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Diagrama de Reparto de Ni, Al y Fe

100

90

80

70

60
Al

50

Fe
Ni

40

30

20

10

0
0

10

12

14

Diagrama de reparto de Al, Fe y Ni con EDTA


100

90

80

70

60
Al

50

Fe
Ni

40

30

20

10

0
0

10

12

14

Diagrama de reparto Ni f (pH)


100

90

80

70

60

50

40

30

20

10

0
0

10

12

14

16

Diagrama Reparto Ni -EDTA


100

90

80

70

60

50

40

30

20

10

0
0

10

12

14

Hoja de Ca
DATOS PARA EL AGENTE EXTRACTANTE (L)

pH
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
1.1
1.2
1.3
1.4
1.5
1.6
1.7
1.8
1.9
2
2.1
2.2
2.3
2.4
2.5
2.6
2.7
2.8
2.9
3
3.1

H+
1
0.79432823
0.63095734
0.50118723
0.39810717
0.31622777
0.25118864
0.19952623
0.15848932
0.12589254
0.1
0.07943282
0.06309573
0.05011872
0.03981072
0.03162278
0.02511886
0.01995262
0.01584893
0.01258925
0.01
0.00794328
0.00630957
0.00501187
0.00398107
0.00316228
0.00251189
0.00199526
0.00158489
0.00125893
0.001
0.00079433

DATOS DE COMP. DE M CON L EN


MLn
398.107171 LOG BETA 1
Kd
LOG BETA 2
0.00001 LOG BETA 3
Ka 1
1.9953E-10 LOG BETA 4
Ka 2
LOG BETA 5
0.05
Oxina
LOG BETA 6
3
Volumen Forg
10
Volumen Facuo
0.3
r
0.15
n*

Log Kd
H2OX
pKa 1
pKa 2

2.6

D
0.00398103
0.00501181
0.00630947
0.00794312
0.00999975
0.01258886
0.0158483
0.01995162
0.02511728
0.03162026
0.03980674
0.05011241
0.06308574
0.07941698
0.09997489
0.12585274
0.15842625
0.19942628
0.25103025
0.31597678
0.39770946
0.50055707
0.62995893
0.7927465
0.99749441
1.25495689
1.57860864
1.98531218
2.49613687
3.13735675
3.94165515
4.94956104

log D
-2.4000043
-2.3000055
-2.2000069
-2.1000087
-2.0000109
-1.9000137
-1.8000173
-1.7000218
-1.6000274
-1.5000345
-1.4000434
-1.3000547
-1.2000688
-1.1000866
-1.0001091
-0.9001373
-0.8001729
-0.7002176
-0.6002739
-0.5003448
-0.4004341
-0.3005464
-0.2006878
-0.1008657
-0.0010895
0.09862881
0.19827447
0.29782881
0.3972684
0.4965639
0.59567863
0.69456668

5
9.7

%E (L)
0.11928849
0.15012855
0.1889266
0.23772723
0.2990952
0.37624473
0.47319921
0.59498741
0.74788295
0.93969394
1.1801092
1.4811059
1.85741909
2.32706675
2.91191122
3.63821836
4.53714653
5.64505665
7.00348186
8.65853455
10.659472
13.0561132
15.8948391
19.2130674
23.0324194
27.3512971
32.1381777
37.3274018
42.8192749
48.4856593
54.1809126
59.7564187

pL
1.82442711
1.82456123
1.82473001
1.82494241
1.82520964
1.82554583
1.8259687
1.82650046
1.82716896
1.82800908
1.82906437
1.83038921
1.83205127
1.83413451
1.83674279
1.84000392
1.84407433
1.84914408
1.85544205
1.86324077
1.87286023
1.88466969
1.89908609
1.91656762
1.93760091
1.96268088
1.99228322
2.02683104
2.06665908
2.11198059
2.16286231
2.21921212

alpha L (H)
5.0119E+14
3.1623E+14
1.9953E+14
1.259E+14
7.9435E+13
5.012E+13
3.1624E+13
1.9954E+13
1.259E+13
7.9439E+12
5.0124E+12
3.1627E+12
1.9956E+12
1.2592E+12
7.9453E+11
5.0135E+11
3.1635E+11
1.9963E+11
1.2597E+11
7.9496E+10
5.0169E+10
3.1663E+10
1.9984E+10
1.2614E+10
7963234971
5027721269
3174866915
2005262316
1266868695
800637809
506199107
320208839

3.2
3.3
3.4
3.5
3.6
3.7
3.8
3.9
4
4.1
4.2
4.3
4.4
4.5
4.6
4.7
4.8
4.9
5
5.1
5.2
5.3
5.4
5.5
5.6
5.7
5.8
5.9
6
6.1
6.2
6.3
6.4
6.5
6.6
6.7
6.8
6.9
7
7.1
7.2
7.3
7.4
7.5
7.6
7.7
7.8
7.9
8
8.1
8.2
8.3

0.00063096
0.00050119
0.00039811
0.00031623
0.00025119
0.00019953
0.00015849
0.00012589
0.0001
7.9433E-05
6.3096E-05
5.0119E-05
3.9811E-05
3.1623E-05
2.5119E-05
1.9953E-05
1.5849E-05
1.2589E-05
0.00001
7.9433E-06
6.3096E-06
5.0119E-06
3.9811E-06
3.1623E-06
2.5119E-06
1.9953E-06
1.5849E-06
1.2589E-06
0.000001
7.9433E-07
6.3096E-07
5.0119E-07
3.9811E-07
3.1623E-07
2.5119E-07
1.9953E-07
1.5849E-07
1.2589E-07
0.0000001
7.9433E-08
6.3096E-08
5.0119E-08
3.9811E-08
3.1623E-08
2.5119E-08
1.9953E-08
1.5849E-08
1.2589E-08
0.00000001
7.9433E-09
6.3096E-09
5.0119E-09

6.21113358
7.78789338
9.7549662
12.2033501
15.2421313
19.000349
23.6280343
29.2957303
36.1915544
44.5146472
54.4637798
66.2201199
79.9239187
95.6463263
113.359665
132.911845
154.012256
176.236176
199.051599
221.866652
244.089432
265.187849
284.737042
302.446201
318.162973
331.859341
343.606028
353.542743
361.849975
368.725633
374.367775
378.963153
382.680587
385.667939
388.051517
389.936968
391.410968
392.543205
393.388374
393.98796
394.37174
394.558924
394.558924
394.37174
393.98796
393.388374
392.543205
391.410968
389.936968
388.051517
385.667939
382.680587

0.79317087
0.89142
0.98922577
1.08647907
1.1830457
1.27876158
1.37342759
1.46680433
1.55860724
1.64850294
1.73610778
1.82098996
1.90267677
1.98066829
2.05445855
2.12356369
2.18755528
2.24609506
2.29896567
2.34609203
2.38754898
2.42355362
2.45444397
2.48064813
2.50264964
2.52095405
2.53606077
2.54844193
2.55852855
2.56670333
2.57329846
2.57859699
2.58283643
2.58621354
2.58888939
2.59099441
2.59263299
2.59388746
2.59482152
2.59548295
2.59590579
2.59611187
2.59611187
2.59590579
2.59548295
2.59482152
2.59388746
2.59263299
2.59099441
2.58888939
2.58621354
2.58283643

65.0757516
70.0272873
74.5319602
78.5453996
82.0551819
85.0748601
87.6366311
89.7841588
91.5664951
93.0334921
94.2326993
95.2075229
95.9963448
96.6323047
97.1435019
97.5534302
97.881521
98.1437086
98.3529736
98.5198341
98.6527782
98.758633
98.8428753
98.90989
98.9631815
99.0055471
99.0392173
99.065969
99.0872164
99.1040847
99.117468
99.1280764
99.1364733
99.1431048
99.1483234
99.1524065
99.1555715
99.1579866
99.1597805
99.1610484
99.161858
99.1622523
99.1622523
99.161858
99.1610484
99.1597805
99.1579866
99.1555715
99.1524065
99.1483234
99.1431048
99.1364733

2.28078167
2.34718269
2.41791322
2.49238831
2.56996968
2.64999033
2.73177191
2.81463461
2.89790064
2.98089361
3.06293614
3.14334869
3.22145207
3.29657595
3.3680748
3.43535114
3.49788457
3.55526259
3.60720817
3.65359835
3.69446965
3.73000855
3.76052859
3.78643841
3.80820598
3.82632451
3.84128357
3.85354743
3.86354091
3.87164177
3.87817826
3.8834303
3.88763296
3.89098102
3.89363401
3.89572115
3.89734586
3.89858976
3.89951596
3.90017184
3.90059113
3.90079548
3.90079548
3.90059113
3.90017184
3.89951596
3.89858976
3.89734586
3.89572115
3.89363401
3.89098102
3.88763296

202688510
128404429
81428086.8
51703617.6
32881703
20952624.1
13383583.4
8574240.69
5513060.57
3560385.83
2311491.08
1510115.05
993855.466
659677.553
442121.307
299527.231
205326.365
142529.558
100238.447
71434.4937
51576.3998
37709.1184
27896.9055
20861.8043
15752.5318
11996.2623
9203.20776
7104.90168
5514.05957
4298.29947
3362.80389
2638.77897
2075.69514
1636.01192
1291.54819
1020.95262
807.917489
639.900627
507.199106
402.269448
319.223028
253.447569
201.32056
159.990506
127.208769
101.199526
80.558716
64.1751673
51.1688421
40.8423398
32.6427292
26.1314536

8.4
8.5
8.6
8.7
8.8
8.9
9
9.1
9.2
9.3
9.4
9.5
9.6
9.7
9.8
9.9
10
10.1
10.2
10.3
10.4
10.5
10.6
10.7
10.8
10.9
11
11.1
11.2
11.3
11.4
11.5
11.6
11.7
11.8
11.9
12
12.1
12.2
12.3
12.4
12.5
12.6
12.7
12.8
12.9
13
13.1
13.2
13.3
13.4
13.5

3.9811E-09
3.1623E-09
2.5119E-09
1.9953E-09
1.5849E-09
1.2589E-09
1E-09
7.9433E-10
6.3096E-10
5.0119E-10
3.9811E-10
3.1623E-10
2.5119E-10
1.9953E-10
1.5849E-10
1.2589E-10
1E-10
7.9433E-11
6.3096E-11
5.0119E-11
3.9811E-11
3.1623E-11
2.5119E-11
1.9953E-11
1.5849E-11
1.2589E-11
1E-11
7.9433E-12
6.3096E-12
5.0119E-12
3.9811E-12
3.1623E-12
2.5119E-12
1.9953E-12
1.5849E-12
1.2589E-12
1E-12
7.9433E-13
6.3096E-13
5.0119E-13
3.9811E-13
3.1623E-13
2.5119E-13
1.9953E-13
1.5849E-13
1.2589E-13
1E-13
7.9433E-14
6.3096E-14
5.0119E-14
3.9811E-14
3.1623E-14

378.963153
374.367775
368.725633
361.849975
353.542743
343.606028
331.859341
318.162973
302.446201
284.737042
265.187849
244.089432
221.866652
199.051599
176.236176
154.012256
132.911845
113.359665
95.6463263
79.9239187
66.2201199
54.4637798
44.5146472
36.1915544
29.2957303
23.6280343
19.000349
15.2421313
12.2033501
9.7549662
7.78789338
6.21113358
4.94956104
3.94165515
3.13735675
2.49613687
1.98531218
1.57860864
1.25495689
0.99749441
0.7927465
0.62995893
0.50055707
0.39770946
0.31597678
0.25103025
0.19942628
0.15842625
0.12585274
0.09997489
0.07941698
0.06308574

2.57859699
2.57329846
2.56670333
2.55852855
2.54844193
2.53606077
2.52095405
2.50264964
2.48064813
2.45444397
2.42355362
2.38754898
2.34609203
2.29896567
2.24609506
2.18755528
2.12356369
2.05445855
1.98066829
1.90267677
1.82098996
1.73610778
1.64850294
1.55860724
1.46680433
1.37342759
1.27876158
1.1830457
1.08647907
0.98922577
0.89142
0.79317087
0.69456668
0.59567863
0.4965639
0.3972684
0.29782881
0.19827447
0.09862881
-0.0010895
-0.1008657
-0.2006878
-0.3005464
-0.4004341
-0.5003448
-0.6002739
-0.7002176
-0.8001729
-0.9001373
-1.0001091
-1.1000866
-1.2000688

