is approval of the invoice.
5.2 Adding Chemicals to the Catalog
For an illustration of this procedure, see Figure 1.
Step Person Action
1. Authorized CMS
requester
If the required chemical is not listed in the catalog, submits a catalog add request.
The tcmIS help menu describes each step, including the submission of product
specifications and an MSDS.
2. tcmIS Notifies ESH reviewers that a new chemical addition is pending.
Confirms that submitted chemical information (such as the MSDS, supplier, and
package size) is current.
3. ESH reviewers Review new chemical request within three business days against approved screening
criteria to determine the status of the chemical or product: approved, conditional
approval, or rejected (Hazardous Materials: Chemical Screening Criteria)
Fast track approval: chemicals similar to previously approved products may be
expedited automatically. To initiate fast track approval for time-sensitive projects,
contact the hazardous materials program manager.
If the chemical or product is approved, go to step 10.
4. ESH reviewer(s) Contact the chemical user (and ESH safety coordinator if appropriate) to discuss
Less toxic substitute(s)
Conditional approval contingent on restrictions or controls
Rejection of the request based on established screening criteria
The need for upper management approval for toxic or hazardous mission critical
products that otherwise may have been rejected. May result in the hazardous
Step Person Action
material program manager requesting the completion of the justification form (as
described in steps 7 through 9).
5. Chemical user Accepts ESH reviewers assessment of the chemical and works with directorate or
local ESH coordinator to identify and implement controls. ESH will review
implementation prior to approval.
6. Chemical user Appeal process: If the chemical user disagrees with the ESH SME assessment on
the categorization, restrictions, or mitigations attached to the use of the materials:
Works directly with the SME with whose assessment he/she disagrees.
Communicates the issue; includes directorate ESH coordinator and provides
supporting documentation and alternative mitigations if necessary.
If the issue is still not resolved, communicates with direct supervisor and site safety
officer. The decision at this level is final and binding.
Note: ESHs primary goal is to support scientific work through the ISEMS process.
Justifying purchase of toxic and hazardous products
7. Chemical user Completes the Hazardous Materials: Toxic and Hazardous Chemical Justification
Form (pdf or Word), which requires review by the directorate or local ESH coordinator
to verify adequate controls are in place and approval by the associate laboratory
director (ALD or designee) for the responsible directorate.
If justification is approved, submits justification form to the hazardous material
program manager
If justification is declined, an alternative chemical or product will need to be found
8. Directorate or local
ESH coordinator and
ALD or designee
Review submitted Hazardous Materials: Toxic and Hazardous Chemical Justification
Form and approve or decline.
ESH coordinator review verifies adequate controls are in place.
Management approval is acknowledgement that the use is justified.
9. Hazardous material
program manager
Compiles approved justification form and informs tcmIS representative of approved
request(s)
Once chemical or product is approved
10. On-site tcmIS
representative
Approves catalog addition
11. tcm buyer Obtains pricing for approved request within one business day
12. tcmIS Adds specifications, safety data, conditions of use, and controls, if any, to catalog and
notifies requester of approval status
13. Requester Places chemical order through Haas tcmIS as described in Section 5.1, Ordering
from the Catalog

Figure 1 Adding a New Chemical to the Catalog Flow Chart
6 References
SLAC Environment, Safety, and Health Manual (SLAC-I-720-0A29Z-001), Chapter 40, Hazardous
Materials
Hazardous Materials: Chemical Screening Criteria (SLAC-I-730-0A09S-033)
Hazardous Materials: Toxic and Hazardous Chemical J ustification Form (SLAC-I-730-0A09J-006)
pdf or Word
Hazardous Materials: Purchasing Flow Chart (SLAC-I-730-0A09S-014)
Chemical Management Services (CMS)
CMS Authorized Users
DOE New tcmIS

Hazardous Materials: Chemical Screening Criteria
URL: http://www-group.slac.stanford.edu/esh/eshmanual/references/hazmatCriteriaChemScreen.pdf
Authority: ESH Manual, Chapter 40, "Hazardous Material"
1 Purpose
All hazardous material requisitions and Haas tcmIS catalog add requests must be reviewed by
Environment, Safety, and Health (ESH) prior to purchase. ESH review must be done in a timely manner
and based on clear and transparent criteria that are communicated, and therefore can be anticipated by
management and staff and made part of the chemical and product selection process
The purpose of chemical screening is to reduce risk by identifying hazards and implementing appropriate
controls before a toxic or hazardous material is delivered to the site.
2 Scope
These criteria apply to the screening of requests to add chemicals to the Haas catalog.
For information on how to initiate a new chemical request, see Hazardous Material: Purchasing Procedure
and Hazardous Material: Purchasing Flow Chart.
3 Applicability
These criteria are to be used by ESH reviewers to screen all Haas tcmIS catalog add requests.
Management and staff can refer to the criteria to make informed chemical and product selections.
4 Prerequisites
Chemical requesters must have access to the Haas tcmIS system and know how to use it.
ESH reviewers must have
Comprehensive knowledge of applicable regulatory lists and requirements
Ability to interpret material safety data sheets (MSDSs)
Haas tcmIS ESH approver status
19 Aug 2009 (updated 19 Aug 2009) SLAC-I-730-0A09S-033-R000 1 of 7
5 Reviewers
Requests for new additions to the Haas catalog are screened by subject matter experts (SMEs) representing
various ESH disciplines, which are organized as distinct approval groups as shown in Table 1. Back-up
within each group is highly recommended to ensure continuity. Divisional and local ESH coordinators are
vital in this review due to their process knowledge and understanding of the organizational needs of the
users and existing controls. They can choose to be in the initial review or only participate when line
management approval and controls are required. Contact the hazardous materials program manager
regarding ESH reviewer assignments.
Table 1 ESH Review Groups and Areas of Responsibility
ESH Discipline / Group Subject or Area of Review Responsibility
Industrial Hygiene (IH) Exposure, nano safety
Risk Management (RM) Fire safety, emergency management
Hazardous Waste (HW) Disposal restrictions
Waste Minimization / Pollution Prevention (WM/P2) Preferred purchases (Greener Choice)
Water (IW,SW,GW) Industrial wastewater discharge, stormwater discharge,
groundwater discharge
Air Quality (AQ) Permitted air emissions, greenhouse gases, ozone depleting
substances (ODSs)
Radiation Protection (RP) Radioactive material
Chemical Management System (CMS) / Hazardous
Material (HM)
Hazardous material storage, hazardous material inventory
6 Chemical Status Determination
Each group will review products against the predefined screening criteria as described below. Each
discipline will apply their expertise to determine the status of the product. The most restrictive status will
apply and will fall into one of the following review results:
Approve. There are no additional controls required. The product has ESH approval for use in the
requesting work area.
Conditional Approval. The product is approved for use with specified conditions. Conditions can
include limiting the quantity, restricting use to a project or process, and in the case of a highly
hazardous material, documentation that the material is required for mission-critical work with no
alternatives available. In this case, the form Hazardous Materials: Toxic and Hazardous Chemical
J ustification Form (pdf or Word) must be completed and submitted prior to making the product
available for purchase.
Rejected. The product is rejected and will not be made available for purchase. J ustification for
rejection can include any of the following:
The material is highly hazardous and is not mission critical.
A less hazardous substitute is available.
The material is highly hazardous and there are no available mitigations.
The quantities will exceed known thresholds that will impact the site due to additional regulatory
restrictions and oversight or high cost of implementing new requirements.
The material is one of the listed banned materials.
The material will be used in a manner that results in unacceptable exposure risks.
7 Chemical Categorization
7.1.1 Categorization Considerations
For chemical screening purposes, chemicals are divided into the following four categories:
1. Banned
2. Of concern
3. Material restricted
4. Use restricted
A description of each category follows. In arriving at a categorization the SME may review various
information sources and consider many factors, including the following:
Analysis of the product MSDS
Identification of human toxicity and analysis of potential for exposure
Identification of environmental toxicity and potential exposure including impacts to air and water
quality, soils/land, and climate, including an analysis of environmental persistence and
bioaccumulation
Availability of substitutes that deliver required performance
Availability of controls to manage identifiable risks
Consideration of the quantity in use and/or storage
Impacts on mission capability and business costs, including decontamination and disposal costs
Comparison of chemicals or constituents against applicable regulatory and environmental hazard lists
such as priority chemicals identified by the US Environmental Protection Agency (EPA), any agency-
specific toxic or hazardous chemical lists, and emerging contaminants identified by the United States
Geological Survey (USGS)
7.1.2 Categories
Categories provide a review process framework and assist in identifying risk types, such as exposure or
environmental release. Understanding the category helps in determining controls so that the material can be
used safely.
Note If a hazardous material belongs to more than one, use the more restrictive category.
Table 2 Toxic and Hazardous Materials Categories
Category Description
Banned The following are banned for use at SLAC due to policy and DOE or regulatory
directives:
Polychlorinated biphenyls (PCBs)
Department of Transportation (DOT) Class 1.1: Explosives (49 CFR 173.50)
Explosive substances release pressure, gas, and heat suddenly when they are
subjected to shock, heat, or high pressure. Division 1.1: Explosives with a mass
explosion hazard: A mass explosion is one which affects almost the entire load
instantaneously. Examples: dynamite, TNT, black powder.
Class I ODSs
Banned asbestos products
Controlled and listed substances listed in the Stanford University Controlled
Substances & Precursor Chemicals Program
California Air Resources Board (CARB) / Bay Area Air Quality Management District
(BAAQMD) banned air contaminants
Lead paint, lead shot, or lead wool
Of Concern Materials that are judged to pose a higher exposure or environmental risk fall into one
of several types as listed below. This category of materials may require justification
for use. Safer alternatives should be evaluated.
Highly hazardous materials
These materials present an exposure risk to workers, emergency responders and the
surrounding community due to physical and chemical hazards. Chemicals with the
following properties are of particular concern:
Highly Reactive, water reactive or pyrophoric (butyllithium solutions in solvents)
Explosive (such as heavy metal azides, perchlorates with heavy metals, picric acid
[[f dry], and peroxide forming substances)
Highly corrosive (concentrated, glacial, fuming acids, concentrated bases)
Highly toxic (cyanide compounds, due to potential generation of HCN gas,
isocyanates (especially MDI), chromium (especially Cr+6), cadmium, lead, nickel,
beryllium -- including Cu-Be alloys
Chemicals with permissible exposure levels (PELs) that are below levels that can
be monitored
Occupational Safety and Health Administration (OSHA)-listed hazardous and toxic
substances (1910 Subpart Z)
OSHA-listed carcinogens, mutagens, teratogens, reproductive toxins per 29 CFR
1910.1003
Proposition 65 (List)
Persistent, bio-accumulative and toxic pollutants (PBTs)
The EPAs Persistent Bio-accumulative and Toxic Chemical Program addresses
chemicals that are a risk due to their persistence, bioaccumulation within the food
web, and toxicity to living organisms. PBTs transfer relatively easily among air, water,
and land, and span boundaries of regulatory programs, geographic entities, and
generations, and so require stringent controls to prevent release into the environment.
Priority chemicals
The National Waste Minimization Program focuses efforts on reducing 31 priority
chemicals (PCs) found in our nation's products and wastes by finding ways to
eliminate or substantially reduce their use by recovering or recycling them. Use the
Priority Chemical Query Tool to retrieve and manipulate PC data.
Materials Restricted These materials are subject to regulated thresholds that must not be exceeded and
apply to the SLAC site as a whole. Every instance of using these products must be
tracked by work groups and areas.
Total toxic organics (TTO) must never exceed levels specified in the Solvent
Management Plan (SMP). For information, see ESH Manual, Chapter 43,
Industrial Wastewater.
Air pollutants listed in ESH Manual, Chapter 30, Air Quality
Greenhouse gases: Carbon dioxide, methane, nitrous oxide, and fluorinated gases,
many of which have high global warming potential and include SF6 and PFCs
Ozone depleting substances, Class I (such as R-11, R-12) will be banned
completely by 2010
Non-exempt uses of high volatile organic content (VOC) material, which generally
includes products that contain more than 300 grams/liter (g/l) VOCs. Note:
BAAQMD regulations include specific limits in the 50-800 g/l range, such as
lacquer thinner or other solvents for which the limit is 50 g/l
Use Restricted The following materials can only be used in a specified area or processes and/or are
kept under specified quantity thresholds, and includes justified mission-critical
materials of concern. Use restricted products must be highly controlled and may
require additional work authority and control procedures.
Radioactive materials and standards require prior approval by the Radiation
Protection Department and specified training. See ESH Manual Chapter 9,
Radiological Safety.
Cyanide salts can only be used within the constraints of the SLAC Risk
Management Plan
Mercury-containing apparatus and equipment cannot be purchased unless the
exceptions specified by the California Department of Toxic Substances Control
(DTSC) are met (see DTSC Fact Sheet, March 2006). (See also DTSCs Mercury
in Thermostats and California Health and Safety Code, Division 20, Chapter 6.5,
Sections 25214.8.1 through 25214.8.6.)
Asbestos containing products can only be purchased and used if approved by the
SLAC industrial hygiene group and the air quality program manager
National Fire Protection Association (NFPA) Health rated 3 and 4 materials must
remain at or below quantities that can be easily and safely manipulated by one
person [see 29 CFR 1910.1450(b)] unless approved by the fire marshal. May
need additional assessment if stored or used in an area above 5 gallons. Must be
tracked in 1-gallon quantities.
New lead purchases must be justified in part by determining that on-site stock will
not meet requirement.
Small volumes of high VOC content material can be approved for specified used
with the approval of the air quality program manager
Toxic gases can only be purchased if all required controls are in place prior to
purchase
8 Preferred Materials
Identifying chemicals and products with fewer health and environmental risks that meet performance
specifications is an integral part of the ESH chemical screening process. In the longer term, the goal is to
identify greener substitutes and increase the number of available choices.
8.1 Greener Choices
The Haas catalog identifies preferable Greener Choice products based on assessment by such
organizations as Green Seal. A product earns the greener choice label by exhibiting such attributes as
Minimized exposure to concentrates
Contains non-ozone depleting substances
Reduced bio-concentration and toxicity
Reduced flammability (HMIS/NFPA ratings of 1 or 2 preferably)
Reduced or no added dyes, except when added for safety purposes
Reduced or no added fragrances
Reduced or no skin irritants
Reduced or no VOCs
Reduced packaging
Recyclable packaging
Recycled-content in packaging
Reduced use of disinfectants
8.2 Resources
Chemical requesters and ESH reviewers can use the resources in the following table to identify
environment-friendly products.
Table 3 Environment-friendly Product Resources
Product Category Resources Legal and Other Requirements
Recycled Content

US EPA Comprehensive Procurement
Guidelines Wastes Resource
Conservation
Executive Order (EO) 13423, Strengthening
Federal Environmental, Energy, and
Transportation Management
Federal Acquisition Regulation (FAR), Parts
7, 11, 23
Resource Conservation and Recovery Act
(RCRA), Section 6002
Environmentally
Preferable
US EPA Environmentally Preferable
Purchasing
EO 13423
FAR, Parts 7, 11, 23
Energy Efficiency US EPA Energy Star EO 13423
Product Category Resources Legal and Other Requirements
DOE Federal Energy Management
Program: Energy Efficient Products
FAR, Part 23
EO 13221, Energy Efficient Standby Power
Devices
Bio-based

