VIDYANCHAL

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10/1/2009 Topic: Test Class: XIIth Page No. (1)
CH3MgBr
1. CH3COCH2CH2CH2Cl     → A, A is:
CH3
H3C CH3
(a) CH3CCH2CH2CH2Cl (b) CH3CCH2CH2CH2CH3 (c) CH3 (d)
O CH3 O
OH O H3C

H3O+
OCH3 A, A is
2.

(a) OH (b) O (c) (d)

3.
Br
1. Mg/ ether II: CH3CHCH2CH III: CH3CHCH2CH
Product (s) I:
2. CH3CH(OH)CH2CHO
3. H3O+ OH O OH OH
(a) III (b) I, III (c) I, II (d) II, III
4. Maximum hydration takes place of:
(a) CF3COCF3 (b) CH3COCH3 (c) CH3CHClCOCH3 (d) C6H5COC6H5
5.CH3COCH2CH2COOCH2CH3  (i)CH 3MgBr ( onemol ), (ii )H3O +
           →A, A formed in this reaction is:
OH O O O CH3 CH3
H3C O
(a) CH3CCH2CH2COCH2CH3 (b) CH3CCH2CH2CCH3 (c) O (d) CH3CCH2CH2CCH3
H3C
CH3 OH OH

6. Hydrolysis product of A (given below) is: O O

(b) (c) (d) ring is stable hence no hydrolysis

(a) O O
HO OH H O HO OH
O H O H
O O O
O
(a) (b) (c) (d) C6H5CC6H5

7. Enolisation is maximum in case of: O

O
O CH3Br (excess)
+ X, X is:
H3O
8.
OH O OH O
H3C HO
(a) OH (b) (c) (d)
H3C OH CH3
H3C
O O O
Br C H
(a) (b) (c) (d) equal
Br
9. Greatest amount of hydration is in:
CH3 CH3
Al-t-butoxide H3O+
Aldehyde A(C4H8O) B(ester) CHCOOH + CHCH2OH
Tischenko CH3 CH3
10. A and B are:
CH3 CH3 CH3
CH3 CH3
(a) CHCHO, CHCOOH2CHC (b) (c) both (d) none is correct
CHCHO, CH3CHCOOCH
CH3 CH3 CH3 CH3 CH3
CH3MgBr (2mol) conc. H2SO4
CH3CN A B; A and B are:
11. H3O+

Concept by- Devender Singh Help Line-01332-

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10/1/2009 Topic: Test Class: XIIth Page No. (2)
CH3

(d) none is correct

(a) CH3COCH3, (b) (CH3)3COH, (CH3)2C=CH2 (c) (CH3)3CHOH, CH3CH=CH2
H3C CH3
12. Which one of the following is correct regarding an acetal?
(a) it is the condensation product from 2 molecules of aldehyde (b) it is the condensation product from 2
molecules of ketone
(c) it is the condensation product from 2 molecules of alcohol (d) it is a diether
13. Oppenauer oxidation:
(a) is used to prepare ketone (b) uses aluminium t-butoxide as catalyst
(c) both are correct (d) none is correct
14. Suggest suitable oxidising reagents for following conversions:

OH
O
(A) CH3CH2CH=CHCH2OH → CH3CH2CH=CHCHO (B)
(a) MnO2 in A and CrO3 (in glacial acetic acid) in B (b) CrO3 in A and MnO2 in B (c) both correct (d) none is
correct
15. Aldehyde group can be protected:
(a) by acetal formation against attack by alkaline oxidising agents (c) both statements are correct
(b) by mercaptal formation against attack by acidic oxidising agents (d) none is correct
16. Mixture of CH3CH2OH and CH3CHO can be separated by using:
(a) NaHSO3 (b) NH2OH (c) HCN (c) LiAlH4
17. End product of the following sequence of reactions is:
COCH3 CN COOH
COCH3
NBS Mg/ether CH3CN (a) (b) (c) (d)
H3O+
O

HgSO4/H2SO4
C CH A, A is:
18.
O O O OH

(a) C CH3 (b) CH2CHO (c) COOH (d) CH2CHO

O
O

1
2 O
3

19. Following is hydrated maximum at the position O (a) 1 (b) 2 (c) 3 (d) equal
2CH3M gBr
20. C2H5O-CO-OC2H5    → A. Product A formed can:
(a) give iodoform test (b) further react with CH3MgBr / H3O+ to give t-butyl alcohol
(c) be obtained by the ozonolysis of 2,3-dimethyl-2-butene (d) all correct
O
1. KBrO, ∆
COCH3 A, A is:
CH3 2. H+
21. 3. ∆
O O

(a) COOH (b) CH3 (c) COOH (d) COOH

CH3 CH3
OH OH

Concept by- Devender Singh Help Line-01332-

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10/1/2009 Topic: Test Class: XIIth Page No. (3)

1.O3/H2O
2. ∆ A, A is:
22. (a) CH3COOH (b) CH2(COOH)2 (c) both (d) none
Answers:-
1. C 2. B 3. (c) 4.(a) 5. C 6. A 7. B 8. A 9. C 10. A 11. B 12. (d) 13. (c) 14. (a) 15.
(c) 16. (a) 17. B 18. B 19. (b) 20. (d) 21. B 22. (a)

Concept by- Devender Singh Help Line-01332-

270969,9897888342