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CHEMISTRY
SECTION I
Single Correct Choice Type
This section contains 6 single correct choice type questions. Each question has 4 choices: (a),
(b), (c) and (d) for its answer, out of which ONLY ONE is correct.





1. An electron in Hatom in its ground state absorbs 1.50 times as much as energy as the minimum
required for its escape (13.6 eV) from the atom. Thus KE given to emitted electron is
(a) 13.6 eV (b) 20.4 eV (c) 34.0 eV (d) 6.8 eV

2. The reaction 2NO +Br
2
2NOBr, obeys the following mechanism,
NO + Br
2

NOBr
2

NOBr
2

slow
+ NO 2NOBr
The rate expression of the above reaction can be written as
(a) r =k[NO]
2
[Br
2
] (b) r =k[NO] [Br
2
] (c) r =k[NO] [Br
2
]
2
(d) r =k[NOBr
2
]

3. 0.1 M aqueous solution of CH
3
COONH
4
has [H
+
] equal to
[Given: K
a
(CH
3
COOH) =10
5
, K
b
(NH
4
OH) =10
5
3
10

]
(a) 1 (b) (c) 10
7
(d) 10
4


4. Phenol gives 2,4,6-tribromophenol when treated with bromine in aqueous solution but only
o and pbromophenol in CCl
4
solution because
(a) in aqueous solution, phenol exists in equilibrium with phenoxide ion, which has more
activating effect.
(b) in CCl
4
solution, phenol exists in equilibrium with phenoxide ion which has more
activating effect.
(c) in CCl
4
, the electrophilicity of Br
2
increases.
(d) in CCl
4
, the other positions of benzene rings are blocked by the solvent.

5. A compound (A) has molecular formula C
2
Cl
3
OH. It reduces Fehlings solution and on
oxidation gives a monocarboxylic acid (B). (A) is obtained by action of Cl
2
on ethyl alcohol.
(A) is:
(a) Chloral (b) Chloroform (c) Westrosol (d) Chloro acetic acid


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6. When sodium metal is dissolved in liquid ammonia, a blue solution is formed. The blue
colour is due to
(a) Solvated Na
+

2
NH
ions (b) Solvated electrons
(c) Solvated ions (d) Solvated protons

SECTION II
Multiple Correct Choice Type
This section contains 5 multiple correct choice type questions. Each question has
4 choices: (a), (b), (c) and (d) for its answer, out of which ONE OR MORE is/ are correct.



7. Which of the following statements is/are correct?
(a) In S
N
2 mechanism, the rate determining step involves two species
(b) The S
N
2 mechanism involves the formation of intermediate carbocation
(c) The S
N
2 mechanism is accompanied with Walden inversion
(d) The S
N
2 mechanisms may involve intramolecular rearrangement

8. Which of the following is/are false?
(a) AlCl
3
exists as Al
2
Cl
6
in vapour state.
(b) All the AlCl bonds in Al
2
Cl
6
are equivalent.
(c) Borax when heated with ammonium chloride forms ammonium tetraborate.
(d) AlF
3
is a high melting point. solid while AlCl
3
) pm 181 r , pm 95 r
Cl Na
= =
+
is a low melting point volatile solid.

9. Which of the following statements is/are correct?
(a) The coordination number of each type of ion in CsCl is 8.
(b) A metal that crystallizes is bcc structure has a coordination number of 12.
(c) A unit cell of an ionic crystal shares some of its ions with other unit cells.
(d) The length of the unit cell in NaCl is 552 pm. ( .
10.

+

OH H C . Anhyd / O H C
5 2
5 2 5 2
I H C
OH

(a) C
6
H
5
OC
2
H
5
(b) C
2
H
5
OC
2
H
5
(c) C
6
H
5
OC
6
H
5
(d) C
6
H
5
I


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11. Which of the following statement is correct for the isothermal process?
(a) in reversible compression the work done will be maximum than irreversible compression.
(b) in reversible expansion the work done will be maximum than irreversible expansion.
(c) both reversible and irreversible work done will be same.
(d) work done in reversible compression will not be same as work done in irreversible
compression.


SECTION III
Reasoning Type
This section contains 5 reasoning type questions. Each question contains Statement-1 and
Statement-2. Each question has 4 choices (a), (b), (c) and (d), out of which ONLY ONE is
correct.



Directions: Read the following questions and choose
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for
Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is not a correct explanation for
Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.

12. Statement 1 : In electrolysis, the quantity of electricity needed for deposition of 1 mole of
silver is different from that required for 1 mole of copper.
Statement 2 : The molecular weights of silver and copper are different.
(a) A (b) B (c) C (d) D

13. Statement 1 : A reaction which is spontaneous and accompanied by decrease of randomness
must be exothermic.
Statement 2 : All exothermic reactions are accompanied by decrease of randomness.
(a) A (b) B (c) C (d) D

14. Statement 1 : Aryl halides readily undergo nucleophilic substitution.
Statement 2 : Carbon-halogen bond in aryl halide has partial double bond character.
(a) A (b) B (c) C (d) D


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15. Statement 1 : Benzonitrile is prepared by the reaction of chlorobenzene with potassium
cyanide
Statement 2 : Cyanide (CN

) is a strong nucleophile.
(a) A (b) B (c) C (d) D

16. Statement 1 : Colloidal sol of Fe(OH)
3
formed by peptization carries positive charge.
Statement 2 : During the formation of positively charged colloidal particles of Fe(OH)
3
, the
electrons are lost by the colloidal particles of Fe(OH)
3
MatrixMatch Type
.
(a) A (b) B (c) C (d) D

SECTIONIV
This section contains 2 questions. Each question contains statements given in two columns,
which have to be matched. The statements in Column I are labelled A, B, C and D, while the
statements in Column II are labelled 1, 2, 3, 4 and 5. Any given statement in Column I can
have correct matching with ONE OR MORE statement(s) in Column II. The appropriate
bubbles corresponding to the answers to these questions have to be darkened as illustrated in
the following example:
If the correct matches are A 1, 4 and 5; B 2 and 3; C 1 and 2; and D 4 and 5; then the
correct darkening of bubbles will look like the following.

A

1 2 3 4
1 2 3 4
1 2 3 4
1 2 3 4
B

C

D

1 2 3 4
5
5
5
5
5




1.

Column I Column II
(A) N
2
(g) +3H
2
(g) 2NH
3
1. forward shift by increase in pressure (g), H <0
(B) 2SO
2
(g) +O
2
(g) 2SO
3
2. unaffected by change in pressure (g), H <0
(C) N
2
(g) +O
2
(g) 2NO(g), H >0 3. forward shift by rise in temperature
(D) PCl
3
(g) +Cl
2
(g) PCl
5
4. forward shift by lowering the temperature (g), H >0
5. reaction has n
g
<0



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2. Match the solutions in Column-I with their osmotic properties in Column-II:


Column I
(Concentration S
1
and S
2
are taken at 298 K)
Column II
(A) S
1
: 0.1 M glucose; S
2
=0.1 M urea 1. S
1
and S
2
are isotonic
(B) S
1
: 0.1 M NaCl; S
2
: 0.1 M Na
2
SO
4
2. No migration of solvent across the
membrane
(C) S
1
: 0.1 M NaCl; S
2
: 0.1 M KCl 3. S
1
is hypertonic to S
2

(D) S
1
: 0.1 M CuSO
4
; S
2
: 0.1 M sucrose 4. S
1
is hypotonic to S
2

5. Solution has Vant Hoff factor more than
one for any or all components