USDA Bio-Preferred

EO 13423
2002 Farm Security and Rural Investment
Act, Section 9002
Alternative Fuels, Fuel
Efficiency
DOE Federal Energy Management
Program: Federal Fleet Management
DOE Energy Efficiency and Renewable
Energy: Vehicle Technologies Program
EO 13423
Energy Policy Act of 1992 (EPAct), Section
303
Non-ozone Depleting
Substances
US EPA Ozone Layer Depletion
Alternatives / SNAP
Clean Air Act , Section 613
9 References
SLAC Environment, Safety, and Health Manual (SLAC-I-720-0A29Z-001), Chapter 40, Hazardous
Materials
Hazardous Materials: Purchasing Procedure (SLAC-I-730-0A09C-001)
Hazardous Materials: Toxic and Hazardous Chemical J ustification Form (SLAC-I-730-0A09J-006) pdf
or Word
DOE New tcmIS
FedCenter, Checklist For Toxic And Hazardous Chemicals Plans
Risk Management Plan
Solvent Management Plan (SLAC-I-750-3A03M-001)

Hazardous Materials: Toxic and Hazardous Chemical
J ustification Form
URL: http://www-group.slac.stanford.edu/esh/eshmanual/references/hazmatFormJ ust.pdf or Word
Revision Record: https://www-internal.slac.stanford.edu/esh/docreview/reports/revisions.asp?ProductID=461
Authority: ESH Manual, Chapter 40, Hazardous Materials
This form documents line management review approving a purchase request for toxic or hazardous chemicals. The
hazardous material program manager issues this form to the user/requestor if ESH review found that the toxic or
hazardous chemical 1) falls into one of the chemical categories (banned, of concern, material restricted, use
restricted) based on hazard or regulatory status, and 2) there are less toxic substitutes, or 3) this chemical exceeds
screening criteria and is mission-critical. Submit the completed form to the hazardous materials program manager.
For additional detail, see Hazardous Materials: Purchasing Procedure (SLAC-I-730-0A09C-001) and Hazardous
Materials: Chemical Screening Criteria (SLAC-I-730-0A09S-033).
Request to add new chemical to the tcmIS catalog (completed by user/requester)
Name: Phone number: E-mail:
Directorate: Dept/group: Dept/group code: Mail stop:
Material safety data sheet (MSDS) attached? Yes No
Product name: Manufacturer:
Container size (specify units): Proposed storage location:
Estimated maximum quantity (# of containers): Average quantity:
Mission-critical activity description:

How will this product be used? (maintenance, construction, research, fabrication, synthesis)

Less toxic or hazardous substitute was not procured because it is not available (select all that apply):
Within a reasonable period of time At a reasonable price Within performance requirements
Other (explain):
Provide a detailed justification and attach supporting documentation for each indicated reason:

Check if applicable and provide supporting documentation:
Safe storage, use and disposal controls have been identified, implemented and personnel are trained in their use.

(print name, title):

Signature:

Date:
19 Aug 2009 (updated 19 Aug 2009) SLAC-I-730-0A09J -006-R000 1 of 2
Hazardous Materials: Toxic and Hazardous Chemical J ustification Form
19 Aug 2009 (updated 19 Aug 2009) SLAC-I-730-0A09J -006-R000 2 of 2
Review (completed by directorate or local ESH coordinator)
Select one:
I have verified that appropriate controls are in place for the use described.
The request for the item not approved.


Signature: Date:
Approval (completed by ALD or designee))
Select one:
The use is justified and this item is approved for the use described.
The request for the item is not approved.


Signature: Date:

Send completed form to the hazardous materials program manager at M/S 84.
Hazardous Materials: Ethanol Purchasing Procedure
1

17 November 2008
This document is out and being revised.
For guidance, contact the hazards materials program manager (ext. 4538, http://www-
group.slac.stanford.edu/esh/groups/cgs/hmaq/default.htm)

4 J an 2007 (updated 17 Nov 2008) SLAC-I-730-0A09C-002-R001 Draft v1 1 of 1

Hazardous Materials: Chemical Storage Asset
Requirements
1

Bulk Storage Tanks
Bulk storage tanks are used at SLAC to store such materials as liquid nitrogen, helium,
water treatment chemicals (acids, bases, and proprietary treatment chemicals), propane,
isobutene, and others. The installation of hazardous materials bulk storage tanks requires
a design review by the fire marshal and the hazardous materials program manager prior to
purchase or installation. This review evaluates issues such as sighting, material
compatibility, safety controls, pressure relief, seismic design, security, and fire
protection.
Tube Trailers
Tube trailers contain 20 to 40 long, horizontal, compressed gas cylinders bundled
together and connected by manifolds for ease of use, transport, and safety. SLAC
currently uses tube trailers for managing hydrogen and helium. Tube trailers are subject
to the same seismic safety considerations as bulk tanks and are part of the work scope
mentioned above.
It is a Department of Transportation requirement that tube trailers that are in commerce
(that is, will be transported over public roads) must be pressure tested every five years. It
is the responsibility of the custodian to arrange for this testing. Any exception to the five-
year pressure testing requirement must be agreed to in writing by the chairman of the
Hazardous Experimental Equipment Committee and the hazardous materials program
manager.
2

Flammable Container Storage Cabinets
Flammable liquid in quantities greater than 10 gallons per use area
3
must be stored in
approved chemical storage cabinets that meet the design requirements of the California
Fire Code
4
and NFPA 30-2003, Flammable and Combustible Liquids Code.
5
Approved

2 Hazardous Experimental Equipment Committee, https://www-
internal.slac.stanford.edu/esh/committees/heec/charter.htm
3 This is defined here as an aggregate quantity per contiguous area that is controlled and used by one
work group and is a reference to the exemption in ICBO UFC-1997 7902.5.8.
4 Title 24, California Code of Regulations, Part 9, California Fire Code, Chapters 27 through 41,
http://www.bsc.ca.gov/title_24/default.htm. Title 24, California Code of Regulations, California
Building Standards Code, is available only through depository libraries and the publishers of its
Hazardous Materials: Chemical Storage Asset Requirements
and rated hazardous materials storage cabinets will not be used for ordinary (non-
hazardous) storage. Cabinets used to store flammable liquids must meet the following
specifications:
The combined total of all liquids will not exceed 120 gallons (454 L).
Cabinets used to store flammable liquids must be provided with a conspicuous label
in red letters on contrasting background which reads FLAMMABLEKEEP FIRE
AWAY.
Doors must be well fitted and equipped with a latch and new cabinets must be self-
closing.
Cabinets must be seismically braced to a sound structure to prevent dislodgement
during an earthquake. The seismic bracing must not penetrate the cabinet in such a
way that it would facilitate release of the chemical from the cabinet. The SLAC fire
marshal approves seismic bracing of chemical cabinets.
The bottom of the cabinet will be liquid tight to a height of at least two inches (50.8
mm).
Cabinets must be constructed of metal and must be listed (by an accredited listing
agency).
The cabinet, including the door, must be double walled with 1.5 inch (38.1 mm)
airspace between the walls.
J oints must be riveted or welded and tight-fitting.
Unlisted cabinets can be used if approved by the SLAC fire marshal and they
Are constructed from steel with a thickness of at least 0.044 inch (1.12 mm) (18
gauge)
Meet all the requirements of a listed cabinet
Combustible material (wood shelves added after the fact, cardboard boxes and paper)
should be minimized or eliminated.
The number of flammable liquid storage cabinets and quantity of flammable materials
allowed in a building is regulated and determined by occupancy codes, space between
cabinets, and if the building is sprinklered. Contact the SLAC fire marshal for details.
Corrosive Material Storage Cabinets
Incompatible corrosives must not be stored in the same cabinet. All corrosive storage
cabinets must be conspicuously labeled (letters on contrasting background) with
CORROSIVE ACID or CORROSIVE BASE, and seismically braced without
penetrating the cabinet in such a way that would facilitate release of the contents during
an earthquake. All seismic bracing must be approved by the SLAC fire marshal. Cabinets
must be listed by an accredited listing agency for the intended storage of corrosives, or
meet the following requirements:

various components. See the SLAC Research Library Community Pages, http://www-
group.slac.stanford.edu/library/CommunityPages.asp, for available standards. A hard copy of the 2007
California Fire Code is available; see
http://www.slac.stanford.edu/spires/find/books/www?key=352675.
5 National Fire Protection Association (NFPA), Flammable and Combustible Liquids Code (NFPA 30-
2003). See the SLAC Research Library Community Pages, http://www-
group.slac.stanford.edu/library/CommunityPages.asp, for available standards.
The bottom of the cabinet must be liquid tight to a height of at least two inches.
Cabinets will be constructed from steel with a thickness of at least 0.044 inch (1.12
mm) (18 gauge).
Cabinets, including the door, must be double walled with 1.5-inch air space between
the walls.
J oints must be riveted or welded and tight-fitting.
Doors must be well fitted, self-closing, and equipped with a self-latching device.
Cabinets must be treated or coated on the interior with a material that is non-reactive
with the hazardous material stored, and this treatment or coating must cover the entire
interior of the cabinet.
The quantity of corrosive materials allowed in a building is regulated and determined
by occupancy codes, space between cabinets, and if the building is sprinklered.
Contact the SLAC fire marshal for details.
Laboratory Hoods with Built-in Storage Cabinets
Built-in flammable liquid and corrosive material storage cabinets in laboratory hoods are
subject to the requirements listed above.
Note For requirements regarding electrical equipment and devices within cabinets
used for the storage of hazardous materials, see the National Electrical Code.
6

Chemical Refrigerators
Ordinary domestic refrigerators and freezers must not be used for storing flammable
liquids due to exposure to electrical components (light bulbs, switches, contacts and
motors) that can become potential ignition sources. These ignition sources may initiate a
fire or an explosion if flammable vapors are present. Refrigerators and freezers for
storing flammable liquids and/or temperature sensitive chemicals such as peroxides or
epoxies must be designed, constructed and approved for that purpose. Domestic
refrigerator/freezers as well as units that have been modified to remove spark sources are
not acceptable.
Refrigerators must be labeled on the exterior: CAUTION FOR CHEMICAL
STORAGE ONLY; DO NOT STORE FOOD OR BEVERAGES IN THIS
REFRIGERATOR. Labels may be fabricated by users provided the labels are legible
and securely affixed to the refrigerator.
The custodian must have a means (manual or automated) to document the storage
temperature of the temperature-sensitive materials.
Refrigerators used for food storage in or near work areas (shops and labs) must be
labeled with words to the effect of: NOTICE FOOD MAY BE STORED IN THIS
REFRIGERATOR. DO NOT STORE CHEMICALS. Refrigerators used for food and
beverage storage that are located in lunch rooms and office buildings, where there is
no shop or laboratory type chemical use, do not require any postings.

6 National Fire Protection Association (NFPA), National Electrical Code (NFPA 70-2005) See the
SLAC Research Library Community Pages, http://www-
group.slac.stanford.edu/library/CommunityPages.asp, for available standards. A hard copy of NFPA
70-2005 is available; see http://www.slac.stanford.edu/spires/find/books/www?key=327328.

Other Storage Cabinets
It is SLAC policy to allow storage of small quantities of non-flammable, non-highly
hazardous materials in other storage cabinets if present in quantities below the exempt
limits for that chemical class as provided by the California Fire Code, provided the
following conditions are met:
7

The cabinet is clearly identified through exterior labeling as containing chemicals.
The total quantity of chemicals stored in this fashion per cabinet is less than five
gallons.
The cabinet is shown on the CMS map.
8

The cabinet is included in the custodian monthly inspections.
Gas Racks and Compressed Gas Cylinder Storage
At SLAC, gas cylinders are managed in one of two ways: as individual cylinders or as
groups of gas cylinders known as six-packs (six individual cylinders managed as a
unit and connected by manifold). See Chapter 38, Compressed Gas Cylinders,
9
for
more information.

7 See note 4
8 Chemical Use Maps, http://www-group.slac.stanford.edu/esh/groups/cgs/hmaq/cms/ (System
Links>Chemical Use Maps)
9 SLAC Environment, Safety, and Health Manual (SLAC-I-720-0A29Z-001), Chapter 38, Compressed
Gas Cylinders, http://www-
group.slac.stanford.edu/esh/hazardous_substances/compressed_gases/policies.htm
Hazardous Materials: Storage Inspection Procedure and
Form
1

Monthly documented inspections must be carried out by the chemical asset custodian or
designated person for all chemical storage areas and all chemical container types.
Inspection results must be kept on record for a minimum of one year, and must be made
available to ES&H when requested. The following forms can be adapted to meet the
specifications of your storage area, but all basic inspection elements must be included.
Note For inspection requirements for hazardous waste storage areas and waste
containers, see Chapter 17, Hazardous Waste.
2

Documenting Inspection Results
1. Enter the inspection location on the inspection form and verify that this location is
accurately mapped on the CMS chemical use map.
3
If the location is new, or
information is missing or out of date, contact the hazardous materials program
manager or the ESH coordinator to relay any updates.
2. Each month, enter the date, your initials, and place a check in every square that
applies to this location if the condition meets all safety requirements. The form
accommodates 12 inspections, or one full year.
Note If the item does not apply, cross the section out. For example, if there are no
compressed gas cylinders (CGCs), mark one large line or X through the
section. Alternatively, modify the form to more closely meet the conditions of
the storage area.
3. If an inspection item requires corrective action, record your observations and
comments on the Observations and Corrective Actions Log below. Also record the
date that the corrective action was completed.

Waste, http://www-group.slac.stanford.edu/esh/environment/hazardous_waste/policies.htm
3 Chemical Use Maps, http://www-group.slac.stanford.edu/esh/groups/cgs/hmaq/cms/ (System
Links>Chemical Use Maps)
4 J an 2007 (updated 30 Dec 2008) SLAC-I-730-0A09J -001-R001 1 of 3
Hazardous Materials: Storage Inspection Procedure and Form
Inspection location:
Check this box if this location is accurately mapped on the CMS chemical use map per the accompanying instructions.