99.1280764
99.117468
99.1040847
99.0872164
99.065969
99.0392173
99.0055471
98.9631815
98.90989
98.8428753
98.758633
98.6527782
98.5198341
98.3529736
98.1437086
97.881521
97.5534302
97.1435019
96.6323047
95.9963448
95.2075229
94.2326993
93.0334921
91.5664951
89.7841588
87.6366311
85.0748601
82.0551819
78.5453996
74.5319602
70.0272873
65.0757516
59.7564187
54.1809126
48.4856593
42.8192749
37.3274018
32.1381777
27.3512971
23.0324194
19.2130674
15.8948391
13.0561132
10.659472
8.65853455
7.00348186
5.64505665
4.53714653
3.63821836
2.91191122
2.32706675
1.85741909

3.8834303
3.87817826
3.87164177
3.86354091
3.85354743
3.84128357
3.82632451
3.80820598
3.78643841
3.76052859
3.73000855
3.69446965
3.65359835
3.60720817
3.55526259
3.49788457
3.43535114
3.3680748
3.29657595
3.22145207
3.14334869
3.06293614
2.98089361
2.89790064
2.81463461
2.73177191
2.64999033
2.56996968
2.49238831
2.41791322
2.34718269
2.28078167
2.21921212
2.16286231
2.11198059
2.06665908
2.02683104
1.99228322
1.96268088
1.93760091
1.91656762
1.89908609
1.88466969
1.87286023
1.86324077
1.85544205
1.84914408
1.84407433
1.84000392
1.83674279
1.83413451
1.83205127

20.9605664
16.8539438
13.5924164
11.0019953
8.94454127
7.31036777
6.01237352
4.98138793
4.16247719
3.51201232
2.99534175
2.58494331
2.25895703
2.00001995
1.79434082
1.63096529
1.50119225
1.39811033
1.31622976
1.2511899
1.19952703
1.15848982
1.12589286
1.1000002
1.07943295
1.06309581
1.05011877
1.03981075
1.0316228
1.02511888
1.01995263
1.01584894
1.01258926
1.01
1.00794328
1.00630957
1.00501187
1.00398107
1.00316228
1.00251189
1.00199526
1.00158489
1.00125893
1.001
1.00079433
1.00063096
1.00050119
1.00039811
1.00031623
1.00025119
1.00019953
1.00015849

13.6
13.7
13.8
13.9
14

2.5119E-14
1.9953E-14
1.5849E-14
1.2589E-14
1E-14

0.05011241
0.03980674
0.03162026
0.02511728
0.01995162

-1.3000547 1.4811059 1.83038921 1.00012589


-1.4000434 1.1801092 1.82906437
1.0001
-1.5000345 0.93969394 1.82800908 1.00007943
-1.6000274 0.74788295 1.82716896 1.0000631
-1.7000218 0.59498741 1.82650046 1.00005012

Hoja de Calculo para la Extraccion de Quelatos meatlicos MLn

ATOS DE COMP. DE M CON L EN FASE ACUOSADATOS DE COMP. DE M CON OH EN FASE ACUOSA


MOHn
-10
1E-10
4.6
39810.7171
BETA 1
LOG BETA 1
BETA 1
-10
1E-10
-10
1E-10
BETA 2
LOG BETA 2
BETA 2
-10
1E-10
-10
1E-10
BETA 3
LOG BETA 3
BETA 3
-10
1E-10
-10
1E-10
BETA 4
LOG BETA 4
BETA 4
-10
1E-10
-10
1E-10
BETA 5
LOG BETA 5
BETA 5
-10
1E-10
-10
1E-10
BETA 6
LOG BETA 6
BETA 6

L libre
alpha M (L)LOG alpha M(L)
OH
2.9893E-17
1
0
1E-14
4.7362E-17
1
0
1.2589E-14
7.5035E-17
1
0
1.5849E-14
1.1886E-16
1
0
1.9953E-14
1.8827E-16
1
0
2.5119E-14
2.9815E-16
1
0
3.1623E-14
4.7208E-16
1
0
3.9811E-14
7.4727E-16
1
0
5.0119E-14
1.1825E-15
1
0
6.3096E-14
1.8705E-15
1
0
7.9433E-14
2.9573E-15
1
0
1E-13
4.6726E-15
1
0
1.2589E-13
7.377E-15
1
0
1.5849E-13
1.1635E-14
1
0
1.9953E-13
1.8329E-14
1
0
2.5119E-13
2.8831E-14
1
0
3.1623E-13
4.5264E-14
1
0
3.9811E-13
7.0899E-14
1
0
5.0119E-13
1.1073E-13
1
0
6.3096E-13
1.7235E-13
1
0
7.9433E-13
2.6712E-13
1
0
1E-12
4.1189E-13
1
0
1.2589E-12
6.3129E-13
1
0
1.5849E-12
9.6065E-13
1
0
1.9953E-12
1.4498E-12
1
0
2.5119E-12
2.1674E-12
1
0
3.1623E-12
3.2062E-12
1
0
3.9811E-12
4.6881E-12
1
0
5.0119E-12
6.7703E-12
1
0
6.3096E-12
9.6512E-12
1
0
7.9433E-12
1.3577E-11
1
0
1E-11
1.8852E-11
1
0
1.2589E-11

alpha M (L)LOGalphaM(L)
1
1.729E-10
1
2.1766E-10
1
2.7402E-10
1
3.4497E-10
1
4.3429E-10
1
5.4674E-10
1
6.8831E-10
1
8.6653E-10
1
1.0909E-09
1
1.3734E-09
1
1.729E-09
1.00000001 2.1766E-09
1.00000001 2.7402E-09
1.00000001 3.4497E-09
1.00000001 4.3429E-09
1.00000001 5.4674E-09
1.00000002 6.8831E-09
1.00000002 8.6653E-09
1.00000003 1.0909E-08
1.00000003 1.3734E-08
1.00000004 1.729E-08
1.00000005 2.1766E-08
1.00000006 2.7402E-08
1.00000008 3.4497E-08
1.0000001 4.3429E-08
1.00000013 5.4674E-08
1.00000016 6.8831E-08
1.0000002 8.6653E-08
1.00000025 1.0909E-07
1.00000032 1.3734E-07
1.0000004 1.729E-07
1.0000005 2.1766E-07

2.5846E-11
3.5014E-11
4.6915E-11
6.2243E-11
8.1861E-11
1.0685E-10
1.3857E-10
1.7872E-10
2.2946E-10
2.935E-10
3.7426E-10
4.7604E-10
6.0426E-10
7.6576E-10
9.6913E-10
1.2252E-09
1.5476E-09
1.9536E-09
2.4647E-09
3.1081E-09
3.9181E-09
4.9379E-09
6.2218E-09
7.8381E-09
9.8729E-09
1.2435E-08
1.5659E-08
1.9719E-08
2.4831E-08
3.1265E-08
3.9366E-08
4.9564E-08
6.2403E-08
7.8566E-08
9.8913E-08
1.2453E-07
1.5678E-07
1.9738E-07
2.4849E-07
3.1283E-07
3.9384E-07
4.9581E-07
6.2419E-07
7.858E-07
9.8926E-07
1.2454E-06
1.5678E-06
1.9737E-06
2.4847E-06
3.1279E-06
3.9376E-06
4.9568E-06

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
9.6433E-17
9.6433E-17
9.6433E-17
9.6433E-17
9.6433E-17
1.9287E-16
1.9287E-16

1.5849E-11
1.9953E-11
2.5119E-11
3.1623E-11
3.9811E-11
5.0119E-11
6.3096E-11
7.9433E-11
1E-10
1.2589E-10
1.5849E-10
1.9953E-10
2.5119E-10
3.1623E-10
3.9811E-10
5.0119E-10
6.3096E-10
7.9433E-10
1E-09
1.2589E-09
1.5849E-09
1.9953E-09
2.5119E-09
3.1623E-09
3.9811E-09
5.0119E-09
6.3096E-09
7.9433E-09
0.00000001
1.2589E-08
1.5849E-08
1.9953E-08
2.5119E-08
3.1623E-08
3.9811E-08
5.0119E-08
6.3096E-08
7.9433E-08
0.0000001
1.2589E-07
1.5849E-07
1.9953E-07
2.5119E-07
3.1623E-07
3.9811E-07
5.0119E-07
6.3096E-07
7.9433E-07
0.000001
1.2589E-06
1.5849E-06
1.9953E-06

1.00000063
1.00000079
1.000001
1.00000126
1.00000158
1.000002
1.00000251
1.00000316
1.00000398
1.00000501
1.00000631
1.00000794
1.00001
1.00001259
1.00001585
1.00001995
1.00002512
1.00003162
1.00003981
1.00005012
1.0000631
1.00007943
1.0001
1.00012589
1.00015849
1.00019953
1.00025119
1.00031623
1.00039811
1.00050119
1.00063096
1.00079433
1.001
1.00125893
1.00158489
1.00199526
1.00251189
1.00316228
1.00398107
1.00501187
1.00630957
1.00794328
1.01
1.01258925
1.01584893
1.01995262
1.02511886
1.03162278
1.03981072
1.05011872
1.06309573
1.07943282

2.7402E-07
3.4497E-07
4.3429E-07
5.4674E-07
6.8831E-07
8.6653E-07
1.0909E-06
1.3734E-06
1.729E-06
2.1766E-06
2.7402E-06
3.4497E-06
4.3429E-06
5.4674E-06
6.883E-06
8.6652E-06
1.0909E-05
1.3733E-05
1.7289E-05
2.1766E-05
2.7401E-05
3.4496E-05
4.3427E-05
5.4671E-05
6.8826E-05
8.6644E-05
0.00010908
0.00013731
0.00017286
0.00021761
0.00027393
0.00034484
0.00043408
0.0005464
0.00068777
0.00086567
0.00108953
0.00137119
0.00172553
0.00217119
0.0027316
0.00343609
0.00432137
0.00543331
0.00682913
0.00858
0.01077423
0.01352092
0.01695429
0.0212384
0.02657238
0.03319562

6.2397E-06
7.8545E-06
9.8869E-06
1.2445E-05
1.5664E-05
1.9714E-05
2.481E-05
3.1221E-05
3.9283E-05
4.9421E-05
6.2165E-05
7.8177E-05
9.8286E-05
0.00012353
0.00015518
0.00019484
0.00024446
0.00030647
0.00038379
0.00047998
0.0005993
0.00074674
0.00092813
0.00115002
0.00141961
0.00174444
0.00213192
0.00258867
0.00311954
0.0037266
0.00440796
0.00515691
0.00596149
0.00680481
0.00766626
0.00852333
0.00935401
0.01013891
0.01086295
0.01151621
0.01209391
0.01259581
0.01302519
0.01338769
0.01369035
0.01394068
0.01414615
0.01431373
0.0144497
0.01455956
0.01464802
0.01471905

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

2.893E-16
3.8573E-16
3.8573E-16
5.786E-16
6.7503E-16
8.6789E-16
1.0608E-15
1.3501E-15
1.7358E-15
2.1215E-15
2.7001E-15
3.3751E-15
4.243E-15
5.4002E-15
6.7503E-15
8.4861E-15
1.0608E-14
1.3308E-14
1.6683E-14
2.0829E-14
2.6037E-14
3.2401E-14
4.0309E-14
5.0049E-14
6.1717E-14
7.5893E-14
9.2768E-14
1.1273E-13
1.3587E-13
1.6239E-13
1.9229E-13
2.2507E-13
2.6046E-13
2.9759E-13
3.3549E-13
3.7339E-13
4.1003E-13
4.4475E-13
4.7696E-13
5.0598E-13
5.3173E-13
5.5401E-13
5.731E-13
5.893E-13
6.028E-13
6.1399E-13
6.2315E-13
6.3057E-13
6.3675E-13
6.4157E-13
6.4562E-13
6.488E-13

2.5119E-06
3.1623E-06
3.9811E-06
5.0119E-06
6.3096E-06
7.9433E-06
0.00001
1.2589E-05
1.5849E-05
1.9953E-05
2.5119E-05
3.1623E-05
3.9811E-05
5.0119E-05
6.3096E-05
7.9433E-05
0.0001
0.00012589
0.00015849
0.00019953
0.00025119
0.00031623
0.00039811
0.00050119
0.00063096
0.00079433
0.001
0.00125893
0.00158489
0.00199526
0.00251189
0.00316228
0.00398107
0.00501187
0.00630957
0.00794328
0.01
0.01258925
0.01584893
0.01995262
0.02511886
0.03162278
0.03981072
0.05011872
0.06309573
0.07943282
0.1
0.12589254
0.15848932
0.19952623
0.25118864
0.31622777

1.1
1.12589254
1.15848932
1.19952623
1.25118864
1.31622777
1.39810717
1.50118723
1.63095734
1.79432823
2
2.25892541
2.58489319
2.99526231
3.51188643
4.16227766
4.98107171
6.01187234
7.30957344
8.94328235
11
13.5892541
16.8489319
20.9526231
26.1188643
32.6227766
40.8107171
51.1187234
64.0957344
80.4328235
101
126.892541
159.489319
200.526231
252.188643
317.227766
399.107171
502.187234
631.957344
795.328235
1001
1259.92541
1585.89319
1996.26231
2512.88643
3163.27766
3982.07171
5012.87234
6310.57344
7944.28235
10001
12590.2541

