2009 CST243 (Pink)

Data Sheet for Chemistry

GCE Advanced level and Advanced Subsidiary
Chemistry 3882, 7882
Chemistry units 2811 2816
These data are for the use of candidates following Chemistry 3882 or 7882.
Clean copies of this sheet must be issued to candidates in the examination room, and must be given
up to the invigilator at the end of the examination.
Copies of this sheet may be used for teaching.
SP (SLM/CGW) T61655/6
*
O
C
E
/
T
6
1
6
5
5
*
2 2009 CST243 (Pink)
Characteristic infra-red absorptions in organic molecules
bond location wavenumber
CO alcohols, esters 1000 1300 cm
1
C=O aldehydes, ketones, carboxylic acids, esters 1680 1750 cm
1
OH hydrogen bonded in carboxylic acids 2500 3300 cm
1
(broad)
NH primary amines 3100 3500 cm
1
OH hydrogen bonded in alcohols, phenols 3230 3550 cm
1
OH free 3580 3670 cm
1
Chemical shifts for some types of protons in n.m.r. spectra
Chemical shifts are for hydrogen relative to TMS (tetramethylsilane)
Chemical shifts are typical values and can vary slightly depending on the solvent,
concentration and substituents.
type of proton chemical shift,
RCH3
0.71.6
RCH2 R 1.21.4
R3CH 1.62.0
C
O
CH
3
C
O
CH
2
R
2.02.9
CH
3
CH
2
R
2.32.7
OCH3 OCH2R 3.34.3
ROH 3.55.5
OH
6.57.0
H
7.17.7
R C
O
H
C H
O 9.510
C
O
OH
11.011.7
type of proton
RCH
3
RCH
2
R
R
3
CH
0.7 1.6
1.2 1.4
1.6 2.0
2.0 2.9
2.3 2.7
3.3 4.3
3.5 5.5
6.5 7.0
7.1 7.7
9.5 10
11.0 11.7
C CH
3
CH
3
O
C CH
2
R
O
OH
H
C

H
O
CH
2
R
ROH
O CH
3
O CH
2
R

C

OH
O
R

C

H
O
3
2
0
0
9
C
S
T
2
4
3

(
P
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1
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8
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5
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6
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7
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5
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4
3
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4
4
1
0
3
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d
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4
5
1
0
6
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4
6
1
0
8
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4
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1
1
2
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8
1
1
5
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1
1
9
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5
0
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2
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7
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1
3
1
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5
4
1
3
3
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5
5
1
3
7
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a
b
a
r
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m

5
6
1
3
9
L
a
l
a
n
t
h
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m
5
7
*
1
7
8
H
f
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a
f
n
i
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m

7
2
1
8
1
T
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t
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n
t
a
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m

7
3
1
8
4
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t
u
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g
s
t
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n

7
4
1
8
6
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e
r
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e
n
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m

7
5
1
9
0
O
s
o
s
m
i
u
m

7
6
1
9
2
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r
i
r
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m

7
7
1
9
5
P
t
p
l
a
t
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n
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m

7
8
1
9
7
A
u
g
o
l
d

7
9
2
0
1
H
g
m
e
r
c
u
r
y

8
0
2
0
4
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l
t
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a
l
l
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m

8
1
2
0
7
P
b
l
e
a
d

8
2
2
0
9
B
i
b
i
s
m
u
t
h

8
3

P
o
p
o
l
o
n
i
u
m

8
4

A
t
a
s
t
a
t
i
n
e

8
5

R
n
r
a
d
o
n

8
6

F
r
f
r
a
n
c
i
u
m

8
7

R
a
r
a
d
i
u
m

8
8

A
c
a
c
t
i
n
i
u
m

8
9
**

R
f
r
u
t
h
e
r
f
o
r
d
i
u
m

1
0
4

D
b
d
u
b
n
i
u
m

1
0
5

S
g
s
e
a
b
o
r
g
i
u
m

1
0
6

B
h
b
o
h
r
i
u
m

1
0
7

H
s
h
a
s
s
i
u
m

1
0
8

M
t
m
e
i
t
n
e
r
i
u
m

1
0
9

U
n
n
u
n
u
n
n
i
l
i
u
m

1
1
0

U
u
u
u
n
u
n
u
n
i
u
m

1
1
1

U
u
b
u
n
u
n
b
i
u
m

1
1
2

U
u
q
u
n
u
n
q
u
a
d
i
u
m

1
1
4

U
u
h
u
n
u
n
h
e
x
i
u
m

1
1
6

U
u
o
u
n
u
n
o
c
t
i
u
m

1
1
8





l
a
n
t
h
a
n
i
d
e
s
*
1
4
0
C
e
c
e
r
i
u
m

5
8
1
4
1
P
r
p
r
a
s
e
o
d
y
m
i
u
m

5
9
1
4
4
N
d
n
e
o
d
y
m
i
u
m

6
0

P
m
p
r
o
m
e
t
h
i
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6
1
1
5
0
S
m
s
a
m
a
r
i
u
m

6
2
1
5
2
E
u
e
u
r
o
p
i
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m

6
3
1
5
7
G
d
g
a
d
o
l
i
n
i
u
m

6
4
1
5
9
T
b
t
e
r
b
i
u
m

6
5
1
6
3
D
y
d
y
s
p
r
o
s
i
u
m

6
6
1
6
5
H
o
h
o
l
m
i
u
m

6
7
1
6
7
E
r
e
r
b
i
u
m

6
8
1
6
9
T
m
t
h
u
l
i
u
m

6
9
1
7
3
Y
b
y
t
t
e
r
b
i
u
m

7
0
1
7
5
L
u
l
u
t
e
t
i
u
m

7
1









a
c
t
i
n
i
d
e
s
**

T
h
t
h
o
r
i
u
m

9
0

P
a
p
r
o
t
a
c
t
i
n
i
u
m

9
1
U
u
r
a
n
i
u
m

9
2

N
p
n
e
p
t
u
n
i
u
m

9
3

P
u
p
l
u
t
o
n
i
u
m

9
4

A
m
a
m
e
r
i
c
i
u
m

9
5

C
m
c
u
r
i
u
m

9
6

B
k
b
e
r
k
e
l
i
u
m

9
7

C
f
c
a
l
i
f
o
r
n
i
u
m

9
8

E
s
e
i
n
s
t
e
i
n
i
u
m

9
9

F
m
f
e
r
m
i
u
m

1
0
0

M
d
m
e
n
d
e
l
e
v
i
u
m

1
0
1

N
o
n
o
b
e
l
i
u
m

1
0
2

L
w
l
a
w
r
e
n
c
i
u
m

1
0
3
4 2009 CST243 (Pink)
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