Storage Area All Containers
Additional Inspection Items for Compressed Gas
Cylinders (CGC)
Inspection Date
I
n
s
p
e
c
t
o
r
s

I
n
i
t
i
a
l
s

S
t
o
r
a
g
e

a
r
e
a

h
a
s

p
r
o
p
e
r

s
i
g
n
a
g
e

a
n
d

s
i
g
n
s

a
r
e

l
e
g
i
b
l
e

S
t
o
r
a
g
e

a
r
e
a

f
r
e
e

o
f

s
p
i
l
l
s

a
n
d

l
e
a
k
s

a
n
d

c
o
n
t
a
i
n
e
r
s

a
r
e

n
o
t

i
n

c
o
n
t
a
c
t

w
i
t
h

s
t
a
n
d
i
n
g

w
a
t
e
r

E
y
e

w
a
s
h
\
s
a
f
e
t
y

s
h
o
w
e
r
s

s
e
r
v
i
c
e
d

a
n
d

t
a
g
g
e
d

(
w
e
e
k
l
y
)

E
R

e
q
u
i
p
m
e
n
t

a
n
d

s
p
i
l
l

k
i
t
s

f
u
n
c
t
i
o
n
a
l

a
n
d

m
a
i
n
t
a
i
n
e
d

F
i
r
e

e
x
t
i
n
g
u
i
s
h
e
r
s

s
e
r
v
i
c
e
d

a
n
d

t
a
g
g
e
d

(
m
o
n
t
h
l
y
)

C
o
n
t
a
i
n
e
r
s

p
r
o
p
e
r
l
y

l
a
b
e
l
e
d

a
n
d

l
a
b
e
l
s

a
r
e

l
e
g
i
b
l
e

C
o
n
t
a
i
n
e
r
s

f
r
e
e

o
f

d
a
m
a
g
e
,

r
e
s
i
d
u
e
,

o
r

c
o
r
r
o
s
i
o
n

A
p
p
r
o
p
r
i
a
t
e

s
e
c
o
n
d
a
r
y

c
o
n
t
a
i
n
m
e
n
t

i
s

i
n

p
l
a
c
e

C
o
n
t
a
i
n
e
r
s

s
e
a
l
e
d

w
i
t
h

t
i
g
h
t
-
f
i
t
t
i
n
g

l
i
d
s
/
b
u
n
g
s

I
n
c
o
m
p
a
t
i
b
l
e
s

p
r
o
p
e
r
l
y

s
e
g
r
e
g
a
t
e
d

C
G
C
s

s
e
c
u
r
e
d

t
o

r
a
c
k

o
r

w
a
l
l

w
i
t
h

t
w
o

s
t
r
a
p
s

o
r

a
p
p
r
o
v
e
d

a
l
t
e
r
n
a
t
e

C
G
C

v
a
l
v
e
s

c
l
o
s
e
d

a
n
d

f
i
t
t
e
d

w
i
t
h

s
a
f
e
t
y

c
a
p
s

C
G
C
s

c
o
n
t
a
i
n
i
n
g

t
o
x
i
c

o
r

f
l
a
m
m
a
b
l
e

g
a
s
e
s

l
e
a
k

t
e
s
t
e
d

(
m
o
n
t
h
l
y
)

E
m
p
t
y

C
G
C
s

l
a
b
e
l
e
d

e
m
p
t
y

a
n
d

s
e
g
r
e
g
a
t
e
d

f
r
o
m

C
G
C
s

c
o
n
t
a
i
n
i
n
g

p
r
o
d
u
c
t

C
G
C
s

w
e
l
l

v
e
n
t
i
l
a
t
e
d
,

n
o
t

b
l
o
c
k
i
n
g

e
x
i
t
s

o
r

n
e
a
r

a

h
e
a
t

s
o
u
r
c
e

(
>
1
2
5

F
)

O
b
s
e
r
v
a
t
i
o
n
s

/

c
o
r
r
e
c
t
i
v
e

a
c
t
i
o
n

(
l
i
s
t

f
u
l
l

d
e
t
a
i
l
s

o
n

b
a
c
k

o
f

f
o
r
m
)

Hazardous Materials: Storage Inspection Procedure and Form
Observations and Corrective Actions Log
Inspection Date
Inspector
Initials
Observation or Comment Corrective Action Required
Date Action
Completed

Hazardous Materials: Fume Hood Velocity Survey Form
1

Activity Log #__________________

Date: Surveyor:

Location:

PC Number/Unique Identifier:

Temperature:

Equipment Used:

Hood dimensions: Length Width Depth
Inches
Feet

Hood Face area (square feet):

Face air velocity measurements:

Average velocity:

Measure velocity range:

Comment:


Hazardous Materials: Fume Hood Survey Sticker
1

Approximate
dimension of both
portions of label =
7" H 3.25" W
FUME HOOD SURVEY

HOOD ID# ________________________

FACE VELOCITY ______________ FPM

NAME DATE RESULT

GOOD WORK PRACTICES FOR
FUME HOOD USE

Store chemicals and equipment outside of hood
Keep containers and equipment >6 from
front/back of hood

Provide space under large equipment for proper
air flow
Keep sash closed or at lowest possible usable
position

Do not conduct perchloric acid digestion in this
hood
Prevent release of chemicals into fume hood sink
Open chemical storage containers only when
dispensing
Perforate bottom
portion across width
at line. Approximate
dimension of bottom
portion =1.1" H
3.25" W

Avoid open container procedures when using
volatiles

Lower Sash to Here

For Adequate Protection


Hazardous Materials: Secondary Containment Decision
Flow Chart
1

Secondary containment is required for the storage of all regulated hazardous materials.

This flow chart illustrates the steps to take to make the determination. If containment is
required, follow the instructions in Hazardous Materials: Secondary Containment
Requirements.
2

Secondary Containment Decision Process
no
v. 07-10-2006
Start Start
Is it a Is it a
Haz Mat Haz Mat
? ?
No secondary No secondary
contai nment containment
needed needed
Container size Container size
Single Single
contai ner contai ner
> > 55 Gal ( 55 Gal (liq liq) or ) or
550 lb 550 lb
(solid) (solid)
Secondary Secondary
contai nment contai nment
needed needed
yes
Multiple Multiple
vessels vessels > >
1,000 gal ( 1,000 gal (liq liq) or ) or
10,000 lb 10,000 lb
(solid) (solid)
no
Any material if: Any material if:
Leak threatens Leak threatens
personnel or the personnel or the
environment (e.g., environment (e.g.,
contami nates soil contami nates soil
or water) or water)
* (e.g., emits toxic gas,
ignites, explodes, etc.)
Material which Material which
could produce could produce
an i ncompatible an i ncompatible
chemical reaction with chemical reaction with
other nearby other nearby
substances* substances*
Contain 110% of the vol. of the largest container. If multiple c Contain 110% of the vol. of the largest container. If multiple containers, must contain ontai ners, must contain
either 10% of the aggregate vol . or 150% of the largest contai ne either 10% of the aggregate vol . or 150% of the largest contai ner, whichever is greater. r, whichever is greater.
If i n an If i n an i nterior i nterior Haz Mat storage room, must also contai n 20 mi nutes of sprinkler Haz Mat storage room, must also contai n 20 mi nutes of sprinkler flow, flow,
at the design flow rate for that area, plus the vol ume of the ch at the design flow rate for that area, plus the vol ume of the chemical contai ner. emical contai ner.
If stored i n an exterior storage area and open to rainfall, must If stored i n an exterior storage area and open to rainfall, must contain the vol. of the contain the vol. of the
chemical contai ner pl us the vol ume of a 24 chemical contai ner pl us the volume of a 24- -hour rainfall as determined by a 25 hour rainfall as determined by a 25- -year year
storm and provisions shall be made to drain accumulations of the storm and provisions shall be made to drain accumulations of the rai nwater. rai nwater.
Life or Life or
Environmental Hazard Environmental Hazard
Reactivity Hazard Reactivity Hazard
yes
no
yes
no
no
no
yes

2 Hazardous Materials: Secondary Containment Requirements (SLAC-I-730-0A09S-020), http://www-
group.slac.stanford.edu/esh/eshmanual/references/hazmatReqSecondContain.pdf

Hazardous Materials: Secondary Containment
Requirements
1

2

To determine if secondary containment is needed in your case, see Hazardous Materials:
Secondary Containment Decision Flow Chart.
3

Containment Volume
Secondary containment for a single container (tank) will be 110 percent of the primary
container. Secondary containment for multiple containers will be 150 percent of the
largest containers volume or 10 percent of the aggregate volumes of all containers,
whichever is greater. All secondary containment systems open to rainfall must be able to
hold 4.5 inches of rainfall in addition to the required secondary containment volume. All
secondary containment systems open to fire sprinkler discharge must be able to hold the
discharge from all sprinkler heads over the secondary containment system for 20 minutes
in addition to the required secondary containment volume.
Containment Construction
Secondary containment must be constructed using materials capable of containing a spill
or leak for at least as long as the period between monitoring inspections.
Overfill Protection
A means of providing overfill protection for any primary container may be required. This
may be an overfill prevention device and/or an attention getting high level alarm.
Separation of Materials
Materials that in combination may cause a fire or explosion, or the production of a
flammable, toxic, or poisonous gas, or the deterioration of a primary or secondary
container will be separated in both the primary and secondary containment so as to avoid
intermixing.

2 These requirements are taken directly from the Unidocs Hazardous Materials Storage Secondary
Containment Guidelines (UN-083), http://www.unidocs.org/hazmat/aboveground/un-083.html
3 Hazardous Materials: Secondary Containment Decision Flow Chart (SLAC-I-730-0A09S-015),
http://www-group.slac.stanford.edu/esh/eshmanual/references/hazmatFlowSecondContain.pdf
Hazardous Materials: Secondary Containment
Requirements
1

2

To determine if secondary containment is needed in your case, see Hazardous Materials:
Secondary Containment Decision Flow Chart.
3

Containment Volume
Secondary containment for a single container (tank) will be 110 percent of the primary
container. Secondary containment for multiple containers will be 150 percent of the
largest containers volume or 10 percent of the aggregate volumes of all containers,
whichever is greater. All secondary containment systems open to rainfall must be able to
hold 4.5 inches of rainfall in addition to the required secondary containment volume. All
secondary containment systems open to fire sprinkler discharge must be able to hold the
discharge from all sprinkler heads over the secondary containment system for 20 minutes
in addition to the required secondary containment volume.
Containment Construction
Secondary containment must be constructed using materials capable of containing a spill
or leak for at least as long as the period between monitoring inspections.
Overfill Protection
A means of providing overfill protection for any primary container may be required. This
may be an overfill prevention device and/or an attention getting high level alarm.
Separation of Materials
Materials that in combination may cause a fire or explosion, or the production of a
flammable, toxic, or poisonous gas, or the deterioration of a primary or secondary
container will be separated in both the primary and secondary containment so as to avoid
intermixing.

2 These requirements are taken directly from the Unidocs Hazardous Materials Storage Secondary
Containment Guidelines (UN-083), http://www.unidocs.org/hazmat/aboveground/un-083.html
3 Hazardous Materials: Secondary Containment Decision Flow Chart (SLAC-I-730-0A09S-015),
http://www-group.slac.stanford.edu/esh/eshmanual/references/hazmatFlowSecondContain.pdf
Hazardous Materials: Secondary Containment Requirements
Containment Drainage
Uncontrolled drainage from a secondary containment system is not allowed.
Accumulated rainwater or sprinkler flow water may only be released from a secondary
containment system after it has been determined to be uncontaminated. The drainage
system must be kept closed or pumps turned off unless the drainage process is monitored.
Other Requirements and Suggestions
All storage areas must be secured to prevent access by unauthorized personnel.
Secondary containment systems may be covered to prevent rainfall from entering.
Constructed secondary containment systems, that is, poured pads with berms, must be
tested to ensure that they are leak tight.
Approved coatings must be applied to secondary containment surfaces when spills or
leaks would damage or penetrate the uncoated secondary containment system. Secondary
containment systems can be provided through the use of trays or drums placed in over-
pack drums as long as all provisions of the secondary containment requirements are met.

Hazardous Materials: On-site Transportation
Requirements
1

The following provides guidance on packaging, labeling, and securing hazardous
materials and waste for on-site transportation from one room to another, from one floor in
a building to another, or from one building to any other location at SLAC.
Package hazardous materials and waste in containers that are compatible.
Ensure that any cushioning or absorbent material used for packaging is also
compatible with the hazardous material or waste.
Use drums that are in good condition and free of rust and major dents.
Ensure that drums are not leaking or overfilled before transporting them.
Ensure that drum bungs are tight.
Carefully inspect pallets before they are loaded.
Do not use pallets with cracked or broken slats.
Use a drum dolly to place drums on pallets.
Secure all drums to the pallet with appropriate strapping material.
When packaging small containers of hazardous materials or waste for transportation,
use carrying cases, racks, or trays to keep the containers upright and to minimize
shifting during transport.
Do not place incompatible materials in the same tray or carrying case.
Protect and cushion glass containers to minimize the risk of breakage.
Only containers of chemicals in consumer packaging/quantities may be transported in
personal vehicles. On-site transportation of any other type/quantity of hazardous
material must be in a SLAC- or GSA-owned government vehicle. Off-site
transportation (that is, on public roads) may only be through a licensed hazardous
materials transporter.
Prior to transport, verify that all containers for hazardous materials and waste have
proper identification labels.
If a hazardous material or waste has been repackaged, label the new container with
the required information.
Containers for hazardous waste must be labeled with the following additional
information:
Date that the hazardous waste was placed in the container
The words HAZARDOUS WASTE
Name of the hazardous waste
Hazard class

Hazardous Materials: On-site Transportation Requirements
Name and extension of the person responsible for the contents of the container
Only hazardous waste containers provided by the Waste Management Group in the
ES&H Division may be used.
Verify that hazardous waste containers are labeled with the above information for
their contents before transporting.
Secure containers to prevent sliding or shifting during transport using cinch straps to
keep the containers upright.
If the containers shift during transport, stop immediately and re-secure the containers.
When transporting hazardous materials or waste on site, only SLAC-owned or GSA
government vehicles may be used, not personal vehicles.
Ensure that no incompatible materials are present when using passenger vehicles for
transport.
Never use mopeds or bicycles to transport hazardous materials or waste.
When transporting chemicals by foot:
All flammable and hazardous liquids (at normal temperature and pressure) and all
powdered or granular hazardous solids in glass containers should be transferred
through corridors and between buildings, using chemical carriers or secondary
containers.
Bottle carriers should be used for flammable liquids and corrosive chemicals in
glass bottles of two liters or more capacity, or plastic bags for smaller quantities.
Great care should be exercised even when transporting containers within
workspaces.
Hazardous Materials: Chemical Use Planning Guidelines
1

Before using a new chemical, personnel and supervisors should consider the following:
1. The chemicals or types of chemicals to be used, their hazards and exposure limits,
and their proposed storage and use locations. The material safety data sheet (MSDS)
is one tool to be used during this evaluation, as are the chemical-specific safe use
guidelines.
2

2. The building or area occupancy classification and the maximum chemical quantities
allowed to ensure exempt or maximum amounts are not exceeded. The following
occupancies are present at SLAC:
1. A: assembly areas such as cafeteria and auditorium
2. B: business areas, laboratories under exempt amounts, vocational shops
3. F: factories and industrial areas
4. S-1: moderate hazard storage and service garage
5. S-2: low hazard storage
6. H: laboratories and scientific areas not classified as B, and industrial areas not
classified as F due to quantity and hazard of material used or stored

Refer to the California Building Code and California Fire Code, or contact the fire
marshal for details on occupancy and storage.
3

