Gr 11 Physical Science Paper II MEMO

Question 1 Question 2
1.1 Dative covalent bond each 2.1 C each 2.6 A
1.2 Boyles law 2.2 B 2.7 A
1.3 Activated complex 2.3 C 2.8 C
1.4 OH
-
2.4 B 2.9 B
1.5 Oxidation reaction (5) 2.5 B 2.10 A (20)
[25]

Question 3
3.1 Molecule Lewis structure Shape of the
molecule
Polarity of
the bonds
Polarity of
the molecule
CO
2 (g)


Linear Polar Non polar
H
2
O
(g)


Angular/bent Polar Polar








(8)
3.2 CO
2
no lone pairs on central atom
- Shared pairs repel equally
H
2
O 2 lone pairs on central atom
- Lone pairs repel more than shared pairs



(2)
3.3 CO
2
symmetrical shape; opposite sides of the molecule have the same charge
H
2
O asymmetrical shape; opposite sides of the molecule have opposite charge

(2)

Question 4
4.1 Hydrogen chloride (1)
4.2 Dipole-dipole (1)
4.3 Hydrogen fluoride (1)
4.4 Molecular size increase
strength of intermolecular/ vd Waals/ dipole-dipole forces increase
more energy required to break bonds


(3)
4.5 HF has strong hydrogen bonds
More energy needed to overcome intermolecular force

(2)

Question 5
5.1 pT (1)
5.2 Gay-Lussacc Law (1)
5.3 Volume/ mass of gas (1)
5.4

T2 =

T2 = 447 K




(3)

Paper II MEMO Nov 2013
2

5.5 pV = nRT
(10010
3
) (110
-3
) = n(8,3)(298)
n =

n = 0.04 mol
n =

0,04 =

m = 2.59g



(6)
5.6 B used a smaller mass (less moles) of gas (1)
5.7 High pressure and low temperature (2)

Question 6
6.1
n =

= 2,5 10
-3
mol
M[Na
2
CO
3
] = 232+12+163 = 106 gmol
-1


(3)
6.2 Mol ratio: Na
2
CO
3
: HC
1:2
2,5 10
-3
: 5 10
-3
mol HC


(2)
6.3
c =

= 0,25 moldm
-3



(3)
6.4
n =

2,5 10
-3
mol =

V = 5,6 10
-2
dm
3

Mol ratio: Na
2
CO
3
: CO
2
1:1
2,5 10
-3
: 2,5 10
-3
mol CO
2




(3)

Question 7
7.1.1 Indicates the simplest ratio in which the atoms have bonded with each other. (1)
7.1.2 Assume 100 g of the sample
76g Pb
n =

= 0,367 mol
13g C
n =

= 0,366 mol
2,2g C
n =

= 0,183 mol
8,8g O
n =

= 0,55 mol

Mol ratio: 2:2:1:3
Empirical formula: Pb
2
C
2
CO
3
OR (PbC)
2
CO
3


(7)
7.2.1
n =

OR
=

= 2,5 mol FeS
2

FeS
2
:O
2

4 : 11
2,5 : 6,875 mol O
2

n =

6,875 =

m = 220 g O
2
needed
O
2
limiting reactant
n =

= 6,25 mol O
2

FeS
2
:O
2

4 : 11
2,27 mol FeS
2
: 6,25
n =

2,27 =

m = 272,4 g FeS
2
needed
O
2
limiting reactant










(4)

Paper II MEMO Nov 2013
3

7.2.2 Mol ratio: O
2
: Fe
2
O
3

11 : 2
6,25 : 1,14 mol Fe
2
O
3

n =

1,14 =

= 181,82g Fe
2
O
3

M[Fe
2
O
3
] = 562+163= 160 gmol
-1





(3)
7.2.3
% yield =

100
= 78,65 %

(2)

Question 8
8.1 The total amount of chemical potential energy in a chemical system. (1)
8.2 H = E
p
E
r

= 270 120
= 150 kJmol
-1



(3)
8.3 Exothermic The energy of the products is less than the energy of the
reactants
(2)
8.4 E
A
= 480 270
= 210 kJmol
-1


(2)
8.5 Decrease (1)

Question 9
9.1.1 A proton donor (1)
9.1.2 HSO
4
-
OR H
3
O
+
- can accept or donate a proton (act as acid or base) (2)
9.1.3 HSO
4
-
and SO
4
2-
H
2
O and H
3
O
+
(2)
9.2

= 0,672 moldm
-3





(4)
9.3 An indicator is a substance of which the colour changes when it is added to an
acid or a base.

(1)

Question 10
10.1.1 2MgO 2Mg + O
2

Mg (+2 to 0) ON decrease reduction
O (-2 to 0) ON increase - oxidation


(2)
10.1.2 2O
2-
O
2
+ 4e
-
(2)
10.1.3 Mg
2+
or MgO (1)
10.2.1 A A + 3e
-
(2)
10.2.2 Cu
2+
+ 2e
-
Cu (2)
10.2.3 2A + 3Cu
2+
2A
3+
+ 3Cu (2)


Paper II MEMO Nov 2013
4

Question 11
11.1 SA has large gold reserves lots of money generated from it (2)
11.2 Cyanidation / leaching (1)
11.3 Zinc/ Zn more reactive than gold displace gold from the compound (2)
11.4 Material, labour, energy required for process
Gold mines deep expensive to create safely

(2)
11.5 Cyanide used is toxic to life forms (2)

Question 12
12.1.1 A (1)
12.1.2 D (1)
12.1.3 E (1)
12.1.4 B (1)
12.2.1 2 methylbut 1 ene (2)
12.2.2




(2)
12.3.1 Propanoic acid (2)
12.3.2





(2)
12.3.3 Ester (1)
12.3.4




(1)
12.4.1 They have the same molecular formulae but different structural formula (2)
12.4.2
C
C
C
C
H
H
H
H
H
H
H
H
but-2-ene




(3)
12.5 H
H C H
H C H
H C C C C H
H C C I






(2)
12.6 CH
3
C(CH
3
)
2
CH(C
2
H
5
)CH
2
CH
3
(2)