0.04139269
0.05149694
0.06389203
0.07900975
0.09732279
0.11933105
0.14554046
0.17643486
0.2124426
0.25390189
0.30103
0.35390189
0.4124426
0.47643486
0.54554046
0.61933105
0.69732279
0.77900975
0.86389203
0.95149694
1.04139269
1.13319562
1.22657238
1.3212384
1.41695429
1.51352092
1.61077423
1.70858
1.80682913
1.90543331
2.00432137
2.10343609
2.2027316
2.30217119
2.40172553
2.50137119
2.60108953
2.70086567
2.80068777
2.9005464
3.00043408
3.10034484
3.20027393
3.30021761
3.40017286
3.50013731
3.60010908
3.70008664
3.80006883
3.90005467
4.00004343
4.1000345

0.01477597
0.0148215
0.01485787
0.01488688
0.01491

1
1
1
1
1

6.5131E-13
6.5333E-13
6.5487E-13
6.5622E-13
6.5729E-13

0.39810717
0.50118723
0.63095734
0.79432823
1

15849.9319
19953.6231
25119.8643
31623.7766
39811.7171

4.2000274
4.30002177
4.40001729
4.50001373
4.60001091

atlicos MLn
DATOS DE COMP. DE M CON X EN FASE ACUOSA
DATOS DE LA EXTRACCION MLn
MXn
-10
1E-10
LOG BETA 1
BETA 1
M + nL
MLnorg
-10
1E-10
LOG BETA 2
BETA 2
-10
1E-10
2
LOG BETA 3
BETA 3
n
-10
1E-10
20.85
LOG BETA 4
BETA 4
Log K extraccion
-10
1E-10
LOG BETA 5
BETA 5
-10
1E-10
LOG BETA 6
BETA 6
HX
-10
1E-10
LOG BETA 1
BETA 1
-10
1E-10
LOG BETA 2
BETA 2
-10
1E-10
LOG BETA 3
BETA 3
-10
1E-10
LOG BETA 4
BETA 4
Conc X

-10

alpha X (H)
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

X libre
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10

alphaM(X) LOGalphaM(X)
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05
1.00009091 3.9479E-05

pL libre
-16.52443146
-16.3245667
-16.1247369
-15.92495107
-15.72522055
-15.52555957
-15.32598599
-15.12652222
-14.92719636
-14.72804357
-14.5291078
-14.33044388
-14.13212009
-13.93422116
-13.73685187
-13.54014123
-13.34424719
-13.14936169
-12.95571599
-12.7635856
-12.5732943
-12.38521609
-12.19977386
-12.01743329
-11.83869044
-11.66405207
-11.49400875
-11.32900223
-11.16939069
-11.01541669
-10.86718368
-10.72464543

Log D" M
-12.198902
-11.799173
-11.399513
-10.999942
-10.600481
-10.201159
-9.8020115
-9.4030839
-9.0044322
-8.6061266
-8.2082551
-7.8109272
-7.4142797
-7.0184818
-6.6237432
-6.230322
-5.8385339
-5.4487629
-5.0614715
-4.6772107
-4.2966281
-3.9204717
-3.5495872
-3.1849061
-2.8274204
-2.4781437
-2.138057
-1.808044
-1.488821
-1.180873
-0.884407
-0.5993306

%E MLn org
1.8977E-11
4.7637E-11
1.1957E-10
3.0004E-10
7.5273E-10
1.8878E-09
4.7327E-09
1.1859E-08
2.9695E-08
7.4301E-08
1.8572E-07
4.6365E-07
1.1557E-06
2.875E-06
7.1347E-06
1.7652E-05
4.351E-05
0.00010675
0.0002604
0.00063082
0.00151526
0.00360275
0.00846247
0.01959431
0.04461769
0.09966543
0.21782973
0.464574
0.96403594
1.93973026
3.76735599
7.01764253

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10

1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091

3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05

-10.5876108
-10.45576269
-10.32868745
-10.20590924
-10.08692398
-9.971228752
-9.858344321
-9.747830278
-9.639293405
-9.532390673
-9.426828364
-9.32235873
-9.218775299
-9.115907658
-9.013616241
-8.911787451
-8.810329287
-8.709167531
-8.608242501
-8.507506324
-8.406920675
-8.306454926
-8.206084625
-8.105790277
-8.005556347
-7.905370468
-7.805222796
-7.705105504
-7.605012367
-7.504938441
-7.404879797
-7.304833317
-7.204796531
-7.10476748
-7.004744621
-6.904726736
-6.804712874
-6.704702296
-6.604694439
-6.504688886
-6.40468534
-6.304683613
-6.204683613
-6.10468534
-6.004688886
-5.904694439
-5.804702296
-5.704712874
-5.604726736
-5.504744621
-5.40476748
-5.304796531

-0.3252614
-0.0615652
0.19258518
0.43814149
0.67611187
0.90750215
1.13327079
1.35429859
1.57137198
1.785177
1.99630105
2.20523961
2.41240558
2.61813974
2.82272116
3.02637695
3.22929104
3.43161173
3.63345823
3.83492611
4.03609177
4.23701618
4.43774785
4.6383253
4.83877901
5.03913295
5.23940586
5.43961221
5.63976294
5.83986605
6.03992702
6.23994908
6.43993342
6.63987921
6.83978358
7.03964146
7.23944534
7.43918486
7.63884627
7.83841175
8.03785848
8.23715751
8.43627231
8.63515702
8.83375424
9.03199242
9.22978267
9.42701506
9.62355427
9.81923476
10.0138555
10.2071747

12.4235881
20.6569024
31.8531418
45.1375477
58.7304235
70.7987146
80.3051981
87.1514332
91.7907118
94.8169236
96.747499
97.9643312
98.7267664
99.203354
99.501132
99.6872901
99.8037839
99.8767657
99.9225388
99.9512762
99.9693342
99.9806902
99.987836
99.9923349
99.9951685
99.996954
99.9980793
99.9987887
99.999236
99.999518
99.9996959
99.9998082
99.999879
99.9999236
99.9999518
99.9999696
99.9999808
99.9999879
99.9999923
99.9999952
99.9999969
99.9999981
99.9999988
99.9999992
99.9999995
99.9999997
99.9999998
99.9999999
99.9999999
99.9999999
100
100

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10

1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091

3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05

-5.204833317
-5.104879797
-5.004938441
-4.905012367
-4.805105504
-4.705222796
-4.605370468
-4.505556347
-4.405790277
-4.306084625
-4.206454926
-4.106920675
-4.007506324
-3.908242501
-3.809167531
-3.710329287
-3.611787451
-3.513616241
-3.415907658
-3.318775299
-3.22235873
-3.126828364
-3.032390673
-2.939293405
-2.847830278
-2.758344321
-2.671228752
-2.586923983
-2.505909242
-2.428687452
-2.355762693
-2.287610803
-2.224645434
-2.16718368
-2.11541669
-2.069390687
-2.029002234
-1.994008748
-1.964052069
-1.938690436
-1.91743329
-1.89977386
-1.88521609
-1.873294304
-1.863585601
-1.855715987
-1.849361691
-1.844247191
-1.840141234
-1.836851865
-1.834221155
-1.832120092

10.3989048
10.5887084
10.776197
10.9609326
11.1424346
11.3201934
11.4936904
11.6624261
11.8259526
11.9839069
12.1360404
12.2822393
12.4225295
12.557067
12.6861132
12.8100009
12.9290944
13.0437512
13.1542872
13.260948
13.3638863
13.4631447
13.5586439
13.6501729
13.7373836
13.8197892
13.8967673
13.9675713
14.0313518
14.0871913
14.1341529
14.171342
14.1979773
14.2134613
14.2174409
14.2098473
14.1909059
14.1611168
14.121208
14.0720727
14.0146993
13.9501074
13.8792939
13.8031938
13.7226559
13.6384307
13.5511675
13.461419
13.3696487
13.2762416
13.1815143
13.0857253

100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100

1
1
1
1
1

-10
-10
-10
-10
-10

1.00009091
1.00009091
1.00009091
1.00009091
1.00009091

3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05

-1.830443884
-1.829107799
-1.828043571
-1.827196363
-1.826522222

12.9890848
12.8917626
12.7938956
12.6955935
12.5969446

100
100
100
100
100

Diagrama de reparto de Fe f(pH)

100
90
80
70
60
50
40
30
20
10
0
0

10

12

14

Diagrama de reparto Fe-EDTA


100

90

80

70

60

50

40

30

20

10

0
0

10

12

14

Hoja de Calculo
DATOS PARA EL AGENTE EXTRACTANTE (L)
Log Kd
H2OX
pKa 1
pKa 2

2.6 Kd

398.107171

5 Ka 1
9.7 Ka 2

0.00001
1.9953E-10

Oxina
Volumen Forg
Volumen Facuo
r
n*

pH

H+
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
1.1
1.2
1.3
1.4
1.5
1.6
1.7
1.8
1.9
2
2.1
2.2
2.3
2.4
2.5
2.6
2.7
2.8
2.9
3
3.1

1
0.79432823
0.63095734
0.50118723
0.39810717
0.31622777
0.25118864
0.19952623
0.15848932
0.12589254
0.1
0.07943282
0.06309573
0.05011872
0.03981072
0.03162278
0.02511886
0.01995262
0.01584893
0.01258925
0.01
0.00794328
0.00630957
0.00501187
0.00398107
0.00316228
0.00251189
0.00199526
0.00158489
0.00125893
0.001
0.00079433

D
0.00398103
0.00501181
0.00630947
0.00794312
0.00999975
0.01258886
0.0158483
0.01995162
0.02511728
0.03162026
0.03980674
0.05011241
0.06308574
0.07941698
0.09997489
0.12585274
0.15842625
0.19942628
0.25103025
0.31597678
0.39770946
0.50055707
0.62995893
0.7927465
0.99749441
1.25495689
1.57860864
1.98531218
2.49613687
3.13735675
3.94165515
4.94956104

log D
-2.4000043
-2.3000055
-2.2000069
-2.1000087
-2.0000109
-1.9000137
-1.8000173
-1.7000218
-1.6000274
-1.5000345
-1.4000434
-1.3000547
-1.2000688
-1.1000866
-1.0001091
-0.9001373
-0.8001729
-0.7002176
-0.6002739
-0.5003448
-0.4004341
-0.3005464
-0.2006878
-0.1008657
-0.0010895
0.09862881
0.19827447
0.29782881
0.3972684
0.4965639
0.59567863
0.69456668

%E (L)
0.11928849
0.15012855
0.1889266
0.23772723
0.2990952
0.37624473
0.47319921
0.59498741
0.74788295
0.93969394
1.1801092
1.4811059
1.85741909
2.32706675
2.91191122
3.63821836
4.53714653
5.64505665
7.00348186
8.65853455
10.659472
13.0561132
15.8948391
19.2130674
23.0324194
27.3512971
32.1381777
37.3274018
42.8192749
48.4856593
54.1809126
59.7564187

0.05
3
10
0.3
0.15

pL
1.82442711
1.82456123
1.82473001
1.82494241
1.82520964
1.82554583
1.8259687
1.82650046
1.82716896
1.82800908
1.82906437
1.83038921
1.83205127
1.83413451
1.83674279
1.84000392
1.84407433
1.84914408
1.85544205
1.86324077
1.87286023
1.88466969
1.89908609
1.91656762
1.93760091
1.96268088
1.99228322
2.02683104
2.06665908
2.11198059
2.16286231
2.21921212

DATOS DE COMP. DE M CON L EN


MLn
LOG BETA 1
LOG BETA 2
LOG BETA 3
LOG BETA 4
LOG BETA 5
LOG BETA 6

alpha L (H)
5.0119E+14
3.1623E+14
1.9953E+14
1.259E+14
7.9435E+13
5.012E+13
3.1624E+13
1.9954E+13
1.259E+13
7.9439E+12
5.0124E+12
3.1627E+12
1.9956E+12
1.2592E+12
7.9453E+11
5.0135E+11
3.1635E+11
1.9963E+11
1.2597E+11
7.9496E+10
5.0169E+10
3.1663E+10
1.9984E+10
1.2614E+10
7963234971
5027721269
3174866915
2005262316
1266868695
800637809
506199107
320208839

3.2
3.3
3.4
3.5
3.6
3.7
3.8
3.9
4
4.1
4.2
4.3
4.4
4.5
4.6
4.7
4.8
4.9
5
5.1
5.2
5.3
5.4
5.5
5.6
5.7
5.8
5.9
6
6.1
6.2
6.3
6.4
6.5
6.6
6.7
6.8
6.9
7
7.1
7.2
7.3
7.4
7.5
7.6
7.7
7.8
7.9
8
8.1
8.2
8.3