3. Potential incompatibilities with other processes in the proposed work location
4. The possibility of substituting a less-hazardous substance

2 DOE MSDS Viewer, http://www.tcmis.com/tcmis/doe/msds
3 Title 24, California Code of Regulations, Part 9, California Fire Code, Chapters 27 through 41,
http://www.bsc.ca.gov/title_24/default.htm. Title 24, California Code of Regulations, California
Building Standards Code, is available only through depository libraries and the publishers of its
various components. See the SLAC Research Library Community Pages, http://www-
group.slac.stanford.edu/library/CommunityPages.asp, for available standards.
A hard copy of the 2007 California Building Code is available; see
A hard copy of the 2007 California Fire Code is available; see
4 J an 2007 (updated 30 Dec 2008) SLAC-I-730-0A09T-018-R001 1 of 2
Hazardous Materials: Chemical Use Planning Guidelines

5. The possibility of acquiring the chemical from a fellow researcher/user at SLAC
rather than placing a new order (material exchange)
6. The ability to incorporate pollution prevention practices to minimize toxicity and
quantity of all wastes and pollutants
7. The need to acquire any specialized equipment, such as new spill kits, early warning
devices, air monitoring equipment, or emergency respiratory equipment, or chemical-
specific antidotes
8. Any approval required by the work authorization process

Changes in planned consumption rates for any bulk purchased or other accelerator
runtime related chemicals should be communicated to the CMS vendor as soon as known,
so that Haas tcmIS may manage the supply chain more effectively.
4

4 Chemical Management Services (CMS), http://www-
group.slac.stanford.edu/esh/groups/cgs/hmaq/cms/
Hazardous Materials: Training Flow Chart
1

EOESH EOESH
Chemical Hygiene Chemical Hygiene
Beryllium Beryllium
Safety (296) Safety (296)
HazWopER HazWopER
8 Hr (285) 8 Hr (285)
DOT HMT & DOT HMT &
Security (259)# Security (259)#
IATA HMT (297)** IATA HMT (297)**
Lead Safety Lead Safety
(240) (240)
Personal Protective Personal Protective
Equipment (255) Equipment (255)
Pesticide Pesticide
Worker (402) Worker (402)
Respirator Respirator
Safety (241) Safety (241)
Stormwater Stormwater
Awareness (298)# Awareness (298)#
Chemical Chemical
Worker? Worker?
Lab Lab
(per (per
CHP) CHP)
Supervisor Supervisor
evaluates for Other evaluates for Other
ESH Training ESH Training
Haz waste Haz waste
Worker? Worker?
Respirator Respirator
needed needed
Beryllium Beryllium
worker worker
Lead Lead
worker worker
Pesticide Pesticide
worker worker
Haz Mat Haz Mat
Shipping Shipping
Exterior Exterior
Chem. Storage Chem. Storage
& use & use
Hazardous Materials Training Curriculum
yes no
yes
yes
yes
yes
Yes (CEF)
yes
yes
1
1
2
8
*One time initial instructor led class
with refresher to be WBT
#Recertification every three years
** Recertification every two years
Determined by EP
Asbestos Asbestos
worker worker
CEF
2
1.5
1.5
1
20 40 +
2*
16
n
=computer/eLearning
=Classroom/instructor
n
Solid line =annual
recertification (unless
otherwise noted)
Dashed line =one time
training
n =#of hours
Asbestos Asbestos
Worker 2 (150) Worker 2 (150)
4
other
Hazardous Hazardous
Materials Materials
Management (105)* Management (105)*
Asbestos Asbestos
Awareness (150) Awareness (150)
v. 08-2006
Haz Waste Haz Waste
Treatment (TBD) Treatment (TBD)
1
1
1
Haz Comm
Awareness (103)
1*


Hazardous Materials: Personal Protective Equipment
Requirements
1

The following are requirements for personal protective equipment (PPE) specific to
working with hazardous materials. For general PPE requirements, including procedures
for purchasing, see Chapter 19, Personal Protective Equipment.
2

Protective Apparel
Protective apparel includes coats, aprons, jump suits, special types of boots, shoe covers
and gauntlets. Appropriate protective apparel is recommended for most laboratory work,
while some tasks require its use. Laboratory apparel should protect against physical
hazards yet enable easy execution of physical tasks. In addition to the use of protective
apparel, follow the general precautions below regarding regular apparel in the work area:
Do not use or wear excessively loose or torn clothing.
Wear shoes at all times.
Do not wear perforated shoes, sandals, or cloth sneakers.
Eye and Face Protection
Eye and face protection is required in areas where chemicals used could cause injury to
the eyes or face upon contact from splashing or pouring. PPE for eye and face protection
must be selected in accordance with Title 29, Code of Federal Regulations, Section
1910.133, Eye and Face Protection (29 CFR 1910.133),
3
and must meet the
requirements specified in American National Standards Institute (ANSI) Z87.1-2003,
Practice for Occupational and Educational Eye and Face Protection.
4

Lab supervisors should contact the equipment manufacturers or the industrial hygiene
program manager for proper equipment selection. Follow the guidelines below to
determine when eye and face protection is required:

2 SLAC Environment, Safety, and Health Manual (SLAC-I-720-0A29Z-001), Chapter 19, Personal
Protective Equipment, http://www-group.slac.stanford.edu/esh/general/ppe/policies.htm
3 Title 29, Code of Federal Regulations, Section 1910.133, Eye and Face Protection (29 CFR
1910.133),
http://www.osha.gov/pls/oshaweb/owadisp.show_document?p_table=STANDARDS&p_id=9778
4 American National Standards Institute (ANSI) Z87.1-2003, Practice for Occupational/Educational
Eye and Face Protection. See the SLAC Research Library Community Pages, http://www-
group.slac.stanford.edu/library/CommunityPages.asp, for available standards. A hard copy is available;
see http://www.slac.stanford.edu/spires/find/books/www?key=327859.
Hazardous Materials: Personal Protective Equipment Requirements
Safety glasses with permanently attached side shields are required whenever there is a
potential for projectile objects in the work area. Safety goggles are required when
handling any chemical or process that can create fine dust, fumes, mists, and sprays.
Face shields are required to protect against the hazards identified above.
Do not use face shields as a substitute for eye protection. When both face and eye
protection is needed, both types of protective equipment must be used.
Eye and face protection is required when radiant energy sources are present in the
work area.

SLAC Stores can provide safety glasses, goggles, and face shields. Employees can
purchase prescription safety glasses through the SLAC contract vendor with the approval
of their supervisor. SLAC will cover the expense of the actual prescription eyeglasses,
but examinations and associated costs are the responsibility of the employee.
Hand Protection
Skin contact is a potential source of exposure to toxic materials. For substances that can
create a significant exposure to individuals through skin contact, see 29 CFR 1910.1000,
Table Z-1, Limits for Air Contaminants (see those marked with skin designation).
5

Appropriate gloves can be selected from safety supply catalogs. Personnel must follow
the guidelines below regarding glove use:
Gloves are required whenever there is potential for contact with corrosive or toxic
materials, or materials of unknown toxicity.
Select glove material based on chemical resistance, as not all gloves are equally
effective in preventing skin exposure to certain chemicals.
Know the time exposure limitations of glove use. Gloves eventually become
permeated by chemicals. However, gloves can be used safely for limited time periods
if you know specific use and glove characteristics (for example, glove thickness and
permeation rate).
Wash gloves after you completed a procedure but before removing them from your
hands.
Replace gloves periodically, depending on frequency of use and permeability of the
substances.
Ensure gloves are air tight, fill the gloves with air, roll the cuff, and check for leaks.

A good summary reference is Stanford Universitys Glove Selection for Laboratory
Workers.
6

5 Title 29, Code of Federal Regulations, Section 1910.1000, Air Contaminants, Table Z-1, Limits for
Air Contaminants (29 CFR 1910.1000 Table Z-1),
http://www.osha.gov/pls/oshaweb/owadisp.show_document?p_table=STANDARDS&p_id=9992
6 Glove Selection for Laboratory Workers,
http://www.stanford.edu/dept/EHS/prod/researchlab/lab/glove/index.html
Hazardous Materials: Personal Protective Equipment Requirements

Respiratory Protection
Respiratory protection prevents the inhalation of hazardous vapors or fumes into the
lungs. Chemical fume hoods will prevent most exposures. However, when procedures
cannot be performed in a fume hood or ventilation is not adequate to provide protection
against inhalation hazards, respiratory protection equipment is required. Consult Chapter
29, Respiratory Protection,
7
for SLAC policy regarding the creation and maintenance
of a respirator program.
Respirators may be used at SLAC only after medical evaluation, training, fit-testing, and
specific approval of the operation by an ES&H industrial hygienist. Respirators are the
last resort for control of exposures and are only to be used when engineering controls,
process modification, and other measures are not practical or have proved inadequate.

7 SLAC Environment, Safety, and Health Manual (SLAC-I-720-0A29Z-001), Chapter 29, Respiratory
Protection, http://www-group.slac.stanford.edu/esh/hazardous_substances/respirator/policies.htm

Hazardous Materials: Eyewash/Shower Inspection
Procedure
1

Emergency eyewash and safety showers are required in areas where personnel can come
into contact with hazardous materials that could harm eyes or skin. All eyewash and
shower stations must be inspected weekly and the results logged (see Hazardous
Materials: Eyewash/Shower Inspection Form).
2

Plumbed Eyewash Stations/Showers
Fed from the domestic water supply
1. Ensure eye wash/shower is clear of obstructions and easily visible from all directions
(adequate signage).
2. Flush weekly, and record the flushing on the tag attached to the station.
3. What to check when flushing:
Eyewash protection caps must be in place and in good condition.
The ON/OFF valves must be operational, activated by a single motion.
Water flow remains ON when the operator removes his/her hand.
Water flows freely and is directed at the proper angles to flush the eyes or body as
appropriate.
4. Run the eyewash/shower for five seconds. The running (or collected) water must be
clear:
If the water is clear, turn off water and sign the inspection tag.
If the water is cloudy, discolored, or contains sediment, start another five-second
flush; stop; and then continue flushing at five-second intervals until the water
flushes clear. Then initial the inspection tag.
5. Ensure the water used for flushing was captured in a suitable container (such as a
plumbed drain, bucket, or large rolling waste can). If any water was spilled on the
floor, dry the area before leaving to prevent a slipping hazard.
Note If a plumbed eyewash station does not run clear after repeated flushings, contact
your ES&H coordinator or building manager immediately.

2 Hazardous Materials: Eyewash/Shower Inspection Form (SLAC-I-730-0A09J-003), http://www-
group.slac.stanford.edu/esh/eshmanual/references/hazmatFormShowerInspect.pdf | .doc (Word)
4 J an 2007 (updated 30 Dec 2008) SLAC-I-730-0A09C-003-R001 1 of 2
Hazardous Materials: Eyewash/Shower Inspection Procedure
4 J an 2007 (updated 30 Dec 2008) SLAC-I-730-0A09C-003-R001 2 of 2

Self-contained Eyewash/Shower Station
1. All self-contained eyewash/shower stations must be filled with a Hydrosep
3
solution
mixed according to the manufacturers specifications.
2. Procedure for changing-out the flushing solution:
The Hydrosep solution must be completely changed out every six months (weekly
flushing is not required).
The inside of the tank must be flushed with fresh water prior to refilling with the
new Hydrosep solution so that the tank is free of residue.
A record showing the date of the last solution change-out, and initialed by the
responsible party, must be affixed to the exterior of the self-contained unit.
3. Ensure the solution was captured in a suitable container (such as a plumbed drain,
bucket, or large rolling waste can). If any solution was spilled on the floor, dry the
area before leaving to prevent a slipping hazard.

3 Hydrosep Ordering Information; Quantity =1 carton (of 4 bottles); Vendor =Lab Safety Supply; Part
No. =7B-10089 Phone =1-800-356-0783; Cost =$24.75 (list) for one carton;
Fax =1-800-543-9910
Hazardous Materials: Eyewash/Shower Inspection Form
1

Emergency eyewash and safety showers are required in areas where personnel can come
into contact with hazardous materials that could harm eyes or skin. All eyewash and
shower stations must be inspected weekly (see Hazardous Materials: Eyewash/Shower
Inspection Procedure).
2
Log inspections by marking the inspectors name and inspection
date on a tag (see below) attached to the equipment.
3

E Em me er r g ge en nc cy y E Ey ye ew wa as sh h/ /S Sh ho ow we er r
I In ns sp pe ec ct t i i o on n R Re ec co or r d d
If this device passes, indicate the date and the initials of the inspector. If the
device fails, remove it from service/red tag it and notify ES&H.
D DA AT TE E B BY Y D DA AT TE E B BY Y

D DO O N NO OT T R RE EM MO OV VE E T TH HI IS S T TA AG G

2 Hazardous Materials: Eyewash/Shower Inspection Procedure (SLAC-I-730-0A09C-003), http://www-
group.slac.stanford.edu/esh/eshmanual/references/hazmatProcedShowerInspect.pdf
3 Contact SLAC Stores for a printed version of this tag.

