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GENERAL

mole calculations




PRODUCTION OF MATERIALS
thermal cracking

catalytic cracking

bromine water
test:
cyclohexene


cyclohexane


Polymersation:
ethylene
LDPE
initiation


propagation



termination
(disproportionation)



backbiting






HDPE


vinyl chloride
PVC


styrene PS









condensation
polymerisation of:
3-hydroxybutanoic
acid PHB;

glucose


acid hydrolysis of
cellulose
(breaking -1,4-
glycosidic bonds)

hydrogenation of
ethylene

fermentation

complete
combustion of
ethanol

incomplete
combustion

heat energy
tranfer



addition of water
and ethylene

dehydration of
ethanol

Leclanch cell:
anode

cathode


Button cell:
anode

cathode


producing
transuranic
elements

medical isotope:
Tc-99m


industrial isotope:
Na-24

Recently
discovered
element:
Ununoctium






THE ACIDIC ENVIRONMENT
pH

determining
whether acid or
base

natural acidity of
rain


releasing SO
2


smelting of
sulfide ores













bacterial
fermentation




S-compounds
producing SO
2



form sulfurous
acid

form sulfuric acid



OR



N
2
and O
2
form
nitric oxide with
high temps

form nitrogen
dioxide

form nitricacid
and nitrous acid

nitrous acid forms
nitric acid

natural buffer
system:
H
2
CO
3
/H
2
CO
3
-

-use LCP when
add acid/base
1


photosynthesis
(endergonic
reaction)

Esterification
(forming an ester)
general


making ethyl
butyrate


CHEMICAL MONITORING AND MANAGEMENT
nitrogen oxides
(in traffic from
car engines)




ozone from
photochemical
smog in
troposphere


catalytic
converters in cars
reduce harmful
emissions

Haber process

sources of H
2


removing CO and
CO
2



1
- if acid added,
- if base added
- in both cases, the equilibrium shifts to neutralise the added acid/base


Formation of
ozone


Destruction of
ozone


increased temp at
stratosphere

CFCs in
stratosphere

Chlorine atom in
CFCs make for
catalyst in
destruction of
stratospheric
ozone
catalytic
destruction of O
3

by high-altitude
supersonic aircraft


INDUSTRIAL CHEMISTRY
fertiliser
production




superphosphate

SBR production

Contact process
obtaining SO
2

(1)
smelting
(see AE)
(2)


catalytic oxidation
of SO
2


absorption of SO
3



conversion of
oleum to H
2
SO
4






safety
diluting H
2
SO
4

ionisation
exothermic



S compounds
produce H
2
S

dehyrating agent




secondary process:
why dangerous, not
dehydration


oxidising agent

electrolysis of
NaCl
-molten
anode

cathode

overall

-concentrated
anode

cathode


overall

-dilute
anode

cathode


overall










Mercury cell
anode

cathode


overall



Diaphragm cell
anode

cathode


overall




Membrane cell
anode

cathode

overall



Downs cell
anode

cathode



Saponification
(making soap)

general







glycerol trilaurate
+ NaOH
glycerol + sodium
laurate


glycerol
tristearate +
NaOH glycerol
+ sodium stearate

soap in hardwater
forming scum
(insoluble)

Solvay Process
overall




brine purification




CO
2
formation


ammonia
recovery




carbonic acid
formation

ammonia
saturation













net HCO
3
-

formation

decomposition of
NaHCO
3

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