2. What is the nature of air? 3. Vegetable staticks 4. Dr. Joseph Black (17281799) 5. The problem of combustion 6. Henry Cavendish (17311810) 7. The discovery of oxygen 8. Joseph Priestley (17331804) 9. Antoine-Laurent Lavoisier (17431794)
Lecture 2:The birth and evolution of our atmosphere 1. The Earth System 2. In the Beginning 3. Has the Earths Atmosphere changed? 4. The Noble Gases 5. The Secondary Atmosphere 6. Evolution of the Secondary Atmosphere 7. The Emergence of Life 8. When did Life evolve on Earth? 9. Where did Life evolve on Earth? 10. Photosynthesis 11. Oxygen and Ozone
Lecture 3: The basic physical and chemical structure of the atmosphere 1. Atmospheric pressure 2. Why does the pressure fall with altitude? 3. The hydrostatic equation 4. Temperature versus altitude 5. Lon Teisserenc de Bort (1855 1913) 6. The vertical temperature structure 7. Temperature versus latitude and season 8. Zonal-mean wind distribution 9. The meridional circulation 10. Methane distribution 11. Nomenclature 12. Vertical ozone profile Basic chemical composition
Lecture 4: Biogeochemical cycles Part I 1. The Earth system 2. Cycles within the Earth system 3. The impact of life on the atmosphere 4. What is a biogeochemical cycle? 5. The global water cycle 6. The global carbon cycle 7. Colours of life 8. Balancing the carbon budget 9. The global nitrogen cycle 10. Changes to the equilibrium
Lecture 5: Chemical reactions 1. Chemistry 2. Chemical kinetics 3. Factors that determine the reaction rate 4. Reaction rate: Example 1 5. Reaction rate: Example 2 6. Dependence of rate on concentration 7. Extablishing a rate law 8. Rate laws and reaction orders 9. Rates also depend on temperature 10. Activation energy 11. Reaction mechanisms 12. Elementary steps 13. Molecularity 14. Rate laws of elementary steps 15. Rate laws and multi-step mechanisms 16. Example: A two-step mechanism 17. Catalysis 18. Appendix: Oscillating reactions
Lecture 6: Photochemical reactions 1. Solar radiation 2. Properties of light waves 3. Electromagnetic spectrum 4. The solar spectrum 5. Solar spectrum at the Earths surface 6. Absorption spectrum at the Earths surface 7. Photochemical reactions 8. Factors that affect the photolysis rate 9. Example: Ozone absorbance 10. Scattering of light 11. Red sky at night? 12. Haze
Lecture 8: Stratospheric Ozone Part I 1. UV irradiance 2. Protection of the biosphere 3. The discovery of ozone 4. Christian F. Schnbein (17991868) 5. Unravelling ozones composition 6. Identifying ozone in the atmosphere 7. The optical properties of ozone 8. Gordon M. B. Dobson (18891976) 9. The vertical ozone distribution 10. Sydney Chapman (18881970) 11. The Chapman mechanism
Lecture 9: Stratospheric Ozone Part II 1. The Chapman mechanism revisited 2. Odd oxygen 3. The ozone profile 4. The vertical ozone distribution 5. The total ozone column 6. The failure of the Chapman mechanism 7. Catalytic odd oxygen loss 8. Appendix A: Chemical lifetime