Hazardous Materials: Cryogenic Gas Safe Handling
Guideline
1

Chemical
Name/Class
Cryogenic gas

Synonyms
Cryogens, liquefied gas, cryogenic liquids
Reactivity and Physical Concerns
Cryogenic liquids are liquefied gases that are kept in their liquid state at very low
temperatures. Different cryogens become liquids under different conditions of
temperature and pressure, but all have two properties in common: they are extremely
cold, and small amounts of liquid can expand into very large volumes of gas. The vapors
and gases released from cryogenic liquids also remain very cold. They often condense
the moisture in air, creating a highly visible fog. Each cryogenic liquid has its own specific
properties but the most commonly used cryogenic liquids can be placed into one of three
groups: inert gases (e.g., helium, nitrogen), flammable gases (e.g., hydrogen) and
oxidizer (e.g., oxygen). Because of the temperature at which these liquefied gases exist,
they can cause other gases to fractionally condense from the atmosphere. For example,
liquid helium has a boiling point below that of oxygen (-183C), which could result in
oxygen being condensed out of air, which in some circumstances can pose a fire risk.
Without adequate venting or pressure-relief devices on the containers, enormous
pressures can build up. The pressure can cause an explosion called a boiling liquid
expanding vapor explosion.
Exposure Hazards
Routes of Exposure
Inhalation, ingestion, skin and/or eye contact
The primary health hazards associated with cryogenic liquids are extreme cold and
asphyxiation. Prolonged exposure of the skin or contact with cold surfaces can cause
frostbite, which may cause the skin to appear waxy and yellow. Eyes can be damaged by
short exposures that may not damage surrounding skin. Intense pain will occur when
frozen tissue thaws. Prolonged breathing of extremely cold air may damage the lungs.
Cold, heavy gas does not disperse readily and can accumulate near the floor, displacing
air, asphyxiation and death can occur. Due to the significant expansion ratio of these
materials (e.g., LN2 has a liquid-to-gas expansion ratio of 710 times), a small amount of
spilled cryogenic liquid can displace a large amount of air, especially in relatively small
rooms.
Chronic Exposure
NA

1 SLAC Environment, Safety, and Health Manual (SLAC-I-720-0A29Z-001), Chapter 40,
Hazardous Materials, http://www-
group.slac.stanford.edu/esh/hazardous_substances/haz_materials/policies.htm
Hazardous Materials: Cryogenic Gas Safe Handling Guideline
First Aid
First aid measures will vary based on the individual chemicals hazard properties. In
general, the following steps should be completed. Move victim to fresh air. Call 911.
Apply artificial respiration if victim is not breathing. Remove and isolate contaminated
clothing and shoes. Clothing frozen to the skin should be thawed before being removed.
In case of contact with liquefied gas, thaw frosted parts with lukewarm water. Keep victim
warm and quiet. Consult a physician immediately if exposures have occurred.
Exposure Limits
Exposure limits will vary based on individual chemical hazards, consult the manufacturers
MSDS for established exposure limits. The primary risk is from oxygen deficiency.
Exposure Controls
Local exhaust ventilation is required. In some cases, gas detection may be required.
Consult the individual chemical hazard properties to determine the proper engineering
controls. Bulk tanks shall be sited in appropriate locations outside of the building. Smaller
tanks and dewars should not be stored inside unless adequate ventilation and detection
are present to prevent the development of an undetected asphyxiation hazard.
Personnel working with the materials must receive detailed training on the hazards, safe
use, and emergency procedures.
Avoid contact with body parts. Always wear thermal protective clothing when handling
refrigerated/cryogenic liquids. Follow individual chemicals MSDS recommendations for
the appropriate PPE. In general, prevent skin/eye contact through the use of impervious
gloves, clothing, boots, apron, and eye goggles or full face shield. In the event of a
possible asphyxiation hazard, only self-contained breathing apparatus may be used for
entry.
Disposal
Contact the Haas representative or the hazardous materials program manager for the
return of empty, or damaged, cylinders or dewars to the supplier.
Medical Monitoring (if applicable)
NA
Emergency Response
In the event of a significant release that poses a threat to employees and/or the
environment, immediately evacuate the area and notify the emergency operator (911).
The Palo Alto Fire Department will respond. Then call Incident Notification (ext. 5555)
and notify your supervisor.
Standards/Regulations
OSHA: PEL: 29 CFR 1910.1000, Table Z-1; Respiratory Protection: 29 CFR
1910.134
EPA: Release: 40 CFR 355.40; Waste: 40 CFR 261.21-261.24
California Fire Code: Chapters 27 through 41
Other References
CCOSH, OSH Answers: Cryogenic Liquids and Their Hazards,
http://www.ccohs.ca/oshanswers/chemicals/cryogenic/cryogen1.html

Hazardous Materials: Crystalline Silica Safe Handling
Guideline
1

Chemical
Name/Class
Crystalline silica

Synonyms
Silica, silicon dioxide
Silica, or silicon dioxide, is a naturally occurring mineral and its physical structure may
exist in either crystal or amorphous forms. It is the crystal form of silica that poses the
greatest health hazard to workers. The crystal form of silica is also called crystalline
silica, and exists in several forms: quartz, cristobalite, tripoli, and tridymite. Quartz is the
most common form of crystalline silica found in nature and in industrial use. Because
crystalline silica is a major component of sand, granite, and other rock materials, it is
common in the work environment. Occupational exposure to silica occurs in abrasive
sand blasting, foundry work, stonecutting, rock drilling, quarry work, tunneling, and other
construction related jobs.
Inhalation of silica can lead to silicosis, a debilitating lung disease. Silicosis creates
inflammation and scar tissue formation in the lungs, reducing the bodys ability to extract
oxygen from the lungs. As the disease progresses, pulmonary and cardiac impairment
may occur to the point where oxygen must be supplied continuously to sustain life. Once
silicosis has developed there is no cure for the disease; however, silicosis is preventable
if one can reduce silica dust exposure.
Exposure Hazards
Likely Exposures at SLAC
Gravel and sand used in cement mixing often contains large amounts of crystalline silica.
During construction activities, fine crystalline silica dust could be generated and become
air borne, posing a hazard to workers and people in the vicinity.
At SLAC, silica dust exposure to employees mainly comes from construction-related
activities such as
Concrete structure drilling
Abrasive polishing using silica sand
Cement mixing
Silica sand blasting
Dry sweeping and other activities that generate a visible cloud of dust
Routes of Exposure
The primary route of exposure that is of concern is through inhalation.

Hazardous Materials: Crystalline Silica Safe Handling Guideline
Chronic Exposure
Chronic overexposure to silica dust results in the formation of fibrotic nodules and
scarring around the trapped silica particles. This condition of the lung is called silicosis. If
the nodules grow too large, breathing becomes difficult and death may result.
First Aid
As exposure to silica is a chronic exposure concern, there are no first aid requirements.
Exposure of dust to the eyes can cause irritation, and the eyes can be flushed with water
to clear them.
Exposure Limits
Refer to the OSHA Table Z-3, Mineral Dusts, 29 CFR 1910.1000, Table Z-3
Exposure Controls
Industrial hygiene assessments should be conducted to include silica dust monitoring,
hazard analysis and providing the results to exposed workers and their supervisors.
Results of these assessments should include
Recommendation of engineering and administrative controls to reduce silica dust
exposure
Recommendation of appropriate and suitable respirators and other PPE for the job
Offering hands-on practical training and quantitative fit tests for respirator use.
If feasible, recommending non-silica material for abrasive blasting operations.
Engineering controls may include: attaching a dust control system to power tools; using a
wet spray method if feasible to suppress dust during sand blasting, jack hammering or
other construction activities; and when feasible, using a local exhaust ventilation system
to remove dust from the work area.
Silica hazards and controls should be identified in pre-work hazard analysis forms prior to
performing construction related activities. This applies to any work project that involves
the job activities listed in the sections above. If the work includes airborne silica particles,
contact the ES&H industrial hygienist at Ext. 4105 for assistance in minimizing exposure.
Silica exposure may also be minimized by reducing exposure time.
Warning signs will be posted if an area is designated by ES&H as a high silica dust area.
Eye: safety glasses or safety goggles
Respiratory: half or full-face air-purifying respirators with the appropriate filters must be
used if concentrations are at or above the PEL
Disposal
NA
Baseline pulmonary function exams should be performed on all employees during
their voluntary initial employment physical examination.
Annual pulmonary function exams shall be performed on any employees whose silica
dust exposure exceeds the OSHA PEL as identified by an industrial hygienist. These
records must be maintained for 40 years.
Emergency Response
NA
Hazardous Materials: Crystalline Silica Safe Handling Guideline
OSHA: PEL: 29 CFR 1926. 55 and 29 CFR 1910.1000, Table Z-1; Respiratory
Protection: 29 CFR 1910.134
Other References
OSHA, Silica, Crystalline: Hazard Recognition,
http://www.osha.gov/SLTC/silicacrystalline/recognition.html
NIOSH, Silica, http://www.cdc.gov/niosh/topics/silica/default.html
NIOSH, Health Effects of Occupational Exposure to Respirable Crystalline Silica
(NIOSH 2002-129), http://www.cdc.gov/niosh/docs/2002-129/02-129a.html
NLM, TOXNET: Toxicology Data Network, http://toxnet.nlm.nih.gov/

Hazardous Materials: Ethane Safe Handling Guideline
1

Chemical
Name/Class
Ethane

Synonyms
Bimethyl, dimethyl, ethyl hydride, methylmethane
Incompatible with chlorine, dioxygenyl tetrafluoroborate, and oxidizing materials.
Extremely flammable. Will be easily ignited by heat, sparks or flames. Will form
explosive mixtures with air. Vapors from liquefied gas are initially heavier than air and
spread along ground. Vapors may travel to source of ignition and flash back. Containers
may explode when heated. DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS
LEAK CAN BE STOPPED.
Exposure Hazards
Routes of Exposure
Inhalation, skin contact
Ethane is considered to be physiologically and toxicologically inert. At high
concentrations, ethane acts primarily as a simple asphyxiant by displacing oxygen from
the blood and air. Oxygen deprivation and asphyxiation symptoms include headache,
dizziness, numbness of the extremities, sleepiness, mental confusion, poor judgment and
coordination, memory loss and may eventually lead to unconsciousness and death. Skin
contact with liquid ethane causes severe frostbite.
Chronic Exposure
NA
First Aid
If inhaled, move victim to fresh air. Call 911. Apply artificial respiration if victim is not
breathing. Administer oxygen if breathing is difficult. Remove and isolate contaminated
clothing and shoes. Clothing frozen to the skin should be thawed before being removed.
In case of contact with liquefied gas, thaw frosted parts with lukewarm water. Keep victim
warm and quiet.
Exposure Limits
ACGIH TLV: 1000 ppm (TWA)
Excursions in worker exposure levels may exceed three times the TLV-TWA for no more
than a total of 30 minutes during a work day, and under no circumstances should they
exceed 5 times the TLV-TWA, provided that the TLV-TWA is not exceeded.

Hazardous Materials: Ethane Safe Handling Guideline
Exposure Controls
Local exhaust ventilation or breathing protection is required. Secondary containment of
all storage and use is required.
J ob hazard analysis and mitigation (J HAM) and procedures should be developed for the
safe use and handling of ethane in all applications. ESH can provide information and
guidance. Depending upon quantities, certain regulatory permits and/or registrations may
be required. Personnel working with the materials must receive detailed training on the
hazards, safe use, and emergency procedures.
Prevent skin contact with liquid by the use of gloves, clothing, boots, apron, and eye
goggles or full face shield capable of protecting from extreme cold. If the airborne
exposure limit may be exceeded and engineering controls are not feasible, wear a
NIOSH-approved self-contained breathing apparatus.
Disposal
Contact the Waste Management Group for specific disposal requirements and
procedures.
NA
Emergency Response
Small spills can be cleaned up with appropriate spill response supplies by trained
employees who have this task authorized in their J HAM.
1910.134
Other References
ILO, International Chemical Safety Card: Ethane (ICSC 0266),
http://www.ilo.org/public/english/protection/safework/cis/products/icsc/dtasht/_icsc02/i
csc0266.htm
Hazardous Materials: Flammable and Combustible
Liquids Safe Handling Guideline
1

Chemical
Name/Class
Flammable and combustible liquids

Synonyms
Will vary depending upon specific chemicals
Liquids that pose a fire hazard are grouped as flammable and combustible according to
their flashpoints. Generally speaking, flammable liquids will ignite and burn easily at
normal working temperatures (i.e., flash points at or below 100F (38C). Combustible
liquids usually burn at temperatures that are above normal working temperatures (i.e.,
must be preheated in order to ignite). At normal room temperatures, flammable liquids
can give off enough vapor to form mixtures with air that present fire hazards. Spray mists
of flammable and combustible liquids in air may burn at any temperature if an ignition
source is present. The vapors from most flammable and combustible liquids are heavier
than air, these vapors can settle and collect in low areas and present a hazard of flash
back. Some flammable and combustible liquids are corrosive. Many undergo dangerous
chemical reactions if they contact incompatible chemicals such as oxidizing materials, or
if they are stored improperly.
Exposure Hazards
Routes of Exposure
The health hazards associated with flammable and combustible liquids will vary
depending upon the individual chemicals hazards, the manufacturers MSDS should be
consulted for each chemical in use. Generally the hazards presented may include the
following:
Inhalation of flammable liquids can cause irritation to the respiratory passages,
nausea, headaches, muscle weakness, drowsiness, loss of coordination,
disorientation, confusion, unconsciousness, and death.
Skin contact with flammable liquids can cause the skins oils to be removed,
resulting in irritated, cracked, dry skin, rashes, and dermatitis.
Eye contact with flammable liquids can cause burning, irritation, and eye damage.
Chronic Exposure
Chronic exposure hazards associated with flammable and combustible will vary greatly
and can range from damage to the lungs, liver, kidneys, heart and/or central nervous
system may occur, cancer and reproductive effects are also possible. Consult the
individual chemicals MSDS for specific chronic hazards.

Hazardous Materials: Flammable and Combustible Liquids Safe Handling Guideline
First Aid
First aid measures will vary based on the individual chemicals hazard properties. In
general the following steps can be followed for flammable and combustible liquids. If
inhaled or ingested remove person from the contaminated area if it is safe to do so. Get
medical attention and do not leave person unattended. If skin contact occurs remove
person from source of contamination. Remove clothing, jewelry, and shoes from the
affected areas. Flush the affected area with water for at least 15 minutes and obtain
medical attention. If eye contact occurs remove person from the source of
contamination. Flush the eyes with water for at least 15 minutes. Obtain medical
attention.
Exposure Limits
MSDS for established exposure limits.
Exposure Controls
Local exhaust ventilation or breathing protection is generally required. Depending upon
the level of flammability involved with specific chemicals, engineering control
requirements may increase. Consult the MSDS for hazardous properties and your local
jurisdictional authority for specific requirements. Secondary containment of all storage
and use is generally required if a exposure risk to employees or the environment is
present.
Administrative controls will vary based on individual chemical hazards. Personnel working
with the materials must receive detailed training on the hazards, safe use, and
emergency procedures.
Follow individual chemicals MSDS recommendations for the appropriate PPE. In
general, prevent skin/eye contact through the use of impervious gloves, clothing, boots,
apron, and eye goggles or full face shield. If the airborne oxygen concentrations are
elevated and engineering controls are not feasible wear a NIOSH-approved self-
contained breathing apparatus with full face-piece operated in the pressure demand or
other positive pressure mode
Disposal
In general, flammable and combustible liquids are disposed of as hazardous waste.
Regulatory requirements will vary depending on the individual chemical, contact the
Waste Management Group for specific disposal requirements and procedures.
Medical monitoring will vary depending on the individual chemical hazards. Consult the
MSDS or industrial hygiene program manager for the appropriate medical monitoring for
the chemical of concern.
Emergency Response
Hazardous Materials: Flammable and Combustible Liquids Safe Handling Guideline
1910.134
EPA: Release: 40 CFR 355.40, 302, 116.4; Waste: 40 CFR 261.21-261.24
Other References
CCOSH, OSH Answers: Flammable & Combustible Liquids Hazards,
http://www.ccohs.ca/oshanswers/chemicals/flammable/flam.html
Author unknown, Flammable Liquid Safety, http://www.webworldinc.com/wes-
con/flamable.htm

Hazardous Materials: Flammable Solids Safe Handling
Guideline
1

Chemical
Name/Class
Flammable solids

Synonyms
Will vary depending upon specific chemicals
Many flammable solids may react violently or explosively on contact with water and may
also be ignited with friction, heat, sparks or flame. Some of these materials will burn with
intense heat. Dusts or fumes may form explosive mixtures in air. Containers may explode
when heated. Materials may re-ignite after fire is extinguished. Fires may produce
irritating, corrosive and/or toxic gases. Some of these materials may also be pyrophoric
spontaneously reacting with oxygen in air to ignite.
For metallic flammable solids (e.g., phosphorus, sodium, lithium, magnesium) do not use
water, foam or carbon dioxide as a fire suppressant. Dousing metallic fires with water
may generate hydrogen gas, an extremely dangerous explosion hazard, particularly if fire
is in a confined environment. Additionally, fires involving flammable metals (lithium,
sodium, potassium etc.) or flammable metal compounds (butyllithium, diethylzinc etc.)
can be fueled by using water or carbon dioxide fire extinguishers. You must have a class
D extinguisher on hand if you are using these materials
Exposure Hazards
Routes of Exposure
Inhalation, ingestion, skin and eye contact
The health hazards associated with flammable solids will vary depending upon the
individual chemicals hazards, the manufacturers MSDS should be consulted for each
chemical in use. Many flammable solids are metals, oxides from metallic fires are a
severe health hazard, inhalation or contact with substance or decomposition products
may cause severe injury or death.
Chronic Exposure
Chronic exposure hazards associated with flammable solids will vary greatly. Consult the
individual chemicals MSDS for specific chronic hazards.
First Aid
First aid measures will vary greatly based on the individual chemicals hazard properties.
Consult the specific chemicals manufacturers MSDS and when necessary, a medical
professional for the appropriate first aid procedures.