0.00063096
0.00050119
0.00039811
0.00031623
0.00025119
0.00019953
0.00015849
0.00012589
0.0001
7.9433E-05
6.3096E-05
5.0119E-05
3.9811E-05
3.1623E-05
2.5119E-05
1.9953E-05
1.5849E-05
1.2589E-05
0.00001
7.9433E-06
6.3096E-06
5.0119E-06
3.9811E-06
3.1623E-06
2.5119E-06
1.9953E-06
1.5849E-06
1.2589E-06
0.000001
7.9433E-07
6.3096E-07
5.0119E-07
3.9811E-07
3.1623E-07
2.5119E-07
1.9953E-07
1.5849E-07
1.2589E-07
0.0000001
7.9433E-08
6.3096E-08
5.0119E-08
3.9811E-08
3.1623E-08
2.5119E-08
1.9953E-08
1.5849E-08
1.2589E-08
0.00000001
7.9433E-09
6.3096E-09
5.0119E-09

6.21113358
7.78789338
9.7549662
12.2033501
15.2421313
19.000349
23.6280343
29.2957303
36.1915544
44.5146472
54.4637798
66.2201199
79.9239187
95.6463263
113.359665
132.911845
154.012256
176.236176
199.051599
221.866652
244.089432
265.187849
284.737042
302.446201
318.162973
331.859341
343.606028
353.542743
361.849975
368.725633
374.367775
378.963153
382.680587
385.667939
388.051517
389.936968
391.410968
392.543205
393.388374
393.98796
394.37174
394.558924
394.558924
394.37174
393.98796
393.388374
392.543205
391.410968
389.936968
388.051517
385.667939
382.680587

0.79317087
0.89142
0.98922577
1.08647907
1.1830457
1.27876158
1.37342759
1.46680433
1.55860724
1.64850294
1.73610778
1.82098996
1.90267677
1.98066829
2.05445855
2.12356369
2.18755528
2.24609506
2.29896567
2.34609203
2.38754898
2.42355362
2.45444397
2.48064813
2.50264964
2.52095405
2.53606077
2.54844193
2.55852855
2.56670333
2.57329846
2.57859699
2.58283643
2.58621354
2.58888939
2.59099441
2.59263299
2.59388746
2.59482152
2.59548295
2.59590579
2.59611187
2.59611187
2.59590579
2.59548295
2.59482152
2.59388746
2.59263299
2.59099441
2.58888939
2.58621354
2.58283643

65.0757516
70.0272873
74.5319602
78.5453996
82.0551819
85.0748601
87.6366311
89.7841588
91.5664951
93.0334921
94.2326993
95.2075229
95.9963448
96.6323047
97.1435019
97.5534302
97.881521
98.1437086
98.3529736
98.5198341
98.6527782
98.758633
98.8428753
98.90989
98.9631815
99.0055471
99.0392173
99.065969
99.0872164
99.1040847
99.117468
99.1280764
99.1364733
99.1431048
99.1483234
99.1524065
99.1555715
99.1579866
99.1597805
99.1610484
99.161858
99.1622523
99.1622523
99.161858
99.1610484
99.1597805
99.1579866
99.1555715
99.1524065
99.1483234
99.1431048
99.1364733

2.28078167
2.34718269
2.41791322
2.49238831
2.56996968
2.64999033
2.73177191
2.81463461
2.89790064
2.98089361
3.06293614
3.14334869
3.22145207
3.29657595
3.3680748
3.43535114
3.49788457
3.55526259
3.60720817
3.65359835
3.69446965
3.73000855
3.76052859
3.78643841
3.80820598
3.82632451
3.84128357
3.85354743
3.86354091
3.87164177
3.87817826
3.8834303
3.88763296
3.89098102
3.89363401
3.89572115
3.89734586
3.89858976
3.89951596
3.90017184
3.90059113
3.90079548
3.90079548
3.90059113
3.90017184
3.89951596
3.89858976
3.89734586
3.89572115
3.89363401
3.89098102
3.88763296

202688510
128404429
81428086.8
51703617.6
32881703
20952624.1
13383583.4
8574240.69
5513060.57
3560385.83
2311491.08
1510115.05
993855.466
659677.553
442121.307
299527.231
205326.365
142529.558
100238.447
71434.4937
51576.3998
37709.1184
27896.9055
20861.8043
15752.5318
11996.2623
9203.20776
7104.90168
5514.05957
4298.29947
3362.80389
2638.77897
2075.69514
1636.01192
1291.54819
1020.95262
807.917489
639.900627
507.199106
402.269448
319.223028
253.447569
201.32056
159.990506
127.208769
101.199526
80.558716
64.1751673
51.1688421
40.8423398
32.6427292
26.1314536

8.4
8.5
8.6
8.7
8.8
8.9
9
9.1
9.2
9.3
9.4
9.5
9.6
9.7
9.8
9.9
10
10.1
10.2
10.3
10.4
10.5
10.6
10.7
10.8
10.9
11
11.1
11.2
11.3
11.4
11.5
11.6
11.7
11.8
11.9
12
12.1
12.2
12.3
12.4
12.5
12.6
12.7
12.8
12.9
13
13.1
13.2
13.3
13.4
13.5

3.9811E-09
3.1623E-09
2.5119E-09
1.9953E-09
1.5849E-09
1.2589E-09
1E-09
7.9433E-10
6.3096E-10
5.0119E-10
3.9811E-10
3.1623E-10
2.5119E-10
1.9953E-10
1.5849E-10
1.2589E-10
1E-10
7.9433E-11
6.3096E-11
5.0119E-11
3.9811E-11
3.1623E-11
2.5119E-11
1.9953E-11
1.5849E-11
1.2589E-11
1E-11
7.9433E-12
6.3096E-12
5.0119E-12
3.9811E-12
3.1623E-12
2.5119E-12
1.9953E-12
1.5849E-12
1.2589E-12
1E-12
7.9433E-13
6.3096E-13
5.0119E-13
3.9811E-13
3.1623E-13
2.5119E-13
1.9953E-13
1.5849E-13
1.2589E-13
1E-13
7.9433E-14
6.3096E-14
5.0119E-14
3.9811E-14
3.1623E-14

378.963153
374.367775
368.725633
361.849975
353.542743
343.606028
331.859341
318.162973
302.446201
284.737042
265.187849
244.089432
221.866652
199.051599
176.236176
154.012256
132.911845
113.359665
95.6463263
79.9239187
66.2201199
54.4637798
44.5146472
36.1915544
29.2957303
23.6280343
19.000349
15.2421313
12.2033501
9.7549662
7.78789338
6.21113358
4.94956104
3.94165515
3.13735675
2.49613687
1.98531218
1.57860864
1.25495689
0.99749441
0.7927465
0.62995893
0.50055707
0.39770946
0.31597678
0.25103025
0.19942628
0.15842625
0.12585274
0.09997489
0.07941698
0.06308574

2.57859699
2.57329846
2.56670333
2.55852855
2.54844193
2.53606077
2.52095405
2.50264964
2.48064813
2.45444397
2.42355362
2.38754898
2.34609203
2.29896567
2.24609506
2.18755528
2.12356369
2.05445855
1.98066829
1.90267677
1.82098996
1.73610778
1.64850294
1.55860724
1.46680433
1.37342759
1.27876158
1.1830457
1.08647907
0.98922577
0.89142
0.79317087
0.69456668
0.59567863
0.4965639
0.3972684
0.29782881
0.19827447
0.09862881
-0.0010895
-0.1008657
-0.2006878
-0.3005464
-0.4004341
-0.5003448
-0.6002739
-0.7002176
-0.8001729
-0.9001373
-1.0001091
-1.1000866
-1.2000688

99.1280764
99.117468
99.1040847
99.0872164
99.065969
99.0392173
99.0055471
98.9631815
98.90989
98.8428753
98.758633
98.6527782
98.5198341
98.3529736
98.1437086
97.881521
97.5534302
97.1435019
96.6323047
95.9963448
95.2075229
94.2326993
93.0334921
91.5664951
89.7841588
87.6366311
85.0748601
82.0551819
78.5453996
74.5319602
70.0272873
65.0757516
59.7564187
54.1809126
48.4856593
42.8192749
37.3274018
32.1381777
27.3512971
23.0324194
19.2130674
15.8948391
13.0561132
10.659472
8.65853455
7.00348186
5.64505665
4.53714653
3.63821836
2.91191122
2.32706675
1.85741909

3.8834303
3.87817826
3.87164177
3.86354091
3.85354743
3.84128357
3.82632451
3.80820598
3.78643841
3.76052859
3.73000855
3.69446965
3.65359835
3.60720817
3.55526259
3.49788457
3.43535114
3.3680748
3.29657595
3.22145207
3.14334869
3.06293614
2.98089361
2.89790064
2.81463461
2.73177191
2.64999033
2.56996968
2.49238831
2.41791322
2.34718269
2.28078167
2.21921212
2.16286231
2.11198059
2.06665908
2.02683104
1.99228322
1.96268088
1.93760091
1.91656762
1.89908609
1.88466969
1.87286023
1.86324077
1.85544205
1.84914408
1.84407433
1.84000392
1.83674279
1.83413451
1.83205127

20.9605664
16.8539438
13.5924164
11.0019953
8.94454127
7.31036777
6.01237352
4.98138793
4.16247719
3.51201232
2.99534175
2.58494331
2.25895703
2.00001995
1.79434082
1.63096529
1.50119225
1.39811033
1.31622976
1.2511899
1.19952703
1.15848982
1.12589286
1.1000002
1.07943295
1.06309581
1.05011877
1.03981075
1.0316228
1.02511888
1.01995263
1.01584894
1.01258926
1.01
1.00794328
1.00630957
1.00501187
1.00398107
1.00316228
1.00251189
1.00199526
1.00158489
1.00125893
1.001
1.00079433
1.00063096
1.00050119
1.00039811
1.00031623
1.00025119
1.00019953
1.00015849

13.6
13.7
13.8
13.9
14

2.5119E-14
1.9953E-14
1.5849E-14
1.2589E-14
1E-14

0.05011241
0.03980674
0.03162026
0.02511728
0.01995162

-1.3000547 1.4811059 1.83038921 1.00012589


-1.4000434 1.1801092 1.82906437
1.0001
-1.5000345 0.93969394 1.82800908 1.00007943
-1.6000274 0.74788295 1.82716896 1.0000631
-1.7000218 0.59498741 1.82650046 1.00005012

Hoja de Calculo para la Extraccion de Quelatos meatlicos MLn

ATOS DE COMP. DE M CON L EN FASE ACUOSADATOS DE COMP. DE M CON OH EN FASE ACUOSA


MOHn
-10 BETA 1
1E-10 LOG BETA 1
11 BETA 1
1E+11
-10 BETA 2
1E-10 LOG BETA 2
21.7 BETA 2
5.0119E+21
-10 BETA 3
1E-10 LOG BETA 3
-10 BETA 3
1E-10
-10 BETA 4
1E-10 LOG BETA 4
-10 BETA 4
1E-10
-10 BETA 5
1E-10 LOG BETA 5
-10 BETA 5
1E-10
-10 BETA 6
1E-10 LOG BETA 6
-10 BETA 6
1E-10

L libre
alpha M (L) LOG alpha M(L)
OH
2.9893E-17
1
0
1E-14
4.7362E-17
1
0 1.2589E-14
7.5035E-17
1
0 1.5849E-14
1.1886E-16
1
0 1.9953E-14
1.8827E-16
1
0 2.5119E-14
2.9815E-16
1
0 3.1623E-14
4.7208E-16
1
0 3.9811E-14
7.4727E-16
1
0 5.0119E-14
1.1825E-15
1
0 6.3096E-14
1.8705E-15
1
0 7.9433E-14
2.9573E-15
1
0
1E-13
4.6726E-15
1
0 1.2589E-13
7.377E-15
1
0 1.5849E-13
1.1635E-14
1
0 1.9953E-13
1.8329E-14
1
0 2.5119E-13
2.8831E-14
1
0 3.1623E-13
4.5264E-14
1
0 3.9811E-13
7.0899E-14
1
0 5.0119E-13
1.1073E-13
1
0 6.3096E-13
1.7235E-13
1
0 7.9433E-13
2.6712E-13
1
0
1E-12
4.1189E-13
1
0 1.2589E-12
6.3129E-13
1
0 1.5849E-12
9.6065E-13
1
0 1.9953E-12
1.4498E-12
1
0 2.5119E-12
2.1674E-12
1
0 3.1623E-12
3.2062E-12
1
0 3.9811E-12
4.6881E-12
1
0 5.0119E-12
6.7703E-12
1
0 6.3096E-12
9.6512E-12
1
0 7.9433E-12
1.3577E-11
1
0
1E-11
1.8852E-11
1
0 1.2589E-11

alpha M (L)
1.0010005
1.00125972
1.00158615
1.00199726
1.00251505
1.00316729
1.00398901
1.00502446
1.00632953
1.00797491
1.01005012
1.01266869
1.01597482
1.02015215
1.02543509
1.03212396
1.04060505
1.05137765
1.065091
1.0825951
1.10501187
1.13383582
1.17107857
1.21947885
1.28281142
1.36634649
1.47753999
1.62707977
1.83048358
2.110556
2.50118723
3.05325365

