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CHEMISTRY
Atomic masses: H =1, C =12, O =16, S =32
Universal gas constant : R = 0.0821 L atm K
1
mol
1
=8.314 J K
1
mol
1
=2 cal K
1
mol

1


SECTION I
Straight Objective Type
This section contains 8 multiple choice questions numbered 1 to 8. Each question has
4 choices (a), (b), (c) and (d), out of which ONLY ONE is correct.


1. A cubic solid has formula AB
2
C
4
where C atoms are forming fcc lattice B atoms are present
in half of octahedral voids and A atoms present in 1/8
th
+ 2
2
Hg
of the tetrahedral voids. What will be
packing fraction if A, B and C touch each other?
(a) 0.68 (b) 0.74
(c) 0.77 (d) 0.88

2. An aqueous solution of a substance gives white precipitate on treatment with dilute
hydrochloric acid which dissolves on heating. When hydrogen sulphide is passed through hot
acidic solution, a black precipitate is obtained. The substance is a
(a) salt (b) Cu
2+
salt
(c) Ag
+
salt (d) Pb
2+
(a) CH
salt

3. Which one of the following compounds is most easy to decarboxylate by heating?
2
=CHCH
2
COOH
O
COOH (b)
(c)
COOH
(d) (CH
3
)
2
CHCOOH


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4. The co-ordination compound which is expected to react with AgNO
3
(a)
to give a white
precipitate as well as also reacts with ethylene diamine is

Cl
NO
2

Cr
en
en
Cl
(b)

NO
2

Cl
Cr
en en
Cl

(c)

Cl
NO
2

Cr
en
en
Cl (d)

Cl
NO
2

Cr
en
en
Cl


5.
Cl
Me
Me
on treatment with aqueous KOH followed by the action of H
2
SO
4
(a)
gives

Me
Me
(b)
Me
Me

(c)

Me
Me
(d)
OH
Me
Me



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6.

CH
2

C2H5ONa
(A)
COOC
2
H
5

COOC
2
H
5

(B) (C)
H2O/H
+

(D)

(E)
BrCH2CH2Br C2H5ONa

Identify the compound (E) formed in the above sequence of reactions.
(a) BrCH
2
CH
2
CH
2

COOH Br (b)
(c)

COOH
COOH
(d) BrCH
2
CH
2
CH
2
(a)
COOH

7. Which one of the following compounds has the highest percentage of enolic content?

Me
O
O
Me
(b)
O O

(c)
O
O
(d)

Me
O O
Me


8. Sample of air containing SO
2
as an impurity measured 1 kilo litre at NTP. It is passed through
excess of aqueous solution of H
2
O
2
. The resultant solution requires 20 ml of 0.1 N NaOH
solution for complete neutralisation. The concentration of SO
2
in air by volume is
(a) 10 ppm (b) 15 ppm
(c) 22.4 ppm (d) 25 ppm


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SECTION II
Reasoning Type
This section contains 4 reasoning type questions numbered 9 to 12. Each question contains
Statement-1 and Statement-2. Each question has 4 choices (a), (b), (c) and (d), out of which
ONLY ONE is correct.



Directions: Read the following questions and choose
(A) Statement-1 is True, Statement-2 is True ; Statement-2 is a correct explanation for
Statement-1.
(B) Statement-1 is True, Statement-2 is True ; Statement-2 is not a correct explanation for
Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.

9. Statement-1: A mixture of zinc oxide and cupric oxide can be separated by boiling the
mixture with caustic soda solution and filtering.
Statement-2: ZnO is amphoteric oxide while CuO is slightly basic oxide.
(a) A (b) B (c) C (d) D

10. Statement-1: An electron in energy level n =1 is given energy which is slightly more than
energy required to excite to level n =2 and less than energy required to excite
to level n =3 then electron will be excited to level n =2.
Statement-2: On plotting a graph stopping potential against the frequency of radiation that
has emitted the electrons, then the slope would be equal to (e/h).
(a) A (b) B (c) C (d) D

11. Statement-1: Boric acid is a weak monobasic acid in aqueous solution.
Statement-2: By addition of glycol in aqueous solution of boric acid, pH of solution
decreases.
(a) A (b) B (c) C (d) D

12. Statement-1: According to principle of common ion effect, the solubility of HgI
2
is expected
to be less in an aqueous solution of KI than in pure water but HgI
2
is more
soluble in aqueous solution of KI.

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Statement-2: Iodide ion is highly polarizable.
(a) A (b) B (c) C (d) D


SECTIONIII
Linked Comprehension Type
This section contains 2 paragraphs C
13
C
18

. Based upon each paragraph, 3 multiple choice
questions have to be answered. Each question has 4 choices (a), (b), (c) and (d), out of which
ONLY ONE is correct.