Hazardous Materials: Flammable Solids Safe Handling Guideline
Exposure Limits
MSDS for established exposure limits.
Exposure Controls
Local exhaust ventilation or breathing protection is generally required. Depending upon
the level of flammability involved with specific chemicals, engineering control
requirements may increase (e.g., use of inert atmospheres, glove boxes, special
detection and/or extinguishing systems, etc.). Consult the MSDS for hazardous
properties and your local jurisdictional authority for specific requirements.
Administrative controls will vary based on individual chemical hazards. Personnel working
with the materials must receive detailed training on the hazards, safe use, and
emergency procedures.
Avoid breathing dusts, vapors or fumes. Follow individual chemicals MSDS
recommendations for the appropriate PPE. In general, prevent skin/eye contact through
the use of impervious gloves, clothing, boots, apron, and eye goggles or full face shield. If
the airborne concentrations are elevated and engineering controls are not feasible wear a
NIOSH-approved self-contained breathing apparatus with full face-piece operated in the
pressure demand or other positive pressure mode
Disposal
In general, flammable solids are regulated as hazardous waste. Regulatory requirements
will vary depending on the individual chemical. Contact the Waste Management Group
for specific disposal requirements and procedures.
Medical and exposure monitoring will vary depending on the individual chemical hazards.
Consult the MSDS or industrial hygiene program manager for the appropriate monitoring
for the chemical of concern.
Emergency Response
1910.134
Other References
Safety Emporium, The MSDS HyperGlossary: Flammable Solid,
http://www.ilpi.com/msds/ref/flammablesolid.html

Hazardous Materials: Sodium Hypochlorite Safe
Handling Guideline
1

Chemical
Name/Class
Sodium hypochlorite

Synonyms
Hypochlorite, hypochlorous acid, chlorinated water
Incompatible with strong acids, amines, ammonia, ammonium salts, reducing agents,
metals, aziridine, methanol, formic acid, phenylacetonitrile. When combined with an acid
or ammonia may produce chlorine and chloramine gas. Decomposition of sodium
hypochlorite takes place within a few seconds with the following salts: ammonium
acetate, ammonium carbonate, ammonium nitrate, ammonium oxalate, and ammonium
phosphate. Contact with metals may evolve flammable hydrogen gas. Containers may
explode when heated. Releases chlorine gas when heated above 35C. Anhydrous
sodium hypochlorite is very explosive. Hypochlorites react with urea to form nitrogen
trichloride, which explodes. Explosive reaction with formic acid (at 55C),
phenylacetonitrile. Reacts to form explosive products with amines, ammonium salts,
aziridine, and methanol.
Exposure Hazards
Routes of Exposure
Sodium hypochlorite has a pronounced irritant effect and may cause severe burns to skin
and eyes. Poisonous vapor (chlorine gas) is corrosive to respiratory passages and may
cause irritation of mouth, nose and throat. If ingested sodium hypochlorite is poisonous,
causes burns, abdominal cramps, nausea, vomiting, lowered blood pressure, diarrhea,
shock, coma, shock, and death may occur.
Chronic Exposure
Repeated or prolonged contact with skin may cause dermatitis, coughing, runny nose,
bronchopneumonia, headaches, breathing difficulty, pulmonary edema and lung injury.
Caustic dusts are irritating to the upper respiratory system; prolonged exposure to high
concentrations may cause discomfort and ulceration of nasal passages.
First Aid
If inhaled or ingested, move victim to fresh air. Call 911. Apply artificial respiration if
victim is not breathing. Do not use mouth-to-mouth method if victim ingested or
inhaled the substance; induce artificial respiration with the aid of a pocket mask
equipped with a one-way valve or other proper respiratory medical device. Administer

Hazardous Materials: Sodium Hypochlorite Safe Handling Guideline
oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In
case of skin contact with substance, immediately flush skin or eyes with running water
for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected
skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion or skin
contact) to substance may be delayed.
Exposure Limits
Permissible exposure limit: not established
NIOSH recommended exposure limit: not established
Immediately dangerous to life and health: not established
Exposure Controls
safe use and handling of sodium hypochlorite in all applications. ESH can provide
information and guidance. Depending upon quantities, certain regulatory permits and/or
registrations may be required. Personnel working with the materials must receive detailed
training on the hazards, safe use, and emergency procedures
Avoid bodily contact with the material. Contact lenses should not be worn while
working with this substance. Prevent skin/eye contact through the use of impervious
gloves, clothing, boots, apron, and eye goggles or full face shield. Avoid breathing
vapors. If the airborne exposure limit may be exceeded and engineering controls are not
feasible, wear a NIOSH-approved self-contained breathing apparatus with full face-piece
operated in the pressure demand or other positive pressure mode.
Disposal
Material is regulated as a RCRA hazardous waste. Contact the Waste Management
Group for specific disposal requirements and procedures. Containers and other materials
that are contaminated must also be treated as hazardous waste.
NA
Emergency Response
1910.134
EPA: Release: 40 CFR 355.40, 302, 116.4; Waste: 40 CFR 261.21261.24
Other References
Hazardous Materials: Sodium Hypochlorite Safe Handling Guideline
NIOSH, International Chemical Safety Card: Sodium Hypochlorite (Solution, Active
Chlorine >10%) (ICSC 1119), http://www.cdc.gov/niosh/ipcsneng/neng1119.html
NIOSH, International Chemical Safety Card: Sodium Hypochlorite (Solution, Active
Chlorine <10%) (ICSC 0482), http://www.cdc.gov/niosh/ipcsneng/neng0482.html

Hazardous Materials: Sodium Hydroxide Safe Handling
Guideline
1

Chemical
Name/Class
Sodium hydroxide

Synonyms
Caustic soda, lye, soda lye, sodium hydrate
Incompatible with water, acids, flammable liquids, organic halogens, metals such as
aluminum, tin and zinc, and nitromethane. The substance is a strong base; it reacts
violently with acid and is corrosive in moist air to metals like zinc, aluminum, tin and lead
forming combustible/explosive hydrogen gas. Reacts with ammonium salts to produce
ammonia, causing fire hazard. Attacks some forms of plastics, rubber or coatings.
Rapidly absorbs carbon dioxide and water from air. Contact with moisture or water may
generate sufficient heat to ignite combustible substances.
Exposure Hazards
Routes of Exposure
Sodium hydroxide causes severe irritation to eyes, skin, mucous membrane;
pneumonitis; eye, skin burns; temporary loss of hair. The substance is very corrosive to
the eyes, the skin and the respiratory tract. Corrosive on ingestion. Inhalation of an
aerosol of the substance may cause lung edema. Inhalation may result in a burning
sensation, sore throat, cough, labored breathing, shortness of breath. Symptoms may be
delayed. Skin contact may result in redness, pain, serious skin burns, blisters. Eyes
contact may result in redness, pain, blurred vision, severe deep burns. Ingestion may
result in a burning sensation, abdominal pain, shock or collapse.
Chronic Exposure
Repeated or prolonged contact with skin may cause dermatitis. Caustic dusts are
irritating to the upper respiratory system. Prolonged exposure to high concentrations may
cause discomfort and ulceration of nasal passages.
First Aid
If inhaled, move victim to fresh air, rest and maintain a half-upright position. Use artificial
respiration if necessary. Immediately seek medical attention. If skin contact occurs,
remove contaminated clothes, rinse skin with plenty of cold water or shower. Seek
medical attention. If eye contact occurs, first rinse with plenty of cold water for several
minutes, then immediately seek medical attention. If ingested, rinse mouth. Do not
induce vomiting. Give plenty of water to drink. Immediately seek medical attention.

Hazardous Materials: Sodium Hydroxide Safe Handling Guideline
Exposure Limits
Permissible exposure limit: 2 mg/m
3
(OSHA TWA)
NIOSH recommended exposure limit: 2 mg/m
3
(C)
Immediately dangerous to life and health: 10 ppm
Exposure Controls
Prevent generation of dusts. Avoid all contact. Local exhaust ventilation or breathing
protection is required. Secondary containment of all storage and use is required if an
exposure risk to employees or the environment is present.
safe use and handling of sodium hydroxide in all applications. ESH can provide
training on the hazards, safe use, and emergency procedures.
Prevent skin/eye contact through the use of impervious gloves, clothing, boots, apron,
and eye goggles or full face shield. If the airborne exposure limit may be exceeded and
engineering controls are not feasible, wear appropriate respiratory protection.
Disposal
that are contaminated with sodium hydroxide must also be treated as hazardous waste.
The skin, eyes, and respiratory tract should receive special attention in any placement or
periodic examination. NIOSH recommends that workers subject to sodium hydroxide
exposure have comprehensive pre-placement medical examinations. Medical
examinations should be made available promptly to all workers with signs or symptoms of
skin, eye, or upper respiratory tract irritation resulting from exposure to sodium hydroxide.
Emergency Response
1910.134
EPA: Release: 40 CFR 355.40, 302, 116.4; Waste: 40 CFR 261.21261.24
Other References
NIOSH, NIOSH Pocket Guide to Chemical Hazards (NIOSH 2005-151), Sodium
Hydroxide, http://www.cdc.gov/niosh/npg/npgd0565.html
Hazardous Materials: Sodium Hydroxide Safe Handling Guideline
NIOSH, International Chemical Safety Card: Sodium Hydroxide (ICSC 0360),
http://www.cdc.gov/niosh/ipcsneng/neng0360.html

Hazardous Materials: Potassium Cyanide Safe Handling
Guideline
1

Chemical
Name/Class
Potassium cyanide

Synonyms
Potassium salt of hydrocyanic acid
Incompatible with acids; reaction will produce highly toxic hydrogen cyanide gas.
Moisture may also release cyanide gas. In addition to toxicity, hydrogen cyanide is also
flammable. Potassium cyanide itself is not flammable but may explode if heated above
450 C with chlorates or nitrites. In case of a fire in the presence of cyanides, do not use
carbon dioxide extinguishing agents. Reaction between cyanides, carbon dioxide and
water (moisture) can liberate hydrogen cyanide. Use dry chemical extinguishers or
copious amounts of water.
Exposure Hazards
Routes of Exposure
May be fatal if swallowed, inhaled, or absorbed through skin. Contact with acids liberates
poisonous hydrogen cyanide gas. Contact with mucous membranes or concentrated
solutions may cause burns to skin, eyes, and respiratory tract. Affects blood,
cardiovascular system, central nervous system, and thyroid.
Exposure may cause headache, weakness, dizziness, labored breathing nausea and
vomiting, which can be followed by weak and irregular heart beat, unconsciousness,
convulsions, coma and death. Ingestion may result in bitter almond odor that may noted
on the breath or vomitus.
Chronic Exposure
Prolonged or repeated skin exposure may cause a rash and nasal sores.
First Aid
In case of cyanide poisoning, remove victim to a safe area and start first aid treatment
immediately, then get medical attention. Trained emergency response personnel should
administer a cyanide antidote kit (amyl nitrite, sodium nitrite and sodium thiosulfate).
Actions to be taken in case of cyanide poisoning should be planned and practiced before
beginning work with cyanides. Oxygen and amyl nitrite can be given by a first responder
before medical help arrives. Allow victim to inhale amyl nitrite for 15-30 seconds per
minute until sodium nitrite and sodium thiosulfate can be administered intravenously. A

Hazardous Materials: Potassium Cyanide Safe Handling Guideline
new amyl nitrite ampoule should be used every 3 minutes. If conscious but symptoms
(nausea, difficult breathing, dizziness, etc.) are evident, give oxygen. If consciousness is
impaired (non-responsiveness, slurred speech, confusion, drowsiness) or the patient is
unconscious but breathing, give oxygen and amyl nitrite by means of a respirator. If not
breathing, give oxygen and amyl nitrite immediately by means of a positive pressure
respirator (artificial respiration).
In case of skin contact, immediately flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Get medical attention
immediately. Contaminated articles of clothing should be treated as hazardous waste.
Exposure Limits
3
(OSHA TWA)
3
(NIOSH ceiling limit)
Immediately dangerous to life and health: 25 mg/m
3
(as CN)
Exposure Controls
Local exhaust ventilation is required. Secondary containment of all storage and use is
required if an exposure risk to employees or the environment is present.
J ob hazard analysis and mitigation (J HAM), area hazard analyses (AHA), and
procedures must be developed for all cyanide use applications and should be reviewed
and approved by ESH. Depending upon quantities, certain regulatory permits and/or
Prevent skin/eye contact through the use of impervious gloves, clothing, boots, apron,
and eye goggles or full face shield.
If the airborne exposure limit may be exceeded and engineering controls are not feasible,
wear a supplied air, full-face piece respirator, supplied airline respirator, or self-contained
breathing apparatus (SCBA) This substance has poor warning properties.
Disposal
that are contaminated with cyanides must also be treated as hazardous waste.
Workers using cyanide may need pre-placement and annual medical exams.
Emergency Response
1910.134
EPA: Release: 40 CFR 355.40; Waste: 40 CFR 261.21261.24
Hazardous Materials: Potassium Cyanide Safe Handling Guideline
Other References
EPA, Technology Transfer Network Air Toxics Website, Cyanide Compounds,
http://www.epa.gov/ttn/atw/hlthef/cyanide.html
NIOSH, International Chemical Safety Card: Potassium Cyanide (ICSC 0671),
NIOSH, NIOSH Pocket Guide to Chemical Hazards (NIOSH 2005-151), Potassium
Cyanide, http://www.cdc.gov/niosh/npg/npgd0522.html

Hazardous Materials: Organic Peroxides Safe Handling
Guideline
1

Chemical
Name/Class
Organic peroxides

Synonyms
None, will vary based on individual chemicals
Organic peroxides can be explosive, corrosive, and toxic and present extreme fire
hazards. They are also strong oxidizing agents and combustible materials contaminated
with most organic peroxides can catch fire very easily and burn very intensely. Many
organic peroxides give off flammable vapors when decomposing. Because they combine
both fuel (carbon) and oxygen in the same compound, some organic peroxides are
dangerously reactive. They can decompose very rapidly or explosively if they are
exposed to only slight heat, friction, mechanical shock, or contamination with
incompatible materials.
Storage of some chemicals can form explosive organic peroxides spontaneously.
Generally the types of chemicals that may form peroxides include aldehydes, ethers and
unsaturated hydrocarbon compounds (allyl compounds, haloalkenes, dienes, monomeric
vinyl compounds, vinylacetylenes, and unsaturated cyclic hydrocarbons like
tetrahydronapthalene and dicyclopentadiene). If crystals are seen in containers, do not
handle - these peroxides can be extremely shock sensitive and explosion is possible.
Exposure Hazards
Routes of Exposure
Many organic peroxides are toxic and can produce allergic response and eye damage.
Individual chemical health hazards may vary greatly and it is very important that users
consult the manufacturers MSDS to familiarize themselves with potential health hazards.
Chronic Exposure
Chronic exposures to organic peroxides will vary greatly and can range from liver and
kidney damage to respiratory illnesses such as pneumonia. Consult the individual
chemicals MSDS for specific chronic hazards.
First Aid
First aid measures will vary based on the individual chemicals hazard properties. In all
cases, always remove any contaminated clothing due to the fire hazard present. Consult
a physician immediately if exposures have occurred.