LOGalphaM(L)
0.00043429
0.00054675
0.00068831
0.00086653
0.0010909
0.00137336
0.00172896
0.00217663
0.00274022
0.00344972
0.00434292
0.00546738
0.00688295
0.00866495
0.01090818
0.01373186
0.01728593
0.02175874
0.02738671
0.03446606
0.04336694
0.05455017
0.06858603
0.08617427
0.10816282
0.13556085
0.16953925
0.21140885
0.26256584
0.32439688
0.3981462
0.48476288

2.5846E-11
3.5014E-11
4.6915E-11
6.2243E-11
8.1861E-11
1.0685E-10
1.3857E-10
1.7872E-10
2.2946E-10
2.935E-10
3.7426E-10
4.7604E-10
6.0426E-10
7.6576E-10
9.6913E-10
1.2252E-09
1.5476E-09
1.9536E-09
2.4647E-09
3.1081E-09
3.9181E-09
4.9379E-09
6.2218E-09
7.8381E-09
9.8729E-09
1.2435E-08
1.5659E-08
1.9719E-08
2.4831E-08
3.1265E-08
3.9366E-08
4.9564E-08
6.2403E-08
7.8566E-08
9.8913E-08
1.2453E-07
1.5678E-07
1.9738E-07
2.4849E-07
3.1283E-07
3.9384E-07
4.9581E-07
6.2419E-07
7.858E-07
9.8926E-07
1.2454E-06
1.5678E-06
1.9737E-06
2.4847E-06
3.1279E-06
3.9376E-06
4.9568E-06

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
9.6433E-17
9.6433E-17
9.6433E-17
9.6433E-17
9.6433E-17
1.9287E-16
1.9287E-16

1.5849E-11
1.9953E-11
2.5119E-11
3.1623E-11
3.9811E-11
5.0119E-11
6.3096E-11
7.9433E-11
1E-10
1.2589E-10
1.5849E-10
1.9953E-10
2.5119E-10
3.1623E-10
3.9811E-10
5.0119E-10
6.3096E-10
7.9433E-10
1E-09
1.2589E-09
1.5849E-09
1.9953E-09
2.5119E-09
3.1623E-09
3.9811E-09
5.0119E-09
6.3096E-09
7.9433E-09
0.00000001
1.2589E-08
1.5849E-08
1.9953E-08
2.5119E-08
3.1623E-08
3.9811E-08
5.0119E-08
6.3096E-08
7.9433E-08
0.0000001
1.2589E-07
1.5849E-07
1.9953E-07
2.5119E-07
3.1623E-07
3.9811E-07
5.0119E-07
6.3096E-07
7.9433E-07
0.000001
1.2589E-06
1.5849E-06
1.9953E-06

3.8438186
4.99052463
6.67416409
9.17415
12.9243541
18.6011265
27.2621966
40.5660589
61.1187234
93.0220776
142.741473
220.478855
342.34663
533.81001
835.138952
1310.04414
2059.35805
3242.71048
5112.87234
8070.17489
12748.7434
20153.1494
31874.9652
50435.9511
79831.9306
126394.728
200158.189
317023.094
502188.234
795588.16
1260511.3
1997258.58
3164790.55
5015035.61
7947264.42
12594267
19958933.7
31630720.9
50128724.4
79445413.7
125908391
199546185
316252886
501218857
794368046
1258975532
1995325412
3162357094
5011972337
7943408241
1.2589E+10
1.9953E+10

0.58476288
0.6981462
0.82439688
0.96256584
1.11140885
1.26953925
1.43556085
1.60816282
1.78617427
1.96858603
2.15455017
2.34336694
2.53446606
2.72738671
2.92175874
3.11728593
3.31373186
3.51090818
3.70866495
3.90688295
4.10546738
4.30434292
4.50344972
4.70274022
4.90217663
5.10172896
5.30137336
5.5010909
5.70086653
5.90068831
6.10054675
6.30043429
6.50034497
6.70027402
6.90021766
7.1001729
7.30013734
7.50010909
7.70008665
7.90006883
8.10005467
8.30004343
8.5000345
8.7000274
8.90002177
9.10001729
9.30001373
9.50001091
9.70000867
9.90000688
10.1000055
10.3000043

6.2397E-06
7.8545E-06
9.8869E-06
1.2445E-05
1.5664E-05
1.9714E-05
2.481E-05
3.1221E-05
3.9283E-05
4.9421E-05
6.2165E-05
7.8177E-05
9.8286E-05
0.00012353
0.00015518
0.00019484
0.00024446
0.00030647
0.00038379
0.00047998
0.0005993
0.00074674
0.00092813
0.00115002
0.00141961
0.00174444
0.00213192
0.00258867
0.00311954
0.0037266
0.00440796
0.00515691
0.00596149
0.00680481
0.00766626
0.00852333
0.00935401
0.01013891
0.01086295
0.01151621
0.01209391
0.01259581
0.01302519
0.01338769
0.01369035
0.01394068
0.01414615
0.01431373
0.0144497
0.01455956
0.01464802
0.01471905

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

2.893E-16
3.8573E-16
3.8573E-16
5.786E-16
6.7503E-16
8.6789E-16
1.0608E-15
1.3501E-15
1.7358E-15
2.1215E-15
2.7001E-15
3.3751E-15
4.243E-15
5.4002E-15
6.7503E-15
8.4861E-15
1.0608E-14
1.3308E-14
1.6683E-14
2.0829E-14
2.6037E-14
3.2401E-14
4.0309E-14
5.0049E-14
6.1717E-14
7.5893E-14
9.2768E-14
1.1273E-13
1.3587E-13
1.6239E-13
1.9229E-13
2.2507E-13
2.6046E-13
2.9759E-13
3.3549E-13
3.7339E-13
4.1003E-13
4.4475E-13
4.7696E-13
5.0598E-13
5.3173E-13
5.5401E-13
5.731E-13
5.893E-13
6.028E-13
6.1399E-13
6.2315E-13
6.3057E-13
6.3675E-13
6.4157E-13
6.4562E-13
6.488E-13

2.5119E-06
3.1623E-06
3.9811E-06
5.0119E-06
6.3096E-06
7.9433E-06
0.00001
1.2589E-05
1.5849E-05
1.9953E-05
2.5119E-05
3.1623E-05
3.9811E-05
5.0119E-05
6.3096E-05
7.9433E-05
0.0001
0.00012589
0.00015849
0.00019953
0.00025119
0.00031623
0.00039811
0.00050119
0.00063096
0.00079433
0.001
0.00125893
0.00158489
0.00199526
0.00251189
0.00316228
0.00398107
0.00501187
0.00630957
0.00794328
0.01
0.01258925
0.01584893
0.01995262
0.02511886
0.03162278
0.03981072
0.05011872
0.06309573
0.07943282
0.1
0.12589254
0.15848932
0.19952623
0.25118864
0.31622777

3.1623E+10
5.0119E+10
7.9433E+10
1.2589E+11
1.9953E+11
3.1623E+11
5.0119E+11
7.9433E+11
1.2589E+12
1.9953E+12
3.1623E+12
5.0119E+12
7.9433E+12
1.2589E+13
1.9953E+13
3.1623E+13
5.0119E+13
7.9433E+13
1.2589E+14
1.9953E+14
3.1623E+14
5.0119E+14
7.9433E+14
1.2589E+15
1.9953E+15
3.1623E+15
5.0119E+15
7.9433E+15
1.2589E+16
1.9953E+16
3.1623E+16
5.0119E+16
7.9433E+16
1.2589E+17
1.9953E+17
3.1623E+17
5.0119E+17
7.9433E+17
1.2589E+18
1.9953E+18
3.1623E+18
5.0119E+18
7.9433E+18
1.2589E+19
1.9953E+19
3.1623E+19
5.0119E+19
7.9433E+19
1.2589E+20
1.9953E+20
3.1623E+20
5.0119E+20

10.5000034
10.7000027
10.9000022
11.1000017
11.3000014
11.5000011
11.7000009
11.9000007
12.1000005
12.3000004
12.5000003
12.7000003
12.9000002
13.1000002
13.3000001
13.5000001
13.7000001
13.9000001
14.1000001
14.3
14.5
14.7
14.9
15.1
15.3
15.5
15.7
15.9
16.1
16.3
16.5
16.7
16.9
17.1
17.3
17.5
17.7
17.9
18.1
18.3
18.5
18.7
18.9
19.1
19.3
19.5
19.7
19.9
20.1
20.3
20.5
20.7

0.01477597
0.0148215
0.01485787
0.01488688
0.01491

1
1
1
1
1

6.5131E-13
6.5333E-13
6.5487E-13
6.5622E-13
6.5729E-13

0.39810717
0.50118723
0.63095734
0.79432823
1

7.9433E+20
1.2589E+21
1.9953E+21
3.1623E+21
5.0119E+21

20.9
21.1
21.3
21.5
21.7

os MLn
DATOS DE COMP. DE M CON X EN FASE ACUOSA DATOS DE LA EXTRACCION MLn
MXn
LOG BETA 1
25.1 BETA 1
1.2589E+25 M + nL
MLnorg
LOG BETA 2
-10 BETA 2
1E-10
LOG BETA 3
-10 BETA 3
1E-10 n
3
LOG BETA 4
-10 BETA 4
1E-10 Log K extraccion
42.3
LOG BETA 5
-10 BETA 5
1E-10
LOG BETA 6
-10 BETA 6
1E-10
HX
LOG BETA 1
-10 BETA 1
1E-10
LOG BETA 2
-10 BETA 2
1E-10
LOG BETA 3
-10 BETA 3
1E-10
LOG BETA 4
-10 BETA 4
1E-10
Conc X

0.01

alpha X (H) X libre


1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01

alphaM(X) LOGalphaM(X)
pL libre
Log D" M
1.2589E+23
23.1 -16.524431 -30.373294
1.2589E+23
23.1 -16.324567
-29.7737
1.2589E+23
23.1 -16.124737 -29.174211
1.2589E+23
23.1 -15.924951 -28.574853
1.2589E+23
23.1 -15.725221 -27.975662
1.2589E+23
23.1
-15.52556 -27.376679
1.2589E+23
23.1 -15.325986 -26.777958
1.2589E+23
23.1 -15.126522 -26.179567
1.2589E+23
23.1 -14.927196 -25.581589
1.2589E+23
23.1 -14.728044 -24.984131
1.2589E+23
23.1 -14.529108 -24.387323
1.2589E+23
23.1 -14.330444 -23.791332
1.2589E+23
23.1
-14.13212
-23.19636
1.2589E+23
23.1 -13.934221 -22.602663
1.2589E+23
23.1 -13.736852 -22.010556
1.2589E+23
23.1 -13.540141 -21.420424
1.2589E+23
23.1 -13.344247 -20.832742
1.2589E+23
23.1 -13.149362 -20.248085
1.2589E+23
23.1 -12.955716 -19.667148
1.2589E+23
23.1 -12.763586 -19.090757
1.2589E+23
23.1 -12.573294 -18.519883
1.2589E+23
23.1 -12.385216 -17.955648
1.2589E+23
23.1 -12.199774 -17.399322
1.2589E+23
23.1 -12.017433
-16.8523
1.2589E+23
23.1
-11.83869 -16.316071
1.2589E+23
23.1 -11.664052 -15.792156
1.2589E+23
23.1 -11.494009 -15.282026
1.2589E+23
23.1 -11.329002 -14.787007
1.2589E+23
23.1 -11.169391 -14.308172
1.2589E+23
23.1 -11.015417
-13.84625
1.2589E+23
23.1 -10.867184 -13.401551
1.2589E+23
23.1 -10.724645 -12.973936

%E MLn org
1.2701E-29
5.0515E-29
2.0087E-28
7.9849E-28
3.1729E-27
1.2602E-26
5.0022E-26
1.9841E-25
7.862E-25
3.1116E-24
1.2297E-23
4.8505E-23
1.9088E-22
7.4896E-22
2.928E-21
1.1395E-20
4.4094E-20
1.6945E-19
6.4561E-19
2.4342E-18
9.0623E-18
3.3226E-17
1.1962E-16
4.2152E-16
1.4489E-15
4.8413E-15
1.5671E-14
4.8991E-14
1.4755E-13
4.2744E-13
1.1901E-12
3.1856E-12