PassageI

The rate of reaction depends on the concentration of reacting species i.e. reactants in rate
equation or rate law as well as rate of reaction depends upon the order of the reaction. Consider the
following gaseous reaction.
aA + bB Product
The rate law will be as under
rate =k[A]
x
[B]
13. For the first order reaction 3A B, concentration
varies with time as shown in the adjacent graph. The
half life (t
y

where x and y are order of the reaction w.r.t. A and B respectively and (x +y) is the overall
order of the reactions. If either of A or B is taken in excess then order with respect to this reactant
will be taken zero.

1/2

Time (minutes)
2 4 6
C
o
n
c
e
n
t
r
a
t
i
o
n

(
M
)

A
B
) of reaction would be
(a) 2 minutes
(b) 4 minutes
(c) 8 minutes
(d) 16 minutes


14. 1 mole of a gas is changed from its initial state (15 litre, 2 atm) to final state (4 litre, 10 atm)
reversibly. If this change can be represented by straight line in PV curve. The value of rate
constant at the maximum temperature that the gas can attain if maximum rate constant is

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equal to 20 sec
1
and the value of activation energy is 40 kJ mol
1
(assume that activation
energy does not change in this temperature range) [anti log (2.99) =0.001]
(a) 5 10
4
sec
1
(b) 2 10
2
sec
1

(c) 8 10
5
sec
1
(d) 7 10
6
sec
1


15. For forward and backward reactions of the following equilibrium
dCH
3
CH(OH)CH
2
CH
3

lCH
3
CH(OH)CH
2
CH
3

are of first order with half life 10 hrs at 400 K. The reaction quotient at 10 hrs would be
[antilog (0.60) =0.25]
(a) 0.3 (b) 0.15
(c) 5.7 (d) 0.6

PassageII

Alkanes undergo substitution reactions in which one or more hydrogen atoms are replaced or
substituted by different atoms or groups such as halogen atoms (Cl, Br or I). Chlorination of
alkanes is carried out by treating alkane with chlorine in presence of sunlight or heating it to high
temperature. It is a free radical mechanism. Halo alkanes are one of the most reactive class of
organic compounds. They can be used for the preparation of large variety of useful organic
compounds. Some of the reactions of alkyl halides are:
(i) Nucleophilic substitution reaction (ii) Elimination reaction (iii) Reactions with metals
(iv) Reduction.

16. A compound (A) has molecular formula C
5
H
9
Cl. It does not react with bromine in carbon
tetrachloride on treatment with strong base it produces a single compound (B). Compound (B)
has the molecular formula C
5
H
8
and reacts with bromine in carbon tetrachloride. Reductive
ozonolysis of compound (B) produces a compound (C) with molecular formula C
5
H
8
O
2
(a)
.
The structure of compound (A) would be
Cl
(b)

Cl CH
3
(c)
Cl
(d)
Cl

17. The product of peroxide catalysed reaction between methylene cyclopentane and
chloroform is

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(a)

CH
2
CCl
3

H
(b)

CH
3

CCl
3


(c)

CCl
3

(d)

CH
2
CHCl
2



18. The major product of reaction CCl
3
CH=CH
2
peroxide
HBr
(Product) is
(a) CCl
3
CH=CHBr (b) CCl
3
(Br)CHCH
2
Br
(c) CCl
2
(H)CH(Cl)CH
2
Br (d) HCCl
2
(Cl)C(Br)CH
2

A

1 2 3 4
1 2 3 4
1 2 3 4
1 2 3 4
B

C

D

1 2 3 4
Br



SECTIONIV
MatrixMatch Type
This section contains 3 questions. Each question contains statements given in two columns
which have to be matched. Statements (A), (B), (C), (D) in Column I have to be matched
with statements (1, 2, 3, 4) in Column II. One statement in first column has one or more than
one match with the statements in second column. The answers to these questions have to be
appropriately bubbled as illustrated in the following example.
If the correct matches are A1,3, B3, C2,3 and D2,4, then the correctly bubbled
4 4 matrix should be as follows:






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1.

Column I
(addition of dil. HCl/dil. H
2
SO
4
)
Column II
(observation)
(A)
2
3 2
O S
1. Gas evolved turns lime water milky.
(B)
2
3
SO
2. Gas turns lead acetate paper black.
(C)
2
3
CO
3. Gas turns acidified K
2
Cr
2
O
7
solution green.
(D) S 4. gives yellowish turbidity.
2



2.

Column I
(Unit cells)
Column II
(Characteristics)
(A) Body centred and face centred cubic 1. are two crystal system
(B) Hexagonal and tetragonal 2. have only two crystallographic angle of 90
(C) Hexagonal and monoclinic 3. have only two crystallographic sides equal
(D) Cubic and orthorhombic 4. have the cell parameters = = =90