Hazardous Materials: Organic Peroxides Safe Handling Guideline
Exposure Limits
Exposure limits will vary based on individual chemical hazards, consult the
manufacturers MSDS for established exposure limits.
Exposure Controls
Local exhaust ventilation or breathing protection is required. Explosion proof electrical
equipment and construction materials compatible with organic peroxides are required.
Ensure all incompatible exhaust streams are segregated. Store all materials in
appropriate containers. Secondary containment of all storage and use is required.
Organic peroxides should be stored in sealed, air-impermeable containers. In most
cases, dark amber glass with a tight fitting cap is acceptable. Do not store organic
peroxides in containers with loose fitting caps or ground-glass stoppers. Plastic
containers are not recommended. Diethyl ether should be stored in steel containers,
because the iron tends to neutralize peroxides.
safe use and handling of organic peroxides in all applications. ESH can provide
information and guidance. Ensure J HAMs and procedures comply with all
manufacturers recommendations regarding storage conditions and time limits/chemical
expiration dates. Personnel working with the materials must receive detailed training on
the hazards, safe use, and emergency procedures.
Establish a regular inventory check to remove older chemicals from inventory, label new
chemicals, and ensure each chemical is properly stored. Information on each label
should include: date received, date opened, responsible person, and expiration date. If
no expiration date is provided by the manufacturer, it should be recorded as six (6)
months from the date received.
Avoid all contact with substances. Follow individual chemicals MSDS
recommendations for the appropriate PPE. In general, prevent skin/eye contact through
the use of impervious gloves, clothing, boots, apron, and eye goggles or full face shield.
Avoid breathing dusts, mists or vapors. If the airborne concentration limits are
exceeded and engineering controls are not feasible wear a NIOSH-approved self-
contained breathing apparatus with full face-piece operated in the pressure demand or
other positive pressure mode.
Disposal
Organic peroxides are generally regulated as hazardous waste. Containers and other
materials that are contaminated with organic peroxides must also be treated as
hazardous waste and handled in a safe manner due to the unusual stability issues
related to organic peroxides. Contact the Waste Management Group for specific disposal
requirements and procedures.
Medical monitoring will vary depending on the individual chemical hazards. Consult the
MSDS or an Industrial Hygienist for the appropriate medical monitoring for the chemical
of concern.
Emergency Response
In the event of a release that poses a threat to employees and/or the environment,
immediately evacuate the area and notify the emergency operator (911). The Palo Alto
Hazardous Materials: Organic Peroxides Safe Handling Guideline
Fire Department will respond. Then call Incident Notification (ext. 5555) and notify your
supervisor.
1910.134
Other References
CCOHS, OSH Answers: How Do I Work Safely with Organic Peroxides?,
http://www.ccohs.ca/oshanswers/prevention/orgperox.html
UC Berkeley, Office of Environment, Health & Safety, Guidelines for Explosive and
Potentially Explosive Chemicals Safe Storage and Handling,
http://www.ehs.berkeley.edu/pubs/guidelines/pecguidelines.html

Hazardous Materials: Oxygen Safe Handling Guideline
1

Chemical
Name/Class
Oxygen

Synonyms
Pure oxygen, liquid oxygen, LOX, molecular oxygen
Substance does not burn but intensely supports combustion, may react explosively with
fuels. Oxygen may ignite combustibles (wood, paper, oil, clothing, etc.). Vapors from
liquefied gas are initially heavier than air and spread along ground. Runoff may create fire
or explosion hazard (liquefied oxygen will react with asphalt). Containers may explode
when heated. Ruptured cylinders may rocket. Incompatible with certain metal (e.g.,
reaction with aluminum powder will produce an explosion). Oxygen is a strong oxidizer
and corrosive to metals.
Exposure Hazards
Routes of Exposure
Inhalation and skin contact
Vapors may cause dizziness or asphyxiation without warning. Inhalation of 100% oxygen
can result in fever, nausea, vomiting, dizziness, tracheal and pulmonary irritation leading
to pulmonary edema and pneumonitis. Intense and potentially fatal pulmonary edema
may develop. Acute bronchitis developing several hours later, sinusitis, malaise, transient
paresthesias and conjunctivitis may occur. Skin contact with gas or liquefied gas may
cause burns, severe injury and/or frostbite. Eye splashes with liquid oxygen may result in
burns, severe injury, and/or frostbite.
Chronic Exposure
None
First Aid
Move victim to fresh air. Call 911. Apply artificial respiration if victim is not breathing.
Remove and isolate contaminated clothing and shoes. Clothing frozen to the skin should
be thawed before being removed. In case of contact with liquefied gas, thaw frosted parts
with lukewarm water. Keep victim warm and quiet. Seek medical attention immediately.
Exposure Limits
No exposure limits set by NIOSH or OSHA

Hazardous Materials: Oxygen Safe Handling Guideline
Exposure Controls
Bulk oxygen supply location must be outside buildings. Gas should be piped to the
laboratory at the lowest usable pressure. Store extra oxygen cylinders in well ventilated
outdoor locations away from flammable and combustible materials. Oxygen cylinders
must be stored at least 20 feet from all flammable gases or be separated by a
noncombustible, fire-resistant barrier with at least a half-hour rating. Permanently
installed containers shall have substantial noncombustible supports on firm
noncombustible foundations. All fittings for oxygen service must be oil and grease free to
prevent fire or explosion.
safe use and handling of oxygen in all applications. ESH can provide information and
guidance. Personnel working with the materials must receive detailed training on the
Safety glasses or goggles are recommended when handling compressed gas cylinders.
Thermal protective gloves should be worn when handling refrigerated/cryogenic liquids.
Disposal
Contact the Haas representative or the hazardous materials program manager for the
return of empty, or damaged, cylinders or dewars to the supplier.
NA
Emergency Response
Remove ignition sources. Do not touch spilled material. Stop leak if possible without
personal risk and if task is authorized in your J HAM. Evacuate area. Ventilate closed
spaces before entering.
In the event of an exposure or significant release that poses a threat to employees and/or
the environment, immediately evacuate the area and notify the emergency operator
(911). The Palo Alto Fire Department will respond. Then call Incident Notification (ext.
5555) and notify your supervisor.
1910.134
Other References
Matheson Tri-Gas, Safe Handling of Compressed Gases in the Laboratory and the
Plant, http://www.mathesontrigas.com/litcenter/
NFPA 51, Standard for the Design and Installation of Oxygen-Fuel Gas Systems for
Welding, Cutting, and Allied Process, http://www.nfpa.org/codesonline/ (SLAC login)
NFPA 55, Standard for the Storage, Use, and Handling of Compressed Gases and
Cryogenic Fluids in Portable and Stationary Containers, Cylinders, and Tanks,
http://www.nfpa.org/codesonline/ (SLAC login)
Hazardous Materials: Nitric Acid Safe Handling
Guideline
1

Chemical
Name/Class
Nitric acid

Synonyms
Aqua fortis, engravers acid, hydrogen nitrate, red fuming nitric acid (RFNA), white fuming
nitric acid (WFNA)
Incompatible with many organic materials, combustible materials, metallic powders,
hydrogen sulfide, carbides, alcohols, reacts with water to produce heat, corrosive to
metals. May generate hydrogen gas on contact with certain metals (e.g., aluminum). Not
combustible but enhances combustion of other substances. May give off poisonous
oxides of nitrogen & acid fumes when heated in fires. The substance decomposes on
warming producing nitrogen oxides. The substance is a strong oxidant and reacts
violently with combustible and reducing materials, e.g., turpentine, charcoal, alcohol. The
substance is a strong acid, it reacts violently with bases. Reacts very violently with
organic chemicals (e.g., acetone, acetic acid, acetic anhydride), causing fire and
explosion hazard. Attacks some plastics. Reacts explosively with metallic powders,
carbides, cyanides, sulfides, alkalies, and turpentine.
Exposure Hazards
Routes of Exposure
Inhalation may result in a burning sensation, cough, labored breathing, chemical
pneumonia, unconsciousness, and death. Symptoms may be delayed. Skin contact may
result in serious skin burns, pain, and yellow discoloration. Eye contact may result in
redness, pain, and severe deep burns. Ingestion may result in abdominal pain, burning
sensation and shock.
Chronic Exposure
Long-term exposure to concentrated vapors may cause erosion of teeth and lung
damage. Long-term exposures seldom occur due to the corrosive properties of the acid.
First Aid
If exposed through inhalation, bring victim out into fresh air, keep in a half-upright
position, do not allow to lay flat (fluid may accumulate in lungs), provide oxygen if
needed. Artificial respiration may be needed. Provide immediate medical attention. If
skin contact occurs, remove contaminated clothes. Flush skin with (cool or tepid) water
or shower for 15 minutes. Provide medical attention. If eye contact occurs, flush with
cool or tepid water for at least 15 minutes (remove contact lenses if easily possible).

Hazardous Materials: Nitric Acid Safe Handling Guideline
Provide medical attention. If ingested, do not induce vomiting. Give plenty of water to
drink. Rest. Provide immediate medical attention.
Exposure Limits
3
; 2 ppm (OSHA TWA)
3
; 2 ppm (TWA)
Exposure Controls
all storage and use is required if an exposure risk to employees or the environment is
present.
safe use and handling of nitric acid in all applications. ESH can provide information and
Avoid all contact with substance. Prevent skin/eye contact through the use of
impervious gloves, clothing, boots, apron, eye goggles and full face shield. If the airborne
exposure limit may be exceeded and engineering controls are not feasible, wear
appropriate respiratory protection.
Disposal
Material is disposed of as a RCRA hazardous waste. Contact the Waste Management
that are contaminated with nitric acid must also be treated as hazardous waste.
NIOSH recommends that workers subject to chronic nitric acid exposure have
comprehensive pre-placement and annual medical examinations including a 14X17
posterior-anterior chest x-ray, pulmonary function tests, and a visual examination of the
teeth for evidence of dental erosion.
Emergency Response
1910.134
Other References
Hazardous Materials: Nitric Acid Safe Handling Guideline
NIOSH, NIOSH Pocket Guide to Chemical Hazards (NIOSH 2005-151), Nitric Acid,
http://www.cdc.gov/niosh/npg/npgd0447.html
NIOSH, International Chemical Safety Card: Nitric Acid (ICSC 0183),

Hazardous Materials: Mercury and Mercury Compounds
Safe Handling Guideline
1

Chemical
Name/Class
Mercury and mercury compounds

Synonyms
Mercury metal, colloidal mercury, metallic mercury, quicksilver
Mercury is a silver liquid metal that vaporizes at temperatures as low as 10 F. Mercury
vapor is colorless and odorless. If a mercury spill is not cleaned up promptly it may be
ground into the floor, dispersing into extremely small particles with a large total surface
area (6.4 ft
2
for 1 ml as 10 micron spheres). From such large areas mercury may
vaporize at a rate faster than the rooms ventilation can safely dilute it. The rate of
mercury volatilization is directly related to temperature. A common occurrence is the
breaking of thermometers in ovens due to bumping or raising the oven above the
thermometers capacity. Additionally, the impact of mercury at high velocities or its
release into high air velocity systems will also atomize mercury into extremely small
particle sizes and large surface area.
Elemental mercury is incompatible with acetylene, aluminum, ammonia, azides, calcium,
chlorates, chlorine dioxide, copper, copper alloys, ethylene oxide, halogens, iron, metal
oxides, nitrates, oxygen, lithium, lead, nitromethane, rubidium, sodium carbide, sulfur,
sulfuric acid, and others.
Exposure Hazards
Routes of Exposure
A pool of mercury exposed to the air can produce airborne concentrations greater than
the permissible exposure limit of 0.05 mg/m
3
. Organo-alkyl mercury compounds are
highly toxic and can be fatal on contact with skin (e.g., a Dartmouth chemistry professor
died in 1997 from an exposure to dimethylmercury that penetrated through a latex glove).
Elemental mercury can remain on the skin for many hours creating the potential for
ingestion.
Chronic Exposure
Chronic poisoning can be caused by long-term exposure to low levels of mercury. Steady
exposure can cause a slow buildup of mercury in the body that produces illness,
personality changes, and eventual disability. Symptoms of chronic poisoning include
tremors, mental disturbances such as insomnia, irritability and indecision, headache,

Hazardous Materials: Mercury and Mercury Compounds Safe Handling Guideline
fatigue, muscular weakness, stomach ache, excessive salivation, digestive disturbances,
anorexia, weight loss, inability to absorb protein, and eye and skin irritation.
First Aid
Immediately seek emergency medical attention.
Eye contact: irrigate immediately
Skin contact: wash promptly with soap
Breathing: oxygen administration and respiratory support
Ingestion: medical attention immediately
Exposure Limits
Metallic Mercury Vapor
NIOSH REL: TWA 0.05 mg/m
3
(skin)
Other: C 0.1 mg/m
3
(skin)
OSHA PEL: C 0.1 mg/m
3

IDLH: 10 mg/m
3
(as Hg)
Organo-alkyl Mercury Compounds
NIOSH REL: TWA 0.01 mg/m
3
, ST 0.03 mg/m
3
(skin)
OSHA PEL: TWA 0.01 mg/m
3
C 0.04 mg/m
3