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01

1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23

23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1

-10.587611
-10.455763
-10.328687
-10.205909
-10.086924
-9.9712288
-9.8583443
-9.7478303
-9.6392934
-9.5323907
-9.4268284
-9.3223587
-9.2187753
-9.1159077
-9.0136162
-8.9117875
-8.8103293
-8.7091675
-8.6082425
-8.5075063
-8.4069207
-8.3064549
-8.2060846
-8.1057903
-8.0055563
-7.9053705
-7.8052228
-7.7051055
-7.6050124
-7.5049384
-7.4048798
-7.3048333
-7.2047965
-7.1047675
-7.0047446
-6.9047267
-6.8047129
-6.7047023
-6.6046944
-6.5046889
-6.4046853
-6.3046836
-6.2046836
-6.1046853
-6.0046889
-5.9046944
-5.8047023
-5.7047129
-5.6047267
-5.5047446
-5.4047675
-5.3047965

-12.562832
-12.167288
-11.786062
-11.417728
-11.060772
-10.713686
-10.375033
-10.043491
-9.7178802
-9.397172
-9.0804851
-8.7670762
-8.4563259
-8.147723
-7.8408487
-7.5353624
-7.2309879
-6.9275026
-6.6247275
-6.322519
-6.020762
-5.7193648
-5.4182539
-5.1173708
-4.816669
-4.5161114
-4.2156684
-3.9153165
-3.6150371
-3.3148153
-3.0146394
-2.7145
-2.4143896
-2.1143024
-1.8142339
-1.5141802
-1.2141386
-0.9141069
-0.6140833
-0.3140667
-0.014056
0.28594916
0.58594916
0.88594398
1.18593334
1.48591668
1.78589311
2.08586138
2.38581979
2.68576614
2.98569756
3.28561041

8.209E-12
2.041E-11
4.9097E-11
1.1466E-10
2.6083E-10
5.8001E-10
1.265E-09
2.7141E-09
5.7444E-09
1.2021E-08
2.4925E-08
5.1291E-08
1.049E-07
2.135E-07
4.3279E-07
8.745E-07
1.7625E-06
3.545E-06
7.1186E-06
1.4276E-05
2.86E-05
5.7247E-05
0.00011452
0.00022895
0.00045756
0.00091413
0.00182577
0.00364577
0.00727868
0.01452924
0.02899719
0.05785887
0.11540647
0.23004806
0.45802968
0.9098536
1.79927411
3.52711511
6.79919652
12.7067698
22.5074055
36.6897335
53.6242574
69.7619696
82.1528782
90.1807992
94.8250211
97.3374526
98.6474761
99.3174442
99.6566891
99.8276072

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01

1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23

23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1
23.1

-5.2048333
-5.1048798
-5.0049384
-4.9050124
-4.8051055
-4.7052228
-4.6053705
-4.5055563
-4.4057903
-4.3060846
-4.2064549
-4.1069207
-4.0075063
-3.9082425
-3.8091675
-3.7103293
-3.6117875
-3.5136162
-3.4159077
-3.3187753
-3.2223587
-3.1268284
-3.0323907
-2.9392934
-2.8478303
-2.7583443
-2.6712288
-2.586924
-2.5059092
-2.4286875
-2.3557627
-2.2876108
-2.2246454
-2.1671837
-2.1154167
-2.0693907
-2.0290022
-1.9940087
-1.9640521
-1.9386904
-1.9174333
-1.8997739
-1.8852161
-1.8732943
-1.8635856
-1.855716
-1.8493617
-1.8442472
-1.8401412
-1.8368519
-1.8342212
-1.8321201

3.58550005
3.88536061
4.18518468
4.4849629
4.78468349
5.08433161
5.3838886
5.68333096
5.98262917
6.28174612
6.58063522
6.87923797
7.17748103
7.4752725
7.77249741
8.06901214
8.36463765
8.65915128
8.95227703
9.2436741
9.53292381
9.81951491
10.102828
10.3821198
10.6565092
10.924967
11.1863137
11.439228
11.6822722
11.9139376
12.1327118
12.3371674
12.5260634
12.6984485
12.8537492
12.9918268
13.1129916
13.217971
13.3078394
13.3839218
13.4476892
13.5006611
13.5443243
13.5800737
13.6091744
13.632743
13.6517421
13.6669845
13.6791422
13.6887566
13.696247
13.7019142

99.9135026
99.956616
99.978243
99.9890889
99.9945277
99.997255
99.9986228
99.9993089
99.9996531
99.9998258
99.9999125
99.999956
99.9999778
99.9999888
99.9999944
99.9999972
99.9999986
99.9999993
99.9999996
99.9999998
99.9999999
99.9999999
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100

1
1
1
1
1

0.01
0.01
0.01
0.01
0.01

1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23
1.2589E+23

23.1
23.1
23.1
23.1
23.1

-1.8304439
-1.8291078
-1.8280436
-1.8271964
-1.8265222

13.7059367
13.7083552
13.7090402
13.7076367
13.703479

100
100
100
100
100

Diagrama de reparto de Al f(pH)


100

90

80

70

60

50

40

30

20

10

0
0

10

12

14

Diagrama de reparto de Al-EDTA


100

90

80

70

60

50

40

30

20

10

0
0

10

12

14

Hoja de Calculo
DATOS PARA EL AGENTE EXTRACTANTE (L)
Log Kd
H2OX
pKa 1
pKa 2

2.6 Kd

398.107171

5 Ka 1
9.7 Ka 2

0.00001
1.9953E-10

Oxina
Volumen Forg
Volumen Facuo
r
n*

pH

H+
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
1.1
1.2
1.3
1.4
1.5
1.6
1.7
1.8
1.9
2
2.1
2.2
2.3
2.4
2.5
2.6
2.7
2.8
2.9
3
3.1

1
0.79432823
0.63095734
0.50118723
0.39810717
0.31622777
0.25118864
0.19952623
0.15848932
0.12589254
0.1
0.07943282
0.06309573
0.05011872
0.03981072
0.03162278
0.02511886
0.01995262
0.01584893
0.01258925
0.01
0.00794328
0.00630957
0.00501187
0.00398107
0.00316228
0.00251189
0.00199526
0.00158489
0.00125893
0.001
0.00079433

D
0.00398103
0.00501181
0.00630947
0.00794312
0.00999975
0.01258886
0.0158483
0.01995162
0.02511728
0.03162026
0.03980674
0.05011241
0.06308574
0.07941698
0.09997489
0.12585274
0.15842625
0.19942628
0.25103025
0.31597678
0.39770946
0.50055707
0.62995893
0.7927465
0.99749441
1.25495689
1.57860864
1.98531218
2.49613687
3.13735675
3.94165515
4.94956104

log D
-2.4000043
-2.3000055
-2.2000069
-2.1000087
-2.0000109
-1.9000137
-1.8000173
-1.7000218
-1.6000274
-1.5000345
-1.4000434
-1.3000547
-1.2000688
-1.1000866
-1.0001091
-0.9001373
-0.8001729
-0.7002176
-0.6002739
-0.5003448
-0.4004341
-0.3005464
-0.2006878
-0.1008657
-0.0010895
0.09862881
0.19827447
0.29782881
0.3972684
0.4965639
0.59567863
0.69456668

%E (L)
0.11928849
0.15012855
0.1889266
0.23772723
0.2990952
0.37624473
0.47319921
0.59498741
0.74788295
0.93969394
1.1801092
1.4811059
1.85741909
2.32706675
2.91191122
3.63821836
4.53714653
5.64505665
7.00348186
8.65853455
10.659472
13.0561132
15.8948391
19.2130674
23.0324194
27.3512971
32.1381777
37.3274018
42.8192749
48.4856593
54.1809126
59.7564187

0.05
3
10
0.3
0.15

pL
1.82442711
1.82456123
1.82473001
1.82494241
1.82520964
1.82554583
1.8259687
1.82650046
1.82716896
1.82800908
1.82906437
1.83038921
1.83205127
1.83413451
1.83674279
1.84000392
1.84407433
1.84914408
1.85544205
1.86324077
1.87286023
1.88466969
1.89908609
1.91656762
1.93760091
1.96268088
1.99228322
2.02683104
2.06665908
2.11198059
2.16286231
2.21921212

DATOS DE COMP. DE M CON L EN


MLn
LOG BETA 1
LOG BETA 2
LOG BETA 3
LOG BETA 4
LOG BETA 5
LOG BETA 6

alpha L (H)
5.0119E+14
3.1623E+14
1.9953E+14
1.259E+14
7.9435E+13
5.012E+13
3.1624E+13
1.9954E+13
1.259E+13
7.9439E+12
5.0124E+12
3.1627E+12
1.9956E+12
1.2592E+12
7.9453E+11
5.0135E+11
3.1635E+11
1.9963E+11
1.2597E+11
7.9496E+10
5.0169E+10
3.1663E+10
1.9984E+10
1.2614E+10
7963234971
5027721269
3174866915
2005262316
1266868695
800637809
506199107
320208839

3.2
3.3
3.4
3.5
3.6
3.7
3.8
3.9
4
4.1
4.2
4.3
4.4
4.5
4.6
4.7
4.8
4.9
5
5.1
5.2
5.3
5.4
5.5
5.6
5.7
5.8
5.9
6
6.1
6.2
6.3
6.4
6.5
6.6
6.7
6.8
6.9
7
7.1
7.2
7.3
7.4
7.5
7.6
7.7
7.8
7.9
8
8.1
8.2
8.3

0.00063096
0.00050119
0.00039811
0.00031623
0.00025119
0.00019953
0.00015849
0.00012589
0.0001
7.9433E-05
6.3096E-05
5.0119E-05
3.9811E-05
3.1623E-05
2.5119E-05
1.9953E-05
1.5849E-05
1.2589E-05
0.00001
7.9433E-06
6.3096E-06
5.0119E-06
3.9811E-06
3.1623E-06
2.5119E-06
1.9953E-06
1.5849E-06
1.2589E-06
0.000001
7.9433E-07
6.3096E-07
5.0119E-07
3.9811E-07
3.1623E-07
2.5119E-07
1.9953E-07
1.5849E-07
1.2589E-07
0.0000001
7.9433E-08
6.3096E-08
5.0119E-08
3.9811E-08
3.1623E-08
2.5119E-08
1.9953E-08
1.5849E-08
1.2589E-08
0.00000001
7.9433E-09
6.3096E-09
5.0119E-09

6.21113358
7.78789338
9.7549662
12.2033501
15.2421313
19.000349
23.6280343
29.2957303
36.1915544
44.5146472
54.4637798
66.2201199
79.9239187
95.6463263
113.359665
132.911845
154.012256
176.236176
199.051599
221.866652
244.089432
265.187849
284.737042
302.446201
318.162973
331.859341
343.606028
353.542743
361.849975
368.725633
374.367775
378.963153
382.680587
385.667939
388.051517
389.936968
391.410968
392.543205
393.388374
393.98796
394.37174
394.558924
394.558924
394.37174
393.98796
393.388374
392.543205
391.410968
389.936968
388.051517
385.667939
382.680587

0.79317087
0.89142
0.98922577
1.08647907
1.1830457
1.27876158
1.37342759
1.46680433
1.55860724
1.64850294
1.73610778
1.82098996
1.90267677
1.98066829
2.05445855
2.12356369
2.18755528
2.24609506
2.29896567
2.34609203
2.38754898
2.42355362
2.45444397
2.48064813
2.50264964
2.52095405
2.53606077
2.54844193
2.55852855
2.56670333
2.57329846
2.57859699
2.58283643
2.58621354
2.58888939
2.59099441
2.59263299
2.59388746
2.59482152
2.59548295
2.59590579
2.59611187
2.59611187
2.59590579
2.59548295
2.59482152
2.59388746
2.59263299
2.59099441
2.58888939
2.58621354
2.58283643

65.0757516
70.0272873
74.5319602
78.5453996
82.0551819
85.0748601
87.6366311
89.7841588
91.5664951
93.0334921
94.2326993
95.2075229
95.9963448
96.6323047
97.1435019
97.5534302
97.881521
98.1437086
98.3529736
98.5198341
98.6527782
98.758633
98.8428753
98.90989
98.9631815
99.0055471
99.0392173
99.065969
99.0872164
99.1040847
99.117468
99.1280764
99.1364733
99.1431048
99.1483234
99.1524065
99.1555715
99.1579866
99.1597805
99.1610484
99.161858
99.1622523
99.1622523
99.161858
99.1610484
99.1597805
99.1579866
99.1555715
99.1524065
99.1483234
99.1431048
99.1364733

