Академический Документы
Профессиональный Документы
Культура Документы
mole calculations
PRODUCTION OF MATERIALS
thermal cracking
catalytic cracking
bromine water
test:
cyclohexene
cyclohexane
Polymersation:
ethylene
LDPE
initiation
propagation
termination
(disproportionation)
backbiting
HDPE
vinyl chloride
PVC
styrene PS
condensation
polymerisation of:
3-hydroxybutanoic
acid PHB;
glucose
acid hydrolysis of
cellulose
(breaking -1,4-
glycosidic bonds)
hydrogenation of
ethylene
fermentation
complete
combustion of
ethanol
incomplete
combustion
heat energy
tranfer
addition of water
and ethylene
dehydration of
ethanol
Leclanch cell:
anode
cathode
Button cell:
anode
cathode
producing
transuranic
elements
medical isotope:
Tc-99m
industrial isotope:
Na-24
Recently
discovered
element:
Ununoctium
THE ACIDIC ENVIRONMENT
pH
determining
whether acid or
base
natural acidity of
rain
releasing SO
2
smelting of
sulfide ores
bacterial
fermentation
S-compounds
producing SO
2
form sulfurous
acid
form sulfuric acid
OR
N
2
and O
2
form
nitric oxide with
high temps
form nitrogen
dioxide
form nitricacid
and nitrous acid
nitrous acid forms
nitric acid
natural buffer
system:
H
2
CO
3
/H
2
CO
3
-
-use LCP when
add acid/base
1
photosynthesis
(endergonic
reaction)
Esterification
(forming an ester)
general
making ethyl
butyrate
CHEMICAL MONITORING AND MANAGEMENT
nitrogen oxides
(in traffic from
car engines)
ozone from
photochemical
smog in
troposphere
catalytic
converters in cars
reduce harmful
emissions
Haber process
sources of H
2
removing CO and
CO
2
1
- if acid added,
- if base added
- in both cases, the equilibrium shifts to neutralise the added acid/base
Formation of
ozone
Destruction of
ozone
increased temp at
stratosphere
CFCs in
stratosphere
Chlorine atom in
CFCs make for
catalyst in
destruction of
stratospheric
ozone
catalytic
destruction of O
3
by high-altitude
supersonic aircraft
INDUSTRIAL CHEMISTRY
fertiliser
production
superphosphate
SBR production
Contact process
obtaining SO
2
(1)
smelting
(see AE)
(2)
catalytic oxidation
of SO
2
absorption of SO
3
conversion of
oleum to H
2
SO
4
safety
diluting H
2
SO
4
ionisation
exothermic
S compounds
produce H
2
S
dehyrating agent
secondary process:
why dangerous, not
dehydration
oxidising agent
electrolysis of
NaCl
-molten
anode
cathode
overall
-concentrated
anode
cathode
overall
-dilute
anode
cathode
overall
Mercury cell
anode
cathode
overall
Diaphragm cell
anode
cathode
overall
Membrane cell
anode
cathode
overall
Downs cell
anode
cathode
Saponification
(making soap)
general
glycerol trilaurate
+ NaOH
glycerol + sodium
laurate
glycerol
tristearate +
NaOH glycerol
+ sodium stearate
soap in hardwater
forming scum
(insoluble)
Solvay Process
overall
brine purification
CO
2
formation
ammonia
recovery
carbonic acid
formation
ammonia
saturation
net HCO
3
-
formation
decomposition of
NaHCO
3