IDLH: 2 mg/m
3
(as Hg)
Exposure Controls
The use of mercury is restricted. Use an alternative if one is available. For example: use
alcohol thermometers instead of mercury ones; oil bubblers instead of mercury bubblers
when possible; reducing agents other than mercury amalgams; etc. Avoid using mercury
thermometers in ovens if it breaks, this will be a significant hazmat clean up situation.
When handling mercury use a glass, plastic, or steel tray to contain any spills that might
occur. Glass or plastic vessels should have a secondary steel or plastic container around
them in case the vessel fails.
Managers and supervisors must notify ES&H before beginning new processes involving
mercury or mercury compounds. Plastic containers should be used to store mercury
whenever possible. Label all equipment and vessels containing mercury. Close all
containers of mercury when not in use. Store mercury in a secured area. Maintain a
written inventory of mercury usage, location, and amounts.
Skin. Elemental mercury require nitrile, PVC, or latex gloves. Organo-alkyl mercury
compounds require the use of silver shield, 4H, or other brand laminate-style gloves and
outer gloves (heavy-duty nitrile or neoprene, with long cuffs).
Eye. Safety glasses or safety goggles.
Respiratory. Elemental mercury vapor: concentrations up to 0.5 mg/m
3
, a half-face air
purifying respirator with a cartridge that provides protection for mercury vapor can be
used. For concentrations between 0.5 and 2.5 mg/m
3
a full face cartridge respirator may
be used. Above that a self-contained breathing apparatus is required. Organo-alkyl
mercury vapor: due to the high toxicity of organo-alkyl mercury compounds, a self-
contained breathing apparatus is required if concentrations are in excess of the PEL.
Disposal
Dispose of mercury as hazardous waste. Do not combine it with regular organic or
inorganic wastes. Never dispose of it down the sink.
Hazardous Materials: Mercury and Mercury Compounds Safe Handling Guideline
Contact the Waste Management Group for specific disposal requirements and
procedures.
Medical Services will determine the need for biological monitoring or medical surveillance
examinations of workers with potential mercury exposure based on an evaluation of the
operation and workplace controls, as well as input received from ES&H.
Emergency Response
In the event of a release, immediately evacuate the area:
Do not attempt to clean up spilled mercury.
Immediately notify ES&H and Waste Management (extension 2399).
Evacuate the area and prevent reentry.
If after business hours or if there has been an exposure call (911). The Palo Alto Fire
Department will respond. Then call Incident Notification (ext. 5555) and notify your
supervisor.
1910.134
Other References
NIOSH, International Chemical Safety Card: Mercury (ICSC 0056),
Lawrence Livermore National Laboratory, Environment, Safety, and Health Manual,
Document 14.5, Safe Handling of Mercury and Mercury Compounds,
http://www.llnl.gov/es_and_h/hsm/doc_14.05/doc14-05.html

Hazardous Materials: Hydrofluoric Acid Safe Handling
Guideline
1

Chemical
Name/Class
Hydrofluoric acid

Synonyms
Hydrogen fluoride solution, HF, fluorohydric acid, fluoric acid
Incompatible with strong bases, metals, glass, leather, water, alkalis, concrete, silica,
sulfides, cyanides, carbonates. Violent exothermic reaction occurs with water. Sufficient
heat may be produced to ignite combustible materials. Reaction with metals may form
flammable hydrogen gas. In the event of a fire, wear full protective clothing and NIOSH-
approved self-contained breathing apparatus with full face-piece operated in the pressure
demand or other positive pressure mode. Keep upwind of fire. Use water or carbon
dioxide on fires in which hydrofluoric acid is involved; halon or foam may also be used. In
case of fire, the sealed containers can be kept cool by spraying with water. Avoid getting
water in tanks or drums; water can cause generation of heat and spattering. In contact
with air, the acid gives off corrosive fumes which are heavier than air. Do not store in
glass containers. Light sensitive.
Exposure Hazards
Routes of Exposure
Inhalation, ingestion, skin contact, eye contact
Poison! Danger! Corrosive. Extremely hazardous liquid and vapor. Causes severe
burns which may not be immediately painful or visible. May be fatal if swallowed or
inhaled. Liquid and vapor can burn skin, eyes and respiratory tract. Causes bone
damage.
Severely corrosive to the respiratory tract. May cause sore throat, coughing, labored
breathing and lung congestion/inflammation. If ingested may cause sore throat,
abdominal pain, diarrhea, vomiting, severe burns of the digestive tract, and kidney
dysfunction. Skin contact causes serious skin burns which may not be immediately
apparent or painful. Symptoms may be delayed 8 hours or longer. The fluoride ion readily
penetrates the skin causing destruction of deep tissue layers and bone. Corrosive to the
eyes. symptoms include redness, pain, blurred vision, and permanent eye damage
and/or blindness may occur.

Hazardous Materials: Hydrofluoric Acid Safe Handling Guideline
Chronic Exposure
Intake of more than 6 mg of fluorine per day may result in fluorosis, bone, and joint
damage. Hypocalcemia and hypomagnesemia can occur from absorption of fluoride ion
into blood stream.
First Aid
If exposed through inhalation, get medical help immediately. If patient is unconscious,
give artificial respiration or use inhalator. Keep patient warm and resting, and send to
hospital after first aid is complete. If swallowed, do not induce vomiting. Give large
quantities of water. Never give anything by mouth to an unconscious person. Get medical
attention immediately. If skin contact occurs 1) Remove the victim from the
contaminated area and immediately place him under a safety shower or wash with
copious amounts of water, whichever is available. 2) Remove all contaminated clothing.
Handle all HF-contaminated material with gloves made of appropriate material, such as
PVC or neoprene. 3) Keep washing with large amounts of water for a minimum of 15
minutes. 4) Have someone make arrangements for medical attention while you continue
flushing the affected area with water. 5) Seek medical attention as soon as possible for
all burns regardless of how minor they may appear initially. If eye contact occurs irrigate
eyes for at least 30 minutes with copious quantities of water, keeping the eyelids apart
and away from eyeballs during irrigation. 2) Get competent medical attention
immediately, preferably an eye specialist. 3) Place ice pack on eyes until reaching
emergency room.
Medical treatment will involve the use of either topical or subcutaneous administration of
calcium gluconate or other medicines that will bind the fluoride to stop its corrosive and
toxic effects.
Exposure Limits
3
; 3 ppm (OSHA TWA)
NIOSH recommended exposure limit: 2.5mg/m
3
; 3 ppm (TWA)
Exposure Controls
safe use and handling of hydrofluoric acid in all applications. ESH can provide
impervious gloves, clothing, boots, apron, and eye goggles or full face shield. If the
airborne exposure limit may be exceeded and engineering controls are not feasible wear
a NIOSH-approved self-contained breathing apparatus with full face-piece operated in
the pressure demand or other positive pressure mode.
Disposal
that are contaminated with hydrofluoric acid must also be treated as hazardous waste.
Hazardous Materials: Hydrofluoric Acid Safe Handling Guideline
Initial physical examination to detect pre-existing conditions and establish a baseline for
future monitoring including eyes, respiratory tract, central nervous system, skeletal
system, kidneys, urinalysis, pelvic roentgenogram, 14x17 chest roentgenogram, FVC
and FEV. All tests should be conducted on an annual basis, with the exception of the
radiological examination of the pelvis which should be conducted only when medically
indicated.
Emergency Response
1910.134
Other References
NIOSH, International Chemical Safety Card: Hydrogen Fluoride (ICSC 0283),
OSHA, Occupational Health Guideline for Hydrogen Fluoride,
http://www.cdc.gov/niosh/pdfs/0334.pdf

Hazardous Materials: Hydrochloric Acid Safe Handling
Guideline
1

Chemical
Name/Class
Hydrochloric acid

Synonyms
Hydrogen chloride, muriatic acid
Incompatible with hydroxides, amines, alkalis, cyanides, sulfides, sulfites, formaldehyde,
copper, brass, and zinc. Hydrochloric acid solution in water is a strong acid: it reacts
violently with bases and is corrosive. Reacts violently with oxidants forming toxic chlorine
gas. Attacks many metals in the presence of water, forming flammable/explosive
hydrogen gas. When heated to decomposition, emits toxic hydrogen chloride fumes and
will react with water or steam to produce heat and toxic and corrosive fumes. Thermal
oxidative decomposition produces toxic chlorine fumes and explosive hydrogen gas.
If involved in a fire use water spray and neutralize with soda ash or slaked lime.
Exposure Hazards
Routes of Exposure
Skin contact will result in frostbite, serious skin burns, dermatitis and pain. Contact with
mucous membranes will result in burning sensation, cough, labored breathing, shortness
of breath, sore throat, symptoms may be delayed. The symptoms of lung edema often do
not manifest until a few hours have passed and they are aggravated by physical effort.
Persons with pre-existing skin disorders or eye disease may be more susceptible to the
effects of this substance.
Contact with oxidizers liberates poisonous chlorine gas. If chlorine gas comes in contact
with mucous membranes it may cause burning of eyes, nose, mouth; lacrimation
(discharge of tears), rhinorrhea (discharge of thin mucus); cough, choking, substernal
(occurring beneath the sternum) pain; nausea, vomiting; headache, dizziness; syncope;
pulmonary edema; pneumonitis; hypoxemia (reduced oxygen in the blood); dermatitis;
liquid: frostbite
Chronic Exposure
May have effects on the lungs, resulting in chronic bronchitis. May have effects on the
teeth, resulting in erosion.

Hazardous Materials: Hydrochloric Acid Safe Handling Guideline
First Aid
In case of eye contact, immediately wash (irrigate) the eyes with large amounts of
water, occasionally lifting the lower and upper lids. Get medical attention immediately.
In case of skin contact, immediately flush the contaminated skin with water. If this
chemical penetrates the clothing, immediately remove the clothing and flush the skin with
water. Get medical attention promptly. In case of inhalation of large amounts of this
chemical, immediately move the exposed person to fresh air. If breathing has stopped,
perform artificial resuscitation. Keep the affected person warm and at rest. Get medical
attention as soon as possible. If this chemical has been ingested, do not induce
vomiting; get medical attention immediately.
Exposure Limits
Permissible exposure limit: 7mg/m
3
; 5 ppm (OSHA TWA)
NIOSH recommended exposure limit: 7mg/m
3
; 5 ppm (NIOSH ceiling limit)
Exposure Controls
all storage and use is required if an exposure risk to employees or the environment is
present.
safe use and handling of hydrochloric acid in all applications. ESH can provide
impervious gloves, clothing, boots, apron, and eye goggles or full face shield. If the
airborne exposure limit may be exceeded and engineering controls are not feasible;
conditions of 50ppm or less a chemical cartridge respirator may be used with an acid gas
cartridge or wear a NIOSH-approved self-contained breathing apparatus with full face-
piece operated in the pressure demand or other positive pressure mode.
Disposal
that are contaminated with hydrochloric acid must also be treated as hazardous waste.
Store waste acid separated from combustible and reducing substances, strong oxidants,
strong bases, metals. Keep in a cool, dry, well-ventilated room.
Initial medical examination may be required to detect any pre-existing conditions and
establish a baseline for future monitoring. Contact Industrial Hygienist regarding
exposure and medical monitoring requirements.
Emergency Response
Hazardous Materials: Hydrochloric Acid Safe Handling Guideline
1910.134
Other References
NIOSH, International Chemical Safety Card: Hydrogen Chloride (ICSC 0163),
OSHA, Occupational Health Guideline for Hydrogen Chloride,
http://www.cdc.gov/niosh/pdfs/0332.pdf

Hazardous Materials: Sulfuric Acid Safe Handling
Guideline
1

Chemical
Name/Class
Sulfuric acid

Synonyms
Battery acid, hydrogen sulfate, oil of vitriol, sulfuric acid (aqueous)
Incompatible with organic materials, chlorates, carbides, fulminates, water, powdered
metals, reacts violently with water with evolution of heat, corrosive to metals. Not
combustible. Concentrated sulfuric acid is a strong oxidant and reacts violently with
combustible and reducing materials. The substance is a strong acid; it reacts violently
with bases and is corrosive to most common metals forming a flammable/explosive
hydrogen gas. Sulfuric acid reacts violently with water and organic materials with
evolution of heat. Upon heating, irritating or toxic fumes (or gases) (sulfur oxides) are
formed.
Exposure Hazards
Routes of Exposure
Sulfuric acid causes irritation to the eyes, skin, nose, throat; pulmonary edema,
bronchitis; emphysema; conjunctivitis; stomatis; dental erosion; eye, skin burns;
dermatitis. The substance is very corrosive to the eyes, the skin, and the respiratory tract
and attacks the enamel of the teeth. Inhalation may result in a burning sensation, sore
throat, cough, labored breathing, shortness of breath and lung edema. Symptoms may be
delayed. Skin contact may result in redness, pain, blisters, serious skin burns. Eye
contact may result in redness, pain and severe deep burns. Corrosive on ingestion and
may result in abdominal pain, burning sensation, shock or collapse.
Chronic Exposure
Lungs may be affected by repeated or prolonged exposure to an aerosol of this
substance. There is a risk of tooth erosion upon repeated or prolonged exposure to an
aerosol of this substance. Strong inorganic acid mists containing this substance are
carcinogenic to humans.
First Aid
If inhaled move victim to fresh air, rest and maintain a half-upright position. Use artificial
respiration if indicated, immediately seek medical attention. If skin contact occurs
remove contaminated clothes, rinse skin with plenty of water or shower. Immediately
seek medical attention. If eye contact occurs, first rinse with plenty of water for

Hazardous Materials: Sulfuric Acid Safe Handling Guideline
15minutes. Immediately seek medical attention. If ingested rinse mouth. Do not induce
vomiting. Immediately seek medical attention.
Exposure Limits
3
(OSHA TWA)
3
(TWA)
Exposure Controls
Prevent generation of mists. Avoid all contact. Local exhaust ventilation or breathing
protection is required. Secondary containment of all storage and use is required.
safe use and handling of sulfuric acid in all applications. ESH can provide information and
hazards, safe use, and emergency procedures
Avoid all contact with substance. Contact lenses should not be worn while working
with this substance. Prevent skin/eye contact through the use of impervious gloves,
clothing, boots, apron, and eye goggles or full face shield. If the airborne exposure limit
may be exceeded and engineering controls are not feasible, wear appropriate respiratory
protection.
Disposal
that are contaminated with sulfuric acid must also be treated as hazardous waste.
Workers should receive pre-employment and periodical medical exam. The pre-
employment exam should be particularly directed at the detection of chronic respiratory,
GI, or nervous diseases and any eye and skin diseases. Periodic exam should take place
at frequent intervals and should include a check on the condition of the teeth.
Emergency Response
1910.134
Other References
Hazardous Materials: Sulfuric Acid Safe Handling Guideline
NIOSH, NIOSH Pocket Guide to Chemical Hazards (NIOSH 2005-151), Sulfuric
Acid, http://www.cdc.gov/niosh/npg/npgd0577.html
NIOSH, International Chemical Safety Card: Sulfuric Acid (ICSC 0362),

ESHch 40

Загружено:

Сведения о документе

Оригинальное название

Авторское право

Доступные форматы

Поделиться этим документом

Поделиться или встроить документ

Параметры публикации

Этот документ был вам полезен?

Это неприемлемый материал?

Авторское право:

Доступные форматы

ESHch 40

Загружено:

Авторское право:

Доступные форматы

Chapter 40

Вам также может понравиться