2.28078167
2.34718269
2.41791322
2.49238831
2.56996968
2.64999033
2.73177191
2.81463461
2.89790064
2.98089361
3.06293614
3.14334869
3.22145207
3.29657595
3.3680748
3.43535114
3.49788457
3.55526259
3.60720817
3.65359835
3.69446965
3.73000855
3.76052859
3.78643841
3.80820598
3.82632451
3.84128357
3.85354743
3.86354091
3.87164177
3.87817826
3.8834303
3.88763296
3.89098102
3.89363401
3.89572115
3.89734586
3.89858976
3.89951596
3.90017184
3.90059113
3.90079548
3.90079548
3.90059113
3.90017184
3.89951596
3.89858976
3.89734586
3.89572115
3.89363401
3.89098102
3.88763296

202688510
128404429
81428086.8
51703617.6
32881703
20952624.1
13383583.4
8574240.69
5513060.57
3560385.83
2311491.08
1510115.05
993855.466
659677.553
442121.307
299527.231
205326.365
142529.558
100238.447
71434.4937
51576.3998
37709.1184
27896.9055
20861.8043
15752.5318
11996.2623
9203.20776
7104.90168
5514.05957
4298.29947
3362.80389
2638.77897
2075.69514
1636.01192
1291.54819
1020.95262
807.917489
639.900627
507.199106
402.269448
319.223028
253.447569
201.32056
159.990506
127.208769
101.199526
80.558716
64.1751673
51.1688421
40.8423398
32.6427292
26.1314536

8.4
8.5
8.6
8.7
8.8
8.9
9
9.1
9.2
9.3
9.4
9.5
9.6
9.7
9.8
9.9
10
10.1
10.2
10.3
10.4
10.5
10.6
10.7
10.8
10.9
11
11.1
11.2
11.3
11.4
11.5
11.6
11.7
11.8
11.9
12
12.1
12.2
12.3
12.4
12.5
12.6
12.7
12.8
12.9
13
13.1
13.2
13.3
13.4
13.5

3.9811E-09
3.1623E-09
2.5119E-09
1.9953E-09
1.5849E-09
1.2589E-09
1E-09
7.9433E-10
6.3096E-10
5.0119E-10
3.9811E-10
3.1623E-10
2.5119E-10
1.9953E-10
1.5849E-10
1.2589E-10
1E-10
7.9433E-11
6.3096E-11
5.0119E-11
3.9811E-11
3.1623E-11
2.5119E-11
1.9953E-11
1.5849E-11
1.2589E-11
1E-11
7.9433E-12
6.3096E-12
5.0119E-12
3.9811E-12
3.1623E-12
2.5119E-12
1.9953E-12
1.5849E-12
1.2589E-12
1E-12
7.9433E-13
6.3096E-13
5.0119E-13
3.9811E-13
3.1623E-13
2.5119E-13
1.9953E-13
1.5849E-13
1.2589E-13
1E-13
7.9433E-14
6.3096E-14
5.0119E-14
3.9811E-14
3.1623E-14

378.963153
374.367775
368.725633
361.849975
353.542743
343.606028
331.859341
318.162973
302.446201
284.737042
265.187849
244.089432
221.866652
199.051599
176.236176
154.012256
132.911845
113.359665
95.6463263
79.9239187
66.2201199
54.4637798
44.5146472
36.1915544
29.2957303
23.6280343
19.000349
15.2421313
12.2033501
9.7549662
7.78789338
6.21113358
4.94956104
3.94165515
3.13735675
2.49613687
1.98531218
1.57860864
1.25495689
0.99749441
0.7927465
0.62995893
0.50055707
0.39770946
0.31597678
0.25103025
0.19942628
0.15842625
0.12585274
0.09997489
0.07941698
0.06308574

2.57859699
2.57329846
2.56670333
2.55852855
2.54844193
2.53606077
2.52095405
2.50264964
2.48064813
2.45444397
2.42355362
2.38754898
2.34609203
2.29896567
2.24609506
2.18755528
2.12356369
2.05445855
1.98066829
1.90267677
1.82098996
1.73610778
1.64850294
1.55860724
1.46680433
1.37342759
1.27876158
1.1830457
1.08647907
0.98922577
0.89142
0.79317087
0.69456668
0.59567863
0.4965639
0.3972684
0.29782881
0.19827447
0.09862881
-0.0010895
-0.1008657
-0.2006878
-0.3005464
-0.4004341
-0.5003448
-0.6002739
-0.7002176
-0.8001729
-0.9001373
-1.0001091
-1.1000866
-1.2000688

99.1280764
99.117468
99.1040847
99.0872164
99.065969
99.0392173
99.0055471
98.9631815
98.90989
98.8428753
98.758633
98.6527782
98.5198341
98.3529736
98.1437086
97.881521
97.5534302
97.1435019
96.6323047
95.9963448
95.2075229
94.2326993
93.0334921
91.5664951
89.7841588
87.6366311
85.0748601
82.0551819
78.5453996
74.5319602
70.0272873
65.0757516
59.7564187
54.1809126
48.4856593
42.8192749
37.3274018
32.1381777
27.3512971
23.0324194
19.2130674
15.8948391
13.0561132
10.659472
8.65853455
7.00348186
5.64505665
4.53714653
3.63821836
2.91191122
2.32706675
1.85741909

3.8834303
3.87817826
3.87164177
3.86354091
3.85354743
3.84128357
3.82632451
3.80820598
3.78643841
3.76052859
3.73000855
3.69446965
3.65359835
3.60720817
3.55526259
3.49788457
3.43535114
3.3680748
3.29657595
3.22145207
3.14334869
3.06293614
2.98089361
2.89790064
2.81463461
2.73177191
2.64999033
2.56996968
2.49238831
2.41791322
2.34718269
2.28078167
2.21921212
2.16286231
2.11198059
2.06665908
2.02683104
1.99228322
1.96268088
1.93760091
1.91656762
1.89908609
1.88466969
1.87286023
1.86324077
1.85544205
1.84914408
1.84407433
1.84000392
1.83674279
1.83413451
1.83205127

20.9605664
16.8539438
13.5924164
11.0019953
8.94454127
7.31036777
6.01237352
4.98138793
4.16247719
3.51201232
2.99534175
2.58494331
2.25895703
2.00001995
1.79434082
1.63096529
1.50119225
1.39811033
1.31622976
1.2511899
1.19952703
1.15848982
1.12589286
1.1000002
1.07943295
1.06309581
1.05011877
1.03981075
1.0316228
1.02511888
1.01995263
1.01584894
1.01258926
1.01
1.00794328
1.00630957
1.00501187
1.00398107
1.00316228
1.00251189
1.00199526
1.00158489
1.00125893
1.001
1.00079433
1.00063096
1.00050119
1.00039811
1.00031623
1.00025119
1.00019953
1.00015849

13.6
13.7
13.8
13.9
14

2.5119E-14
1.9953E-14
1.5849E-14
1.2589E-14
1E-14

0.05011241
0.03980674
0.03162026
0.02511728
0.01995162

-1.3000547 1.4811059 1.83038921 1.00012589


-1.4000434 1.1801092 1.82906437
1.0001
-1.5000345 0.93969394 1.82800908 1.00007943
-1.6000274 0.74788295 1.82716896 1.0000631
-1.7000218 0.59498741 1.82650046 1.00005012

Hoja de Calculo para la Extraccion de Quelatos meatlicos MLn

ATOS DE COMP. DE M CON L EN FASE ACUOSADATOS DE COMP. DE M CON OH EN FASE ACUOSA


MOHn
-10 BETA 1
1E-10 LOG BETA 1
-10 BETA 1
1E-10
-10 BETA 2
1E-10 LOG BETA 2
-10 BETA 2
1E-10
-10 BETA 3
1E-10 LOG BETA 3
-10 BETA 3
1E-10
-10 BETA 4
1E-10 LOG BETA 4
33.3 BETA 4
1.9953E+33
-10 BETA 5
1E-10 LOG BETA 5
-10 BETA 5
1E-10
-10 BETA 6
1E-10 LOG BETA 6
-10 BETA 6
1E-10

L libre
alpha M (L) LOG alpha M(L)
OH
alpha M (L)
2.9893E-17
1
0
1E-14
1
4.7362E-17
1
0 1.2589E-14
1
7.5035E-17
1
0 1.5849E-14
1
1.1886E-16
1
0 1.9953E-14
1
1.8827E-16
1
0 2.5119E-14
1
2.9815E-16
1
0 3.1623E-14
1
4.7208E-16
1
0 3.9811E-14
1
7.4727E-16
1
0 5.0119E-14
1
1.1825E-15
1
0 6.3096E-14
1
1.8705E-15
1
0 7.9433E-14
1
2.9573E-15
1
0
1E-13
1
4.6726E-15
1
0 1.2589E-13
1
7.377E-15
1
0 1.5849E-13
1
1.1635E-14
1
0 1.9953E-13
1
1.8329E-14
1
0 2.5119E-13
1
2.8831E-14
1
0 3.1623E-13
1
4.5264E-14
1
0 3.9811E-13
1
7.0899E-14
1
0 5.0119E-13
1
1.1073E-13
1
0 6.3096E-13
1
1.7235E-13
1
0 7.9433E-13
1
2.6712E-13
1
0
1E-12
1
4.1189E-13
1
0 1.2589E-12
1
6.3129E-13
1
0 1.5849E-12
1
9.6065E-13
1
0 1.9953E-12
1
1.4498E-12
1
0 2.5119E-12
1
2.1674E-12
1
0 3.1623E-12
1
3.2062E-12
1
0 3.9811E-12
1
4.6881E-12
1
0 5.0119E-12
1
6.7703E-12
1
0 6.3096E-12
1
9.6512E-12
1
0 7.9433E-12
1
1.3577E-11
1
0
1E-11
1
1.8852E-11
1
0 1.2589E-11
1

LOGalphaM(L)
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
9.6433E-17
9.6433E-17
3.8573E-16
8.6789E-16
2.218E-15
5.4967E-15
1.3693E-14
3.4523E-14
8.6693E-14
2.1765E-13
5.4677E-13
1.3734E-12
3.4497E-12
8.6654E-12
2.1766E-11

2.5846E-11
3.5014E-11
4.6915E-11
6.2243E-11
8.1861E-11
1.0685E-10
1.3857E-10
1.7872E-10
2.2946E-10
2.935E-10
3.7426E-10
4.7604E-10
6.0426E-10
7.6576E-10
9.6913E-10
1.2252E-09
1.5476E-09
1.9536E-09
2.4647E-09
3.1081E-09
3.9181E-09
4.9379E-09
6.2218E-09
7.8381E-09
9.8729E-09
1.2435E-08
1.5659E-08
1.9719E-08
2.4831E-08
3.1265E-08
3.9366E-08
4.9564E-08
6.2403E-08
7.8566E-08
9.8913E-08
1.2453E-07
1.5678E-07
1.9738E-07
2.4849E-07
3.1283E-07
3.9384E-07
4.9581E-07
6.2419E-07
7.858E-07
9.8926E-07
1.2454E-06
1.5678E-06
1.9737E-06
2.4847E-06
3.1279E-06
3.9376E-06
4.9568E-06

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
9.6433E-17
9.6433E-17
9.6433E-17
9.6433E-17
9.6433E-17
1.9287E-16
1.9287E-16

1.5849E-11
1.9953E-11
2.5119E-11
3.1623E-11
3.9811E-11
5.0119E-11
6.3096E-11
7.9433E-11
1E-10
1.2589E-10
1.5849E-10
1.9953E-10
2.5119E-10
3.1623E-10
3.9811E-10
5.0119E-10
6.3096E-10
7.9433E-10
1E-09
1.2589E-09
1.5849E-09
1.9953E-09
2.5119E-09
3.1623E-09
3.9811E-09
5.0119E-09
6.3096E-09
7.9433E-09
0.00000001
1.2589E-08
1.5849E-08
1.9953E-08
2.5119E-08
3.1623E-08
3.9811E-08
5.0119E-08
6.3096E-08
7.9433E-08
0.0000001
1.2589E-07
1.5849E-07
1.9953E-07
2.5119E-07
3.1623E-07
3.9811E-07
5.0119E-07
6.3096E-07
7.9433E-07
0.000001
1.2589E-06
1.5849E-06
1.9953E-06

1
1
1
1
1.00000001
1.00000001
1.00000003
1.00000008
1.0000002
1.0000005
1.00000126
1.00000316
1.00000794
1.00001995
1.00005012
1.00012589
1.00031623
1.00079433
1.00199526
1.00501187
1.01258925
1.03162278
1.07943282
1.19952623
1.50118723
2.25892541
4.16227766
8.94328235
20.9526231
51.1187234
126.892541
317.227766
795.328235
1996.26231
5012.87234
12590.2541
31623.7766
79433.8235
199527.231
501188.234
1258926.41
3162278.66
7943283.35
19952624.1
50118724.4
125892542
316227767
794328236
1995262316
5011872337
1.2589E+10
3.1623E+10

5.4674E-11
1.3734E-10
3.4497E-10
8.6653E-10
2.1766E-09
5.4674E-09
1.3734E-08
3.4497E-08
8.6653E-08
2.1766E-07
5.4674E-07
1.3734E-06
3.4497E-06
8.6652E-06
2.1766E-05
5.4671E-05
0.00013731
0.00034484
0.00086567
0.00217119
0.00543331
0.01352092
0.03319562
0.07900975
0.17643486
0.35390189
0.61933105
0.95149694
1.3212384
1.70858
2.10343609
2.50137119
2.9005464
3.30021761
3.70008664
4.1000345
4.50001373
4.90000547
5.30000218
5.70000087
6.10000034
6.50000014
6.90000005
7.30000002
7.70000001
8.1
8.5
8.9
9.3
9.7
10.1
10.5

6.2397E-06
7.8545E-06
9.8869E-06
1.2445E-05
1.5664E-05
1.9714E-05
2.481E-05
3.1221E-05
3.9283E-05
4.9421E-05
6.2165E-05
7.8177E-05
9.8286E-05
0.00012353
0.00015518
0.00019484
0.00024446
0.00030647
0.00038379
0.00047998
0.0005993
0.00074674
0.00092813
0.00115002
0.00141961
0.00174444
0.00213192
0.00258867
0.00311954
0.0037266
0.00440796
0.00515691
0.00596149
0.00680481
0.00766626
0.00852333
0.00935401
0.01013891
0.01086295
0.01151621
0.01209391
0.01259581
0.01302519
0.01338769
0.01369035
0.01394068
0.01414615
0.01431373
0.0144497
0.01455956
0.01464802
0.01471905

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

2.893E-16
3.8573E-16
3.8573E-16
5.786E-16
6.7503E-16
8.6789E-16
1.0608E-15
1.3501E-15
1.7358E-15
2.1215E-15
2.7001E-15
3.3751E-15
4.243E-15
5.4002E-15
6.7503E-15
8.4861E-15
1.0608E-14
1.3308E-14
1.6683E-14
2.0829E-14
2.6037E-14
3.2401E-14
4.0309E-14
5.0049E-14
6.1717E-14
7.5893E-14
9.2768E-14
1.1273E-13
1.3587E-13
1.6239E-13
1.9229E-13
2.2507E-13
2.6046E-13
2.9759E-13
3.3549E-13
3.7339E-13
4.1003E-13
4.4475E-13
4.7696E-13
5.0598E-13
5.3173E-13
5.5401E-13
5.731E-13
5.893E-13
6.028E-13
6.1399E-13
6.2315E-13
6.3057E-13
6.3675E-13
6.4157E-13
6.4562E-13
6.488E-13

2.5119E-06
3.1623E-06
3.9811E-06
5.0119E-06
6.3096E-06
7.9433E-06
0.00001
1.2589E-05
1.5849E-05
1.9953E-05
2.5119E-05
3.1623E-05
3.9811E-05
5.0119E-05
6.3096E-05
7.9433E-05
0.0001
0.00012589
0.00015849
0.00019953
0.00025119
0.00031623
0.00039811
0.00050119
0.00063096
0.00079433
0.001
0.00125893
0.00158489
0.00199526
0.00251189
0.00316228
0.00398107
0.00501187
0.00630957
0.00794328
0.01
0.01258925
0.01584893
0.01995262
0.02511886
0.03162278
0.03981072
0.05011872
0.06309573
0.07943282
0.1
0.12589254
0.15848932
0.19952623
0.25118864
0.31622777

7.9433E+10
1.9953E+11
5.0119E+11
1.2589E+12
3.1623E+12
7.9433E+12
1.9953E+13
5.0119E+13
1.2589E+14
3.1623E+14
7.9433E+14
1.9953E+15
5.0119E+15
1.2589E+16
3.1623E+16
7.9433E+16
1.9953E+17
5.0119E+17
1.2589E+18
3.1623E+18
7.9433E+18
1.9953E+19
5.0119E+19
1.2589E+20
3.1623E+20
7.9433E+20
1.9953E+21
5.0119E+21
1.2589E+22
3.1623E+22
7.9433E+22
1.9953E+23
5.0119E+23
1.2589E+24
3.1623E+24
7.9433E+24
1.9953E+25
5.0119E+25
1.2589E+26
3.1623E+26
7.9433E+26
1.9953E+27
5.0119E+27
1.2589E+28
3.1623E+28
7.9433E+28
1.9953E+29
5.0119E+29
1.2589E+30
3.1623E+30
7.9433E+30
1.9953E+31

10.9
11.3
11.7
12.1
12.5
12.9
13.3
13.7
14.1
14.5
14.9
15.3
15.7
16.1
16.5
16.9
17.3
17.7
18.1
18.5
18.9
19.3
19.7
20.1
20.5
20.9
21.3
21.7
22.1
22.5
22.9
23.3
23.7
24.1
24.5
24.9
25.3
25.7
26.1
26.5
26.9
27.3
27.7
28.1
28.5
28.9
29.3
29.7
30.1
30.5
30.9
31.3

0.01477597
0.0148215
0.01485787
0.01488688
0.01491

1
1
1
1
1

6.5131E-13
6.5333E-13
6.5487E-13
6.5622E-13
6.5729E-13

0.39810717
0.50118723
0.63095734
0.79432823
1

5.0119E+31
1.2589E+32
3.1623E+32
7.9433E+32
1.9953E+33

31.7
32.1
32.5
32.9
33.3

os MLn
DATOS DE COMP. DE M CON X EN FASE ACUOSA DATOS DE LA EXTRACCION MLn
MXn
LOG BETA 1
-10 BETA 1
1E-10 M + nL
MLnorg
LOG BETA 2
-10 BETA 2
1E-10
LOG BETA 3
-10 BETA 3
1E-10 n
3
LOG BETA 4
-10 BETA 4
1E-10 Log K extraccion
31
LOG BETA 5
-10 BETA 5
1E-10
LOG BETA 6
-10 BETA 6
1E-10
HX
LOG BETA 1
-10 BETA 1
1E-10
LOG BETA 2
-10 BETA 2
1E-10
LOG BETA 3
-10 BETA 3
1E-10
LOG BETA 4
-10 BETA 4
1E-10
Conc X

-10

alpha X (H) X libre


1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10

alphaM(X)
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091

LOGalphaM(X)
pL libre
Log D" M
3.9479E-05 -16.524431 -18.573334
3.9479E-05 -16.324567
-17.97374
3.9479E-05 -16.124737
-17.37425
3.9479E-05 -15.924951 -16.774893
3.9479E-05 -15.725221 -16.175701
3.9479E-05
-15.52556 -15.576718
3.9479E-05 -15.325986 -14.977997
3.9479E-05 -15.126522 -14.379606
3.9479E-05 -14.927196 -13.781629
3.9479E-05 -14.728044
-13.18417
3.9479E-05 -14.529108 -12.587363
3.9479E-05 -14.330444 -11.991371
3.9479E-05
-14.13212
-11.3964
3.9479E-05 -13.934221 -10.802703
3.9479E-05 -13.736852 -10.210595
3.9479E-05 -13.540141 -9.6204632
3.9479E-05 -13.344247 -9.0327811
3.9479E-05 -13.149362 -8.4481246
3.9479E-05 -12.955716 -7.8671874
3.9479E-05 -12.763586 -7.2907963
3.9479E-05 -12.573294 -6.7199224
3.9479E-05 -12.385216 -6.1556877
3.9479E-05 -12.199774 -5.5993611
3.9479E-05 -12.017433 -5.0523393
3.9479E-05
-11.83869 -4.5161108
3.9479E-05 -11.664052 -3.9921957
3.9479E-05 -11.494009 -3.4820657
3.9479E-05 -11.329002 -2.9870462
3.9479E-05 -11.169391 -2.5082115
3.9479E-05 -11.015417 -2.0462896
3.9479E-05 -10.867184 -1.6015905
3.9479E-05 -10.724645 -1.1739758

%E MLn org
8.0129E-18
3.187E-17
1.2673E-16
5.0377E-16
2.0018E-15
7.9507E-15
3.1559E-14
1.2517E-13
4.9601E-13
1.9631E-12
7.7582E-12
3.0602E-11
1.2043E-10
4.7252E-10
1.8473E-09
7.1888E-09
2.7819E-08
1.069E-07
4.0732E-07
1.5358E-06
5.7174E-06
2.0962E-05
7.5467E-05
0.00026594
0.00091413
0.0030543
0.00988582
0.03089875
0.09300485
0.26894416
0.74521602
1.97017009

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10

1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091

3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05

-10.587611
-10.455763
-10.328687
-10.205909
-10.086924
-9.9712288
-9.8583443
-9.7478303
-9.6392934
-9.5323907
-9.4268284
-9.3223587
-9.2187753
-9.1159077
-9.0136162
-8.9117875
-8.8103293
-8.7091675
-8.6082425
-8.5075063
-8.4069207
-8.3064549
-8.2060846
-8.1057903
-8.0055563
-7.9053705
-7.8052228
-7.7051055
-7.6050124
-7.5049384
-7.4048798
-7.3048333
-7.2047965
-7.1047675
-7.0047446
-6.9047267
-6.8047129
-6.7047023
-6.6046944
-6.5046889
-6.4046853
-6.3046836
-6.2046836
-6.1046853
-6.0046889
-5.9046944
-5.8047023
-5.7047129
-5.6047267
-5.5047446
-5.4047675
-5.3047965

-0.7628719
-0.3673276
0.01389816
0.38223279
0.73918857
1.08627426
1.42492754
1.75646965
2.08208022
2.40278828
2.71947488
3.03288296
3.34363117
3.65222888
3.95909003
4.2645435
4.56883536
4.87211312
5.17436743
5.47527055
5.77376567
6.06707603
6.34851393
6.60358651
6.8068698
6.92996923
6.96499108
6.93318213
6.86372261
6.77660391
6.6819242
6.58412873
6.48506396
6.38547993
6.28567948
6.18578529
6.08584764
5.98588765
5.88591451
5.78593248
5.68594363
5.58594902
5.48594911
5.38594396
5.28593333
5.18591668
5.08589311
4.98586138
4.88581979
4.78576614
4.68569756
4.58561041

4.92402398
11.4075041
23.6498884
41.9737938
62.2006084
78.5374514
88.8651885
94.4822824
97.3147953
98.6986277
99.3680964
99.6919255
99.8491338
99.925813
99.9633875
99.9818759
99.9910049
99.9955255
99.997769
99.9988842
99.9994388
99.9997144
99.9998506
99.999917
99.999948
99.9999608
99.9999639
99.9999611
99.9999544
99.9999442
99.9999307
99.9999132
99.9998909
99.9998628
99.9998273
99.9997827
99.9997265
99.9996557
99.9995665
99.9994543
99.999313
99.9991352
99.9989113
99.9986293
99.9982744
99.9978275
99.9972649
99.9965565
99.9956645
99.9945413
99.9931269
99.9913457

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10
-10

1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091
1.00009091

3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05

-5.2048333
-5.1048798
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4.48550005
4.38536061
4.28518468
4.1849629
4.08468349
3.98433161
3.8838886
3.78333096
3.68262917
3.58174612
3.48063522
3.37923797
3.27748103
3.1752725
3.07249741
2.96901214
2.86463765
2.75915128
2.65227703
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2.43292381
2.31951491
2.20282798
2.08211979
1.95650917
1.82496704
1.68631374
1.53922805
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-5.4026635
-5.7963603

99.9891024
99.9862767
99.982717
99.9782319
99.9725795
99.9654541
99.9564688
99.9451332
99.930825
99.9127524
99.8899056
99.860993
99.8243556
99.777853
99.7187076
99.6432905
99.5468223
99.4229491
99.263132
99.0557557
98.7848075
98.4278933
97.9532278
97.3150334
96.4465021
95.2491344
93.5770526
91.2154577
87.8556035
83.0787949
76.3855418
67.3416162
55.9120183
42.8858449
29.9443239
18.9532891
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5.87235374
2.96413069
1.4282441
0.66363555
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0.13209881
0.05714656
0.02433654
0.01023125
0.00425616
0.00175538
0.00071894
0.0002928
0.0001187
4.7947E-05

1
1
1
1
1

-10
-10
-10
-10
-10

1.00009091
1.00009091
1.00009091
1.00009091
1.00009091

3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05
3.9479E-05

-1.8304439
-1.8291078
-1.8280436
-1.8271964
-1.8265222

-6.1913317 1.931E-05
-6.5873234 7.7589E-06
-6.9841307 3.1116E-06
-7.3815891 1.246E-06
-7.7795667 4.9837E-07

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